SPECTRALLY SELECTIVE COATINGS AND ASSOCIATED METHODS FOR MINIMIZING THE EFFECTS OF LIGHTNING STRIKES
A coating composition for reducing structural damage to a substrate resulting from interaction between the substrate and lightening plasma is disclosed. The coating composition includes a binder having a plurality of pigment particles that have a size distribution of a first portion of pigment particles that are relatively large compared to ultraviolet (UV) wavelengths from lightning plasma thereby backscattering UV energy, and a second portion of pigment particles that are relatively small compared to infrared (IR) wavelengths thereby forward scattering IR energy.
This application is a continuation of U.S. patent application Ser. No. 12/474,965 filed on May 29, 2009, the entirety of which is hereby incorporated by reference.
FIELDThe present patent application relates to coatings and methods for resisting plasma damage and degradation and, more particularly, to coatings and associated methods for imparting substrates with the ability to withstand lightning strikes and exposure to similar plasmas.
BACKGROUNDCarbon fiber reinforced plastic (“CFRP”) materials are increasingly being used in place of aluminum to form the skin panels and structural members of commercial airplanes. CFRP materials are advantageous compared to aluminum due to the higher strength-to-weight ratios provided by carbon composites. However, CFRP materials appear to be more susceptible to catastrophic damage from lightning strikes than aluminum materials.
Typical lightning strike related failures in CFRP materials appear to be driven by high temperatures. The carbon fibers in the composite materials become very hot when subjected to a lightning strike. The temperature may exceed the pyrolization temperature of the resin, turning the resin from a solid to a gas. The corresponding increase in internal gas pressure contributes to the damage to the structure by delaminating the layers and, possibly, puncturing the underlying systems or structure. The high temperatures can also cause permanent damage to the fibers, resulting in expansion of the fiber diameter. Localized heating in combination with material coefficient of thermal expansion also influences damage. Impact forces associated with lightning strike are acoustic, electromagnetic and pneumatic in origin. These forces can exceed material tensile strength limits at corresponding elevated temperatures.
Current solutions use electrical paths to effectively conduct and distribute the electrical current away from the lightning attachment zone in an effort to avoid sparking. These electrical paths are integrated into the CFRP material design, such as beneath an outer paint layer (e.g., a polyurethane layer). However, despite the use of well-designed electrical paths to conduct the electrical current, substantial structural damage is still being observed.
Accordingly, those skilled in the art continue to seek new techniques for avoiding structural damage resulting from lightning strikes.
SUMMARYIn one aspect, the disclosed coating composition is for reducing structural damage to a substrate resulting from interaction between the substrate and lightening plasma. The coating composition has a binder having a plurality of pigment particles that have a size distribution of a first portion of pigment particles that are relatively large compared to ultraviolet (UV) wavelengths from lightning plasma thereby backscattering UV energy, and a second portion of pigment particles that are relatively small compared to infrared (IR) wavelengths thereby forward scattering IR energy. In one embodiment, the first portion of pigment particles backscatter wavelengths from about 10 nm to 200 nm. In another embodiment, the first portion of pigment particles backscatter wavelengths below 500 nm.
In one aspect, the first portion of pigment particles and the second portion of pigment particles include substantially spherical pigment particles or substantially flat-shaped pigment particles.
In another aspect, the pigment particles of the plurality include a quarter wave stack including silicon dioxide defining a first sub-layer thickness and titanium dioxide defining a second sub-layer thickness. In one embodiment, the quarter wave stack includes a first material defining a first sub-layer thickness and a second material defining a second sub-layer thickness, where the first material has a different index of refraction as a function of the wavelength than the second material.
In another aspect, composites for reducing structural damage thereto resulting from lightening plasma are disclosed. The composite may have a substrate coated with a coating composition as described herein. The substrate is not inherently reflective of UV energy.
In one embodiment, the substrate includes carbon fibers. In another embodiment, the substrate includes a carbon nanotube reinforced polymer material.
The plurality of pigment particles may include niobium particles, silicon dioxide particles, titanium dioxide particles, or combinations thereof, and the binder may include polyurethane. In one embodiment, the first portion of pigment particles and the second portion of pigment particles include substantially spherical pigment particles or substantially flat-shaped pigment particles.
