CYANURIC ACID REMOVAL
A filter media component containing activated carbon, which undesirably filters chlorine from water in an aquatic reservoir in which a minimum level of chlorine is desired to be maintained, is inserted into a fluid pumping path for water from the reservoir to reduce levels of cyanuric acid without purging the reservoir. Once levels of cyanuric acid drop below a target reduced concentration, chlorine and other required chemicals may be added to the water to restore proper water balance and increase the chlorine concentration to at least the minimum level of chlorine desired to be maintained. The process, which can be completed in a short period of time with sufficient quantities of activated carbon, need only be performed seasonally of periodically and avoids waste and potential damage associated with purging and replacing the water within the aquatic reservoir to reduce cyanuric acid levels.
The present application incorporates by reference the subject matter of U.S. Provisional Patent Application No. 61/702,813 entitled “CYANURIC ACID REMOVAL PROCESS” and filed on Sep. 19, 2012.
TECHNICAL FIELDThe present application relates generally to removal of cyanuric acid from water in swimming pools, spas and other recreational aquatic vessels requiring the presence of free chlorine for disinfecting the water and, more specifically, to removal of cyanuric acid without purging the water from the aquatic vessel.
BACKGROUNDThere are numerous ongoing maintenance and repair requirements associated with swimming pool ownership. In order to keep a pool safe and sanitized, chemical treatment is required to maintain proper water balance, particularly in response to variables such as pool usage, precipitation and temperature. A swimming pool is chemically balanced when the disinfectant, pH, alkalinity, hardness and dissolved solids are at the desired levels.
Environmental factors (such as the intensity and duration of sunlight, bather loads, landscaping and vegetation) significantly affect the rate of chemical reactions within a pool and so maintenance chemicals must be added in different proportions under different circumstances and at different intervals. When the pool is chemically balanced, problems such as algae, mineral and salt saturation, corrosive water, staining, eye irritation and strong chlorine smell are less likely to occur. A regular testing and maintenance routine will result in a stable and more easily maintained pool.
The maintenance of proper chemical balance and the related upkeep and repair of swimming pool equipment, such as pumps, heaters, and filters, as well as safety equipment, create a non-discretionary demand for pool chemicals and other swimming pool supplies and services. The majority of swimming pool owners use chlorine to disinfect their pools. However, regardless of how well appropriate levels of chlorine are maintained, “shocking” is periodically required to break up the contaminants which invariably build up in the pool water. To accomplish this, the pool owner can either super-chlorinate the pool or use a non-chlorinated oxidizing compound.
Independent of super-chlorination, an undesirable accumulate of cyanuric acid is generally seen over time with the use of chlorine in any appreciable amount. Because the cyanuric acid does not dissipate, as does the chlorine, periodic purging of the water within the aquatic vessel is typically required, to eliminate accumulated cyanuric acid and other dissolved solids.
There is, therefore, a need in the art for improved water treatment of recreational aquatic vessels.
SUMMARYA filter media component containing activated carbon, which undesirably filters chlorine from water in an aquatic reservoir in which a minimum level of chlorine is desired to be maintained, is inserted into a fluid pumping path for water from the reservoir to reduce levels of cyanuric acid without purging the reservoir. Once levels of cyanuric acid drop below a target reduced concentration, chlorine and other required chemicals may be added to the water to restore proper water balance and increase the chlorine concentration to at least the minimum level of chlorine desired to be maintained. The process, which can be completed in a short period of time with sufficient quantities of activated carbon, need only be performed seasonally or periodically and avoids waste and potential damage associated with purging and replacing the water within the aquatic reservoir to reduce cyanuric acid levels.
For a more complete understanding of the present disclosure, and the advantages thereof, reference is now made to the following descriptions taken in conjunction with the accompanying drawings, wherein like numbers designate like objects, and in which:
Before undertaking the DETAILED DESCRIPTION below, it may be advantageous to set forth definitions of certain words or phrases used throughout this patent document: the terms “include” and “comprise,” as well as derivatives thereof, mean inclusion without limitation; the term “or” is inclusive, meaning and/or; the phrases “associated with” and “associated therewith,” as well as derivatives thereof, may mean to include, be included within, interconnect with, contain, be contained within, connect to or with, couple to or with, be communicable with, cooperate with, interleave, juxtapose, be proximate to, be bound to or with, have, have a property of, or the like; and the term “controller” means any hardware device that controls at least one operation, whether based upon firmware or user-supplied software executing within the controller. It should be noted that the functionality associated with any particular controller might be centralized or distributed, whether locally or remotely. Definitions for certain words and phrases are provided throughout this patent document, and those of ordinary skill in the art will understand that such definitions apply in many, if not most, instances to prior as well as future uses of such defined words and phrases. While some terms may include a wide variety of embodiments, the appended claims may expressly limit these terms to specific embodiments.
