Patents by Inventor Zuyi Zhang
Zuyi Zhang has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20140313391Abstract: An imaging apparatus for imaging a subject image from a lens on an imaging element through an optical filter has a porous body having pores which three dimensionally communicate with each other at least at a side opposite to the imaging element of the optical filter.Type: ApplicationFiled: July 1, 2014Publication date: October 23, 2014Inventors: Zuyi Zhang, Yoshinori Kotani, Akira Sugiyama, Kenji Takashima, Naoyuki Koketsu
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Publication number: 20140305166Abstract: The present invention provides an optical member having a high transmittance, wherein a composition change of a phase-separable base material glass film is suppressed. A method for manufacturing an optical member provided with a porous glass film on the base member includes the steps of forming a glass powder film containing a glass powder on the base member, forming a phase-separable base material glass film on the base member by heating and fusing the glass powder film in an atmosphere having an oxygen concentration of more than 20%, forming a phase-separated glass film on the base member by heating the base material glass film, and forming a porous glass film on the base member by subjecting the phase-separated glass film to an etching treatment.Type: ApplicationFiled: October 18, 2012Publication date: October 16, 2014Inventors: Naoyuki Koketsu, Zuyi Zhang, Yoshinori Kotani, Akiko Takei, Akira Sugiyama, Kenji Takashima
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Publication number: 20140299573Abstract: The present invention provides a method for producing a porous glass layer easily, wherein a ripple is suppressed. A method for manufacturing an optical member provided with a porous glass layer on a base member includes the steps of forming an intermediate layer containing at least one of silicon, potassium, and aluminum on the base member, forming a phase-separable glass layer on the intermediate layer, forming a phase-separated glass layer on the base member by heating the intermediate layer and the phase-separable glass layer at a temperature higher than or equal to the glass transition temperature of the phase-separable glass layer, and forming a porous glass layer on the base member by subjecting the phase-separated glass layer to an etching treatment.Type: ApplicationFiled: December 11, 2012Publication date: October 9, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Kenji Takashima, Zuyi Zhang, Yoshinori Kotani, Akiko Takei, Akira Sugiyama, Naoyuki Koketsu
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Publication number: 20140293114Abstract: The present invention provides an optical member including a porous glass film on a base member, wherein a ripple is suppressed. The optical member includes the base member and the porous glass film disposed on the base member, wherein the porosity increases in the direction from the base member toward the porous glass film in an interfacial region between the base member and the porous glass film and the porosity is continuous in the film thickness direction from the base member to the surface of the porous glass film in the optical member.Type: ApplicationFiled: November 12, 2012Publication date: October 2, 2014Inventors: Naoyuki Koketsu, Zuyi Zhang, Yoshinori Kotani, Akiko Takei, Akira Sugiyama, Kenji Takashima
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Patent number: 8804140Abstract: An imaging apparatus for imaging a subject image from a lens on an imaging element through an optical filter has a porous body having pores which three dimensionally communicate with each other at least at a side opposite to the imaging element of the optical filter.Type: GrantFiled: June 25, 2012Date of Patent: August 12, 2014Assignee: Canon Kabushiki KaishaInventors: Zuyi Zhang, Yoshinori Kotani, Akira Sugiyama, Kenji Takashima, Naoyuki Koketsu
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Patent number: 8674163Abstract: A DNA hybrid which comprises a porous oxide matrix and DNA immobilized thereon, and is useful for environmental clean-up, where the hybrid is prepared by removing a dispersion medium from a dispersion of colloidal oxide and DNA.Type: GrantFiled: January 16, 2007Date of Patent: March 18, 2014Assignee: Canon Kabushiki KaishaInventors: Zuyi Zhang, Teigo Sakakibara, Yoshinori Kotani, Norio Nishi
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Publication number: 20130333419Abstract: A method for manufacturing a porous glass includes: forming a phase-separated glass by heating at a temperature in a range of 300 to 500 degrees Celsius for 3 to 50 hours for phase separation of a glass body in which the concentration of SiO2 is 50 to 70 percent by weight, the concentration of B2O3 is 15 to 40 percent by weight, the concentration of Li2O is 1.0 to 8.0 percent by weight, the concentration of Na2O is 2.0 to 8.0 percent by weight, the concentration of K2O is 0.3 to 5.0 percent by weight, the total concentration of Li2O, Na2O, and K2O is 3.5 to 15 percent by weight, and the ratio of the concentration of K2O to the total concentration of Li2O, Na2O, and K2O is 0.10 to 0.30; and forming a porous glass by etching the phase-separated glass.Type: ApplicationFiled: February 20, 2012Publication date: December 19, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Naoyuki Koketsu, Zuyi Zhang, Yoshinori Kotani, Akira Sugiyama, Kenji Takashima
