Pre-processing assembly for pre-processing fuel feedstocks for use in a fuel cell system
A pre-processing assembly and method for processing fuel feedstock containing oxygen and hydrocarbons having higher and lower hydrocarbon content for a fuel cell, wherein the pre-processing assembly has a deoxidizing bed for reducing oxygen in the fuel feedstock and a pre-reforming bed for reducing higher hydrocarbon content in the fuel feedstock and wherein the deoxidizing bed and the pre-reforming bed are disposed within a common reaction vessel such that the fuel feedstock first passes through the deoxidizing bed and thereafter through the pre-reforming bed. The pre-reforming assembly may further include a propane processor bed for processing propane and propylene in the fuel feedstock, where the propane processor bed is disposed within the common reaction vessel with the deoxidizing bed and the pre-reforming bed.
This invention relates to processing of fuel feedstocks containing hydrocarbons for use in fuel cell systems and, in particular, to pre-processing assemblies for performing pre-processing of the fuel feedstocks.
A fuel cell is a device which directly converts chemical energy stored in hydrocarbon fuel into electrical energy by means of an electrochemical reaction. Generally, a fuel cell comprises an anode and a cathode separated by an electrolyte, which serves to conduct electrically charged ions. Molten carbonate fuel cells operate by passing a reactant fuel gas through the anode, while oxidizing gas is passed through the cathode. In order to produce a useful power level, a number of individual fuel cells are stacked in series with an electrically conductive separator plate between each cell.
Current fuel cells require as the reactant fuel gas a clean gas composed of hydrogen or a mixture of hydrogen and carbon monoxide. The reactant fuel gas is generally developed from a hydrocarbon-containing feedstock using a reforming process. The hydrocarbon-containing feedstock usually contains substantial amounts of lower hydrocarbons, i.e., hydrocarbons with 2 or less carbons, such as methane, as well as small amounts of hydrogen, carbon dioxide, nitrogen and higher hydrocarbons, i.e. hydrocarbons with more than 2 carbons. This is true, for example, when the fuel feedstock is natural gas, peak shaving gas, digester gas and coal bed methane.
The fuel feedstock is usually subjected to pre-processing to reduce or eliminate the higher hydrocarbons and to convert a portion of the lower hydrocarbons to methane, hydrogen and carbon dioxide. The feedstock is then further processed in a reforming unit to generate a fuel gas rich in hydrogen.
Conventional pre-processing is carried out using a deoxidizer assembly followed by a pre-reforming assembly. The deoxidizer assembly reduces the concentration of oxygen in the fuel feedstock before the feedstock enters the pre-reforming assembly. This protects the catalyst (usually, a Ni-based catalyst) used in the pre-reforming assembly, which otherwise would be deactivated in the presence of oxygen.
In the pre-reforming assembly, the reforming reaction is a conversion process which may inadvertently result in carbon formation based on fuel composition and steam. Carbon formation is of a particular concern when the fuel feedstock contains propylene, since the propensity to form carbon increases as the concentration of propylene increases. The carbon which is produced deposits at the active sites of the reforming catalyst of the pre-reforming assembly, thereby deactivating the catalyst. This reduces the life of the pre-reforming assembly.
In order to reduce carbon formation in conventional pre-reforming assemblies, special catalysts either containing alkali or based on an active magnesia support have been proposed. Another technique is to use adiabatic processing. In such case, a fixed bed adiabatic pre-reforming assembly converts the higher hydrocarbon content at low temperature with steam into methane, hydrogen and carbon oxides.
Propylene-containing fuel feedstocks generally have a high concentration of sulfur-containing compounds. These compounds also tend to deactivate the reforming catalysts in the pre-reforming assembly. Although fuel feedstocks are typically desulfurized in a desulfurizer unit before being carried to the pre-reforming assembly, high sulfur concentration and the propylene in the fuel feedstocks reduce the capacity of the desulfurizer unit.
Fuel feedstocks supplied to the pre-reforming assembly must also be supplied with additional hydrogen from a hydrogen supply. This is required to provide a sufficient concentration of hydrogen in the feedstocks to maintain a reducing environment for the reforming catalyst, thereby maintaining the catalyst activity.
As can be appreciated, conventional pre-processing of fuel feedstocks is complex and costly, due to the need for additional units or special components for supplying hydrogen, for reducing carbon formation and for removing propylene and an additional unit to remove oxygen entering into the pre-reforming assembly. A pre-processing assembly of simpler design, less cost and longer life would thus be desirable.
