DEPILATORY COMPOSITIONS
A depilatory cream composition including a depilatory active, an emollient selected from at least one of mineral oil and emollient esters, and one or more of a talc and polyamide resin.
Latest RECKITT & COLMAN (OVERSEAS) LIMITED Patents:
This application is a continuation of U.S. Ser. No. 12/530,426, filed 30 Oct. 2009, which is a US National Stage of International Application No. PCT/GB2008/000731, filed 3 Mar. 2008, which claims the benefit of GB 0704599.0, filed 9 Mar. 2007, the entire contents and substance of which are hereby incorporated by reference.
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENTN/A
BACKGROUND OF THE INVENTION Field of the InventionThe present invention relates to a depilatory cream composition and its method of use. The present invention also relates to the use of silicone wax, polyamide resin and/or a mineral to improve the skin-feel of a depilatory cream composition.
BRIEF SUMMARY OF THE INVENTIONBriefly described, in a preferred form, the present invention comprises a depilatory cream with an improved skin-feel. In an exemplary embodiment, the depilatory cream composition comprises a depilatory active, an emollient selected from at least one of mineral oil and emollient esters, and one or more of a talc and polyamide resin. The composition can further comprise a humectant.
The polyamide resin can comprise a Nylon-12 resin. The composition can comprise 2 to 20 weight % of the depilatory active. The composition can comprise 1 to 10 weight % of the emollient.
In another exemplary embodiment, the depilatory cream composition comprises a depilatory active, an emollient comprising a mineral oil and an emollient ester, wherein the emollient is present at a concentration greater than about 5 weight %, a skin-feel enhancing agent comprising over 5 weight % of talc.
The emollient ester can comprise pentaerythrityl tetraisostearate.
The humectant can comprise glycerine. The composition can comprise 1 to 5 weight % of the skin-feel enhancing agent. The composition can comprise 2 to 20 weight % of the depilatory active. The emollient can be present at a concentration of about 7 weight %.
In another exemplary embodiment, the depilatory cream composition consists essentially of a depilatory active, an emollient comprising a mineral oil and an emollient ester, wherein the emollient is present at a concentration greater than about 5 weight % to about 10 weight %, and a skin-feel enhancing agent.
In another exemplary embodiment, the depilatory cream composition consists essentially of a depilatory active, an emollient comprising a mineral oil and an emollient ester, a skin feel enhancing agent comprising 5-10 weight % of talc, and a humectant.
In another exemplary embodiment, the depilatory cream composition comprises a depilatory active, an emollient selected from at least one of mineral oil and emollient esters, and a silicone wax, a talc and/or polyamide resin.
The polyamide resin can be a Nylon-12 resin. The silicone wax can be C30-C45 alkyl methicone.
In another exemplary embodiment, the composition comprises silicone wax, dimethicone, cyclopentasiloxane and dimethiconol. The emollient ester can comprise pentaerythrityl tetraisostearate.
The emollient can comprise at least two of mineral oil, silicone oil and emollient esters. The emollient can comprise a mineral oil, silicone oil and an emollient ester.
The depilatory cream composition can further comprise a humectant. The humectant can be glycerin.
The composition can comprise 1 to 5 weight % silicone wax, mineral and/or polyamide resin. The composition can comprise 2 to 20 weight % depilatory active. The composition can comprise 1 to 10 weight % emollient.
In another exemplary embedment of the present invention, a method of depilation can comprise applying a composition to the skin; allowing the composition a residence time on the skin in order to degrade the hairs on the skin's surface; at the end of the residence time removing the composition and depilated hairs form the skin; and rinsing the skin.
DETAIL DESCRIPTION OF THE INVENTIONTo facilitate an understanding of the principles and features of the various embodiments of the invention, various illustrative embodiments are explained below. Although exemplary embodiments of the invention are explained in detail, it is to be understood that other embodiments are contemplated. Accordingly, it is not intended that the invention is limited in its scope to the details of construction and arrangement of components set forth in the following description or illustrated in the drawings. The invention is capable of other embodiments and of being practiced or carried out in various ways. Also, in describing the exemplary embodiments, specific terminology will be resorted to for the sake of clarity.
