AIR PLASMA INDUCED LOW METAL LOSS
Even a very small amount of air plasma can reduce the dross during melting. A method and device is shown, whereby substantial saving in the cost of melting aluminum and the energy to melt aluminum is possible by the technique of introducing a small amount of air plasma in the melting environment. In this manner even though the air contains oxygen, and the common practice is presently directed at air being eliminated from the melting environment, an air plasma is able to very effectively be utilized.
Latest Micropyretics Heaters International, Inc. Patents:
U.S. Pat. No. 5,963,709 and pending patent application Ser. No. 10/725,6161
Other US PatentsU.S. Pat. No. 3,648,015.
U.S. Pat. No. 5,403,453.
U.S. Pat. No. 5,387,842.
U.S. Pat. No. 5,414,324.
U.S. Pat. No. 5,456,972.
U.S. Pat. No. 5,669,583.
U.S. Pat. No. 5,938,854.
U.S. Pat. No. 6,146,724.
U.S. Pat. No. 6,245,132.
Application:The general physical and chemical characteristics of molten aluminum include: Aluminum melts combine with oxygen, moisture, or other oxidizing materials to form dross, and the tendency and ease with which this dross can be entrained in the melt affects the casting made from the melt. Other factors which affect the casting made from aluminum and its alloys are, the readiness with which the melt will absorb nascent hydrogen, and the evolution of hydrogen during solidification of the casting to form porosity (the principal source of hydrogen is moisture from the products of gas/oil combustion); the 3.5 to 8.5% contraction in volume which occurs when the melt solidifies and the low density of molten aluminum which results in low hydrostatic pressure in the mold. Good founding practice begins with good melting practice which is almost always dependent on the type of melt casting furnace used. As will be noted in the sections below the use of any electrically operated system for the melting of aluminum impacts favorably on dross formation as electrically heated systems minimize convection. When the aluminum melts react with the atmosphere or moisture, a dross of aluminum oxide and nitride is formed, which contains some mechanically entrained gas and metal. Since the dross is wetted by the aluminum melt and has about the same density, it often becomes entrained in the melt during melting, handling, or casting, and does not readily separate at the surface of the melt. It is commonly believed that the quantity of dross formed during melting increases with 1) the use of fine or badly weathered or corroded scrap; 2) the presence of magnesium in the alloys in the charge; 3) the increase in turbulence (such as from induction melting) which breaks the protective oxide surface of the melt in the furnace; and 4) the increase in the temperature of gases specially air and oxygen in contact with the surface. The oxide on the melt surface contains a considerable amount of liquid metal, causing the dross layer to be “wet.” Common experience has it therefore that high temperatures cause more dross and that wet dross is increased also by a higher temperature of melting. The melting/casting furnaces presently used in the aluminum industry can typically be classified into three types depending on the source to power the same. These are resistance-heated furnaces, induction-heated furnaces, and gas- or oil-fired furnaces. The common types and their advantages are tested in Table 1. Although each type of the existing melt furnaces have some advantages, they all suffer from several general drawbacks, namely high energy cost, high dross, harmful gas generation, low quality aluminum, and high operational noise, as individually discussed below:
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- Resistance-heated furnace—The resistor elements are inserted in protection tubes or otherwise suspended and installed in the furnace lining with heat transfer to the metal by radiation. The general temperature of operation of these furnaces is between 700 and 1000 C. The heating elements used are generally made of metallic wires (max temperature that these can normally reach is about 1050 C) or silicon carbide (maximum temperature they can reach is about 1500 C). Nevertheless the normal use of electric furnace to melt or contain aluminum is about 700 to 800 C. The costs for investment, maintenance, and operation of this type of furnace are high because of the cost of electricity and when silicon carbide elements are used which frequently are imbalanced because of aging.
- Induction-heated furnaces—In addition to energy inefficiency, induction furnace are generally characterized by high maintenance and labor costs and therefore, the use of this kind of furnace is usually limited only to some very special applications. Induction furnaces also cause churning of the liquid leading to oxide (dross) inclusions. There is also a growing concern about electromagnetic fields (EMF) in the workplace. However, this issue remains controversial. Again when using induction furnaces the melt is kept at about 700 to 800 C.
