Patents Issued in November 21, 2017
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Patent number: 9822012Abstract: Described herein is a new crystalline molecular sieve Al-SSZ-63 prepared by a direct synthesis. The synthesis uses N-cyclodecyl-N-methyl-pyrrolidinium cation as a structure-directing agent. A method for directly synthesizing the Al-SSZ-63 is also provided, as are processes employing the Al-SSZ-63 in a catalyst.Type: GrantFiled: April 12, 2016Date of Patent: November 21, 2017Assignee: Chevron U.S.A. Inc.Inventor: Saleh Ali Elomari
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Patent number: 9822013Abstract: Some embodiments of the present disclosure include a method and method for recovery of solution mined minerals. The method may include creating superheated steam using a steam boiler; passing the superheated steam through a turbine/generator to generate electricity; reheating the steam exiting the turbine/generator to saturation with a steam reheater; using the saturated steam with an absorption chiller to create chilled water; and recovering minerals using the chilled water in a cooling crystallizer system. In embodiments, the method and system may be used to recover minerals, such as potash (KCl), washing soda (Na2CO3.10H2O); nahcolite (NaHCO3); and glauber salt (NaSO4.10H2O). The method may utilize the trigeneration of steam, electrical, and chilled water utilities, which may be used for a recovery process.Type: GrantFiled: July 6, 2016Date of Patent: November 21, 2017Assignee: Innovare Technologies Ltd.Inventors: John Sheldon McEwan, Sandy DeBusschere, Michael John Ferguson, Max E. Ramey
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Patent number: 9822014Abstract: A method for making lithium iron phosphate is provided. A lithium chemical compound, a ferrous chemical compound, and a phosphate-radical chemical compound are mixed in an organic solvent to form a mixture. The mixture is solvothermal reacted in a solvothermal reactor at a predetermined temperature. A protective gas is introduced into the solvothermal reactor during the solvothermal reaction to increase a pressure in the solvothermal reactor to a level higher than a self-generated pressure of the solvothermal reaction.Type: GrantFiled: November 15, 2013Date of Patent: November 21, 2017Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.Inventors: Li Wang, Xiang-Ming He, Ji-Xian Wang, Jian Gao, Jian-Jun Li
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Patent number: 9822015Abstract: The present invention provides a method of producing a lithium mixed metal oxide, a lithium mixed metal oxide and a nonaqueous electrolyte secondary battery. The method includes a step of calcining a mixture of one or more compounds of M wherein M is one or more elements selected from the group consisting of nickel, cobalt and manganese, and a lithium compound, in the presence of one or more inactive fluxes selected from the group consisting of a fluoride of A, a chloride of A, a carbonate of A, a sulfate of A, a nitrate of A, a phosphate of A, a hydroxide of A, a molybdate of A and a tungstate of A, wherein A is one or more elements selected from the group consisting of Na, K, Rb, Cs, Ca, Mg, Sr and Ba. The lithium mixed metal oxide contains nickel, cobalt and manganese, has a BET specific surface area of from 3 m2/g to 15 m2/g, and has an average particle diameter within a range of 0.1 ?m or more to less than 1 ?m, the diameter determined by a laser diffraction scattering method.Type: GrantFiled: December 2, 2010Date of Patent: November 21, 2017Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Satoshi Shimano, Kenji Nakane, Cedric Pitteloud, Kenji Takamori, Yuichiro Imanari
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Patent number: 9822016Abstract: A method to recycle TiB2 articles, and in particular, a method to recycle a TiB2 feedstock including TiB2 articles and Ti-ore and/or Ti-slag by chlorination.Type: GrantFiled: November 4, 2015Date of Patent: November 21, 2017Assignee: Alcoa USA Corp.Inventors: Mark L. Weaver, Andrew L. Schnitgen, Robert A. DiMilia, Frankie A. Phelps, James C. McMillen
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Patent number: 9822017Abstract: The present invention relates to a process for preparing high aspect ratio titanium dioxide (TiO2) nanorods using a one-pot hydrothermal technique. Reaction additives of oxalic acid and sodium hydroxide (NaOH) are used to promote the conversion of titanium dioxide precursors, preferably tetraisopropoxide (TTIP), into a one-dimensional TiO2 morphology.Type: GrantFiled: May 11, 2016Date of Patent: November 21, 2017Assignee: The United States of America as Represented by the Secretary of the ArmyInventors: Dajie Zhang, Brendan S. DeLacy, Zachary B Zander