DETAILED DESCRIPTIONCyanuric acid (CYA) is marketed as a chlorine stabilizer for use in chlorinated swimming pools. Properly managed, cyanuric acid reduces the amount of chlorine needed to effectively sanitize an outdoor pool by preventing the sun's ultraviolet rays from breaking down the chlorine and rendering it ineffective. On long, sunny days, chlorine breaks down as quickly as the same day as the chlorine is added. However, the use of CYA-stabilized chlorine allows pool operators to add chlorine weekly instead of daily while still maintaining the minimum free chlorine required to effectively sanitize and disinfect pool water.
Between 80-85% of the 10 million residential pools in the United States use chlorine as the primary sanitizer, with nearly all using stabilized chlorine—that is, chlorine that is packaged and sold with cyanuric acid already combined. Dichlor and trichlor are examples of solid chlorine compounds that include CYA.
Introduced into the marketplace in 1958 for swimming pool application, dichlor and trichlor have become the most widely used pool sanitizers in the United States, with industry estimates putting market share at around 75 to 80% of all sanitizers sold. Dichlor usually comes in a granular form and is marketed for the residential swimming pool market, while trichlor is often sold in a tablet or stick form for use in an erosion feeder for small commercial pools, such as those at hotels and motels. Dichlor contains 57% cyanuric acid by weight; trichlor contains 54% cyanuric acid.
Cyanuric acid slows the disinfecting action of chlorine, so that the amount of time required to kill viruses, germs, and bacteria lengthens as the concentration of cyanuric acid increases. Although there is some debate about how much CYA is optimal, most experts agree that about 30-50 parts per million (ppm) offers the best balance and that pools reach the point of diminishing returns (where the reduction in chlorine effectiveness outweighs the benefits) at levels above about 50 ppm. CYA levels above 100 ppm create dangerous situations where disease can last for many hours or even days in the water before killed by free chlorine. A pool with too much CYA is said to be “over-stabilized.”
Unlike chlorine, cyanuric acid is never used up and accumulates in the pool. Once added to the pool water, the cyanuric acid will remain in the water. For each individual pool the build-up of CYA varies depending on a) the frequency in which stabilized chlorine is added and b) the frequency and volume of backwashing (build-up is slowed if the filtration system in use requires regular backwashing). For example, the build-up of cyanuric acid over a 26-week pool season is shown in the graph of
As noted above, as the level of cyanuric acid rises, free chlorine's ability to act as a disinfectant is weakened. At above 50 ppm of cyanuric acid, the time required to kill bacteria in the water is longer compared to swimming pool water without cyanuric acid unless more chlorine is added. As the level of chlorine required for effective sanitization increases in the over-stabilized pool, problems with skin and eye irritation also rise. Ultimately, cyanuric acid build up will lead to cloudiness, algae growth and, finally, unsanitary pool conditions. In addition, regulations applicable to commercial pools (including the Model Aquatic Health Code and various state and city codes) generally limit the permissible concentration of cyanuric acid to, for example, levels less than 100 ppm.
The only current option for operators to reduce CYA is to drain the pool and refill with fresh water. The purging can be seasonal or when the cyanuric acid concentration reaches a level where the pool operator begins to experience trouble maintaining water quality. Such draining is wasteful of natural resources, including water in many regions of the United States and other countries, and can negatively impact the environment with excessive amounts of waste water being released. In addition, draining pools (particularly large, commercial pools) can cause “float” due to hydrostatic pressure under the aquatic reservoir, weakening or even cracking the reservoir structure. Moreover, even after draining and refilling, some cyanuric acid will cling to the pool surface, plumbing and filtration system, so there will likely still be detectable to moderate levels of cyanuric acid in the newly added water. To remove 60 ppm of cyanuric acid from a 20,000-gallon swimming pool containing 80 ppm cyanuric acid, replacement of 75% of the pool volume (i.e., 15,000 gallons) with fresh water is required. Because CYA build-up occurs in nearly all chlorinated pools, this routine practice of purging results in many billions of gallons of water being unnecessarily poured into waste lines every year, as reflected by the chart of
The filter media within filter 309 may be changed to include a region of granular activated carbon (GAC) to perform the process in the present disclosure. Coconut shell-based activated carbon has the highest, most dense pore structure of various types of activated carbon currently commercially available, and therefore has exceptional adsorption properties and is particularly suitable for use in the processes of the present disclosure. Use of one-half pound of coconut shell activated carbon can be used to filter 2,000 gallons of water and can produce a 20 ppm reduction in cyanuric acid concentration in the first 30 minutes, and another 20 ppm reduction in the next 30 minutes, depending upon the initial chemical make-up of the water.
