Retort container, and hot melt adhesive therefor
A retort container comprises a container body structured and arranged for holding a food product, the container body defining an opening and a sealing surface surrounding the opening, and a lid bonded to the sealing surface of the container body to close the opening, the lid being bonded to the sealing surface with a hot melt adhesive. The adhesive comprises a polyamide resin blended with a second resin that raises the glass transition temperature of the adhesive above the glass transition temperature of the polyamide resin alone, the adhesive bonding the lid to the sealing surface with a temperature-dependent bond strength that is relatively low at room temperature and substantially higher at retort temperatures of 100° C. to 120° C.
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The invention relates to containers for products, and more particularly relates to retort containers for food.
Retort containers are containers that are hermetically sealed after filling with a food product, and are then heated to a temperature of about 100° C. to 120° C. for a period of time to ensure that all microorganisms in the container have been killed. The chief advantages of retort containers is that they do not require refrigeration prior to opening, and they can be stored for long periods of time in their initially sealed condition. For many years, metal cans were the predominant type of retort container.
More recently, plastic retort containers have been developed. Plastic containers are attractive for various reasons, including microwavability. One of the challenges with plastic retort containers is the closure system. More particularly, the container lid must be hermetically sealed to the container with sufficient strength to withstand the elevated temperature and pressure conditions during retort sterilization; on the other hand, the seal strength must not be so high that the consumer finds it difficult or impossible to remove the lid. Retort integrity and ease of opening are usually at odds with each other, such that anything that is done to improve retort integrity has a deleterious effect on ease of opening, and vice versa.
Prior to the present invention, plastic retort containers have generally included some type of membrane lid that is heat-sealed to the container. The difficulties of accurately controlling the seal strength of heat seals are well known. For instance, some heat seal materials such as SURLYN® (ionomer resin) have a relatively narrow heat sealing temperature window within which the resulting seal strength is in a desirable range. If the sealing temperature is too low, the seal strength may be inadequate to prevent failure during retort; if the temperature is too high, the seal strength may be so great that the consumer cannot remove the lid. It can be difficult to control the sealing temperature with sufficient accuracy to stay within the desired window.
Other requirements for all-plastic retort containers and lids include high-barrier performance against water vapor and oxygen, and fast sealing speed. The high-barrier performance must be achieved without the use of metal foil, which has commonly been used in many retort containers. Fast sealing speed is difficult to achieve with all-plastic lids because induction sealing cannot be used, and direct thermal heat sealing is slow because of the poor thermal conductivity of plastic.
BRIEF SUMMARY OF THE INVENTIONThe invention addresses the above needs and achieves other advantages, by providing an all-plastic retort container wherein the lid is adhesively sealed to the container as opposed to being heat-sealed to the container. The adhesive employed for sealing the lid to the container is specially formulated to provide a temperature-dependent bond, such that at room temperature the bond strength is relatively low, while at retort temperatures of 100° C. to 120° C. the bond strength is higher.
In one embodiment of the invention, a retort container comprises a container body structured and arranged for holding a food product, the container body defining an opening and a sealing surface surrounding the opening, and a lid bonded to the sealing surface of the container body to close the opening, the lid being bonded to the sealing surface with a hot melt adhesive. The adhesive comprises a polyamide resin blended with a second resin that raises the glass transition temperature of the adhesive above the glass transition temperature of the polyamide resin alone, the adhesive bonding the lid to the sealing surface with a temperature-dependent bond strength that is relatively low at room temperature and substantially higher at retort temperatures of 100° C. to 120° C.
The hot melt adhesive preferably has a glass transition temperature (Tg) close to room temperature, for example about 20° C. to 40° C. A preferred adhesive comprises a substantially amorphous polyamide resin as a primary component. The polyamide resin can have a Tg that is less than or equal to 0° C. An example of a suitable polyamide resin is UNI-REZ® 2617 available from Arizona Chemical of Jacksonville, Fla. A second resin is added to the polyamide resin in sufficient amount to raise the Tg of the resulting composition to about room temperature. The second resin can comprise a maleic modified rosin ester. An example of a suitable second resin is a maleic modified glycerine ester of tall oil rosin such as SYLVACOTE® 7071 available from Arizona Chemical of Jacksonville, Fla.
