Patents Issued in May 28, 2019
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Patent number: 10301206Abstract: A desalination system (100) having an intake unit (110) providing seawater to a pre-treatment unit (120) connected to a reverse osmosis (RO) desalination unit (130) and a post treatment unit (150). The desalination system (100) is configured to operate without any external addition of chemicals to simplify logistics and regulation concerns. The units of the system are configured to prevent biofouling, scaling and corrosion by mechanical and biological means including high flow speeds, biological flocculation of colloids, and making the water entering the RO units inhospitable to bacteria and other organisms that cause biofouling, hence preventing their settlement and removing them with the brine. Recovery rate is lowered and energy is recovered to increase the energetic efficiency and minerals that are added to the product water are taken from the brine.Type: GrantFiled: September 27, 2017Date of Patent: May 28, 2019Assignee: I.D.E. TECHNOLOGIES LTDInventors: Amnon Levy, Boris Liberman, Gal Greenberg
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Patent number: 10301207Abstract: There is provided a system and a method for regenerating a material that reduce the incidence of scaling due to scale forming contaminants. The method may include reducing a temperature of a treated material exiting a wet air oxidation unit in a scale reducing heat exchanger prior to delivery of the treated material to a second heat exchanger which heats a source waste material comprising a scale forming contaminant therein with heat from the first treated material to form a heated waste material comprising the scale forming contaminant.Type: GrantFiled: September 11, 2018Date of Patent: May 28, 2019Assignee: SIEMENS ENERGY, INC.Inventors: Curtis D. Cooley, Simon Larson, Chad L. Felch
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Patent number: 10301208Abstract: Continuous flow submerged combustion melter cooling wall panels, including a primary metal plate, and several 90 degree metal pieces welded to the primary metal plate in parallel configuration, each of the 90 degree metal pieces having metal leg plates forming a 90 degree vertex there between. Each metal leg plate has an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent 90 degree metal piece. The plurality of 90 degree metal pieces may have a length (l) such that l<L, each welded to the primary metal plate in staggered configuration to form, along with first and second end plates and a seal plate, a serpentine continuous flow coolant channel.Type: GrantFiled: August 25, 2016Date of Patent: May 28, 2019Inventor: Albert Patrick Faulkinbury
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Patent number: 10301209Abstract: The present invention relates to a method of fabricating an improved lithium silicate glass ceramic and to that material for the manufacture of blocks for dental appliances using a CAD/CAM process and hot pressing system. The lithium silicate material has a chemical composition that is different from those reported in the prior art with 1 to 10% of germanium dioxide in final composition. The softening points are close to the crystallization final temperature of 800° C. indicating that the samples will support the temperature process without shape deformation.Type: GrantFiled: July 21, 2017Date of Patent: May 28, 2019Assignee: James R. Glidewell Dental Ceramics, Inc.Inventor: Rodolfo Castillo
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Patent number: 10301210Abstract: There is provided an apparatus for molding a glass substrate, the apparatus including a pre-heating unit, a molding unit, and a cooling unit sequentially arranged, wherein the pre-heating unit includes a pre-heating body and a glass substrate holder, wherein the molding unit includes: a molding body having a vacuum port, a molding support on the molding body, the molding support being configured to support an edge of a glass substrate, and a heating element configured to heat the molding body, and wherein the cooling unit includes a cooling body and a cooling plate.Type: GrantFiled: April 28, 2016Date of Patent: May 28, 2019Assignees: Samsung Display Co., Ltd., Dowooinsys. Co., Lta.Inventors: Daesik Hong, Bonki Koo, Dongsun Kim, Jinseok Jang, Youngkuil Joo
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Patent number: 10301211Abstract: A method for forming an initiation defect in a glass substrate to facilitate separating the glass substrate into a plurality of substrates is provided. The method includes providing the glass substrate and contacting a broad surface of the glass substrate with an abrasive surface thereby forming a field of initiation defects in the broad surface of the glass substrate. The field of initiation defects has a width of at least about three millimeters between outermost initiation defects. At least one initiation defect is heated with a laser source. The at least one initiation defect is cooled with a cooling fluid such that a crack initiates from the at least one initiation defect, the crack extending through a thickness of the glass substrate and propagating across the glass substrate to separate the glass substrate into the plurality of substrates.Type: GrantFiled: November 5, 2015Date of Patent: May 28, 2019Assignee: Corning IncorporatedInventors: Donald Orrin Bigelow, Robertson Dewhurst Booth, James Joseph Watkins
