Abstract: The present invention relates to a long-chain branched elastic terpolymer capable of satisfying excellent processability and elasticity (flexibility) at the same time, which is obtained in the presence of a Group IV transition metal catalyst, and a preparation method thereof. The elastic terpolymer is a copolymer of ethylene, an alpha-olefin having 3 to 20 carbon atoms, and a diene, wherein i) its weight average molecular weight measured by GPC is 100,000 to 500,000, and ii) its LCB Index which is a ratio of 1st harmonics of storage modulus to 5th harmonics of storage modulus measured at 125° C. using a rubber process analyzer according to a LAOS (Large Angles of Oscillation and high Strains) method has a positive value.

Abstract: Described herein is a peroxide curable, highly fluorinated elastomer derived from tetrafluoroethylene, a perfluoro ether monomer, and a compound selected from at least one of a highly fluorinated bisolefin ether and an iodine-containing perfluorinated ether.

Abstract: A process for producing water-absorbing polymer particles by suspension polymerization and thermal surface postcrosslinking, wherein the base polymer obtained by suspension polymerization has a centrifuge retention capacity of at least 37 g/g and the thermal surface postcrosslinking is conducted at 100 to 190° C.

Abstract: The present invention relates to a polymer comprising an N-vinyl amide monomer and a dual functional monomer. In the case where the dual functional monomer incorporates a glycidyl acrylate, a third polymerizable monomer is also included. The polymer can be varied in charge.

Abstract: Described herein are polymers, polymeric gels, or a composition thereof, for drug delivery. The polymers, which include boronic-acid containing moieties (e.g., and polyol-containing moieties (e.g., are prepared by free-radical polymerization and can self-assemble into polymeric gels such as hydrogels. Also provided are methods or preparing the polymers, kits involving the polymers and/or polymeric gels or a composition thereof, for use as materials or delivery applications of an agent to a subject.

Abstract: The purpose of the present invention is to provide a polar-group-containing propylene-type wax having excellent properties including a low melting point. A modified propylene-(?-olefin) copolymer (A) according to the present invention is produced by grafting at least one compound selected from an unsaturated carboxylic acid, a derivative of the unsaturated carboxylic acid and an unsaturated sulfonic acid salt onto a propylene-(?-olefin) copolymer (A1) and has an acid value of 1 to 100 KOHmg/g, wherein the propylene-(?-olefin) copolymer (A1) comprises 60 to 95 mol % of a propylene-derived constituent unit (a) and 5 to 40 mol % of a constituent unit (b) derived from an ?-olefin having 4 or more carbon atoms, and satisfies the specific requirements (i) to (iii).

Abstract: The present invention provides a resin composition for an optical waveguide and a resin film for optical waveguides, the composition and the film being soluble in an aqueous alkaline solution, being patternable as required by alkali development, and exhibiting a lower optical propagation loss at a wavelength of from 830 to 850 nm, and an optical waveguide using the composition or the film. The resin composition for an optical waveguide according to the present invention includes (A) a polymer, (B) a polymerizable compound, and (C) a polymerization initiator. A refractive index A of the film after irradiation with UV light and heat-curing and a refractive index B of the film after irradiation with UV light, immersion in an alkali developer, and then heat-curing satisfy the relationship of A>B.

Abstract: Disclosed is a method for producing a plastisol acrylic polymer which can have a satisfactory adhesion property even when the heating time is short and the heating temperature is low, and which has excellent storage stability. The method comprises (1) a step of polymerizing an acrylic monomer mixture (a) to produce a polymer (A) and (2) a step of polymerizing an acrylic monomer mixture (b) in a dispersion containing the polymer (A), wherein a monomer having a hydroxy group is contained in the acrylic monomer mixture (a), a monomer having an acetoacetyl group or a block isocyanate group is contained in the acrylic monomer mixture (b), and the dissolution parameter (SA) for the polymer (A) and the dissolution parameter (SB) for a polymer (B) produced by the polymerization of the acrylic monomer mixture (b) are different from each other.

