Stabilizer mixtures

Info

Publication number: 20060270764
Type: Application
Filed: Aug 3, 2006
Publication Date: Nov 30, 2006
Inventor: Francois Gugumus (Allschwil)
Application Number: 11/498,351

Abstract

A stabilizer mixture containing the components (A) and (B) wherein component (A) is for example a compound of the formula (A-1) wherein A1 is hydrogen or C1-C4alkyl, A2 is a direct bond or C1-C10alkylene, and n1 is a number from 2 to 50; and component (B) is formed by two different low molecular weight sterically hindered amine compounds containing a group of the formula (I) or (II); with the proviso that components (A) and (B) are different.

Description

Description

This application is a continuation of copending application Ser. No. 11/052,714, filed Jan. 19, 2005, herein incorporated by reference, which is a continuation of parent application Ser. No. 10/276,120, filed Nov. 11, 2002 now abandoned.

The present invention relates to a stabilizer mixture containing a specific sterically hindered amine ester or amide, and two different low molecular weight sterically hindered amines.

Stabilizer mixtures containing blends of sterically hindered amines are for example described in U.S. Pat. No. 4,692,468, U.S. Pat. No. 4,863,981, U.S. Pat. No. 5,719,217, U.S. Pat. No. 5,919,399, U.S. Pat. No. 5,965,643, U.S. Pat. No. 5,980,783, U.S. Pat. No. 6,015,849 and U.S. Pat. No. 6,020,406.

The present invention relates to a stabilizer mixture containing the components (A) and (B) wherein

component (A) is

a compound of the formula (A-1)
wherein
A₁is hydrogen or C₁-C₄alkyl,
A₂is a direct bond or C₁-C₁₀alkylene, and
n₁is a number from 2 to 50;
at least one compound of the formulae (A-2-a) and (A-2-b)
wherein
n₂and n₂* are a number from 2 to 50;
a compound of the formula (A-3)
wherein
A₃and A₄independently of one another are hydrogen or C₁-C₈alkyl, or A₃and A₄together form a C₂-C₀₄alkylene group, and
the variables n₃independently of one another are a number from 1 to 50; or
a compound of the formula (A-4)
wherein
n₄is a number from 2 to 50,
A₅is hydrogen or C₁-C₄alkyl,
the radicals A₆and A₇independently of one another are C₁-C₄alkyl or a group of the formula (a-I)
wherein A₈is hydrogen, C₁-C₈alkyl, O⁻, —OH, —CH₂CN, C₁-C₁₈alkoxy, C₅-C₁₂cycloalkoxy,
C₃-C₆alkenyl, C₇-C₉phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C₁-C₄alkyl; or C₁-C₈acyl,
with the proviso that at least 50% of the radicals A₇are a group of the formula (a-I); and component (B) is formed by two different low molecular weight sterically hindered amine compounds containing a group of the formula (I) or (II);
with the proviso that components (A) and (B) are different.

Preferably the compounds of component (B) have a molecular weight up to 1,000 g/mol, for example 155 to 800 g/mol or 155 to 1,000 g/mol or 300 to 800 g/mol or 300 to 1,000 g/mol.

The two different compounds of component (B) are preferably selected from the group consisting of the following classes
β-1) a compound of the formula (B-1)
in which
E₁is hydrogen, C₁-C₈alkyl, O⁻, —OH, —CH₂CN, C₁-C₁₈alkoxy, C₅-C₁₂cycloalkoxy, C₃-C₆alkenyl, C₇-C₉phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C₁-C₄alkyl; or C₁-C₈acyl,
m₁is 1, 2 or 4,
if m₁is 1, E₂is C₁-C₂₅alkyl,
if m₁is 2, E₂is C₁-C₁₄alkylene or a group of the formula (b-I)
wherein E₃is C₁-C₁₀alkyl or C₂-C₁₀alkenyl, E₄is C₁-C₁₀alkylene, and
E₅and E₆independently of one another are C₁-C₄alkyl, cyclohexyl or methylcyclohexyl, and
if m₁is 4, E₂is C₄-C₁₀alkanetetrayl;
β-2) a compound of the formula (B-2)
in which
two of the radicals E₇are —COO—(C₁-C₂₀alkyl), and
two of the radicals E₇are a group of the formula (b-II)
with E₈having one of the meanings of E₁;
β-3) a compound of the formula (B-3)
in which
E₉and E₁₀together form C₂-C₁₄alkylene,
E₁₁is hydrogen or a group -Z₁-COO-Z₂,
Z₁is C₂-C₁₄alkylene, and
Z₂is C₁-C₂₄alkyl, and
E₁₂has one of the meanings of E₁;
β-4) a compound of the formula (B-4)
wherein
the radicals E₁₃independently of one another have one of the meanings of E₁,
the radicals E₁₄independently of one another are hydrogen or C₁-C₁₂alkyl, and
E₁₅is C₁-C₁₀alkylene or C₃-C₁₀alkylidene;
β-5) a compound of the formula (B-5)
wherein
the radicals E₁₆independently of one another have one of the meanings of E₁;
β-6) a compound of the formula (B-6)
in which
E₁₇is C₁-C₂₄alkyl, and
E₁₈has one of the meanings of E₁;
β-7) a compound of the formula (B-7)
in which
E₁₉, E₂₀and E₂₁independently of one another are a group of the formula (b-III)
wherein E₂₂has one of the meanings of E₁;
β-8) a compound of the formula (B-8)
wherein
the radicals E₂₃independently of one another have one of the meanings of E₁, and E₂₄is hydrogen, C₁-C₁₂alkyl or C₁-C₁₂alkoxy;
β-9) a compound of the formula (B-9)
wherein
m₂is 1, 2 or 3,
E₂₅has one of the meanings of E₁, and
when m₂is 1, E₂₆is a group
when m₂is 2, E₂₆is C₂-C₂₂alkylene, and
when m₂is 3, E₂₆is a group of the formula (b-IV)
wherein the radicals E₂₇independently of one another are C₂-C₁₂alkylene, and the radicals E₂₈independently of one another are C₁-C₁₂alkyl or C₅-C₁₂cycloalkyl;
β-10) a compound of the formula (B-10)
wherein
the radicals E₂₉independently of one another have one of the meanings of E₁, and
E₃₀is C₂-C₂₂alkylene, C₅-C₇cycloalkylene, C₁-C₄alkylenedi(C₅-C₇cycloalkylene), phenylene or phenylenedi(C₁-C₄alkylene); or
β-11) a compound of the formula (B-11)
in which
E₃₁is C₁-C₁₀alkyl, C₅-C₁₂cycloalkyl, C₁-C₄alkyl-substituted C₅-C₁₂cycloalkyl, phenyl or
C₁-C₁₀alkyl-substituted phenyl,
E₃₂is C₃-C₁₀alkylene,
E₃₃has one of the meanings of E₁, and
m₃is a number from 2 to 6.

One of the preferred embodiments of this invention relates to stabilizer mixtures wherein the two compounds of component (B) are selected from different classes.

Examples of component (B) are:

- A compound selected from the class β-1 and a compound selected from the class β-3, β-4, β-5, β-6, β-7, β-8, β-9, β-10 or β-11, preferably the class β-3, β-5, β-6, β-10 or β-11.
- A compound selected from the class β-3 and a compound selected from the class β-4, β-5, β-6, β-7, β-9, β-10 or β-11, preferably β-5, β-6, β-10 or β-11.
- A compound selected from the class β-5 and a compound selected from the class β-6, β-7, β-8, β-9, β-10 or β-11, preferably β-6, β-10 or β-11.
- A compound selected from the class β-6 and a compound selected from the class β-10 or β-11.
- A compound selected from the class β-7 and a compound selected from the class β-8, β-10 or β-11.
- A compound selected from the class β-9 and a compound selected from the class β-10 or β-11.
- A compound selected from the class β-10 and a compound selected from the class β-11.

Examples of alkyl having up to 25 carbon atoms are methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, 2-ethylbutyl, n-pentyl, isopentyl, 1-methylpentyl, 1,3-dimethylbutyl, n-hexyl, 1-methylhexyl, n-heptyl, isoheptyl, 1,1,3,3-tetramethylbutyl, 1-methylheptyl, 3-methylheptyl, n-octyl, 2-ethylhexyl, 1,1,3-trimethylhexyl, 1,1,3,3-tetramethylpentyl, nonyl, decyl, undecyl, 1-methylundecyl, dodecyl, 1,1,3,3,5,5-hexamethylhexyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, eicosyl and docosyl. One of the preferred definitions of A₈, E₁, E₈, E₁₂, E₁₃, E₁₆, E₁₈, E₂₂, E₂₃, E₂₅, E₂₉and E₃₃is C₁-C₄alkyl, especially methyl.

Examples of alkoxy having up to 18 carbon atoms are methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, pentoxy, isopentoxy, hexoxy, heptoxy, octoxy, decyloxy, dodecyloxy, tetradecyloxy, hexadecyloxy and octadecyloxy. One of the preferred meanings of E₁is octoxy. E₂₄is preferably C₁-C₄alkoxy.

Examples of C₅-C₁₂cycloalkyl are cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl and cyclododecyl. C₅-C₈Cycloalkyl, especially cyclohexyl, is preferred.

C₁-C₄Alkyl-substituted C₅-C₁₂cycloalkyl is for example methylcyclohexyl or dimethylcyclohexyl.

Examples of C₅-C₁₂cycloalkoxy are cyclopentoxy, cyclohexoxy, cycloheptoxy, cyclooctoxy, cyclodecyloxy and cyclododecyloxy. C₅-C₈Cycloalkoxy, in particular cyclopentoxy and cyclohexoxy, is preferred.

C₁-C₁₀Alkyl-substituted phenyl is for example methylphenyl, dimethylphenyl, trimethylphenyl or tert-butylphenyl.

Examples of C₇-C₉phenylalkyl are benzyl and phenylethyl.

C₇-C₉Phenylalkyl which is substituted on the phenyl radical by 1, 2 or 3 C₁-C₄alkyl is for example methylbenzyl, dimethylbenzyl, trimethylbenzyl or tert-butylbenzyl.

Examples of alkenyl having up to 10 carbon atoms are allyl, 2-methallyl, butenyl, pentenyl and hexenyl. Allyl is preferred. The carbon atom in position 1 is preferably saturated.

Examples of acyl containing not more than 8 carbon atoms are formyl, acetyl, propionyl, butyryl, pentanoyl, hexanoyl, heptanoyl, octanoyl, acryloyl, methacryloyl and benzoyl. C₁-C₈Alkanoyl, C₃-C₈alkenyl and benzoyl are preferred. Acetyl and acryloyl are especially preferred.

Examples of alkylene having up to 22 carbon atoms are methylene, ethylene, propylene, trimethylene, tetramethylene, pentamethylene, 2,2-dimethyltrimethylene, hexamethylene, trimethylhexamethylene, octamethylene and decamethylene.

An example of C₃-C₁₀alkylidene is the group

An example of C₄-C₁₀alkanetetrayl is 1,2,3,4-butanetetrayl.

An example of C₅-C₇cycloalkylene is cyclohexylene.

An example of C₁-C₄alkylenedi(C₅-C₇cycloalkylene) is methylenedicyclohexylene.

An example of phenylenedi(C₁-C₄alkylene) is methylene-phenylene-methylene or ethylene-phenylene-ethylene.

n₁, n₂, n₂* and n₄are preferably a number from 2 to 25, in particular 2 to 20.

n₃is preferably a number from 1 to 25, in particular 1 to 20.

m₃is preferably a number from 2 to 6 or 2 to 5, in particular 2 to 4.

The compounds described above as components (A) and (B) are essentially known and commercially available. All of them can be prepared by known processes.

The preparation of the compounds of component (A) is disclosed for example in U.S. Pat. No. 4,233,412, U.S. Pat. No. 4,340,534, WO-A-98/51,690 and EP-A-1,803.

The preparation of the compounds of component (B) is disclosed for example in U.S. Pat. No. 5,679,733, U.S. Pat. No. 3,640,928, U.S. Pat. No. 4,198,334, U.S. Pat. No. 5,204,473, U.S. Pat. No. 4,619,958, U.S. Pat. No. 4,110,306, U.S. Pat. No. 4,110,334, U.S. Pat. No. 4,689,416, U.S. Pat. No. 4,408,051, SU-A-768,175 (Derwent 88-138,751/20), U.S. Pat. No. 5,049,604, U.S. Pat. No. 4,769,457, U.S. Pat. No. 4,356,307, U.S. Pat. No. 4,619,956, U.S. Pat. No. 5,182,390, GB-A-2,269,819, U.S. Pat. No. 4,292,240, U.S. Pat. No. 5,026,849, U.S. Pat. No. 5,071,981, U.S. Pat. No. 4,547,538, U.S. Pat. No. 4,976,889 and U.S. Pat. No. 5,051,458.

Component (A) is preferably TINUVIN 622 (RTM), HOSTAVIN N 30 (RTM) or FERRO AM 806 (RTM).

The compounds of component (B) are preferably selected from the group consisting of DASTIB 845 (RTM), TINUVIN 770 (RTM), TINUVIN 765 (RTM), TINUVIN 144 (RTM), TINUVIN 123 (RTM), ADK STAB LA 52 (RTM), ADK STAB LA 57 (RTM), ADK STAB LA 62 (RTM), ADK STAB LA 67 (RTM), HOSTAVIN N 20 (RTM), HOSTAVIN N 24 (RTM), SANDUVOR 3050 (RTM), DIACETAM 5 (RTM), SUMISORB TM 61 (RTM), UVINUL 4049 (RTM), SANDUVOR PR 31(RTM), GOODRITE UV 3034 (RTM), GOODRITE UV 3150 (RTM), GOODRITE UV 3159 (RTM), GOODRITE 3110×128 (RTM), UVINUL 4050H (RTM), UVASIL 299 LM (RTM) and UVASIL 2000 LM (RTM).

The meanings of the terminal groups which saturate the free valences in the compounds of the formulae (A-1), (A-2-a), (A-2-b), (A₄) and (B-11) depend on the processes used for their preparation. The terminal groups can also be modified after the preparation of the compounds.