- Gas- or oil-fired furnaces—This type of furnace is more energy inefficient than the other two types of furnaces because of uncontrolled combustion flames inside the furnace. All gas- or oil-fired furnaces suffer from high noise due to the burning explosive process and serious environmental problem due to the release of harmful combustion product gases such as PAH, soot, sulfur dioxide, NOx, and CO. In addition, this type of furnace usually has low recovery rated because air is allowed into the furnace for the operation of the gas/oil burners which results in severe melt loss due to oxidation. Moisture in the gas often leads to hydrogen pick up in the melt.
It is clearly noted from the chart above that conventional radiant electric heating is the most efficient and clean method of heating. The total metal melt loss in dross could be as high as 80% of the dross weight. In radiant rod furnaces, electric currents of up to 4000 to 5000 amperes are commonly used to heat silicon carbide resistance elements which radiate to the furnace load and walls (note however as described above such elements are not the most optimal). These furnaces are made to oscillate, thereby facilitating conduction to the melt from the furnace walls. Radiant rod furnaces require relatively low investment cost, but are primarily being used as holding furnace. Operating costs are impacted by dross formation and energy usage. Typical dross loss
The result of reduced dross is significant from our experiments. We find that even a small amount of air plasma in an aluminum heating furnace can substantially reduce dross.
It is common knowledge that nitrogen gas is used as a cover to reduce the oxidation (dross formation). There are several technologies which are also used to recover aluminum from dross by re-melting and cleaning means. Our invention will make possible substantial savings in melting costs because Nitrogen a gas often used during melting or holding aluminum to melt aluminum can be eliminated. The dross is often reclaimed by re-melting thus incurring energy and productivity penalties. Thus by using our invention the energy costs are reduced for aluminum processing and the productivity of aluminum melting can be enhanced. We anticipate that the product of the invention can be used to separate debris from aluminum where the debris can be sprues or dross or other contaminants.
EXPERIMENT # 1
From the results and the table 2 we note that in addition to dross reduction the energy and time required to melt aluminum is also low when even a small amount of air plasma is present. The heat transfer coefficient may have been increased because of the presence of even small amounts of plasma. In our experiments we estimate that that at least 5% of the total heat came from the plasma generator.
Most importantly the dross content is reduced substantially which is an unusual result and totally unexpected from common wisdom which is that as the temperature is higher then the dross increases especially in the presence of hot air. The reason for the low dross, we suspect possibly comes from the air nitrogen becoming partially ionized. However, this reasoning is only a speculation at this stage. Normally it would be expected that an Airtorch™ enhanced melting which uses hot air (i.e. hot oxygen) would show high dross but the experiments all appear to indicate that the dross in reality reduced substantially. As discussed below this is thought to occur because of the plasma content in the air, albeit small.
The surface of a metallic part especially if the surface is electrically conducting, i.e. where electrons are available in abundance, may give up electrons to the air plasma and also produce heat according to the reaction:
2N++2e−=2N+E (approximately 1480 kJ/mole)
2N=N2+E
This is a manner in which nitrogen and heat automatically could be thought to deposit on the surface of aluminum thus increasing the energy transfer rate substantially as well as providing a cover of nitrogen gas which prevents oxidation. Typically ˜1 CFM of air plasma contains in excess of 1023 atoms and one percent ionization leads to nearly 1022 ions which can easily produce a layers of inert (non oxygen containing) atoms after absorbing electrons from the solid or liquid metal surface. The air plasma is expected to be mostly nitrogen plasma although the presence of oxygen plasma may not be ruled out because the first ionization energies of nitrogen and oxygen are very similar.
EXPERIMENT #7A Plasma Airtorch™ with a ¾″ diameter nozzle system was used for melting small pieces of aluminum with the sample in proximity with the hot air plasma atmosphere generated by the Airtorch. During solidification and cooling the plasma Airtorch was powered down slowly. The melted and solidified product looked clean. The clean melt and resultant clean surface solid is presumably because of the ionized plasma which protected the aluminum from large oxidation even though the atmosphere contained mostly air. This is an example which shows that a air plasma can be used by itself providing all the heat required to melt aluminum.
The melting or holding environment comprises of the total atmosphere in the melting or holding device. When the plasma generator is a device of the type displayed in
The typical devices which may used with the element to melt or contain liquid metal are furnaces (batch, continuous, holding, melting), crucibles, laddles, launder systems (channels for moving liquid metals), holding furnaces, melting furnaces, casting furnaces, transportation vessels for molten metals and other similar equipment.