Abstract: The present application provides the block copolymers and their application. The present application may provide the block copolymers that have excellent self assembling and phase separation properties and therefore that can be effectively used in various applications. The present application may also provide applications of the block copolymers.

Abstract: The present application provides the block copolymers and their application. The present application may provide the block copolymers that have excellent self assembling and phase separation properties and therefore that can be effectively used in various applications. The present application may also provide applications of the block copolymers.

Abstract: The present application provides the block copolymers and their application. The present application may provide the block copolymers that have excellent self assembling and phase separation properties and therefore that can be effectively used in various applications. The present application may also provide applications of the block copolymers.

Abstract: The present application provides the block copolymers and their application. The present application may provide the block copolymers that have excellent self assembling and phase separation properties and therefore that can be effectively used in various applications. The present application may also provide applications of the block copolymers.

Abstract: The present application provides the block copolymers and their application. The present application may provide the block copolymers that have excellent self assembling and phase separation properties and therefore that can be effectively used in various applications. The present application may also provide applications of the block copolymers.

Abstract: A polyisocyanate modified with sulphamic acid and a mixture thereof, the preparation method thereof, and the use thereof in the production of polyurethane, especially as a cross-linking ingredient in the field of aqueous coatings and adhesives containing groups that are capable of reacting with isocyanate groups.

Abstract: The present invention relates to a process for producing a polyurethane sealant, which comprises mixing (a) polyisocyanate, (b) polyetherpolyols, (c) aliphatic, exclusively amine initiated alkoxylation products having an OH-number of 400 to 1000 mg KOH/g and a functionality of 4, (d) blowing agents and optionally (e) chain extenders and/or crosslinking agents, (f) catalysts and (g) auxiliaries and/or additives to give a reaction mixture and reacting the reaction mixture to give the polyurethane sealant. The present invention further relates to a cast in place polyurethane sealant, obtained according to a process according to the present invention.

Abstract: The present invention provides a method for preparing a foam that includes a polyurethaneurea dispersion. These foams have enhanced flexibility and resistance to compressibility compared to convention polyurethane foam. These foams may also be made by a reaction injection molding process. The method includes preparing a shaped polyurethane foam article by: (a) providing a first composition comprising at least one polyol, a chain extender composition and a blowing agent; (b) providing a second composition comprising at least one of a diisocyanate, a capped glycol, and combinations thereof; (c) mixing the first composition and the second composition to form a reaction mixture into a heated mold; and (d) allowing the reaction mixture to form a polyurethane foam; wherein the first composition includes one of: (i) the chain extender composition includes at least one amine compound; (ii) the blowing agent includes a polyurethaneurea aqueous dispersion; and (iii) combinations of (i) and (ii).

Abstract: There is provided a method that can realize the treatment of an amine compound, a deterioration product thereof and the like in a simple and a low-cost manner. The method includes treating a carbon dioxide absorbing agent, comprising a step in which at least one carbon dioxide absorbing agent represented by OH—R2—NR3—R4—OH or H—NR6—R7—NR8—H into contact with a compound containing two or more isocyanate groups in its molecule to produce a solid containing a urethane bond or a urea bond. In the above formula, R2, R3, R4, R6, R7, and R8 each independently represent CvHwOxNy wherein v, w, x, and y are 0?v?10, 0?w?22, 0?x?3, and 0?y?3, respectively.

Abstract: The polymerizable composition for an optical material of the present invention includes: (A) a compound having a carbon-carbon triple bond and at least one group selected from an isocyanate group and an isothiocyanate group in a molecule; and (B) a polythiol compound.

Abstract: Embodiments of the invention provide for polymer polyols and methods of producing polymer polyols. Methods include providing at least one first composition which includes at least one polyol, at least one isocyanate non-reactive seed population, and at least one of a co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom. The at least one isocyanate non-reactive seed population includes less than about 5% by weight of the total weight of the first composition, and the seed population has a maximum particle diameter of less than 10 ?m. The first composition is combined with at least one polyisocyanate under mixing to form at least one of a polyurea, polyurethane, and a polyurethane-urea particle population dispersed in the first composition, wherein at least 90% by weight of the particle population has a particle diameter of less than 100 ?m.

