Abstract: The invention relates to a process for the preparation of precipitated silica formed of aggregates of large primary silica particles, at the surface of which occur small primary silica particles, in which the acid used in at least one of the process steps is a concentrated acid.

Abstract: A process for preparing precipitated silicas in which: (i) an aqueous stock with a pH of between 2 and 5 is formed; (ii) silicate and acid are simultaneously added to said stock, such that the pH of the resulting reaction medium is maintained between 2 and 5; (iii) silicate is added until a pH value of between 7 and 10 is obtained; (iv) silicate and acid are simultaneously added, such that the pH of the reaction medium is between 7 and 10; (v) acid is added until a pH value of between 2.5 and 5.3 is obtained; and (vi) the reaction medium is placed in contact with acid and silicate, such that the pH is between 2.5 and 5.3; wherein the acid used in at least one of the process steps is a concentrated acid.

Abstract: A synthetic gel for crystal growth, which induces only secondary growth from the surface of a silicalite-1 or zeolite beta seed crystal and cannot induce crystal nucleation in the synthetic gel for crystal growth or on the surface of the seed crystal. The synthetic gel contains fumed silica, tetraethylammonium hydroxide (TEAOH), [(NH4)2SiF6], KOH, and H2O, or contains tetraethylorthosilicate (TEOS), tetraethylammonium hydroxide (TEAOH), hydrogen fluoride, and H2O.

Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.

Abstract: The present invention concerns a SAPO-34 molecular sieve and method for preparing the same, whose chemical composition in the anhydrous state is expressed as: mDIPA.(SixAlyPz)O2, wherein, DIPA is diisopropylamine existing in cages and pore channels of said molecular sieve, wherein m is the molar number of diisopropylamine per one mole of (SixAlyPz)O2, and m is from 0.03 to 0.25; x, y, z respectively represents the molar number of Si, Al, P, and x is from 0.01 to 0.30, and y is from 0.40 to 0.60, and z is from 0.25 to 0.49, and x+y+z=1. The SAPO-34 molecular sieve can be used as catalysts for acid-catalyzed reaction or oxygenate to olefins reaction.

Abstract: In an ammonia or hydrogen plant comprising a desulfurisation section, a reforming section and a shift section, where the shift section comprises a low temperature shift converter and a medium temperature shift converter, a vent line is arranged downstream from the low temperature shift converter and the medium temperature shift converter in order to allow the shift converters to be re-heated with process gas at a low pressure (typically 3-7 bar). This way condensation of water vapour in the process gas is avoided. By applying this vent line it becomes possible to save significant time, more specifically 8-24 hours, for restarting the production after temporary shut-down thereof, because a heat-up of the LTS/MTS converter in circulating nitrogen is avoided.

Abstract: A process for preparing sodium bicarbonate particles, comprising the steps of: (a) adding at least one alkali metal carbonate to an aqueous solution in order to form an aqueous composition; wherein the alkali metal carbonate comprises sodium carbonate and wherein the aqueous composition comprises at least one polycarboxylic acid and/or the salts thereof, in an amount of at least 200 ppm based on the weight of the aqueous composition; and (b) precipitating solid particles comprising sodium bicarbonate crystals and separating said sodium bicarbonate particles from the aqueous composition, in order to obtain sodium bicarbonate particles and an aqueous mother liquor.

Abstract: A fused product including lithium-manganese spinel, which is optionally doped, having a spinel structure AB2O4, where the site A is occupied by lithium and the site B is occupied by manganese, it being possible for the site B to be doped with an element B? and it being possible for the site A to exert a substoichiometry or a superstoichiometry with respect to the site B, so that the product observes the formula Li(1+x)Mn(2?y)B?yO4, with ?0.20?x?0.4 and 0?y?1, the element B? being chosen from aluminum, cobalt, nickel, chromium, iron, magnesium, titanium, vanadium, copper, zinc, gallium, calcium, niobium, yttrium, barium, silicon, boron, zirconium and their mixtures.

