Dispensing device for dispensing active substance fluids into the flushing liquid inside a toilet bowl

The invention relates to a dispensing device for dispensing active substance fluid into the flushing liquid inside a toilet bowl. The dispensing device comprises a holder (1) that can be suspended-on the edge of the toilet bowl and comprises at least two reservoirs (2, 3), which are separate from one another, are provided inside the holder (1), and which each accommodate an active substance fluid. Each reservoir (2, 3) has its own discharge opening (4) via which the respective active substance fluid can be dispensed into the flushing liquid. The inventive dispensing device is characterized in that flushing liquid is not permitted to enter the interior of the reservoirs (2, 3), and the discharge openings (4) of the reservoirs (2, 3) are arranged so that only active substance fluid is discharged and a partial quantity of the active substance fluid is dispensed from each of the reservoirs (2,3) into the flushing liquid during each flushing.

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Description
The invention relates to a dispensing device for dispensing active substance fluids into the flushing liquid in a toilet bowl, with the features of the introductory part of claim 1.

[0001] The term active substance fluid means flowable, thus liquid to viscous, in a given case gel-like or even pasty or granular or otherwise pourable, active substance preparations with cleansing, disinfecting, deodorising, bleaching or similar action (particularly described in DE 199 30 362 A1, which is not prior published, as well as in EP 0 775 741 A1 and EP 0 960 984 A2).

[0002] Dispensing devices of the usual kind are known in various forms under the catchword “WC baskets”. In the first instance, dispensing devices are known for a single active substance fluid. The active substance fluid is there disposed in a storage container, which is fixedly arranged or exchangeably inserted in a holder, with an outlet opening arranged at the base side when the storage container is mounted at the holder.

[0003] In a first known dispensing device for a single active substance fluid the active substance fluid is delivered by way of an actuating element (for example, from an open-pore foam material) saturated therewith and loadable by the flushing liquid (EP 785 315 A1). Here the outlet opening of the storage container is for the most part closed after the pushing out of a closure part of the storage container by a sealing element arranged at the holder in stationary position, so that a flow path with only a small cross-section is available for the seeping out of the active substance fluid. The device functions with utilisation of the capillary effect of the open-pore foam material. A similar construction with a rib plate serving for the distribution is also known.

[0004] In the case of both variants it has on occasions felt not to be optimal that the outlet opening is in principle permanently open, so that active substance fluid can continue to seep out over longer term non-use of the toilet bowl.

[0005] Another dispensing device for a single active substance fluid (DE 299 02 066 U1) has at the storage container a sealing element which operates in valve-like manner and which normally adopts a positive, closed closure setting in which the outlet opening is closed. This happens under the action of the gravitational force of a valve ball acting as a sealing element. This sealing element can be displaced against the biasing force into a release setting slightly freeing the outlet opening. An actuating element constructed as a rocker and pivotably mounted on a pivot axis at the holder serves for this purpose. The actuating element has at one side of the axis a loading region having a pan-shaped receptacle for flushing liquid. The arm of the actuating element lying on the other side of the axis bears from below against the sealing element. If the flushing liquid impinges on the influencing region, then the actuating element is lifted off the valve seat at the outlet opening by way of the actuating element and slightly frees the outlet opening. The active substance fluid can seep past the sealing element out of the outlet opening into the current of flushing liquid flowing by or is entrained by the flushing liquid. A dispensing device similar to the previously explained dispensing device is known from DE 199 30 362 A1 already mentioned further above but not prior published, the device having, however, as actuating element a single-arm lever which is pivotably connected at one end with the holder and at which the sealing element is arranged between the end pivotably connected with the holder and the loading region. This construction corresponds, in particular, with a storage container exchangeably arranged at the holder.

[0006] In the case of use of the previously explained dispensing devices of the usual kind all components entering the flushing liquid of the toilet bowl have to be included in common in the active substance fluid. However, many active substance components cannot be realised in a form stable in conjunctive storage. Accordingly, a multi-chamber dispensing device has already been proposed (EP 0 960 984 A2). This known dispensing device serves for dispensing at least two different or equally solid, gel-like, pasty or liquid media in liquid or aqueous form into a toilet bowl. A container, which has at least two independent chambers arranged adjacent to one another for storage of the media, is disposed at a holder able to be suspended at the edge of the toilet bowl. Each chamber has a dispensing device with a dispensing tubelet which exits into the environment by one free end thereof via the base of the container and is surrounded at the other free end thereof in fluid-guiding manner by a cover. The two chambers of the container can be filled via slot-like passages of a cover part by flushing water flowing over, which then issues into the toilet bowl in the manner of a siphon or overflow by way of the dispensing tubelet with entrainment of the respective active substance. The separation of the chambers in the container has the advantage that different media can be used which would otherwise adversely influence one another in their desired effect in the case of common storage in only one chamber. In addition, the consistency of the media can be different in the different chambers.

[0007] In the dispensing device explained above the principle of functioning of known “WC baskets” is utilised, according to which the flushing water flowing over from above flows into the chambers containing the active substance fluid, detaches parts of the active substance material and, with entrainment thereof, flows back out of the chambers. In that case the problem exists that a substantial liquid level is left behind in the chambers by the siphon action effected here. The action of the flushing liquid on the active substance fluid in the respective chambers thus continues even when the flushing process has long been concluded. The consumption of active substance fluid cannot, in practice, be controlled in optimum manner.

[0008] There is also known a double-chamber dispensing device for like or different gel-like active substance fluids (WO 92/20876 A1), in which the outlet openings are executed as perforations in the storage containers at the base and are permanently open. Due to the viscosity and surface tension of the gel, this normally cannot exit by itself under gravitational force. Partial quantities of the active substance fluids can be discharged only by flushing liquid which runs over and which enters from below into the outlet openings and etches to some degree the gel near the outlet openings. In this double-chamber system it is thus similarly the case that the outlet openings are basically permanently open, so that also with longer-term non-use of the toilet bowl the active substance fluids can either seep out or solidify under the influence of the ambient atmosphere and thereafter are no longer activatable.