It must also be noted that, as used in the specification and the appended claims, the singular forms “a,” “an” and “the” include plural references unless the context clearly dictates otherwise. For example, reference to a component is intended also to include composition of a plurality of components. References to a composition containing “a” constituent is intended to include other constituents in addition to the one named.
Also, in describing the exemplary embodiments, terminology will be resorted to for the sake of clarity. It is intended that each term contemplates its broadest meaning as understood by those skilled in the art and includes all technical equivalents which operate in a similar manner to accomplish a similar purpose.
Ranges may be expressed herein as from “about” or “approximately” or “substantially” one particular value and/or to “about” or “approximately” or “substantially” another particular value. When such a range is expressed, other exemplary embodiments include from the one particular value and/or to the other particular value.
Similarly, as used herein, “substantially free” of something, or “substantially pure”, and like characterizations, can include both being “at least substantially free” of something, or “at least substantially pure”, and being “completely free” of something, or “completely pure”.
By “comprising” or “containing” or “including” is meant that at least the named compound, element, particle, or method step is present in the composition or article or method, but does not exclude the presence of other compounds, materials, particles, method steps, even if the other such compounds, material, particles, method steps have the same function as what is named.
It is also to be understood that the mention of one or more method steps does not preclude the presence of additional method steps or intervening method steps between those steps expressly identified. Similarly, it is also to be understood that the mention of one or more components in a composition does not preclude the presence of additional components than those expressly identified.
The materials described as making up the various elements of the invention are intended to be illustrative and not restrictive. Many suitable materials that would perform the same or a similar function as the materials described herein are intended to be embraced within the scope of the invention. Such other materials not described herein can include, but are not limited to, for example, materials that are developed after the time of the development of the invention.
According to one aspect of the present invention there is provided a depilatory cream composition comprising a depilatory active, an emollient selected from at least one of mineral oil, silicone oil and emollient esters, and a silicone wax, talc and/or a polyamide resin.
According to another aspect of the present invention, there is provided the use of silicone wax, polyamide resin and/or talc to improve the skin-feel of a depilatory cream composition.
According to another aspect of the present invention, there is provided a method of depilation comprising applying a composition as defined above to the skin; allowing the composition a residence time on the skin in order to degrade hairs on the skin's surface; at the end of the residence time removing the composition and depilated hairs form the skin; and rinsing the skin.
It has been found that, by incorporating a skin-feel enhancing agent selected from at least one of silicone wax, talc and polyamide resin in the depilatory cream composition, the skin-feel of the composition is improved. In particular, the silicone wax, talc and/or a polyamide resin impart(s) a soft and velvety after-feel to the depilatory cream composition without affecting the composition's hair removal properties.
Talc is particularly preferred over other minerals which have previously been used in cosmetics as it confers a powdery after-feel which is desirable. In addition, it does not alter the color of the composition.
The depilatory cream composition may further include a humectant. Suitable humectants include polyols, such as glycerin, propylene glycol and butylene glycol. Glycerin is preferred. The humectant may be present in an amount of 0 to 10 weight %, preferably 0.5 to 5 weight %.
Preferably, the composition comprises talc.
The talc may be present in an amount of 0.1 to 10 weight %, preferably 0.2 to 5 weight %, more preferably 0.5 to 3 weight %. In one embodiment, the composition includes 1 to 2 weight % talc.
The composition may comprise a polyamide resin as an alternative or in addition to the mineral. The polyamide resin is preferably Nylon-12.
The polyamide resin, preferably Nylon-12, may be present in an amount of 0.1 to 10 weight %, preferably 0.5 to 5 weight %, more preferably 1 to 3 weight %, for example 2 weight %.
The composition may also comprise a silicone wax as an alternative or in addition to the mineral and/or polyamide resin. Suitable silicone waxes include C30-C45 alkyl methicone and a silicone wax formed from stearoxytrimethylsilane and stearyl alcohol. The silicone wax is preferably C30-C45 alkyl methicone.