It is therefore an object of the present invention to provide a pre-processing assembly which is better able to process fuel feedstocks containing hydrocarbons and oxygen without deactivation of the pre-processing catalyst.
It is a further object of the invention to provide a pre-processing assembly which is capable of operating without an additional hydrogen supply and has an increased operating life.
It is yet a further object of the invention to provide a pre-processing assembly which is specifically adapted to retard the affects of propylene and other olefins in hydrocarbon containing fuel feedstocks.
SUMMARY OF THE INVENTIONIn accordance with the principles of the present invention, the above and other objectives are realized in a pre-processing assembly and method for pre-processing a fuel feedstock containing hydrocarbons including higher hydrocarbon content in which a common vessel houses both a deoxidizing unit for reducing the oxygen content in the fuel feedstock and a pre-forming unit for receiving the fuel feedstock after passage through the deoxidizing unit and for reducing the higher hydrocarbon content in the fuel feedstock. In performing this pre-processing the assembly also reduces a portion of the lower hydrocarbon content in the feedstock and increases the hydrogen content.
In the embodiment of the invention disclosed herein, the pre-reforming unit is arranged to follow the deoxidizing unit along the flow path of the fuel feedstock and both units are in bed form. Also, in this embodiment, the catalyst of the deoxidizing bed is one of a Pt—Pd on alumina catalyst or a Pt—Rh-based catalyst or a Rh—Pt-based alumina catalyst and the catalyst of the pre-reforming bed is nickel-based and one of C11-PR (Sud Chemie), CRG-F (Johnson Matthey), CRG-LH (Johnson Matthey) and G-180 (BASF).
In a further aspect of the invention, the pre-processing assembly further includes a propane processor unit for processing propane and propylene in the fuel feedstock. In the embodiment disclosed, the propane processor unit is in bed form and arranged between the deoxidizing bed and the pre-reforming bed. The propane processor bed has a nickel-based carbon resistant catalyst, such as FCR-HC59 (Sud Chemie).
BRIEF DESCRIPTION OF THE DRAWINGSThe above and other features and aspects of the present invention will become more apparent upon reading the following detailed description in conjunction with the accompanying drawings, in which:
The fuel delivery system 101 also includes a desulfurizer 104, a preheater 106 and a reformer 110. The fuel feedstock from the fuel supply 102 is passed to the desulfurizer 104, where sulfur-containing compounds in the fuel feedstock are physically and/or chemically removed. Desulfurized fuel feedstock then flows to the pre-heater 106 where it is preheated to a suitable temperature, e.g., approximately 375° C., before being carried to the fuel pre-processing assembly 108. Pre-processed fuel feedstock exiting the assembly 108 is suitable for use in a fuel cell assembly 112. In the fuel cell assembly 112, the hydrogen-rich fuel undergoes an electrochemical reaction to produce power.
As discussed in detail herein below, in accordance with the principles of the present invention, the pre-processing assembly 108 includes a plurality of fuel processing units disposed or housed in a common vessel for deoxidizing the fuel feedstock and for pre-reforming the deoxidized fuel feedstock to reduce or substantially eliminate the higher hydrocarbon content. This pre-reforming processing also reduces the lower hydrocarbon content by converting it to hydrogen so that the resultant pre-processed fuel feedstock exiting the assembly 108 has increased hydrogen content and methane suitable for high temperature fuel cell applications.
A detailed schematic view of a first embodiment of the pre-processing assembly 108 is shown in
As shown, the pre-reforming bed 206 is arranged to follow the deoxidizer bed 204 along the flow path 201 of the feedstock. Also, a porous member, shown as a screen 212 which typically can be made of Nickel mesh having a mesh size of 10-14, separates the beds and provides support for the bed 204. The pre-processing bed 206, in turn, is supported on the lower surface 202a of the vessel 202.
The deoxidizer bed 204 comprises a deoxidizing catalyst which typically might be Pt/Pd on Alumina, or G-74D, manufactured by Sud Chemie Inc. Other catalysts such as Pt—Rh based catalysts and Rh—Pd based Alumina catalysts also may be used.