[0009] The teaching is based on the problem of optimising the known dispensing device explained in the foregoing, for dispensing active substance fluids from at least two mutually separate storage containers, with respect to possibility of control of the dispensing of the active substance fluids.

[0010] The set problem demonstrated in the foregoing is solved, in the case of a dispensing device with the features of the introductory part of claim 1, by the features of the characterising part of claim 1. According to the invention the storage containers are protected against the entry of flushing liquid into the interior thereof and only active substance fluid issues from the outlet openings of the storage containers. This is realised in the manner that with each flushing process the dispensing of a partial quantity of the active substance fluid into the flushing water takes place from each storage container.

[0011] In the sense of solution of the set problem defined in the foregoing an embodiment of the dispensing device, which is in accordance with the invention, according to claim 16 is particularly advantageous. A positive closure of the outlet openings is advantageous in this concept particularly for the purpose of defined dimensioning of the partial quantities and for the purpose of protection of the active substance fluids in the storage containers in the case of non-use in the longer term.

[0012] The technical principles of dispensing devices for a single active substance fluid, which are known in the state of the art and which have already been comprehensively explained further above, are available for realisation of the construction according to the invention. In particular, reference must be made for this purpose to the state of the art discussed further above.

[0013] Preferred embodiments and developments of the teaching are the subject of the subclaims.

[0014] Moreover, a preferred embodiment of the invention is explained in more detail by reference to the drawing, in which:

[0015] FIG. 1 shows a preferred embodiment of a dispensing device according to the invention, in a plan view,

[0016] FIG. 2 shows a section through the device of FIG. 1 along the line II-II and

[0017] FIG. 3 shows a section through the device of FIG. 2 along the line III-III.

[0018] The dispensing device illustrated in the drawings serves for dispensing of at least two active substance fluids into the flushing liquid which is flushed into a toilet bowl. With regard to what is to be understood in the sense of the teaching as active substance fluid, this has already been defined in the general part of the description and reference may be made thereto.

[0019] Such a dispensing device comprises, in the first instance, a holder 1 which can be suspended at the edge of the toilet bowl and at least two mutually separate storage containers 2, 3, which are provided in the holder 1, each for a respective active substance fluid. The active substance fluids can be corresponding, different, mutually compatible or mutually incompatible active substance fluids. Two storage containers for two active substance fluids or more storage containers for more active substance fluids can be given.

[0020] According to the invention suitable active substance fluids are, for example, aromatic phases, particularly perfumed aromatic phases. Such aromatic phases usually contain at least one aromatic, preferably perfume oil, at least one surfactant or emulsifier and water as well as, in a given case, further ingredients such as preservatives, thickeners, sequestering agents, colorants, further surfactants or emulsifiers, stabilisers, descalers, etc.

[0021] According to the invention equally suitable as active substance fluids are bleaching phases, particularly bleaching phases containing chlorine, for example bleaching phases based on hypochlorite, wherein the bleaching phases can usually contain, apart from the actual bleaching agent and water, optionally further ingredients such as thickeners, surfactants or emulsifiers, neutralisers, colorants, aromatics, etc.

[0022] Further suitable active substance ingredients according to the invention are descaling active substance phases, preferably acidic descaling active substance phases. Such descaling active substance phases can contain, apart from the actual descaler—this is preferably an organic or anorganic acid—and water, optionally further ingredients such as surfactants or emulsifiers, thickeners, aromatics, preservatives, etc.

[0023] It is equally possible to use, as active substance fluids, highly concentrated surfactant phases, so-termed “foam boosters”. Such highly concentrated surfactant phases can contain, apart from the surfactants, also further usual ingredients.

[0024] According to the invention active substance fluids with an antibacterial and/or fungicidal and/or antiviral active substance phase are equally suitable, wherein the active substance phase can contain, apart from the active substance acting antibacterially and/or fungicidally and/or antivirally and water, optionally further ingredients such as, for example, surfactants or emulsifiers, thickeners, aromatics, preservatives, etc.

[0025] In addition, it is possible for the active substance fluids to be active substance phases with an enzyme content. Such active substance phases with enzyme content can contain, apart from the enzyme or enzymes and water, optionally further ingredients such as surfactants or emulsifiers, thickeners, aromatics, preservatives, etc.

[0026] Equally, it is possible for the active substance fluids used in accordance with the invention to be absorbent, particularly odour-absorbent, active substance phases. These can contain, apart from the absorption agent, particularly an odour-absorption agent, and water, optionally further ingredients such as surfactants or emulsifiers, thickeners, aromatics, preservatives, etc.

[0027] The dispensing device according to the invention offers, in accordance with a special embodiment, the possibility of using combinations of different active substance fluids in the storage containers 2, 3, wherein according to a preferred embodiment one of the storage containers 2, 3 contains an aromatic phase, particularly as previously defined.

[0028] Examples of active substance fluid combinations to be used are perfumed aromatic phase combined with chlorine bleach (not stable in storage together with one another), perfumed aromatic phase with highly concentrated surfactant phase (foam booster), aromatic phase with descaling acidic active substance phase, aromatic phase with antibacterial active substance phase, different acid systems, aromatic phase combined with active substance phase having an enzyme content, perfumed acid phase combined with watercolouring phase, aromatic phase with odour-absorbent phase, perfumed acid phase with available oxygen, perfumed acid phase with active substance phase, thickened with polyacrylate, etc. Of particular interest in that case are viscous to gel-like active substance fluids with viscosities in the region of a few thousand mPas, particularly 2000 to 5000 mPas, preferably 2500 to 3500 mPas (measured by Rotovisko LVT, hydrometer 2, 6 rpm, 200° C.).