As an example, the adhesive can comprise a polyamide resin and a maleic modified rosin ester, wherein the maleic modified rosin ester comprises about 10 to about 20 weight percent of the adhesive.
The invention is applicable to a wide range of container types and configurations. As one example, the container body can be thermoformed from an all-plastic high-barrier sheet. The sheet can have a structure, for example, of {polypropylene/tie/EVOH/tie/polypropylene}. The polypropylene layers are good barriers against moisture, while the ethylene vinyl alcohol copolymer (EVOH) layer provides oxygen barrier performance. The sheet can be formed by coextrusion or other processes.
Alternatively, the container body can be formed by a coextrusion blow-molding process. For example, a parison can be coextruded as a multi-layer structure such as {polypropylene/tie/EVOH/tie/polypropylene} and then enclosed in a mold and inflated to form the container body.
The lid similarly can comprise a multi-layer structure such as {polypropylene/tie/EVOH/tie/polypropylene}. Other high-barrier multi-layer structures can be used for the container body and/or lid.
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING(S)Having thus described the invention in general terms, reference will now be made to the accompanying drawings, which are not necessarily drawn to scale, and wherein:
The present inventions now will be described more fully hereinafter with reference to the accompanying drawings, in which some but not all embodiments of the invention are shown. Indeed, these inventions may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will satisfy applicable legal requirements. Like numbers refer to like elements throughout.
With reference to
The lid 14 is bonded to the flange 20 of the container body by a hot melt adhesive 40. The adhesive 40 is formulated to provide a temperature-dependent bond strength between the lid 14 and the container body 12. More specifically, the bond strength is relatively low at room temperature so that the lid can be readily peeled from the container body, while the bond strength is higher at retort temperatures of about 100° C. to 120° C. The adhesive preferably comprises a substantially amorphous polyamide-based composition having a glass transition temperature, Tg, that is approximately room temperature (e.g., 20° C. to 40° C.). When amorphous polymers are near their glass transition temperature, they tend to lose their adhesiveness. Accordingly, by engineering the adhesive 40 so that its Tg is near room temperature, the bond strength provided by the adhesive is relatively low at room temperature. However, at retort temperatures, which are substantially above Tg, the adhesive has greater adhesiveness and hence provides a stronger bond. In this manner, the lid can be bonded to the container body firmly enough to withstand retort without failure, and yet the lid can easily be peeled off when the consumer desires to open the container.
A suitable adhesive 40 can comprise a polyamide resin having a Tg that is less than or equal to 0° C., and a second resin that raises the Tg of the adhesive to about room temperature. The polyamide resin can be, for example, the resin available from Arizona Chemical of Jacksonville, Fla., having the designation UNI-REZ® 2617. This resin has a tensile modulus of 205 MPa (30,000 psi), a softening point (ASTM E 28 ring and ball method) of 163° C. to 175° C., and a shear adhesion failure temperature or SAFT (ASTM D 4498 method with a 1 kg. weight) of 150° C.
The second resin can be a maleic modified rosin ester. An example of a suitable material is SYLVACOTE® 7071 available from Arizona Chemical. This material is a maleic modified glycerine ester of tall oil rosin, and its recommended applications include as a film-forming resin for nitrocellulose-based packaging-gravure inks that contain acetone, and in lacquer wood furniture sealer and sander coats. It has a softening point (ASTM E 28-67 ring and ball method) of 125° C.
The Tg-raising resin is added to the polyamide resin in sufficient quantity to raise the Tg of the resulting composition to about room temperature. The composition can also contain other components as desired. As an example, the adhesive composition can comprise about 70 to 95 weight percent, more preferably about 80 to 90 weight percent, of polyamide resin, and about 30 to 5 weight percent, more preferably about 20 to 10 weight percent, of maleic modified rosin ester.
The adhesive should have a shear adhesion failure temperature (SAFT) above the expected temperature of retort, which is typically between about 100° C. and about 120° C. While the addition of the maleic modified rosin ester to the polyamide resin, which on its own has an SAFT of about 150° C., is likely to bring the SAFT of the composition down somewhat below 150° C., it should still be above 120° C.
As noted, the invention is not limited to any particular container type or configuration. Thus,
The lid 214 can have various constructions. The exemplary construction shown in
Many modifications and other embodiments of the inventions set forth herein will come to mind to one skilled in the art to which these inventions pertain having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. Therefore, it is to be understood that the inventions are not to be limited to the specific embodiments disclosed and that modifications and other embodiments are intended to be included within the scope of the appended claims. Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.