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Patent number: 10301212Abstract: The amorphous, or at least partially crystalline, glass-based joining material is suitable for high-temperature applications, particularly in fuel cells and/or sensors. In addition to SiO2 and B2O3 as glass formers, the joining material similarly contains BaO and CaO, whereby the amount of Al2O3 is limited. The joining material has a coefficient of linear thermal expansion of at least 7.0·10?6 K?1 in a range of 20° C. to 300° C. The joining material can be used for joining ferritic high-grade steels and/or chromium-containing alloys and/or ceramics, such as stabilized zirconium oxide and/or aluminium oxide.Type: GrantFiled: July 25, 2017Date of Patent: May 28, 2019Assignee: SCHOTT AGInventors: Ulf Dahlmann, Sabine Pichler-Wilhelm, Jens Suffner
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Patent number: 10301213Abstract: An inorganic fiber containing silica and magnesia as the major fiber components and which further includes intended addition of lithium oxide to improve the thermal stability of the fiber. The inorganic fiber exhibits good thermal performance at 1260° C. and greater, low linear shrinkage, retains mechanical integrity after exposure to the use temperature, and exhibits low biopersistence in physiological fluids. Also provided are thermal insulation product forms prepared from a plurality of the inorganic fibers, methods of preparing the inorganic fiber and of thermally insulating articles using thermal insulation prepared from a plurality of the inorganic fibers.Type: GrantFiled: June 28, 2017Date of Patent: May 28, 2019Assignee: Unifrax I LLCInventors: Donghui Zhao, Bruce K. Zoitos, Michael J. Andrejcak, Jason M. Hamilton
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Patent number: 10301214Abstract: There are provide a liquid composition for forming a silicon oxide-based cured coating film by the sol-gel method, the liquid composition having excellent storage stability and being capable of forming a coating film excellent in durability, in particular, alkali resistance even after long-term storage. A liquid composition applied on a surface of a substrate and cured by heating to form a coating film, contains: a matrix component containing a hydrolyzable silicon compound whose content is 20 to 60 mass % as a SiO2 content when silicon atoms contained in the matrix component are converted into SiO2 to the total solid content amount in the liquid composition; a functional component containing an ultraviolet absorbent and an infrared absorbent; water; and an acid thermally decomposing at 80° C. or higher and a temperature of the heating or lower, wherein a pH increases between before and after the thermal decomposition of the acid.Type: GrantFiled: August 23, 2016Date of Patent: May 28, 2019Assignee: AGC Inc.Inventors: Shimpei Morita, Hirokazu Kodaira, Takashige Yoneda
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Patent number: 10301215Abstract: A low-E coating has good color stability (a low ?E* value) upon heat treatment (HT). The provision of an as-deposited crystalline or substantially crystalline layer of or including zinc oxide, doped with at least one dopant (e.g., Sn), immediately under an infrared (IR) reflecting layer of or including silver in a low-E coating has effect of significantly improving the coating's thermal stability (i.e., lowering the ?E* value). One or more such crystalline, or substantially crystalline, layers may be provided under one or more corresponding IR reflecting layers comprising silver.Type: GrantFiled: July 16, 2018Date of Patent: May 28, 2019Assignee: Guardian Glass, LLCInventors: Yongli Xu, Brent Boyce, Salah Boussaad, Philip J. Lingle, Jingyu Lao, Richard Vernhes
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Patent number: 10301216Abstract: Spent Claus catalyst having a high alumina content is used as an ingredient in the manufacture of Portland cements in place of all or a portion of a conventional source of alumina. The spent Claus catalyst is preferably of a small particle size and can be ground to the desired fineness before mixing with the other ingredients that are heated in a conventional kiln to produce the cement composition. Finely ground spent Claus catalyst can also be used as an additive at levels of 0.1% to 2% by weight to increase the thickening time of shallow casing cement slurries.Type: GrantFiled: July 17, 2012Date of Patent: May 28, 2019Assignee: Saudi Arabian Oil CompanyInventor: Mansour A. Al-Shafei