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Patent number: 9822018Abstract: A water amount controlling method according to the present disclosure includes: opening a discharge valve that discharges a liquid from a water tank if an impurity concentration is higher than or equal to a first reference value, and opening a sluice gate that introduces the liquid to the water tank a predetermined period after opening the discharge valve, the first reference value being lower than a saturation concentration; throttling the discharge valve and the sluice gate if the impurity concentration is higher than or equal to a second reference value and the temperature is lower than or equal to a third reference value, the second reference value being lower than the first reference value; and closing the discharge valve if the impurity concentration is lower than the second reference value, and closing the sluice gate a predetermined period after closing the discharge valve.Type: GrantFiled: November 26, 2014Date of Patent: November 21, 2017Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Morio Tomiyama, Hisaaki Gyoten, Norihisa Mino, Akira Taomoto, Atsushi Ono, Stephen William John
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Patent number: 9822019Abstract: A desalination system includes a water tank, a water-repellent particle layer located at a lower portion of the tank and composed of water-repellent particles, and a devolatilizing layer located below the water-repellent particle layer. Liquid is introduced to the tank, the introduced liquid is heated to be evaporated into water vapor, and the water vapor passes through the water-repellent particle layer and is liquefied at the devolatilizing layer, so that fresh water is obtained from the liquid. The desalination system further includes a liquid level controller for determining a level of the liquid introduced to the tank in accordance with information on relationship between information corresponding to an amount of the liquid introduced to the tank and a surface level of the liquid in the tank, and an introduced amount controller for adjusting the amount of the liquid introduced to the tank in accordance with the determined liquid surface level.Type: GrantFiled: September 29, 2014Date of Patent: November 21, 2017Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Yumi Wakita, Norihisa Mino, Hiroki Takeuchi, Mikiya Nakata
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Patent number: 9822020Abstract: An apparatus for recovering nutrients or water from digestate comprises one or more solid-liquid separation units, an ammonia stripping device, and a gas scrubbing unit. In a process, digestate is separated into a solids portion and a liquid portion. Ammonia is stripped from the liquid portion and converted into an ammonium salt solution which may be sold or used as, or blended with, a fertilizer product. Optionally, at least part of the remaining liquid portion may be concentrated to produce brine. The brine is mixed with the solids portion. The mixture may be dried and used as, or blended with, a fertilizer product. Optionally, a least part of the remaining liquid portion may be re-used as dilution water in a digester. A solids portion of the digestate, and one or both of an ammonium salt solution and a brine, may be used as fertilizer without thermal drying.Type: GrantFiled: December 18, 2013Date of Patent: November 21, 2017Assignee: Anaergia Inc.Inventors: Ashwani Kumar, Juan Carlos Josse, Michael David Theodoulou, Sasha Michael Rollings-Scattergood
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Patent number: 9822021Abstract: Separation processes using forward osmosis are disclosed generally involving the extraction of a solvent from a first solution to concentrate a solute therein by using a second concentrated solution to draw the solvent from the first solution across a semi-permeable membrane. One or both of the solute and solvent may be a desired product. By manipulating the equilibrium of the soluble and insoluble species of solute within the second solution, a saturated second solution can be used to generate osmotic pressure on the first solution. The various species of solute within the second solution can be recovered and recycled through the process to affect the changes in equilibrium and eliminate waste products. Enhanced efficiency may result from using low grade waste heat from industrial or commercial sources.Type: GrantFiled: May 23, 2016Date of Patent: November 21, 2017Assignee: Yale UniversityInventors: Robert L. McGinnis, Menachem Elimelech
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Patent number: 9822022Abstract: Described herein are methods and apparatus for solid-liquid separation with high efficiency, especially in treating spent filter backwash and sedimentation tank sludge produced in the water treatment process. It combines and applies gravity, electromagnetic force, dynamic filtration, and gravity condensation, magnetic and gravitational compression in one integrated device that produces high quality effluent water (less than 10 ppm suspended solid) and highly condensed sludge (less than 94-96% water content).Type: GrantFiled: September 26, 2014Date of Patent: November 21, 2017Inventor: Nengqiang Ge