Abstract: The invention provides a method for producing barium titanate powder comprising the steps of: adding an aqueous slurry of anatase hydrous titanium oxide having a BET specific surface area in the range of 200 to 400 m2/g and a half width of diffraction peak of (101) plane in the range of 2.3° to 5.0° as measured by X-ray diffraction to an aqueous solution of barium hydroxide while maintaining the aqueous solution of barium hydroxide at a temperature in the range from 80° C. to the boiling point thereof under normal pressure to cause a reaction of the barium hydroxide with the hydrous titanium oxide to provide an aqueous slurry of barium titanate precursor; and subjecting the barium titanate precursor thus obtained to hydrothermal treatment over a period of time shorter than 24 hours to provide barium titanate particles.

Abstract: A biocidal fluid purification cap (2) for a fluid container (1), preferably one storing purified water for use in laboratory environments and especially purified water for cell culture and water for molecular biology. The purification cap (2) includes a cap body (3) including an engagement feature (20) for removably attaching the cap body (3) to a mating engagement feature on a spout of the fluid container (1) to hermetically close a spout opening, at least one LED (7a) adapted to emit light in the UV-C range, electronic circuitry (15) for driving the LED(s) (7a), and a power supply for the electronic circuitry (15). The LED(s) (7a) is/are arranged in said cap body (3) so as to be separated from the environment by an UV-transparent window (6) provided in the cap body (3) such that light emitted from said LED(s) (7a) enters the opening of the spout when the cap (2) is attached to the spout of the container (1).

Abstract: A system is provided that includes one or more acoustic microfilters through which is flowed a mixture of a fluid and a particulate to selectively filter particles from the fluid. Also included are one or more phononic crystal units coupled to the acoustic microfilter(s) to further selectively filter particles from the fluid. Related apparatus, systems, techniques and articles are also described.

Abstract: A reverse osmosis system according to the present disclosure includes a first membrane array, a second membrane array, a hydraulic pressure booster, and a motor-generator. The first membrane array is configured to generate a first permeate stream and a first brine stream from a feed stream. The second membrane array is configured to generate a second permeate stream and a second brine stream from the first brine stream. The booster is configured to use energy from the second brine stream to increase pressure of at least one of the feed stream and the first brine stream. The motor-generator is coupled to the hydraulic pressure booster and is operable to use energy from a power supply to drive the hydraulic pressure booster. The motor-generator is also operable to use energy from the second brine stream to provide power to the power supply.

Abstract: Provided is an interfacial polymerization process for preparation of a highly permeable thin film composite membrane, which can be used for nanofiltration, or forward or reverse osmosis, for use with tap water, seawater and brackish water, particularly for use with brackish water at low energy conditions. The process includes contacting a porous support membrane with an aqueous phase containing a polyamine and a flux enhancing combination, which includes a metal chelate additive containing a bidentate ligand and a metal atom or metal ion and a dialkyl sulfoxide, to form a coated support membrane, and applying an organic phase containing a polyfunctional acid halide to the coated support membrane to interfacially polymerize the polyamine and the polyfunctional acid halide to form a discrimination layer of the thin film composite membrane. Also provided are the membranes prepared by the methods and reverse osmosis modules containing the membranes.

Abstract: This disclosure provides water processing apparatuses, systems, and methods for recovering water from wastewater such as urine. The water processing apparatuses, systems, and methods can utilize membrane technology for extracting purified water in a single step. A containment unit can include an ionomer membrane, such as Nafion®, over a hydrophobic microporous membrane, such as polytetrafluoroethylene (PTFE). The containment unit can be filled with wastewater, and the hydrophobic microporous membrane can be impermeable to liquids and solids of the wastewater but permeable to gases and vapors of the wastewater, and the ionomer membrane can be permeable to water vapor but impermeable to one or more contaminants of the gases and vapors. The containment unit can be exposed to a dry purge gas to maintain a water vapor partial pressure differential to drive permeation of the water vapor, and the water vapor can be collected and processed into potable water.