If the compounds of the formula (A-1) are prepared, for example, by reacting a compound of the formula
in which A₁is hydrogen or methyl, with a dicarboxylic acid diester of the formula Y—OOC-A₂-COO—Y, in which Y is, for example, methyl, ethyl or propyl, and A₂is as defined above, the terminal group bonded to the 2,2,6,6-tetramethyl-4-oxypiperidin-1-yl radical is hydrogen or —CO-A₂-COO—Y, and the terminal group bonded to the diacyl radical is —O—Y or

In the compounds of the formula (A-2-a), the terminal group bonded to the nitrogen can be, for example, hydrogen and the terminal group bonded to the 2-hydroxypropylene radical can be, for example, a
group.

In the compounds of the formula (A-2-b), the terminal group bonded to the dimethylene radical can be, for example, —OH, and the terminal group bonded to the oxygen can be, for example, hydrogen. The terminal groups can also be polyether radicals.

In the compounds of the formula (A-4), the end group bonded to the —CH₂— residue can be, for example, hydrogen and the end group bonded to the —CH(CO₂A₇) residue can be, for example, —CH═CH—COOA₇.

In the compounds of the formula (B-11), the terminal group bonded to the silicon atom can be, for example, (E₃₁)₃Si—O—, and the terminal group bonded to the oxygen can be, for example, —Si(E₃₁)₃.

The compounds of the formula (B-11) can also be in the form of cyclic compounds if m₃is a number from 3 to 6, i.e. the free valences shown in the structural formula then form a direct bond.

A₈is preferably hydrogen, C₁-C₄alkyl, C₁-C₁₀alkoxy, cyclohexyloxy, allyl, benzyl or acetyl. E₁, E₈, E₁₂, E₁₃, E₁₆, E₁₈, E₂₂, E₂₃, E₂₅, E₂₉and E₃₃are preferably hydrogen, C₁-C₄alkyl, C₁-C₁₀alkoxy, cyclohexyloxy, allyl, benzyl or acetyl.

A₈, E₁, E₈, E₁₂, E₁₃, E₁₆, E₁₈, E₂₂, E₂₃, E₂₅, E₂₉and E₃₃are in particular hydrogen or methyl and E₁additionally is C₁-C₈alkoxy.

According to a preferred embodiment

A₁is hydrogen or methyl,

A₂is a direct bond or C₂-C₆alkylene, and

n₁is a number from 2 to 25;

n₂and n₂* are a number from 2 to 25;

A₃and A₄independently of one another are hydrogen or C₁-C₄alkyl, or A₃and A₄together form a C₉-C₁₃alkylene group, and

the variables n₃independently of one another are a number from 1 to 25;

n₄is a number from 2 to 25,

A₅and A₆independently of one another are C₁-C₄alkyl, and

A₇is C₁-C₄alkyl or a group of the formula (a-I)

with the proviso that at least 50% of the radicals A₇are a group of the formula (a-I).

According to a further preferred embodiment

m₁is 1, 2 or 4,

if m₁is 1, E₂is C₁₂-C₂₀alkyl,

if m₁is 2, E₂is C₂-C₁₀alkylene or a group of the formula (b-I)

E₃is C₁-C₄alkyl,

E₄is C₁-C₆alkylene, and

E₅and E₆independently of one another are C₁-C₄alkyl, and

if m₁is 4, E₂is C₄-C₈alkanetetrayl;

two of the radicals E₇are —COO—(C₁₀-C₁₅alkyl), and

two of the radicals E₇are a group of the formula (b-II);

E₉and E₁₀together form C₉-C₁₃alkylene,

E₁₁is hydrogen or a group -Z₁-COO-Z₂,

Z₁is C₂-C₆alkylene, and

Z₂is C₁₀-C₁₆alkyl;

E₁₄is hydrogen, and

E₁₅is C₂-C₆alkylene or C₃-C₅alkylidene;

E₁₇is C₁₀-C₁₄alkyl;

E₂₄is C₁-C₄alkoxy;

m₂is 1, 2 or 3,

when m₂is 1, E₂₆is a group
when m₂is 2, E₂₆is C₂-C₆alkylene, and
when m₂is 3, E₂₆is a group of the formula (b-IV)
the radicals E₂₇independently of one another are C₂-C₆alkylene, and
the radicals E₂₈independently of one another are C₁-C₄alkyl or C₅-C₈cycloalkyl;
E₃₀is C₂-C₈alkylene; and
E₃₁is C₁-C₄alkyl,
E₃₂is C₃-C₆alkylene, and
m₃is a number from 2 to 6.

A particularly preferred embodiment of this invention relates to a stabilizer mixture wherein component (A) is a compound of the formula (A-1-a), (A-2-a), (A-2-b), (A-3-a) or (A-4-a);
wherein n₁is a number from 2 to 20;
wherein n₂and n₂* are a number from 2 to 20;
wherein the variables n₃independently of one another are a number from 1 to 20;
wherein n₄is a number from 2 to 20, and at least 50% of the radicals A₇are a group of the formula (a-I)
wherein A₈is hydrogen, C₁-C₈alkyl, O⁻, —OH, —CH₂CN, C₁-C₁₈alkoxy, C₅-C₁₂cycloalkoxy, C₃-C₆alkenyl, C₇-C₉phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C₁-C₄alkyl; or C₁-C₈acyl,
and the remaining radicals A₇are ethyl; and
component (B) is formed by two different compounds selected from the group consisting of compounds of the formulae (B-1-a), (B-1-b), (B-1-c), (B-1-d), (B-2-a), (B-3-a), (B-3-b), (B-4-a), (B-4-b), (B-5), (B-6-a), (B-7), (B-8-a), (B-9-a), (B-9-b), (B-9-c), (B-10-a) and (B-11-a);
wherein E₁is hydrogen, C₁-C₈alkyl, O⁻, —OH, —CH₂CN, C₁-C₁₈alkoxy, C₅-C₁₂cycloalkoxy, C₃-C₆alkenyl, C₇-C₉phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C₁-C₄alkyl; or C₁-C₈acyl;
in which two of the radicals E₇are —COO—C₁₃H₂₇and
two of the radicals E₇are
and E₈has one of the meanings
of E₁;
wherein E₁₂has one of the meanings of E₁;
wherein E₁₃has one of the meanings of E₁;
wherein E₁₆has one of the meanings of E₁;
wherein E₁₈has one of the meanings of E₁;
in which E₁₉, E₂₀and E₂₁independently of one another are a group of the formula (b-III)
wherein E₂₂has one of the meanings of E₁;
wherein E₂₃has one of the meanings of E₁;
wherein E₂₅has one of the meanings of E₁;
wherein En has one of the meanings of E₁;
wherein m₃is a number from 2 to 6 and E₃₃has one of the meanings of E₁.

A particularly preferred embodiment of this invention also relates to a stabilizer mixture wherein one of the two different compounds forming component (B) is a compound of the formula (B-1-b) with E₁being hydrogen.

Another preferred embodiment of this invention relates to a stabilizer mixture wherein component (A) is a compound of the formula (A-1-a) with n, being a number from 2 to 20 or a compound of the formula (A-2-a) or (A-2-b) wherein n₂and n₂* are a number from 2 to 20; and

one of the two different compounds forming component (B) is a compound of the formula (B-1-b) with E₁being hydrogen.

A further particularly preferred embodiment of this invention is a stabilizer mixture wherein component (A) is a compound of the formula (A-1-a) with n, being a number from 2 to 20 or a compound of the formula (A-2-a) or (A-2-b) wherein n₂and n₂* are a number from 2 to 20;

one of the two different compounds forming component (B) is a compound of the formula (B-1-b) with E₁being hydrogen; and

the other of the two different compounds forming component (B) is a compound of the formula (B-1-a) with E₁being hydrogen, (B-1-b) with E₁being methyl, (B-1-d) with E₁being hydrogen or methyl, (B-3-a) with E₁₂being hydrogen, (B-3-b) with E₁₂being hydrogen, (B-4-b) with E₁₃being hydrogen, (B-5) with E₁₆being hydrogen, (B-6-a) with E₁₈being hydrogen or methyl, (B-8-a) with E₂₃being methyl, (B-9-c) with E₂₅being hydrogen or methyl, (B-10-a) with E₂₉being hydrogen, or (B-11-a) with E₃₃being hydrogen.

Examples of stabilizer mixtures according to the present invention are the following combinations of commercial products:

1. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+TINUVIN 765 (RTM)
2. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+TINUVIN 144 (RTM)
3. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+TINUVIN 123 (RTM)
4. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen
5. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+HOSTAVIN N 24 (RTM)
6. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+DIACETAM 5 (RTM)
7. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+ADK STAB LA 52 (RTM)
8. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+ADK STAB LA 57 (RTM)
9. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+ADK STAB LA 62 (RTM)
10. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+ADK STAB LA 67 (RTM)
11. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+GOODRITE UV 3034 (RTM)
12. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+GOODRITE UV 3150 (RTM)
13. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+GOODRITE UV 3159 (RTM)
14. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
15. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+UVINUL 4049 (RTM)
16. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
17. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
18. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+SUMISORB TM 61 (RTM)
19. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+SANDUVOR 3050 (RTM)
20. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+SANDUVOR PR-31 (RTM)
21. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+UVASIL 299 LM (RTM)
22. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+UVASIL 2000 LM (RTM)
23. TiNUVIN 622 (RTM)+TINUVIN 770 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
24. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
25. TINUVIN 622 (RTM)+TINUVIN 770 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
26. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+TINUVIN 144 (RTM)
27. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+TINUVIN 123 (RTM)
28. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen
29. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+HOSTAVIN N 24 (RTM)
30. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+DIACETAM 5 (RTM)
31. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+ADK STAB LA 52 (RTM)
32. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+ADK STAB LA 57 (RTM)
33. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+ADK STAB LA 62 (RTM)
34. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+ADK STAB LA 67 (RTM)
35. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+GOODRITE UV 3034 (RTM)
36. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+GOODRITE UV 3150 (RTM)
37. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+GOODRITE UV 3159 (RTM)
38. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
39. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+UVINUL 4049 (RTM)
40. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
41. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
42. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+SUMISORB TM 61 (RTM)
43. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+SANDUVOR 3050 (RTM)
44. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+SANDUVOR PR-31 (RTM)
45. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+UVASIL 299 LM (RTM)
46. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+UVASIL 2000 LM (RTM)
47. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
48. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
49. TINUVIN 622 (RTM)+TINUVIN 765 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
50. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+TINUVIN 123 (RTM)
51. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen
52. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+HOSTAVIN N 24 (RTM)
53. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+DIACETAM 5 (RTM)
54. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+ADK STAB LA 52 (RTM)
55. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+ADK STAB LA 57 (RTM)
56. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+ADK STAB LA 62 (RTM)
57. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+ADK STAB LA 67 (RTM)
58. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+GOODRITE UV 3034 (RTM)
59. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+GOODRITE UV 3150 (RTM)
60. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+GOODRITE UV 3159 (RTM)
61. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
62. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+UVINUL 4049 (RTM)
63. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
64. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
65. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+SUMISORB TM 61 (RTM)
66. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+SANDUVOR 3050 (RTM)
67. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+SANDUVOR PR-31 (RTM)
68. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+UVASIL 299 LM (RTM)
69. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+UVASIL 2000 LM (RTM)
70. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
71. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
72. TINUVIN 622 (RTM)+TINUVIN 144 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
73. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen
74. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+HOSTAVIN N 24 (RTM)
75. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+DIACETAM 5 (RTM)
76. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+ADK STAB LA 52 (RTM)
77. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+ADK STAB LA 57 (RTM)
78. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+ADK STAB LA 62 (RTM)
79. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+ADK STAB LA 67 (RTM)
80. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+GOODRITE UV 3034 (RTM)
81. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+GOODRITE UV 3150 (RTM) 482. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+GOODRITE UV 3159 (RTM)
83. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
84. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+UVINUL 4049 (RTM)
85. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
86. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
87. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+SUMISORB TM 61 (RTM)
88. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+SANDUVOR 3050 (RTM)
89. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+SANDUVOR PR-31 (RTM)
90. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+UVASIL 299 LM (RTM) 491. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+UVASIL 2000 LM (RTM)
92. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
93. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
94. TINUVIN 622 (RTM)+TINUVIN 123 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
95. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+HOSTAVIN N 24 (RTM)
96. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+DIACETAM 5 (RTM)
97. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+ADK STAB LA 52 (RTM)
98. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+ADK STAB LA 57 (RTM)
99. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+ADK STAB LA 62 (RTM)
100. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+ADK STAB LA 67 (RTM)
101. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+GOODRITE UV 3034 (RTM)
102. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+GOODRITE UV 3150 (RTM)
103. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+GOODRITE UV 3159 (RTM)
104. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+compound of the formula (B-9-a) wherein E₂₅is hydrogen
105. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+UVINUL 4049 (RTM)
106. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+compound of the formula (B-10-a) wherein E₂₉is hydrogen
107. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+compound of the formula (B-1-a) wherein E₁is hydrogen
108. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+SUMISORB TM 61 (RTM)
109. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+SANDUVOR 3050 (RTM)
110. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+SANDUVOR PR-31 (RTM)
111. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+UVASIL 299 LM (RTM)
112. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+UVASIL 2000 LM (RTM)
113. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+compound of the formula (B-6-a) wherein E₁₈is hydrogen
114. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+compound of the formula (B-6-a) wherein E₁₈is methyl
115. TINUVIN 622 (RTM)+compound of the formula (B-3-a) wherein E₁₂is hydrogen+compound of the formula (B-7) with E₁₉, E₂₀and E₂₁being a group of the formula (b-III) wherein E₂₂is hydrogen.
116. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+DIACETAM 5 (RTM)
117. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+ADK STAB LA 52 (RTM)
118. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+ADK STAB LA 57 (RTM)
119. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+ADK STAB LA 62 (RTM)
120. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+ADK STAB LA 67 (RTM)
121. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+GOODRITE UV 3034 (RTM)
122. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+GOODRITE UV 3150 (RTM)
123. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+GOODRITE UV 3159 (RTM)
124. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
125. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+UVINUL 4049 (RTM)
126. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
127. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
128. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+SUMISORB TM 61 (RTM)
129. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+SANDUVOR 3050 (RTM)
130. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+SANDUVOR PR-31 (RTM)
131. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+UVASIL 299 LM (RTM)
132. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+UVASIL 2000 LM (RTM)
133. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
134. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
135. TINUVIN 622 (RTM)+HOSTAVIN N 24 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
136. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+ADK STAB LA 52 (RTM)
137. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+ADK STAB LA 57 (RTM)
138. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+ADK STAB LA 62 (RTM)
139. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+ADK STAB LA 67 (RTM)
140. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+GOODRITE UV 3034 (RTM)
141. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+GOODRITE UV 3150 (RTM)
142. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+GOODRITE UV 3159 (RTM)
143. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
144. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+UVINUL 4049 (RTM)
145. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
146. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
147. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+SUMISORB TM 61 (RTM)
148. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+SANDUVOR 3050 (RTM)
149. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+SANDUVOR PR-31 (RTM)
150. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+UVASIL 299 LM (RTM)
151. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+UVASIL 2000 LM (RTM)
152. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
153. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
154. TINUVIN 622 (RTM)+DIACETAM 5 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
155. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+ADK STAB LA 57 (RTM)
156. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+ADK STAB LA 62 (RTM)
157. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+ADK STAB LA 67 (RTM)
158. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+GOODRITE UV 3034 (RTM)
159. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+GOODRITE UV 3150 (RTM)
160. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+GOODRITE UV 3159 (RTM)
161. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
162. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+UVINUL 4049 (RTM)
163. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
164. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
165. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+SUMISORB TM 61 (RTM)
166. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+SANDUVOR 3050 (RTM)
167. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+SANDUVOR PR-31 (RTM)
168. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+UVASIL 299 LM (RTM)
169. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+UVASIL 2000 LM (RTM)
170. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
171. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
172. TINUVIN 622 (RTM)+ADK STAB LA 52 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
173. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+ADK STAB LA 62 (RTM)
174. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+ADK STAB LA 67 (RTM)
175. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+GOODRITE UV 3034 (RTM)
176. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+GOODRITE UV 3150 (RTM)
177. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+GOODRITE UV 3159 (RTM)
178. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
179. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+UVINUL 4049 (RTM)
180. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
181. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
182. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+SUMISORB TM 61 (RTM)
183. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+SANDUVOR 3050 (RTM)
184. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+SANDUVOR PR-31 (RTM)
185. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+UVASIL 299 LM (RTM)
186. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+UVASIL 2000 LM (RTM)
187. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
188. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
189. TINUVIN 622 (RTM)+ADK STAB LA 57 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
190. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+ADK STAB LA 67 (RTM)
191. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+GOODRITE UV 3034 (RTM)
192. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+GOODRITE UV 3150 (RTM)
193. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+GOODRITE UV 3159 (RTM)
194. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
195. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+UVINUL 4049 (RTM)
196. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
197. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
198. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+SUMISORB TM 61 (RTM)
199. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+SANDUVOR 3050 (RTM)
200. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+SANDUVOR PR-31 (RTM)
201. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+UVASIL 299 LM (RTM)
202. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+UVASIL 2000 LM (RTM)
203. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
204. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+compound of the formula (B-6-a) wherein E₈is methyl
205. TINUVIN 622 (RTM)+ADK STAB LA 62 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
206. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+GOODRITE UV 3034 (RTM)
207. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+GOODRITE UV 3150 (RTM)
208. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+GOODRITE UV 3159 (RTM)
209. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
210. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+UVINUL 4049 (RTM)
211. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
212. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
213. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+SUMISORB TM 61 (RTM)
214. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+SANDUVOR 3050 (RTM)
215. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+SANDUVOR PR-31 (RTM)
216. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+UVASIL 299 LM (RTM)
217. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+UVASIL 2000 LM (RTM)
218. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
219. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
220. TINUVIN 622 (RTM)+ADK STAB LA 67 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂₁being a group of the formula (b-III) wherein E₂₂is hydrogen.
221. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+GOODRITE UV 3150 (RTM)
222. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+GOODRITE UV 3159 (RTM)
223. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
224. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+UVINUL 4049 (RTM)
225. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
226. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
227. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+SUMISORB TM 61 (RTM)
228. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+SANDUVOR 3050 (RTM)
229. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+SANDUVOR PR-31 (RTM)
230. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+UVASIL 299 LM (RTM)
231. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+UVASIL 2000 LM (RTM)
232. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
233. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
234. TINUVIN 622 (RTM)+GOODRITE UV 3034 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂₁being a group of the formula (b-III) wherein E₂₂is hydrogen.
235. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+GOODRITE UV 3159 (RTM)
236. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
237. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+UVINUL 4049 (RTM)
238. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
239. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
240. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+SUMISORB TM 61 (RTM)
241. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+SANDUVOR 3050 (RTM)
242. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+SANDUVOR PR-31 (RTM)
243. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+UVASIL 299 LM (RTM)
244. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+UVASIL 2000 LM (RTM)
245. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
246. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
247. TINUVIN 622 (RTM)+GOODRITE UV 3150 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
248. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen
249. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+UVINUL 4049 (RTM)
250. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
251. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
252. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+SUMISORB TM 61 (RTM)
253. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+SANDUVOR 3050 (RTM)
254. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+SANDUVOR PR-31 (RTM)
255. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+UVASIL 299 LM (RTM)
256. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+UVASIL 2000 LM (RTM)
257. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
258. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
259. TINUVIN 622 (RTM)+GOODRITE UV 3159 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
260. TINUVIN 622 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen+UVINUL 4049 (RTM)
261. TINUVIN 622 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen+compound of the formula (B-10-a) wherein E₂₉is hydrogen
262. TINUVIN 622 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen+compound of the formula (B-1-a) wherein E₁is hydrogen
263. TINUVIN 622 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen+SUMISORB TM 61 (RTM)
264. TINUVIN 622 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen+SANDUVOR 3050 (RTM)
265. TINUVIN 622 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen+SANDUVOR PR-31 (RTM)
266. TINUVIN 622 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen+UVASIL 299 LM (RTM)
267. TINUVIN 622 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen+UVASIL 2000 LM (RTM)
268. TINUVIN 622 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen+compound of the formula (B-6-a) wherein E₁₈is hydrogen
269. TINUVIN 622 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen+compound of the formula (B-6-a) wherein E₁₈is methyl
270. TINUVIN 622 (RTM)+compound of the formula (B-9-a) wherein E₂₅is hydrogen+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
271. TINUVIN 622 (RTM)+UVINUL 4049 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen
272. TINUVIN 622 (RTM)+UVINUL 4049 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen
273. TINUVIN 622 (RTM)+UVINUL 4049 (RTM)+SUMISORB TM 61 (RTM)
274. TINUVIN 622 (RTM)+UVINUL 4049 (RTM)+SANDUVOR 3050 (RTM)
275. TINUVIN 622 (RTM)+UVINUL 4049 (RTM)+SANDUVOR PR-31 (RTM)
276. TINUVIN 622 (RTM)+UVINUL 4049 (RTM)+UVASIL 299 LM (RTM)
277. TINUVIN 622 (RTM)+UVINUL 4049 (RTM)+UVASIL 2000 LM (RTM)
278. TINUVIN 622 (RTM)+UVINUL 4049 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
279. TINUVIN 622 (RTM)+UVINUL 4049 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
280. TINUVIN 622 (RTM)+UVINUL 4049 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
281. TINUVIN 622 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen+compound of the formula (B-1-a) wherein E₁is hydrogen
282. TINUVIN 622 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen+SUMISORB TM 61 (RTM)
283. TINUVIN 622 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen+SANDUVOR 3050 (RTM)
284. TINUVIN 622 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen+SANDUVOR PR-31 (RTM)
285. TINUVIN 622 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen+UVASIL 299 LM (RTM)
286. TINUVIN 622 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen+UVASIL 2000 LM (RTM)
287. TINUVIN 622 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen+compound of the formula (B-6-a) wherein E₁₈is hydrogen
288. TINUVIN 622 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen+compound of the formula (B-6-a) wherein E₁₈is methyl
289. TINUVIN 622 (RTM)+compound of the formula (B-10-a) wherein E₂₉is hydrogen+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
290. TINUVIN 622 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen+SUMISORB TM 61 (RTM)
291. TINUVIN 622 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen+SANDUVOR 3050 (RTM)
292. TINUVIN 622 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen+SANDUVOR PR-31 (RTM)
293. TINUVIN 622 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen+UVASIL 299 LM (RTM)
294. TINUVIN 622 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen+UVASIL 2000 LM (RTM)
295. TINUVIN 622 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen+compound of the formula (B-6-a) wherein E₁₈is hydrogen
296. TINUVIN 622 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen+compound of the formula (B-6-a) wherein E₁₈is methyl
297. TINUVIN 622 (RTM)+compound of the formula (B-1-a) wherein E₁is hydrogen+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
298. TINUVIN 622 (RTM)+SUMISORB TM 61 (RTM)+SANDUVOR 3050 (RTM)
299. TINUVIN 622 (RTM)+SUMISORB TM 61 (RTM)+SANDUVOR PR-31 (RTM)
300. TINUVIN 622 (RTM)+SUMISORB TM 61 (RTM)+UVASIL 299 LM (RTM)
301. TINUVIN 622 (RTM)+SUMISORB TM 61 (RTM)+UVASIL 2000 LM (RTM)
302. TINUVIN 622 (RTM)+SUMISORB TM 61 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
303. TINUVIN 622 (RTM)+SUMISORB TM 61 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
304. TINUVIN 622 (RTM)+SUMISORB TM 61 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
305. TINUVIN 622 (RTM)+SANDUVOR 3050 (RTM)+SANDUVOR PR-31 (RTM)
306. TINUVIN 622 (RTM)+SANDUVOR 3050 (RTM)+UVASIL 299 LM (RTM)
307. TINUVIN 622 (RTM)+SANDUVOR 3050 (RTM)+UVASIL 2000 LM (RTM)
308. TINUVIN 622 (RTM)+SANDUVOR 3050 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
309. TINUVIN 622 (RTM)+SANDUVOR 3050 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
310. TINUVIN 622 (RTM)+SANDUVOR 3050 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
311. TINUVIN 622 (RTM)+SANDUVOR PR-31 (RTM)+UVASIL 299 LM (RTM)
312. TINUVIN 622 (RTM)+SANDUVOR PR-31 (RTM)+UVASIL 2000 LM (RTM)
313. TINUVIN 622 (RTM)+SANDUVOR PR-31 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
314. TINUVIN 622 (RTM)+SANDUVOR PR-31 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
315. TINUVIN 622 (RTM)+SANDUVOR PR-31 (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
316. TINUVIN 622 (RTM)+UVASIL 299 LM (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
317. TINUVIN 622 (RTM)+UVASIL 299 LM (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
318. TINUVIN 622 (RTM)+UVASIL 299 LM (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
319. TINUVIN 622 (RTM)+UVASIL 2000 LM (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen
320. TINUVIN 622 (RTM)+UVASIL 2000 LM (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl
321. TINUVIN 622 (RTM)+UVASIL 2000 LM (RTM)+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
322. TINUVIN 622 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen+compound of the formula (B-6-a) wherein E₁₈is methyl
323. TINUVIN 622 (RTM)+compound of the formula (B-6-a) wherein E₁₈is hydrogen+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.
324. TINUVIN 622 (RTM)+compound of the formula (B-6-a) wherein E₁₈is methyl+compound of the formula (B-7) with E₁₉, E₂₀and E₂, being a group of the formula (b-III) wherein E₂₂is hydrogen.

Further examples of stabilizer mixtures are those wherein in the above combinations 1 to 324 the commercial product TINUVIN 622 (RTM) is replaced by a compound of the formula (A-2-a) and/or (A-2-b)
wherein n₂and n₂* are a number from 2 to 20.

Additional examples of stabilizer mixtures are those wherein in the above combinations 1 to 324 the commercial product TINUVIN 622 (RTM) is replaced by a compound of the formula (A-4-a)
wherein n₄is a number from 2 to 20, and
at least 50% of the radicals A₇are a group of the formula
and the
remaining radicals A₇are ethyl.

Combinations of particular interest are numbers 1, 4, 7, 8, 12, 13 and 15 to 24, and the corresponding combinations wherein TINUVIN 622 (RTM) is replaced by a compound of the formula (A-2-a) and/or (A-2-b).

Further combinations of particular interest are numbers 3, 4, 8, 17 and 31.

The commercial product TINUVIN 622 (RTM) corresponds to the compound of the formula (A-1-a).

The commercial product TINUVIN 770 (RTM) corresponds to the compound of the formula (B-1-b) wherein E₁is hydrogen.

The commercial product TINUVIN 765 (RTM) corresponds to the compound of the formula (B-1-b) wherein E₁is methyl.

The commercial product TINUVIN 123 (RTM) corresponds to the compound of the formula (B-1-b) wherein E₁is octyloxy.

The commercial product TINUVIN 144 (RTM) corresponds to the compound of the formula (B-1-c) wherein E₁is methyl.

The commercial product ADK STAB LA 57 (RTM) corresponds to the compound of the formula (B-1-d) wherein E, is hydrogen.

The commercial product ADK STAB LA 52 (RTM) corresponds to the compound of the formula (B-1-d) wherein E₁is methyl.

The commercial product ADK STAB LA 67 (RTM) corresponds to the compound of the formula (B-2-a) wherein E₈is hydrogen.

The commercial product ADK STAB LA 62 (RTM) corresponds to the compound of the formula (B-2-a) wherein E₁is methyl.

The commercial product HOSTAVIN N 24 (RTM) corresponds to the compound of the formula (B-3-b) wherein E₁₂is hydrogen.

The commercial product SANDUVOR 3050 (RTM) corresponds to the compound of the formula (B-3-b-1) shown below, wherein E₁₂is hydrogen.

The commercial product DIACETAM 5 (RTM) corresponds to the compound of the formula (B-4-a) wherein E₁₃is hydrogen.

The commercial product SUMISORB TM 61 corresponds to the compound of the formula (B-4-b) wherein E₁₃is hydrogen.

The commercial product UVINUL 4049 (RTM) corresponds to the compound of the formula (B-5) wherein E₁₆is hydrogen.

The commercial product SANDUVOR PR 31 (RTM) corresponds to the compound of the formula (B-8-a) wherein E₂₃is methyl.

The commercial product GOODRITE 3034 (RTM) corresponds to the compound of the formula (B-9-b) wherein E₂₅is hydrogen.

The commercial product GOODRITE 3150 (RTM) corresponds to the compound of the formula (B-9-c) wherein E₂₅is hydrogen.

The commercial product GOODRITE 3159 (RTM) corresponds to the compound of the formula (B-9-c) wherein E₂₅is methyl.

