Patents Issued in December 29, 2015
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Patent number: 9221999Abstract: A method for activating silicone rubber surfaces comprising steps of: i) swelling at least the surface of the silicone rubber matrix with a silicone rubber swelling solvent; ii) treating the silicone rubber matrix during or after the swelling with a solution comprising at least a reactive silane, the reactive silane comprising: a) at least one Si—C bond and; b) at least one hydrolytically labile bond linked to at least one of the Si atoms present in the reactive silane and; c) at least one functional group F1 connected via a Si—C bond to the same or an other Si atom present in the reactive silane, the functional group comprising electrophilic and/or nucleophilic moieties, and/or at least one functional group F2 connected via a Si—C bond to the same or an other Si atom present in the reactive silane comprising moieties which become electrophilic or nucleophilic moieties by a mechanism selected from the group consisting of ring opening of a cyclic structure, hydrolysis, displacement or by a migration reaction;Type: GrantFiled: December 23, 2010Date of Patent: December 29, 2015Assignee: DSM IP ASSETS B.V.Inventors: John Andrew Zupancich, Paul Wyman
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Patent number: 9222000Abstract: A method for coating a surface of a cell culture article includes dissolving a polymer having a covalently attached polypeptide in an aqueous solution to produce a polymer solution. The polymer is formed from monomers selected to form a polymer having a linear backbone, wherein the polymer is crosslink free. The weight percentage of the polypeptide relative to the polymer conjugated to the polypeptide is sufficiently high to render the polymer conjugated to the polypeptide water soluble. The aqueous solution is substantially free of organic solvents. The method further includes (i) disposing the polymer solution on the surface of the cell culture article to produce a coated article; and (ii) subjecting the coated article to sufficient heat or electromagnetic radiation to attach the polymer conjugated to a polypeptide to the surface of the cell culture article.Type: GrantFiled: March 15, 2012Date of Patent: December 29, 2015Assignee: Corning IncorporatedInventors: Anthony Glenn Frutos, David Henry, Corinne Walerack
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Patent number: 9222001Abstract: An adhesive sheet 1 including a binder 3 and adhesive particles 2 mixed in the binder 3 in which the adhesive particle 2 includes an inorganic particle 21 and a polymer 22, the inorganic particle 21 is chemically bonded with the polymer 22, a portion of the adhesive particles 2 is exposed to the surface of the binder 3, the refractive index of the inorganic particle 21 is higher than the refractive index of the binder 3, and the adhesion of the adhesive particle 21 larger than the adhesion of the inorganic particle 21. An adhesive sheet having high refractive index and high adhesion, as well as an optical member and an organic member and an organic light emission device can be provided.Type: GrantFiled: August 16, 2011Date of Patent: December 29, 2015Assignee: HITACHI, LTD.Inventors: Hiroki Kaneko, Hiroshi Sasaki, Akitoyo Konno, Tomokazu Tanase
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Patent number: 9222002Abstract: The present invention relates to a method for producing an adhesive tape (2). The adhesive tape (2) possesses a tapelike carrier (3) and at least one strip (4; 4a, 4b) of adhesive which is applied to the carrier (3) on at least one side. Here, first of all, a carrier web (1), coming from a supply unit (7), is supplied to at least one coating unit (9, 10). The coating unit (9, 10) then generates the at least one strip (4; 4a, 4b) of adhesive on the carrier web (1) in its longitudinal extent, by carrying out coating with an adhesive. Lastly, the carrier web (1) is slit in the longitudinal direction into the individual adhesive tapes (2); the two last-mentioned method steps may also be run in the opposite order.Type: GrantFiled: August 17, 2012Date of Patent: December 29, 2015Assignee: certoplast VORWERK & SOHN GMBHInventors: Thorsten Meier, Peter Rambusch, Kay Ruhnau
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Patent number: 9222003Abstract: An electrode assembly and a battery are provided. The electrode assembly may be effectively fixed inside a can as a pressure-sensitive adhesive tape attached to an outer circumferential surface of the electrode assembly is formed into a 3D shape by an electrolyte. Thus, the electrode assembly does not move and rotate inside the can due to external vibration or impact and damage of welded regions of a tab or disconnection of inner circuits can be prevented.Type: GrantFiled: July 11, 2013Date of Patent: December 29, 2015Assignee: LG CHEM, LTD.Inventors: Sung Jong Kim, Byungkyu Jung, Cha-Hun Ku
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Patent number: 9222004Abstract: A thermal laminating film is provided that has superior intrusion resistance that is well suited to addressing security and anti-counterfeiting needs. The film includes a polymer substrate and an adhesive system with a polymer component having a Vicat softening point temperature that is close to a glass transition temperature of the polymeric substrate, which typically is not greater than about 95° C.Type: GrantFiled: September 30, 2014Date of Patent: December 29, 2015Assignee: Transilwrap Company, Inc.Inventors: Timothy W. Albert, Robert C. Flaherty
