SAP COATING LAYER FOR CABLE COMPONENT AND RELATED SYSTEMS AND METHODS
A process and system for making a water resistant cable component and water resistant cable components are provided. The water resistant cable includes a cable body including an inner surface defining a channel within the cable body and an elongate cable component located within the channel of the cable body. The cable also includes a contiguous layer of crosslinked super absorbent polymer surrounding the elongate cable component. The layer of crosslinked super absorbent polymer is formed by applying a liquid layer including a carrier material and an uncrosslinked super absorbent polymer pre-polymer material onto an outer surface of a component of the cable and then by crosslinking the super absorbent polymer pre-polymer while on the cable component to form a layer of crosslinked super absorbent polymer surrounding the cable component.
This application is a divisional of U.S. patent application Ser. No. 15/709,844, filed Sep. 20, 2017, which is a continuation of International Application No. PCT/US16/20188, filed Mar. 1, 2016, which claims the benefit of priority to U.S. Application Ser. No. 62/139,929, filed Mar. 30, 2015, the contents of which are relied upon and incorporated herein by reference in their entirety.
BACKGROUNDThe disclosure relates generally to cables and more particularly to cables, such as optical communication cables, that include a crosslinked layer, film or coating of a super absorbent polymer material surrounding one or more cable components. Cables, including optical communication cables, have seen increased use in a wide variety of electronics and telecommunications fields. Optical communication cables contain or surround one or more optical fibers, and other non-optical cables typically including a conducting element (e.g., a copper wire) that acts as a transmission element. The cable provides structure and protection for the optical fibers wires within the cable.
SUMMARYOne embodiment of the disclosure relates to a method of manufacturing an optical fiber component. The method includes applying a liquid layer including a carrier material and an uncrosslinked super absorbent polymer pre-polymer material onto an outer surface of an optical fiber cable component. The method includes crosslinking the super absorbent polymer pre-polymer while on the optical fiber cable component to form a layer of crosslinked super absorbent polymer surrounding the optical fiber cable component. The method includes forming a polymer structure around the optical fiber component following formation of the layer of crosslinked super absorbent polymer.
An additional embodiment of the disclosure relates to an optical cable. The optical cable includes a cable body including an inner surface defining a channel within the cable body. The cable includes a plurality of tubes located in the channel of the cable body, wherein each of the plurality of tubes includes an outer surface, an inner surface and a channel defined by the inner surface of the tube. The cable includes a plurality of optical fibers located within the channel of each tube. Each optical fiber includes an optical core, cladding of a different refractive index than the optical core surrounding the core and a polymer coating layer surrounding the cladding. Each optical fiber also includes a contiguous layer of crosslinked super absorbent polymer surrounding the polymer coating layer. The contiguous layer of crosslinked super absorbent polymer is contiguous both circumferentially around the optical fiber and axially along the optical fiber for at least a length of 1 cm.
An additional embodiment of the disclosure relates to an optical fiber cable component. The optical fiber cable component includes an optical fiber having an optical core and a cladding layer of a different refractive index than the optical core surrounding the core. The optical fiber cable component includes an outer polymer layer located outside of and surrounding the optical fiber. The optical fiber cable component includes a contiguous layer of crosslinked super absorbent polymer surrounding the outer polymer layer. The contiguous layer of crosslinked super absorbent polymer is contiguous circumferentially around the optical fiber and contiguous axially along the optical fiber for at least a length of 1 cm.
An additional embodiment of the disclosure relates to a water resistant cable. The cable includes a cable body including an inner surface defining a channel within the cable body. The cable includes an elongate cable component located within the channel of the cable body. The cable includes a contiguous layer of crosslinked super absorbent polymer surrounding the elongate cable component. The contiguous layer of crosslinked super absorbent polymer is contiguous circumferentially around the elongate cable component and contiguous axially along the length of the elongate cable component for at least a length of 1 cm.
Additional features and advantages will be set forth in the detailed description which follows, and in part will be readily apparent to those skilled in the art from the description or recognized by practicing the embodiments as described in the written description and claims hereof, as well as the appended drawings.
It is to be understood that both the foregoing general description and the following detailed description are merely exemplary, and are intended to provide an overview or framework to understand the nature and character of the claims.
