Abstract: The present invention discloses a boron-containing plastic crystal polymer and a preparation method therefor and an application thereof. The described preparation method comprises the following step: curing a mixture containing a plastic crystal, a metal salt, a monomer and a photoinitiator. The plastic crystal polymer prepared by the present invention can be used as all-solid electrolyte, without any liquid additive being added therein. The obtained electrolyte has a room-temperature ionic conductivity up to 3.6×10?4 S/cm, and shows a high sodium ion transference number and a wide electrochemical window up to 4.7V. The present invention further prepares composite positive and negative electrodes for positive and negative electrode modification of a sodium ion battery. A finally assembled all-solid sodium ion battery shows good rate performance and cycle stability at room temperature, achieving a specific discharge capacity up to 104.8 mAh/g at room temperature and a capacity retention ratio of 85.

Abstract: The present invention relates to an electrolyte, an additive thereof, a secondary cell, and an application thereof. An organic electrolyte according to a first aspect of the invention comprises a salt, a phosphate ester and a fluoroether, and does not comprise a carbonate ester. The salt is a lithium salt or a sodium salt. The electrolyte according to a second aspect of the invention comprises a base electrolyte and an additive. The base electrolyte comprises a sodium salt and a flame retardant solvent. The flame retardant solvent comprises a phosphate ester and a fluoroether. The additive comprises a fluorine-containing additive. The electrolyte and the secondary cell of the present invention increase safety.

Abstract: A vanadium sodium phosphate positive electrode material, a sodium ion battery, and a preparation method therefor and application thereof. The preparation method of the vanadium sodium phosphate positive electrode material comprises the following steps: (1) reacting an aqueous solution containing a vanadium source with a phosphorus source, a reducing agent, a sodium source, and a carbon source, the reaction comprising first performing a reaction of an aqueous solution of the vanadium source and the phosphorus source, and then perform a reaction with the reducing agent, or first performing a reaction of the aqueous solution of the vanadium source with the reducing agent and then performing a reaction with the phosphorus source; (2) drying and calcining the reaction liquid obtained in step (1). The vanadium sodium phosphate positive electrode material has a high dispersibility, and has stable circulation performance when used in a battery.

Abstract: The present invention discloses a boron-containing plastic crystal polymer and a preparation method therefor and an application thereof. The described preparation method comprises the following step: curing a mixture containing a plastic crystal, a metal salt, a monomer and a photoinitiator. The plastic crystal polymer prepared by the present invention can be used as all-solid electrolyte, without any liquid additive being added therein. The obtained electrolyte has a room-temperature ionic conductivity up to 3.6×10?4 S/cm, and shows a high sodium ion transference number and a wide electrochemical window up to 4.7V. The present invention further prepares composite positive and negative electrodes for positive and negative electrode modification of a sodium ion battery. A finally assembled all-solid sodium ion battery shows good rate performance and cycle stability at room temperature, achieving a specific discharge capacity up to 104.8 mAh/g at room temperature and a capacity retention ratio of 85.

Abstract: The present invention relates to an electrolyte, an additive thereof, a secondary cell, and an application thereof. An organic electrolyte according to a first aspect of the invention comprises a salt, a phosphate ester and a fluoroether, and does not comprise a carbonate ester. The salt is a lithium salt or a sodium salt. The electrolyte according to a second aspect of the invention comprises a base electrolyte and an additive. The base electrolyte comprises a sodium salt and a flame retardant solvent. The flame retardant solvent comprises a phosphate ester and a fluoroether. The additive comprises a fluorine-containing additive. The electrolyte and the secondary cell of the present invention increase safety.

Abstract: A vanadium sodium phosphate positive electrode material, a sodium ion battery, and a preparation method therefor and application thereof. The preparation method of the vanadium sodium phosphate positive electrode material comprises the following steps: (1) reacting an aqueous solution containing a vanadium source with a phosphorus source, a reducing agent, a sodium source, and a carbon source, the reaction comprising first performing a reaction of an aqueous solution of the vanadium source and the phosphorus source, and then perform a reaction with the reducing agent, or first performing a reaction of the aqueous solution of the vanadium source with the reducing agent and then performing a reaction with the phosphorus source; (2) drying and calcining the reaction liquid obtained in step (1). The vanadium sodium phosphate positive electrode material has a high dispersibility, and has stable circulation performance when used in a battery.

Abstract: Provided are an active electrode material composition for a lithium-ion secondary battery, an electrode for a lithium-ion secondary battery, and a lithium-ion secondary battery using the active electrode material composition. The active electrode material composition includes an active electrode material and a binder. The binder is characterized by existing in the form of a polyamide-amic acid compound in an electrode paste, and forming a polyamide-imide compound with excellent stability by means of high-temperature curing. The electrode paste is a water-based paste, which can avoid the use of an organic solvent in the electrode paste making process, and the obtained electrode has excellent structural stability and the battery performance is improved.