Claims
1. A retort container, comprising:
- a container body structured and arranged for holding a food product, the container body defining an opening and a sealing surface surrounding the opening; and
- a lid bonded to the sealing surface of the container body to close the opening, the lid being bonded to the sealing surface with a hot melt adhesive, the adhesive comprising a polyamide resin blended with a second resin that raises the glass transition temperature of the adhesive above the glass transition temperature of the polyamide resin alone, the adhesive bonding the lid to the sealing surface with a temperature-dependent bond strength that is relatively low at room temperature and substantially higher at retort temperatures of 100° C. to 120° C.
2. The retort container of claim 1, wherein the second resin comprises a maleic modified rosin ester.
3. The retort container of claim 2, wherein the adhesive comprises about 10 to 20 weight percent of the maleic modified rosin ester.
4. The retort container of claim 1, wherein the container body is formed entirely of polymer material.
5. The retort container of claim 1, wherein the lid is formed entirely of polymer material.
6. The retort container of claim 1, wherein the lid and the container body each is formed entirely of polymer material.
7. The retort container of claim 1, wherein the container body comprises a multi-layer body wall.
8. The retort container of claim 7, wherein the container body comprises a thermoformed multi-layer sheet.
9. The retort container of claim 7, wherein the container body comprises a coextrusion blow-molded structure.
10. The retort container of claim 7, wherein the multi-layer sheet includes a first polymer layer providing moisture barrier performance and a second polymer layer providing oxygen barrier performance.
11. The retort container of claim 10, wherein the first polymer layer comprises polypropylene and the second polymer layer comprises ethylene vinyl alcohol copolymer.
12. The retort container of claim 11, wherein the multi-layer sheet further comprises a third polymer layer of polypropylene, the ethylene vinyl alcohol copolymer layer being disposed between the polypropylene layers.
13. The retort container of claim 1, wherein the lid comprises a multi-layer structure.
14. The retort container of claim 13, wherein the lid includes at least a first polymer layer providing moisture barrier performance and a second polymer layer providing oxygen barrier performance.
15. A retort container, comprising:
- a container body structured and arranged for holding a food product, the container body defining an opening and a sealing surface surrounding the opening; and
- a lid bonded to the sealing surface of the container body to close the opening, the lid being bonded to the sealing surface with a hot melt adhesive, the adhesive having a glass transition temperature of about 20° C. to 40° C., the adhesive bonding the lid to the sealing surface with a temperature-dependent bond strength that is relatively low at room temperature and substantially higher at retort temperatures of 100° C. to 120° C.
16. The retort container of claim 15, wherein the hot melt adhesive predominantly comprises a polyamide resin.
17. The retort container of claim 15, wherein the hot melt adhesive comprises a first resin having a glass transition temperature substantially lower than 20° C., and a second resin added to the first resin to raise the glass transition temperature of the adhesive to about 20° C. to 40° C.
18. The retort container of claim 17, wherein the first resin comprises polyamide.
19. The retort container of claim 17, wherein the second resin comprises maleic modified rosin ester.
20. The retort container of claim 17, wherein the first resin comprises polyamide and the second resin comprises maleic modified rosin ester.
21. A hot melt adhesive suitable for retort containers, comprising:
- a polyamide resin having a glass transition temperature less than or equal to about 0° C.; and
- a maleic modified rosin ester blended with the polyamide resin to form the hot melt adhesive, the maleic modified rosin ester being present in the hot melt adhesive in sufficient proportion to give the hot melt adhesive a glass transition temperature of about room temperature.
22. The hot melt adhesive of claim 21, wherein the polyamide resin comprises about 70 to 95 weight percent of the adhesive and the maleic modified rosin ester comprises about 30 to 5 weight percent of the adhesive.
23. The hot melt adhesive of claim 21, wherein the polyamide resin comprises about 80 to 90 weight percent of the adhesive and the maleic modified rosin ester comprises about 20 to 10 weight percent of the adhesive.
Type: Application
Filed: May 17, 2004
Publication Date: Nov 17, 2005
Applicant:
Inventor: Srinivas Nomula (Hartsville, SC)
Application Number: 10/847,270