Other types of granular activated carbon may also be used, and all forms of activated carbon will generally filter disolved solids, including calcium, salt, fecal matter, organic or man-made materials, etc. A significant difference in performance exists, however, such that coconut shell activated carbon can filter 30% of cyanuric acid from water having 100 ppm concentration of that substance while (for example) bituminous coal activated carbon might only filter 10% in 3-4 hours or longer with the same initial concentration.
Activated carbon will undesirably filter free chlorine as well as cyanuric acid. Because free chlorine is desired at minimum concentrations within the water, use of activated carbon to filter and remove cyanuric acid is thus counter-intuitive. However, chlorine can be added back to the water after filtering, and less chlorine overall will be required than if the filtering to remove cyanuric acid had not been performed. Moreover, the filtering enables control over water chemistry, including pH (i.e., total alkalinity). The change in pool chemistry is effected without drainage and with fewer chemicals, at reduced operating costs.
Filtering with activated carbon to remove cyanuric acid may be performed twice per year, consistent with existing seasonal maintenance requirements already necessary, and may exploit existing equipment as discussed in detail herein. Using test currently available, the operator can determine when filtering has reduced cyanuric acid concentrations to levels below 30-50 ppm, which should be within 3-4 hours and will almost always take less than 24 hours of filtering, depending upon the amount of filtering material employed, flow rates, etc. Optionally, the filtering to remove cyanuric acid could be performed monthly, or as needed based on use of the aquatic facility and/or environmental conditions.
A separate container of activated carbon may be attached inline anywhere in the piping system on the suction or return side of the water pump 307. Thus, a bag of granular activated carbon may be placed in the skimmers 306, inside the existing filter media for filter 308, or over the main drains 302 for water to flow through that granular activated carbon. Cyanuric acid (as well as other chemicals and contaminants known or not known) is removed by the granular activated carbon through adsorption, generally a physical process where dissolved contaminants or impurities adhere to the pore structure on the surface of the carbon particles. Granular activated carbon can then be removed, regenerated and recycled for repeated use if desired. This is a key factor in activated carbon's usefulness in this process because it facilitates the recycling and/or reuse of the used carbon material.
This process may be performed by attaching a separate filter containing granular activated carbon to an existing operational water circulation system, or by filling porous bags with granular activated carbon and placing those bags over and/or in front of suction outlets (e.g., skimmer ports, drains, etc.) in the aquatic vessel (pool, spa or other water feature) in a manner that allows water to pass through the granular activated carbon to achieve the desired cyanuric acid removal. In some embodiments, the porous bags may take the shape of the structures in which those bags are being placed. For example, the bags could be appropriately shaped to substantially conform to a skimmer basket, thereby increasing the surface area of contact between the water and the granular activated carbon.
Granular activated carbon is substituted for (or at least used to supplement) the filter media in a conventional filter (sand, diatomaceous earth, paper cartridges, etc.). In one example, the granular activated carbon fills the conventional filter housing. In another, such as might be used in a diatomaceous earth filter, one or more of the existing grids within the filter are exchanged for granular activated carbon grid(s). A similar procedure may be employed for cartridge filters, whereby the standard cartridge is replaced for a short time with a granular activated carbon cartridge. Granular activated carbon may alternatively be added to existing water circulation systems by other means or in other ways.
The granular activated carbon containers should be monitored to ensure that the particles are filtering effectively. A granular activated carbon monitoring system should include: testing of treated water to ensure that the system is removing cyanuric acid and/or other chemicals and contaminants; head loss/reduced flow rate (the amount of friction created by plumbing and contactor walls as water moves from one point to another within the system) through the system to ensure that backwashing (reversing the flow to remove trapped material) is performed as required to ensure proper filtration. In general, as it relates to this process, the flow rate may be in the range of 10 to 120 gallons per minute (GPM).