The catalyst used in the pre-reforming bed 206 may be a standard nickel based catalyst. Examples are nickel-based alumina catalysts, or C11-PR catalyst, manufactured by Sud-Chemie Inc. Additionally, other nickel-based catalysts such as CRG-F and CRG-LH, manufactured by Johnson Matthey or G-180 manufactured by BASF may likewise be used.
The shapes of the catalysts used in both beds may vary. For example, in the case shown, pellet-shaped catalysts are employed in both the deoxidizer bed 204 and the pre-reforming bed 206. In addition, monolith-based catalyst structures, comprising a ceramic monolith substrate with a catalyst coating, are suitable for use in each bed.
As mentioned above, the pre-processing assembly 108 reduces or substantially eliminates the higher hydrocarbon content and the oxygen content in the fuel feedstock. It also reduces the lower hydrocarbon content and increases the hydrogen content in the feedstock. Due to the arrangement of the deoxidizer and pre-reforming beds 204 and 206 in the common vessel 202, the pre-processing reduces the possibility of deactivating the catalysts in the beds and is carried out without the need of adding hydrogen from a hydrogen supply to the fuel feedstock.
In particular, the catalyst of the deoxidizer bed 204 facilitates the removal of oxygen from the fuel feedstock. Where the feedstock is coal mine methane or digester gas, the oxygen is removed by reacting the oxygen with the methane in the feedstock aided by the catalyst, as follows:
2CH4+O2→2CO+4H2+heat
CH4+O2→CO2+2H2+heat
Where the feedstock is peakshaving gas, the oxygen is removed in the deoxidizer bed 204 by reacting the propane in the feedstock with oxygen, as follows:
C3H8+2O2→2CO+2CO2+4H2+heat
Removal of oxygen in the deoxidizer bed 204 prevents the deactivation of the catalyst in the pre-reforming bed 206. It also produces additional hydrogen needed to maintain a reducing environment for such catalyst. In the pre-reforming bed 206, the reduction of the higher hydrocarbon content in the deoxidized feedstock is aided by the catalyst and occurs by conversion of the higher hydrocarbon content into a mixture of hydrogen, carbon oxides and methane. A reduction in the lower hydrocarbon content also occurs through conversion and results in increased hydrogen and carbon oxides. Particularly, approximately 10% of the methane in the fuel is reformed to provide hydrogen for the electrochemical reaction in the fuel cell assembly. The remainder of the methane in the fuel is internally reformed in the fuel cell assembly. The following reactions exemplify the conversion processing:
CnHm+nH2O→nCO+(m/2+n)H2
CH4+H2O→CO+3H2
C3H8+2H2→CO2+2CH4+2H2
As mentioned above, the deoxidizer bed 204 is firstly disposed in the vessel 202 in relation to the direction of the flow or flow path 201 of the fuel feedstock and to the inlet of the vessel 202. The pre-reforming bed 206 then follows the deoxidizer bed 204 in the direction of the flow path 201. As was stated previously, this arrangement causes the removal of oxygen from the fuel feedstock before entering the pre-reforming bed, thereby preventing deactivation of the catalyst in the bed. The life of the pre-processing assembly 108 is thus extended.
As can also be seen from the above, the deoxidizing and pre-reforming reactions in the beds 204 and 206 increase the hydrogen content in the feedstock. This maintains a reducing environment in the pre-reforming bed 206. In particular, back diffusion of hydrogen in the pre-reforming bed 206 provides this reducing environment, thereby allowing the assembly 108 to operate without an additional supply of hydrogen to the fuel feedstock.
The amount of back diffusion of hydrogen in the bed 206 is inversely related to the space velocity of the fuel feedstock. Accordingly, maintaining a low space velocity of the fuel feedstock through the pre-reforming bed 206 is desired in order to realize sufficient hydrogen back diffusion in the bed.
As can be appreciated, the space velocity is directly proportional to the flow of the fuel through the pre-reforming bed 206 and inversely proportional to the volume of the catalyst in the pre-reforming bed 206. Accordingly, the space velocity of the fuel feedstock can be controlled by adjusting the volume of the catalyst in the pre-reforming bed 206 and/or by changing the amount of the fuel flowing through the reforming bed 206, using the following relationship:
In addition to controlling the space velocity of the fuel feedstock, the superficial velocity of the fuel needs to be controlled for a desired amount of hydrogen back diffusion. Superficial velocity is a function of a diameter of the vessel through which the fuel is flowing. Particularly, superficial velocity is directly proportional to the fuel flow and inversely proportional to the diameter of the pre-reforming bed 206.