Abstract: The invention provides polyfunctional bio-based methacrylate oligomers, which are synthesized via the ring-opening reaction between at least one ethylenically unsaturated acid selected from methacrylic acid, acrylic acid, and crotonic acid, and a polyfunctional bio-based epoxy resin, such as epoxidized sucrose soyate. The extent of reaction may be varied to generate a family of methacrylate oligomers with differing degrees of methacrylate. These methacrylate oligomers can optionally be mixed with a reactive diluent, such as styrene, and cured using, for example, a thermally-activated free radical initiator to form a thermoset polymer with high modulus. The thermosets can be used to form composites, adhesives, coatings, and dental restorative materials. Methods of making the methacrylate oligomers are disclosed as are coating compositions and coated objects, such as dental restorative materials, using the methacrylate oligomers.

Abstract: The invention relates to a binder resin which is a plastified epoxide-amine adduct P comprising an adduct EA made of epoxide resins E and amines A, optionally modified by incorporation of unsaturated fatty acids F?, which adduct is plastified by incorporation of a fatty acid amide M, or a mixture M? of the said fatty acid amide M with a glyceride mixture GX which is a mixture of at least two glycerides selected from the group consisting of a triglyceride GT, a diglyceride GD, and a monoglyceride GM, to a process for its preparation, and to a method of use thereof as primer for wood, mineral, and metal substrates.

Abstract: The disclosure relates to at least one partially reacted product of an isocyanate and an amine (e.g., a reaction product comprising at least one adducted compound). The reaction product comprises polyurea oligomers. The reaction product can be combined with at least one amine in order to formulate a curing agent for epoxy resins wherein the cured epoxy resin has enhanced fracture toughness. The at least partially reacted product does not increase the viscosity of the curing agent and is at least partially soluble in the amine component of the curing agent.

Abstract: To provide a technique for producing an epoxy resin cured product having toughness and elasticity. (A) the amine curingagent (B) an epoxy resin curing agent characterized in that the acrylic block copolymer is dissolved.

Abstract: A dual cure system including at least two different and separate types of chemical reactions occurring as the process of the present invention proceeds including, for example, the following two reactions: (1) free radical polymerization of methacrylated or acrylated polyol; and (2) an epoxy-curing agent reaction. The dual cure system of the present invention advantageously provides a first cure reaction of methacrylated or acrylated polyol followed by a second epoxy-curing agent thermoset reaction to form a cured thermoset exhibiting an elongation property of greater than about 5%.

Abstract: The invention relates to bio-based polymer based on at least two different bio-based monomers obtained from biomass-containing carbohydrates, wherein at least one bio-based monomer is a furan derivative according to formula (I). In each case, independently of one another, R1 is a hydrogen or an organofunctional group with 1 to 20 C atoms and optionally, the organofunctional group contains O, N, or S atoms; R2 is an organofunctional group with 1 to 20 C atoms, which optionally contains O, N, or S atoms, the second bio-based monomer is a hydroxyl-functional compound comprising from 1 to 100 C atoms. The polymer has an average molecular weight Mw greater than or equal to 1,000 g/mol, and the proportion of bio-based monomers in the bio-based polymer is greater than or equal to 55 mol-% with respect to all monomers of the polymer.

Abstract: A silicone-modified polyester resin and methods for making the resin are described herein. The method includes production of a siliconized intermediate which is then esterified to give a silicone-modified polyester resin. Coating compositions including the silicone-modified polyester resin are provided, and coated articles with the coating composition applied to at least a portion of a surface thereof are also provided.

Abstract: Provided is a polymer product having a branched chain made of polyester, and a weight average molecular weight of 200,000 or greater when measured by gel permeation chromatography.

