Patents Issued in March 20, 2018
  • Patent number: 9920151
    Abstract: The present invention relates to a method for producing polymers that are suitable for absorbing and storing aqueous liquids, and to polymers that can be obtained by this method. This invention further related to the use of such polymers. The method comprises the following steps: i. crosslinking free-radical polymerization of a monomer composition M comprising a) at least one monomer A having an ethylenic double bond and at least one neutralizable acid group or a group hydrolyzable to a neutralizable acid group, b) optionally one or more comonomers B which are different than the monomers A and have one ethylenic double bond, and c) 0.05 to 10% by weight, based on the total amount of monomers A and B, of at least one crosslinker C, in the presence of at least one polysaccharide-comprising substance S, in an aqueous liquid, where the weight ratio of the monomer composition M to the substance S is in the range from 9:1 to 1:9; and ii.
    Type: Grant
    Filed: October 26, 2012
    Date of Patent: March 20, 2018
    Assignee: BASF SE
    Inventors: Michael Diamantoglou, Christoph Hartmann
  • Patent number: 9920152
    Abstract: UV-absorbing polymers are provided that have at least one anhydride repeating unit that is covalently attached to at least one UV-absorbing moiety selected from the group consisting of functionalized dibenzoylmethanes, benzophenone sulfonamides, triphenyl triazines, and combinations thereof. Also provided are formulations comprising the UV-absorbing polymers.
    Type: Grant
    Filed: January 6, 2017
    Date of Patent: March 20, 2018
    Assignee: ISP INVESTMENTS LLC
    Inventors: Krishnamurthy Nacharaju, Osama M. Musa, Michael A. Tallon
  • Patent number: 9920153
    Abstract: Disclosed are a method of preparing a thermoplastic resin composition having superior surface clearness and gloss. More particularly, the present invention relates to a method of preparing a superior thermoplastic resin composition which has superior surface clearness and superior gloss and may prevent mold deposition during a high speed injection process, by using a reactive emulsifier during emulsion polymerization of rubber latex composed of polybutadiene, preparing resin latex using a hydrophobic initiator during graft copolymerization of rubber latex, an aromatic vinyl monomer, and a vinyl cyan monomer, compression dehydrating a moisture content to less than 10% using a compression type dehydrator after agglomerating the resin latex, and performing a wet powder extrusion process.
    Type: Grant
    Filed: June 23, 2014
    Date of Patent: March 20, 2018
    Assignee: LG CHEM, LTD.
    Inventors: Keun Hoon Yoo, Bong Keun Ahn, Dae Young Kim
  • Patent number: 9920154
    Abstract: Articles, methods of making an article, and resin compositions are disclosed. An article is disclosed that includes a cured light-curable resin having dispersed therein a reflective material that reflects at least 85% of the visible light spectrum. A loading of reflective material may be at least 3 wt. % of the article and the reflective material may comprise over 50 vol. % of a total filler composition of the article. The reflective material may be a white or near-white material, such as cellulose fibers, talc powder, or soy flour. A method is disclosed that includes mixing a reflective material that reflects at least 85% of the visible light spectrum with a photopolymer resin at a loading of at least 3 wt. % to form a resin mixture and curing the resin mixture using a light source in an additive manufacturing process. The disclosed resins may reduce the curing time of additive manufacturing processes.
    Type: Grant
    Filed: November 15, 2016
    Date of Patent: March 20, 2018
    Assignee: Ford Global Technologies, LLC
    Inventors: Amy Ellen Langhorst, Ellen Cheng-chi Lee, Deborah Frances Mielewski
  • Patent number: 9920155
    Abstract: The object of the present invention is to provide a resin particle having a protrusion that is more resistant to the detachment and having a uniform protrusion size and protrusion distribution density. The resin particle of the present invention comprises: a spherical part and a peripheral part having a plurality of convex part formed on the surface of the spherical part, wherein the spherical part and the peripheral part comprise a vinyl polymer and/or a polysiloxane component, the spherical part and the peripheral part are different in the composition, the melting point of the peripheral part is not less than 200° C., and the curvature center of the boundary between the peripheral part and the spherical part determined by a transmission electron microscope observation of the cross-section of the resin particle exists in the spherical part.
    Type: Grant
    Filed: March 18, 2015
    Date of Patent: March 20, 2018
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazuaki Matsumoto, Yohei Okubo, Tomonari Takata, Junko Kita, Naoki Kobayashi
  • Patent number: 9920156
    Abstract: The present invention discloses a block copolymer comprising a block with glass transition temperature higher than 100° C. and a method for preparing the same. In the method, latex of a block copolymer is prepared by taking n-butyl acrylate as a soft block, random copolymer of styrene and ?-methyl-?-methylene-?-butyrolactone as a hard block, utilizing emulsion polymerization system and reversible addition fragmentation chain transfer radical polymerization technology. The method utilizes an amphiphilic macromolecule reversible addition fragmentation chain transfer agent has dual function of both chain transfer agent and emulsifier, thus can achieve good control of monomer polymerization and avoid the use of traditional emulsifier; the reaction has no polymerization inhibition period, has fast reaction rate and high final conversion; colloidal particles can stably grow; product has a hard block with glass transition temperature up to 155° C.