In the pre-processing assembly 108 of the present invention, space velocities between 2,000 to 5,000 h−1 and maximum superficial velocities of approximately 1.3 ft/s have been found desirable in operation of the pre-reforming bed 206.
Moreover, the pre-reforming bed 206 may additionally be adapted to act as a guard to trap sulfur-containing compounds present in the fuel feedstock which are not removed by the desulfurizer unit 104 of
The optimal design of the pre-reforming assembly 108 will depend upon the particular application. Some of the important factors to be considered are the requirements of the fuel cell assembly 112, the type of fuel gas being processed, and the amount of gas to be treated. An illustrative example of a pre-reforming assembly 108 is described herein below.
EXAMPLE 1The pre-processing assembly 108 has been optimized for processing fuel feedstock comprising oxygen and methane for use in a 300 kW Direct Fuel Cell power plant. The deoxidizer bed 204 comprises a G-74D catalyst and has a volume of 0.7 cubic feet. The pre-reforming bed 206 comprises a C11-PR catalyst and has a volume of 2.5 cubic feet. The deoxidizer bed 204 is approximately 4 inches in thickness and the pre-reforming bed 206 is approximately 14.5 inches in thickness. The common vessel 202 is made from 304/310 stainless steel and has a volume of 4 cubic feet and a diameter of 20 inches.
The optimal temperatures of the fuel feedstock entering the vessel 202 through the inlet 208 and of the pre-processed fuel feedstock exiting the vessel 202 through the outlet 210 are approximately 300 to 490° C. The optimal operating temperature range of the deoxidizer bed 204 is between 300° C. and 600° C., and the optimal operating temperature range of the pre-reforming bed 206 is between 320° C. and 540° C. The space velocity of the fuel feedstock flowing through the deoxidizer bed 204 is between 5,000 and 12,000 h−1 and the space velocity of the fuel feedstock flowing through the pre-reforming bed 206 is between 2,000 and 5,000 h−1. Moreover, in order to maintain a desired hydrogen back diffusion in the pre-reforming bed 206, the desired maximum superficial velocity of the fuel feedstock flowing through the bed 206 is 1.3 ft/s at STP conditions.
The performance of the pre-processing assembly 108 was tested by passing through the assembly 108 fuel feedstock comprising 6.31 lb-mole/hr of methane, 0.06 lb-mole/hr of carbon dioxide, 12.48 lb-mole/hr water, 0.08 lb-mole/hr of nitrogen, 0.17 lb-mole/hr of ethane and 0.03 lb-mole/hr of propane. The temperature of the fuel feedstock entering the deoxidizer bed 204 was approximately 425° C. and the space velocity of the fuel feedstock was approximately 10,000 hr−1. The temperature of the pre-processed fuel leaving the pre-reforming bed 206 was about 320° C., and the space velocity of the pre-reformed fuel leaving the pre-reforming bed 206 was about 3,000 hr−1. Fuel pre-processed using the pre-processing assembly comprised about 1.67 lb-mole/hr of hydrogen, 6.25 lb-mole/hr of methane, 0.53 lb-mole/hr of carbon dioxide, 11.54 lb-mole/hr of water and 0.08 lb-mole/hr of nitrogen. From these performance results, it can be seen that all of the ethane or propane present in the fuel feedstock was converted to methane, hydrogen and carbon dioxide in the assembly 108.
EXAMPLE 2In this example, the pre-processing assembly 108 of Example 1 has also been optimized for processing hydrocarbon fuels contaminated with up to 10% oxygen. The optimal temperature range of the fuel feedstock entering the vessel 202 through inlet 208 is approximately 310° C. to 500° C.
The deoxidizing function of the pre-processing assembly 108 of
As the tabulated data of
A pre-processing assembly 108 having this construction is estimated to have a life of approximately 5 years as compared to an average 3-year operating life of a conventional assembly. The life of the pre-processing assembly 108 is increased partly due to the maintenance of the pre-reforming bed 206 in a reducing atmosphere by providing hydrogen from the deoxidizer and from optimized hydrogen back diffusion, thereby increasing the overall life of the pre-reforming catalyst.