The commercial product UVASIL 299 LM (RTM) or UVASIL 2000 LM (RTM) contains as active ingredient the compound of the formula (B-11-a) wherein R₁₆is hydrogen.

The compound of the formula (B-3-b-1) has the following structure:

The stabilizer mixture according to this invention is suitable for stabilizing organic materials against degradation induced by light, heat or oxidation. Examples of such organic materials are the following:

1. Polymers of monoolefins and diolefins, for example polypropylene, polyisobutylene, polybut-1-ene, poly-4-methylpent-1-ene, polyisoprene or polybutadiene, as well as polymers of cycloolefins, for instance of cyclopentene or norbornene, polyethylene (which optionally can be crosslinked), for example high density polyethylene (HDPE), high density and high molecular weight polyethylene (HDPE-HMW), high density and ultrahigh molecular weight polyethylene (HDPE-UHMW), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), (VLDPE) and (ULDPE).

Polyolefins, i.e. the polymers of monoolefins exemplified in the preceding paragraph, preferably polyethylene and polypropylene, can be prepared by different, and especially by the following, methods:

- a) radical polymerisation (normally under high pressure and at elevated temperature).
- b) catalytic polymerisation using a catalyst that normally contains one or more than one metal of groups IVb, Vb, VIb or VIII of the Periodic Table. These metals usually have one or more than one ligand, typically oxides, halides, alcoholates, esters, ethers, amines, alkyls, alkenyls and/or aryls that may be either π- or σ-coordinated. These metal complexes may be in the free form or fixed on substrates, typically on activated magnesium chloride, titanium(III) chloride, alumina or silicon oxide. These catalysts may be soluble or insoluble in the polymerisation medium. The catalysts can be used by themselves in the polymerisation or further activators may be used, typically metal alkyls, metal hydrides, metal alkyl halides, metal alkyl oxides or metal alkyloxanes, said metals being elements of groups Ia, IIa and/or IIIa of the Periodic Table. The activators may be modified conveniently with further ester, ether, amine or silyl ether groups. These catalyst systems are usually termed Phillips, Standard Oil Indiana, Ziegler (-Nafta), TNZ (DuPont), metallocene or single site catalysts (SSC).

2. Mixtures of the polymers mentioned under 1), for example mixtures of polypropylene with polyisobutylene, polypropylene with polyethylene (for example PP/HDPE, PP/LDPE) and mixtures of different types of polyethylene (for example LDPE/HDPE).

3. Copolymers of monoolefins and diolefins with each other or with other vinyl monomers, for example ethylene/propylene copolymers, linear low density polyethylene (LLDPE) and mixtures thereof with low density polyethylene (LDPE), propylene/but-1-ene copolymers, propylene/isobutylene copolymers, ethylene/but-1-ene copolymers, ethylene/hexene copolymers, ethylene/methylpentene copolymers, ethylene/heptene copolymers, ethylene/octene copolymers, propylene/butadiene copolymers, isobutylene/isoprene copolymers, ethylene/alkyl acrylate copolymers, ethylene/alkyl methacrylate copolymers, ethylene/vinyl acetate copolymers and their copolymers with carbon monoxide or ethylene/acrylic acid copolymers and their salts (ionomers) as well as terpolymers of ethylene with propylene and a diene such as hexadiene, dicyclopentadiene or ethylidene-norbornene; and mixtures of such copolymers with one another and with polymers mentioned in 1) above, for example polypropylene/ethylene-propylene copolymers, LDPE/ethylene-vinyl acetate copolymers (EVA), LDPE/ethylene-acrylic acid copolymers (EAA), LLDPE/EVA, LLDPE/EM and alternating or random polyalkylene/carbon monoxide copolymers and mixtures thereof with other polymers, for example polyamides.

4. Hydrocarbon resins (for example C₅-C₉) including hydrogenated modifications thereof (e.g. tackifiers) and mixtures of polyalkylenes and starch.

5. Polystyrene, poly(p-methylstyrene), poly(α-methylstyrene).

6. Copolymers of styrene or α-methylstyrene with dienes or acrylic derivatives, for example styrene/butadiene, styrene/acrylonitrile, styrene/alkyl methacrylate, styrene/butadiene/alkyl acrylate, styrene/butadiene/alkyl methacrylate, styrene/maleic anhydride, styrene/acrylonitrile/methyl acrylate; mixtures of high impact strength of styrene copolymers and another polymer, for example a polyacrylate, a diene polymer or an ethylene/propylene/diene terpolymer; and block copolymers of styrene such as styrene/butadiene/styrene, styrene/isoprene/styrene, styrene/ethylene/butylene/styrene or styrene/ethylene/propylene/styrene.

7. Graft copolymers of styrene or α-methylstyrene, for example styrene on polybutadiene, styrene on polybutadiene-styrene or polybutadiene-acrylonitrile copolymers; styrene and acrylonitrile (or methacrylonitrile) on polybutadiene; styrene, acrylonitrile and methyl methacrylate on polybutadiene; styrene and maleic anhydride on polybutadiene; styrene, acrylonitrile and maleic anhydride or maleimide on polybutadiene; styrene and maleimide on polybutadiene; styrene and alkyl acrylates or methacrylates on polybutadiene; styrene and acrylonitrile on ethylene/propylene/diene terpolymers; styrene and acrylonitrile on polyalkyl acrylates or polyalkyl methacrylates, styrene and acrylonitrile on acrylate/butadiene copolymers, as well as mixtures thereof with the copolymers listed under 6), for example the copolymer mixtures known as ABS, MBS, ASA or AES polymers.

8. Halogen-containing polymers such as polychloroprene, chlorinated rubbers, chlorinated and brominated copolymer of isobutylene-isoprene (halobutyl rubber), chlorinated or sulfochlorinated polyethylene, copolymers of ethylene and chlorinated ethylene, epichlorohydrin homo- and copolymers, especially polymers of halogen-containing vinyl compounds, for example polyvinyl chloride, polyvinylidene chloride, polyvinyl fluoride, polyvinylidene fluoride, as well as copolymers thereof such as vinyl chloride/vinylidene chloride, vinyl chloride/vinyl acetate or vinylidene chloride/vinyl acetate copolymers.

9. Polymers derived from α,β-unsaturated acids and derivatives thereof such as polyacrylates and polymethacrylates; polymethyl methacrylates, polyacrylamides and polyacrylonitriles, impact-modified with butyl acrylate.

10. Copolymers of the monomers mentioned under 9) with each other or with other unsaturated monomers, for example acrylonitrile/butadiene copolymers, acrylonitrile/alkyl acrylate copolymers, acrylonitrile/alkoxyalkyl acrylate or acrylonitrile/vinyl halide copolymers or acrylonitrile/alkyl methacrylate/butadiene terpolymers.

11. Polymers derived from unsaturated alcohols and amines or the acyl derivatives or acetals thereof, for example polyvinyl alcohol, polyvinyl acetate, polyvinyl stearate, polyvinyl benzoate, polyvinyl maleate, polyvinyl butyral, polyallyl phthalate or polyallyl melamine; as well as their copolymers with olefins mentioned in 1) above.

12. Homopolymers and copolymers of cyclic ethers such as polyalkylene glycols, polyethylene oxide, polypropylene oxide or copolymers thereof with bisglycidyl ethers.

13. Polyacetals such as polyoxymethylene and those polyoxymethylenes which contain ethylene oxide as a comonomer; polyacetals modified with thermoplastic polyurethanes, acrylates or MBS.

14. Polyphenylene oxides and sulfides, and mixtures of polyphenylene oxides with styrene polymers or polyamides.

15. Polyurethanes derived from hydroxyl-terminated polyethers, polyesters or polybutadienes on the one hand and aliphatic or aromatic polyisocyanates on the other, as well as precursors thereof.

16. Polyamides and copolyamides derived from diamines and dicarboxylic acids and/or from aminocarboxylic acids or the corresponding lactams, for example polyamide 4, polyamide 6, polyamide 6/6, 6/10, 6/9, 6/12, 4/6, 12/12, polyamide 11, polyamide 12, aromatic polyamides starting from m-xylene diamine and adipic acid; polyamides prepared from hexamethylenediamine and isophthalic or/and terephthalic acid and with or without an elastomer as modifier, for example poly-2,4,4,-trimethylhexamethylene terephthalamide or poly-m-phenylene isophthalamide; and also block copolymers of the aforementioned polyamides with polyolefins, olefin copolymers, ionomers or chemically bonded or grafted elastomers; or with polyethers, e.g. with polyethylene glycol, polypropylene glycol or polytetramethylene glycol; as well as polyamides or copolyamides modified with EPDM or ABS; and polyamides condensed during processing (RIM polyamide systems).

17. Polyureas, polyimides, polyamide-imides, polyetherimids, polyesterimids, polyhydantoins and polybenzimidazoles.

18. Polyesters derived from dicarboxylic acids and diols and/or from hydroxycarboxylic acids or the corresponding lactones, for example polyethylene terephthalate, polybutylene terephthalate, poly-1,4-dimethylolcyclohexane terephthalate, polyalkylene naphthalate (PAN) and polyhydroxybenzoates, as well as block copolyether esters derived from hydroxyl-terminated polyethers; and also polyesters modified with polycarbonates or MBS.

19. Polycarbonates and polyester carbonates.

20. Polysulfones, polyether sulfones and polyether ketones.

21. Crosslinked polymers derived from aldehydes on the one hand and phenols, ureas and melamines on the other hand, such as phenol/formaldehyde resins, urea/formaldehyde resins and melamine/formaldehyde resins.

22. Drying and non-drying alkyd resins.

23. Unsaturated polyester resins derived from copolyesters of saturated and unsaturated dicarboxylic acids with polyhydric alcohols and vinyl compounds as crosslinking agents, and also halogen-containing modifications thereof of low flammability.

24. Crosslinkable acrylic resins derived from substituted acrylates, for example epoxy acrylates, urethane acrylates or polyester acrylates.

25. Alkyd resins, polyester resins and acrylate resins crosslinked with melamine resins, urea resins, isocyanates, isocyanurates, polyisocyanates or epoxy resins.

26. Crosslinked epoxy resins derived from aliphatic, cycloaliphatic, heterocyclic or aromatic glycidyl compounds, e.g. products of diglycidyl ethers of bisphenol A and bisphenol F, which are crosslinked with customary hardeners such as anhydrides or amines, with or without accelerators.

27. Natural polymers such as cellulose, rubber, gelatin and chemically modified homologous derivatives thereof, for example cellulose acetates, cellulose propionates and cellulose butyrates, or the cellulose ethers such as methyl cellulose; as well as rosins and their derivatives.

28. Blends of the aforementioned polymers (polyblends), for example PP/EPDM, Polyamide/EPDM or ABS, PVC/EVA, PVC/ABS, PVC/MBS, PC/ABS, PBTP/ABS, PC/ASA, PC/PBT, PVC/CPE, PVC/acrylates, POM/thermoplastic PUR, PC/thermoplastic PUR, POM/acrylate, POW/MBS, PPO/HIPS, PPO/PA 6.6 and copolymers, PA/HDPE, PA/PP, PA/PPO, PBT/PC/ABS or PBT/PET/PC.

29. Naturally occurring and synthetic organic materials which are pure monomeric compounds or mixtures of such compounds, for example mineral oils, animal and vegetable fats, oil and waxes, or oils, fats and waxes based on synthetic esters (e.g. phthalates, adipates, phosphates or trimellitates) and also mixtures of synthetic esters with mineral oils in any weight ratios, typically those used as spinning compositions, as well as aqueous emulsions of such materials.

30. Aqueous emulsions of natural or synthetic rubber, e.g. natural latex or latices of carboxylated styrene/butadiene copolymers.

This invention therefore additionally relates to a composition comprising an organic material subject to degradation induced by light, heat or oxidation and the stabilizer mixture described herein above.

A further embodiment of the present invention is a method for stabilizing an organic material against degradation induced by light, heat or oxidation, which comprises incorporating into the organic material the stabilizer mixture described herein above.

The organic material is preferably a synthetic polymer, in particular from one of the above groups. Polyolefins are preferred and polyethylene, polypropylene, a polyethylene copolymer and a polypropylene copolymer are particularly preferred.

The compounds of components (A) and (B) may be added to the organic material to be stabilized either individually or mixed with one another.

Each of the compounds of components (A) and (B) may be present in the organic material in an amount of preferably 0.005 to 5%, in particular 0.01 to 1% or 0.05 to 1%, relative to the weight of the organic material.

The weight ratio of the components (A):(B) is preferably 10:1 to 1:100, in particular 10:1 to 1:10 or 5:1 to 1:5. Further examples for the weight ratio are also 1:1 to 1:10, for example 12 to 1:5.

The weight ratio of the two components forming component (B) is for example 1:10 to 10:1 or 15 to 5:1, preferably 1:2 to 2:1, in particular 1:1.

The above components can be incorporated into the organic material to be stabilized by known methods, for example before or during shaping or by applying the dissolved or dispersed compounds to the organic material, if necessary with subsequent evaporation of the solvent. The components can be added to the organic material in the form of a powder, granules or a masterbatch, which contains these components in, for example, a concentration of from 2.5 to 25% by weight.

If desired, the compounds of components (A) and (B) can be blended with each other before incorporation in the organic material. They can be added to a polymer before or during the polymerization or before the crosslinking.

The materials stabilized according to this invention can be used in a wide variety of forms, for example as films, fibres, tapes, moulding compositions, profiles or as binders for paints, adhesives or putties.

The stabilized material may additionally also contain various conventional additives, for example:

1. Antioxidants

1.1. Alkylated monophenols, for example 2,6-di-tert-butyl-4-methylphenol, 2-tert-butyl-4,6-dimethylphenol, 2,6-di-tert-butyl-4-ethylphenol, 2,6-di-tert-butyl-4-n-butylphenol, 2,6-di-tert-butyl-4-isobutylphenol, 2,6-dicyclopentyl-4-methylphenol, 2-(α-methylcyclohexyl)-4,6-dimethylphenol, 2,6-dioctadecyl-4-methylphenol, 2,4,6-tricyclohexylphenol, 2,6-di-tert-butyl-4-methoxymethylphenol, nonylphenols which are linear or branched in the side chains, for example 2,6-di-nonyl-4-methylphenol, 2,4-dimethyl-6-(1′-methylundec-1′-yl)phenol, 2,4-dimethyl-6-(1′-methylheptadec-1′-yl)phenol, 2,4-dimethyl-6-(1′-methyltridec-1′-yl)phenol and mixtures thereof.