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Patent number: 9822023Abstract: The disclosed technology regards a method and system for removing sodium chloride from production water or fracking water produced in an oil well operation, or other wastewater. Generally, the method includes adding a calcium chloride feed to the source water to create a mixture in an amount so that the calcium chloride present in the mixture is at least 31% w/w of the mixture. The mixture is then agitated, and settled to allow sodium chloride crystals to precipitate out of the mixture, leaving a calcium chloride mixture.Type: GrantFiled: December 9, 2016Date of Patent: November 21, 2017Assignee: Clean Water LLCInventors: Donald W Booth, Tony L Anderson
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Patent number: 9822024Abstract: Wastewater treatment methods and systems for removal of phosphorus (P) and nitrogen (N) from wastewater and for recovery of them as usable materials. Sufficient amount of dolomite lime and slaked dolomite lime is added into the wastewater to increase the pH of the wastewater to above 8.5 and to form P precipitates and to convert ammonium to ammonia in a precipitation-ammonia stripping reactor or a continuous flow precipitation reactor. The P precipitates are separated from the wastewater and recovered as usable solid material. The ammonia gas is absorbed and concentrated with acid solution in an ammonia absorption tower as usable liquid material.Type: GrantFiled: December 19, 2013Date of Patent: November 21, 2017Assignee: CHINESE RESEARCH ADADEMY OF ENVIRONMENTAL SCIENCESInventors: Wei Meng, Yonghui Song
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Patent number: 9822025Abstract: The present invention provides a novel method for treating soil-contaminated water, the method using a photocatalytic material capable of efficiently removing, by light irradiation alone, volatile organic compounds and heavy metals that give rise to soil contamination. The present invention provides a method for treating soil-contaminated water that detoxifies volatile organic compounds contained in soil-contaminated water using a photocatalytic material, the method being characterized by including the steps of (1) subjecting the soil-contaminated water to a gas-liquid separation to obtain a gas phase, and (2) decomposing the volatile organic compounds contained in the gas phase obtained in step (1) using the photocatalytic material.Type: GrantFiled: June 28, 2013Date of Patent: November 21, 2017Assignee: SHOWA CO., LTD.Inventors: Teruki Takayasu, Teruo Arai, Kinji Onoda
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Patent number: 9822026Abstract: To provide a sludge treatment method and a sludge treatment system suppressing the fuel costs which can be utilized in the existing treatment facilities that drying and discharging after dehydrating a sludge as a useful improvement for the facility. This invention provides the solution means including a dehydration step of obtaining a dehydrated sludge, a liquefaction step of obtaining a slurry-like sludge, a branching step of branching a digested sludge, a vacuum deaeration step of deaerating a first digested sludge, a reprocessing step of ejecting a high-temperature steam and returning a concentrated digested sludge, a dehydration separation treatment step of separating a second digested sludge, a step of deaerating a digested sludge, a branching step of branching the mixed phase fluid, a step of returning a first mixed phase fluid, and a step of returning a second mixed phase fluid.Type: GrantFiled: May 18, 2015Date of Patent: November 21, 2017Assignees: NIPPON ZOKI PHARMACEUTICAL CO., LTD., TECHNOPLAN INC.Inventors: Masahiro Sugano, Masakazu Sawai
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Patent number: 9822027Abstract: A glass furnace includes a furnace chamber for containing glass melt and a screw conveyor for receiving glass batch material and feeding the glass batch material to the furnace chamber. A dam wall is disposed with respect to the screw conveyor such that batch material from the screw conveyor must flow upward over the dam wall before entering the furnace chamber. The top of the dam wall may be below the level of the melt pool in the furnace chamber.Type: GrantFiled: April 25, 2014Date of Patent: November 21, 2017Assignee: Owens-Brockway Glass Container Inc.Inventors: Zhongming Wang, Scott Weil, Tilak Gullinkala, Udaya Vempati, Shivakumar S. Kadur
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Patent number: 9822028Abstract: Methods of processing a glass ribbon are provided. The method includes the step of traversing the glass ribbon through a travel path at a predetermined velocity and severing the glass ribbon to create an upstream web and a downstream web. The method further includes the step of increasing a relative velocity of a downstream edge portion with respect to an upstream edge portion to create a gap between an upstream severed edge and a downstream severed edge. In other example methods, a segment of the glass ribbon is removed to create a gap between an upstream severed edge and a downstream severed edge. In still further example methods, an upstream severed edge is directed along a second travel path to create a gap between the upstream severed edge and a downstream severed edge.Type: GrantFiled: July 21, 2015Date of Patent: November 21, 2017Assignee: Corning IncorporatedInventors: Chester Hann Huei Chang, Todd Benson Fleming, Dale Charles Marshall, Gary Edward Merz, Christopher Michael Rhoads, John Earl Tosch, Thaddeus Francis Trzeciak