Abstract: The present invention relates to the preparation of modified polymers by incorporating a compositional modifier into a polymer to produce the modified polymer. More particularly, the invention relates the preparation of condensation type copolyesters or copolyamides by joint short length polyester or polyester oligomers or short length polyamide or polyamide oligomers with a modifier which contains hydroxyl acids blocks.

Abstract: A polyester resin composition is provided with which irritant gases do not occur in production and no increase in the viscosity of a polyester resin is exhibited even when a terminal blocking agent is contained. The composition includes an iminoether compound of Formula (1) and a polyester. Further provided are an iminoether compound, a method for producing a carboxylic acid ester, a polyester film, a back sheet for a solar cell module, and a solar cell module. R2 represents an optionally substituted alkyl, cycloalkyl, aryl or alkoxy group; R3 represents a specific alkyl or aryl group; and R11, R12 and R13 each independently represents a hydrogen atom or an optionally substituted alkyl or aryl group.

Abstract: A production method for a polyacetal copolymer that makes deactivation of a catalyst simple and efficient and that achieves a high polymerization yield and high quality using equipment that does not require a cleaning step and a process that involves a simple operation technique. The production method for a polyacetal copolymer uses trioxane as a main monomer and a cyclic ether and/or a cyclic formal having at least one carbon-carbon bond as a comonomer. In the production method, a predetermined heteropoly acid is used as a polymerization catalyst to perform copolymerization, a predetermined salt is added to the reaction product, melt kneading processing is performed, and the polymerization catalyst is deactivated.

Abstract: The present invention concerns a catalyst formulation comprising: (a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and (b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from: (I) group 13 metals, preferably B, Al, Ga, and In, more preferably Al, (II) combinations of Al with group 14 metals or semi-metals, preferably a combination of Al and Si, and (III) combinations of at least two metals selected from (I) and (II). The present invention also relates to a process for polymerizing an epoxide monomer, preferably ethylene oxide, comprising carrying out the process in the presence of the catalyst formulation.

Abstract: The invention concerns a method for producing polyamide from an amino ester of formula NH2—(CH2)n—COOR, in which R represents an alkyl group and n represents an integer ranging from 5 to 14, comprising: a first reaction step in the presence of water, at a first temperature; followed by a second reaction step at a second temperature higher than the first temperature.

Abstract: A polyamide resin, according to the present invention, is formed through polycondensation of a monomer comprising 1,4-cyclohexanedicarboxylic acid, 1,10-decanediamine, and 1,12-dodecanediamine, wherein the molar ratio of 1,10-decanediamine and 1,12-dodecanediamine is approximately 10:90 to approximately 65:35. As a result, the polyamide resin capable of enabling high durability and color stability in the polyamide molded body can be provided.

Abstract: A method for manufacturing a polyamide resin, according to the present invention, comprises the steps of: obtaining a low-order condensate in a solid state through polycondensation of dicarboxylic acid and diamine in the presence of a compound having a wt % of approximately 0.01 to 0.5 with respect to the total amount of the dicarboxylic acid and the diamine; and solid-state polymerizing the low-order condensate, wherein the dicarboxylic acid contains, with respect to the total amount of the dicarboxylic acid, approximately 70 mol % of aliphatic dicarboxylic acid having 9 to 12 carbon atoms, wherein the diamine contains, with respect to the total amount of the diamine, approximately 50 mol % of diamine represented by previously indicated chemical formula 1, wherein the range of the maximum temperature of the polycondensation reaction is approximately 200 to 230° C., and the maximum reaction temperature of the solid-state polymerization is approximately 170 to 230° C.

Abstract: A composition including a polyamic acid modified with an alkoxysilane group; and an oligo silica compound, wherein the polyamic acid modified with an alkoxysilane group includes a reaction product of (i) a condensation reaction product of an acid anhydride and a diamine, and (ii) a reactive organosilane compound, wherein the oligo silica compound includes a condensation reaction product of an organosilane diol and a an alkoxysilane compound, wherein an amount of silicon atoms in the composition is less than or equal to about 15 wt % based on a total weight of solid contents in the composition.