1.2. Alkylthiomethylphenols, for example 2,4-dioctylthiomethyl-6-tert-butylphenol, 2,4-dioctylthiomethyl-6-methylphenol, 2,4-dioctylthiomethyl-6-ethylphenol, 2,6-di-dodecylthiomethyl-4-nonylphenol.

1.3. Hydroquinones and alkylated hydroquinones, for example 2,6-di-tert-butyl-4-methoxyphenol, 2,5-di-tert-butylhydroquinone, 2,5-di-tert-amylhydroquinone, 2,6-diphenyl-4-octadecyloxyphenol, 2,6-di-tert-butylhydroquinone, 2,5-di-tert-butyl-4-hydroxyanisole, 3,5-di-tert-butyl-4-hydroxyanisole, 3,5-di-tert-butyl-4-hydroxyphenyl stearate, bis(3,5-di-tert-butyl-4-hydroxyphenyl) adipate.

1.4. Tocopherols, for example α-tocopherol, β-tocopherol, γ-tocopherol, 6-tocopherol and mixtures thereof (vitamin E).

1.5. Hydroxylated thiodiphenyl ethers, for example 2,2′-thiobis(6-tert-butyl-4-methylphenol), 2,2′-thiobis(4-octylphenol), 4,4′-thiobis(6-tert-butyl-3-methylphenol), 4,4′-thiobis(6-tert-butyl-2-methylphenol), 4,4′-thiobis(3,6-di-sec-amylphenol), 4,4′-bis(2,6-dimethyl-4-hydroxyphenyl)-disulfide.

1.6. Alkylidenebisphenols, for example 2,2′-methylenebis(6-tert-butyl-4-methylphenol), 2,2′-methylenebis(6-tert-butyl-4-ethylphenol), 2,2′-methylenebis[4-methyl-6-(α-methylcyclohexyl)-phenol], 2,2′-methylenebis(4-methyl-6-cyclohexylphenol), 2,2′-methylenebis(6-nonyl-4-methylphenol), 2,2′-methylenebis(4,6-di-tert-butylphenol), 2,2′-ethylidenebis(4,6-di-tert-butyl-phenol), 2,2′-ethylidenebis(6-tert-butyl-4-isobutylphenol), 2,2′-methylenebis[6-(α-methylbenzyl)-4-nonylphenol], 2,2′-methylenebis[6-(α,α-dimethylbenzyl)-4-nonylphenol], 4,4′-methylenebis(2,6-di-tert-butylphenol), 4,4′-methylenebis(6-tert-butyl-2-methylphenol), 1,1-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butane, 2,6-bis(3-tert-butyl-5-methyl-2-hydroxybenzyl)-4-methylphenol, 1,1,3-tris(5-tert-butyl-4-hydroxy-2-methylphenyl)butane, 1,1-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)-3-n-dodecylmercaptobutane, ethylene glycol bis[3,3-bis(3′-tert-butyl-4′-hydroxyphenyl)butyrate], bis(3-tert-butyl-4-hydroxy-5-methyl-phenyl)dicyclopentadiene, bis[2-(3′-tert-butyl-2′-hydroxy-5′-methylbenzyl)-6-tert-butyl-4-methylphenyl]terephthalate, 1,1-bis-(3,5-dimethyl-2-hydroxyphenyl)butane, 2,2-bis(3,5-di-tert-butyl-4-hydroxyphenyl)propane, 2,2-bis-(5-tert-butyl-4-hydroxy2-methylphenyl)-4-n-dodecylmercaptobutane, 1,1,5,5-tetra(5-tert-butyl-4-hydroxy-2-methylphenyl)pentane.

1.7. O-, N- and S-benzyl compounds, for example 3,5,3′,5′-tetra-tert-butyl-4,4′-dihydroxydibenzyl ether, octadecyl-4-hydroxy-3,5-dimethylbenzylmercaptoacetate, tridecyl-4-hydroxy-3,5-di-tert-butylbenzylmercaptoacetate, tris(3,5-di-tert-butyl-4-hydroxybenzyl)amine, bis(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)dithioterephthalate, bis(3,5-di-tert-butyl-4-hydroxybenzyl)sulfide, isooctyl-3,5-di-tert-butyl-4-hydroxybenzylmercaptoacetate.

1.8. Hydroxybenzylated malonates, for example dioctadecyl-2,2-bis(3,5-di-tert-butyl-2-hydroxybenzyl)malonate, di-octadecyl-2-(3-tert-butyl-4-hydroxy-5-methylbenzyl)malonate, di-dodecylmercaptoethyl-2,2-bis(3,5-di-tert-butyl-4-hydroxybenzyl)malonate, bis[4-(1,1,3,3-tetramethylbutyl)phenyl]-2,2-bis(3,5-di-tert-butyl-4-hydroxybenzyl)malonate.

1.9. Aromatic hydroxybenzyl compounds, for example 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, 1,4-bis(3,5-di-tert-butyl-4-hydroxybenzyl)-2,3,5,6-tetramethylbenzene, 2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)phenol.

1.10. Triazine compounds, for example 2,4-bis(octylmercapto)-6-(3,5-di-tert-butyl-4-hydroxyanilino)-1,3,5-triazine, 2-octylmercapto-4,6-bis(3,5-di-tert-butyl-4-hydroxyanilino)-1,3,5-triazine, 2-octylmercapto-4,6-bis(3,5-di-tert-butyl-4-hydroxyphenoxy)-1,3,5-triazine, 2,4,6-tris(3,5-di-tert-butyl-4-hydroxyphenoxy)-1,2,3-triazine, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)isocyanurate, 2,4,6-tris(3,5-di-tert-butyl-4-hydroxyphenylethyl)-1,3,5-triazine, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)-hexahydro-1,3,5-triazine, 1,3,5-tris(3,5-dicyclohexyl-4-hydroxybenzyl)isocyanurate.

1.11. Benzylphosphonates, for example dimethyl-2,5-di-tert-butyl-4-hydroxybenzylphosphonate, diethyl-3,5-di-tert-butyl-4-hydroxybenzylphosphonate, dioctadecyl-3,5-di-tert-butyl-4-hydroxybenzylphosphonate, dioctadecyl-5-tert-butyl-4-hydroxy-3-methylbenzylphosphonate, the calcium salt of the monoethyl ester of 3,5-di-tert-butyl-4-hydroxybenzylphosphonic acid.

1.12. Acylaminophenols, for example 4-hydroxylauranilide, 4-hydroxystearanilide, octyl N-(3,5-di-tert-butyl-4-hydroxyphenyl)carbamate.

1.13. Esters of β-(3,5-di-tert-butyl-4-hydroxyphenyl)proprionic acid with mono- or polyhydric alcohols, e.g. with methanol, ethanol, n-octanol, i-octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N′-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane.

1.14. Esters of B-(5-tert-butyl-4-hydroxy-3-methylphenyl)propionic acid with mono- or polyhydric alcohols, e.g. with methanol, ethanol, n-octanol, i-octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N′-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane; 3,9-bis[2-{3-(3-tertbutyl-4-hydroxy-5-methylphenyl)propionyloxy}-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[5.5]-undecane.

1.15. Esters of β-(3,5-dicyclohexyl-4-hydroxyphenyl)propionic acid with mono- or polyhydric alcohols, e.g. with methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N′-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane.

1.16. Esters of 3,5-di-tert-butyl-4-hydroxyphenyl acetic acid with mono- or polyhydric alcohols, e.g. with methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N′-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane.

1.17. Amides of β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid e.g. N,N′-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)hexamethylenediamide, N,N′-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)trimethylenediamide, N,N′-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)hydrazide, N,N′-bis[2-(3-[3,5-di-tert-butyl-4-hydroxyphenyl]propionyloxy)ethyl]oxamide (Naugard®XL-1, supplied by Uniroyal).

1.18. Ascorbic acid (vitamin C)

1.19. Aminic antioxidants, for example N,N′-di-isopropyl-p-phenylenediamine, N,N′-di-sec-butyl-p-phenylenediamine, N,N′-bis(1,4-dimethylpentyl)-p-phenylenediamine, N,N′-bis(1-ethyl-3-methylpentyl)-p-phenylenediamine, N,N′-bis(1-methylheptyl)-p-phenylenediamine, N,N′-dicyclohexyl-p-phenylenediamine, N,N′-diphenyl-p-phenylenediamine, N,N′-bis(2-naphthyl)-p-phenylenediamine, N-isopropyl-N′-phenyl-p-phenylenediamine, N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylenediamine, N-(1-methylheptyl)-N′-phenyl-p-phenylenediamine, N-cyclohexyl-N′-phenyl-p-phenylenediamine, 4-(p-toluenesulfamoyl)diphenylamine, N,N′-dimethyl-N,N′-di-sec-butyl-p-phenylenediamine, diphenylamine, N-allytdiphenylamine, 4-isopropoxydiphenyl-amine, N-phenyl-1-naphthylamine, N-(4-tert-octylphenyl)-1-naphthylamine, N-phenyl-2-naphthylamine, octylated diphenylamine, for example p,p′-di-tert-octyldiphenylamine, 4-n-butylaminophenol, 4-butyrylaminophenol, 4-nonanoylaminophenol, 4-dodecanoylaminophenol, 4-octadecanoylaminophenol, bis(4-methoxyphenyl)amine, 2,6-di-tert-butyl-4-dimethylaminomethylphenol, 2,4′-diaminodiphenylmethane, 4,4′-diaminodiphenylmethane, N,N,N′,N′-tetramethyl-4,4′-diaminodiphenylmethane, 1,2-bis[(2-methylphenyl)amino]ethane, 1,2-bis(phenylamino)propane, (o-tolyl)biguanide, bis[4-(1′,3′-dimethylbutyl)phenyl]amine, tert-octylated N-phenyl-1-naphthylamine, a mixture of mono- and dialkylated tert-butyl/tert-octyidiphenylamines, a mixture of mono- and dialkylated nonyidiphenylamines, a mixture of mono- and dialkylated dodecyldiphenylamines, a mixture of mono- and dialkylated isopropyl/isohexyldiphenylamines, a mixture of mono- and dialkylated tert-butyidiphenylamines, 2,3-dihydro-3,3-dimethyl-4H-1,4-benzothiazine, phenothiazine, a mixture of mono- and dialkylated tert-butyl/tert-octylphenothiazines, a mixture of mono- and dialkylated tert-octylphenothiazines, N-allylphenothiazine, N,N,N′,N′-tetraphenyl-1,4-diaminobut-2-ene, N,N-bis(2,2,6,6-tetra-methylpiperid-4-yl-hexamethylenediamine, bis(2,2,6,6-tetramethylpiperid-4-yl)sebacate, 2,2,6,6-tetramethylpiperidin-4-one, 2,2,6,6-tetramethylpiperidin-4-ol.

2. UV Absorbers and Light Stabilisers

2.1. 2-(2′-Hydroxyphenyl)benzotriazoles, for example 2-(2′-hydroxy-5′-methylphenyl)benzo-triazole, 2-(3′,5′-di-tert-butyl-2′-hydroxyphenyl)benzotriazole, 2-(5′-tert-butyl-2′-hydroxyphenyl)benzotriazole, 2-(2′-hydroxy-5′-(1,1,3,3-tetramethylbutyl)phenyl)benzotriazole, 2-(3′,5′-di-tert-butyl-2′-hydroxyphenyl)-5-chlorobenzotriazole, 2-(3′-tert-butyl-2′-hydroxy-5′-methylphenyl)-5-chlorobenzotriazole, 2-(3′-sec-butyl-5′-tert-butyl-2′-hydroxyphenyl)benzotriazole, 2-(2′-hydroxy-4′-octyloxyphenyl)benzotriazole, 2-(3′,5′-di-tert-amyl-2′-hydroxyphenyl)benzotriazole, 2-(3′,5′-bis(α,α-dimethylbenzyl)-2′-hydroxyphenyl)benzotriazole, 2-(3′-tert-butyl-2′-hydroxy-5′-(2-octyloxycarbonylethyl)phenyl)-5-chlorobenzotriazole, 2-(3′-tert-butyl-5′-[2-(2-ethylhexyloxy)carbonylethyl]-2′-hydroxyphenyl)-5-chlorobenzotriazole, 2-(3′-tert-butyl-2′-hydroxy-5′-(2-methoxycarbonylethyl)phenyl)-5-chlorobenzotriazole, 2-(3′-tert-butyl-2′-hydroxy-5′-(2-methoxycarbonylethyl)phenyl)benzotriazole, 2-(3′-tert-butyl-2′-hydroxy-5′-(2-octyloxycarbonylethyl)phenyl)benzotriazole, 2-(3′-tert-butyl-5′-[2-(2-ethylhexyloxy)carbonylethyl]-2′-hydroxyphenyl)benzotriazole, 2-(3′-dodecyl-2′-hydroxy-5′-methylphenyl)benzotriazole, 2-(3′-tert-butyl-2′-hydroxy-5′-(2-isooctyloxycarbonylethyl)phenylbenzotriazole, 2,2′-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6-benzotriazole-2-ylphenol]; the transesterification product of 2-[3′-tert-butyl-5′-(2-methoxycarbonylethyl)-2′-hydroxyphenyl]-2H-benzotriazole with polyethylene glycol 300; [R—CH₂CH₂—COO—CH₂CH₂—]₂₂, where R=3′-tert-butyl-4′-hydroxy-5′-2H-benzotriazol-2-ylphenyl, 2-[2′-hydroxy-3′-(α,α-dimethylbenzyl)-5′-(1,1,3,3-tetramethylbutyl)phenyl]-benzotriazole; 2-[2′-hydroxy-3′-(1,1,3,3-tetramethylbutyl)-5′-(α,α-dimethylbenzyl)phenyl]benzotriazole.

2.2. 2-Hydroxybenzophenones, for example the 4-hydroxy, 4-methoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4,2′,4′-trihydroxy and 2′-hydroxy-4,4′-dimethoxy derivatives.

2.3. Esters of substituted and unsubstituted benzoic acids, for example 4-tert-butylphenyl salicylate, phenyl salicylate, octylphenyl salicylate, dibenzoyl resorcinol, bis(4-tert-butylbenzoyl)resorcinol, benzoyl resorcinol, 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate, hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate, octadecyl 3,5-di-tert-butyl-4-hydroxybenzoate, 2-methyl-4,6-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate.