The accompanying drawings are included to provide a further understanding and are incorporated in and constitute a part of this specification. The drawings illustrate one or more embodiment(s), and together with the description serve to explain principles and operation of the various embodiments.
Referring generally to the figures, various embodiments of a cable (e.g., a fiber optic cable, an optical fiber cable, a communication cable, an electrical conductor cable, etc.) are shown. In general, in the various cable embodiments disclosed herein, one or more cable component is coated or surrounded by a crosslinked super absorbent polymer (SAP) material. In various embodiments, the super absorbent polymer material forms a contiguous, continuous and relatively thin layer or film of super absorbent polymer material that surrounds one or more component of the cable. In various embodiments, the SAP coated cable components may be elongate cable components such as optical fibers, optical fiber buffer tubes, optical fiber ribbons, and/or electrical conductor wires.
In general, the systems, processes and related cable components relate to cable components that include the water blocking/absorbing functionality of the SAP material. However, in contrast to cable arrangements that utilize SAP powders or particles, the SAP coated components discussed herein may provide for even distribution of SAP along the length of the cable component, and this even distribution may result in a reduction or elimination of particle-based bend attenuation that may be experienced by optical fibers within a cable utilizing SAP particles for water blocking. In addition, because the SAP coating layer discussed herein surrounds the cable components, the SAP material of the presented disclosure tends to remain substantially fixed relative to the coated cable component even as the cable is wound, unwound and deployed in the installation environment.
In addition, in various embodiments, the SAP coating layer provides a relatively thin but consistent thickness of SAP material distributed along the length of the coated cable component. It is believed that the thin, evenly distributed SAP coating disclosed herein allows the cable component to hold enough SAP material to provide satisfactory water blocking capabilities while at the same time allowing for a the cable component to have a smaller overall cross-sectional area as compared to cables that use a particulate SAP water blocking material.
The present disclosure also relates to a system and method for forming an SAP coated cable component. In various embodiments, a cable component is provided, and an application device applies a liquid material including an uncrosslinked SAP pre-polymer material on the outer surface of the cable component. Following application, the SAP pre-polymer material is crosslinked or cured while on the outer surface of the cable component forming a relatively thin and continuous SAP layer or film around the cable component. In this manner the present disclosure provides a system and process for forming an SAP coated cable component in a continuous process suitable for integration with cable formation systems. For example, in various embodiments, the continuous SAP layer is formed around one or more optical fiber, and then following SAP layer formation, a buffer tube is extruded around the one or more SAP coated fibers. In other embodiments, the continuous SAP layer may be formed on the outer surface of a wide range of cable components including optical fiber buffer tubes, optical fiber ribbons, armor layers, strength members, electrical conductors, etc.
In various non-limiting embodiments the SAP comprises polyacrylate and polyacrylamide polymers and copolymers; polyacrylic acid; polyacrylic acid ammonium and/or alkali salts where the alkali comprises salts Li, Na or K; maleic anhydride (acid) copolymers and their ammonium and/or alkali salts where the alkali comprises salts Li, Na or K; carboxymethylcellulose and its ammonium and/or alkali salts where the alkali comprises salts Li, Na or K; polyvinyl alcohol polymers and copolymers and polyethylene oxide polymers and copolymers.
Referring to
In the embodiment shown in
In the embodiment shown, buffer tubes 20 are shown in a helical stranding pattern, such as an SZ stranding pattern, around central strength member 22. In some embodiments, one or more intermediate layer, shown as layer 24, surrounds buffer tubes 20. In some embodiments, layer 24 may be a thin-film, extruded sheath that holds buffer tubes 20 in position around strength member 22. In various embodiments, cable 10 may include a reinforcement sheet or layer, such as a corrugated armor layer, between layer 24 and jacket 12, and in such embodiments, the armor layer generally provides an additional layer of protection to optical fibers 18 within cable 10, and may provide resistance against damage (e.g., damage caused by contact or compression during installation, damage from the elements, damage from rodents, etc.). In some embodiments, designed for indoor applications, cable 10 may include a variety of fire resistant components, such as fire resistant materials embedded in jacket 12 and/or fire resistant intumescent particles located within channel 16.