Where a silicone wax is employed, the composition preferably includes a silicone oil to optimize the skin-feel properties of the composition. Preferably a silicone oil selected from dimethicone, cyclopentasiloxane and dimethiconol. In a preferred embodiment, the composition includes dimethicone, cyclopentasiloxane and dimethiconol in combination with a silicone wax (preferably C30-C45 alkyl methicone)
The silicone wax may be present in an amount of 0.1 to 10 weight %, preferably 0.5 to 5 weight %, more preferably 1 to 3 weight %, for example 1 to 2 weight %.
The emollient is selected from at least one of mineral oil, silicone and emollient esters. Together with the silicone wax, mineral and/or polyamide resin (and optional humectant), the emollient plays an important role in providing the depilatory cream composition with its desired skin-feel characteristics.
The emollient may be present in an amount of 1 to 10 weight %, preferably 3 to 7 weight % of the composition.
Mineral oil may be present in an amount of 0 to 10 weight %, preferably 0.5 to 5 weight % of the composition.
Silicone oil may be present in an amount of 0 to 10 weight %, preferably 0.5 to 5 weight %, for example 1 to 4 weight % of the composition.
Emollient esters may be present in an amount of 0 to 10 weight %, preferably 0.5 to 5 weight % of the composition, for example 1 to 3 weight %.
It is possible for the emollient to consist essentially of mineral oil. For example, in one embodiment, the composition includes talc and an emollient that consists essentially of mineral oil. In this embodiment, the emollient is present in an amount of 3 to 6 weight %, preferably 5 weight %. The talc is present in an amount of 0.3 to 1 weight %, preferably 0.5 weight %. Where an emollient consisting essentially of mineral oil emollient is employed, the composition preferably includes a humectant, such as glycerin.
It is also possible for the emollient to comprise or consist essentially of silicone oil(s). A combination of silicone oils can be present. The silicone oil may include at least one of cyclopentasiloxane, dimethiconol and dimethicone. Preferably, if used, the silicone oil comprises cyclopentasiloxane, dimethiconol and dimethicone. The silicone oil may include 0.1 to 5 weight %, preferably 1 to 2 weight % dimethicone; and/or 1 to 5 weight %, for example, 1 to 3 weight % cyclopentasiloxane and dimethiconol.
It is possible for the emollient to consist essentially of an emollient ester. However, the emollient ester is preferably used in combination with a mineral oil and/or a silicone oil.
In one embodiment, the emollient comprises at least two of mineral oil, silicone oil and emollient esters. For example, the emollient may include mineral oil and silicone oil, or mineral oil and emollient esters, or silicone oil and emollient esters. In one embodiment, the emollient includes mineral oil, silicone oil and emollient esters.
Many suitable silicone oils may be employed. Examples include cyclopentasiloxane, dimethiconol and dimethicone. In one embodiment, the silicone oil comprises cyclopentasiloxane and dimethiconol. In another embodiment, the silicone oil comprises dimethicone, cyclopentasiloxane and dimethiconol. The total amount of silicone oil in the composition may be 0.1 to 10 weight %, for example, 2 to 5 weight %. Where dimethicone is employed, the amount of dimethicone may range from 0.1 to 5 weight %, for example 1 to 2 weight %. Where cyclopentasiloxane and dimethiconol are employed, this combination may be present in an amount of 0.1 to 5 weight %, for example 1 to 3 weight %.
Many suitable emollient esters may be employed. Suitable examples include isopropyl palmitate, isopropyl myristate, myristyl lactate, cetyl esters, isotridecyl isononanoate, C12-15 alkyl benzoate, caprylic/capric triglyceride and pentaerythrityl tetraisostearate.