In another embodiment, the pigment particles of the plurality include a quarter wave stack including silicon dioxide defining a first sub-layer thickness and titanium dioxide defining a second sub-layer thickness.
Other aspects of the disclosed spectrally selective coatings and associated methods for minimizing the effects of lightning strikes will become apparent from the following description, the accompanying drawings and the appended claims.
Lightning has both direct and indirect effects on substrates. Specifically, it has now been discovered that radiative heating has a significant direct effect, in addition to other direct effects, such as electrical resistance heating, electromagnetic and acoustic forces and electrical sparking. Indirect effects include an intense electromagnetic pulse (EMP), bound charges and induced voltage exposure to wire bundles and avionics.
Typical lightning direct effects protection provides the substrate (e.g., the exterior structure of an aircraft) with the ability to withstand the initial and subsequent attachments of the lightning plasma at currents of up to 200,000 amperes without adverse consequence. Typical lightning direct effects protection may also assure that no sparking occurs at structural joints or on fuel and hydraulic couplings as the electrical current travels between the lightning attachment and exit points.
Pursuant to the present disclosure, lightning direct effects protection may also include protection from radiative heating between the lightning plasma (or any other destructive high temperature plasma) and the substrate. Specifically, in one aspect of the present disclosure, a substrate may be provided with a spectrally selective coating that is designed and fabricated to provide a high level of reflectivity of the incident ultraviolet (“UV”) energy radiated from the lightning plasma source. In another aspect, the spectrally selective coating may also be emissive in the infrared (“IR”) bands, thereby helping to dissipate the energy absorbed from the lightning plasma by re-radiating it back to the environment to minimize heat soaking into the substrate, which, as discussed above, may adversely affect the substrate.
As used herein, “substrate” broadly refers to any substrate capable of being damaged by a lightning strike or other damaging plasma. The substrate may be any substrate that is not inherently reflective of UV energy or a substrate that is in need of additional UV reflectivity. CFRP materials are only one example of appropriate substrates.
Lightning is believed to have a plasma temperature of about 28,000° K, perhaps ranging from about 25,000 to about 30,000° K. Therefore, referring to
Thus, in one aspect, the disclosed spectrally selective coating may be configured to reflect or backscatter the shorter wavelength (e.g., about 100 nm) incident UV energy from the lightning plasma. In another aspect, the disclosed spectrally selective coating may be configured to reflect or backscatter incident UV energy in the vacuum ultraviolet (“VUV”) regime (i.e., 200 nm to 10 nm). In yet another aspect, the disclosed spectrally selective coating may be configured to reflect or backscatter incident UV energy in the other UV regimes that affect lightning strike performance, including UVC (below 280 nm), UVB (320 nm-280 nm) and UVA (400 nm-320 nm). In yet another aspect, the disclosed spectrally selective coating may provide high reflectivity below 500 nm.
Similar analyses have shown the benefits of a higher IR emissivity after the lightning strike where the higher emissivity effectively re-radiates heat from the panel post-strike surface due to elevated surface temperatures compared to the surrounding environment, but at lower temperatures than the lightning plasma.
The foregoing establishes the benefits of controlling the substrate spectral absorptivity. In this case, if the UV absorptivity can be reduced to 0.1, the peak outer surface temperature is limited to 1,869° F. If the IR emissivity is maximized after the lightning strike the backside heat soak temperature is limited. Low UV absorptivity and high IR emissivity is possible by selectively tailoring the coating emissivity.
Thus, the coating spectral selectivity may be facilitated by the temperature regimes of the lightning plasma temperatures and subsequent surface temperatures which separate the peak energy spectral regimes from about 100 nm UV peak (based upon a source temperature of 2,897° K) to about 1 μm and above, where IR surface emissions are significant.
In one aspect, the disclosed spectrally selective coating may be designed and fabricated to be reflective in the UV wavelengths and emissive in the IR wavelengths by depositing particles upon the surface of the substrate which are relatively large compared to the UV wavelengths and relatively small compared to the IR wavelengths. UV reflectivity measurements, including VUV reflectivity measurements, are possible with special instruments available within the industry. In one example, these particles may be metallic (e.g., niobium particles). As another example, these particles may include SiO2 or TiO2, as well as combinations thereof.