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Patent number: 9822029Abstract: A method for processing a brittle plate includes a breaking step in which a pressing member for pressing a surface of the brittle plate and a support member for supporting a back face of the brittle plate are used to bend and deform the brittle plate and break the brittle plate along a score line formed on the surface of the brittle plate. The support member includes a flat portion that is arranged flat against one portion of the brittle plate to support the brittle plate, and a regulating portion that regulates a bending deformation shape of the brittle plate when the pressing member is pressed against a predetermined position of a remaining portion of the brittle plate. The breaking step includes breaking the brittle plate along the score line that is within the remaining portion of the brittle plate.Type: GrantFiled: June 14, 2016Date of Patent: November 21, 2017Assignee: Asahi Glass Company, LimitedInventors: Takashi Yamamoto, Toshiyuki Ishibashi, Mitsuhiko Endo, Masashi Kasajima
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Patent number: 9822030Abstract: Annealing treatments for modified titania-silica glasses and the glasses produced by the annealing treatments. The annealing treatments include an isothermal hold that facilitates equalization of non-uniformities in fictive temperature caused by non-uniformities in modifier concentration in the glasses. The annealing treatments may also include heating the glass to a higher temperature following the isothermal hold and holding the glass at that temperature for several hours. Glasses produced by the annealing treatments exhibit high spatial uniformity of CTE, CTE slope, and fictive temperature, including in the presence of a spatially non-uniform concentration of modifier.Type: GrantFiled: January 21, 2016Date of Patent: November 21, 2017Assignee: Corning IncorporatedInventors: Sezhian Annamalai, Carlos Alberto Duran, Kenneth Edward Hrdina, William Rogers Rosch
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Patent number: 9822031Abstract: Enamel composition, in particular intended for covering a glass pane of a fireplace insert, comprising at least one glass frit, at least one pigment in a content varying from 40 to 65% of the total weight of the enamel, preferably from 45 to 60%, and optionally at least one vehicle or medium, characterized in that the glass frit comprises the following constituents, within the limits defined below, limits included, expressed as percentages by weight of the total weight of the frit: SiO2 45-65%? Al2O3 0-13% B2O3 23-55%? Na2O 0-10% K2O 0-10% Li2O ?0-10%.Type: GrantFiled: December 13, 2010Date of Patent: November 21, 2017Assignee: EUROKERA S.N.C.Inventors: Marie-Helene Chopinet, Maike Hillers, Caroline Faillat, Pablo Vilato
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Patent number: 9822032Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).Type: GrantFiled: January 7, 2015Date of Patent: November 21, 2017Assignee: CORNING INCORPORATEDInventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
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Patent number: 9822033Abstract: Certain example embodiments relate to Ni-inclusive ternary alloy being provided as a barrier layer for protecting an IR reflecting layer comprising silver or the like. The provision of a barrier layer comprising nickel, chromium, and/or molybdenum and/or oxides thereof may improve corrosion resistance, as well as chemical and mechanical durability. In certain examples, more than one barrier layer may be used on at least one side of the layer comprising silver. In still further examples, a NixCryMoz-based layer may be used as the functional layer, rather than or in addition to as a barrier layer, in a coating.Type: GrantFiled: January 20, 2017Date of Patent: November 21, 2017Assignee: Guardian Glass, LLCInventors: Muhammad Imran, Bernd Disteldorf, Marcus Frank, Richard Blacker
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Patent number: 9822034Abstract: The present invention discloses a method for electroless plating of a metal or metal alloy onto a metal or a metal alloy structure comprising a metal such as molybdenum or titanium and alloys containing such metals. The method comprises the steps of activation, treatment in an aqueous solution comprising at least one nitrogen-containing compound or a hydroxy carboxylic acid and electroless plating of a metal or metal alloy.Type: GrantFiled: April 17, 2012Date of Patent: November 21, 2017Assignee: Atotech Deutschland GmbHInventors: Frank Brüning, Birgit Beck, Bexy Dosse, Johannes Etzkorn
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Patent number: 9822035Abstract: A technique is described for fabricating one or more optical devices in a carbon-coated optical fiber. A photosensitive optical fiber is provided having a hermetic carbon coating. Further provided is a laser having a beam output that is configured to inscribe one or more refractive index modulations into the optical fiber through the hermetic carbon layer while leaving the hermetic carbon layer intact. The laser is used to inscribe one or more optical devices into the optical fiber through the hermetic carbon layer.Type: GrantFiled: May 2, 2016Date of Patent: November 21, 2017Assignee: OFS FITEL, LLCInventors: Adam Hokansson, David J Kudelko, Yaowen Li, Joanna Y Ng, Debra A Simoff