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Patent number: 9222005Abstract: The present invention relates to a slip prevention pad and a method of manufacturing the slip prevention pad. The method includes coating emery with a rubber-metal adhesive and then drying the adhesive-coated emery; kneading a raw rubber with a rubber reinforcing material and a vulcanizing agent to prepare an unvulcanized rubber; mixing the adhesive-coated emery with the unvulcanized rubber to obtain a mixture; introducing the mixture into a rubber molding machine to vulcanize and mold the mixture to obtain a rubber product; and cutting the rubber product. The slip prevention pad may effectively prevent slipping on a slippery road surface such as a snowy road or an icy road.Type: GrantFiled: July 8, 2011Date of Patent: December 29, 2015Inventors: Kwon Ho Lee, Yong Beom An
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Patent number: 9222006Abstract: A method and apparatus comprising a sol-gel solution. Zirconium n-propoxide is aged in a solvent to form a first part for the sol-gel solution. The first part is combined with deionized water to form a second part for the sol-gel solution. Aminoaryltrialkoxysilane is combined with an alcohol to form a third part for the sol-gel solution. The third part is combined with the second part to form a mixture for the sol-gel solution. The deionized water, or the alcohol, or a combination thereof is combined with the mixture to form a solution. The solution is aged to form the sol-gel solution comprising a mole balance ratio of approximately 1:5 between the zirconium n-propoxide and the aminoaryltrialkoxysilane.Type: GrantFiled: February 28, 2013Date of Patent: December 29, 2015Assignee: THE BOEING COMPANYInventors: Kay Youngdahl Blohowiak, Kristin L. Krieg, Robert A. Anderson, Jr.
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Patent number: 9222007Abstract: One embodiment of the invention includes a shape memory polymer which functions similar to a traditional mechanical clamp. A shape memory polymer may exhibit adhesive properties when heated above its glass transition temperature. The shape memory polymers may function as a reversible dry adhesive clamp.Type: GrantFiled: September 13, 2012Date of Patent: December 29, 2015Assignee: GM Global Technology Operations LLCInventors: Tao Xie, Chen-Shih Wang
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Patent number: 9222008Abstract: A two-component curable adhesive or sealant composition is provided. The first component may comprise a mixture of at least one polyol selected from the group comprising a polyester polyol, a polyester-polycarbonate copolymer polyol, and combinations thereof, a resin, and optionally a solvent. The second component may comprise a prepolymer obtained by reacting a polyester-polycarbonate copolymer polyol which is the reaction product of a polyester polyol which is the reaction product of one or more organic acids, and one or more glycols having a functionality of two or more and one or more polycarbonate polyols, at least one organic polyisocyanate component, and at least one chain extending agent and optionally a solvent. Alternatively, the first component may comprise a polyester-polycarbonate copolymer polyol, a resin, and optionally a solvent. The second component may comprise a polyisocyanate curative and optionally a solvent.Type: GrantFiled: December 4, 2012Date of Patent: December 29, 2015Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Harpreet Singh, Viviano Bertolone, Orazio Rubulotta, Jorge Jimenez, William H. Heath, Amarnath Singh, William A. Koonce
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Patent number: 9222009Abstract: Provided are fine abrasive particles which have a high rate of polishing and generate few polishing flaws. A process for producing then abrasive particles is also provided in which the fine abrasive particles have a reduced coefficient of fluctuation in particle diameter, the production steps are simple, and the production cost is low. The fine abrasive particles comprise cerium oxide, at least one element selected from La, Pr, Nd, Sm, and Eu, and one or more element selected from Y, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu, and are characterized in that the cerium oxide has a Ce content of 20 mol % or higher and that the sum (mol %) of the content of the at least one element selected from La, Pr, Nd, Sm, Nd Eu and the content of Ce in the cerium oxide is greater than the sum (mol %) of the contents of the one or more elements selected from Y, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu.Type: GrantFiled: October 7, 2011Date of Patent: December 29, 2015Assignee: Konica Minolta, Inc.Inventors: Akihiro Maezawa, Atsushi Takahashi, Yuuki Nagai
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Patent number: 9222010Abstract: The invention concerns the use of a carbohydrate-based compound as a mixing aid and dispersing agent in a pumpable geopolymeric suspension for oil and/or gas industry applications, said suspension further comprising an aluminosilicate source, a carrier fluid, and an activator, and method for placing such a suspension in a borehole. In particular, the suspension according to the invention is used for well primary cementing operations and/or remedial applications.Type: GrantFiled: November 10, 2010Date of Patent: December 29, 2015Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Olivier Porcherie, Elena Pershikova, Gaetan Rimmele, Hafida Achtal, Yamina Boubeguira