2.4. Acrylates, for example ethyl α-cyano-β,β-diphenylacrylate, isooctyl α-cyano-β,β-diphenylacrylate, methyl α-carbomethoxycinnamate, methyl α-cyano-β-methyl-p-methoxycinnamate, butyl α-cyano-β-methyl-p-methoxycinnamate, methyl α-carbomethoxy-p-methoxycinnamate and N-(β-carbomethoxy-β-cyanovinyl)-2-methylindoline.

2.5. Nickel compounds, for example nickel complexes of 2,2′-thiobis[4-(1,1,3,3-tetramethylbutyl)phenol], such as the 1:1 or 1:2 complex, with or without additional ligands such as n-butylamine, triethanolamine or N-cyclohexyldiethanolamine, nickel dibutyldithiocarbamate, nickel salts of the monoalkyl esters, e.g. the methyl or ethyl ester, of 4-hydroxy-3,5-di-tert-butylbenzylphosphonic acid, nickel complexes of ketoximes, e.g. of 2-hydroxy-4-methylphenylundecylketoxime, nickel complexes of 1-phenyl-4-lauroyl-5-hydroxypyrazole, with or without additional ligands.

2.6. Oxamides, for example 4,4′-dioctyloxyoxanilide, 2,2′-diethoxyoxanilide, 2,2′-dioctyloxy-5,5′-di-tert-butoxanilide, 2,2′-didodecyloxy-5,5′-di-tert-butoxanilide, 2-ethoxy-2′-ethyloxanilide, N,N′-bis(3-dimethylaminopropyl)oxamide, 2-ethoxy-5-tert-butyl-2′-ethoxanilide and its mixture with 2-ethoxy-2′-ethyl-5,4′-di-tert-butoxanilide, mixtures of o- and p-methoxy-disubstituted oxanilides and mixtures of o- and p-ethoxy-disubstituted oxanilides.

2.7. 2-(2-Hydroxyphenyl)-1,3,5-triazines, for example 2,4,6-tris(2-hydroxy-4-octyloxyphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-octyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2,4-dihydroxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2,4-bis(2-hydroxy-4-propyloxyphenyl)-6-(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-octyloxyphenyl)-4,6-bis(4-methylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-dodecyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-tridecyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-[2-hydroxy-4-(2-hydroxy-3-butyloxypropoxy)phenyl]-4,6-bis(2,4-dimethyl)-1,3,5-triazine, 2-[2-hydroxy-4-(2-hydroxy-3-octyloxypropyloxy)phenyl]-4,6-bis(2,4-dimethyl)-1,3,5-triazine, 2-[4-(dodecyloxy/tridecyloxy-2-hydroxypropoxy)-2-hydroxyphenyl]-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-[2-hydroxy-4-(2-hydroxy-3-dodecyloxypropoxy)phenyl]-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-hexyloxy)phenyl-4,6-diphenyl-1,3,5-triazine, 2-(2-hydroxy-4-methoxyphenyl)-4,6-diphenyl-1,3,5-triazine, 2,4,6-tris[2-hydroxy-4-(3-butoxy-2-hydroxypropoxy)phenyl]-1,3,5-triazine, 2-(2-hydroxyphenyl)-4-(4-methoxyphenyl)-6-phenyl-1,3,5-triazine, 2-{2-hydroxy-4-[3-(2-ethylhexyl-1-oxy)-2-hydroxypropyloxy]phenyl}-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine.

3. Metal deactivators, for example N,N′-diphenyloxamide, N-salicylal-N′-salicyloyl hydrazine, N,N′-bis(salicyloyl)hydrazine, N,N′-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)hydrazine, 3-salicyloylamino-1,2,4-triazole, bis(benzylidene)oxalyl dihydrazide, oxanilide, isophthaloyl dihydrazide, sebacoyl bisphenylhydrazide, N,N′-diacetyladipoyl dihydrazide, N,N′-bis(salicyloyl)oxalyl dihydrazide, N,N′-bis(salicyloyl)thiopropionyl dihydrazide.

4. Phosphites and phosphonites, for example triphenyl phosphite, diphenylalkyl phosphites, phenyldialkyl phosphites, tris(nonylphenyl) phosphite, trilauryl phosphite, trioctadecyl phosphite, distearylpentaerythritol diphosphite, tris(2,4-di-tert-butylphenyl) phosphite, diisodecyl pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl)pentaerythritol diphosphite, bis(2,4-dicumylphenyl)pentaerythritol diphosphite, bis(2,6-di-tert-butyl-4-methylphenyl)pentaerythritol diphosphite, diisodecyloxypentaerythritol diphosphite, bis(2,4-di-tert-butyl-6-methylphenyl)pentaerythritol diphosphite, bis(2,4,6-tris(tert-butylphenyl)pentaerythritol diphosphite, tristearyl sorbitol triphosphite, tetrakis(2,4-di-tert-butylphenyl) 4,4′-biphenylene diphosphonite, 6-isooctyloxy-2,4,8,10-tetra-tert-butyl-12H-dibenz[d,g]-1,3,2-dioxaphosphocin, bis(2,4-di-tertbutyl-6-methylphenyl)methyl phosphite, bis(2,4-di-tert-butyl-6-methylphenyl)ethyl phosphite, 6-fluoro-2,4,8,10-tetra-tert-butyl-12-methyl-dibenz[d,g]-1,3,2-dioxaphosphocin, 2,2′,2″-nitrilo-[triethyltris(3,3′,5,5′-tetra-tert-butyl-1,1′-biphenyl-2,2′-diyl)phosphite], 2-ethylhexyl(3,3′,5,5′-tetra-tert-butyl-1,1′-biphenyl-2,2′-diyl)phosphite, 5-butyl-5-ethyl-2-(2,4,6-tri-tert-butylphenoxy)-1,3,2-dioxaphosphirane.

The following phosphites are especially preferred:

Tris(2,4-di-tert-butylphenyl) phosphite (Irgafos® 168, Ciba-Geigy), tris(nonylphenyl) phosphite,

5. Hydroxylamines, for example N,N-dibenzylhydroxylamine, N,N-diethylhydroxylamine, N,N-dioctylhydroxylamine, N,N-dilaurylhydroxylamine, N,N-ditetradecylhydroxylamine, N,N-dihexadecylhydroxylamine, N,N-dioctadecylhydroxylamine, N-hexadecyl-N-octadecylhydroxylamine, N-heptadecyl-N-octadecylhydroxylamine, N,N-dialkylhydroxylamine derived from hydrogenated tallow amine.

6. Nitrones, for example N-benzyl-alpha-phenylnitrone, N-ethyl-alpha-methylnitrone, N-octyl-alpha-heptylnitrone, N-lauryl-alpha-undecylnitrone, N-tetradecyl-alpha-tridecylnitrone, N-hexadecyl-alpha-pentadecylnitrone, N-octadecyl-alpha-heptadecyinitrone, N-hexadecyl-alpha-heptadecylnitrone, N-ocatadecyl-alpha-pentadecyinitrone, N-heptadecyl-alpha-heptadecylnitrone, N-octadecyl-alpha-hexadecyinitrone, nitrone derived from N,N-dialkylhydroxylamine derived from hydrogenated tallow amine.

7. Thiosynergists, for example dilauryl thiodipropionate or distearyl thiodipropionate.

8. Peroxide scavengers, for example esters of β-thiodipropionic acid, for example the lauryl, stearyl, myristyl or tridecyl esters, mercaptobenzimidazole or the zinc salt of 2-mercaptobenzimidazole, zinc dibutyldithiocarbamate, dioctadecyl disulfide, pentaerythritol tetrakis(β-dodecylmercapto)propionate.

9. Polyamide stabilisers, for example copper salts in combination with iodides and/or phosphorus compounds and salts of divalent manganese.

10. Basic co-stabilisers, for example melamine, polyvinylpyrrolidone, dicyandiamide, triallyl cyanurate, urea derivatives, hydrazine derivatives, amines, polyamides, polyurethanes, alkali metal salts and alkaline earth metal salts of higher fatty acids, for example calcium stearate, zinc stearate, magnesium behenate, magnesium stearate, sodium ricinoleate and potassium palmitate, antimony pyrocatecholate or zinc pyrocatecholate.

11. Nucleating agents, for example inorganic substances, such as talcum, metal oxides, such as titanium dioxide or magnesium oxide, phosphates, carbonates or sulfates of, preferably, alkaline earth metals; organic compounds, such as mono- or polycarboxylic acids and the salts thereof, e.g. 4-tert-butylbenzoic acid, adipic acid, diphenylacetic acid, sodium succinate or sodium benzoate; polymeric compounds, such as ionic copolymers (ionomers). Especially preferred are 1,3:2,4-bis(3′,4′-dimethylbenzylidene)sorbitol, 1,3:2,4-di(paramethyldibenzylidene)sorbitol, and 1,3:2,4-di(benzylidene)sorbitol.

12. Fillers and reinforcing agents, for example calcium carbonate, silicates, glass fibres, glass bulbs, asbestos, talc, kaolin, mica, barium sulfate, metal oxides and hydroxides, carbon black, graphite, wood flour and flours or fibers of other natural products, synthetic fibers.

13. Other additives, for example plasticisers, lubricants, emulsifiers, pigments, rheology additives, catalysts, flow-control agents, optical brighteners, flameproofing agents, antistatic agents and blowing agents.

14. Benzofuranones and indolinones, for example those disclosed in U.S. Pat. No. 4,325,863; U.S. Pat. No. 4,338,244; U.S. Pat. No. 5,175,312; U.S. Pat. No. 5,216,052; U.S. Pat. No. 5,252,643; DE-A-4316611; DE-A-4316622; DE-A-4316876; EP-A-0589839 or EP-A-0591102 or 3-[4-(2-acetoxyethoxy)phenyl]-5,7-di-tert-butylbenzofuran-2-one, 5,7-di-tert-butyl-3-[4-(2-stearoyloxyethoxy)phenyl]-benzofuran-2-one, 3,3′-bis[5,7-di-tert-butyl-3-(4-[2-hydroxyethoxy]phenyl)benzofuran-2-one], 5,7-di-tert-butyl-3-(4-ethoxyphenyl)benzofuran-2-one, 3-(4-acetoxy-3,5-dimethylphenyl)-5,7-di-tert-butylbenzofuran-2-one, 3-(3,5-dimethyl-4-pivaloyloxyphenyl)-5,7-di-tert-butylbenzofuran-2-one, 3-(3,4-dimethylphenyl)-5,7-di-tert-butylbenzofuran-2-one, 3-(2,3-dimethylphenyl)-5,7-di-tert-butylbenzofuran-2-one.

The weight ratio of the total amount of components (A) and (B) to the total amount of the conventional additives can be, for example, 100:1 to 1:100 or 10:1 to 1:10.

The examples below illustrate the invention in greater detail. All percentages and parts are by weight, unless stated otherwise.

LIGHT STABILIZERS USED IN THE FOLLOWING EXAMPLES 1 AND 2

TINUVIN 622 (RTM)
Mixture (A-2):

Mixture of the compounds (A-2-a) and (A-2-b) in a weight ratio of 4:1
Compound (B-1-a-1):
TINUVIN 770 (RTM):
TINUVIN 765 (RTM):
TINUVIN 123 (RTM):
TINUVIN 144 (RTM):
ADK STAB LA 52 (RTM):
ADK STAB LA 57 (RTM):
ADK STAB LA 62 (RTM):
in which two of the radicals E₇are —COO—C₁₃H₂₇and
two of the radicals E₇are
ADK STAB LA 67 (RTM):
in which two of the radicals E₇are —COO—C₁₃H₂₇and
two of the radicals E₇are
HOSTAVIN N 20 (RTM):
SANDUVOR 3050 (RTM):
HOSTAVIN N 24 (RTM):
UVINUL 4049H (RTM):
Compound (B-6-a-1):
Compound (B-6-a-2):
SANDUVOR PR 31 (RTM):
GOODRITE UV 3034 (RTM):
GOODRITE UV 3150 (RTM):
Compound (B-10-a-1):
Compound (B-7-1):
in which E₁₉, E₂₀and E₂₁are the group

Example 1 Light Stabilization of Polypropylene Homopolymer Films

100 parts of unstabilized polypropylene powder (melt flow index: 2.4 g/10 minutes at 230° C. and 2160 g) are homogenized at 200° C. for 10 minutes in a Brabender plastograph with 0.05 parts of pentaerythrityl-tetrakis{3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate}, 0.05 parts of tris{2,4-di-tert-butylphenyl} phosphite, 0.1 parts of Ca stearate, 0.25 parts of titanium dioxide (anatase) and the stabilizer system indicated Table 1. The material thus obtained is compression molded in a laboratory press between two aluminum foils for 6 minutes at 260° C. to a 0.5 mm thick film which is cooled immediately to room temperature in a water-cooled press. Samples of 60 mm×25 mm are cut out of these 0.5 mm films and are exposed in a WEATHER-OMETER Ci 65 (black panel temperature 63±2° C., without water-spraying).

Periodically, these samples are removed from the exposure apparatus and their carbonyl content is measured with an infrared spectrophotometer.

The exposure time (T_0.1) corresponding to the formation of a carbonyl absorbance of 0.1 is a measure for the efficiency of the light stabilizer system. The values obtained are summarized in Table 1. High T_0.1values are desired.