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Patent number: 9822036Abstract: The invention discloses a rapid-hardening high-belite calcium sulfoaluminate cement clinker and relates generally to a rapid-hardening high-belite calcium sulfoaluminate cement clinker and methods to use and to manufacture the clinker. The clinker of the present invention comprises 20% to 35% by weight of C4A3S 3% to 9% by weight of C4AF, 37% to 47% by weight of C2S, 0.5% to 4.6% by weight of f-CaO and 14% to 26.3% by weight of CaSO4. The chemical compositions of the clinker are 12.9% to 16.1% by weight of SiO2, 12% to 19% by weight of Al2O3, 1% to 3% by weight of Fe2O3, 49% to 54% by weight of CaO and 12% to 18.43% by weight of SO3. It is manufactured by calcining, at a temperature of 1300° C.±50° C. in a rotary kiln, the raw meal, comprising 33% to 62% by weight of limestone, 10.5% to 28% by weight of fly ash, and 19% to 45% by weight of FGD gypsum.Type: GrantFiled: January 9, 2015Date of Patent: November 21, 2017Assignee: Tangshan Polar Bear Building Materials Co., Ltd.Inventor: Zhenqiu Zhang
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Patent number: 9822037Abstract: The invention comprises a composition comprising hyaloclastite having a volume-based mean particle size of less than or equal to 40 ?m. The invention also comprises a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 ?m. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 ?m and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed.Type: GrantFiled: May 15, 2017Date of Patent: November 21, 2017Inventor: Romeo Ilarian Ciuperca
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Patent number: 9822038Abstract: A chemically inert concrete composition includes, based on dry weight, about 50% to about 95% by weight glass particles and about 3% to about 40% by weight colloidal silica particles. Optional additional chemically inert ingredients can be included in amounts of about 3% to about 40% by weight. The concrete composition is substantially or totally free of Group I and Group II metal oxides, exclusive of the glass particles, and is substantially or totally free of cement.Type: GrantFiled: September 28, 2016Date of Patent: November 21, 2017Assignee: Magneco/Metrel, Inc.Inventors: Dominic Pautler, Michael W. Anderson, Lara Binz, Daniel Snyder
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Patent number: 9822039Abstract: Provided are metal oxide ceramic materials and intermediate materials thereof (e.g., nanozirconia gels, nanozirconia green bodies, pre-sintered ceramic bodies, zirconia dental ceramic materials, and dental articles). The nanozirconia gels are formable gels. Also provided are methods of making and using the metal oxide materials and intermediate materials. The nanozirconia gels can be made using, for example, osmotic processing. The nanozirconia gels can be used to make nanozirconia green bodies, pre-sintered ceramic bodies, zirconia dental ceramic materials, and dental article. The nanozirconia green bodies, pre-sintered ceramic bodies, zirconia dental ceramic materials, and dental articles have desirable properties (e.g., optical properties and mechanical properties).Type: GrantFiled: August 18, 2016Date of Patent: November 21, 2017Assignee: Ivoclar Vivadent AGInventors: Wei Xu, Yijun Wang, Dmitri Brodkin
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Patent number: 9822040Abstract: Inventive manufacture of CrB2—Al2O3 composites is based on pressureless sintering. According to typical inventive practice, CrB2 powder and Al2O3 powder are mixed together in selected volumetric proportions so that the volume of the CrB2 does not exceed 50% of the overall volume of the CrB2—Al2O3 mixture. The CrB2—Al2O3 mixture is shaped into a green body. The green body is pressureless sintered in a non-oxidizing atmosphere at a firing temperature in the approximate range between 1600° C. and 2050° C. The present invention succeeds in preparing, via pressureless sintering, a proportionality-associated range of compositions in the CrB2—Al2O3 system, which is a potentially “advanced” ceramic system. A typical inventively fabricated CrB2—Al2O3 composite is inventively configured in a complex shape, and has “advanced” material (e.g., mechanical) properties that are favorable for a contemplated application.Type: GrantFiled: October 6, 2008Date of Patent: November 21, 2017Assignee: The United States of America as represented by the Secretary of the NavyInventors: Curtis A. Martin, James A. Zaykoski, Inna G. Talmy