Abstract: A conductive micro-channel structure includes a layer having layer edges and an electrode having first and second portions formed in or under the layer. One or more fluid micro-channels are formed in the layer, expose the first portion of the electrode, and extend to a layer edge to form a fluid port. A conductor micro-channel includes a solid conductor in the conductor micro-channel. The solid conductor is electrically conductive, is electrically connected to the second portion of the electrode, and extends from the second portion to a layer edge to form a conductor port.

Abstract: The present invention consists of a method of pre-treatment of adulterated water for distillation, including adulterated water produced during hydraulic fracturing (“fracking”) of shale rock during natural gas drilling. In particular, the invention is directed to a method of treating adulterated water, said adulterated water having an initial level of bicarbonate ion in a range of about 250 ppm to about 5000 ppm and an initial level of calcium ion in a range of about 500 ppm to about 50,000 ppm, said method comprising contacting the adulterated water with a non-thermal arc discharge plasma to produce plasma treated water having a level of bicarbonate ion of less than about 100 ppm. Optionally, the plasma treated water may be further distilled.

Abstract: A micro-channel electrode structure includes a layer and an electrode micro-channel formed in the layer, the electrode micro-channel having an electrode micro-channel bottom forming the bottom of the electrode micro-channel and an electrode micro-channel top forming the top the electrode micro-channel. The electrode micro-channel is at least partially filled with an electrode that extends along the electrode micro-channel and extends from the electrode micro-channel bottom toward the electrode micro-channel top. A fluid micro-channel adapted to carry a fluid is formed in the layer. An electrical power source is connected to the electrode. The fluid micro-channel intersects the electrode micro-channel in the layer to form a micro-channel intersection and the electrode extends from the electrode micro-channel into the micro-channel intersection without occluding the fluid micro-channel.

Abstract: Embodiments of the invention provide a method of regenerating a capacity of a flow-through capacitor. A target value for a water property concentration in a discharge water stream exiting the flow-through capacitor is established. A feed value for the water property concentration in a feed water stream entering the flow-through capacitor is measured. An amount of the water property concentration to be added to the feed water stream is calculated based on the feed value to achieve the target value for the water property concentration in the discharge water stream. An amperage of the flow-through capacitor and a flow rate through the flow-through capacitor is controlled to add ions to the feed water stream to achieve the target value for the water property concentration in the discharge water stream. In some embodiments, the amperage can be set and the flow rate controlled to achieve the target concentration.

Abstract: A method of treating mineral slurries to inhibit bacterial growth includes adding an effective amount of one or more of sodium N-methyldithiocarbamate or methylammonium monomethyldithiocarbamate to the mineral slurry to inhibit bacterial growth.

Abstract: A floating monitoring apparatus and system comprising: a base; a first flotation device attached to the base and located generally below the base, the flotation device configured to float on a surface of water; a light support member extending downward from the base, and configured to be at least partially below the surface of water; a camera attached to the base and configured to be aimed to capture images of a target below the base, where the camera is generally kept above the surface of the water; a light source attached to the light support member, and configured to direct light to illuminate the target, the lights located below the surface of the water.

Abstract: Methods and apparatus for generation of dual biocides are provided. The electrolytic generation of chlorine as a biocide is employed for further generation of additional biocides within a single system or generator, including bromine, iodine, chlorine dioxide, fluorine, or chloramines from their respective salts and/or precursors. A single on-site generating system produces a combination of biocides for applications of use providing cost, safety and efficacy improvements. Methods of using the disinfecting biocides provide a synergistic effect through simultaneous or sequential applications.

Abstract: A device for generating high pressure ozone water by using a low pressure ozone gas source includes an ozone gas and water mixture bucket. A water inlet of the ozone gas and water mixture bucket is connected with a tap water inlet through a pipe system and a water inlet solenoid valve. A water outlet of the ozone gas and water mixture bucket is connected with a water outlet through the pipe system and a water outlet one-way valve. An ozone gas inlet of the ozone gas and water mixture bucket is connected with an ozone inlet through the pipe system and an ozone gas inlet one-way valve. The ozone gas and water mixture bucket is provided with an off-gas outlet. The off-gas outlet is connected with a discharge outlet through the off-gas destruct bucket. The water inlet solenoid valve is connected with a power control unit.

