Abstract: The present invention relates to nucleated propylene-ethylene-butylene-terpolymers comprising propylene, butylene, and ethylene, having improved stiffness, better impact behaviour and improved optical properties such as low haze, and low amounts of soluble or extractable fractions.

Abstract: Catalyst compositions and polymerization systems include at least one thioguanidine complex according to Formula (I): MQaX4_a (I) in which M is Ti, Zr, or Hf; a is 1 or 2; each group Q of the thioguanidine complex is a bidentate thioguanidine ligand bound to the metal center and having Formula (1a) or Formula (1b), In Formulas (1a) and (1b), each group R1, R2, and R3 is independently chosen from alkyl groups or aryl groups; each group Z1 is independently chosen from alkylene groups. If a=2, groups R3 of the two groups Q are optionally linked to each other through at least one covalent bond. Each X is covalently bonded or coordinated to the metal center and is independently chosen from alkyl groups or halides. The polymerization systems may be configured to copolymerize ethylene and ?-olefins.

Abstract: The invention provides compositions, each comprising an ethylene/alpha-olefin interpolymer, which has a reduced level of a low density, low molecular weight oligomeric fraction, as indicated by an HCC value, as described herein, and reduced levels of inorganic content or lower Tm. The invention also provides processes for forming such interpolymers.

Abstract: Methods for producing polyolefin polymers may use a predictive melt index regression to estimate the melt index of the polyolefin during production based on the composition of the gas phase and, optionally, the concentration of catalyst in the reactor or reactor operating conditions. Such predictive melt index regression may include multiple terms to account for concentration of ICA in the reactor, optionally concentration of hydrogen in the reactor, optionally concentration of comonomer in the reactor, optionally the catalyst composition, and optionally reactor operating conditions. One or more terms may independently be represented by a smoothing function that incorporates a time constant.

Abstract: Mono- and multi-layer films comprising a polyethylene composition which comprises the reaction product of ethylene and optionally one or more alpha olefin comonomers in the presence of a catalyst composition comprising a multi-metallic procatalyst via a solution polymerization process in at least one reactor; wherein said polyethylene composition is characterized by one or more of the following properties: a melt index, I2, measured according to ASTM D 1238 (2.16 kg @ 190° C.), from 0.1 to 5 g/10 min; density, measured according to ASTM D-792, from 0.910 to 0.935 g/cc; melt flow ratio, I10/I2, wherein I10 is measured according to ASTM D1238 (10 kg @ 190° C.), from 6 to 7.4; and molecular weight distribution, (Mw/Mn) from 2.5 to 3.5 are provided. Also provided are articles made from the mono- and/or multi-layer films.

Abstract: This invention relates to a polyethylene composition, and films therefrom, comprising at least 65 wt % ethylene derived units and from 0.1 to 35 wt % of C3-C12 olefin comonomer derived units, where the polyethylene composition has: a) an RCI,m of less than 85 kg/mol; b) a Tw1-Tw2 value of from ?15 to ?40° C.; and c) an Mw1/Mw2 value of less than 1.5 where the film has a) a heat seal initiation temperature of X ° C. or less at 5 N of force, where X=0.0015×Y(psi)+62.6 (where Y is the average 1% Secant modulus ((MD+TD)/2)) of the film; b) a dart drop impact of 300 g/mil or more; c) an MD Elmendorf tear of 230 g or more; and d) average 1% Secant modulus ((MD+TD)/2) of 20,000 psi or more.

Abstract: A catalytic system based at least on a preformation monomer which is ethylene or a mixture of ethylene and of a conjugated diene, on a metallocene of formula {P(Cp1)(Cp2)Y} or Cp3Cp4Y and on an organometallic compound as cocatalyst, Y denoting a group comprising a metal atom which is a rare earth metal, the Cp1, Cp2, Cp3 and Cp4 groups, which are identical or different, being selected from the group consisting of fluorenyl groups, cyclopentadienyl groups and indenyl groups, the groups being substituted or unsubstituted, and P being a group bridging the two Cp1 and Cp2 groups and comprising a silicon or carbon atom, is provided. Such a catalytic system exhibits an improved stability of the catalytic activity over time, in particular on storage.