Referring to
As noted above, in various embodiments, one or more cable component may be coated or covered within a continuous crosslinked or layer of SAP polymer material. In various embodiments, any of the cable components of cable 10 may be coated with an SAP coating as discussed herein. In general, the SAP materials discussed herein are polymeric materials that swell and absorb water. In this manner the SAP coatings discussed herein limit water propagation within cable 10 by swelling and absorbing water. Thus, the SAP coating layers discussed herein are different from many other polymer layers and materials typically found in cable constructions (e.g., acrylate polymer layers surrounding optical fiber cores, ribbon bodies, buffer tubes, cable jackets, etc.). As will be noticed in
Referring to
Referring to
In the embodiment shown SAP layer 40 has a thickness shown as T1. In various embodiments, T1 graphically represents a maximum thickness of SAP layer 40 (also referred to herein as T1max), and in some embodiments, T1 graphically represents an average thickness of SAP layer 40 along the length of the fiber (also referred to herein as T1ave). In various embodiments, T1max and/or T1ave is less than the average diameter of the typical SAP particles used in optical cables. In various embodiments, T1max and/or T1ave is less than 200 micrometers. In various embodiments, T1max and/or T1ave is less than 60 micrometers and more specifically is less than or equal to 50 micrometers. In addition, because SAP layer 40 is substantially contiguous, in some embodiments layer 40 has a minimum thickness greater than or equal to 1 micrometer.
In some embodiments, in addition to having a relatively low maximum thickness, SAP layer 40 also has a relatively even or consistent thickness in the circumferential direction and/or in the axial direction, as compared to cables that use SAP particles for water blocking. For example, in some such embodiments, T1ave is greater than or equal to 1 micrometer and less than or equal to 200 micrometers. In other embodiments, T1ave is greater than or equal to 1 micrometer and less than or equal to 50 micrometers (i.e., 1 micrometers≤T1ave≤50 micrometers). In another exemplary embodiment, T1ave is greater than or equal to 1 micrometer and less than or equal to 30 micrometers (i.e., 1 micrometers≤T1ave≤30 micrometers). In various embodiments, the average thickness of layer 40 is relatively small as compared to the size of optical fiber 18. In various embodiments, the average thickness of SAP layer 40, T1ave, is between 0.2% and 30% of FD, and in other embodiments, T1ave is between 1% and 20% of FD.
Referring back to
In various embodiments in which buffer tube 20 contains optical fiber ribbons instead of or in addition optical fibers 18, BID is between 1 millimeters and 7 millimeters. Each tube surrounding the optical fibers or optical fiber ribbons the has an inner diameter, BID, thus having an inner cross-sectional area, BID1XC, and the total cross-sectional area of the crosslinked super absorbent polymer inside the tube (that is all of the SAP coated on all of the fibers or fiber components inside the tube) is a1total. In various embodiments, the cross-sectional area percent of the SAP inside the tube relative to the tube inner diameter cross-sectional area is 0.01%≤100% (a1total/BID1XC)≤10% and, in various other embodiments, is 0.2%≤100% (a1total/BID1XC)≤10%. It should be noted that a1total is the cross-sectional area of the crosslinked super absorbent polymer inside the buffer tube prior to the swelling that occurs in the presence of water.
In some buffer tube designs that utilize SAP particles within the buffer tube, optical attenuation of optical fibers can occur because of microbending experienced by the optical fiber at the point of contact between the optical fiber and the relatively large and discreet SAP particles. However it is believed that, in various embodiments discussed herein, the even distribution of SAP provided by layer 40 decreases/eliminates the microbending common with SAP particle water blocking arrangements, and correspondingly, decreases or reduces the optical attenuation associated with microbending in the presence of SAP particles. Further, in various embodiments, the SAP layer 40 on the outer surface of fiber 18 acts to limit sticking, friction or adhesion between the SAP coated optical fiber and adjacent cable components. In such embodiments, the SAP layer 40 results in the coated optical fiber having a lower pull-out force (i.e., the force required to withdraw one of the optical fibers out of its buffer tube) as compared to a buffer tube filled with optical fibers without SAP layer 40.
