Extrudable styrenic block copolymer compositions containing a metallocene polyolefin
An extrudable elastomeric composition for making elastic films having a recoverable energy greater than 60%, the composition includes an elastomeric block copolymer, a metallocene polyolefin, and a tackifying resin. The composition optionally may contain a crystalline polyolefin and an extending oil.
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Claims
1. An elastic film having recoverable energy greater than 60%, comprising:
- from 25% to 70% by weight of a block copolymer having at least two monoalkenyl arene blocks separated by a hydrogenated conjugated diene block;
- from 15% to 60% by weight of the polymer components of an elastomeric polyolefin having a density from 0.86 to 0.91 and a molecular weight distribution having a polydispersity less than 3, wherein the elastomeric polvolefin is produced by polymerizing ethylene and from 8% to 30% by weight of an.alpha.-olefin comonomer having from 4 to 12 carbon atoms with a metallocene catalyst;
- from 0% to 25% by weight of a crystalline polyolefin; and
- a from 15% to 28% by weight of a tackifying resin.
2. The film of claim 1, wherein the block copolymer has the structure styrene-poly(ethylene-butylene)-styrene.
3. The film of claim 1, further comprising an extending oil.
4. The film of claim 1, wherein the comonomer in the elastomeric polyolefin is butene.
5. The film of claim 1, wherein the comonomer in the elastomeric polyolefin is octene.
Referenced Cited
U.S. Patent Documents
Foreign Patent Documents
4663220 | May 5, 1987 | Wisneski et al. |
4789699 | December 6, 1988 | Kieffer et al. |
4970259 | November 13, 1990 | Mitchell et al. |
4977014 | December 11, 1990 | Mitchell et al |
5068138 | November 26, 1991 | Mitchell et al. |
5093422 | March 3, 1992 | Himes |
5260126 | November 9, 1993 | Collier, IV et al. |
5272236 | December 21, 1993 | Lai et al. |
5320899 | June 14, 1994 | Djiauw |
5322728 | June 21, 1994 | Davey et al. |
5591792 | January 7, 1997 | Hattori et al. |
9418263 | August 1994 | WOX |
Patent History
Patent number: H1808
Type: Grant
Filed: Nov 26, 1996
Date of Patent: Oct 5, 1999
Assignee: Shell Oil Company (Houston, TX)
Inventors: Lie Khong Djiauw (Houston, TX), Rodney Ray Pease (Houston, TX)
Primary Examiner: Charles T. Jordan
Assistant Examiner: Meena Chelliah
Application Number: 8/756,354
Type: Grant
Filed: Nov 26, 1996
Date of Patent: Oct 5, 1999
Assignee: Shell Oil Company (Houston, TX)
Inventors: Lie Khong Djiauw (Houston, TX), Rodney Ray Pease (Houston, TX)
Primary Examiner: Charles T. Jordan
Assistant Examiner: Meena Chelliah
Application Number: 8/756,354
Classifications
Current U.S. Class:
Solid Block Or Solid Block-type Copolymer With Other Solid Polymer, Sicp Or Spfi (524/505)
International Classification: C08F 1000;
International Classification: C08F 1000;