In one embodiment, the emollient comprises mineral oil, pentaerythrityl tetraisostearate, cyclopentasiloxane and dimethiconol. The mineral oil may be present in an amount of 3 to 6 weight %, preferably 5 weight %. The pentaerythrityl tetraisostearate may be present in an amount of 1 to 3 weight %, preferably 1 weight %. The cyclopentasiloxane and dimethiconol may be present in an amount of 1 to 3 weight %, preferably 1 weight %. In a preferred embodiment, this combination of emollients is used together with at least one of talc and polyamide resin.
The depilatory active is a compound capable of degrading keratin and may be, for example, a sulfur compound such as potassium thioglycolate, dithioetythritol, thioglycerol, thioglycol, thioxanthine, thipsalicylcic acid, N-acetyl-L-cysteine, lipic acid, NaHSO3, Li2S, Na2S, K2S, MgS, CaS, SrS, BaS, (NH4)2S, sodium dihydrolipoate 6, 8-dithiooctanoate, sodium 6,8-dithiooctanoate, salts of hydrogen sulphide for example NaSH or KSH, thioglycolic acid, thioglycerol, 2-mercaptopropionic acid, 3-mercaptropropionic acid, thiomalic acid, ammonium thioglycolate, glyceryl monothioglycolate, monoethanolamine thioglycolate, monoethanolamine, thioglycolic acid, diammonium dithiodiglycolate, ammonium thiolactate, monoethanolamine thiolactate, thioglycolamide, homo-cysteine, cysteine, glutathione, dithiothreitol, dihydrolipoic acid, 1,3-dithiopropanol, thioglycolamide, glycerylmonothioglycolate, thioglycolhydrazine, keratinase, hydrazine sulfate, hydrazine disulfate triisocyanate, guanidine thioglycolate, calcium thioglycolate and/or cysteamine. However, the composition is preferably substantially or, more preferably, is completely free from depilatory agents that destroy the thermodynamic equilibrium or the surface tension of the composition; examples of such agents include alkali metal sulfides.
Preferred depilatory compounds are thioglycolates, or their precursor thioglycolic acid. Most preferred is potassium thioglycolate, which may be produced by mixing thioglycolic acid with a neutralizing source of potassium hydroxide (as noted above excess potassium hydroxide over that required to effect neutralization cannot be used).
The depilatory active may be present in an amount of 2 to 25 weight %, preferably 5 to 20 weight %, more preferably 10 to 15 weight %. In one embodiment, the composition includes potassium thioglycolate in an amount of 2 to 25 weight %, preferably 5 to 20 weight %, more preferably 10 to 15 weight %.
The depilatory cream composition of the present invention preferably includes water. Water may be present in an amount of at least 40 weight %, preferably at least 50 weight %. Suitable amounts of water range from 40 to 70 weight %, preferably 50 to 65 weight %, more preferably 55 to 60 weight %.
The depilatory cream composition may include an oil. Suitable oils include sweet almond oil, iso-hexane, sunflower seed oil, apricot kernel oil and/or shea butter. Preferably, sweet almond oil is employed. The oil may form 0.01 to 5 weight %, more preferably 0.1 to 1 weight %, of the depilatory cream composition.
The depilatory cream composition may optionally include one or more surfactant(s). The surfactant may be anionic, cationic or non-ionic. It is preferably non-ionic. Examples of suitable surfactants include cetearyl phosphate, cetearyl alcohol, cetearyl glucoside, cetostearyl alcohol and/or ceteareth 20. It is preferably present in an amount of from 0.5 to 15 wt % relative to the weight of the depilatory cream composition, more preferably from 1 to 10 wt %.
The depilatory cream composition may optionally include a source of alkalinity. This may include hydroxides, such as hydroxides of alkali and alkaline earth metals. Suitable hydroxides include sodium hydroxide, potassium hydroxide, calcium hydroxide and magnesium hydroxide. Preferably, calcium hydroxide is employed, optionally together with potassium hydroxide. The source of alkalinity (e.g. calcium hydroxide) may be present in an amount of 0.1 to 10 weight %, preferably 1 to 6 weight %, for example 2 to 5 weight % of the depilatory cream composition.
The depilatory cream composition preferably has a pH of greater than 7, for example, 9 to 12.5.