In accordance with a further aspect of the invention and to further improve the performance and the operating life of the pre-processing assembly 108 when the fuel feedstock includes propane and/or propylene, the assembly 108 is additionally adapted as shown in
As shown in
In the embodiment of
C3H6+2H2O→CO2+2CH4+H2
C3H8+2H2O→CO2+2CH4+2H2
The pre-processing assembly 108 of
As with the embodiment of
The pre-processing assembly of
The optimal temperature of the fuel feedstock entering the vessel 202 through the inlet 208 is approximately 350° C. and the temperature of the pre-processed fuel exiting the vessel 202 through the outlet 210 is approximately 350° C. The deoxidizer bed 204 is adapted to operate at a temperature between 300° and 600° C., while the propane processor bed 301 and the pre-reforming bed 206 are adapted to operate at temperature between 300° and 540° C. The optimal operating temperature range of beds 204, 301 and 206 of the assembly 108 is between 300° C. and 400° C. The desired space velocity of the fuel feedstock flowing through the deoxidizer bed 204 is between 5,000 and 12,000 h−1. The desired space velocity of the fuel feedstock flowing through the propane processor bed 301 is between 5,000 and 11,000 h−1, while the desired space velocity of the fuel feedstock flowing through the pre-processing bed 206 is between 2,000 and 5,000 h−1. Moreover, it is preferred that the steam to carbon ratio of the fuel feedstock entering the assembly is approximately 3.
The performance of the pre-processing assembly 108 of
As shown in
As can be seen from
As can also be seen, as the inlet temperature of the feedstock increased, the concentration of hydrogen in the exiting pre-processed fuel feedstock gas also increased, while the concentration of methane in the exiting pre-processed fuel feedstock gas decreased. Moreover, as shown, at all inlet temperatures the pre-processed fuel feedstock gas exiting the assembly included a sufficient concentration of hydrogen to maintain the pre-reforming catalyst in a reducing atmosphere, thus extending the operating life of the assembly 108.
Based on the above tests performed at different fuel feedstock inlet temperatures, it can be seen that the performance of the assembly 108 is excellent over a wide temperature range, allowing the inlet temperature to be varied according to the desired outlet concentrations of hydrogen and methane. The optimal operating temperatures for the pre-processing assembly of
The effect of fuel feedstock space velocity on the performance of the pre-processing assembly 108 of
The performance of the assembly 108 of
Furthermore, the performance of the assembly 108 of
The performance of the assembly 108 was also tested with propane fuel feedstock to which was added different hydrogen concentrations. Fuel feedstock used during this test comprised 5 scfm of propane and 39 scfm of steam (steam to carbon ratio of 2.6) and had an inlet temperature of 310° C. Different amounts of hydrogen were added to the fuel feedstock at the inlet of the assembly 108.
In all cases it is understood that the above-described arrangements are merely illustrative of the many possible specific embodiments which represent applications of the present invention. Numerous and varied other arrangements can be readily devised in accordance with the principles of the present invention without departing from the spirit and the scope of the invention. For example, various modifications of the catalyst bed construction of the invention may be made to optimize the space velocity and the superficial velocity of the fuel feedstock gas as it is being passed through the pre-reforming bed. Moreover, other deoxidizing and pre-reforming catalysts may be used in the beds 202 and 204 in lieu of those discussed above.
Claims
1. A pre-processing assembly for processing fuel feedstock for a fuel cell, the fuel feedstock including oxygen and hydrocarbons having higher and lower hydrocarbon content, said pre-processing assembly comprising:
- a deoxidizing unit for reducing the oxygen in said fuel feedstock; and
- a pre-reforming unit for reducing the higher hydrocarbon content in said fuel feedstock;
- and a common vessel;
- wherein said deoxidizing unit and said pre-reforming unit are disposed within said common vessel such that said fuel feedstock passes through said deoxidizing unit first and thereafter through said pre-reforming unit.
2. A pre-processing assembly according to claim 1, wherein said deoxidizing unit comprises a deoxidizing bed and said pre-reforming unit comprises a pre-reforming bed, said pre-reforming bed following said deoxidizing bed along the flow path of said fuel feedstock.
3. A pre-processing assembly according to claim 2, wherein said deoxidizing bed comprises a deoxidizing catalyst and said pre-reforming bed comprises a pre-reforming catalyst.
4. A pre-processing assembly according to claim 3, wherein said deoxidizing catalyst is one of Pt—Pd on alumina catalyst, Pt—Rh-based catalyst and Rh—Pd-based alumina catalyst.