[0029] In the case of the illustrated dispensing device each storage container 2, 3 has an own outlet opening 4 by way of which the respective active substance fluid can be dispensed into the flushing liquid. By contrast to the state of the art forming the starting point for the teaching, it is now the case here that the storage containers 2, 3 are protected against entry of flushing liquid into the interior thereof. The outlet openings 4 of the storage containers 2, 3 are then so arranged that only active substance fluid issues. The dispensing of a partial quantity of the active substance fluid from each of the storage containers 2, 3 into the flushing liquid takes place in each flushing process. In the illustrated embodiment this is realised by the fact that the outlet opening 4 of the respective storage container 2, 3 in use setting, thus as illustrated in FIG. 2, is arranged at the base. Flushing water flowing over always impinges laterally on the storage containers 2, 3.

[0030] Many different possibilities exist for the arrangement and mounting of the storage containers 2, 3 at the holder 1. In the embodiment which to that extent is preferred and is illustrated in the drawing it is provided that the storage containers 2, 3 are mounted or mountable in the container 1 to be individually exchangeable. An alternative consists in coupling the storage containers 2, 3 together by means of an adapter or the like and mounting them, thus coupled, in the holder 1. A further alternative consists in directly coupling the storage containers 2, 3 together and mounting them, thus directly coupled, in the holder 1. Finally, it is also conceivable to construct the storage containers 2, 3 in a common unitary housing, for example as separate chambers in a cohesive housing, and then mount them in that form at the holder 1. One or other variant can be selected according to preferences in practice and the active substance fluids to be used.

[0031] The storage containers 2, 3 can be designed, as described in the state of the art (DE 299 02 066 U1, DE 199 15 322 A1), to each be individually refillable by way of a refilling opening optionally equipped with a valve. In particular, in this case the storage containers 2, 3 can also be fixedly mounted or constructed in the container 1, thus a unitary arrangement closed in itself can be selected.

[0032] The illustrated embodiment, however, shows the storage containers 2, 3 as exchangeable single-use containers which will be very widespread in practice. The illustrated and preferred embodiment shows the storage containers 2, 3 arranged adjacent to one another at the holder 1. The same applies to an arrangement of the storage containers 2, 3 one behind the other. Alternatively, it could also be provided to arrange the storage containers 2, 3 one above the other for the purpose of product delivery in cascade manner.

[0033] The illustrated and preferred embodiment further shows that the storage containers 2, 3, which here are, in fact, individually exchangeable, can be mounted in the container 1 by plugging in from above (into use setting). Diverse other possibilities of fastening come into question as alternatives. For example, it could be conceivable to push the storage containers 2, 3 into the holder 1 from the side. It could also be conceivable to place the storage containers 2, 3 laterally at the holder 1 and then pivot into the use setting about a pivot axis. One or other variant can be selected according to the respective construction of the outlet openings 4 and the method of closure thereof.

[0034] In principle, it is possible to use as active substance fluid, for example, gels with very high viscosity or pastes which are not independently capable of flowing. In this case it can be recommended for the storage container 2, 3 to have a flexible wall portion or a flexible wall overall and an expulsion of the active substance fluid disposed therein takes place by pressure loading of the storage container 2, 3. This pressure loading can be exerted by way of, for example, an appropriate mechanism via the flushing liquid which flows over.

[0035] It has already been mentioned above that in the case of the multi-chamber dispensing device according to the invention dispensing mechanisms can, in principle, be used which are known from the state of the art for dispensing devices for a single active substance fluid. To that extent a constructional possibility, which generally speaking goes back to EP 0 538 957 B1, applicable in the present case is that a plate-shaped distribution element is provided at the holder 1 and has a loading region flowed over by flushing liquid during the flushing process, wherein the interior of the storage container 2, 3 is disposed in permanent connection with the distribution element by way of the outlet opening 4, optionally with interposition of an arrangement preventing free flowing of the active substance fluid. According to a particularly preferred embodiment the plate-shaped distribution element is associated in common with all storage containers 2, 3.

[0036] The illustrated and preferred embodiment depicts a solution operating with an actively closing sealing element. Here the outlet opening 4, which is arranged at the base, of the storage container 2, 3 is closed by means of, in particular, a sealing element 5. The sealing element 5 is biased into the closed setting closing the outlet opening 4 and is displaceable against the biasing force into a release setting slightly freeing the outlet opening 4.

[0037] For displacing the sealing element 5 there is provided an actuating element 6 which cooperates with the sealing element 5 and which is transiently loaded by a force via the flushing liquid in each flushing process to such an extent that the sealing element 5 temporarily adopts the release setting against the biasing force. For that purpose a loading region 7 which is acted on by flushing liquid during the flushing process and on which the flushing liquid thus impinges during the flushing process is disposed at the actuating element 6. The actuating element 6 is constructed as a single-arm lever pivotably connected at one end with the holder 1. The sealing element 5 is arranged at the actuating element 6 at a specific spacing from the loading region 7. Due to the single-arm construction of the lever forming the actuating element 6 (FIG. 3) the effective direction of the force exerted by the flushing liquid is aligned with the direction of opening of the sealing element 5. The sealing element 5 can thereby be lifted from below from the outlet opening 4 of the storage container 2, 3. It is thus possible without further measures to exchangeably mount the storage container 2, 3 without special constructional features.