Optionally, the composition includes an accelerator that will accelerate the hair removal reaction. Examples of such accelerators include urea, thiourea, dimethyl, isosorbide (DMI), ethoxydiglycol (Transcutol) or methyl propyl diol (MP diol). Preferably the accelerator is urea. The composition according to the invention preferably comprises from 5% to 15% wt, more preferably from 6 to 10 wt % of an accelerator (e.g. urea).
The depilatory cream composition may comprise other optional ingredients, such as perfumes, pigments and fillers, such as clays. Examples of suitable clays include sodium magnesium silicate, magnesium trisilicate and titanium dioxide. The inclusion of a clay, preferably sodium magnesium silicate, more preferably in an amount of from 0.1 to 10 wt % relative to the weight of the depilatory composition, most preferably from 0.1 to 1 wt %, is particularly advantageous, since this provides sodium and magnesium ions for the buffer system and improves the efficiency of depilation.
The depilatory cream composition desirably includes a chelating agent, such as sodium gluconate. The chelating agent may be present in an amount of less than 1 weight %, preferably 0.01 to 0.5 weight %, for example 0.05 to 0.1 weight %.
The depilatory cream composition may also include an additive that prevents phase separation. Suitable additives include polymers or copolymers of acrylic acid, for example, an acrylate copolymer. Such additives may be present in an amount of up to 2 weight %, preferably less than 1 weight %, more preferably less than 0.5 weight %, for example 0.1 to 0.4 weight %.
The depilatory cream composition may also include an malodor absorbent, such as spray dried silica. Such absorbents may be present in an amount of up to 2 weight %, preferably less than 1 weight %, more preferably less than 0.5 weight %, for example 0.001 to 0.1 weight %.
Optionally, additives such as aloe vera and Vitamin E may also be included in the composition. Such additives are employed in amounts of less than 1 weight %, for example, 0.1 to 0.5 weight % of the composition.
The depilatory cream composition may be made by first mixing components, such as the emollient and silicone wax, polyamide resin and/or talc, together to form a pre-mix. The pre-mix may be made at a temperature not exceeding 85° C., preferably in the range 65° C. to 80° C. The pre-mix may be actively or passively cooled. The depilatory compound may then be mixed with the pre-mix. The resulting mixture may be mixed at a temperature in the range 15° C. to 40° C.
In the method of depilation of the present invention the composition is allowed a residence time on the skin. Preferably the residence time is less than 10 minutes, more preferably not more than 6 minutes, even. Very suitably the residence time is 1 to 5 minutes, about 2 to 3 minutes being especially preferred.
It is found that using the composition of the present invention depilation after a residence time of only 3 minutes can be excellent, yet without significant skin irritation in subjects with normal skin.
The composition may be removed from the skin by many means, for example using a sponge, spatula or scraper device.
An advantage of the composition of the present invention is that it leaves the skin feeling soft and smooth. The composition of the present invention preferably also feels smooth and soft when applied to the skin.
The following Examples further illustrate the present invention.
Example 1
The ingredients labeled “a” were mixed together at a temperature of approximately 70° C. The mixture was then cooled and a pre-mix containing ingredients “b” was added at a temperature of approximately 50° C. The resulting mixture was agitated further and then cooled. A pre-mix of ingredients “c” was then added at a temperature of approximately 40° C., together with the potassium thioglycolate and potassium hydroxide.
Example 2
The ingredients labeled “a” were mixed together at a temperature of approximately 70° C. The mixture was then cooled and a pre-mix containing ingredients “b” was added at a temperature of approximately 50° C. The resulting mixture was agitated further and then cooled. A pre-mix of ingredients “c” was then added at a temperature of approximately 40° C., together with the potassium thioglycolate and potassium hydroxide.
Example 3
The ingredients labeled “a” were mixed together at a temperature of approximately 70° C. The mixture was then cooled and a pre-mix containing ingredients “b” was added at a temperature of approximately 50° C. The resulting mixture was agitated further and then cooled. A pre-mix of ingredients “c” was then added at a temperature of approximately 40° C., together with the potassium thioglycolate and potassium hydroxide.