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Patent number: 10301217Abstract: Cementitious compositions and methods for producing the cementitious compositions are described herein. The methods can include mixing a compound of the general formula MaSibXcOd, MaSibXcOd(OH)e, MaSibXc(OH)e, or MaSibXc(OH)e.(H2O)f, wherein M comprises a metal that can react with carbon dioxide in a carbonation reaction to form a carbonate, Si forms an oxide during the carbonation reaction, X is an element other than M or Si, a, b, d, e, and f are greater than zero, and c is zero or greater, with a rapid setting hydraulic cement to produce a cementitious mixture. The methods can further include hydrating the cementitious mixture and carbonating the cementitious mixture. Carbonating the cementitious mixture can occur simultaneously with hydrating the cementitious mixture or subsequent to hydrating the cementitious mixture. In some embodiments, the non-hydraulic cement can comprise wollastonite. The hydraulic cement can be in an amount of from 5 wt % to 80 wt % of the cementitious composition.Type: GrantFiled: December 23, 2014Date of Patent: May 28, 2019Assignee: BORAL IP HOLDINGS (AUSTRALIA) PTY LIMITEDInventors: Russell L. Hill, Amitabha Kumar
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Patent number: 10301218Abstract: The low cement content strain-hardening cementitious composite is cement with a natural pozzolan replacing a significant portion of the Portland cement therein. The strain-hardening cementitious composite includes a mixture of cement, fly ash, sand, a polycarboxylic ether-based superplasticizer, and reinforcing polyvinyl alcohol fibers. The mixture is formed with a low content of Portland cement (6-12 wt %) and with ground scoria as the natural pozzolan (5-20%). The sand forms at least 22 wt % of the strain-hardening cementitious composite and is preferably in the form of sieved dune sand, having a silicon dioxide concentration of between approximately 80 and 90 wt %, and a feldspar concentration of between approximately 10 and 20 wt %. The dune sand is sieved such that the sand grains have a median diameter of less than or equal to approximately 300 ?m, and preferably have a median diameter of approximately 200 ?m.Type: GrantFiled: September 7, 2018Date of Patent: May 28, 2019Assignee: King Saud UniversityInventors: Mohammad Iqbal Khan, Galal Fares
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Patent number: 10301219Abstract: Burning and cooling carbonate rock in cocurrent regenerative lime kilns may involve alternately operating two shafts such that a first shaft operates as a burning shaft and a second shaft operates as a regenerative shaft during a first period and such that the first shaft operates as the regenerative shaft and the second shaft operates as the burning shaft during a second period. Carbonate rock introduced to upper regions of the shafts may be preheated and calcined. The carbonate rock may then be cooled in lower regions of the shafts before being discharged through discharge devices. The cooling of the carbonate rock may comprise introducing cooling air into the shafts partially through central displacement bodies in the shafts and partially through the discharge devices. Amounts of air entering through the central displacement bodies compared to the discharge devices may vary widely from the burning shaft to the regenerative shaft.Type: GrantFiled: July 28, 2014Date of Patent: May 28, 2019Assignee: MAERZ OFENBAU AGInventor: Hannes Piringer
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Patent number: 10301220Abstract: A composition for applying to a honeycomb body includes a refractory filler, an organic binder, an inorganic binder, and a liquid vehicle, wherein the refractory filler, the particle size distribution of the refractory filler, the organic binder, and the inorganic binder are selected such that, when the composition is applied to plug a plurality of channels of the honeycomb body, the plug depth variability is reduced.Type: GrantFiled: May 24, 2016Date of Patent: May 28, 2019Assignee: Corning IncorporatedInventors: Keith Norman Bubb, Anthony Joseph Cecce, Allison Elizabeth Cronin, Huthavahana Kuchibhotla Sarma, Courtney Spencer Warren
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Patent number: 10301221Abstract: A superconducting material having a strong magnetic-flux pinning by way of sites having high electronic effective mass and charge carrier density. The superconducting material involves a superconducting host material and a dopant pinning material being inert in relation to the superconducting host material and has a ?{square root over (?)}/m* in a range less than that of the superconducting host material, the dopant pinning material doping the superconducting host material.Type: GrantFiled: September 20, 2016Date of Patent: May 28, 2019Assignee: United States of America as represented by Secretary of the NavyInventor: Benjamin J. Taylor