Abstract: The disclosure relates to polymers including one or more 1,1-disubstitued alkene monomers. By employing a plurality of monomers and/or tailored chain structure, polymers having improved combinations of properties are achieved. The polymer may be a copolymer, preferably including two or more 1,1-disubstituted alkene monomers. The polymer may be a homopolymer having a tailored chain structure.

Abstract: A both terminal-modified conjugated diene-based polymer, which includes a functional group derived from a modification polymerization initiator and a functional group derived from a modifier, and has excellent affinity with a filler and improved mechanical properties and viscoelasticity properties, and a method for preparing the same.

Abstract: A coating composition consisting essentially of one or more aliphatic or aromatic polyisocyanates, or combinations thereof, one or more catalysts, and one or more solvents. The composition is capable of forming a hard clear protective paint coating when applied to a surface, and the polyisocyanate is allowed to react with ambient moisture. A method for applying the coating comprising filtering compressed air to reduce moisture and impurities and then applying the coating composition to a painted surface using the filtered compressed air.

Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.

Abstract: A vegetable oil-based cartilage bionic cushioning and shock-absorbing material, and a preparation method and use thereof, is provided. The vegetable oil-based cartilage bionic cushioning and shock-absorbing material is prepared from a premix A and an isocyanate mixture B; the premix A including a vegetable oil-based modified polyol, a type 1 polyether polyol, a type 2 polyether polyol, a polymer polyol, a surfactant, a foaming agent, a chain extender, a catalyst and a cell regulator; the type 1 polyether polyol is a polyether polyol with a molecular weight of 400-1000 and a hydroxyl value of 110-280 mgKOH/g; and the type 2 polyether polyol is a polyether polyol with a molecular weight of 1000-10000 and a hydroxyl value of 25-56 mg KOH/g. The material provided by the present invention is environment-friendly and breathable with open cells, and has a high cushioning effect and a low permanent compression set value.

Abstract: The invention relates to a method for producing a biomass-resource-derived polyurethane, which comprises: reacting a dicarboxylic acid and an aliphatic diol to produce a polyester polyol; and reacting the polyester polyol and a polyisocyanate compound, wherein the dicarboxylic acid contains at least one component derived from biomass resources, a content of an organic acid in the dicarboxylic acid is more than 0 ppm and not more than 1,000 ppm relative to the dicarboxylic acid, and a pKa value of the organic acid at 25° C. is not more than 3.7.

Abstract: To provide a urethane resin for sliding members which has high abrasion resistance and is considered that crosslinking points are uniformly dispersed so that molecular motion is suitably possible. Particularly, to provide the urethane resin can be advantageously used as a polishing pad. There is provided the urethane resin for polishing is obtained by polymerizing a polymerizable composition comprising (A) a polyrotaxane having a composite molecular structure formed by an axial molecule and a plurality of cyclic molecules clathrating the axial molecule and side chains having an active hydrogen group introduced into at least some of the cyclic molecules and (B) a polyiso(thio)cyanate compound.

Abstract: An aerogel according to the present invention is obtained by reacting silanol moieties on a surface of a clay; an isocyanate compound A; an isocyanate compound B; a cyclic ether compound; a solvent A; and a solvent B. Aerogels according to the present invention have good mechanical properties and good thermal insulation properties.

Abstract: Disclosed is a continuous process and device for making polybutylene terephthalate (PBT) resin, particularly high molecular weight PBT resin. Also disclosed are a device for conducting the process, and a monitoring process for determining the carboxylic acid end group concentration of the resulting PBT.