[0038] In the illustrated embodiment the sealing element 5 is arranged between the end, which is pivotably connected with the holder 1, of the actuating element 6 and the loading region 7. The opening path of the sealing element 5 is thus comparatively small and opening takes place, as desired, with only a quite small gap. Moreover, this gap is, with appropriate design of the sealing element 5, opened asymmetrically, namely opening more strongly in the direction of the loading region 7 so that the effective substance fluid preferentially issues in this direction. That is the direction for the flushing liquid, with which the effective substance fluid then appropriately mixes. The effective substance fluid can thus run on the upper side of the actuating element 6 in the direction of the loading region 7 and already mixes on this path with the flushing liquid which flows over.

[0039] It is possible to provide for the sealing element 5 to be integrally formed at the actuating element 6. This is recommended particularly in the case of design of the actuating element 6 from a plastic material, particularly from plastic material capable of injection moulding. In addition, the holder 1 can, in particularly preferred manner, consist of plastic material, especially a plastic material capable of injection moulding, preferably thermoplastic synthetic material. Overall, it can be provided that the actuating element 6 is integrally formed at the holder 1 and the biasing force is produced by the inherent resilience of the actuating element 6.

[0040] The illustrated and preferred embodiment is now distinguished in particular manner by the fact that the actuating element 6 is associated in common with the sealing elements 5 for at least two storage containers 2, 3, preferably for all storage containers 2, 3. There can be recognised in FIG. 1 in plan view the wide actuating element 6, which is of plate-shaped construction, with the equally wide, pan-shaped loading region 7 and the small outflow openings 8 recognisable therein, all in the frame-shaped base plate 9 of the holder 1. The arrangement of the outlet openings 4 at the storage containers 2, 3 is matched thereto. In particular, these containers are, with respect to the centre of the overall dispensing device, constructed asymmetrically with outlet openings 4 offset relative to the centre of the dispensing device overall (FIG. 2). There is thereby obtained a concentration of the active substance exit at a relatively narrowly defined region regardless of the fact that two storage containers 2, 3 are provided.

[0041] Finally, a dispensing, which is controlled in specific manner, of active substance fluid from the different storage containers 2, 3 can be realised in the manner that the flow cross-sections at the outlet openings 4 and/or at the sealing elements 5 are able to be determined and/or set to be different.

[0042] Finally, there are a number of design possibilities of the illustrated dispensing device in constructional respects, particularly with regard to the arrangement and formation of the outlet openings and sealing elements. In this connection, there is a contemporaneously filed parallel patent application of the applicant, to the disclosure content of which reference may be made (DE . . . ). In particular, a simultaneous metering or a metering delayed in time can be realised with the same or different concentration from the different storage containers.

[0043] The present invention is further explained by reference to the following examples, which do not, however, restrict the invention in any manner. Different active substance fluid combinations for the storage containers 2, 3 of the dispensing device according to the invention are described in the examples.

[0044] 1) Perfumed aromatic phase combined with chlorine bleach: not able to be realised in practice with storage stability in a single-tank system.

[0045] a) Aromatic phase 1 Composition: FAEOS-Na, C12-14 + 2 EO 24.50% basic surfactant alkyl (C8-10)-1.5-glucoside 2.88% co. surfactant/ emulsifier 1,2-propandiol 5.00% emulsifier ethanol 96%, 1% MEK denatured 5.00% co. emulsifier hydroxyethylcellulose(1) 0.45% thickener perfume oil, pine tang 10.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100 (1)e.g. Natrosol 250 HHBR

[0046] approx. 3000 mPas, 20° C., Rotovisko LVT, hydrometer 2, 6 rpm 6.5 pH, undiluted clear solution

Production

[0047] Provide warm water of 20-25° C. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time (test by glass-plate test for freedom from pinholing); if pinholes are still present, further agitation needed. Add surfactants, then alcohols. Finally, add perfume and check batch with respect to release parameters.

[0048] b) Bleach phase containing chlorine (approx. 1% active chlorine) 2 Composition: Na-hypochlorite (12.5% active chlorine) 8.00% chlorine bleach sodium hydroxide (50%) 2.50% neutraliser Oxy-Rite (Registered Trade Mark) 0.10% stabilisation of 100(1) rheological properties polyacrylate polymer(2) 1.00% thickener cocos alkyldimethylaminoxide(3) 2.00% surfactant/emulsifier distilled water ad.100 (1)maker BF Goodrich (2)maker BF Goodrich, e.g. Carbopol (Registered Trade Mark) 676 (3)e.g. Genaminox CS/company Clariant GmbH

[0049] approx. 2500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 6 rpm 12.7 pH, undiluted opaque solution

Production

[0050] Provide water. Spread in thickener at medium to high rotational speed (approx. 800 rpm) (test by glass-plate test for freedom from pinholing); if polymer particles are still present, further agitation needed. Thereafter add Oxyrite. Neutralise the solution by NaOH. For a maximum viscosity, the pH value should be set to above 12.5. Stir in the Na-hypochlorite solution at reduced rotational speed.

[0051] 2) Highly perfumed aromatic phase combined with foam booster phase.

[0052] a) Aromatic phase with high perfume content 3 Composition: FAEOS-Na, C12-14 + 2 EO(1) 24.50% basic surfactant alkyl (C8-10)-1.5-glucoside(2) 2.88% co. surfactant/ emulsifier 1,2-propandiol 10.00% emulsifier ethanol 96%, 1% MEK denatured 5.00% co. emulsifier hydroxyethylcellulose 0.45% thickener perfume oil, citrus tang 20.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100 (1)e.g. Texapon N 70 (2)e.g. Glucopon 220 UP-W

[0053] approx. 2500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 6 rpm 6.5 pH, undiluted clear solution

Production

[0054] Provide warm water of 20-25° C. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time (test by glass-plate test for freedom from pinholing); if pinholes are still present, further agitation needed. Add surfactants, then alcohols. Finally, add perfume and check batch with respect to release parameters.