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Patent number: 9222011Abstract: A self-adaptive cement formulation includes cement, water, block copolymer and asphaltite-mineral particles. The set cement demonstrates self-healing properties when exposed to methane, and is particularly suited for well-cementing applications. After placement and curing, the self-healing properties help maintain zonal isolation should bonding be disrupted between the set cement and the formation or a casing string, should cracks or defects appear in the set-cement matrix, or both.Type: GrantFiled: June 30, 2014Date of Patent: December 29, 2015Assignee: Schlumberger Technology CorporationInventors: Sylvaine Le Roy-Delage, Laure Martin
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Patent number: 9222012Abstract: Stabilizing smectite shale may include treating a smectite shale in a subsurface formation with a dewatering fluid so as to yield a stabilized smectite shale, the dewatering fluid comprising an aqueous base fluid and a dewatering additive. In some instances, at least a portion of a highwall in a highwall mine may be formed at a highwall mine site comprising stabilized smectite shale.Type: GrantFiled: April 30, 2013Date of Patent: December 29, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Charles R. Landis, Thomas S. Cortner, Eric B. Frantz
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Patent number: 9222013Abstract: A well treatment microemulsion includes an oil external phase, an internal aqueous phase and a hydrophilic surfactant. The surfactant has a hydrophile lipophile balance of between 8-18. The oil external phase may include d-Limonene, xylenes, light mineral oil, or kerosene. The surfactant is configured to emulsify the water of the internal aqueous phase into the oil of the external (continuous) phase. The surfactant may include polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tristearate, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monolaurate or mixtures therebetween. The use of hydrophilic surfactants to emulsify an internal aqueous phase within an oil external microemulsion produces unexpected and beneficial results.Type: GrantFiled: November 13, 2009Date of Patent: December 29, 2015Assignee: CESI Chemical, Inc.Inventors: Lakia M. Champagne, David S. Morrison
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Patent number: 9222014Abstract: Method of treating a subterranean formation comprising providing a consolidation fluid, introducing the resin consolidation fluid into a subterranean formation comprising unconsolidated particulates; and, curing the resin to at least partially consolidate the unconsolidated particulates. The consolidation fluid comprises a resin in emulsified form with an aqueous external phase and an organic internal phase wherein the emulsified resin does not comprise a hardening agent and an aqueous base fluid that further comprises a hardening agent. The consolidation fluid may further comprise an emulsifying agent.Type: GrantFiled: April 27, 2012Date of Patent: December 29, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Richard D. Rickman, Ronald G. Dusterhoft, Philip D. Nguyen, Thomas D. Welton, Jimmie D. Weaver, Mike W. Sanders, Harvey J. Fitzpatrick
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Patent number: 9222015Abstract: A thermochromic coating which comprises a thermochromic compound and a polyurea resin. The thermochromic compound and polyurea resin form a thermochromic layer. The coating optionally has a protective layer containing a resin and a UV-blocking material arranged on top of the thermochromic layer. A reflective layer containing a reflective material is optionally arranged between the thermochromic layer and the substrate. A thermochromic coating is formed by applying successive reflective, thermochromic, and protective layers on a substrate.Type: GrantFiled: November 24, 2010Date of Patent: December 29, 2015Assignee: SWIFT RIVER PROPERTIES, LLCInventors: John C. Becker, IV, Richard S. Himmelwright
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Patent number: 9222016Abstract: A compound of the present invention comprises a triazapentalene backbone represented by the general formula 1 below as a fluorescent chromophore.Type: GrantFiled: March 8, 2012Date of Patent: December 29, 2015Assignee: National University Corporation Hokkaido UniversityInventors: Kosuke Namba, Ayumi Osawa, Keiji Tanino
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Patent number: 9222017Abstract: A method of manufacturing a fluoride phosphor includes mixing a first solution which contains at least Mn and F, a second solution which contains at least K and F, and a third solution which contains at least Si and F to form phosphor cores whose composition is represented by a formula K2[M1-aMn4+aF6] wherein a satisfies 0<a<0.2, and M includes at least one selected from group-IV elements of Ti, Zr, and Hf and group IVB elements of Si, Ge, Sn. The phosphor cores and a fourth solution containing a reducing agent are mixed to form a surface region on each of the phosphor cores so that a concentration of tetravalent Mn on the surface region of one of the phosphor cores is lower than in an inner region of the one of the phosphor cores.Type: GrantFiled: July 21, 2015Date of Patent: December 29, 2015Assignee: NICHIA CORPORATIONInventor: Tomokazu Yoshida