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Publication number: 20130233018Abstract: To provide a method of manufacturing a porous glass in which the porosity decreases as a function of the distance from the surface in the direction of depth. A method of manufacturing a porous glass includes a step of bringing one or more than one ion species selected from silver ion, potassium ion and lithium ion into contact with a matrix glass containing borosilicate glass as main ingredient and heating the matrix glass to form a glass body having an ion concentration distribution with a concentration of the one or more than one ion species decreasing as a function of a distance from a surface in a direction of depth, a step of heating and phase-separating the glass body to form a phase-separated glass, and a step of etching the phase-separated glass to form a porous glass having a porosity decreasing as the function of the distance from the surface in the direction of depth.Type: ApplicationFiled: November 25, 2011Publication date: September 12, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Kenji Takashima, Zuyi Zhang, Yoshinori Kotani, Akira Sugiyama, Naoyuki Koketsu
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Publication number: 20130224494Abstract: This invention provides a porous glass with a varied porous structure that shows an excellent optical performance. A method of manufacturing a porous glass comprising: a first step of forming a surface layer containing a boron compound and an alkali metal compound as main ingredients on a matrix glass containing a silicon oxide, a boron oxide and an alkali metal oxide; a second step of heat treatment the matrix glass and the surface layer for phase separation to form a phase-separated glass; and a third step of acid treatment the phase-separated glass to form the porous glass having pores.Type: ApplicationFiled: November 25, 2011Publication date: August 29, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Yoshinori Kotani, Zuyi Zhang, Akira Sugiyama, Kenji Takashima, Naoyuki Koketsu
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Publication number: 20130216775Abstract: Provided is an optical member having high strength, low reflection, and a high transmittance. The optical member includes: a transparent substrate; and a porous glass layer having a spinodal-type porous structure disposed on the transparent substrate, in which at least one of the average pore diameter of a pore formed in the porous glass layer and the average skeleton diameter of a skeleton of the porous glass layer is set so that the optical member has a transmittance of 50% or more in the wavelength region of 450 nm or more and 650 nm or less.Type: ApplicationFiled: November 1, 2011Publication date: August 22, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Akira Sugiyama, Zuyi Zhang, Yoshinori Kotani, Kenji Takashima, Naoyuki Koketsu
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Publication number: 20130194483Abstract: A porous glass having high strength and a low refractive index, an optical member by using the porous glass, and a method for manufacturing the porous glass are provided. A method for manufacturing a porous glass includes the steps of heat-treating a glass body, which can be phase-separated through heating and which is formed from a plurality of components, at a first temperature to effect the phase separation, heat-treating the glass body, which has been heat-treated at the first temperature, at a second temperature, higher than the first temperature, to effect the phase separation, and bringing the glass body, which has been heat-treated at the second temperature, into contact with an aqueous solution, wherein the total time of the heat treatment time at the first temperature and the heat treatment time at the second temperature is 7 hours or more.Type: ApplicationFiled: September 21, 2011Publication date: August 1, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Kenji Takashima, Zuyi Zhang, Yoshinori Kotani, Akira Sugiyama
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Publication number: 20130192306Abstract: There is provided a method for producing a porous glass having high porosity and nanosized pores even at a deeper portion in the glass. A method for producing a porous glass includes the steps of preparing a glass body containing boron, subjecting the glass body to heat treatment for phase separation, and bringing the phase-separated glass body into contact with a boron-containing solution having a boron concentration of 5 to 140 ppm.Type: ApplicationFiled: September 16, 2011Publication date: August 1, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Akira Sugiyama, Zuyi Zhang, Yoshinori Kotani, Kenji Takashima
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Publication number: 20130157026Abstract: The present invention provides a porous glass having excellent antireflection performance for visible light. A porous glass includes a porous layer which is mainly composed of silica and which has pores attributed to spinodal phase separation and pores attributed to binodal phase separation.Type: ApplicationFiled: August 25, 2011Publication date: June 20, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Yoshinori Kotani, Zuyi Zhang, Kenji Takashima, Akira Sugiyama