Abstract: A fluidized bed reactor for ammonia laden wastewater includes a column, a plurality of carrier particles, a first settling tank and a fluidizing means. The column defines a fluidizing chamber therein, and the fluidizing means is adapted for introducing the ammonia laden wastewater into the fluidizing chamber and further into the first settling tank. The reactor is further provided with microorganisms including nitrifying bacteria, anammox bacteria and heterotrophic denitrifying bacteria attached to the carrier particles. Nitrification reaction, anammox reaction and heterotrophic denitrification reaction are simultaneously taking place in the fluidizing chamber to transform ammonia into nitrogen by the microorganisms. A method for treating ammonia laden wastewater is also provided. The fluidized bed reactor is advantageous in the fact that its start-up is significantly shortened and it is adapted to efficiently treat thin ammonia laden wastewater.

Abstract: A method for reducing release of resistance genes during sludge anaerobic treatment includes controlling concentration of to-be-treated sludge in a concentration tank to be 12-20 g/L by sedimentation under gravity. The concentrated sludge is transferred to a supersonic pre-treatment device to proceed with supersonic pre-treatment. The supersonic pre-treatment is conducted for 5-30 minutes at a power of 0.1-0.5 kW and a frequency of 10-40 kHz. The pre-treated sludge is then transferred to an anaerobic treatment device for anaerobic treatment. The anaerobic treatment is conducted for 4-12 days at a temperature of 20-37° C. The release amount of resistance genes in the residual sludge and the supernatant liquid in the anaerobic treatment device is detected. A feedback dosage of an alkali liquid is fed into the anaerobic treatment device according to the release amount of the resistance genes, controlling a pH value to be 9.0-11.0 during the anaerobic treatment.

Abstract: In a wastewater treatment system, a suction duct clarifier is converted to a suction pipe clarifier without penetrating existing concrete at the base of the tank. An elevated sludge collection box is added, positioned on the center column to rotate with rake arms, and a series of sludge riser pipes extend from the rake arms up into the sludge collection box for sludge delivery by hydraulic pressure differential. A sludge discharge downpipe is provided within the center/influent column for delivery of sludge from the collection box, and at the bottom of this pipe, above the tank floor, the discharge pipe exits through an opening in the center/influent column. At the outside of this opening is a sludge transfer box that receives sludge exiting the discharge pipe and conveys it down through the existing floor opening and to the existing under-floor RAS return pipe.

Abstract: A roll for use in glass manufacture, such as in the production of non-dusting TFT glass, includes a hollow silica cylinder. A rod extends through the interior of the silica cylinder. A cooling volume is contained within the cylinder and extends around the rod. End caps are mechanically fixed to the roll. Pulling flats are fixed in place by inner and outer end plates. A compression fitting secures at least the outer end plate to the roll. The rod may serve to reinforce the roll and may be secured to the shaft by a plurality of supports. The supports accommodate differences in thermal expansion.

Abstract: A production method of an optical fiber preform includes first preparing a first preform having a plurality of glass preforms and a first cladding portion disposed between the plurality of glass preforms, and first arranging a second cladding portion to surround the first preform. At the first arranging, a material gas and a combustion gas are ejected from a burner to produce glass particles. The first preform and the burner are moved relative to each other in a longitudinal direction of the first preform. The glass particles are deposited on the first preform.

Abstract: A glass particle deposit producing method capable of preventing the variation in the outside diameter of a glass particle deposit and enhancing the yield of a glass raw material is provided. A glass particle deposit is produced by mounting a starting rod 11 and a glass particle generating burner 22 inside a reaction vessel 2, introducing a glass raw material into the burner 22, subjecting the glass raw material to a flame decomposition reaction inside a flame formed by the burner 22 to generate glass particles, and depositing the generated glass particles on the starting rod 11. At this time, the dispersion angle of the glass raw material jetted from the burner 22 with respect to the center axis of the burner 22 is set to the range of 5 to 70 degrees.