Abstract: The invention relates to processes for producing an amine adduct in which in a 1st step a polyamine (A) is reacted with a monomer (C) in the form of an epoxide, an oxetane or a cyclic carbonate to afford an (intermediate) product (AC) which in a subsequent 2nd step is reacted with a monomer (B) in the form of a lactone, an acyclic hydroxycarboxylic acid or a hydroxy-functional acyclic ester to afford a (descendant) product (ACB), wherein the polyamine (A) in each case comprises at least three amino groups (A+) selected from primary and secondary amino groups and each capable of reaction with the monomers (C) and (B), the monomer (C) contains no ester groups, no carboxyl groups and no primary or secondary amino groups and in the 1st step with ring opening and formation of a hydroxyl group (H+) reacts with one of the amino groups (A+) of the polyamine (A) with additional formation of either a carbon-nitrogen bond or a urethane bond, the monomer (B) contains no primary or secondary amino groups, has a molecular

Abstract: The present invention relates to a semi-crystalline semi-aromatic polyamide consisting of 95-100 mole % of monomeric units derived from diamine comprising aliphatic diamine comprising 5-40 mole % of a cycloaliphatic diamine, and dicarboxylic acid comprising at least 50 mole % of naphthalene dicarboxylic acid (N), or biphenyl dicarboxylic acid (B), or a combination thereof.

Abstract: The invention relates to a thermoplastic composition comprising (A) a semi-aromatic copolyamide comprising repeat units derived from diamine consisting primarily of tetramethylene diamine and hexamethylene diamine, or pentamethylene diamine and hexamethylene diamine, and dicarboxylic acid consisting primarily of terephthalic acid, having a VN of at least 100 ml/g; and (B) a reinforcing agent. The invention also relates to a plastic part made of the thermoplastic composition. The invention further relates to an automotive vehicle comprising a structural part made of the thermoplastic composition and to an electrical assembly comprising a plastic component made of the thermoplastic composition.

Abstract: The present disclosure relates to a process for preparing polymers using a plug flow reactor. The process includes providing an aqueous monomer solution comprising amide monomers; evaporating the aqueous monomer solution to form a concentrated monomer solution; and polymerizing the concentrated monomer solution in a plug flow reactor comprising a shell side and a tube side to form a first process fluid comprising polymers. The concentrated monomer solution flows on the shell side from the inlet to the outlet.

Abstract: A polyimide resin of the present invention contains a repeating unit represented by the formula (1). X1 is a tetravalent organic group having at least one ring structure, and each two of four carbonyl groups bonded to X1 form a pair and, together with X1 and a nitrogen atom, form a five-membered ring. R2 is a hydrogen, an alkyl group having 1-9 carbon atoms, or an alkoxy group having 1-10 carbon atoms. Y is a divalent organic group having a phenolic hydroxyl group. The polyimide resin of the present invention can be practically used as a thermosetting resin composition or a positive type photosensitive resin composition.

Abstract: This disclosure relates to a polyimide polymer that includes the reaction product of: (a) at least one diamine selected from the group consisting of a diamine of Structure (I) Structure (I) (b) at least one tetracarboxylic acid dianhydride, and optionally (c) at least one compound containing a first functional group reactive with an amine or an anhydride and at least one second functional group selected from the group consisting of a substituted or unsubstituted alkenyl group and a substituted or unsubstituted alkynyl group. Each variable in the above formula is defined in the specification.

Abstract: Embodiments relate to an organopolysiloxane composition which includes: an organopolysiloxane polymer containing a silicon-bonded hydroxyl group or a silicon-bonded hydrolysable group; light calcium carbonate having a specific surface area according to the BET method of 15 to 35 m2/g; heavy calcium carbonate having a specific surface area according to the BET method of 0.5 to 5 m2/g; a curing accelerating catalyst; and a silane-based curing agent, wherein the mixing weight ratio of the light calcium carbonate and the heavy calcium carbonate is 1:0.04 to 1:0.25, and the silane-based curing agent is a compound represented by the following formula: Gx-Si—R4-x, G is selected from the group consisting of alkoxy, acetoxy, oxime, and a hydroxy group, R is selected from the group consisting of a C1 to C10 alkenyl group, a C1 to C10 alkynyl group, and a C6 to C10 aryl group, and X is 2, 3, or 4.