[0055] b) Highly concentrated surfactant phase thickened with betaine/chlorine 4 Composition: FAEOS-Na, C12-14 + 2 EO 30.00% basic surfactant cocamidopropyl betatine(1) 20.00% co. surfactant NaCl, denatured 1.50% thickener hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100 (1)e.g. Dehyton K

[0056] approx. 5500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 20 rpm 6.5 pH, undiluted clear solution

Production

[0057] Provide water. Dissolve colorants and preservative and then stir in surfactant. Set viscosity with NaCl.

[0058] 3) Aromatic phase combined with acid descaling active substance phase.

[0059] a) Aromatic phase 5 Composition: FAS-Na, C12-14(1) 29.50% basic surfactant alkyl (C12-14)-polyglucoside(2) 3.30% co. surfactant/ emulsifier 1,2-propandiol 5.00% emulsifier ethanol 96%, 1% MEK denatured 5.00% co. emulsifier hydroxyethylcellulose 0.45% thickener perfume oil, aqua tang 10.00% aromatic trisodium citrate(1) 2 H2O 2.00% sequestering agent hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100 (1)e.g. Texapon LS 35 (2)e.g. Glucopon 600 CS-UP

[0060] approx. 2500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 6 rpm 8.0 pH, undiluted clear solution

Production

[0061] Provide warm water of 20-25° C. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time (test by glass-plate test for freedom from pinholing); if pinholes are still present, further agitation needed. Add surfactants, then alcohols. Finally, add perfume and check batch with respect to release parameters.

[0062] b) Acid descaling phase, thickened by polysaccharide 6 Composition: FAEOS-Na, C12-14 + 2 EO 8.11% basic surfactant alkyl (C8-10)-1.5-glucoside 5.44% co. surfactant citric acid 3.00% descaler polysaccharide/xanthene gum(1) 0.20% thickener ethanol 96%, 1% MEK denatured 3.00% co. emulsifier perfume oil, aqua tang 6.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100 (1)e.g. Rhodopol T

[0063] approx. 3500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 20 rpm 2.5 pH, undiluted clear solution

Production

[0064] Provide water. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time. Add surfactants, then alcohols. Finally, add perfume and citric acid and check batch with respect to release parameters.

[0065] 4) Aromatic phase combined with antibacterial active substance phase.

[0066] a) Aromatic phase/foam-activated by ABS formulation 7 Composition: Na-alkylbenzolsulfonate(1) 25.50% basic surfactant C12-15-oxoalcohol + 10 EO(2) 10.00% co. surfactant emulsifier 1,2-propandiol 5.00% emulsifier ethanol 96%, 1% MEK denatured 5.00% co. emulsifier hydroxyethylcellulose 0.45% thickener perfume oil, lemon tang 10.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100 (1)e.g. Marlon A 350, company Hüls (2)e.g. Genapol-OX-100, company Clariant

[0067] approx. 2500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 6 rpm 9.1 pH, undiluted clear solution

Production

[0068] Provide warm water of 20-25° C. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time (test by glass-plate test for freedom from pinholing); if pinholes are still present, further agitation needed. Add surfactants, then alcohols. Finally, add perfume and check batch with respect to release parameters.

[0069] b) Antibacterial phase 8 Composition: FAEOS-Na, C12-14 + 2 EO 24.50% basic surfactant alkyl (C8-10)-1.5-glucoside 2.88% co. surfactant/emulsifier 1,2-propandiol 5.00% emulsifier ethanol 96%, 1% MEK denatured 5.00% co. emulsifier hydroxyethylcellulose 0.45% thickener perfume oil, lemon tang 10.00% aromatic hemiacetal-isothiazolin combination 0.10% preservative/ antibacterial active substance salicyclic acid, tech. 0.60% antibacterial active substance colorants <1.00% tap water ad.100

[0070] approx. 2700 mPas, 20° C., Rotovisko LVT, hydrometer 2, 6 rpm 5.5 pH, undiluted clear solution

Production

[0071] Provide warm water of 20-25° C. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time (test by glass-plate test for freedom from pinholing); if pinholes are still present, further agitation needed. Add surfactants, then alcohols. Finally, add perfume and check batch with respect to release parameters.

[0072] 5) Different acid systems with high descaling activity

[0073] a) Lactic acid phase 9 Composition: FAEOS-Na, C12-14 + 2 EO 8.11% basic surfactant alkyl (C8-10)-1.5-glucoside 5.44% co. surfactant lactic acid(1) 2.50% descaler polysaccharide/xanthene gum 0.22% thickener ethanol 96%, 1% MEK denatured 3.00% co. emulsifier perfume oil, orange tang 8.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100 (1)Purac 80

[0074] approx. 3500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 20 rpm 2.2 pH, undiluted clear solution

Production

[0075] Provide water. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time. Add surfactants, then alcohols. Finally, add perfume and lactic acid and check batch with respect to release parameters.

[0076] b) Citric acid phase/nio-surfactant base 10 Composition: FA-C12-18 + 7 EO(1) 12.50% basic surfactant/ emulsifier alkyl (C8-10)-1.5-glucoside 5.44% co. surfactant oleyl-cetylalcohol + 5 EO(2) 3.00% co. emulsifier citric acid 5.00% descaler polysaccharide/xanthene gum 0.20% thickener ethanol 96%, 1% MEK denatured 3.00% co. emulsifier perfume oil, orange tang 12.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100 (1)e.g. Dehydol LT7 (2)e.g. Eumulgin O 5

[0077] approx. 3500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 20 rpm 2.5 pH, undiluted clear solution

Production

[0078] Provide water. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time. Add surfactants, then alcohols. Finally, add perfume and citric acid and check batch with respect to release parameters.