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Patent number: 9222018Abstract: Formulations for stripping titanium nitride (TiN or TiNxOy; x=0 to 1.3 and y=0 to 2) hard mask and removing titanium nitride etch residue are low pH (<4) comprise a weakly coordinating anion having negative charge highly dispersed throughout its structure, amine salt buffer, a non-oxidizing trace metal ion, a non-ambient trace oxidizer, and the remaining being solvent selected from the group consisting of water, sulfolane, dimethyl sulfide, lactic acid, glycol, and mixtures thereof. The formulations contain no hydrogen peroxide, and are exposed to air. Bifluoride, corrosion inhibitors, surfactants may be added to the formulations. Systems and processes use the formulations for stripping titanium nitride hard mask and removing titanium nitride etch residue.Type: GrantFiled: March 10, 2015Date of Patent: December 29, 2015Assignee: Air Products and Chemicals, Inc.Inventors: William Jack Casteel, Jr., Seiji Inaoka, Wen Dar Liu, Tianniu Chen
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Patent number: 9222019Abstract: Corrosion inhibitors and methods for inhibiting or reducing corrosion are provided. The corrosion inhibitors include one or more niobate containing compounds. The corrosion inhibitors may be added to an aqueous system and inhibit the corrosion of a surface contained in the aqueous system. Illustrative examples of suitable niobate compounds are potassium niobate, ammonium niobate, and ammonium niobate oxalate.Type: GrantFiled: October 29, 2013Date of Patent: December 29, 2015Assignee: Ecolab USA Inc.Inventors: Danilo Zim, Matheus Paes Paschoalino
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Patent number: 9222020Abstract: The disclosure relates to oxygen scavenging molecules, compositions, methods of making the compositions, articles prepared from the compositions, and methods of making the articles. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: GrantFiled: May 7, 2013Date of Patent: December 29, 2015Assignee: Plastipak Packaging, Inc.Inventor: Girish N. Deshpande
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Patent number: 9222021Abstract: Disclosed is a liquid-crystal display device comprising a polarizing plate comprising a polarizing element and a thermoplastic-resin film which comprises a lactone ring-having polymer and satisfies the following formulas (I) and (II): (I) 0=|Re(630)|=10, and |Rth(630)|=25 (II) |Re(400)?Re(700)|=10, and |Rth(400)?Rth(700)|=35 wherein Re(?) means retardation (nm) in plane at a wavelength ? nm; and Re(?) means retardation (nm) along the thickness direction at a wavelength ? nm.Type: GrantFiled: September 26, 2008Date of Patent: December 29, 2015Assignee: FUJIFILM CorporationInventor: Kotaro Yasuda
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Patent number: 9222022Abstract: An embodiment provides a polymer-stabilized optical isotropic liquid crystal formulation, including 50 to 99.5 parts by weight of an optical isotropic liquid crystal material; and 0.5 to 50 parts by weight of polymer, wherein the polymer is polymerized by an acrylic monomer containing fluorine groups and an acrylic monomer with a liquid crystal phase and/or an acrylic monomer without a liquid crystal phase.Type: GrantFiled: May 9, 2013Date of Patent: December 29, 2015Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventor: Pao-Ju Hsieh
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Patent number: 9222023Abstract: A liquid crystal composition and a liquid crystal display wherein the liquid crystal composition includes: a compound of general formula (I) including 1%-50% of the total weight of the liquid crystal composition; a compound of general formula (II) including 1%-60% of the total weight of the liquid crystal composition; a compound of general formula (III) including 1%-60% of the total weight of the liquid crystal composition; and a compound of general formula (IV) including 0-50% of the total weight of the liquid crystal composition—wherein the liquid crystal composition has a suitably wider nematic phase scope, a suitable optical anisotropy, a favorable low-temperature storage stability a faster response speed, can be used for outdoor work, has a good image display effect, and substantially free of streaking phenomenon.Type: GrantFiled: April 10, 2013Date of Patent: December 29, 2015Assignee: Jiangsu Hecheng Display Technology Co., Ltd.Inventors: Wenming Han, Yudong Tan, Dingfu Ma, Biao Hu, Yiming Wang, Zhaoyuan Chen, Shizhi You
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Patent number: 9222024Abstract: The present invention relates to a process for producing polymerized films with line texture or fingerprint texture or for producing substrates coated with polymerized films with line texture or fingerprint texture, to polymerized films, obtainable by this process, with line texture or fingerprint texture or substrates coated with polymerized films with line texture or fingerprint texture, to pigments obtainable by comminuting such films, to the use of such films, substrates or pigments as or in optical filter(s), polarizers, decorative media, forgeryproof markers, reflective media or for focusing light (in solar cells), to the use of such films as an antibacterial coating, to a forgeryproof marker which comprises such a film, and to a process for detecting forgeryproof markings.Type: GrantFiled: April 20, 2011Date of Patent: December 29, 2015Assignee: BASF SEInventors: Jochen Brill, Ulrich Schalkowsky, Thomas Musiol, Claus Hoffmann, Olivier Enger, Oliver Seeger