EXPERIMENT #8Several small batches about 50 gms of Aluminum alloy 356 were melted in different configurations for a comparative study of the melting surface on resolidification. One batch was heated with a Plasma Airtorch™. The result is shown as (A) in
A typical device in which the method of air plasma melting can be done is shown in
An air plasma can be created by the products of U.S. Pat. No. 5,963,709 and pending patent application Ser. No. 10/725,6161 (herein incorporated fully). Small amounts of thermal plasma may also be created in very high temperature environments. Very small amounts of thermal ionization are possible by high temperature heating elements such as molybdenum, tungsten and molybdenum disilicide materials. The type of useful plasma for the invention is one which can be employed at normal or high pressure as opposed to very low pressure plasma. Plasma can also created by RF means U.S. Pat. Nos. 3,648,015, 5,403,453, 5,387,842, 5,414,324, 5,456,972, 5,669,583, 5,938,854, 6,146,724, 6,245,132 all incorporated herein. Not all techniques can produce Air Plasma at normal pressures and not all techniques except for U.S. Pat. No. 5,963,709 and Ser. No. 10/725,6161 can be considered to produce substantial heat. Unless an air plasma is used, the cost benefits to melting aluminum from using air instead of a gas like nitrogen, helium or argon are difficult to realize. Of course gas plasmas may also be employed and their use is anticipated.
The best mode appears to be the use of even a small amount even as low as 0.5-1% (of the total environment) of air plasma in any existing or specially constructed device which holds or melts molten aluminum. In this manner even though the air contains oxygen and common practice would involve hot oxygen being removed from the environment, an air plasma is able to very effectively utilize hot air and yet provide beneficial melting. The environment also protects against oxidation in the solid cool down or solid heat up stage.
Charge: The ingot, or other parts made of metal which are melted or heated. The charge can include ingots, cut pieces of metal, metal chips, or metal waste, or mixed debris and metal.
Melting: All processes involving partial or fully molten metal whether in containment, direct melting or transfer configurations.
Dross: Oxide and complex oxide scale(s) formed on molten aluminum or other metals which can additionally contain trapped metal as well as fluxes.
Air-Plasma: The plasma obtained from the ionization of air. The air plasma may contain substantially hot air and a percentage of ionized air gases.
Claims
1-10. (canceled)
11. An apparatus for processing a metal comprising:
- a receptacle for containing the metal; and
- at least one plasma arrangement configured to provide a combination of a heated gas and an ionized gas over a free surface of the metal,
- wherein, when the plasma arrangement provides the combination over the free surface, a dross that is formed when an entire charge of the metal is melted comprises less than about 3% by weight of the entire charge.
12. The apparatus of claim 11, wherein the combination provides at least about five percent of the total heat used for melting of the entire charge.
13. The apparatus of claim 11, wherein the receptacle comprises a heating arrangement configured to provide heat to the entire charge.
14. The apparatus of claim 13, wherein the heating arrangement comprises a plurality of resistance heating elements.
15. The apparatus of claim 14, wherein the resistance heating elements comprise molybdenum disilicide.
16. The apparatus of claim 11, wherein the heated gas is air.
17. The apparatus of claim 11, wherein the heated gas comprises oxygen.
18. The apparatus of claim 11, wherein the combination comprises a small amount of the ionized gases.
19. The apparatus of claim 11, wherein the combination comprises less than about 1% of the ionized gases.
20. The apparatus of claim 11, wherein the combination comprises between about 0.5% and about 1% of the ionized gases.
21. The apparatus of claim 11, wherein the metal comprises aluminum.
22. The apparatus of claim 11, wherein the receptacle comprises at least one of a launder system or a molten metal transportation vessel.
23. The apparatus of claim 11, wherein the at least one plasma arrangement comprises a plurality of plasma arrangements.
24. The apparatus of claim 11, further comprising an enclosure configured to provide an enclosed region above the receptacle, wherein the combination is provided into the enclosed region.
25. The apparatus of claim 11, wherein the receptacle comprises at least one of a furnace, a crucible, a holding furnace, a melting furnace, or a casting furnace.
Type: Application
Filed: Oct 11, 2007
Publication Date: Jun 12, 2008
Applicant: Micropyretics Heaters International, Inc. (Cincinnati, OH)
Inventors: Ganta S. Reddy (Cincinnati, OH), Jainagesh A. Sekhar (Cincinnati, OH)
Application Number: 11/870,591
International Classification: C22B 9/00 (20060101); C22B 21/00 (20060101);