As shown in
In various embodiments, optical fiber 18 may include a colored outer portion. For example, outer polymer layer 46 may be formed from a colored material or may include colored indicia along its outer surface. In such embodiments, layer 40 is formed from a transparent or translucent SAP material such that the colored portion of optical fiber 18 is visible through layer 40. In various embodiments, layer 40 has a transmittance through the contiguous layer of crosslinked super absorbent polymer at least one wavelength between 400-700 nm that is between 0.2 and 1.
Referring back to
In
In the embodiment shown, SAP coating system 104 includes applicator 106, a heater 108 and curing station 110. In general, applicator 106 is configured to deposit a liquid material 112 that includes uncrosslinked SAP pre-polymer material onto the outer surface of fiber 18 as fiber 18 moves through applicator 106. The liquid material 112 includes a carrier material or solvent in which the SAP pre-polymer material is suspended or dissolved. In a specific exemplary embodiment, liquid material 112 is an aqueous solution of SAP pre-polymer material and the carrier material is water. In various embodiments, applicator 106 may be a variety of application systems suitable for application of the SAP pre-polymer liquid, including roll coaters, spray coaters, bath coaters, dip coaters, printing systems, ink-jet printing systems, sponge applicators, etc., such that liquid material 112 coats the entire circumference of fiber 18. In various embodiments, applicator 106 can apply a continuous layer of liquid 112 to form a substantial continuous SAP layer axially along fiber 18. In another embodiment, applicator 106 can apply intermittent bands of liquid 112 to form bands of SAP material interrupted by uncoated sections of fiber.
In an exemplary embodiment, after liquid SAP material 112 has been applied to fiber 18, coated fiber 18 passes through heater 108. Heater 108 causes the carrier material (e.g., water) of liquid material 112 to evaporate leaving a coating of dried SAP pre-polymer material 114 surrounding fiber 18. Because liquid material 112 coated the entire circumference of fiber 18, dried SAP pre-polymer material 114 also coats and surrounds the entire outer surface of fiber 18.
Following drying, fiber 18 coated with dried SAP pre-polymer material 114 passes through curing station 110. In general, curing station 110 causes the SAP pre-polymer to crosslink with each other to form an SAP material layer, such as SAP layer 40 discussed above, surrounding fiber 18. Curing station 110 may be any curing system suitable for causing crosslinking of the SAP pre-polymer material present on fiber 18. In various embodiments, curing station 110 may generate UV radiation or heat to crosslink the SAP pre-polymer material.
In general, following formation of the SAP layer on the cable component, an exterior polymer layer or polymer tube is formed around the SAP coated cable component. In the embodiment of
Further, as shown in
It should be understood that while
Specifically,
To produce a cable, such as cable 10, buffer tubes 20 are unwound from reels 120 and are advanced through SAP coating systems 104. SAP coating systems 104 form an SAP coating layer, such as layer 48, around each buffer tube 20, in the same manner discussed above regarding
Following formation of the SAP layer, SAP coated buffer tubes 20 move into stranding station 124. Stranding station 124 couples buffer tubes 20 together along with any filler tubes and central strength element 22. In one embodiment, buffer tubes 20 and any filler tubes are coupled around strength element 22 in a pattern 126, such as a helical pattern or in a reversing helical pattern, such as an SZ stranding pattern. Similar to the system described in
Referring to
Various embodiments of this disclosure also relate to methods or processes for forming SAP coated cable components as discussed herein. In specific embodiments, the coating methods include a method of manufacturing an optical fiber component. In such embodiments, the method includes applying a liquid layer including a carrier material and an uncrosslinked super absorbent polymer pre-polymer material onto an outer surface of an optical fiber cable component. The method includes crosslinking the super absorbent polymer pre-polymer while on the optical fiber cable component to form a layer of crosslinked super absorbent polymer surrounding the optical fiber cable component, and the method includes forming a polymer structure around the optical fiber component following formation of the layer of crosslinked super absorbent polymer around the optical fiber cable component. In various embodiments, such methods form SAP coated cable components such as optical fibers 18, buffer tubes 20, and ribbons 144 as discussed herein. In addition, in various embodiments, such methods may be performed utilizing SAP coating systems discussed herein, such as coating system 104.