5. A pre-processing assembly according to claim 4, wherein said deoxidizing catalyst is G-74D.
6. A pre-processing assembly according to claim 4, wherein said pre-reforming catalyst is a nickel-based catalyst.
7. A pre-processing assembly according to claim 6, wherein said pre-reforming catalyst is one of C11-PR, CRG-F, CRG-LH and G-180.
8. A pre-processing assembly according to claim 7, wherein said deoxidizing catalyst and said pre-reforming catalyst are pellet-shaped catalysts.
9. A pre-processing assembly according to claim 7, wherein each of said deoxidizing catalyst and said pre-reforming catalyst comprises a catalyst-coated ceramic monolith.
10. A pre-processing assembly according to claim 1, wherein said deoxidizing bed in reducing said oxygen produces hydrogen and said pre-reforming bed converts said lower hydrocarbon content to hydrogen to maintain a reducing environment in said pre-reforming bed.
11. A pre-processing assembly according to claim 10, wherein the space velocity of the fuel feedstock in said pre-reforming bed is such that hydrogen back diffusion is developed and maintained in said pre-reforming bed.
12. A pre-processing assembly according to claim 11, wherein the space velocity of said fuel feedstock in said pre-reforming bed is between 2,000 and 5,000 h−1.
13. A pre-processing assembly according to claim 12, wherein the space velocity of said fuel feedstock in said deoxidizer bed is between 5,000 and 12,000 h−1.
14. A pre-processing assembly according to claim 13, wherein:
- said deoxidizer bed has a volume of 0.7 cubic feet; and
- said pre-reforming bed has a volume of 2.5 cubic feet.
15. A pre-processing assembly according to claim 14, wherein the temperature of said fuel feedstock upon entry into said assembly is approximately 375° C.
16. A pre-processing assembly according to claim 15, wherein the deoxidizer bed operates at temperatures between 300° C. and 600° C., and said pre-reforming bed operates at temperatures between 320° C. and 540° C.
17. A pre-processing assembly according to claim 16, wherein the steam to carbon ratio of the fuel feedstock is between 2.9 and 3.4.
18. A pre-processing assembly according to claim 17, wherein the superficial velocity of the fuel feedstock in said pre-reforming bed is 1.3 ft/s at STP conditions.
19. A pre-processing assembly in accordance with claim 1, wherein said pre-reforming unit is further adapted to remove sulfur-containing compounds from said fuel feedstock.
20. A pre-processing assembly for processing fuel feedstock for a fuel cell, the fuel feedstock including oxygen and hydrocarbons having higher and lower hydrocarbon content, said pre-processing assembly comprising:
- a deoxidizing unit for reducing the oxygen in said fuel feedstock;
- a propane processor unit for reducing the propylene in said fuel feedstock; and
- a pre-reforming unit for reducing the higher hydrocarbon content in said fuel feedstock.
21. A pre-processing assembly according to claim 20, wherein said propane processor unit comprises a nickel-based carbon resistant catalyst.
22. A pre-processing assembly according to claim 21, wherein said deoxidizing unit, said propane processor unit and said pre-reforming unit are disposed within a common vessel.
23. A pre-processing assembly according to claim 22, wherein said deoxidizing unit comprises a deoxidizing bed, said pre-reforming unit comprises a pre-reforming bed and said propane processor unit comprises a propane processor bed.
24. A pre-processing assembly according to claim 23, wherein said deoxidizing bed, said propane processor bed and said pre-reforming bed are disposed within said common vessel such that said fuel feedstock passes through said deoxidizing bed first, then through one of said propane processor bed and said pre-reforming bed, and thereafter through the other of said propane processor bed and said pre-reforming bed.
25. A pre-processing assembly according to claim 24, wherein said deoxidizing bed, said propane processor bed and said pre-reforming bed are disposed within said common vessel such that said fuel feedstock passes through said deoxidizing bed first, then through said propane processor bed, and thereafter through said pre-reforming bed.
26. A pre-processing assembly according to claim 24, wherein said deoxidizing bed comprises a deoxidizing catalyst and said pre-reforming bed comprises a pre-reforming catalyst.
27. A pre-processing assembly according to claim 26, wherein said deoxidizing catalyst is one of Pt—Pd on alumina catalyst, Pt—Rh-based catalyst and Rh—Pd-based alumina catalyst.