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Patent number: 9222025Abstract: A method for coking coals having high driving pressure properties in a “non-recovery” or “heat-recovery” coking oven, wherein a coking oven battery which is composed of coking oven chambers arranged side by side is used for cyclic coking of coal, and wherein an amount of coal preheated to a high temperature is admitted into the coking chamber that is to be filled at such a level that the driving pressure resulting from the coking can escape over the coke cake into the gas chamber, in such a manner that the coking oven chamber wall surrounding the coking oven chamber is relieved by the driving pressure resulting from the coking. Also disclosed is a device with which this method can be carried out.Type: GrantFiled: February 4, 2011Date of Patent: December 29, 2015Assignee: THYSSENKRUPP UHDE GMBHInventors: Ronald Kim, Franz-Josef Schuecker
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Patent number: 9222026Abstract: A process for forming and maintaining a carbonaceous bed with coke replacement units suitable for use in pyrolytic processes includes the steps of: forming a plurality of non-coke units that are either or both irregularly shaped natural wood blocks and bricks including carbon-containing fines and one or more binders; forming an initial carbonaceous bed by a quantity of particles of coke in which at least about 25% of the carbon content of the initial bed is provided by said quantity of non-coke units and up to about 75% of the carbon content of the initial bed is provided by said quantity of particles of coke; and performing a pyrolytic process with the carbonaceous bed including reacting carbon in the bed with other added process material at an elevated temperature in the bed and supplementing carbon material during the pyrolytic process by adding additional carbon material of which at least 25% of the additional carbon material is not coke.Type: GrantFiled: March 14, 2013Date of Patent: December 29, 2015Assignee: Alter NRG Corp.Inventors: James Santoianni, Michael Erskine Heier, Aleksandr Gorodetsky, Stephanie Reese, Kent O. Hicks
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Patent number: 9222027Abstract: A process and apparatus for making isotropic pitch are disclosed. A tubular reactor operating at high velocity and pressure converts aromatic rich liquid feed to pitch within minutes. Reactor is heated by electric resistance or inductance, a salt or molten metal bath, or fired heater. Reactor effluent flashes and isotropic pitch recovered from the flash drum. Softening point is affected by flash drum pressure or stripping steam. Unconverted feed may be recycled. Process makes little gasoline, simple condensation of flash drum vapor may produce gas oil and gasoline fractions. Isotropic pitch is made in a single step with a coking value of 50 to 55 wt %. Time and temperature in the reactor convert at least 20 wt % of feed and any recycle material present to isotropic pitch. Pressure is preferably above 500 psig, to suppress mesophase formation and produce isotropic pitch with less than 0.5 wt % mesophase.Type: GrantFiled: March 11, 2013Date of Patent: December 29, 2015Assignee: Advanced Carbon Products, LLCInventors: Donald P. Malone, Donald M Lee
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Patent number: 9222028Abstract: Biofuels can be produced by: (i) providing a biomass containing celluloses, hemicelluloses, lignin, nitrogen compounds and sulfur compounds; (ii) removing sulfur compounds and nitrogen compounds from the biomass by contacting the biomass with a digestive solvent to form a pretreated biomass containing carbohydrates and having less than 35% of the sulfur content and less than 35% of the nitrogen content of untreated biomass on a dry mass basis; (iii) contacting the pretreated biomass directly with hydrogen in the presence of a hydrogenolysis catalyst to form a plurality of oxygenated intermediates, and (vi) processing at least a portion of the oxygenated intermediates to form a liquid fuel.Type: GrantFiled: December 20, 2011Date of Patent: December 29, 2015Assignee: Shell Oil CompanyInventors: Joseph Broun Powell, Juben Nemchand Chheda
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Patent number: 9222029Abstract: The present invention is a method for extracting bitumen from an oil sand feed stream including at least the steps of: (a) providing an oil sand feed stream; (b) contacting the oil sand feed stream with a liquid comprising an aliphatic hydrocarbon solvent thereby obtaining a solvent-diluted oil sand slurry; (c) depositing the solvent-diluted oil sand slurry as a filter cake on a filter medium and filtering the solvent-diluted oil sand slurry, thereby obtaining a solids-enriched stream and a filtrate, wherein during the filtering the pressure above the filter cake is at least 1.7 bara; and (d) lowering the pressure of the solids-enriched stream to below 1.2 bara.Type: GrantFiled: March 20, 2012Date of Patent: December 29, 2015Assignee: Shell Oil CompanyInventors: Ingmar Hubertus Josephina Ploemen, Ronald Jan Schoonebeek, Bernardus Cornelis Maria In't Veen