Using a vessel or contactor containing 30 pounds of coconut shell GAC at a flow rate of 40 GPM should produce a cyanuric acid reduction of 10 ppm per hour per 3,500 gallons of water. When the desired level of cyanuric acid has been removed, the granular activated carbon filtration is ended and normal water filtration should resume. Since granular activated carbon also adsorbs chlorine and other chemicals normally used in aquatic facilities, bather water should be tested for free chlorine, alkalinity and pH upon completion of the cyanuric removal process. Based on test results, proper water balance based on industry standards should be immediately restored as needed.
A separate/independent circulation system (portable) may also be built using granular activated carbon as the filter media for mobile service applications.
In the present disclosure, a filter media component 416 may be selectively inserted into the interior of filter 309a, placed on top of the loose filter media 402.
The filter media component 416 is configured such that the media contained therein (activated carbon) spans the cross-section of the water flow path through the filter 309a. In the example shown, the configuration of the filter media component 416 is generally disk shaped, with a diameter allowing the filter media component 416 to extend across the entire interior cross-section of the filter 309a at a level equal to the top of the loose filter media 402. An opening 417 at the center of filter media component 416 fits snugly around the feed pipe to diffuser 407 when in place, and a slit 418 allows the filter media component 416 to be placed in such a position around the feed pipe. Although depicted for clarity in
Filter media component 416 is selectively removable from the interior of filter 309a, and may be placed in the position shown in
In the present disclosure, a filter media component 516 may be selectively inserted as each one of the grids 502 of filter 309b.
Similar to filter media component 416, filter media component 516 is selectively removable from the interior of filter 309b and may be installed in the position shown in
In the present disclosure, a filter media component 616 may be selectively inserted into the interior 603 within the fluid path between inlet 605 and outlet 611.
Similar to filter media components 416 and 516, filter media component 616 is selectively removable from the interior of filter 309c and may be installed in the position shown in
The pool system's pump(s) are then run and levels of cyanuric acid remaining are at least periodically tested (step 802). For example, an initial period of 1, 2 or 3 hours may be allowed to pass before first testing the amount of reduction of cyanuric acid. After that, if the reduction has not yet achieved the desired levels, checks may be made a 1, 4 or 6 hour increments, until the desired reduction is achieved. For as long as the cyanuric acid levels within the water remains above the desired levels discussed above, the pump(s) are run, GAC filter media components are replaced when necessary, and periodic checks of the remaining cyanuric acid levels are made.
Once the level of remaining cyanuric acid is established as having fallen below the desired maximum level (step 803), the GAC filter media components are replaced within conventional filter media components (step 804). In addition, the level of chlorine remaining is tested and additional chlorine is added until the desired level is achieved.
While each process flow and/or event sequence depicted in the figures and described herein involves a sequence of steps and/or events, occurring either in series or in tandem, unless explicitly stated or otherwise self-evident, no inference should be drawn regarding specific order of performance of steps or occurrence of events, performance of steps or portions thereof or occurrence of events serially rather than concurrently or in an overlapping manner, or performance the steps or occurrence of the events depicted exclusively without the occurrence of intervening or intermediate steps or events. Moreover, those skilled in the art will recognize that complete processes and event sequences are not illustrated or described. Instead, for simplicity and clarity, only so much of the respective processes and event sequences as is unique to the present disclosure or necessary for an understanding of the present disclosure is depicted and described.
While this disclosure has described certain embodiments and generally associated methods, alterations and permutations of these embodiments and methods will be apparent to those skilled in the art. Accordingly, the descriptions of example embodiments do not define or constrain this disclosure. Other changes, substitutions, and alterations are also possible without departing from the spirit and scope of this disclosure, as defined by the following claims.
Claims
1. A method, comprising:
- inserting a filter media component containing activated carbon in a fluid pumping system for an aquatic reservoir in which maintenance of a minimum level of chlorine is desired;
- pumping fluid from the aquatic reservoir through the activated carbon in the filter media component to reduce an amount of cyanuric acid within the fluid;
- removing the filter media component containing the activated carbon once a level of remaining cyanuric acid within the fluid falls below a desired concentration; and
- adding chlorine to the fluid to restore a level of chlorine in the fluid to at least the minimum level of chlorine desired.
2. The method according to claim 1, further comprising:
- placing the filter media component on top of loose filter media within a filter housing, between a diffuser and a lateral outlet assembly, the filter media component spanning a region between a supply line to the diffuser and interior surfaces of the filter housing.