    Type: Grant
    Filed: January 10, 2015
    Date of Patent: March 20, 2018
    Assignee: ZHEJIANG UNIVERSITY
    Inventors: Shaohong Xu, Xiang Gao, Yingwu Luo
  • Patent number: 9920157
    Abstract: The present invention relates to an alkoxysilane-terminated prepolymer, characterized in that it is obtainable by reaction of at least A) a polyol, B) a compound having two or more isocyanate groups, and C) an alkoxysilane having at least an isocyanate group and/or an isocyanate-reactive group, wherein the polyol A) comprises at least a polyethercarbonatepolyol obtainable by addition of carbon dioxide and alkylene oxides onto H-functional starter molecules. The present invention further relates to a process for preparing the alkoxysilane-terminated prepolymer of the present invention and also to a composition and a multicomponent system comprising an alkoxysilane-terminated prepolymer of the present invention. The present invention further relates to a shaped article obtainable by polymerizing the alkoxysilane-terminated prepolymer of the present invention, by polymerizing a composition of the present invention or by polymerizing a multicomponent system of the present invention.
    Type: Grant
    Filed: October 23, 2013
    Date of Patent: March 20, 2018
    Assignee: Covestro Deutschland AG
    Inventors: Jürgen Köcher, Ute Nattke
  • Patent number: 9920158
    Abstract: A coating composition for one-coat-one bake coating includes a resin, a pigment, a solvent, and a general additive. The resin is an acryl modified urethane resin manufactured by polymerizing polycarbonate diol, polyester diol, an acryl resin, and an isocyanate monomer. The coating composition using one-coat-one bake coating can provide soft texture, excellent chemical resistance, and adhesion.
    Type: Grant
    Filed: November 5, 2015
    Date of Patent: March 20, 2018
    Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATION, NOROO BEE CHEMICAL CO., LTD.
    Inventors: Eun Ju Noh, Woo Chul Jung, Min Hee Lee, Yong Chul Lee, Dea Geun Oh, Young Seok Kim, Ji Yeon Jung, Jae Beom Ahn
  • Patent number: 9920159
    Abstract: The present invention relates to a process for producing a polyurethane, comprising at least the following steps (A) bringing at least one polymer polyol into contact with an amount of from 0.1 to 20 mol %, based on the entire amount of polyisocyanate, of at least one first polyisocyanate, in order to obtain a prepolymer which in essence has terminal hydroxy groups, and (B) bringing the prepolymer from step (A) into contact with at least one second polyisocyanate and optionally with further additives, in order to obtain the polyurethane, to a polyurethane obtainable via said process, and also to the use of this polyurethane as cladding in automobiles, coatings, cables, plug connectors, solar modules, foils, moldings, shoe soles and shoe components, balls and ball components, rollers, fibers, profiles, laminates and wiper blades, hoses, cable plugs, bellows, drag cables, cable sheathing, gaskets, nonwoven fabrics, drive belts, or damping elements.
    Type: Grant
    Filed: February 24, 2014
    Date of Patent: March 20, 2018
    Assignee: BASF SE
    Inventors: Frank Prissok, Henning Wettach
  • Patent number: 9920160
    Abstract: A method for a synthesis of a polymer containing multiple epoxy groups includes steps of: under protection of nitrogen or argon, with a photosensitive free radical initiator under an ultraviolet light irradiation, initiating a mixture of a dithiol compound and alkynyl glycidyl ether or other alkynyl-containing compounds to proceed a thiol-yne polymerization, so as to obtain the polymer. The number of the epoxy groups is able to be adjusted through changing a type of a dithiol monomer, a mixing ratio of the dithiol monomer, and a mixing ratio between the alkynyl glycidyl ether and other alkynyl compounds. The present invention has advantages of: fast reaction, convenient process, easy post-processing, a large number of the epoxy groups, and adjustable and controllable content. The obtained polymer has a wide potential application in fields of coating, adhesive, ink, encapsulating material, resin for composite material, additive, high performance material, function material, and so on.
    Type: Grant
    Filed: April 29, 2015
    Date of Patent: March 20, 2018
    Assignee: ZHEJIANG UNIVERSITY
    Inventors: Chao Gao, Yaochen Zheng, Li Peng, Shengying Cai, Zhulin Weng
  • Patent number: 9920161
    Abstract: Compositions and methods for forming epoxy resin systems are provided. In one embodiment, a composition is provided for an epoxy resin system including a reaction product of an epoxy resin component and a curing agent component comprising a first amine compound having the formula R1R2R3N, wherein R1 and R2 are independently an aliphatic or alicyclic organic functional group and R3 is an alkyl group, having a backbone of 2-18 carbon atoms, and a second amine compound having one or more primary or secondary amine groups, with the stoichiometic ratio of —NH bonds of the second amine compound to the epoxy groups of the epoxy resin component being from 1:20 to about 21:20. The composition may be used to form composites, such as used in commercial wind turbine blade manufacturing.
    Type: Grant
    Filed: August 10, 2017
    Date of Patent: March 20, 2018
    Assignee: Hexion Inc.