[0079] 6) Aromatic phase combined with active substance phase with enzyme content

[0080] a) Aromatic phase 11 Composition: FAEOS-Na, C12-14 + 2 EO 24.50% basic surfactant Na-alkane-sulfonate(1) 8.50% co. surfactant 1,2-propandiol 5.00% emulsifier ethanol 96%, 1% MEK denatured 5.00% co. emulsifier hydroxyethylcellulose 0.45% thickener perfume oil, fruit blossom 9.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100 (1)e.g. Hostapur SAS 60/company Hoechst

[0081] approx. 2500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 6 rpm 6.8 pH, undiluted clear solution

Production

[0082] Provide warm water of 20-25° C. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time (test by glass-plate test for freedom from pinholing); if pinholes are still present, further agitation needed. Add surfactants, then alcohols. Finally, add perfume and check batch with respect to release parameters.

[0083] b) Enzyme phase 12 Composition: FAEOS-Na, C12-14 + 2 EO 24.50% basic surfactant alkyl (C8-10)-1.5-glucoside 2.88% co. surfactant/emulsifier 1,2-propandiol 5.00% emulsifier ethanol 96%, 1% MEK denatured 5.00% co. emulsifier hydroxyethylcellulose 0.45% thickener perfume oil, fruit blossom 9.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative/ antibacterial active substance lipase 0.50% enzyme colorants <1.00% tap water ad.100

[0084] approx. 2700 mPas, 20° C., Rotovisko LVT, hydrometer 2, 6 rpm 6.5 pH, undiluted clear solution

Production

[0085] Provide warm water of 20-25° C. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time (test by glass-plate test for freedom from pinholing); if pinholes are still present, further agitation needed. Add surfactants, then alcohols. Finally, add perfume and check batch with respect to release parameters.

[0086] 7) Perfumed acid phase combined with active substance phase to colour flushing water

[0087] a) Acid phase 13 Composition: FAEOS-Na, C12-14 + 2 EO 20.10% basic surfactant alkyl (C8-10)-1.5-glucoside 5.44% co. surfactant citric acid 2.50% descaler formic acid 1.50% descaler polysaccharide/xanthene gum 0.22% thickener ethanol 96%, 1% MEK denatured 3.00% co. emulsifier perfume oil, mint 10.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100

[0088] approx. 3500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 20 rpm 2.5 pH, undiluted clear solution

Production

[0089] Provide water. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time. Add surfactants, then alcohols. Finally, add perfume and acids and check batch with respect to release parameters.

[0090] b) Flushing water colouring phase/trisodium citrate as sequestering agent 14 Composition: FAEOS-Na, C12-14 + 2 EO 9.11% basic surfactant alkyl (C8-10)-1.5-glucoside 5.44% co. surfactant trisodium citrate(1) 2 H2O 2.00% sequestering agent polysaccharide/xanthene gum 0.20% thickener ethanol 96%, 1% MEK denatured 3.00% co. emulsifier perfume oil, mint 7.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorant(1) 3.00% water-soluble dye tap water ad.100 (1)Basic Acid Blue 755 gr.

[0091] approx. 3500 mPas 20° C., Rotovisko LVT, hydrometer 2, 20 rpm 7.5 pH, undiluted clear solution

Production

[0092] Provide water. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time. Add surfactants, then alcohols. Finally, add perfume and citric acid and check batch with respect to release parameters.

[0093] 8) Aromatic phase combined with odour-absorbent active substance phase

[0094] a) Aromatic phase 15 Composition: FAEOS-Na, C12-14 + 2 EO 24.50% basic surfactant alkyl (C8-10)-1.5-glucoside 2.88% co. surfactant/emulsifier 1,2-propandiol 10.00% emulsifier hydroxyethylcellulose 0.50% thickener perfume oil, willow green 10.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100

[0095] approx. 2500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 6 rpm 6.5 pH, undiluted clear solution

Production

[0096] Provide warm water of 20-25° C. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time (test by glass-plate test for freedom from pinholing); if pinholes are still present, further agitation needed. Add surfactants, then alcohols. Finally, add perfume and check batch with respect to release parameters.

[0097] b) Absorber phase 16 Composition: FAEOS-Na, C12-14 + 2 EO 24.50% basic surfactant alkyl (C8-10)-1.5-glucoside 2.88% co. surfactant/emulsifier ethanol 96%, 1% MEK denatured 10.00% emulsifier hydroxyethylcellulose 0.45% thickener perfume oil, willow green 10.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative/ antibacterial active substance zinc ricinoleate(1) 1.00% odour absorber colorants <1.00% tap water ad.100 (1)Tego-Sorb, conc. 50, company Goldschmidt

[0098] approx. 2700 mPas 20° C., Rotovisko LVT, hydrometer 2, 6 rpm 5.5 pH, undiluted clear solution

Production

[0099] Provide warm water of 20-25° C. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time (test by glass-plate test for freedom from pinholing); if pinholes are still present, further agitation needed. Add surfactants, then alcohols. Finally, add perfume and check batch with respect to release parameters.

[0100] 9) Perfumed acid phase combined with active substance phase with available oxygen

[0101] a) Acid phase with available oxygen 17 Composition: FAEOS-Na, C12-14 + 2 EO 20.10% basic surfactant alkyl (C8-10)-1.5-glucoside 5.46% co. surfactant citric acid 2.00% descaler polysaccharide/xanthene gum 0.22% thickener ethanol 96%, 1% MEK denatured 3.00% co. emulsifier perfume oil, apple 8.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative hydrogen peroxide, 35% 2.86% available oxygen (1%) diethylenetriaminepentamethylenephosphonic 0.16% stabiliser acid Na(1) colorants, pigment <1.00% tap water ad.100 (1)Dequest 2066, company Monsanto

[0102] approx. 3500 mPas 20° C., Rotovisko LVT, hydrometer 2, 20 rpm 2.5 pH, undiluted clear solution

Production

[0103] Provide water. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time. Add surfactants, then alcohols. Add perfume and acids and finally add the stabiliser and hydrogen peroxide and check batch with respect to release parameters.