TABLE 1 T_0.1in hours Light stabilizer system in combination with TINUVIN 622 (RTM) T_0.1in hours The amount of The amount of the the light light stabilizers stabilizers used used is 0.075% is 0.05% Light stabilizer system each*). each*). Without 185 — TINUVIN 770 (RTM) + TINUVIN 765 (RTM) 1780 3095 TINUVIN 770 (RTM) + TINUVIN 144 (RTM) 1990 2815 TINUVIN 770 (RTM) + TINUVIN 123 (RTM) 1780 2650 TINUVIN 770 (RTM) + HOSTAVIN N 20 (RTM) 2760 3205 TINUVIN 770 (RTM) + ADK STAB LA 57 (RTM) 2245 3045 TINUVIN 770 (RTM) + GOODRITE UV 3034 (RTM) 2440 3570 TINUVIN 770 (RTM) + GOODRITE UV 3150 (RTM) 2715 3230 TINUVIN 770 (RTM) + Compound (B-6-a-1) 1930 3095 TINUVIN 770 (RTM) + Compound (B-6-a-2) 2000 3400 TINUVIN 770 (RTM) + Compound (B-10-a-1) 3510 3940 TINUVIN 770 (RTM) + Compound (B-1-a-1) 1715 3520 TINUVIN 770 (RTM) + SANDUVOR 3050 (RTM) 1630 3040 TINUVIN 770 (RTM) + SANDUVOR PR-31 (RTM) 1885 2730 HOSTAVIN N 20 (RTM) + ADK STAB LA 57 (RTM) 2485 2765 HOSTAVIN N 20 (RTM) + Compound (B-6-a-1) 2625 3010 HOSTAVIN N 20 (RTM) + UVINUL 4049 H (RTM) 2655 3245 HOSTAVIN N 20 (RTM) + Compound (B-1-a-1) 2510 3055 HOSTAVIN N 20 (RTM) + SANDUVOR PR-31 (RTM) 2120 3140 ADK STAB LA 57 (RTM) + TINUVIN 765 (RTM) 2290 2705 ADK STAB LA 57 (RTM) + GOODRITE UV 3150 (RTM) 2305 2930 ADK STAB LA 57 (RTM) + Compound (B-6-a-2) 2255 2745 ADK STAB LA 57 (RTM) + UVINUL 4049 H (RTM) 2400 2735 ADK STAB LA 57 (RTM) + SANDUVOR PR-31 (RTM) 1670 2655 GOODRITE UV 3150 (RTM) + Compound (B-6-a-1) 2390 3040 GOODRITE UV 3150 (RTM) + Compound (B-6-a-2) 2155 2670 GOODRITE UV 3150 (RTM) + SANDUVOR PR-31 (RTM) 2075 2840 Compound (B-6-a-1) + TINUVIN 765 (RTM) 2230 3010 Compound (B-6-a-1) + Compound (B-6-a-2) 2235 2980 Compound (B-6-a-1) + UVINUL 4049 H (RTM) 2465 3235 Compound (B-6-a-1) + Compound (B-1-a-1) 2225 2775 Compound (B-10-a-1) + UVINUL 4049 H (RTM) 3430 4055 Compound (B-10-a-1) + SANDUVOR PR-31 (RTM) 2710 3255 Compound (B-1-a-1) + TINUVIN 765 (RTM) 2365 3060 Compound (B-1-a-1) + UVINUL 4049 H (RTM) 2475 3205 Compound (B-1-a-1) + SANDUVOR PR-31 (RTM) 1845 2550 Compound (B-1-a-1) + Compound (B-6-a-2) 2240 2650
*)The overall concentration of the light stabilizers is 0.15%.

Example 2 Light Stabilization of Polypropylene Homopolymer Films

100 parts of unstabilized polypropylene powder (melt flow index: 3.8 g/10 minutes at 230° C. and 2160 g) are homogenized at 200° C. for 10 minutes in a Brabender plastograph with 0.05 parts of pentaerythrityl {tetrakis-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate}, 0.05 parts of tris{2,4-di-tert-butylphenyl)phosphite}, 0.1 parts of Ca stearate, 0.25 parts of titanium dioxide (anatase) and the stabilizer system indicated in Tables 2A to 2H. The material thus obtained is compression molded in a laboratory press between two aluminum foils for 6 minutes at 260° C. to a 0.5 mm thick film which is cooled immediately to room temperature in a water-cooled press. Samples of 60 mm×25 mm are cut out of these 0.5 mm films and are exposed in a WEATHER-OMETER Ci 65 (black panel temperature 63±2° C., without water-spraying).

Periodically, these samples are removed from the exposure apparatus and their carbonyl content is measured with an infrared spectrophotometer.

The exposure time (T_0.1) corresponding to the formation of a carbonyl absorbance of 0.1 is a measure for the efficiency of the light stabilizer system. The values obtained are summarized in the following tables. High T_0.1values are desired.

TABLE 2A T_0.1in hours T_0.1in hours Light stabilizer T_0.1in hours Light stabilizer system in Light stabilizer system in combination system in combination with TINUVIN combination with TINUVIN 622 (RTM) with TINUVIN 622 (RTM) The amount of 622 (RTM) The amount of the stabilizers The amount of the stabilizers of the light the stabilizers of the light stabilizer of the light T_0.1in hours stabilizer system is stabilizer The amount of system is 0.05% 0.075% each system is 0.09% the light each and the and the each and stabilizers amount of amount of the amount of used is 0.1% TINUVIN 622 TINUVIN 622 TINUVIN 622 Light stabilizer system each*). (RTM) is 0.10%*). (RTM) is 0.05%*). (RTM) is 0.02%*).* Without 300 TINUVIN 770 (RTM) + TINUVIN 4635 7530 7585 6235 144 (RTM) TINUVIN 770 (RTM) + TINUVIN 4935 7940 7170 7130 123 (RTM) TINUVIN 770 (RTM) + HOSTAVIN 5105 7455 7030 6890 N 24 (RTM) TINUVIN 770 (RTM) + ADK 6710 6945 7865 8010 STAB LA 52 (RTM) TINUVIN 770 (RTM) + ADK 5450 7225 7225 7280 STAB LA 57 (RTM) TINUVIN 770 (RTM) + ADK 5915 6700 7190 7025 STAB LA 67 (RTM) TINUVIN 770 (RTM) + GOODRITE 6925 >8340 >8340 7360 UV 3034 (RTM) TINUVIN 770 (RTM) + GOODRITE 6325 7965 7625 7025 UV 3150 (RTM) TINUVIN 770 (RTM) + Compound 6040 7400 7540 7025 (B-1-a-1) TINUVIN 770 (RTM) + SANDUVOR 5070 7005 6990 5735 3050 (RTM) TINUVIN 770 (RTM) + SANDUVOR 5745 7470 6765 6705 PR-31 (RTM)
*)The overall concentration of the light stabilizers is 0.20%.

TABLE 2B T_0.1in hours Light stabilizer system in combination with Mixture (A-2) T_0.1in hours The amount of the stabilizers of The amount of the the light stabilizer system is light stabilizers used 0.075% each and the amount Light stabilizer system is 0.1% each*). of Mixture (A-2) is 0.05%*). Without 300 — TINUVIN 770 (RTM) + TINUVIN 4635 6025 144 (RTM) TINUVIN 770 (RTM) + TINUVIN 4935 6080 123 (RTM) TINUVIN 770 (RTM) + HOSTAVIN 5105 6005 N 24 (RTM) TINUVIN 770 (RTM) + ADK 5450 6800 STAB LA 57 (RTM) TINUVIN 770 (RTM) + GOODRITE 6925 7735 UV 3034 (RTM) TINUVIN 770 (RTM) + Compound 6530 7335 (B-6-a-2) TINUVIN 770 (RTM) + Compound 6040 6905 (B-1-a-1) TINUVIN 770 (RTM) + SANDUVOR 5070 >6495 3050 (RTM)
*)The overall concentration of the light stabilizers is 0.20%.

TABLE 2C T_0.1in hours Light stabilizer system in combination with TINUVIN 622 (RTM) T_0.1in hours The amount of the stabilizers of the The amount of the light stabilizer system is 0.075% each light stabilizers used and the amount of TINUVIN 622 Light stabilizer system is 0.1% each*). (RTM) is 0.05%*). Without 315 — TINUVIN 770 (RTM) + TINUVIN 4815 >7260 765 (RTM) TINUVIN 770 (RTM) + TINUVIN 5695 7145 144 (RTM) TINUVIN 770 (RTM) + TINUVIN 4670 7080 123 (RTM) TINUVIN 770 (RTM) + HOSTAVIN 5390 6710 N 24 (RTM) TINUVIN 770 (RTM) + ADK 6655 >7260 STAB LA 52 (RTM) TINUVIN 770 (RTM) + ADK 5040 6760 STAB LA 62 (RTM) TINUVIN 770 (RTM) + ADK 5010 6205 STAB LA 67 (RTM) TINUVIN 770 (RTM) + Compound 5825 >7260 (B-10-a-1) TINUVIN 770 (RTM) + Compound 6125 7215 (B-1-a-1) TINUVIN 770 (RTM) + SANDUVOR 5690 >7260 3050 (RTM) TINUVIN 770 (RTM) + SANDUVOR 5100 6475 PR-31 (RTM)
*)The overall concentration of the light stabilizers is 0.20%.

TABLE 2D T_0.1in hours Light stabilizer system in combination with TINUVIN 622 (RTM) T_0.1in hours The amount of the stabilizers of the The amount of the light stabilizer system is 0.075% each light stabilizers used and the amount of TINUVIN 622 Light stabilizer system is 0.1% each*). (RTM) is 0.05%*). Without 315 — TINUVIN 765 (RTM) + TINUVIN 4930 7180 144 (RTM) TINUVIN 765 (RTM) + TINUVIN 4640 >7260 123 (RTM) TINUVIN 765 (RTM) + HOSTAVIN 6580 >7260 N 20 (RTM) TINUVIN 765 (RTM) + HOSTAVIN 5325 7040 N 24 (RTM) TINUVIN 765 (RTM) + ADK 5605 >7260 STAB LA 52 (RTM) TINUVIN 765 (RTM) + ADK 5360 6905 STAB LA 57 (RTM) TINUVIN 765 (RTM) + ADK 4620 >7260 STAB LA 62 (RTM) TINUVIN 765 (RTM) + ADK 4840 6625 STAB LA 67 (RTM) TINUVIN 765 (RTM) + GOODRITE 6550 >7260 UV 3034 (RTM) TINUVIN 765 (RTM) + GOODRITE 5715 >7260 UV 3150 (RTM) TINUVIN 765 (RTM) + Compound 5105 >7260 (B-6-a-1) TINUVIN 765 (RTM) + Compound 6145 >7260 (B-1-a-1) TINUVIN 765 (RTM) + SANDUVOR 5425 >7260 3050 (RTM) TINUVIN 765 (RTM) + SANDUVOR 4920 6675 PR-31 (RTM)
*)The overall concentration of the light stabilizers is 0.20%.

TABLE 2E T_0.1in hours Light stabilizer system in combination with TINUVIN 622 (RTM) T_0.1in hours The amount of the stabilizers of the The amount of the light stabilizer system is 0.075% light stabilizers used each and the amount of TINUVIN 622 Light stabilizer system is 0.1% each*). (RTM) is 0.05%*). Without 330 TINUVIN 144 (RTM) + TINUVIN 3185 5765 123 (RTM) TINUVIN 144 (RTM) + HOSTAVIN 4295 6150 N 20 (RTM) TINUVIN 144 (RTM) + HOSTAVIN 3725 5720 N 24 (RTM) TINUVIN 144 (RTM) + ADK 4195 5635 STAB LA 52 (RTM) TINUVIN 144 (RTM) + ADK 4870 6350 STAB LA 57 (RTM) TINUVIN 144 (RTM) + ADK 2815 5695 STAB LA 62 (RTM) TINUVIN 144 (RTM) + ADK 3910 4940 STAB LA 67 (RTM) TINUVIN 144 (RTM) + GOODRITE 4185 6115 UV 3034 (RTM) TINUVIN 144 (RTM) + GOODRITE 4290 5725 UV 3150 (RTM) TINUVIN 144 (RTM) + Compound 5515 6565 (B-6-a-1) TINUVIN 144 (RTM) + Compound 5100 6810 (B-6-a-2) TINUVIN 144 (RTM) + Compound 5380 6585 (B-10-a-1) TINUVIN 144 (RTM) + Compound 5470 6305 (B-1-a-1) TINUVIN 144 (RTM) + SANDUVOR 4030 5200 3050 (RTM) TINUVIN 144 (RTM) + SANDUVOR 3105 5890 PR-31 (RTM)
*)The overall concentration of the light stabilizers is 0.20%.

TABLE 2F T_0.1in hours Light stabilizer system in combination with TINUVIN 622 (RTM) T_0.1in hours The amount of the stabilizers of the The amount of the light stabilizer system is 0.075% each light stabilizers used and the amount of TINUVIN 622 Light stabilizer system is 0.1% each*). (RTM) is 0.05%*) Without 330 TINUVIN 123 (RTM) + HOSTAVIN 4455 5715 N 20 (RTM) TINUVIN 123 (RTM) + HOSTAVIN 3490 5265 N 24 (RTM) TINUVIN 123 (RTM) + ADK 4620 5610 STAB LA 52 (RTM) TINUVIN 123 (RTM) + ADK 4275 5670 STAB LA 57 (RTM) TINUVIN 123 (RTM) + ADK 3380 5185 STAB LA 62 (RTM) TINUVIN 123 (RTM) + ADK 3470 5355 STAB LA 67 (RTM) TINUVIN 123 (RTM) + GOODRITE 4520 >6280 UV 3034 (RTM) TINUVIN 123 (RTM) + GOODRITE 4260 5635 UV 3150 (RTM) TINUVIN 123 (RTM) + Compound 4760 6145 (B-6-a-1) TINUVIN 123 (RTM) + Compound 5115 6365 (B-6-a-2) TINUVIN 123 (RTM) + Compound 5785 6700 (B-10-a-1) TINUVIN 123 (RTM) + Compound 4345 6115 (B-1-a-1) TINUVIN 123 (RTM) + SANDUVOR 3650 5040 3050 (RTM) TINUVIN 123 (RTM) + SANDUVOR 3655 5390 PR-31 (RTM) TINUVIN 123 (RTM) + Compound 4305 5205 (B-7-1)
*)The overall concentration of the light stabilizers is 0.20%.