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Patent number: 9822041Abstract: Various embodiments are directed to ceramic articles. The ceramic articles include a fired ceramic honeycomb body having a plurality of cell channels and at least one plug disposed in at least one cell channel of the fired ceramic honeycomb body. The at least one plug includes a refractory filler, an inorganic binder, and an organic binder. The refractory filler comprises particles having a d50 in the range from about 10 ?m to about 40 ?m, and a d90 less than about 110 ?m.Type: GrantFiled: January 18, 2017Date of Patent: November 21, 2017Assignee: Corning IncorporatedInventors: Keith Norman Bubb, Anthony Joseph Cecce, Thomas Richard Chapman
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Patent number: 9822042Abstract: A method of hydroponic growing of plants comprising hydroponically growing the plants in the presence of a controlled release hydroponic fertilizer composition. The hydroponic fertilizer composition comprises a polymerically coated controlled release fertilization nutrient formulation which further comprises micronutrients and optionally chelated iron.Type: GrantFiled: November 8, 2016Date of Patent: November 21, 2017Assignee: Florikan E.S.A. LLCInventors: Edward Rosenthal, Eric Morris Rosenthal
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Patent number: 9822043Abstract: A system for the continuous production of a liquid fertilizer is provided. The system operates by feeding a compost material at a continuous rate to an extractor. The extractor uses a belt system to convey the compost along a path. Sprayers above the belt spray water or similar liquid water based substance onto the compost. The water absorbs nutrients and other components of the compost and is then drained through the belt to a receptacle to store the liquid fertilizer.Type: GrantFiled: November 10, 2015Date of Patent: November 21, 2017Inventor: Kevin Gunn
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Patent number: 9822044Abstract: The present disclosure provides a liquid composition, comprising a dialkylcarbonate, and one or more phosphoric triamide compounds. Also provided is a liquid composition, comprising a C1-C4 alcohol, a vegetable oil or petroleum distillate, a surfactant, and one or more phosphoric triamide compounds. A further aspect of the disclosure provides a method for treating a nitrogen-containing fertilizer, comprising contacting a nitrogen-containing fertilizer with the liquid compositions described herein.Type: GrantFiled: January 29, 2015Date of Patent: November 21, 2017Assignee: AgXplore International, Inc.Inventor: Paul Hayes
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Patent number: 9822045Abstract: A hybrid rocket solid fuel grain having a cylindrical shape and defining a center port is additive manufactured from a compound of thermoplastic fuel and passivated nanocomposite aluminum additive. The fuel grain comprises a stack of fused layers, each formed as a plurality of fused abutting concentric circular beaded structures of different radii arrayed defining a center port. During operation, an oxidizer is introduced along the center port, with combustion occurring along the exposed port wall. Each circular beaded structure possesses geometry that increases the surface area available for combustion. As each layer ablates the next abutting layer, exhibiting a similar geometry is revealed, undergoes a gas phase change, and ablates. This process repeats and persists until oxidizer flow is terminated or the fuel grain material is exhausted. To safety achieve this construction, a fused deposition additive manufacturing apparatus, modified to shield the nanocomposite material from the atmosphere is used.Type: GrantFiled: September 25, 2016Date of Patent: November 21, 2017Inventor: Ronald D Jones
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Patent number: 9822046Abstract: An alkylate base oil of biological origin and a process to make an alkylate base oil comprising: a) hydrogenating a farnesene to make a farnesane comprising from zero to less than 5 wt % unsaturated molecules; and b) alkylating the farnesane with one or more C6 to C43 olefins in the presence of an acidic alkylation catalyst to make the alkylate base oil having a kinematic viscosity at 100° C. from 3 mm2/s to 20 mm2/s.Type: GrantFiled: May 19, 2016Date of Patent: November 21, 2017Assignee: Chevron U.S.A. Inc.Inventor: Sven Ivar Hommeltoft
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Patent number: 9822047Abstract: A process is provided comprising contacting and reacting the compound CF3CF2CHXCl, wherein X is H or Cl, or the compound CF3CF?CXCl, wherein X is H or Cl, with hydrogen in the presence of a catalyst consisting essentially of Cu, Ru, Cu—Pd, Ni—Cu, and Ni—Pd, to obtain as a result thereof reaction product comprising hydrofluoropropenes or intermediates convertible to said hydrofluoropropenes, notably CF3CF?CH2 and CF3CH?CHF.Type: GrantFiled: March 22, 2017Date of Patent: November 21, 2017Assignee: THE CHEMOURS COMPANY FC, LLCInventor: Xuehui Sun