[0104] b) Aromatic phase 18 Composition: FAEOS-Na, C12-14 + 2 EO 20.10% basic surfactant alkyl (C8-10)-1.5-glucoside 5.44% co. surfactant citric acid 2.00% descaler polysaccharide/xanthene gum 0.22% thickener ethanol 96%, 1% MEK denatured 6.00% co. emulsifier perfume oil, apple 10.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100

[0105] approx. 3500 mPas 20° C., Rotovisko LVT, hydrometer 2, 20 rpm 2.5 pH, undiluted clear solution

Production

[0106] Provide water. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time. Add surfactants, then alcohols. Work in perfume and acids and check batch with respect to release parameters.

[0107] 10) Perfumed acid phase combined with polyacryl-thickened active substance phase

[0108] a) Acid phase with available oxygen 19 Composition: FAEOS-Na, C12-14 + 2 EO 20.10% basic surfactant alkyl (C8-10)-1.5-glucoside 5.44% co. surfactant citric acid 4.00% descaler polysaccharide/xanthene gum 0.22% thickener ethanol 96%, 1% MEK denatured 3.00% co. emulsifier perfume oil, citrus tang 8.00% aromatic hemiacetal-isothiazolin combination 0.05% preservative colorants <1.00% tap water ad.100

[0109] approx. 3500 mPas, 20° C., Rotovisko LVT, hydrometer 2, 20 rpm 3.0 pH, undiluted clear solution

Production

[0110] Provide water. Add colorants and preservative under continuous agitation and subsequently dissolve for 5 minutes. Spread in thickener at medium to high rotational speed. Keep agitator running during the approx. 60 minute swelling time. Add surfactants, then alcohols. Add perfume and acids and finally add stabiliser and hydrogen peroxide and check batch with respect to release parameters.

[0111] b) Polyacrylate-thickened active substance phase 20 Composition: FAEOS-Na, C12-14 + 2 EO 10.10% basic surfactant alkyl (C8-10)-1.5-glucoside 2.50% co. surfactant ethanol 96%, 1% MEK denatured 3.00% co. emulsifier sodium hydroxide (50%) 1.50% neutraliser perfume oil, citrus tang 4.00% aromatic polyacrylate polymer(1) 0.80% thickener distilled water ad.100 (1)maker BF Goodrich, e.g. Carbopol ETD 2690

[0112] approx. 3500 mPas 20° C., Rotovisko LVT, hydrometer 2, 6 rpm 10.0 pH, undiluted clear solution

Production

[0113] Provide water. Spread in thickener at medium to high rotational speed (about 800 rpm) (test by glass-plate test for freedom from pinholing); if polymer particles are still present, further agitation needed. Neutralise solution by NaOH. Stir in perfume oil at reduced rotational speed.

Claims

1. Dispensing device for dispensing active substance fluids into the flushing liquid in a toilet bowl, with a holder (1), which can be suspended at the edge of the toilet bowl, and with at least two storage containers (2, 3), which are provided in the holder (1) and are separate from one another, each for a respective active substance fluid, wherein each storage container (2, 3) has an own outlet opening (4) by way of which the respective active substance fluid can be dispensed into the flushing liquid, characterised in that the storage containers (2, 3) are protected against entry of flushing liquid into the interior thereof and the outlet openings (4) of the storage containers (2, 3) are so arranged that only active substance fluid issues and that in each flushing process the dispensing of a partial quantity of the active substance fluid from each of the storage containers (2, 3) into the flushing liquid takes place.

2. Dispensing device according to claim 1, characterised in that the outlet opening (4) of the storage container (2, 3) is arranged at the base side in use setting.

3. Dispensing device according to claim 1 or 2, characterised in that the storage containers (2, 3) are mounted or mountable in the holder (1) to be individually exchangeable.

4. Dispensing device according to claim 1 or 2, characterised in that the storage containers (2, 3) are coupled together by means of an adapter or the like and can be mounted thus-coupled in the holder (1).

5. Dispensing device according to claim 1 or 2, characterised in that the storage containers (2, 3) are directly coupled together and are mountable thus-coupled in the holder (1).

6. Dispensing device according to claim 1 or 2, characterised in that the storage containers (2, 3) are formed in a common, unitary housing.

7. Dispensing device according to one of claims 1 to 6, characterised in that the storage containers (2, 3) are each individually refillable by way of a respective refilling opening and are optionally fixedly arranged or formed in the holder (1).

8. Dispensing device according to one of claims 1 to 7, characterised in that the storage containers (2, 3) are arranged adjacent to one another at the holder (1).

9. Dispensing device according to one of claims 1 to 7, characterised in that the storage containers (2, 3) are arranged one above the other at the holder (1).

10. Dispensing device according to one of claims 1 to 9, characterised in that the storage containers (2, 3) are mounted at the holder (1) by plugging in from above.

11. Dispensing device according to one of claims 1 to 9, characterised in that the storage containers (2, 3) can be mounted at the holder (1) by pushing in from the side.

12. Dispensing device according to one of claims 1 to 9, characterised in that the storage containers (2, 3) can be mounted at the holder (1) by placing at the side and pivoting in.

13. Dispensing device according to one of claims 1 to 12, characterised in that the storage container (2, 3) has a flexible wall section or a flexible wall overall and expulsion of the active substance fluid disposed therein is carried out by pressure loading of the storage container (2, 3).