    Inventors: Larry Steven Corley, Robert D. Farris, Carlton E. Ash
  • Patent number: 9920162
    Abstract: The invention provides a heat-shrinkable polyester film with high mechanical strength in a width direction that is orthogonal to the main shrinking direction and high tensile rupture elongation in the film width direction after being subjected to an aging treatment in a high-temperature environment. The heat-shrinkable polyester film is made from a polyester resin containing ethylene terephthalate as the main component and a monomer component that can serve as an amorphous component in an amount of 0 mol % or more and less than 1 mol % relative to the total amount of polyester resin components.
    Type: Grant
    Filed: August 28, 2013
    Date of Patent: March 20, 2018
    Assignee: Toyobo Co., Ltd.
    Inventors: Masayuki Haruta, Shintaro Ishimaru, Takuro Endo
  • Patent number: 9920163
    Abstract: The present invention relates to a polyester polyol, suitable for use in the manufacture of a polyurethane, suitable for use in the manufacture of a polyurethane, the polyester polyol having an ABA-structure, in which A represents a lactide-oligomer and in which B represents an initiator. The initiator includes a reaction product having long chain dicarboxylic acid components having 18 or more carbon atoms. The invention also relates to a method for the manufacture of the polyester polyol. The invention further pertains to polyurethanes including the before-mentioned polyester polyol as well as the use of these polyurethanes as an elastomer having a high toughness. The toughness is believed to originate from the combination of the hydrophobic character of the initiator and the hydrophilic character of the lactide parts in the polyol structure. The strength of the invented polylactide-polyurethane elastomers can be further improved by incorporating a carbodiimide in the elastomer material.
    Type: Grant
    Filed: April 15, 2013
    Date of Patent: March 20, 2018
    Assignee: PURAC BIOCHEM BV
    Inventors: Wilhelmus Jacobus Adrianus Honcoop, Chris François Hubert Schaekens, Jurgen Cornelis Henricus Maas, Mauraline Alison Maxine Gumbs
  • Patent number: 9920164
    Abstract: The present invention relates to a process for the preparation of monohydroxypolyalkylene oxides (MPAO) which are substantially free of diols, comprising the reaction of at least one monoalcohol as a starter with at least one alkylene oxide in the presence of at least one basic catalyst, the catalyst being used as a solution in water or alcohol or in solvent mixtures which comprise water and/or alcohol.
    Type: Grant
    Filed: June 16, 2010
    Date of Patent: March 20, 2018
    Assignee: BASF SE
    Inventors: Markus Klumpe, Matthias Zipplies
  • Patent number: 9920165
    Abstract: A method of making an organic salt comprising: reacting a polyphenol with a base and optionally a dihaloaromatic compound. The polyphenol is resveratrol; dihydroresveratrol; 4,4?-(but-2-ene-1,4-diyl)bis-2-methoxyphenol; 4,4?-(1,4-butane-diyl)bis-2-methoxyphenol; 1-ethyl-2-methyl-3-(4-hydroxyphenyl)-5-hydroxyindane; 4,4?-(ethane-1,1-diyl)diphenol; 5,5?-methylenebis(2-methoxy-4-methylphenol); 4,4?-methylenebis(5-isopropyl-2-methylphenol); 4,4?-(1-ethyl-2-methyl-1,3-propanediyl)bisphenol; or 5,5?-(ethane-1,1-diyl)bis(2-methoxy-4-methylphenol. The dihaloaromatic compound if present comprises a carbonyl group, a sulfonyl group, a sulfinyl group, or a phosphoryl group. There is a molar excess of the hydroxy groups of the polyphenol relative to halo groups of the dihaloaromatic compound if present. The corresponding phthalonitrile monomers and thermosets made from the organic salts are disclosed.
    Type: Grant
    Filed: March 30, 2016
    Date of Patent: March 20, 2018
    Assignee: The United States of America, as Represented by the Secretary of the Navy
    Inventors: Matthew Laskoski, Teddy M. Keller
  • Patent number: 9920166
    Abstract: The present invention relates to flame retardant thermoplastic polyurethane (TPU) compositions, and more particularly to flame retardant thermoplastic polyurethane compositions comprising non-halogen flame retardants. The TPU compositions are useful for applications where high flame performance, and optionally low smoke properties, as well as high tensile strength are desirable, such as wire and cable applications, film applications, molding applications, and the like. This invention also relates to processes to produce the non-halogen flame retardant TPU compositions and processes to produce wire and cable jacketing from such compositions.
    Type: Grant
    Filed: June 5, 2013
    Date of Patent: March 20, 2018
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Chetan M. Makadia, Ann Giovannitti-Jensen
  • Patent number: 9920167
    Abstract: A polymer having a repeating unit represented by Formula 1, wherein R1 through R14, X1, and Ar1 are the same as defined in the detailed description, and an organic light-emitting diode including the polymer are described.
    Type: Grant
    Filed: November 7, 2012
    Date of Patent: March 20, 2018
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Hye-yeon Yang, Ho-suk Kang, Jhun-mo Son, Yong-sik Jung, Mi-jeong Kim, Tae-gon Kim, Won-jae Joo, Hyeon-ho Choi, Seok-hwan Hong
  • Patent number: 9920168
    Abstract: A polymer of intrinsic microporosity having a repeating subunit including a spirobisindane imide moiety as illustrated below.