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Patent number: 9222030Abstract: The present invention provides a method for removing oxygen from an oil sand stream, the method including the steps of: (a) providing an oil sand stream; (b) introducing the oil sand stream into a liquid bath; (c) transporting the oil sand through the liquid bath to a confined space above the surface of the liquid bath; (d) removing the oil sand from the confined space; and (e) extracting bitumen from the oil sand removed in step (d).Type: GrantFiled: May 9, 2013Date of Patent: December 29, 2015Assignee: Shell Oil CompanyInventors: Stephen Gerard Delude, Steven Paul Giles, Cristiane Michaëla Visser
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Patent number: 9222031Abstract: A process to prepare a suspension of solid biomass particles in a hydrocarbon-containing liquid for a catalytic cracking process is provided. A catalytic cracking process and subsequent processing of the cracked product from such suspension of solid biomass particles in the hydrocarbon-containing liquid is also provided.Type: GrantFiled: April 23, 2012Date of Patent: December 29, 2015Assignee: Shell Oil CompanyInventors: Andries Quirin Maria Boon, Johan Willem Gosselink, John William Harris, Andries Hendrik Janssen, Sander Van Paasen, Colin John Schaverien, Nicolaas Wilhelmus Joseph Way
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Patent number: 9222032Abstract: Certain embodiments of the present invention are configured to produce boiler and transportation fuels. A first phase of the method may include oxidation and/or hyper-acidification of bio-oil to produce an intermediate product. A second phase of the method may include catalytic deoxygenation, esterification, or olefination/esterification of the intermediate product under pressurized syngas. The composition of the resulting product—e.g., a boiler fuel—produced by these methods may be used directly or further upgraded to a transportation fuel. Certain embodiments of the present invention also include catalytic compositions configured for use in the method embodiments.Type: GrantFiled: May 1, 2013Date of Patent: December 29, 2015Assignee: Mississippi State UniversityInventors: Philip H. Steele, Sathishkumar Tanneru, Sanjeev K. Gajjela
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Patent number: 9222033Abstract: A method and system for processing naphtha, including a high shear mechanical device. In one embodiment, the method comprises forming a dispersion of gas in a naphtha hydrocarbon liquid in a high shear device prior to introduction in a cracking reactor/furnace. In another instance the system for processing naphtha comprises a high shear device for mechanically shearing hydrocarbons.Type: GrantFiled: February 11, 2014Date of Patent: December 29, 2015Assignee: H R D CorporationInventors: Abbas Hassan, Aziz Hassan, Krishnan Viswanathan, Gregory G. Borsinger
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Patent number: 9222034Abstract: A process for removing at least one product from coal tar is described. The process involves extraction with an extraction agent or adsorption with an adsorbent. The extraction agent includes at least one of amphiphilic block copolymers, cyclodextrins, functionalized cyclodextrins, and cyclodextrin-functionalized polymers, and the adsorbent includes exfoliated graphite oxide, thermally exfoliated graphite oxide or intercalated graphite compounds.Type: GrantFiled: August 28, 2014Date of Patent: December 29, 2015
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Patent number: 9222035Abstract: A process for the preparation of at least one ARN acid or salt thereof comprising: (I) allowing at least one ARN acid salt to form during the production of crude oil in the presence of water; (II) removing at least 5 wt % of the formed at least one ARN acid salt, e.g. from the oil water interface; and optionally (III) converting said salt into an acid.Type: GrantFiled: November 17, 2008Date of Patent: December 29, 2015Assignee: STATOIL PETROLEUM ASInventors: Jens Emil Vindstad, Heidi Mediaas, Knut Vebjørn Grande
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Patent number: 9222036Abstract: This invention relates to a process for treatment of a gasoline comprising diolefins, olefins, and sulfur-containing compounds including mercaptans, in which: Gasoline is injected into a distillation column comprising at least one reaction zone to produce a desulfurized light gasoline; with the process also comprising the following stages: An intermediate gasoline fraction is drawn off at a level located above the reaction zone; A heavy gasoline comprising the majority of the sulfur-containing compounds is drawn off at the bottom of the column; In a demercaptization reactor, said intermediate gasoline fraction is brought into contact with a second catalyst to produce an effluent that contains sulfides; The effluent that is obtained from the demercaptization reactor is recycled in the distillation column (3).Type: GrantFiled: January 9, 2014Date of Patent: December 29, 2015Assignee: IFP Energies nouvellesInventors: Olivier Touzalin, Philibert Leflaive