Abstract: Alkali-free glasses are disclosed having (in weight %) 50?SiO2?80%, 2?Al2O3?17%, 8?B2O3?36%, and greater than or equal to 2% and less than or equal to 25% of at least one of CaO, MgO, BaO, SrO or ZnO. The alkali-free glasses can have a surface layer with greater than 0.2 weight % N. Such alkali-free glasses are achieved by nitriding processes and exhibit increased strength, scratch resistance and chemical durability.

Abstract: Lithium silicate glass ceramics and glasses containing specific oxides of tetravalent elements are described which crystallize at low temperatures and are suitable in particular as dental materials.

Abstract: A method of forming high strength glass fibers in a refractory-lined glass melter, products made there from and batch compositions suited for use in the method are disclosed. The glass composition for use in the method of the present invention is up to about 64-75 weight percent SiO2, 16-24 weight percent Al2O3, 8-12 weight percent MgO and 0.25-3 weight percent R2O, where R2O equals the sum of Li2O and Na2O, has a fiberizing temperature less than about 2650° F., and a ?T of at least 80° F. By using oxide-based refractory-lined furnaces the cost of production of glass fibers is substantially reduced in comparison with the cost of fibers produced using a platinum-lined melting furnace. High strength composite articles including the high strength glass fibers are also disclosed.

Abstract: A system and method of forming fiberglass air filtration media is disclosed which does not require the use of oil additives. A mixture of resin binder, polymer, and dry adhering agent is formed and applied to the fiberglass as it spins onto the drum. Additionally, the fiberglass filtration media density can vary such that the fiber on the air inflow is less dense than the fiber on the air outflow. After oven curing, the finished air filtration media has an improved ability to attract and hold dust and other contaminants.

Abstract: Certain example embodiments of this invention relate to articles including anticondensation coatings that are exposed to an external environment, and/or methods of making the same. In certain example embodiments, the anticondensation coatings may be survivable in an outside environment. The coatings also may have a sufficiently low sheet resistance and hemispherical emissivity such that the glass surface is more likely to retain heat from the interior area, thereby reducing (and sometimes completely eliminating) the presence condensation thereon. The articles of certain example embodiments may be, for example, skylights, vehicle windows or windshields, IG units, VIG units, refrigerator/freezer doors, and/or the like.

Abstract: In accordance with the present invention, there is provided a treat chlorine bypass dust while preventing increases in chemical cost and concentrations of heavy metals in clinker, and ensuring stability in quality of cement. In a chlorine bypass facility 1 extracting a part G of combustion gas, while cooling it, from a kiln exhaust gas passage, which runs from an inlet end of a cement kiln to a bottom cyclone, and recovering a high chlorine concentration chlorine bypass dust D5 from the extracted gas G1, a slurry S containing chlorine bypass dust and SO2 gas or/and CO2 gas are contacted with each other to obtain solid content. The slurry containing chlorine bypass dust and an exhaust gas from the chlorine bypass facility or/and the exhaust gas from the cement kiln can be contacted with each other, and the solid content can be fed to a cement finishing process, which allows cement with low CaO and Ca(OH)2 contents and with stable property such as setting time to be produced.

Abstract: A sialon sintered body includes a ?-sialon (Si6-ZAlZOZN8-Z) and at least one polytype sialon, wherein a Z value is 0.4 or greater and 1.0 or less, a proportion of a total of peak intensities of each polytype sialon to a total of peak intensities of each sialon, is 10% or greater and 50% or less, at least one rare earth element B selected from a group consisting of La and Ce and at least one rare earth element C selected from a group consisting of Y, Nd, Sm, Eu, Gd, Dy, Er, Yb, and Lu is included, a molar ratio of the rare earth element B and the rare earth element C is 1.0:0.06 to 1.0:3.5 in terms of an oxide, and a total content of the rare earth elements B and C is 0.8 mol % or greater and 4.0 mol % or less in terms of an oxide.