28. A pre-processing assembly according to claim 27, wherein said deoxidizing catalyst is G-74D.
29. A pre-processing assembly according to claim 27, wherein said pre-reforming catalyst is a nickel based catalyst.
30. A pre-processing assembly according to claim 29, wherein said pre-reforming catalyst is one of C11-PR, CRG-F, CRG-LH and G-180.
31. A pre-processing assembly according to claim 30, wherein said carbon resistant catalyst is FCR-HC59.
32. A pre-processing assembly according to claim 31, wherein:
- said deoxidizing bed has a volume of 0.7 cubic feet;
- said propane processor bed has a volume of 0.75 cubic feet;
- said pre-reforming bed has a volume of 1.7 cubic feet.
33. A pre-processing assembly according to claim 32, wherein:
- the space velocity of said fuel feedstock in said deoxidizing bed is between 5,000 and 10,000 h−1;
- the space velocity of said fuel feedstock in said propane processor bed is between 1900 and 10,000 h−1; and
- the space velocity of said fuel feedstock in said pre-reforming processor bed is between 2,000 and 5,000 h−1.
34. A pre-processing assembly according to claim 33, wherein the fuel inlet temperature is between 300 and 450° C.
35. A pre-processing assembly according to claim 34, wherein said deoxidizer bed is adapted to operate at a temperature between 300° C. and 600° C., said propane processor bed is adapted to operate at a temperature between 300° C. and 540° C., and said pre-reforming bed is adapted to operate at temperature between 300° C. and 540° C.
36. A pre-processing assembly according to claim 35, wherein the steam to carbon ratio in said fuel feedstock is between 2.9 and 3.4.
37. A pre-processing assembly according to claim 20, wherein said pre-reforming unit is further adapted to remove sulfur-containing compounds from said fuel feedstock.
38. A fuel processing method for processing fuel feedstock for a fuel cell, the fuel feedstock including oxygen and hydrocarbons having higher and lower hydrocarbon content, the fuel processing method comprising the steps of:
- providing said fuel feedstock;
- reducing oxygen in said fuel feedstock using a deoxidizing unit;
- reducing said higher hydrocarbon content in said fuel feedstock using a pre-reforming unit;
- wherein said deoxidizing unit and said pre-reforming unit are disposed within a common vessel such that said fuel feedstock first flows through said deoxidizing unit and thereafter through said pre-reforming unit.
39. A fuel processing method according to claim 38, wherein said deoxidizing unit comprises a deoxidizing bed and said pre-reforming unit comprises a pre-reforming bed, said pre-reforming bed following said deoxidizing bed along the flow path of said fuel feedstock.
40. A fuel processing method according to claim 39, wherein said deoxidizing bed comprises a deoxidizing catalyst and said pre-reforming bed comprises a pre-reforming catalyst.
41. A fuel processing method according to claim 40, wherein said deoxidizing catalyst is one of Pt—Pd on alumina catalyst, Pt—Rh-based catalyst and Rh—Pd-based alumina catalyst, and wherein said pre-reforming catalyst is a nickel-based catalyst.
42. A fuel processing method according to claim 41, wherein said deoxidizing catalyst is G-74D.
43. A fuel processing method according to claim 41, wherein said pre-reforming catalyst is one of C11-PR, CRG-F, CRG-LH and G-180.
44. A fuel processing method according to claim 39, further comprising a step of reducing the propylene in said fuel feedstock using a propane processor unit.
45. A fuel processing method according to claim 34, wherein said propane processor unit is disposed in said common vessel and comprises a propane processing bed.
46. A fuel processing method according to claim 45, wherein said deoxidizer bed, said pre-reforming bed and said propane processing bed are disposed in said common vessel such that said fuel feedstock flows first through said deoxidizing bed, and then through one of said propane processing bed and said pre-reforming bed, and thereafter through the other of said propane processing bed and said pre-reforming bed.
47. A fuel processing method according to claim 46, wherein said propane processing bed comprises a nickel-based carbon resistant catalyst.
48. A fuel processing method according to claim 43, wherein said carbon resistant catalyst is FCR-HC59.
49. A fuel processing method according to claim 38, wherein reducing said oxygen in said deoxidizing bed produces hydrogen, and said lower hydrocarbon content is converted to produce hydrogen in said pre-reforming bed.
50. A fuel processing method according to claim 49, wherein the space velocity of said fuel feedstock in said pre-reforming bed is such that hydrogen back diffusion is developed and maintained in said pre-reforming bed.