The particles may be contained in a binder which may be transparent or semi-transparent to visual light. For example, the binder may be polyurethane. The interactions of the pigment, binder, environment and human visual response result in perceived brightness and color. These characteristics can also be broken down into directional and spectral quantification.
A phenomenon with metals exposed to the VUV spectral region where the UV energy propagates through the metals is referred to as the ultraviolet transparency of metals.
Two types of materials which remain transmissive at sub-micron wavelengths are silicone based polymers and fluoropolymers, although currently these are not transmissive in the VUV. Silicone based polymers have transparencies of 85 percent at 250 nm for a 60 micron thick film. In lieu of available VUV transmissive binder materials, the pigment may be mixed into a standard binder such as polyurethane. With properly tuned pigment/binder volumetric fractions the binder is expected to erode only to the depth of underlying pigment particles (including binder residue) with little to no degradation of the surface reflectivity.
At this point, those skilled in the art will appreciate that (1) the functional pigment particles may be bound to the upper surface of a substrate and contained on the upper surface of the substrate within a binder material, (2) the pigment particles may be contained within a binder material that is sufficiently transparent in the VUV, (3) the pigment particles may be contained within a binder material that is not (or substantially not) transparent in the VUV, and (4) combinations thereof.
In another aspect, the disclosed spectrally selective coating may also limit reflectivity in the IR, thereby functioning in a manner similar to a “cold mirror.” A cold mirror is a specialized dielectric mirror, a dichroic filter which reflects the visible light spectrum while efficiently transmitting IR wavelengths.
Typically, cold mirrors that are made for optical purposes are relatively small and expensive compared to coverage required for a composite panel coating and compared to the cost that would be allowable for a composite panel coating. The cold mirrors are produced by stacking layers of materials, which through optical properties and layer thicknesses result in constructive and destructive interference of the wavefront. Dichroic filters are not typically available for the wavelength associated with peak lightning strike radiant energy (i.e., about 100 nm).
One way of accomplishing the desired dichroic functionality of the coating is through the use of a distribution of surface particles that are relatively large compared to the UV wavelength and relatively small compared to the IR wavelengths. As shown in
According to MIE theory, depending upon particle optical properties, small wavelengths will backscatter and larger wavelengths will forward scatter. The particle materials may also be fabricated from multi-layer stacks where the materials are produced through various deposition processes, ground and sieved to produce the appropriate size distributions.
Aluminum is a common reflective material choice for space-based optical sensors designed to study solar VUV.
and the coating sub-layer thickness TTiO2 of TiO2 may be determined using Eq. 2 as follows:
wherein λpeak is the peak wavelength, nSiO2(λpeak) is the index of refraction of SiO2 as a function of the wavelength and nTiO2(λpeak) is the index of refraction of TiO2 as a function of the wavelength.
Those skilled in the art will appreciate that the aluminum layer may alternatively be positioned between layers of TiO2 and SiO2. Also, those skilled in the art will appreciate that metals other than aluminum may be used.
For example, when the peak wavelength is 100 nanometers, the composition and thicknesses of the layers of the pigment particle may be as shown in Table 1.
The total pigment thickness may be less than about 1.4 μm and may provide a net reflectivity of about 96 percent. The thickness of the layers in the stack may shorten by the real index of refraction component compared to in a vacuum.
Accordingly, the disclosed spectrally selective coatings provide a means of eliminating or reducing material and structural damage from extreme radiative heating due to lightning strike. Subsequent to the lightning strike, heat soak may be minimized by maximizing the thermal emissions in the IR band. Therefore, those skilled in the art will appreciate that the disclosed spectrally selective coatings may be used in conjunction with available electrical conductivity designs, including conductive adhesive binder materials, to minimize or prevent panel damage due to lightning strike.
Furthermore, those skilled in the art will appreciate that parametrics have shown that a spectral transition wavelength of about 0.5 μm with a high reflectivity, such as about 0.1 below about 0.5 μm, and a high emissivity, such as about 0.8 above about 0.5 μm, significantly reduces material temperatures during and after a lightning strike.
Still furthermore, those skilled in the art will appreciate that the selective reflectivity coating may be attained through the development of a coating comprising a distribution of particles sized to backscatter the UV energy, but to allow forward IR scattering into the coating. The forward IR scattering results in absorption. The coating will likewise provide high emissivity in the IR bands which will effectively radiate post lightning strike radiative energy to the surrounding environment. The high UV reflectivity may be attained through the use of quarter wave stack lay-ups over aluminum.