    Type: Grant
    Filed: February 26, 2016
    Date of Patent: March 20, 2018
    Assignee: Dow Global Technologies LLC
    Inventors: Robert E. Hefner, Jr., Brian L. Cramm, Ian A. Tomlinson, Lauren M. Huffman, Abhishek Roy
  • Patent number: 9920169
    Abstract: According to the present invention, a curable composition can be provided, said composition being characterized by comprising: (A) an episulfide compound; and (B) a photobase generator comprising an organoboron compound represented by general formula (1) below: (In general formula (1), R1, R2, R3, R4 and R5 may be the same as or different from one another and independently represent an alkyl group having 1 to 8 carbon atoms; and Ar1, Ar2 and Ar3 may be the same as or different from one another and independently represent a group selected from the group consisting of a phenyl group, a naphthyl group, an anthracenyl group and a phenanthryl group, each of which may have a substituent selected from the group consisting of an alkyl group, an aryl group, an alkenyl group, a cycloalkyl group and a heterocyclic group.
    Type: Grant
    Filed: June 26, 2014
    Date of Patent: March 20, 2018
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Kousuke Namiki, Hitoshi Okazaki, Eiji Koshiishi, Sawako Fuse, Kikuo Furukawa
  • Patent number: 9920170
    Abstract: A process includes utilizing biorenewable cis-3-hexenol to form a bio-derived cross-linker and utilizing the bio-derived cross-linker to form a cross-linked polymeric material.
    Type: Grant
    Filed: January 19, 2017
    Date of Patent: March 20, 2018
    Assignee: International Business Machines Corporation
    Inventors: Sarah K. Czaplewski, Brandon M. Kobilka, Joseph Kuczynski, Jason T. Wertz
  • Patent number: 9920171
    Abstract: A process includes utilizing biorenewable resveratrol or a resveratrol-derived material as a bio-derived crosslinker to form a crosslinked polymeric material.
    Type: Grant
    Filed: January 27, 2017
    Date of Patent: March 20, 2018
    Assignee: International Business Machines Corporation
    Inventors: Scott B. King, Brandon M. Kobilka, Joseph Kuczynski, Jason T. Wertz
  • Patent number: 9920172
    Abstract: A method can include consecutively batch processing at least two different polyethylene grades in pellet form in a pellet handling unit. A ratio of a melt flow index (MI) of a first polyethylene in pellet form (MIf) to a MI of a later processed polyethylene in pellet form (MIl) can be smaller than 0.30. The method can include processing an intermediate polyethylene grade in pellet form. An amount of intermediate polyethylene grade processed can be at most 1/100th of a handling capacity of the pellet handling unit. The intermediate polyethylene grade can have the same MI as the later processed polyethylene in pellet form.
    Type: Grant
    Filed: January 24, 2012
    Date of Patent: March 20, 2018
    Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Peter Stevens, Franky Fant, Daan Dewachter, Alain Brusselle
  • Patent number: 9920173
    Abstract: Rubber compounds comprising one or more rubber with polar functionality and one or more polar filler are prepared by a method comprising the steps: (i) adding a polar volatile liquid to the polar filler; (ii) mixing the one or more rubber with polar functionality with the polar volatile liquid and polar filler to produce a dispersion of the polar filler in the one or more rubber; and (iii) removing the polar volatile liquid from the dispersion. The invention Improves the consistency and uniformity of mixing of rubber compounds based on elastomers having polar functionality, such as epoxidized natural rubber, containing polar reinforcing fillers, such as precipitated silica, The compounds, when vulcanized, have improved mechanical properties. The method is particularly useful in the manufacture of vehicle tires.
    Type: Grant
    Filed: November 11, 2014
    Date of Patent: March 20, 2018
    Assignee: Tun Abdul Razak Research Centre
    Inventors: Jaymini Patel, Pamela Jean Martin, Stuart Cook
  • Patent number: 9920174
    Abstract: Provided are a thermoplastic resin shaped-article in which vacancies with satisfactory light emission efficiency are formed, and a thermoplastic resin light guide that uses the thermoplastic resin shaped-article. Pulse laser irradiation is performed in a state in which the pulse laser is focused to an inner region of a primary thermoplastic resin shaped-article, thereby forming cracks at the inner side of the primary thermoplastic resin shaped-article. Then, a heat treatment is performed at a temperature equal to or higher than a glass transition temperature of a thermoplastic resin that constitutes the primary thermoplastic resin shaped-article, thereby obtaining a thermoplastic resin shaped-article 20 in which substantially spherical vacancies 244 having minimum diameter of 30 ?m or more are formed only at the inner region distant from a surface thereof by 10 ?m or more.
    Type: Grant
    Filed: February 24, 2014
    Date of Patent: March 20, 2018
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tomonari Yoshimura, Kenji Yagi, Junichi Ikeno
  • Patent number: 9920175
    Abstract: The invention relates to prepregs and to a method for producing storage-stable polyurethane prepregs (pre-impregnated fibers) using polyols with a high content of secondary hydroxyl end groups, to composite fiber components (composite components) which are produced from the prepregs and which can be obtained by impregnating fiber-shaped materials such as woven fabrics and fleece, and to a method for producing said composite fiber components.