Abstract: A monolithic refractory castable material comprises from about 25 to about 80 weight percent of graphite, from about 1 to about 15 weight percent of a water dispersible, curable phenolic novolac resin, and from about 70 to about 15 weight percent of one or more refractory aggregates, based on the weight of the monolithic refractory castable material. The monolithic refractory castable material is water dispersible and may be delivered to a structure surface by casting, pumping, shotcreting or gunning processes. In one embodiment, the monolithic refractory castable material may be employed to install or replace a blast furnace lining.

Abstract: Method for producing shaped bodies from reaction-bonded, silicon-infiltrated silicon carbide and/or boron carbide, characterized in that a monolithic preliminary body is built up in layers using a formless granulation to which a physical or chemical hardening or melt process is applied, wherein the granulation has a weight fraction of at least 95% silicon carbide and/or boron carbide with an average grain size of 70 to 200 ?m, the so-created preliminary body is impregnated at least once by the introduction of a carbon black suspension or via a gas-phase separation and secondary silicon carbide is created in contact with liquid or gaseous silicon by a subsequent reaction firing that solidifies an engagement composite produced.

Abstract: A composite material combining—a precious metal or an alloy containing a precious metal—and a boron-based ceramic having a melting point greater than that of said precious metal and a density at most equal to 4 g/cm3.

Abstract: Aspects of the invention include compositions for fertilizing and remediating soil. Compositions according to certain embodiments include a cellulose nutrient composition, a microbial blend composition, a source of nitrogen, a source of phosphorus and exotic micronutrients. Methods for using compositions of the invention to fertilize and remediate soil and kits having one or more compositions for fertilizing and remediating soil are also described.

Abstract: The invention describes a new method for treating sludge, which can result in the production of high nitrogen organically-augmented inorganic fertilizer that incorporates municipal sludges or biosolids or organic sludges that can compete with traditional fertilizers such as ammonium phosphate, ammonium sulfate and urea on the commodity fertilizer marketplace. The method takes advantage of the thixotropic property of dewatered biosolids or organic sludge to create a pumpable paste-like material from the biosolids or organic sludge that is then treated with an oxidizer to reduce odorant effects and an acid. This mix is then interacted with concentrated sulfuric and or phosphoric acids and an ammonia source or alternatively a hot or molten melt or salt of ammonium sulfate/phosphate to form a fertilizer mix. The present invention controls the heat, atmospheric pressure and retention time of the fertilizer mix in the reaction vessel.

Abstract: A hydrothermal conversion process includes a mixing step wherein an aqueous slurry of a solid feedstock material with a steam stream to produce a reaction mixture having a temperature of at least 160° C. and which is at a pressure sufficient to keep water as a subcooled liquid. The process is fast and effective, requires only simple equipment and is highly energy-efficient. The process is also readily scalable, can be operated continuously or semi-continuously and can be tailored to produce carbonized solids or liquefaction products, all of which typically have increased economic value compared with the starting materials.

Abstract: Methods, catalysts, and reactor systems for producing in high yield aromatic chemicals and liquid fuels from a mixture of oxygenates comprising di- and polyoxygenates are disclosed. Also disclosed are methods, catalysts, and reactor systems for producing aromatic chemicals and liquid fuels from oxygenated hydrocarbons such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like; and methods, catalysts, and reactor systems for producing the mixture of oxygenates from oxygenated hydrocarbons such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like. The disclosed catalysts for preparing the mixture of oxygenates comprise a NinSnm alloy and a crystalline alumina support.

Abstract: A process for preparing a selective hydrogenation catalyst is described, wherein is provided a catalyst precursor, comprising at least one group VIII metal in the metallic form, and at least one support formed of at least one oxide, characterized in that a step is performed of contacting the said catalyst precursor in the metallic form, in the liquid phase and in the presence of a reducing and/or inert atmosphere, with a non-polar solvent containing a silicon compound, the said silicon compound is selected from the silanes containing at least one Si—H bond and at least one Si—C bond, the silanols and the cyclic siloxanes. The selective hydrogenation process implementing the said catalyst is also described.