Although various aspects of the disclosed spectrally selective coatings and associated methods for minimizing the effects of lightning strikes have been shown and described, modifications may occur to those skilled in the art upon reading the specification. The present application includes such modifications and is limited only by the scope of the claims.
Claims
1. A coating composition for reducing structural damage to a substrate resulting from interaction between the substrate and lightening plasma comprising:
- a binder having a plurality of pigment particles;
- wherein the plurality of pigment particles has a size distribution comprising a first portion of pigment particles that are relatively large compared to ultraviolet (UV) wavelengths from lightning plasma thereby backscattering UV energy, and a second portion of pigment particles that are relatively small compared to infrared (IR) wavelengths thereby forward scattering IR energy.
2. The coating composition of claim 1 wherein the first portion of pigment particles backscatter wavelengths from about 10 nm to 200 nm.
3. The coating composition of claim 1 wherein the first portion of pigment particles backscatter wavelengths below 500 nm.
4. The coating composition of claim 1 wherein the first portion of pigment particles and the second portion of pigment particles include substantially spherical pigment particles or substantially flat-shaped pigment particles.
5. The coating composition of claim 1 wherein the pigment particles of the plurality include a quarter wave stack including silicon dioxide defining a first sub-layer thickness and titanium dioxide defining a second sub-layer thickness.
6. The coating composition of claim 1 wherein the pigment particles of the plurality include a quarter wave stack including a first material defining a first sub-layer thickness and a second material defining a second sub-layer thickness, wherein the first material has a different index of refraction as a function of the wavelength than the second material.
7. The coating composition of claim 6 wherein the quarter wave stack is received over a layer of aluminum.
8. The coating composition of claim 7 wherein the layer of aluminum is at most about 1 μm thick and the total thickness of the spectrally selective coating, including the layer of aluminum, is less than about 1.4 μm.
9. The coating composition of claim 1 wherein the binder comprises one or more of a material that is transparent or semitransparent to visible light, and a material sufficiently transparent in the vacuum ultraviolet range.
10. A composite for reducing structural damage thereto resulting from lightening plasma comprising:
- a substrate coated with a coating composition comprising:
- a binder having a plurality of pigment particles;
- wherein the plurality of pigment particles has a size distribution comprising a first portion of pigment particles that are relatively large compared to ultraviolet (UV) wavelengths from lightning plasma thereby backscattering UV energy, and a second portion of pigment particles that are relatively small compared to infrared (IR) wavelengths thereby forward scattering IR energy.
11. The composite of claim 10 wherein the substrate is not inherently reflective of UV energy.
12. The composite of claim 10 wherein the substrate include carbon fibers.
13. The composite of claim 10 wherein the substrate includes a carbon nanotube reinforced polymer material.
14. The composite of claim 10 wherein the plurality of pigment particles includes niobium particles, silicon dioxide particles, titanium dioxide particles, or combinations thereof.
15. The composite of claim 10 wherein the binder includes polyurethane.
16. The composite of claim 10 wherein the first portion of pigment particles and the second portion of pigment particles include substantially spherical pigment particles or substantially flat-shaped pigment particles.
17. The composite of claim 10 wherein the first portion of pigment particles and the second portion of pigment particles include substantially spherical pigment particles.
18. The composite of claim 10 wherein the first portion of pigment particles and the second portion of pigment particles include substantially flat-shaped pigment particles.
19. The composite of claim 10 wherein the pigment particles of the plurality include a quarter wave stack including silicon dioxide defining a first sub-layer thickness and titanium dioxide defining a second sub-layer thickness.
20. The composite of claim 10 wherein the pigment particles of the plurality include a quarter wave stack including a first material defining a first sub-layer thickness and a second material defining a second sub-layer thickness, wherein the first material has a different index of refraction as a function of the wavelength than the second material.
21. The coating composition of claim 20 wherein the quarter wave stack is received over a layer of aluminum.
Type: Application
Filed: Dec 1, 2014
Publication Date: Mar 26, 2015
Inventor: Michael M. Ladd (Renton, WA)
Application Number: 14/556,559
International Classification: C09D 5/33 (20060101);