    Type: Grant
    Filed: April 14, 2014
    Date of Patent: March 20, 2018
    Assignee: COVESTRO DEUTSCHLAND AG
    Inventors: Florian Hupka, Marcel Schornstein, Hartmut Nefzger
  • Patent number: 9920176
    Abstract: This invention relates to catalyst supports having high surface area (SA?400 m2/g), low pore volume (PV?2 mL/g), a specific mean pore diameter range (PD=1-20 nm), and high average particle size (PS?30 ?m), supported catalysts, and supportation processes; and further relates to: high porosity (?15%) and/or low pore diameter (PD<165 ?m) propylene polymers; bimodal polymers and/or heterophasic copolymers based on the high porosity and/or low pore diameter propylene polymers; propylene polymerization processes using the supported catalysts and/or to prepare the high porosity and/or low pore diameter propylene polymers, bimodal polymers and/or heterophasic copolymers.
    Type: Grant
    Filed: April 29, 2016
    Date of Patent: March 20, 2018
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Lubin Luo, Gregory S. Day, Jian Yang, Matthew W. Holtcamp
  • Patent number: 9920177
    Abstract: Disclosed herein is a method for producing a polystyrene foam. The polystyrene is dosed with a gas and the polystyrene and gas are mixed in an extruder in order to obtain a homogenous mixture. The homogeneous mixture is cooled as it travels through the extruder and is then extruded from the die at a pressure of less than 7 MPa to form a foam with a smooth skin.
    Type: Grant
    Filed: June 6, 2013
    Date of Patent: March 20, 2018
    Assignee: NMC S.A.
    Inventors: Vincent Navez, Robert Frere, Jean-Pierre Mayeres, Emmanuel Noel
  • Patent number: 9920178
    Abstract: A compressible, thermally-conductive, removable nanocomposite gasket includes: a nanocomposite foam; and a nanoparticle filler, wherein the nanocomposite foam has a filler loading of less than approximately 20%. A compressible, thermally-conductive, removable nanocomposite gasket includes: a nanocomposite foam; a nanoparticle filler; and a metallic mesh embedded in the foam wherein the nanocomposite foam has a filler loading of less than approximately 20%.
    Type: Grant
    Filed: December 11, 2015
    Date of Patent: March 20, 2018
    Assignee: Northrop Grumman Systems Corporation
    Inventors: John A. Starkovich, Jesse B. Tice, Edward M. Silverman, Hsiao-Hu Peng
  • Patent number: 9920179
    Abstract: A method for preparing composites of polymer and fly ash particles, wherein the fly ash particles contains heterogeneous compositions of carbon and metal oxides, the method including: the steps of mixing the fly ash particles and an aqueous coating solution, including: a coating component selected from the group consisting of monomers, oligomers, pre-polymers, polymers, and combinations thereof, and an aqueous solvent serving to dissolve the coating component; and, while performing the step of mixing, initiating polymerization or crosslinking or both polymerization and crosslinking of the coating component to at least partially coat the fly ash particles with polymer or a crosslinked polymer network that agglomerates the fly ash particles and coats the surface of the fly ash particles, wherein the polymer or crosslinked polymer network formed in the step of initiating is hydrophobic.
    Type: Grant
    Filed: September 22, 2016
    Date of Patent: March 20, 2018
    Assignee: The University of Akron
    Inventor: Steven S. Chuang
  • Patent number: 9920180
    Abstract: An object is to provide a polyester resin having excellent hydrolysis resistance and good color tone and a method of producing the same. There is provided a polyester resin composition comprising a polyester resin that is prepared from a dicarboxylic acid or a dicarboxylic acid dialkyl ester and a diol as main raw material and mixed with: a copper halide; and at least one additive selected from the group consisting of compounds expressed by a formula (i) and compounds expressed by a formula (ii): MXn . . . (i) (where M denotes an alkali metal or an alkaline earth metal, X denotes at least one element selected from bromine, iodine and chlorine, and n=1 or 2); and (RCOO)nM . . . (ii) (where R denotes hydrogen or an alkyl group containing 1 to 30 carbon atoms, M denotes an alkali metal or an alkaline earth metal, and n=1 or 2).
    Type: Grant
    Filed: March 26, 2015
    Date of Patent: March 20, 2018
    Assignee: TORAY INDUSTRIES, INC.
    Inventors: Masato Akahira, Koya Kato
  • Patent number: 9920181
    Abstract: A polylactic acid resin composition includes: 0.005 parts by weight to 1.2 parts by weight of a metal phosphate represented by Formula (1): MxHyPOz??(1) (in Formula (1), M is an alkali metal atom or an alkaline earth metal atom, and x, y, and z are integers satisfying 1?x?2, 1?y?4, and 2?z?8, respectively) with respect to 100 parts by weight of a polylactic acid resin including a poly-L-lactic acid component and a poly-D-lactic acid component, wherein a crystallization enthalpy of crystals in the polylactic acid resin is not less than 5 J/g when a temperature of the polylactic acid resin composition is increased to 250° C., and the temperature is kept constant for 3 minutes, followed by decreasing the temperature at a cooling rate of 20° C./min in differential scanning calorimetry.