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Patent number: 10301222Abstract: Disclosed herein are methods for preparing a titanate compound powder comprising titanate compound particles having a controlled particle size and/or particle size distribution. The methods include mixing at least one first inorganic compound chosen from sources of a first metal or metal oxide, at least one second inorganic compound chosen from sources of titania, and at least one binder to form a mixture; calcining the mixture to form a polycrystalline material comprising a plurality of titanate compound grains and a plurality of microcracks; and breaking the polycrystalline material along at least a portion of the microcracks. Also disclosed are titanate compound powders having a controlled particle size distribution, ceramic batch compositions comprising the powders, and ceramic articles prepared from the batch compositions.Type: GrantFiled: November 18, 2015Date of Patent: May 28, 2019Assignee: Corning IncorporatedInventors: Monika Backhaus-Ricoult, Robert John Locker, Huthavahana Kuchibhotla Sarma, Patrick David Tepesch
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Patent number: 10301223Abstract: Beneficial use structures are disclosed that include coal combustion residuals (“CCR”) mixed with water and a binder to form a structural material, and adapted to be compacted for use in the formation of the beneficial use structure. Various structures having beneficial uses are described, including compressed air storage facilities and a pumped hydroelectric facility, including such a facility adapted for use with a lock system of a waterway.Type: GrantFiled: June 1, 2018Date of Patent: May 28, 2019Assignee: Go Team CCR LLCInventors: Francis Norbert Hector, Jr., Juan Keith Carroll
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Patent number: 10301224Abstract: A ceramic component is generally provided that includes a silicon-based layer comprising a silicon-containing material (e.g., a silicon metal and/or a silicide) and about 0.001% to about 85% of an In-containing compound. For example, the silicon-based layer can be a bond coating directly on the surface of the substrate. Alternatively or additionally, the silicon-based layer can be an outer layer defining a surface of the substrate, with an environmental barrier coating on the surface of the substrate. Gas turbine engines are also generally provided that include such a ceramic component.Type: GrantFiled: March 13, 2018Date of Patent: May 28, 2019Assignee: General Electric CompanyInventors: Glen Harold Kirby, Julin Wan
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Patent number: 10301225Abstract: A method of fabricating a multi-perforated part out of composite material includes positioning a sand-blasting mask on a preform including a fiber texture impregnated with a polymerized ceramic-precursor resin, the mask having a plurality of openings corresponding to the perforations to be made in the preform; projecting abrasive particles at high speed against the surface of the mask so as to perforate the preform exposed in the openings of the mask; and pyrolyzing the multi-perforated preform so as to form a ceramic matrix in the multi-perforated fiber texture.Type: GrantFiled: April 2, 2015Date of Patent: May 28, 2019Assignee: SAFRAN CERAMICSInventors: Pascal Ducharlet, Xavier Martin, Jocelin Laborde
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Patent number: 10301226Abstract: A process for production of anaerobic digestate based organic fertilizer includes combining anaerobic digestate and one or more grain by-products to create a combination of anaerobic digestate and one or more grain by-products. The combination of anaerobic digestate and one or more grain by-products is processed to yield the pH adjusted anaerobic digestate based organic fertilizer product.Type: GrantFiled: April 13, 2016Date of Patent: May 28, 2019Assignee: True Organic Products, Inc.Inventor: Jacob Matthew Evans
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Patent number: 10301227Abstract: Soil improving compositions and methods of using the compositions for improving soil properties are described.Type: GrantFiled: April 14, 2017Date of Patent: May 28, 2019Assignee: DTA Consulting, LLCInventor: Paul G. Deckard
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Patent number: 10301228Abstract: Biochar is provided that is treated to have certain chemical and physical properties found to have the highest impact on plant growth and/or soil health. In particular, the following physical and/or chemical properties, among others, of a biochar have been identified as critical properties to control for in the selection of biomass feedstock, pyrolysis conditions, and/or enhancing treatment to increase biochar performance: (i) bulk density (ii) impregnation capacity; (iii) particle size distribution; (iv) solid particle density; (v) surface area; (vi) porosity; (vii) total porosity; (viii) ratio of macroporosity to total porosity (ix) content of residual organic compounds; (x) content of volatile organic compounds; (xii) ash content; (xiii) water holding capacity; (xiv) water retention capabilities; (xv) levels of dioxins and other potentially hazardous byproducts of pyrolysis; and (xvi) pH.Type: GrantFiled: October 24, 2017Date of Patent: May 28, 2019Assignee: Cool Planet Energy Systems, Inc.Inventors: Ranko Panayatov Bontchev, Han Suk Kim, Richard W. Wilson, Richard Wilson Belcher, Cameron Cheyne, Leo E. Manzer, Mark L. Jarand, Haijun Wan, Rajashekharam Malyala