TABLE 2G T_0.1in hours Light stabilizer system in combination with TINUVIN 622 (RTM) T_0.1in hours The amount of the stabilizers of the The amount of the light stabilizer system is 0.075% each light stabilizers used and the amount of TINUVIN 622 Light stabilizer system is 0.1% each*). (RTM) is 0.05%*). Without 325 HOSTAVIN N 20 (RTM) + HOSTAVIN 3695 4565 N 24 (RTM) HOSTAVIN N 20 (RTM) + ADK 4375 5525 STAB LA 52 (RTM) HOSTAVIN N 20 (RTM) + ADK 4485 5535 STAB LA 57 (RTM) HOSTAVIN N 20 (RTM) + ADK 3810 5315 STAB LA 62 (RTM) HOSTAVIN N 20 (RTM) + ADK 3655 5045 STAB LA 67 (RTM) HOSTAVIN N 20 (RTM) + GOODRITE 5005 5610 UV 3034 (RTM) HOSTAVIN N 20 (RTM) + GOODRITE 3950 5050 UV 3150 (RTM) HOSTAVIN N 20 (RTM) + Compound 5025 >5890 (B-6-a-1) HOSTAVIN N 20 (RTM) + Compound 5465 >5890 (B-6-a-2) HOSTAVIN N 20 (RTM) + Compound 5405 >5890 (B-10-a-1) HOSTAVIN N 20 (RTM) + Compound 5410 >5890 (B-1-a-1) HOSTAVIN N 20 (RTM) + SANDUVOR 3985 5090 3050 (RTM) HOSTAVIN N 20 (RTM) + SANDUVOR 4085 5255 PR-31 (RTM) HOSTAVIN N 20 (RTM) + Compound 4200 5220 (B-7-1)
*)The overall concentration of the light stabilizers is 0.20%.

TABLE 2H T_0.1in hours Light stabilizer system in combination with TINUVIN 622 (RTM) The amount of the stabilizers of the light stabilizer system T_0.1in hours is 0.075% each The amount of the and the amount of light stabilizers used TINUVIN 622 Light stabilizer system is 0.1% each*). (RTM) is 0.05%*). Without 325 ADK STAB LA 57 4035 5020 (RTM) + HOSTAVIN N 24 (RTM) ADK STAB LA 57 3855 4985 (RTM) + ADK STAB LA 52 (RTM) ADK STAB LA 57 4320 4890 (RTM) + GOODRITE UV 3150 (RTM) ADK STAB LA 57 3970 4430 (RTM) + SANDUVOR PR-31 (RTM) ADK STAB LA 57 3765 4475 (RTM) + Compound (B-7-1)
*)The overall concentration of the light stabilizers is 0.20%.

Claims

1. A stabilizer mixture containing the components (A) and (B) wherein

component (A) is

a compound of the formula (A-1)

wherein

A1 is hydrogen or C1-C4alkyl,

A2 is a direct bond or C1-C10alkylene, and

n1 is a number from 2 to 50;

at least one compound of the formulae (A-2-a) and (A-2-b)

wherein

n2 and n2* are a number from 2 to 50;

a compound of the formula (A-3)

wherein

A3 and A-4 independently of one another are hydrogen or C1-C8alkyl, or A3 and A-4 together form a C2-C14alkylene group, and

the variables n3 independently of one another are a number from 1 to 50; or

a compound of the formula (A-4)

wherein

n4 is a number from 2 to 50,

A5 is hydrogen or C1-C4alkyl,

the radicals 3 and A7 independently of one another are C1-C4alkyl or a group of the formula (a-I)

wherein A8 is hydrogen, C1-C8alkyl, O−, —OH, —CH2CN, C1-C18alkoxy, C5-C12cycloalkoxy, C3-C6alkenyl, C7-C9phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C1-C4alkyl; or C1-C8acyl,

with the proviso that at least 50% of the radicals A7 are a group of the formula (a-I); and

component (B) is formed by two different low molecular weight sterically hindered amine compounds containing a group of the formula (I) or (II);

with the proviso that components (A) and (B) are different.

2. A stabilizer mixture according to claim 1 wherein the two different compounds of component (B) are selected from the group consisting of the classes

β-1) a compound of the formula (B-1)

in which

E1 is hydrogen, C1-C8alkyl, O−, —OH, —CH2CN, C1-C18alkoxy, C5-C12cycloalkoxy, C3-C6alkenyl, C7-C9phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C1-C4alkyl; or

C1-C8acyl,

m1 is 1, 2 or 4,

if m1 is 1, E2 is C1-C25alkyl,

if m1 is 2, E2 is C1-C14alkylene or a group of the formula (b-I)

wherein E3 is C1-C10alkyl or C2-C10alkenyl, E4 is C1-C10alkylene, and

E5 and E6 independently of one another are C1-C4alkyl, cyclohexyl or methylcyclohexyl, and

if m1 is 4, E2 is C4-C10alkanetetrayl;

β-2) a compound of the formula (B-2)

in which

two of the radicals E7 are —COO—(C1-C20alkyl), and

two of the radicals E7 are a group of the formula (b-II)

with E8 having one of the meanings of E1;

β-3) a compound of the formula (B-3)

in which

E9 and E10 together form C2-C14alkylene,

E11 is hydrogen or a group -Z1-COO-Z2,

Z1 is C2-C14alkylene, and

Z2 is C1-C24alkyl, and

E12 has one of the meanings of E1;

β-4) a compound of the formula (B-4)

wherein

the radicals E13 independently of one another have one of the meanings of E1,

the radicals E14 independently of one another are hydrogen or C1-C12alkyl, and

E15 is C1-C10alkylene or C3-C10alkylidene;

β-5) a compound of the formula (B-5)

wherein

the radicals E16 independently of one another have one of the meanings of E1;

β-6) a compound of the formula (B-6)

in which

E17 is C1-C24alkyl, and

E18 has one of the meanings of E1;

β-7) a compound of the formula (B-7)

in which

E19, E20 and E21 independently of one another are a group of the formula (b-III)

wherein E22 has one of the meanings of E1;

β-8) a compound of the formula (B-8)

wherein

the radicals E23 independently of one another have one of the meanings of E1, and E24 is hydrogen, C1-C12alkyl or C1-C12alkoxy;

β-9) a compound of the formula (B-9)

wherein

m2 is 1, 2 or 3,

E25 has one of the meanings of E1, and

when m2 is 1, E26 is a group

when m2 is 2, E26 is C2-C22alkylene, and

when m2 is 3, E26 is a group of the formula (b-IV)

wherein the radicals E27 independently of one another are C2-C12alkylene, and the radicals E28 independently of one another are C1-C12alkyl or C5-C12cycloalkyl;

β-10) a compound of the formula (B-10)

wherein

the radicals E29 independently of one another have one of the meanings of E1, and

E30 is C2-C22alkylene, C5-C7cycloalkylene, C1-C4alkylenedi(C5-C7cycloalkylene), phenylene or phenylenedi(C1-C4alkylene); or

β-11) a compound of the formula (B-11)

in which

E31 is C1-C10alkyl, C5-C12cycloalkyl, C1-C4alkyl-substituted C5-C12cycloalkyl, phenyl or

C1-C10alkyl-substituted phenyl,

E32 is C3-C10alkylene,

E33 has one of the meanings of E1, and

m3 is a number from 2 to 6.

3. A stabilizer mixture according to claim 1 wherein

A1 is hydrogen or methyl,

A2 is a direct bond or C2-C6alkylene, and

n1 is a number from 2 to 25;

n2 and n2* are a number from 2 to 25;

A3 and A4 independently of one another are hydrogen or C1-C4alkyl, or A3 and A4 together form a C9-C13alkylene group, and

the variables n3 independently of one another are a number from 1 to 25;

n4 is a number from 2 to 25,

A5 and A6 independently of one another are C1-C4alkyl, and

A7 is C1-C4alkyl or a group of the formula (a-I)

with the proviso that at least 50% of the radicals A7 are a group of the formula (a-I).

4. A stabilizer mixture according to claim 2 wherein

m1 is 1, 2 or 4,

if m1 is 1, E2 is C12-C20alkyl,

if m1 is 2, E2 is C2-C10alkylene or a group of the formula (b-I)

E3 is C1-C4alkyl,

E4 is C1-C6alkylene, and

E5 and E6 independently of one another are C1-C4alkyl, and

if m1 is 4, E2 is C4-C8alkanetetrayl;

two of the radicals E7 are —COO—(C10-C15alkyl), and

two of the radicals E7 are a group of the formula (b-II);

E9 and E10 together form C9-C13alkylene,

E11 is hydrogen or a group -Z1-COO-Z2,

Z1 is C2-C6alkylene, and

Z2 is C10-C16alkyl;

E14 is hydrogen, and

E15 is C2-C6alkylene or C3-C5alkylidene;

E17 is C10-C14alkyl;

E24 is C1-C4alkoxy;

m2 is 1, 2 or 3,

when m2 is 1, E26 is a group

when m2 is 2, E26 is C2-C6alkylene, and

when m2 is 3, E26 is a group of the formula (b-IV)

the radicals E27 independently of one another are C2-C6alkylene, and

the radicals E28 independently of one another are C1-C4alkyl or C5-C8cycloalkyl;

E30 is C2-C8alkylene; and

E31 is C1-C4alkyl,

E32 is C3-C6alkylene, and

m3 is a number from 2 to 6.

5. A stabilizer mixture according to claim 1 wherein

component (A) is a compound of the formula (A-1-a), (A-2-a), (A-2-b), (A-3-a) or (A-4-a);

wherein n1 is a number from 2 to 20;

wherein n2 and n2* are a number from 2 to 20;

wherein the variables n3 independently of one another are a number from 1 to 20;

wherein n4 is a number from 2 to 20, and

at least 50% of the radicals A7 are a group of the formula (a-I)

wherein A8 is hydrogen, C1-C8alkyl, O−, —OH, —CH2CN, C1-C18alkoxy, C5-C12cycloalkoxy, C3-C6alkenyl, C7-C9phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C1-C4alkyl; or C1-C8acyl,

and the remaining radicals A7 are ethyl; and

component (B) is formed by two different compounds selected from the group consisting of compounds of the formulae (B-1-a), (B-1-b), (B-1-c), (B-1-d), (B-2-a), (B-3-a), (B-3-b), (B-4-a), (B-4-b), (B-5), (B-6-a), (B-7), (B-8-a), (B-9-a), (B-9-b), (B-9-c), (B-10-a) and (B-11-a);

wherein E1 is hydrogen, C1-C8alkyl, O−, —OH, —CH2CN, C1-C18alkoxy, C5-C12cycloalkoxy, C3-C6alkenyl, C7-C9phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3

in which two of the radicals E7 are —COO—C13H27 and

two of the radicals E7 are

and E8 has one of the meanings

of E1;

wherein E12 has one of the meanings of E1;

wherein E13 has one of the meanings of E1;

wherein E16 has one of the meanings of E1;

wherein E18 has one of the meanings of E1;

in which E19, E20 and E21 independently of one another are a group of the formula (b-III)

wherein E22 has one of the meanings of E1;

wherein E23 has one of the meanings of E1;

wherein E25 has one of the meanings of E1;

wherein E29 has one of the meanings of E1;

wherein m3 is a number from 2 to 6 and E33 has one of the meanings of E1.

6. A stabilizer mixture according to claim 1 wherein A8 is hydrogen, C1-C4alkyl, C1-C10alkoxy, cyclohexyloxy, allyl, benzyl or acetyl.

7. A stabilizer mixture according to claim 2 wherein E1, E8, E12, E13, E16, E18, E22, E23, E25, E29 and E33 are hydrogen, C1-C4alkyl, C1-C10alkoxy, cyclohexyloxy, allyl, benzyl or acetyl.

8. A stabilizer mixture according to claim 5 wherein A8, E1, E8, E12, E13, E16, E18, E22, E23, E25, E29 and E33 are hydrogen or methyl and E1 additionally is C1-C8alkoxy.

9. A stabilizer mixture according to claim 5 wherein one of the two different compounds forming component (B) is a compound of the formula (B-1-b) with E1 being hydrogen.

10. A stabilizer mixture according to claim 5 wherein

component (A) is a compound of the formula (A-1-a) with n1 being a number from 2 to 20 or a compound of the formula (A-2-a) or (A-2-b) wherein n2 and n2* are a number from 2 to 20; and

one of the two different compounds forming component (B) is a compound of the formula (B-1-b) with E1 being hydrogen.

11. A stabilizer mixture according to claim 5 wherein component (A) is a compound of the formula (A-1-a) with n, being a number from 2 to 20 or a compound of the formula (A-2-a) or (A-2-b) wherein n2 and n2* are a number from 2 to 20;

one of the two different compounds forming component (B) is a compound of the formula (B-1-b) with E1 being hydrogen; and

the other of the two different compounds forming component (B) is a compound of the formula (B-1-a) with E1 being hydrogen, (B-1-b) with E1 being methyl, (B-1-d) with E1 being hydrogen or methyl, (B-3-a) with E12 being hydrogen, (B-3-b) with E12 being hydrogen, (B-4-b) with E13 being hydrogen, (B-5) with E16 being hydrogen, (B-6-a) with E18 being hydrogen or methyl, (B-8-a) with E23 being methyl, (B-9-c) with E25 being hydrogen or methyl, (B-10-a) with E29 being hydrogen, or (B-11-a) with E33 being hydrogen.

12. A stabilizer mixture according to claim 5 wherein

component (A) is a compound of the formula (A-1-a) with n1 being a number from 2 to 20,

component (B) is a compound of the formula (B-1-b) wherein E1 is hydrogen, and

component (C) is a compound of the formula (B-1-b) wherein E1 is octyloxy; or

component (A) is a compound of the formula (A-1-a) with n1 being a number from 2 to 20,

component (B) is a compound of the formula (B-1-b) wherein E1 is hydrogen, and

component (C) is a compound of the formula (B-3-a) wherein E12 is hydrogen; or

component (A) is a compound of the formula (A-1-a) with n1 being a number from 2 to 20,

component (B) is a compound of the formula (B-1-b) wherein E1 is hydrogen, and

component (C) is a compound of the formula (B-1-d) wherein E1 is hydrogen; or

component (A) is a compound of the formula (A-1-a) with n, being a number from 2 to 20,

component (B) is a compound of the formula (B-1-b) wherein E1 is hydrogen, and

component (C) is a compound of the formula (B-1-a) wherein E1 is hydrogen; or

component (A) is a compound of the formula (A-1-a) with n, being a number from 2 to 20,

component (B) is a compound of the formula (B-1-b) wherein E1 is methyl, and

component (C) is a compound of the formula (B-1-d) wherein E1 is methyl.

13. A composition comprising an organic material subject to degradation induced by light, heat or oxidation and a stabilizer mixture according to claim 1.

14. A composition according to claim 13 wherein the organic material is a synthetic polymer.

15. A composition according to claim 13 wherein the organic material is a polyolefin.

16. A composition according to claim 13 wherein the organic material is polyethylene, polypropylene, a polyethylene copolymer or a polypropylene copolymer.

17. A method for stabilizing an organic material against degradation induced by light, heat or oxidation, which comprises incorporating into the organic material a stabilizer mixture according to claim 1.