    Type: Grant
    Filed: September 12, 2013
    Date of Patent: March 20, 2018
    Assignee: Toray Industries, Inc.
    Inventors: Yoshitake Takahashi, Takuma Naotsuka, Yasuto Tachibana, Hiroyuki Ome
  • Patent number: 9920182
    Abstract: The invention relates to a method for manufacturing composite particles, particularly composite particles based on titanium dioxide and carbonate, with the help of combined mixing, homogenization and precipitation in a pipeline mixer based on the rotor-stator principle. The method is based on an aqueous suspension of a particulate base component (e.g. titanium dioxide), which is preferably produced in an intermediate vessel equipped with a high-speed agitator. At least one of the required precursor substances and/or a pH-controlling component for precipitating calcium carbonate, for example, is metered into the pipeline mixer, and the calcium carbonate is precipitated. The method can be operated as a continuous process or as a batch process and permits shorter production times. The composite particles produced display homogeneous dispersion of the precipitated particles and the particulate base component.
    Type: Grant
    Filed: December 9, 2014
    Date of Patent: March 20, 2018
    Assignee: Kronos International, Inc.
    Inventors: Uwe Wilkenhoener, Juergen Bender, Ingo Grosser
  • Patent number: 9920183
    Abstract: A polyacetal resin composition which, when formed into a molded article, minimizes degradation caused by contact with a fuel. This resin composition contains 100 parts by weight of a polyacetal copolymer resin, 0.1-1.0 parts by weight of a hindered phenol-based antioxidant, 0.1-2.0 parts by weight of a divalent metal oxide, and 0.5-3.0 parts by weight of an alkylene oxide adduct of an alkylamine and/or an alkylene oxide adduct of an alkylene diamine. Component contains magnesium oxide and/or zinc oxide, and component is one or more of general formulae (1) to (3). In these general formulae, X represents (C2H4O)m(C3H6O)nH, and m and n are each an integer of 0 or higher. In addition, R1 is an alkyl group having 12-18 carbon atoms, and R2 is an alkylene group having 2 or 3 carbon atoms.
    Type: Grant
    Filed: March 12, 2015
    Date of Patent: March 20, 2018
    Assignee: POLYPLASTICS CO., LTD.
    Inventors: Akihide Shimoda, Satomi Nakada
  • Patent number: 9920184
    Abstract: A production method for a rubber composition, comprising: using an internal mixer to mix/disperse a rubber wet masterbatch containing a carbon black, a hydrazide compound, an antiaging agent, and sulfur, wherein a timing when the hydrazide compound is charged into the internal mixer is not the same timing when the antiaging agent is charged thereinto but the same timing when the component sulfur is charged thereinto.
    Type: Grant
    Filed: May 7, 2014
    Date of Patent: March 20, 2018
    Assignee: TOYO TIRE & RUBBER CO., LTD.
    Inventor: Norio Minouchi
  • Patent number: 9920185
    Abstract: An apparatus and a process for modifying the surface energy of particles using a reactive gas or reactive energetic species generated in an excited and/or unstable gas stream is provided. The apparatus and process incorporates a process container, a portion of which is movable and having a shape in which the particles are tumbled during exposure to the energetic species. The resulting surface treatment allows the energy modified particles to be more easily dispersed in a liquid medium with a reduction in the occurrence of particle agglomeration or flocculation.
    Type: Grant
    Filed: April 7, 2015
    Date of Patent: March 20, 2018
    Assignee: Powder Treatment Technology, LLC
    Inventors: Rolf Thierry, Frank Thierry, George Osenga
  • Patent number: 9920186
    Abstract: Disclosed is a crosslinked polyethylene resin composition. According to the present disclosure, a crosslinked polyethylene resin composition having general allowance temperature due to excellent heat resistance characteristics, enhanced long-term workability due to superior long-term aging resistance, and water tree inhibition effects similar or better than those of conventional crosslinked polyethylene (XLPE)), and a power cable manufactured from the composition may be provided.
    Type: Grant
    Filed: March 25, 2015
    Date of Patent: March 20, 2018
    Assignee: LG CHEM, LTD.
    Inventors: Ka Ram Sun, In Gyu Park, Youn Sun Nam, Young Il Song
  • Patent number: 9920187
    Abstract: An object of the present invention is to provide an HNBR composition and an HNBR crosslinked body excellent in abrasion resistance and pressure resistance. The object is achieved by an HNBR composition containing 3 to 20 parts by weight of carbon fibers or wollastonite as a hard filler per 100 parts by weight of a hydrogenated nitrile rubber and containing 72 to 87 parts by weight of a carbon black having an average particle diameter of 40 to 50 nm, an iodine adsorption of 35 to 49 g/kg, and a DBP oil absorption of 100 to 160 ml/100 g, as well as an HNBR crosslinked body acquired by crosslinking the HNBR composition.