In various embodiments, the buffer tubes discussed herein may be formed from a variety of extruded polymer materials including polypropylene, polyethylene, polycarbonate material, polybutylene terephthalate (PBT), polyamide (PA), polyoxymethylene (POM), poly(ethene-co-tetrafluoroethene) (ETFE), or combinations of any of the polymer materials discussed herein, etc. In various embodiments, cable jacket 12 may be a made from a wide variety of materials used in cable manufacturing such as medium density polyethylene, polyvinyl chloride (PVC), polyvinylidene difluoride (PVDF), nylon, polyester or polycarbonate and their copolymers. In addition, the material of cable jacket 12 may include small quantities of other materials or fillers that provide different properties to the material of cable jacket 12. For example, the material of cable jacket 12 may include materials that provide for coloring, UV/light blocking (e.g., carbon black), burn resistance, etc.
The optical fibers discussed herein may be flexible, transparent optical fibers made of glass or plastic. The fibers may function as a waveguide to transmit light between the two ends of the optical fiber. Optical fibers may include a transparent core surrounded by a transparent cladding material with a lower index of refraction. Light may be kept in the core by total internal reflection. Glass optical fibers may comprise silica, but some other materials such as fluorozirconate, fluoroaluminate, and chalcogenide glasses, as well as crystalline materials, such as sapphire, may be used. The light may be guided down the core of the optical fibers by an optical cladding with a lower refractive index that traps light in the core through total internal reflection. The cladding may be coated by a buffer and/or another coating(s) that protects it from moisture and/or physical damage. These coatings may be UV-cured urethane acrylate composite materials applied to the outside of the optical fiber during the drawing process. The coatings may protect the strands of glass fiber.
While the specific cable embodiments discussed herein and shown in the figures relate primarily to cables and core elements that have a substantially circular cross-sectional shape defining substantially cylindrical internal lumens, in other embodiments, the cables and core elements discussed herein may have any number of cross-section shapes. For example, in various embodiments, the cable jacket and/or buffer tubes may have a square, rectangular, triangular or other polygonal cross-sectional shape. In such embodiments, the passage or lumen of the cable or buffer tube may be the same shape or different shape than the shape of the cable jacket and/or buffer tubes. In some embodiments, the cable jacket and/or buffer tubes may define more than one channel or passage. In such embodiments, the multiple channels may be of the same size and shape as each other or may each have different sizes or shapes.
In accordance with yet other embodiments of the present disclosure, the SAP coating system and methods described herein may be used in micromodule cables. Micromodule cables are cables comprising one or more micromodule subunits, each micromodule subunit comprising an extremely flexible tube surrounding one or more optical fibers, typically twelve optical fibers. The extreme flexibility of the tube of a micromodule subunit may derive from using a sheath material comprising inorganic fillers such as, for example, ethylene vinyl acetate (EVA) copolymers or linear low density polyethylene (LLDPE). An inner diameter of the flexible tube of the micromodule subunit may be so small that during extrusion the fibers are partly surrounded by the sheath material. The fibers and/or the flexible tubes of the micromodule subunits may comprise an SAP coating in accordance with aspects of the present disclosure, resulting in a dry, water-blocked micromodule.
Unless otherwise expressly stated, it is in no way intended that any method set forth herein be construed as requiring that its steps be performed in a specific order. Accordingly, where a method claim does not actually recite an order to be followed by its steps or it is not otherwise specifically stated in the claims or descriptions that the steps are to be limited to a specific order, it is in no way intended that any particular order be inferred. In addition, as used herein the article “a” is intended to include one or more than one component or element, and is not intended to be construed as meaning only one.
It will be apparent to those skilled in the art that various modifications and variations can be made without departing from the spirit or scope of the disclosed embodiments. Since modifications, combinations, sub-combinations and variations of the disclosed embodiments incorporating the spirit and substance of the embodiments may occur to persons skilled in the art, the disclosed embodiments should be construed to include everything within the scope of the appended claims and their equivalents.