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Patent number: 9222037Abstract: Apparatuses and methods for deoxygenating a biomass-derived pyrolysis oil are provided herein. In one example, the method comprises of dividing a feedstock stream into first and second feedstock portions. The feedstock stream comprises the biomass-derived pyrolysis oil and has a temperature of about 60° C. or less. The first feedstock portion is combined with a heated organic liquid stream to form a first heated diluted pyoil feed stream. The first heated diluted pyoil feed stream is contacted with a first deoxygenating catalyst in the presence of hydrogen to form an intermediate low-oxygen pyoil effluent. The second feedstock portion is combined with the intermediate low-oxygen pyoil effluent to form a second heated diluted pyoil feed stream. The second heated diluted pyoil feed stream is contacted with a second deoxygenating catalyst in the presence of hydrogen to form additional low-oxygen pyoil effluent.Type: GrantFiled: November 14, 2012Date of Patent: December 29, 2015Assignee: UOP LLCInventor: Tom N. Kalnes
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Patent number: 9222038Abstract: A plasma gasification reactor vessel having a top section with a conical wall extending up from a bottom section, containing a carbonaceous bed into which plasma is injected by plasma torches, to a roof of the vessel is arranged in ways that can contribute to characteristics of gas flow and solids residence time that are favorable for thoroughness of reactions and yield of useful reactions products. In some cases, such a conical wall is combined in arrangements with other features such as one or more feed ports arranged to give more uniform distribution including examples with a feed port that has a distributive feed mechanism. The roof of the vessel, in some examples, has vertical outlet ports that include intrusions into the interior volume of the reactor proximate the conical wall of the top section. The configurations of outlet ports with intrusions and the configurations of feed ports for more uniform distribution of feed material are also applicable to reactor vessels with other geometries.Type: GrantFiled: February 11, 2009Date of Patent: December 29, 2015Assignee: Alter NRG Corp.Inventors: Shyam V. Dighe, Mark F. Darr, Ivan A. Martorell, Pieter van Nierop, Aleksandr Gorodetsky, Richard Dale Bower
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Patent number: 9222039Abstract: An improved active grate consisting of at least two elongated rockers positioned parallel to one and another, each rocker having a lower surface and an upper surface and configured to rotate back and forth about their longitudinal axis. Each individual rocker is further configured to rotate in the opposite direction of the adjacent rockers such that any pair of adjacent rockers alternately forms a void allowing material to pass through active grate when rotating in one direction into a first position, and closes the void when rotated in the opposite direction in a second position. The active grate finds particular utility in a combined gasification/vitrification waste treatment system, where it is used to pass partially oxidized materials from a gasification chamber to a vitrification chamber. The rockers include a coolant loop through the longitudinal axis of the rockers.Type: GrantFiled: December 12, 2011Date of Patent: December 29, 2015Assignee: INENTEC INC.Inventors: Jeffrey E. Surma, James A. Batdorf
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Patent number: 9222040Abstract: A system includes a slurry depressurizing system that includes a liquid expansion system configured to continuously receive a slurry at a first pressure and continuously discharge the slurry at a second pressure. For example, the slurry depressurizing system may include an expansion turbine to expand the slurry from the first pressure to the second pressure.Type: GrantFiled: June 7, 2012Date of Patent: December 29, 2015Assignee: General Electric CompanyInventors: Raymond Douglas Steele, Judith Pauline Oppenheim
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Patent number: 9222041Abstract: An optimized gasification/vitrification processing system having a gasification unit which converts organic materials to a hydrogen rich gas and ash in communication with a joule heated vitrification unit which converts the ash formed in the gasification unit into glass, and a plasma which converts elemental carbon and products of incomplete combustion formed in the gasification unit into a hydrogen rich gas.Type: GrantFiled: February 11, 2014Date of Patent: December 29, 2015Assignee: INENTEC INC.Inventors: Jeffrey E. Surma, James A. Batdorf
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Patent number: 9222042Abstract: In a plant having integrated CO2 removal, for pig iron production or synthesizing gas, at least part of the offgas or synthesis gas is discharged as export gas from the plant, optionally collected in an export gas container and subsequently thermally utilized in a gas turbine. The offgas from the gas turbine is fed to a waste heat boiler for generation of steam. To reduce the addition of high-grade fuel gases, at least part of the tailgas from the CO2 removal plant is mixed into the export gas upstream of the gas turbine as a function of the joule value of the export gas after addition of the tailgas. The proportion of tailgas is increased when the joule value of the export gas goes above a predefined maximum joule value and the proportion of tailgas is reduced when the joule value of the export gas drops below a predefined minimum joule value.Type: GrantFiled: August 3, 2012Date of Patent: December 29, 2015Assignee: PRIMETALS TECHNOLOGIES AUSTRIA GmBHInventors: Robert Millner, Jan-Friedemann Plaul