    Type: Grant
    Filed: March 20, 2015
    Date of Patent: March 20, 2018
    Assignee: NOK Corporation
    Inventors: Takafumi Aiba, Hideyuki Murakami, Kenichi Uchida, Akira Morio, Hiroaki Sato
  • Patent number: 9920188
    Abstract: Novel phantoms are provided herein that can accurately mimic the optical and/or acoustic properties of living tissue. The disclosed phantoms are constructed of one or more polyvinyl chloride plastisol (PVCP) gels comprising a PVC and a binary plasticizer. The phantoms can be used, for example, to calibrate or test an optical and/or acoustic detection system, such as a photoacoustic imaging system or an ultrasound imaging system.
    Type: Grant
    Filed: November 2, 2016
    Date of Patent: March 20, 2018
    Assignee: The United States of America, as represented by the Secretary, Department of Health and Human Services
    Inventors: William Vogt, Thomas Joshua Pfefer, Congxian Jia, Keith Wear, Brian Garra
  • Patent number: 9920189
    Abstract: Provided is a rubber composition for a tire tread containing: a diene rubber; silica in an amount of from 60 to 200 parts by mass per 100 parts by mass of the rubber; a polysiloxane represented by the average composition formula: (A)a(B)b(C)c(D)d(R1)eSiO(4-2a-b-c-d-e)/2; and an alkyl triethoxysilane having an alkyl group with from 7 to 20 carbon atoms. Also provided is a pneumatic tire using this rubber composition in the tire tread.
    Type: Grant
    Filed: December 27, 2016
    Date of Patent: March 20, 2018
    Assignee: The Yokohama Rubber Co., LTD.
    Inventors: Masaki Sato, Satoshi Mihara, Yoshihiro Goto
  • Patent number: 9920190
    Abstract: The present invention relates to a multimodal polyethylene composition which can be manufactured into pipes showing improved pressure resistance comprising a high density multimodal ethylene polymer component (A) having a density of at least 930 kg/m3, and a MFR21 of not more than 15 g/10 min, wherein said composition exhibits a LAOS-NLF defined as L ? ? A ? ? O ? ? S - N ? ? L ? ? F = ? G 1 ? G 3 ? ? where G1?—first order Fourier Coefficient G3?—third order Fourier Coefficient of at least 1.7. Such a polyethylene composition is useful for the manufacture of pressure pipes that exhibit improved pressure resistance and creep resistance and do not undergo sagging. Further disclosed is a process for the production of a pipe using such a multimodal polyethylene composition and a pipe comprising such a multimodal polyethylene composition.
    Type: Grant
    Filed: July 6, 2015
    Date of Patent: March 20, 2018
    Assignee: BOREALIS AG
    Inventors: Yi Liu, Alexandra Romina Albunia, Tanja Piel, Qizheng Dou, Hermann Prokschi
  • Patent number: 9920191
    Abstract: A surface property-improving agent for molded bodies made of polyolefin resins contains 50.0 parts to 90.0 parts by mass of a non-polar wax with a melting point of 50° C. to 100° C. and 10.0 parts to 50.0 parts by mass of a vinyl copolymer obtained by copolymerizing two types of monomers (b1) and (b2). The sum of the non-polar wax and the vinyl copolymer is 100.0 parts by mass. The monomer (b1) is styrene and/or acrylonitrile. The vinyl copolymer contains 0.1 parts to 49.9 parts by mass of the monomer (b1) and 0.1 parts to 9.9 parts by mass of the monomer (b2) wherein the sum of the monomer (b1) and the monomer (b2) is 10.0 parts to 50.0 parts by mass. To 100.0 parts by mass of a polyolefin resin, 0.5 parts to 10.0 parts by mass of the agent is added. The monomer (b2) is a methacryloxypropyl polyorganosiloxane.
    Type: Grant
    Filed: February 7, 2013
    Date of Patent: March 20, 2018
    Assignee: NOF Corporation
    Inventors: Yusuke Sakata, Toru Tamura, Yasushi Sugihara
  • Patent number: 9920192
    Abstract: Disclosed is a method for improving vibration damping of a substrate, such as the underbody of an automobile. The method comprises applying a plastisol which comprises a polymeric component, a general purpose plasticizer and a rosin ester resin. The fused plastisol has improved damping behavior as determined using Dynamic Mechanical Thermal Analysis.
    Type: Grant
    Filed: May 19, 2016
    Date of Patent: March 20, 2018
    Assignee: Eastman Chemical Company
    Inventors: Michael Dean Funderburg, Jr., Joseph Alexander DeLoach, Terri Roxanne Carvagno
  • Patent number: 9920193
    Abstract: Provided are: fine vinylidene fluoride resin particles which are solid and have an average particle diameter of 0.3 ?m or more but less than 100 ?m, a particle diameter distribution index of 1-2, a repose angle of less than 40°, and an average sphericity of 80 or more said fine vinylidene fluoride particles being suitable for coating materials and coating applications; and a method for producing the fine vinylidene fluoride resin particles.
    Type: Grant
    Filed: August 26, 2013
    Date of Patent: March 20, 2018
    Assignee: TORAY INDUSTRIES, INC.