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Patent number: 9822048Abstract: A method of extending the catalyst life of a hydrogenolysis catalyst activity in the presence of biomass and aqueous solution is described. Lignocellulosic biomass solids and aqueous solution is provided to in a hydrothermal digestion unit in the presence of a digestive solvent, and a supported hydrogenolysis catalyst containing (a) sulfur, (b) Mo or W, and (c) Co, Ni or mixture thereof, incorporated into a solid metal oxide support. The lignocellulosic biomass solids in the hydrothermal digestion unit is heated to a temperature in the range of 180° C. to less than 300° C. in the presence of digestive solvent, hydrogen, and in the range of 0.15 wt. % to 12.5 wt. %, based on catalyst, of H2S or H2S source at least partially soluble in aqueous solution, and the supported hydrogenolysis catalyst forming a product solution containing plurality of oxygenated hydrocarbons, the hydrothermal digestion unit maintaining protective sulfur concentration.Type: GrantFiled: December 14, 2016Date of Patent: November 21, 2017Assignee: SHELL OIL COMPANYInventors: Andries Quirin Maria Boon, Joseph Broun Powell
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Patent number: 9822049Abstract: The present invention provides an improved process for removing heat from an exothermic reaction. In particular, the present invention provides a process wherein heat can be removed from multiple reaction trains using a common coolant system.Type: GrantFiled: October 20, 2015Date of Patent: November 21, 2017Assignee: Velocys Technologies LimitedInventors: Ivan Phillip Greager, Steven Claude LeViness, Roger Allen Harris, Andre Peter Steynberg, Jasmeer Jaichland Ramlal, Dennis Parker, John Dolan
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Patent number: 9822050Abstract: Provided are a terminal conjugated trienal acetal compound useful as an intermediate for producing a terminal conjugated trienal compound, and a method for producing a terminal conjugated trienal compound through deprotection of the terminal conjugated trienal acetal compound. More specifically, provided are a terminal conjugated trienal acetal compound represented by General Formula (1); a method for producing a (Z,E)-terminal conjugated trienal acetal compound, the method comprising the step of: reacting a phosphonium salt represented by General Formula (7) with (E)-2,4-pentadienal through Wittig reaction to obtain a (Z,E)-terminal conjugated trienal acetal compound represented by General Formula (3); and a method for producing a terminal conjugated trienal compound, the method comprising the step of: deprotecting the terminal conjugated trienal acetal compound represented by General Formula (1) to obtain a terminal conjugated trienal compound represented by General Formula (2).Type: GrantFiled: March 2, 2017Date of Patent: November 21, 2017Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Naoki Ishibashi, Shinnosuke Wakamori, Yuki Miyake, Miyoshi Yamashita, Takeshi Kinsho
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Patent number: 9822051Abstract: The present invention relates to a process for preparing acrolein from propylene by catalytic gas phase oxidation with molecular oxygen (for example air). The invention further relates to the use of particular propylene-containing starting materials, for example refinery grade propylene, for preparation of acrolein.Type: GrantFiled: May 23, 2014Date of Patent: November 21, 2017Assignee: Evonik Degussa GmbHInventors: Martin Steffan, Helmut Mueller, Philipp Roth, Christoph Weckbecker, Harald Jakob
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Patent number: 9822052Abstract: Methods for converting an alcohol, such as cyclohexanol to a ketone, such as cyclohexanone, include reacting the alcohol in the presence of a catalyst and oxygen to produce the ketone. In one exemplary embodiment, the catalyst comprises a microporous copper chloropyrophosphate framework including a plurality of noble metal nanoparticles. In one exemplary embodiment, the noble metal nanoparticles include at least one metal selected from the group consisting of platinum, palladium, and gold.Type: GrantFiled: September 29, 2016Date of Patent: November 21, 2017Assignees: ADVANSIX RESINS & CHEMICALS LLC, UNIVERSITY OF SOUTHAMPTONInventors: Alan B. Levy, Scott R. Keenan, Robert Raja, Arran M. Gill, Matthew E. Potter, Sivan A. Van Aswegen
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Patent number: 9822053Abstract: Disclosed is a method of making and using a titania supported palladium catalyst for the single step synthesis of 2-ethylhexanal from a feed of n-butyraldehyde. This titania supported palladium catalyst demonstrates high n-butyraldehyde conversion but also produces 2-ethylhexanal in an appreciable yield with maintained activity between runs. This method provides a single step synthesis of 2-ethylhexanal from n-butyraldehyde with a catalyst that can be regenerated that provides cleaner downstream separations relative to the traditional caustic route.Type: GrantFiled: January 28, 2016Date of Patent: November 21, 2017Assignee: Eastman Chemical CompanyInventors: Venkata Bharat Boppana, Kenneth Wayne Hampton, Jr., Zhufang Liu, Charles Edwan Sumner, Jr., Gerald C. Tustin, Guy Ralph Steinmetz, Melissa Page Steffey