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Patent number: 10301229Abstract: The present invention relates to a process for the preparation of fertilizing compositions and to the compositions obtained.Type: GrantFiled: June 27, 2014Date of Patent: May 28, 2019Assignee: Best Green Technologies Inc.Inventors: Domenico Terenzio, Aldo Perotti
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Patent number: 10301230Abstract: The present invention relates to improving the efficacy of man-made and/or natural organic-based animal manure fertilizers by administration of an organic solvent formula containing polyorganic acids and/or their salts. The formulation liberates nutrient(s) that are normally bound in the soil as insoluble salts and complexes. These delivery formulations also provide an environmentally sound and inherently safe solvating system that improves diffusion of polyorganic acids to the granule fertilizer. These delivery formulations enable safe storage, transport and subsequent application or blending with solid or liquid fertilizers. The combined formulation and fertilizer can be applied to soil to provide improved efficacy of fertilizer by liberating nutrients bound in the soil for uptake by plant life.Type: GrantFiled: June 16, 2015Date of Patent: May 28, 2019Inventors: Gary David McKnight, Randall Linwood Rayborn, Wei Xu, Zehui Yang
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Patent number: 10301231Abstract: An improved solvent system for the formulation and application of N-alkyl thiophosphoric triamide urease inhibitors. These formulations provide safety and performance benefits relative to existing alternatives and enable storage, transport and subsequent coating or blending with urea based or organic based fertilizers. These formulations are comprised primarily of environmentally friendly aprotic and protic solvents (particularly dimethyl sulfoxide and alcohols/polyols) to stabilize the urease inhibitor.Type: GrantFiled: June 28, 2017Date of Patent: May 28, 2019Inventors: Gary David McKnight, David Bruce Parker, Yang Zehni, Ray Perkins, Wei Xu
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Patent number: 10301232Abstract: Disclosed is a pepper spray composition comprising: (a) a chemical irritant; (b) a propellant, wherein the propellant comprises transHFO-1234ze; (c) a solvent, wherein said solvent comprises transHFO-1233zd; and (d) a non-ionic surfactant and/or an ionic surfactant.Type: GrantFiled: July 28, 2017Date of Patent: May 28, 2019Assignee: HONEYWELL INTERNATIONAL INC.Inventors: Madan Parvatiyar, Barbara Ruth Decaire, Ryan Hulse, Anthony Anzalone
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Patent number: 10301233Abstract: We provide a process, comprising: a. dehydrogenating natural gas liquid to produce a mixture comprising olefins and unconverted paraffins; b. without further purification or modification other than mixing with an isoparaffin, sending the mixture to a single alkylation reactor; c. alkylating the olefins with the isoparaffin, using an ionic liquid catalyst, to produce one or more alkylate products; and d. distilling the one or more alkylate products and collecting a bottoms distillation fraction that is a middle distillate blending component having a sulfur level of 50 wppm or less and a Bromine number less than 1.Type: GrantFiled: July 3, 2017Date of Patent: May 28, 2019Assignee: Chevron U.S.A. Inc.Inventors: Hye-Kyung Cho Timken, Kenneth John Peinado, Bong-Kyu Chang
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Patent number: 10301234Abstract: Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.Type: GrantFiled: January 7, 2015Date of Patent: May 28, 2019Assignee: SILURIA TECHNOLOGIES, INC.Inventors: Greg Nyce, Richard Black, Peter Czerpak, Carlos Faz, Erik Freer, Hatem Harraz, Ajay Madgavkar, Jarod McCormick, William Michalak, Bipinkumar Patel, Guido Radaelli, Tim A. Rappold, Ron Runnebaum, Erik C. Scher, Aihua Zhang, Hassan Taheri, Humera A. Rafique, Joel Cizeron, Jin Ki Hong, Wayne Schammel
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Patent number: 10301235Abstract: Systems and methods for recycling waste plastics are provided, including a system for recovering styrene monomer from waste polystyrene.Type: GrantFiled: February 17, 2017Date of Patent: May 28, 2019
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Patent number: 10301236Abstract: The disclosure relates to a method for hydrofluorination of an olefin of the formula: RCX=CYZ to produce a hydrofluoroalkane of formula RCXFCHYZ or RCHXCFYZ, wherein X, Y, and Z are independently the same or different and are selected from the group consisting of H, F, Cl, Br, and C1-C6 alkyl which is partially or fully substituted with chloro or fluoro or bromo; and R is a C1-C6 alkyl which is unsubstituted or substituted with chloro or fluoro or bromo, comprising reacting the olefin with HF in the liquid-phase, in the presence of SbF5, at a temperature ranging from about ?30° C. to about 65° C.Type: GrantFiled: May 20, 2016Date of Patent: May 28, 2019Assignee: THE CHEMOURS COMPANY FC, LLCInventors: Xuehui Sun, Mario Joseph Nappa, Karl Krause