Abstract: Various embodiments provide random copolyimides that may possess the mechanical, thermal, chemical and optical properties associated with polyimides yet achieve a low energy surface. In various embodiments, the copolyimides may be prepared using a minor amounts of a diamino terminated fluorinated alkyl ether oligomer and a diamino terminated siloxane oligomer. The various embodiments include processes for making the copolyimides containing fluorine and silicon surface modifying agents and anisotropic coatings and articles of manufacture from them. Thus the coatings and articles of manufacture made with the copolyimides of the various embodiments may be characterized as having an anisotropic fluorine and silicon composition and low surface energy.

Abstract: A method for forming a high melt viscosity polyarylene sulfide is provided. The method comprises reacting a sulfur source with a dihaloaromatic compound during a first stage to form an arylene sulfide prepolymer having halogen end groups; and thereafter, reacting the arylene sulfide prepolymer with a secondary sulfur source during a second stage to form the polyarylene sulfide.

Abstract: A curable resin composition having high transparency in the UV region, UV resistance and heat resistance. The curable resin composition includes an alkoxy oligomer represented by Formula 1 of (R1R2R3SiO1/2)w(R4R5SiO2/2)x(R6SiO3/2)y(SiO4/2)z and a curing catalyst. The curing catalyst is phosphoric acid present in an amount of 3-30 parts by weight based on 100 parts by weight of the alkoxy oligomer, or alkoxide of at least one metal selected from the group consisting of B, Al, P, Sc, Ga, Y, Zr, Nb, In, Sn, La, Gd, Dy, Yb, Hf, Ta and W, present in an amount of 0.5-20 parts by weight based on 100 parts by weight of the alkoxy oligomer. Each of R1, R2, R3, R4, R5 and R6 independently represents the same or a different organic group, w, x, y and z are 0 or positive numbers satisfying the relationship of w+x+y+z=1, and the atomic ratio of O/Si is 2.3-3.5.

Abstract: The present invention relates to a photo-dimerization functional group-containing organopolysiloxane represented by the following formula (1): (R3SiO1/2)m (R2SiO2/2)n (RSiO3/2)p (SiO4/2)q (1) wherein, R are each independently selected from the group consisting of monovalent hydrocarbon groups, alkoxy groups having 1 to 6 carbon atoms, photo-dimerization functional groups, and hydroxyl groups, provided that an average of at least three R in a molecule are the photo-dimerization functional groups; and m, n, p, and q are each numbers greater than or equal to 0, and satisfy the following condition: 3.0?m+n?20,000. The photo-dimerization functional group-containing organopolysiloxane cures rapidly due to irradiation by activation energy radiation such as ultraviolet radiation or the like.

Abstract: Disclosed are a superabsorbent polymer including a water-soluble salt and a method of preparing the same, wherein the addition of a water-soluble metal salt in the polymerization process of a superabsorbent polymer is very effective at decreasing the concentration of residual monomer.

Abstract: Various embodiments disclosed relate to melt-stabilized ultra high molecular weight antioxidant, methods of making the same, and medical implants made from the same. In various embodiments, the present invention provides a method of melt-stabilizing ultra high molecular weight polyethylene (UHMWPE). The method can include coating a solid material including LIMA/PE with an antioxidant, to provide an antioxidant-coated solid material. The method can include pre-irradiatively heating the antioxidant-coated solid material to diffuse the antioxidant therein, to provide an antioxidant-diffused solid material. The method can include irradiating the antioxidant-diffused solid material, to provide an irradiated solid material. The method can include post-irradiatively heating the irradiated solid material, the heating sufficient to melt at least part of the UHMWPE, to provide a heated material. The method can also include solidifying the heated material, to provide a melt-stabilized material.

Abstract: Thermosets are formed by mixing an epoxy resin with a hardener composition that includes a norbornene-based anhydride hardener such as methyl nadic anhydride and a core-shell rubber. The presence of the core-shell rubber unexpectedly reduces the strong odor of that is normally produced in thermosets containing these anhydride hardeners.