Example 4
The ingredients labeled “a” were mixed together at a temperature of approximately 70° C. The mixture was then cooled and a pre-mix containing ingredients “b” was added at a temperature of approximately 50° C. The resulting mixture was agitated further and then cooled. A pre-mix of ingredients “c” was then added at a temperature of approximately 40° C., together with the potassium thioglycolate and potassium hydroxide.
Example 5
The ingredients labeled “a” were mixed together at a temperature of approximately 70° C. The mixture was then cooled and a pre-mix containing ingredients “b” was added at a temperature of approximately 50° C. The resulting mixture was agitated further and then cooled. A pre-mix of ingredients “c” was then added at a temperature of approximately 40° C., together with the potassium thioglycolate and potassium hydroxide.
While several variations of the present invention have been illustrated by way of example in preferred or particular embodiments, it is apparent that further embodiments could be developed within the spirit and scope of the present invention, or the inventive concept thereof. However, it is to be expressly understood that such modifications and adaptations are within the spirit and scope of the present invention, and are inclusive, but not limited to the following appended claims as set forth.
Claims
1. A depilatory cream composition comprising:
- a depilatory active;
- an emollient selected from at least one of mineral oil and emollient esters; and
- one or more of a talc and polyamide resin.
2. The composition of claim 1 further comprising a humectant.
3. The composition of claim 2, wherein the polyamide resin comprises a Nylon-12 resin.
4. The composition of claim 2 comprising 2 to 20 weight % of the depilatory active.
5. The composition of claim 2 comprising 1 to 10 weight % of the emollient.
6. A depilatory cream composition comprising:
- a depilatory active, an emollient comprising a mineral oil and an emollient ester, wherein the emollient is present at a concentration greater than about 5 weight %; and
- a skin-feel enhancing agent comprising over 5 weight % of talc.
7. The composition of claim 6, wherein the polyamide resin is a Nylon-12 resin; and
8. The composition of claim 6, wherein the emollient ester comprises pentaerythrityl tetraisostearate.
9. The composition of claim 6 further comprising a humectant.
10. The composition of claim 9, wherein the humectant is glycerine.
11. The composition of claim 6 comprising 1 to 5 weight % of the skin-feel enhancing agent.
12. The composition of claim 6 comprising 2 to 20 weight % of the depilatory active.
13. The composition of claim 6, wherein the emollient is present at a concentration of about 7 weight %.
14. A depilatory cream composition consisting essentially of:
- a depilatory active;
- an emollient comprising a mineral oil and an emollient ester, wherein the emollient is present at a concentration greater than about 5 weight % to about 10 weight %; and
- a skin-feel enhancing agent.
15. The composition of claim 14, wherein the skin-feel enhancing agent comprises polyamide resin.
16. The composition of claim 14, wherein the polyamide resin comprises a Nylon-12 resin.
17. The composition of claim 14, wherein the skin-feel enhancing agent comprises 5-10 weight % of talc.
18. The composition of claim 14, wherein the emollient ester comprises pentaerythrityl tetraisostearate.
19. A depilatory cream composition consisting essentially of:
- a depilatory active;
- an emollient comprising a mineral oil and an emollient ester;
- a skin feel enhancing agent comprising 5-10 weight % of talc; and
- a humectant.
20. The composition of claim 19, wherein the humectant is glycerine.
21. The composition of claim 19 comprising 2 to 20 weight % of the depilatory active, and wherein the emollient is present at a concentration of about 7 weight %.
Type: Application
Filed: Apr 14, 2014
Publication Date: Aug 7, 2014
Applicant: RECKITT & COLMAN (OVERSEAS) LIMITED (Slough)
Inventors: ANNE TINDAL (Hull), OUMOU MANGASSI (Hull)
Application Number: 14/251,880
International Classification: A61K 8/92 (20060101); A61K 8/88 (20060101); A61Q 9/04 (20060101);