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Patent number: 10301238Abstract: This invention provides a process for producing 2-chloro-3,3,3-trifluoropropene, comprising: reacting anhydrous hydrogen fluoride with at least one chlorine-containing compound selected from the group consisting of chloropropanes and chloropropenes represented by specific formulas in a gas phase in the presence of a chromium atom-containing fluorination catalyst while heating, the reaction being carried out in the presence of molecular chlorine or with a water content in the reaction system of 300 ppm or less. This invention enables suppression of catalyst deterioration and efficient production of 2-chloro-3,3,3-trifluoropropene in a simple and economically advantageous manner on an industrial scale.Type: GrantFiled: June 9, 2017Date of Patent: May 28, 2019Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Yuzo Komatsu, Masayuki Kishimoto
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Patent number: 10301239Abstract: A method for the preparation of polyol from an unsaturated TAG oil that can function similarly to castor oil in certain applications. The method comprises controlled epoxidation of the TAG oil with an acid and an oxidizing agent to obtain a partially epoxidized TAG oil with desired iodine and oxirane values; hydroxylating the partially epoxidized TAG oil using a monoalcohol and a solid acid catalyst to obtain the polyol. The resulting polyols are comprised of a triglyceride structure and hydroxyl values, viscosities, and colors that are similar to castor oil.Type: GrantFiled: July 29, 2016Date of Patent: May 28, 2019Inventors: Jonathan M. Curtis, Tolibjon S. Omonov, Ereddad Kharraz
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Patent number: 10301241Abstract: The present invention generally relates to processes for preparation of higher alcohols such as n-butanol from lower alcohols such as ethanol by Guerbet condensation. In some aspects, the present invention relates to improvements in n-butanol yield and selectivity by the selection of process reaction conditions such as, but not limited to, mole ratio of hydrogen to ethanol, mole ratio of acetaldehyde to ethanol, mole ratio of ethyl acetate to ethanol and/or mole ratio of carbon monoxide to ethanol.Type: GrantFiled: December 24, 2014Date of Patent: May 28, 2019Assignee: Abengoa Bioenergia Nuevas Tecnologias, S.A.Inventors: Juan Luis Sanz Yague, Jose David Martinez Perez, Yolanda Pena Gomez, Carmen Maria Reyes Valle, Mario Ramos Sanchez
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Patent number: 10301242Abstract: A method of extracting cannabidiol from hemp.Type: GrantFiled: January 21, 2017Date of Patent: May 28, 2019Assignee: Yunnan Hansu bio-technology Co.,LtdInventors: Ke Zhang, Xin Tan, Weibo Gao, Tanran Chang
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Patent number: 10301243Abstract: An industrial scale continuous process for the production and recovery of cyclohexanone from phenol and hydrogen, said process comprising: hydrogenating phenol in a phenol hydrogenation reactor; separating cyclohexanone from a hydrogenated product stream in a separation and purification section [II] comprising at least 4 distillation sections; wherein at least some of the reaction heat produced in the phenol hydrogenation reaction section [I] is applied for the production of steam; and wherein the molar ratio of cyclohexanone to phenol that is charged to said phenol hydrogenation reactor is from 0.02 to 0.10; and/or wherein the molar ratio of cyclohexanol to phenol that is charged to said phenol hydrogenation reactor is from 0.001 to 0.10.Type: GrantFiled: November 6, 2015Date of Patent: May 28, 2019Assignee: CAP III B.V.Inventors: Johan Thomas Tinge, Corinne Daguenet, Iris Verschuren, Wilhelmus Rudolf Maria Martens, Roeland Wilhelmus Theodorus Maria Brands, Robert Jan de Korte
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Patent number: 10301244Abstract: The present invention relates to a process for the preparation of an optically active carbonyl compound by asymmetric hydrogenation of a prochiral ?,?-unsaturated carbonyl compound with hydrogen in the presence of at least one optically active transition metal catalyst that is soluble in the reaction mixture and which has rhodium as catalytically active transition metal and a chiral, bidentate bisphosphine ligand, wherein the reaction mixture during the hydrogenation of the prochiral ?,?-unsaturated carbonyl compound additionally comprises at least one compound of the general formula (I): in which R1, R2: are identical or different and are C6- to C10-aryl which is unsubstituted or carries one or more, e.g. 1, 2, 3, 4 or 5, substituents which are selected from C1- to C6-alkyl, C3- to C6-cycloalkyl, C6- to C10-aryl, C1- to C6-alkoxy and amino; Z is a group CHR3R4 or aryl which is unsubstituted or carries one or more, e.g.Type: GrantFiled: April 27, 2018Date of Patent: May 28, 2019Assignee: BASF SEInventors: Mathias Schelwies, Rocco Paciello, Gunnar Heydrich, Günter Wegner, Gerd-Dieter Tebben, Martin Haubner, Andreas Keller, Oliver Bey, Stephanie Renz, Georg Seeber