3. The method according to claim 1, further comprising:
- connecting the activated carbon filter media component to a manifold sized to receive a diatomaceous earth filter media component, the activated carbon filter media spanning an outlet from a filter housing.
4. The method according to claim 1, further comprising:
- mounting an annulus formed by porous materials and filled with the activated carbon within a filter housing in a position spanning a fluid communication path between an inlet and an outlet for the filter housing at at least one point along the fluid communication path.
5. The method according to claim 1, further comprising:
- replacing the activated carbon filter media component with a traditional filter media component.
6. The method according to claim 1, further comprising:
- reducing both a level of chlorine in the fluid and a level of cyanuric acid within the fluid.
7. A system, comprising:
- a filter receptacle for a filter configured to filter water from an aquatic reservoir in which maintenance of a minimum level of chlorine is desired, the filter receptacle having an inlet configured to admit fluid into an interior space of the filter receptacle and an outlet configured to permit passage of fluid from the interior space; and
- a filter media component sized to fit within the filter receptacle and configured to span a fluid communication path within the interior space between the inlet and the outlet at at least one point along the fluid communication path, the filter media component containing activated carbon in a quantity sufficient to reduce levels of cyanuric acid within water from the aquatic reservoir.
8. The system according to claim 7, wherein the filter media component is configured to rest on top of loose filter media within the filter receptacle, between a diffuser and a lateral outlet assembly, and to span a region between a supply line to the diffuser and interior surfaces of the filter housing.
9. The system according to claim 7, wherein the activated carbon filter media component is configured to connect to a manifold sized to receive diatomaceous earth filter media component, and to span an outlet from the filter receptacle.
10. The system according to claim 7, wherein the filter media further comprises:
- an annulus formed by porous materials and filled with the activated carbon, the annulus configured to pass fluid from the inlet through a sidewall of the annulus and to pass fluid from a center conduit of the annulus to the outlet.
11. The system according to claim 7, wherein the filter media further comprises:
- an enclosure formed of a porous material and configured to contain the activated carbon in a body sized to span the fluid communication path between the inlet and the outlet at the at least one point.
12. The system according to claim 7, wherein the filter media further comprises:
- a rigid enclosure with openings and covered by a porous material, the rigid enclosure and the porous material collectively configured to contain the activated carbon in a body sized to span the fluid communication path between the inlet and the outlet at the at least one point.
13. A filter media component, comprising:
- a porous material forming an enclosure sized to fit within a filter receptacle and configured to span a fluid communication path within an interior space of a filter receptacle for a filter configured to filter water from an aquatic reservoir in which maintenance of a minimum level of chlorine is desired, the interior space in fluid communication with an inlet configured to admit fluid into the filter receptacle and an outlet configured to permit passage of fluid from the interior space; and
- a body of activated carbon within the enclosure in a quantity sufficient to reduce levels of cyanuric acid within water from the aquatic reservoir.
14. The filter media component according to claim 13, wherein the filter media component is configured to rest on top of loose filter media within the filter receptacle, between a diffuser and a lateral outlet assembly, and to span a region between a supply line to the diffuser and interior surfaces of the filter receptacle.
15. The filter media component according to claim 13, wherein the activated carbon filter media component is configured to connect to a manifold sized to receive diatomaceous earth filter media component, and to span an outlet from the filter receptacle.
16. The filter media component according to claim 13, wherein the filter media further comprises:
- an annulus formed by porous materials and filled with the activated, carbon, the annulus configured to pass fluid from the inlet through a sidewall of the annulus and to pass fluid from a center conduit of the annulus to the outlet.
17. The filter media component according to claim 13, wherein the filter media further comprises:
- an enclosure formed of a porous material and configured to contain the activated carbon in a body sized to span the fluid communication path between the inlet and the outlet at the at least one point.
18. The filter media component according to claim 13, wherein the filter media further comprises:
- a rigid enclosure with openings and covered by a porous material, the rigid enclosure and the porous material collectively configured to contain the activated carbon in a body sized to span the fluid communication path between the inlet and the outlet at the at least one point.
Type: Application
Filed: Sep 19, 2013
Publication Date: Mar 20, 2014
Applicant: AquaNovus, LLC (Dallas, TX)
Inventor: Kermit Lee Monzingo (Kaufman, TX)
Application Number: 14/031,769
International Classification: E04H 4/12 (20060101);