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Patent number: 9222043Abstract: Marking a petroleum product includes adding a covert dye selected from the group consisting of azadipyrromethene dyes, dipyrromethene dyes, and any combination thereof to the petroleum product and distributing the dye in the petroleum product. A petroleum product selected for analysis may be spectroscopically analyzed for the presence of an azadipyrromethene dye, a dipyrromethene dye, or a combination thereof. A concentration of at least one azadipyrromethene or dipyrromethene dye present in the portion of the petroleum product may be determined to identify the petroleum product as counterfeit, adulterated, or authentic based on the determined concentration of the azadipyrromethene or dipyrromethene dye.Type: GrantFiled: September 20, 2010Date of Patent: December 29, 2015Assignee: Authentix, Inc.Inventors: Philip B. Forshee, Greg R. Hundt, Jeffrey L. Conroy
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Patent number: 9222044Abstract: Methods for producing low oxygen biomass-derived pyrolysis oil are provided. Starting biomass-derived pyrolysis oil is deoxygenated by exposing the biomass-derived oil to a first catalyst in the presence of hydrogen-containing gas at first hydroprocessing conditions to produce a partially deoxygenated biomass-derived pyrolysis oil. The first catalyst has a neutral catalyst support. The partially deoxygenated biomass-derived pyrolysis oil is exposed to a second catalyst in the presence of additional hydrogen-containing gas at second hydroprocessing conditions to produce a hydrocarbon product. The biomass-derived pyrolysis oil may be esterified prior to deoxygenation. A portion of the low oxygen biomass-derived pyrolysis oil is recycled.Type: GrantFiled: July 26, 2010Date of Patent: December 29, 2015Assignee: UOP LLCInventors: Thomas Traynor, Timothy A. Brandvold
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Patent number: 9222045Abstract: The invention relates to a method for producing a stable boron solution with lubricating characteristics which is intended to be used preferably as an addition in the form of a concentrate/additive to a liquid, e.g. to a liquid fuel or a lubricant. The invention is achieved by the method steps of using a boron substance of pharmaceutical quality (1, 11), using a liquid as solvent, applying a mixing ratio between the boron substance and the solvent (3, 13) of preferably 1 g of boron per 15-25 liters of liquid, agitating the mixture for an initial predetermined period of time (4, 14), adding further liquid to dilute the solution (6, 15), the quantity of liquid being chosen such that a final user mixture reaches a concentration of between 20 and 30 ppm of boron (8), and further agitating the mixture (7, 16) for a second predetermined period of time so that the boron substance is completely dissolved in the boron solution, resulting in a boron solution which is stable over time.Type: GrantFiled: May 10, 2010Date of Patent: December 29, 2015Assignee: Triboron International ABInventors: Tommy Lindblom, Magnus Undén
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Patent number: 9222046Abstract: A fuel soluble additive for a diesel engine, a method for improving performance of fuel injectors and a method for cleaning fuel injectors for a diesel engine. The fuel soluble additive includes a quaternary ammonium salt derived from an amido amine containing at least one tertiary amino group and an epoxide, in the presence of a proton donor selected from a carboxylic acid and an alkyl phenol. The amido amine is made in a reaction medium that is substantially devoid of an acylating agent.Type: GrantFiled: April 26, 2013Date of Patent: December 29, 2015Assignee: Afton Chemical CorporationInventors: Xinggao Fang, Scott D. Schwab
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Patent number: 9222047Abstract: A liquid fuel composition containing (a) a diesel base fuel suitable for use in an internal combustion engine; and (b) one or more organic sunscreen compounds. The liquid fuel composition of the present invention provides benefits in terms of power output of a diesel engine, and modifying the ignition delay and/or modifying the burn period and/or increasing the cetane number of the liquid fuel composition.Type: GrantFiled: December 19, 2013Date of Patent: December 29, 2015Assignee: Shell Oil CompanyInventor: Mark Lawrence Brewer
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Patent number: 9222048Abstract: Embodiments of the invention provide a process in which a gas comprising biomethane having a heating value of about 350-950 BTU/cubic foot is introduced to a pipeline system at a combination point that is downstream of natural gas in the pipeline system having a heating value of at least about 950 BTU/cubic foot. This produces a mixed gas downstream of the combination point. At least a portion of the mixed gas downstream of the combination point is withdrawn for use by a user that combusts the mixed gas to generate heat and/or electricity. A corresponding amount of natural gas is withdrawn at an upstream location for use as a transportation fuel, a fuel intermediate or as a feedstock for producing a fuel. The process can enable fuel credit generation.Type: GrantFiled: May 21, 2015Date of Patent: December 29, 2015Assignee: Iogen CorporationInventor: Patrick J Foody