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Patent number: 10301245Abstract: The present invention relates to the use of molybdenum and vanadium mixed oxides, optionally iron doped, as catalysts for the oxidation of unsaturated alcohols, in particular allyl alcohol, and also to a process for the production of unsaturated carboxylic acids, in particular acrylic acid, in the gas phase, in the presence of such a catalyst.Type: GrantFiled: June 18, 2015Date of Patent: May 28, 2019Assignees: Centre National de la Recherche Scientifique, Universite des Sciences et Technologies de Lille 1, Hokkaido University, Ecole Centrale de LilleInventors: Sébastien Paul, Benjamin Katryniok, Franck Dumeignil, Marcia Araque Marin, Toru Murayama, Wataru Ueda
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Patent number: 10301246Abstract: Processes for the catalytic dehydration of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propanoic acid, and acetic acid, are provided. The processes can be carried out either in a gas phase or in a liquid phase.Type: GrantFiled: December 16, 2015Date of Patent: May 28, 2019Assignee: The Procter & Gamble CompanyInventors: Jane Ellen Godlewski, Janette Villalobos Lingoes, Dimitris Ioannis Collias, Juan Esteban Velasquez
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Patent number: 10301247Abstract: A method of making acrylic acid in liquid phase by contacting a feed stream containing lactic acid, lactide, or mixtures thereof with a molten salt catalyst comprising a protic ionic liquid (PIL), which contains a bromide anion (Br?), is provided.Type: GrantFiled: March 7, 2018Date of Patent: May 28, 2019Assignees: The Procter & Gamble Company, Friedrich Alexander Universitat Erlangen-NurnbergInventors: Jakob Albert, Peter Wasserscheid, Nicola Taccardi, Jens Nagengast, Matthias Kehrer, Julian Kadar, Dimitris Ioannis Collias
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Patent number: 10301248Abstract: The present technology relates to synthesis of resveratrol compositions, in particular to methods of synthesizing resveratrol salicylates such as those formed through the activation of resveratrol and salicylic acid, and cosmetic and pharmaceutical compositions comprising the same.Type: GrantFiled: February 5, 2015Date of Patent: May 28, 2019Assignee: Biocogent, LLCInventors: Joseph D. Ceccoli, Michael L. Ingrassia, Christopher M. Judd, Brian R. Costello
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Patent number: 10301249Abstract: Methods and systems for producing alkyl hydroxyalkanoates from hydroxycarboxylic acid recovery bottoms. The methods generally comprise the steps of obtaining a hydroxycarboxylic acid recovery bottom, adding a mono-alcohol to the hydroxycarboxylic acid recovery bottom to obtain a first mixture, heating the first mixture, optionally in the presence of a catalyst to form a reaction product, distilling the reaction product, and recovering an alkyl hydroxyalkanoate fraction.Type: GrantFiled: April 4, 2018Date of Patent: May 28, 2019Assignee: CARGILL, INCORPORATEDInventors: Timothy Walter Abraham, Ravi R. Gokarn
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Patent number: 10301250Abstract: A method of producing an ethylenically unsaturated carboxylic acid or ester, preferably an ?, ? ethylenically unsaturated carboxylic acid or ester. The method includes contacting formaldehyde or a suitable source thereof with a carboxylic acid or ester in the presence of a catalyst and optionally in the presence of an alcohol. The catalyst includes a nitrided metal oxide having at least two types of metal cations, M1 and M2, wherein M1 is selected from the metals of group 2, 3, 4, 13 (called also IIIA) or 14 (called also IVA) of the periodic table and M2 is selected from the metals of groups 5 or 15 (called also VA) of the periodic table.Type: GrantFiled: June 21, 2016Date of Patent: May 28, 2019Assignee: LUCITE INTERNATIONAL UK LIMITEDInventors: Ian Andrew York, Sabina Zieman
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Patent number: 10301251Abstract: The present invention relates to a process for preparing methyl methacrylate by direct oxidative esterification of methacrolein. Methyl methacrylate is used in large amounts for preparing polymers and copolymers with other polymerizable compounds. In addition, methyl methacrylate is an important synthesis unit for a variety of specialty esters based on methacrylic acid (MAA) which can be prepared by transesterification with the appropriate alcohol. There is consequently a great interest in very simple, economic and environmentally friendly processes for preparing this starting material. In particular the present invention relates to an optimized workup of the reactor effluent from the oxidative esterification of methacrolein by means of which process waste streams can be minimized and process water can be recycled in optimal fashion. The methacrylic acid generated in the process is also optimally recovered and isolated or converted into the commodity alkyl methacrylate.Type: GrantFiled: September 14, 2016Date of Patent: May 28, 2019Assignee: Evonik Röhm GmbHInventors: Matthias Groemping, Steffen Krill, Alexander Lygin, Milica Lukic, Steffen Finger