14. Dispensing device according to one of claims 1 to 13, characterised in that a plate-shaped distribution element is provided at the holder (1) and has a loading region flowed over by flushing liquid during the flushing process and the interior of the storage container (2, 3) is permanently connected with the distribution element by way of the outlet opening (4), optionally with interposition of an arrangement preventing free flowing of the active substance fluid.

15. Dispensing device according to claim 14, characterised in that the plate-shaped distribution element is provided for at least two storage containers (2, 3) in common, preferably for all storage containers (2, 3).

16. Dispensing device according to one of claims 1 to 13, characterised in that the outlet opening (4) arranged at the storage container (2, 3) at the base side is closed by means of a sealing element (5), that the sealing element (5) is biased into the closed setting closing the outlet opening (4) and is adjustable against the biasing force into a release setting slightly freeing the outlet opening (4), that for adjustment of the sealing element (5) there is provided an actuating element (6) which co-operates with the sealing element (5) and which in each flushing process can be transiently loaded with a force by the flushing liquid to such an extent that the sealing element (5) temporarily adopts the release setting against the biasing force and that for that purpose a loading region (7) loaded by flushing liquid during the flushing process is located at the actuating element (6).

17. Dispensing device according to claim 16, characterised in that the actuating element (6) is constructed as a single-arm lever pivotably connected at one end with the holder (1), that the sealing element (5) is arranged at the actuating element (6) between the end pivotably connected with the holder (1) and the loading region (7) and that the actuating element (6) preferably extends linearly or with a decline from the sealing element (5) towards the loading region (7).

18. Dispensing device according to claim 16 or 17, characterised in that the actuating element (6) is associated in common with the sealing elements (5) for at least two storage containers (2, 3), preferably for all storage containers (2, 3).

19. Dispensing device according to one of claims 1 to 18, characterised in that in the case of two storage containers (2, 3) these are constructed asymmetrically with respect to the centre of the dispensing device as a whole.

20. Dispensing device according to claim 19, characterised in that the outlet openings (4) of the storage containers (2, 3) are arranged at the storage containers (2, 3) to be offset towards the centre of the dispensing device as a whole.

21. Dispensing device according to one of claims 1 to 20, characterised in that the flow cross-sections at the outlet openings (4) and/or the biasing forces at the sealing elements (5) can be determined to be different and/or set to be different.

22. Dispensing device according to one of claims 1 to 21, characterised in that the storage containers (2, 3) contain corresponding active substance fluids, in particular are filled therewith.

23. Dispensing device according to one of claims 1 to 21, characterised in that the storage containers (2, 3) contain different active substance fluids, in particular are filled therewith, wherein the different active substance fluids can be compatible or incompatible with one another.

24. Dispensing device according to claim 22 or 23, characterised in that the active substance fluid is an aromatic phase, particularly a perfumed aromatic phase.

25. Dispensing device according to claim 24, characterised in that the aromatic phase contains at least one aromatic, preferably a perfume oil, at least one surfactant or an emulsifier and water as well as optionally further ingredients such as preservatives, thickeners, sequestering agents, colorants, further surfactants or emulsifiers, stabilisers or descalers.

26. Dispensing device according to claim 22 or 23, characterised in that one active substance fluid comprises a bleaching phase, particularly a bleaching phase containing chlorine, preferably on the basis of hypochlorite, wherein the bleaching phase can optionally contain further ingredients such as thickeners, surfactants and emulsifiers, neutralisers, colorants and aromatics.

27. Dispensing device according to claim 22 or 23, characterised in that one active substance fluid comprises a descaler active substance phase, preferably an acid descaling active substance phase, wherein the descaling active substance phase can contain, apart from the descaler, particularly an organic or anorganic acid, optionally further ingredients such as surfactants or emulsifiers, thickeners, aromatics or preservatives.

28. Dispensing device according to claim 22 or 23, characterised in that one active substance fluid comprises a highly concentrated surfactant phase (foam booster).

29. Dispensing device according to claim 22 or 23, characterised in that one active substance fluid comprises an active substance phase which acts antibacterially and/or fungicidally and/or antivirally and which can contain, apart from the active substance acting antibacterially and/or fungicidally and/or antivirally, optionally further ingredients such as surfactants and emulsifiers, thickeners, aromatics or preservatives.

30. Dispensing device according to claim 22 or 23, characterised in that one active substance fluid comprises an active substance phase which has an enzyme content and which can contain, apart from the enzyme, further ingredients such as surfactants and emulsifiers, thickeners, aromatics or preservatives.

31. Dispensing device according to claim 22 or 23, characterised in that one active substance fluid comprises an absorbent, particularly odour-absorbent, active substance phase which can contain, apart from the absorption agent, particularly odour-absorption agent, optionally further ingredients such as surfactants and emulsifiers, thickeners, aromatics or preservatives.

32. Dispensing device according to claims 23 to 24 and optionally one or more of claims 25 to 31, characterised in that the storage containers (2, 3) contain different active ingredient fluids, wherein one of the storage containers (2, 3) contains an aromatic phase particularly as defined in claim 24 and/or claim 25.

Patent History
Publication number: 20040068782
Type: Application
Filed: Oct 23, 2003
Publication Date: Apr 15, 2004
Inventors: Ralph Butter-Jentsch (Langenfeld), Ronald Menke (Mettmann), Georg Muehlhausen (Duesseldorf), Frank Pessel (Duesseldorf), Stefan Huchler (Leverkusen), Thomas Jungmann (Neuss)
Application Number: 10416681
Classifications
Current U.S. Class: Chemical Holder Suspended In Bowl (004/231)
International Classification: B65B001/04; E03D009/02;