Abstract: A process for the conversion of linear pentenes to propylene is disclosed. The process may include feeding hydrogen and a C5-olefin containing stream comprising linear pentenes, dienes, acetylenes, and cyclopentene to a catalytic distillation reactor system. Concurrently in the catalytic distillation reactor system, the acetylenes and dienes may be hydrogenated and the C5-olefin containing stream may be fractionated, thereby recovering an overheads fraction comprising the linear pentenes, a side draw fraction comprising the cyclopentene, and a bottoms fraction. In some embodiments, at least a portion of the overheads fraction may then be fed to a metathesis reactor for converting the linear pentenes to propylene.

Abstract: This invention relates to a process for producing ethanol comprises supplying a feed comprising carbon monoxide, hydrogen and dimethyl ether to a reaction zone operated under conditions such that (i) part of the carbon monoxide in the feed reacts with part of the hydrogen in the feed to produce methanol; (ii) part of the carbon monoxide in the feed reacts with at least part of the dimethyl ether in the feed to produce methyl acetate; and (iii) part of the hydrogen in the feed reacts with at least part of the methyl acetate produced in (ii) to produce an effluent comprising methanol and ethanol. At least part of the ethanol is recovered from the effluent and at least part of the methanol is dehydrated to produce dimethyl ether, which is recycled to the reaction zone.

Abstract: A multi-reactor hydroformylation process wherein a common product-catalyst separation zone is employed.

Abstract: The present invention relates to a process for preparing acrylic acid from acetic acid and formaldehyde, which comprises (a) provision of a stream S1 comprising acetic acid and formaldehyde, where the molar ratio of acetic acid to formaldehyde in the stream S1 is in the range from 0.5:1 to 2:1; (b) contacting of the stream S1 with an aldol condensation catalyst comprising vanadium, phosphorus and oxygen to give a stream S2 comprising acrylic acid, where, in (b), the space velocity WHSV is in the range from 0.35 to 7.0 kg/kg/h.

Abstract: A process for producing a mixture comprising tertiary isononanoic acids proceeding from 2-ethylhexanol is characterized in that 2-ethylhexanol is (a) reacted at a temperature of 0° C. to 40° C. with a mixture of concentrated formic acid and a concentrated Brønsted acid, wherein 2 to 10 mol of formic acid are used per mole of 2-ethylhexanol and the concentrated Brønsted acid is used in an amount that corresponds to 6 to 90 mol of protons per mole of 2-ethylhexanol. The resulting reaction mixture from step (a) is subsequently (b) brought into contact with water, and the mixture comprising tertiary isononanoic acids formed according to step b) is removed.

Abstract: A process for producing acetic acid comprising the steps of carbonylating methanol in a reaction medium to form a crude acetic acid product; conveying the crude acetic acid product to a flash vessel at a flash flow rate; flashing the crude acetic acid product to form a first vapor stream comprising acetic acid and a liquid residue stream comprising metal catalyst and halide salt; separating the flashed vapor stream to form a second vapor stream comprising methyl iodide a sidedraw comprising purified acetic acid and water, and a liquid residue stream. The process further comprises the steps of condensing at least a portion of the second vapor stream to form at least one liquid phase and refluxing to the light ends column at least a portion of the at least one liquid phase at a reflux rate. The reflux rate is adjusted based on changes in the flash flow rate.

Abstract: A method for the preparation of an alkali metal cinnamate powdery product, preferably potassium cinnamate or sodium cinnamate, is disclosed herein. The resulting product has novel structural properties. The powder of the present disclosure is made via spray-drying and/or spray agglomeration and has a higher flowability, is less cohesive and less dusty, has an improved dissolution rate and in particular has a very favorable organoleptic profile. The disclosure is also directed to product applications in which the novel cinnamate product of the present disclosure may be applied.