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Publication number: 20130074548Abstract: Provided is a method of producing porous glass having pores with a uniform pore diameter entirely, particularly in the case of phase-separated glass, including selectively removing a denatured layer formed on the surface of glass easily. The method of producing glass includes: forming phase-separated glass containing silicon oxide, boron oxide, and an alkali metal oxide; bringing an alkaline solution held by a porous supporting member into contact with the denatured layer formed on the surface of the phase-separated glass to remove the denatured layer; and immersing the phase-separated glass with the denatured layer removed therefrom in an acid solution to form pores in the phase-separated glass.Type: ApplicationFiled: May 20, 2011Publication date: March 28, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Kenji Takashima, Zuyi Zhang, Yoshinori Kotani
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Publication number: 20130068725Abstract: Provided is a method of producing a porous glass, including selectively etching a phase-separated glass with an acid solution, in which the method allows a processing time to be shortened and suppresses gel-like silica from remaining and being deposited in pores of a porous portion. The method of producing a porous glass includes: immersing the phase-separated glass in a bath containing an acid solution; setting an angle ?, which is formed by a surface to be porosified of the phase-separated glass and a bath liquid surface, to 10° or more to 90° or less; and irradiating the bath with an ultrasonic wave to etch the phase-separated glass, thereby obtaining the porous glass.Type: ApplicationFiled: May 20, 2011Publication date: March 21, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Kenji Takashima, Zuyi Zhang, Yoshinori Kotani
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Publication number: 20130067957Abstract: Provided a method of producing a glass having a silica skeleton with a phase-separated structure, particularly in the case of a phase-separated glass, by selectively removing a compositionally deviated layer on the surface of a phase-separated borosilicate glass. The method of producing a glass includes forming a glass body containing silicon oxide, boron oxide, and an alkali metal oxide; and bringing an alkaline aqueous solution having a viscosity of 5 mPa·s or more to 200 mPa·s or less into contact with a surface of the glass body.Type: ApplicationFiled: May 20, 2011Publication date: March 21, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Zuyi Zhang, Yoshinori Kotani, Kenji Takashima
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Publication number: 20130045853Abstract: Provided is a method of producing a porous glass having a high strength by a safe, simple process that does not involve the use of any high-temperature heat treatment or acid treatment step. The method includes: mixing 4 wt % or more to 6.5 wt % or less of sodium oxide, 26 wt % or more to 36 wt % or less of boron oxide, and 60 wt % or more to 68 wt % or less of silicon oxide; heating the mixed materials to melt the materials and cooling the molten materials to obtain a glass body; and a step involving bringing the glass body into contact with water without reheating the glass body to obtain the porous glass.Type: ApplicationFiled: May 13, 2011Publication date: February 21, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Yoshinori Kotani, Zuyi Zhang, Kenji Takashima
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Publication number: 20130003096Abstract: An imaging apparatus for imaging a subject image from a lens on an imaging element through an optical filter has a porous body having pores which three dimensionally communicate with each other at least at a side opposite to the imaging element of the optical filter.Type: ApplicationFiled: June 25, 2012Publication date: January 3, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Zuyi Zhang, Yoshinori Kotani, Akira Sugiyama, Kenji Takashima, Naoyuki Koketsu
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Patent number: 8343392Abstract: A composite material is constituted by fine nano-oxide particles, a dispersant, and a transparent resin material. The dispersant includes a polymer of vinyl monomer having a binding acidic group. When ? is a dimensionless number defined by an average particle size (nm) of the fine nano-oxide particles divided by nm, the polymer has a degree of polymerization of an integer of 3 or more and 8×? or less with the proviso that the integer is a numerical value obtained by dropping a decimal fraction. The composite material is produced through a step of obtaining a dispersant comprising a polymer by polymerizing a vinyl monomer having a binding acidic group in the presence of polyamine or in an aqueous dilute dispersion, and a step of mixing the dispersant, fine nano-oxide particles, and a transparent resin material.Type: GrantFiled: August 30, 2007Date of Patent: January 1, 2013Assignee: Canon Kabushiki KaishaInventor: Zuyi Zhang
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Patent number: 8273675Abstract: Provided is a ferroelectric ceramic material containing BaTiO3 as a main component which can control a Curie temperature in a wide range, has no phase transition in the vicinity of a room temperature, and exhibits excellent ferroelectric characteristics. The ferroelectric ceramic material includes an oxide represented by the formula: (100?a?b)BaTiO3.aBi2O3.bM2O3, where M represents a trivalent metal other than Bi, and a and b satisfy 1?a?15, 0?b?5, and 5?a+3b?15 and M is preferably a trivalent metal selected from fifth period transition metals or rare earth metals having an atomic number of 59 or higher to 69 or lower.Type: GrantFiled: September 25, 2009Date of Patent: September 25, 2012Assignee: Canon Kabushiki KaishaInventors: Zuyi Zhang, Jumpei Hayashi, Kenji Takashima, Tatsuo Furuta