    Inventors: Yuji Echigo, Makiko Saito, Itaru Asano, Yoko Wakahara, Hiroshi Takezaki
  • Patent number: 9920194
    Abstract: The present invention relates to a composition comprising a bimorphological aqueous dispersion of first and second polymer particles, wherein the first polymer particles comprise a shell and a phosphorus acid functionalized protuberating core, and the second polymer particles do not comprise a protuberating core. The composition is useful for pigmented coatings formulations.
    Type: Grant
    Filed: March 21, 2016
    Date of Patent: March 20, 2018
    Assignee: Rohm and Haas Company
    Inventors: James C. Bohling, Arnold S. Brownell, Wei Gao, Ericka Lynn Killian, Yogesh Tiwary
  • Patent number: 9920195
    Abstract: Composition comprising a polypropylene matrix (M-PP), at least one elastomeric copolymer (EP), a high density polyethylene (HDPE) being bimodal or multimodal, and a filler (F).
    Type: Grant
    Filed: June 18, 2014
    Date of Patent: March 20, 2018
    Assignee: Borealis AG
    Inventors: Klaus Bernreitner, Claudia Kniesel, Robert Gubo, Klaus Maureder
  • Patent number: 9920196
    Abstract: An object of the present invention is to prevent an occurrence of flow-mark molding defects to improve an appearance of molded articles, and as a means for achieving the object, a propylene-based block copolymer is used as an appearance improver, the copolymer comprising 80 to 60% by weight of crystalline propylene polymer portion which has an intrinsic viscosity [?]p of 0.90 dL/g or less and 20 to 40% by weight of propylene/ethylene random copolymer portion which has an ethylene content of 35 to 50% by weight and an intrinsic viscosity [?]c of 7.0 dL/g or higher ([?]c/[?]p being 7.5 to 30), in which the propylene-based block copolymer has a MFR of 10 to 50 g/10 min.
    Type: Grant
    Filed: June 19, 2014
    Date of Patent: March 20, 2018
    Assignee: JAPAN POLYPROPYLENE CORPORATION
    Inventors: Tomohiro Hosoi, Shigeo Mizukami, Masahiro Nagata, Kouichi Nakayama, Yuji Ryosho
  • Patent number: 9920197
    Abstract: A liquid binder composition for binding fibrous materials in the fabrication of resin-infusible preform is disclosed. The binder composition is an aqueous dispersion containing (a) one or more multifunctional epoxy resins, (b) at least one thermoplastic polymer, (c) one or more surfactants selected from anionic surfactants, nonionic surfactants, and combinations thereof, (d) water, and is essentially free of organic solvents. Also disclosed is an emulsification process for producing the liquid binder composition.
    Type: Grant
    Filed: June 12, 2013
    Date of Patent: March 20, 2018
    Inventors: Carmelo Luca Restuccia, Gerald Hobisch, William Jacobs, Dominique Ponsolle
  • Patent number: 9920198
    Abstract: A polycarbonate (PC) and poly(lactic acid) (PLA) blend comprising (a) Bisphenol A PC, (b) PLA, (c) a chain extender, and (d) a glycidyl methacrylate (GMA) functionalized polyolefin copolymer/terpolymer and method of manufacturing the PC and PLA blend, including blending (i) Bisphenol A PC, (ii) PLA, (iii) a chain extender, and (iv) a glycidyl methacrylate (GMA) functionalized polyolefin copolymer/terpolymer at an elevated temperature, wherein the elevated temperature is between about 250 and 300° C.
    Type: Grant
    Filed: May 6, 2016
    Date of Patent: March 20, 2018
    Inventors: Amar K. Mohanty, Yury Yuryev, Manjusri Misra
  • Patent number: 9920199
    Abstract: An improved silane modified polymer useful in adhesive compositions is made from a silane precursor material made by a process comprising reacting an organic compound having a backbone that is terminated by an amino group having at least one active amino hydrogen and a hydrolysable silane, wherein the backbone is comprised of at least one secondary amino group having one active amino hydrogen and a Michael addition acceptor compound, wherein the Michael addition compound fails to have a group reactive with an isocyanate group to form the silane precursor compound. The silane precursor compound is reacted with an isocyanate terminated polyurethane prepolymer to form a silane modified prepolymer. The silane modified prepolymer may then be cured with moisture and may be employed in an adhesive composition containing other components such as a plasticizer, catalyst and filler.
    Type: Grant
    Filed: August 26, 2015
    Date of Patent: March 20, 2018
    Assignee: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Syed Z. Mahdi, Yiyong He
  • Patent number: 9920200
    Abstract: A method for producing an asphaltic sheet having expandable graphite dispersed in one or more asphaltic components thereof, the method comprising preparing a masterbatch by combining asphalt binder and polymeric modifier at a first temperature, cooling the masterbatch to a second temperature, where the second temperature is lower than the first temperature, adding, after said step of cooling, expandable graphite to the masterbatch to thereby form an asphaltic composition including expandable graphite, and fabricating a sheet with the asphaltic composition including expandable graphite.
    Type: Grant
    Filed: July 21, 2014
    Date of Patent: March 20, 2018
    Assignee: Firestone Building Products Co., LLC
    Inventors: Wensheng Zhou, Michael Hubbard