Abstract: To provide a process for producing a fluorinated crosslinked product which is excellent in stability and produces less HF. A process for producing a fluorinated crosslinked product, which comprises irradiating a fluorinated polymer having a unit represented by the following formula (1), with active energy rays having a wavelength of from 150 to 300 nm: wherein X1 and X2 are each independently a hydrogen atom or a fluorine atom, Rf1 is a fluoroalkylene group or a fluoroalkylene group having at least two carbon atoms and an etheric oxygen atom between carbon-carbon atoms, Q1 is a single bond or an etheric oxygen atom, and Z1 is OH, OR1 or NR2R3, wherein R1 is an alkyl group, and R2 and R3 are each independently a hydrogen atom or an alkyl group.

Abstract: This disclosure relates to a method for preparing superabsorbent polymer. The method for preparing superabsorbent polymer according to one aspect of the invention comprises obtaining hydrogel polymer during the process of preparing superabsorbent polymer, and then, spraying a surface crosslinking solution comprising a surface crosslinker, alcohol, and ionic liquid to crosslink the surface of the pulverized polymer. The method for preparing superabsorbent polymer may use ionic liquid without using lower alcohol, or if lower alcohol is used together, may minimize the amount, and thus, reduce cost and additional drying treatment, and may control swelling of gel to prepare superabsorbent polymer with excellent product properties.

Abstract: Methods for making and curing resin-based adhesives are disclosed using encapsulated amine accelerators activated by providing ultrasonic energy.

Abstract: This invention relates to a process of making a fiber-reinforced composite. Glass fibers may be provided. These glass fibers may be treated with a sizing composition that has a coupling-activator compound with the formula: S—X-(A)n, where S represents a silicon-containing coupling moiety capable of bonding to the surface of glass fibers, X represents a linking moiety, and (A)n represents one or more polymerization activator moieties. The treated glass fibers may be combined with a resin to make a fiber-resin mixture. The resin may have a monomer, a catalyst, and an activator compound capable of initiating a polymerization of the monomer. The monomer may be a lactam or lactone having 3-12 carbon atoms in the main ring. The fiber-resin mixture may then be cured so that the monomer polymerizes to form a thermoplastic polymer matrix of the fiber-reinforced composite. The thermoplastic polymer matrix may be formed by in situ polymerization initiated from both the surface of the glass fibers and the resin.

Abstract: A water-soluble film including a polyvinyl alcohol copolymer resin, a plasticizer, an anti-block filler, and a release modifier is disclosed herein. Also disclosed are related packets incorporating the film, and related methods of making and using the film and packets.

Abstract: An ion exchange membrane includes: a cation exchange resin material; and a macromolecular material that has an acidic functional group and is mixed in the cation exchange resin material.

Abstract: The present invention provides a heat-curable resin composition, which comprises (1) a heat-curable resin mixture comprising a heat-curable resin (a) and thickener particles (b) and exhibiting a viscosity (150° C.) after having been held at a temperature of 150° C. for 30 seconds that is a viscosity (S), and (2) a curing agent, and is characterized in that the heat-curable resin composition exhibits a lowest viscosity (R) at 80-120° C., the lowest viscosity (R) is 0.1-10 Pa·s, and the viscosity (S) and lowest viscosity (R) satisfy the relationship of formula (1): 5<S/R<200??formula (1).

Abstract: The prepreg comprises: a reinforcing fiber layer including reinforcing fibers and a resin composition with which the space between fibers of the reinforcing fibers is impregnated and which contains (A) a benzoxazine resin, (B) an epoxy resin, and (C) a curing agent having 2 or more phenolic hydroxy groups in a molecule; and a surface layer provided on a surface of the reinforcing fiber layer and containing the (A) to (C) components, and (D) polyamide resin particles having an average particle size of 5 to 50 ?m, wherein the polyamide resin particles include a polyamide 12 resin particle and a polyamide resin particle made of a copolymer in which caprolactam and laurolactam are copolymerized at a molar ratio of 9:1 to 7:3.