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Patent number: 10301252Abstract: A process for continuously preparing the tert-butyl ester of an ethylenically unsaturated carboxylic acid, by a) reacting an ethylenically unsaturated carboxylic acid with isobutene in the presence of an acidic catalyst to give an esterification mixture; b) removing the acidic catalyst; c) removing low-boiling components; and d) supplying a tert-butyl ester-comprising liquid to a distillation apparatus and subjecting it to purifying distillation in the distillation apparatus, where d1) in the distillation apparatus the tert-butyl ester-comprising liquid is separated into a tert-butyl ester-comprising gaseous top product and a carboxylic acid-comprising liquid bottom product; d2) the tert-butyl ester-comprising gaseous top product is at least partly condensed and the condensate is recycled partly as reflux to the distillation apparatus; d3) the carboxylic acid-comprising liquid bottom product is recycled at least partly to step a); d4) carboxylic acid-comprising liquid bottom product is drawn off and passed toType: GrantFiled: November 28, 2016Date of Patent: May 28, 2019Assignee: BASF SEInventors: Catharina Horstmann, Claus Hechler, Gregor Grackiewicz, Bernd Schall
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Patent number: 10301253Abstract: Provided herein are compounds of formula I: and salts thereof and compositions and uses thereof. The compounds are useful as inhibitors of LSD1. Also included are pharmaceutical compositions comprising a compound of formula I or a pharmaceutically acceptable salt thereof, and methods of using such compounds and salts in the treatment of various LSD1-mediated disorders.Type: GrantFiled: July 24, 2017Date of Patent: May 28, 2019Assignees: GENENTECH, INC., CONSTELLATION PHARMACEUTICALS, INC.Inventors: Brian K. Albrecht, James Edmund Audia, Alexandre Cote, Martin Duplessis, Victor S. Gehling, Andrew Charles Good, Jean-Christophe Harmange, Yves LeBlanc, Christopher G. Nasveschuk, Alexander M. Taylor, Rishi G. Vaswani
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Patent number: 10301254Abstract: The present invention includes polycationic amphiphilic compounds of formula VII useful as antimicrobial agents. The present invention further includes novel polymers of polycationic amphiphilic compounds useful as antimicrobial agents. The present invention further includes methods useful for removing microorganisms and/or biofilm-embedded microorganisms from a surface. The present invention further includes compositions and methods useful for preventing or reducing the growth or proliferation of microorganisms and/or biofilm-embedded microorganisms on a surface.Type: GrantFiled: April 22, 2016Date of Patent: May 28, 2019Assignee: Temple University—Of The Commonwealth System of Higher EducationInventors: William M. Wuest, Kevin P. C. Minbiole
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Patent number: 10301255Abstract: The present invention discloses compounds of Formula (I), or pharmaceutically acceptable salts, esters, or prodrugs thereof: X-A1-Y-A2-Z-L-R??(I) which inhibit the protein(s) encoded by hepatitis B virus (HBV) or interfere with the function of the HBV life cycle of the hepatitis B virus and are also useful as antiviral agents. The present invention further relates to pharmaceutical compositions comprising the aforementioned compounds for administration to a subject suffering from HBV infection. The invention also relates to methods of treating an HBV infection in a subject by administering a pharmaceutical composition comprising the compounds of the present invention.Type: GrantFiled: July 21, 2016Date of Patent: May 28, 2019Assignee: ENANTA PHARMACEUTICALS, INC.Inventors: Yao-Ling Qiu, Wei Li, Hui Cao, Meizhong Jin, Jorden Kass, Xuri Gao, Xiaowen Peng, Yat Sun Or
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Patent number: 10301256Abstract: The present invention provides compounds and pharmaceutical compositions for treating neurological diseases such as multiple sclerosis.Type: GrantFiled: November 29, 2016Date of Patent: May 28, 2019Assignee: Alkermes Pharma Ireland LimitedInventors: Thomas Andrew Wynn, Christopher P. Hencken
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Patent number: 10301257Abstract: Compounds (A) can be used for increasing the yield of useful plants or crop plants with respect to their harvested plant organs, wherein the Compound (A) is selected from compounds of the formula (I) or salts thereof, wherein the symbols are defined as in claim 1, preferably cyprosulfamide [Compound (A1)].Type: GrantFiled: September 14, 2012Date of Patent: May 28, 2019Assignee: BAYER INTELLECTUAL PROPERTY GMBHInventors: Erwin Hacker, Georg Bonfig-Picard, Stefan Lehr, Udo Bickers, Martin Hess, Klaus Trabold, Mathias Schmidt, Frank Ziemer, Juan Pedro Ruiz-Santaella Moreno