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Patent number: 9822054Abstract: The present technology relates to a rhodium catalyzed carbonylation process of alcohols, ethers, and esters in the presence of phosphine oxide and ruthenium additives to produce carboxylic acids. In some embodiments, the technology provides for an improved method of preparing acetic acid from methyl acetate or methanol using a rhodium catalyst with a phosphine oxide and a ruthenium additive.Type: GrantFiled: January 18, 2016Date of Patent: November 21, 2017Assignee: LyondellBasell Acetyis, LLCInventors: Noel C. Hallinan, David L. Ramage, Daniel F. White
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Patent number: 9822055Abstract: The present disclosure relates to methods of removing halides from a reactor effluent comprising treating the halide containing carbonylation product with a resin or material comprising a metal ion with a metal loading of greater than 15 wt % are provided herein. In some aspects, the methods involve treating the halide containing carbonylation product with a silver loaded resin which comprises a loading of greater than 15 wt % of silver to remove inorganic or organic halides.Type: GrantFiled: June 22, 2016Date of Patent: November 21, 2017Assignee: LyondellBasell Acetyls, LLCInventors: David L. Ramage, Noel C. Hallinan, Daniel F. White
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Patent number: 9822056Abstract: A process for preparing a carboxylic acid, including a step of bringing at least one vicinal diol or at least one vicinal polyol into contact with an atmosphere including oxygen, and a catalyst, and in the absence of additional solvent.Type: GrantFiled: December 24, 2014Date of Patent: November 21, 2017Assignees: Avril, Oleon SA, Centre National de la Recherche Scientifique (CNRS), Université Claude Bernard Lyon 1Inventors: Marc Lemaire, Estelle Metay, Marc Sutter, Yann Raoul, Eric Da Silva, Sophie Sambou, Philippe Blach
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Patent number: 9822057Abstract: There is provided individual polymorphic forms of treprostinil and pharmaceutical formulations comprising the same, methods of making and using the same.Type: GrantFiled: March 7, 2014Date of Patent: November 21, 2017Assignee: United Therapeutics CorporationInventors: Ken Phares, Michael Scannell
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Patent number: 9822058Abstract: Certain compounds, or pharmaceutically acceptable salts or prodrugs thereof, are provided herein. Also provided are pharmaceutical compositions comprising at least one compound, or pharmaceutically acceptable salt or prodrug thereof, described herein and one or more pharmaceutically acceptable vehicle. Methods of treating patients suffering from certain diseases and disorders responsive to the inhibition of KMO activity are described, which comprise administering to such patients an amount of at least one compound, or pharmaceutically acceptable salt or prodrug thereof, described herein effective to reduce signs or symptoms of the disease or disorder are disclosed. These diseases include neurodegenerative disorders such as Huntington's disease.Type: GrantFiled: March 13, 2013Date of Patent: November 21, 2017Assignee: CHDI Foundation, Inc.Inventors: Leticia M. Toledo-Sherman, Celia Dominguez, Michael Prime, William Leonard Mitchell, Peter Johnson, Naomi Went
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Patent number: 9822059Abstract: The invention relates to a method for separating a mixture containing at least one carboxylic acid vinyl ester of general formula R?—C(O)O—CH?CH2 and at least one carboxylic acid of general formula R?—COOH, wherein R? in either case can be an aliphatic group having 12 to 22 C atoms or a cycloaliphatic group having 12 to 22 C atoms, or an aromatic group having 12 to 22 C atoms, and R? can be identical or different, characterized in that the carboxylic acid is converted to its anhydride R?—C(O)—O—C(O)—R? and the carboxylic acid vinyl ester is subsequently separated.Type: GrantFiled: May 21, 2015Date of Patent: November 21, 2017Assignee: Wacker Chemie AGInventors: Peter Gigler, Jürgen Stohrer
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Patent number: 9822060Abstract: A compound having a group represented by the formula (Ia): wherein R1 represents a C1 to C8 fluorinated alkyl group, R2 represents a group having an optionally substituted C5 to C18 alicyclic hydrocarbon group, and * represents a binding site.Type: GrantFiled: August 25, 2015Date of Patent: November 21, 2017Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Tatsuro Masuyama, Satoshi Yamamoto, Koji Ichikawa
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Patent number: 9822061Abstract: A compound represented by formula (1): can be produced by: a step wherein a compound represented by formula (2): is reacted with a compound represented by formula (3): thereby obtaining a compound represented by formula (4): a step wherein a compound represented by formula (4) is reacted with hypohalogenous acid or a salt thereof, thereby obtaining a compound represented by formula (5): and a step wherein a compound represented by formula (5) is reduced.Type: GrantFiled: April 8, 2015Date of Patent: November 21, 2017Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Teruki Takahashi, Kazuya Ueki, Yuta Nagashima