Claims
1. An optical cable comprising:
- a cable body including an inner surface defining a channel within the cable body; and
- a plurality of tubes located in the channel of the cable body, wherein each of the plurality of tubes includes an outer surface, an inner surface and a channel defined by the inner surface of the tube; and
- a plurality of optical fibers located within the channel of each tube, wherein each optical fiber comprises:
- an optical core;
- cladding of a different refractive index than the optical core surrounding the core;
- a polymer coating layer surrounding the cladding; and
- a contiguous layer of crosslinked super absorbent polymer surrounding the polymer coating layer, wherein the contiguous layer of crosslinked super absorbent polymer is contiguous both circumferentially around the optical fiber and axially along the optical fiber for at least a length of 1 cm.
2. The optical cable of claim 1 wherein the contiguous layer of crosslinked super absorbent polymer has a maximum thickness less than 200 micrometers.
3. The optical cable of claim 1 wherein the contiguous layer of crosslinked super absorbent polymer has a maximum thickness less than 60 micrometers.
4. The optical cable of claim 1 wherein the contiguous layer of crosslinked super absorbent polymer has a maximum thickness less than 60 micrometers and an average thickness, T1ave, in micrometers of 1≤T1ave≤50.
5. The optical cable of claim 1 wherein the mass, m1, of the crosslinked super absorbent polymer in the contiguous layer of each optical fiber in milligrams per meter length of the optical fiber is 1≤m1≤200.
6. The optical cable of claim 1 wherein the mass, m1, of the crosslinked super absorbent polymer in the contiguous layer of each optical fiber in milligrams per meter length of the optical fiber is 1≤m1≤60.
7. The article of claim 1 wherein the channel of each tube has an inner diameter, BID, and a cross-sectional area, BID1XC, wherein a total cross-sectional area of the crosslinked super absorbent polymer inside each tube is a1total, and wherein 0.2%≤100% (a1total/BID1XC)≤10%.
8. The optical cable of claim 1 wherein the polymer coating of the optical fiber includes a colored section, wherein the contiguous layer of crosslinked super absorbent polymer is translucent such that the colored section is visible through the contiguous layer of crosslinked super absorbent polymer.
9. The optical cable of claim 8 wherein the transmittance of the contiguous layer of crosslinked super absorbent polymer at least one wavelength between 400-700 nm is between 0.2 and 1.
10. The optical cable of claim 1 wherein each of the plurality of tubes includes at least six optical fibers, wherein the inner diameter of the tube is between 0.7 and 3 millimeters.
11. An optical fiber cable component comprising:
- an optical fiber including an optical core and a cladding layer of a different refractive index than the optical core surrounding the core;
- an outer polymer layer located outside of and surrounding the optical fiber; and
- a contiguous layer of crosslinked super absorbent polymer surrounding the outer polymer layer, wherein the contiguous layer of crosslinked super absorbent polymer is contiguous circumferentially around the optical fiber and contiguous axially along the optical fiber for at least a length of 1 cm.
12. The optical fiber cable component of claim 11 wherein the contiguous layer of crosslinked super absorbent polymer has a maximum thickness less than 60 micrometers and an average thickness in micrometers, T1ave, of 1≤T1ave≤50.
13. The optical fiber cable component of claim 11 wherein outer polymer layer is at least one of a buffer tube, a ribbon body, and an optical fiber coating layer surrounding and in contact with the cladding layer.
14. A water resistant cable comprising:
- a cable body including an inner surface defining a channel within the cable body;
- an elongate cable component located within the channel of the cable body; and
- a contiguous layer of crosslinked super absorbent polymer surrounding the elongate cable component;
- wherein the contiguous layer of crosslinked super absorbent polymer is contiguous circumferentially around the elongate cable component and contiguous axially along the length of the elongate cable component for at least a length of 1 cm.
15. The water resistant cable of claim 14 wherein the contiguous layer of crosslinked super absorbent polymer has a maximum thickness less than 60 micrometers and an average thickness in micrometers, T1ave, of 1≤T1ave≤50.
16. The water resistant cable of claim 14 wherein the elongate cable component is at least one of an optical fiber, a buffer tube and an optical fiber ribbon.
17. The water resistant cable of claim 14 wherein the elongate cable component is an electrical conductor.
Type: Application
Filed: Aug 23, 2019
Publication Date: Dec 12, 2019
Inventors: Dana Craig Bookbinder (Corning, NY), Waldemar Stöcklein (Coburg)
Application Number: 16/549,414