51. A fuel processing method according to claim 38, further comprising removing sulfur-containing compounds from said fuel feedstock in said pre-reforming unit.
52. A fuel cell system for use with a fuel feedstock, said fuel feedstock including oxygen and hydrocarbons having higher and lower hydrocarbon content, said fuel cell system comprising:
- pre-processing assembly for processing said fuel feedstock comprising: a deoxidizing unit for reducing the oxygen in said fuel feedstock; a pre-reforming unit for reducing the higher hydrocarbon content in said fuel feedstock; and a common vessel; wherein said deoxidizing unit and said pre-reforming unit are disposed within said common vessel such that said fuel feedstock passes through said deoxidizing unit first and thereafter through said pre-reforming unit; and
- a fuel cell for receiving said fuel feedstock after passage through said pre-processing assembly.
53. A fuel cell system according to claim 52, wherein said pre-processing assembly further comprises a propane processor unit for processing propane and propylene in said fuel, said propane processor unit being disposed in said common reaction vessel.
54. A fuel cell system according to claim 53, wherein said deoxidizing unit comprises a deoxidizing bed, said pre-reforming unit comprises a pre-reforming bed and said propane processor unit comprises a propane processor bed.
55. A fuel cell system according to claim 54, wherein:
- said deoxidizing bed, said propane processor bed and said pre-reforming bed are disposed within a common vessel such that said fuel feedstock passes through said deoxidizing bed first, then through one of said propane processor bed and said pre-reforming bed, and thereafter through the other of said propane processor bed and said pre-reforming bed.
56. A fuel cell system according to claim 55, further comprising:
- a preheater for preheating said fuel feedstock before said fuel feedstock is processed by said pre-processing assembly.
57. A fuel cell system according to claim 56, further comprising:
- a desulfurizer for reducing the sulfur content in said fuel feedstock before said fuel feedstock is processed by said pre-processing assembly.
58. A fuel cell system according to claim 57, wherein said desulfurizer precedes said preheater.
59. A fuel cell system in accordance with claim 56, wherein said preheater heats said fuel feedstock to approximately 375° C.
60. A fuel cell system in accordance with claim 54, wherein:
- said deoxidizer bed comprises one of Pt—Pd on alumina catalyst, Pt—Rh-based catalyst and Rh—Pd-based alumina catalyst;
- said pre-reforming bed comprises a nickel based catalyst; and
- said propane processor bed comprises a nickel-based carbon resistant catalyst.
61. A fuel cell system in accordance with claim 60, wherein said nickel-based carbon resistant catalyst is doped with promoters comprising at least one of cerium oxide, lanthanum oxide, palladium and platinum.
62. A fuel cell system in accordance with claim 61, wherein:
- deoxidizing bed comprises a G-74D catalyst;
- said pre-reforming bed comprises one of C11-PR, CRG-F, CRG-LH and G-180; and
- said propane processor bed comprises FCR-HC59 catalyst.
63. A fuel cell system according to claim 52, wherein said deoxidizing unit in reducing said oxygen produces hydrogen and said pre-reforming unit converts a portion of said lower hydrocarbon content to hydrogen to maintain a reducing environment in said pre-reforming unit.
64. A fuel cell system according to claim 63, wherein the space velocity of the fuel feedstock in said pre-reforming unit is such that hydrogen back diffusion is developed and maintained in said pre-reforming unit.
65. A fuel cell system according to claim 52, wherein said pre-reforming unit is further adapted to remove sulfur-containing compounds from said fuel feedstock.
66. A fuel cell system according to claim 52, wherein said fuel cell is one of a molten carbonate fuel cell and solid oxide fuel cell.
67. A pre-processing assembly according to claim 1, wherein said fuel feedstock is a multi fuel such as natural gas, peak shaving gas, coal bed methane, digester gas, propane, LPG, and HD-5.
68. A pre-processing assembly according to claim 20, wherein said assembly is adapted to process natural gas, HD-5 and LPG hydrocarbon fuel feedstocks to produce methane rich gas for use in a high temperature fuel cell.
Type: Application
Filed: Nov 2, 2004
Publication Date: May 4, 2006
Inventors: Sai Katikaneni (Brookfield, CT), Joseph Daly (Bethel, CT)
Application Number: 10/979,698
International Classification: B01J 8/00 (20060101);