Abstract: The present invention generally relates to silicone hydrogel contact lenses each inherently having, on lens surfaces, a relatively-high concentration of primary amino groups and to a method for producing the same. The invention is also related to silicone hydrogel contact lens precursors each inherently having, on lens surfaces, a relatively-high concentration of N-Boc-protected primary amino groups which can be easily and conveniently deprotected during lens extraction and/or hydration steps.

Abstract: A copolymer composition that includes a silicone copolymer, methods of making the composition, and articles that include the composition, wherein the copolymer composition includes a silicone copolymer having a backbone composition that includes: silicone segments in an amount of 5 wt-% to 40 wt-%, based on the total weight of the silicone copolymer; hydrophilic segments in an amount of 40 wt-% to 75 wt-%, based on the total weight of the silicone copolymer; and reinforcing segments in an amount of 5 wt-% to 30 wt-%, based on the total weight of the silicone copolymer, wherein the reinforcing segments are derived from the reaction of one or more chain extenders with one or more multi-functional isocyanates, multi-functional carboxylic acids, multi-functional anhydrides, multi-functional esters, and/or multi-functional acid halides; wherein the silicone segments, hydrophilic segments, and reinforcing segments are connected through urea, urethane, amide, and/or oxamide linkages; wherein the hydrophilic segments

Abstract: The invention provides a polymerizable composition and a hydrogel obtained or obtainable from the polymerizable composition. The polymerizable composition comprises cucurbituril and a first monomer having a guest for the cucurbituril, wherein the total monomer concentration, Cmon, within the polymerizable composition is at least 0.5 M. The composition may be an aqueous composition.

Abstract: Disclosed are methods of functionalizing lignin using reactive extraction. The invention also generally relates to functionalized lignin. An exemplary method for producing functionalized lignin is disclosed, which comprises: providing a residue comprising lignin and cellulose; subjecting the residue to a liquid comprising an organic compound, thereby forming a first mixture; wherein the subjecting is performed at a first temperature of about 100° C. or less; and wherein the first mixture comprises: a first liquid fraction comprising solubilized functionalized lignin, wherein the solubilized functionalized lignin is functionalized with the organic compound; and a first solid fraction comprising cellulose.

Abstract: A process for producing non-surface modified nanocellulose particles in the form of a powder, comprising the steps of i. providing a suspension of never-dried, non-surface modified nanocellulose particles in an aqueous liquid, which is non-solubilising for the non-surface modified nanocellulose particles, and which is water or an aqueous solution of morpholine or piperidine or mixtures thereof, ii. contacting the suspension of non-surface modified nanocellulose particles with a fluid in a supercritical state, which fluid is miscible with the aqueous liquid and is non-solubilising for the non-surface modified nanocellulose particles, under conditions suitable for the transfer of the aqueous liquid into the fluid in a supercritical state, iii. removing the aqueous liquid and the fluid in a supercritical state by controlling pressure and/or temperature, to form the non-surface modified nanocellulose particles, and iv.

Abstract: Provided are, a spherical powder aggregate which is formed from a material including a core material, a binder, and a thickener, and which has a particle size of 1.0-6.0 mm, a breaking strength of 5.0-25.0 N, and a strain ratio of 6.0-30.0%; and a production method for the spherical powder aggregate.

Abstract: Existing methods of extrusion and other techniques to compound host and additives material uniformly disperse the additive in the host. This innovation uses ball milling to a coat a host particle with an additive dramatically reducing the additive required to achieve a percolative network in the host.

Abstract: In some aspects, the disclosure relates to processes involving a two-component resin system to provide a composite matrix binder. The first component may be a liquid reactive diluent, like an epoxidized vegetable oil, and the second component may be a solid, powdered polymer component, like a carboxylic functional acrylic or polyester, that may react with the liquid component. The liquid component may wet and coat the filler materials, while the powdered resin may soften/melt at higher temperatures below its threshold reactive temperature, thus allowing it to flow, diffuse and mix with the liquid component. This facilities processing and allows use of higher molecular weight resins and/or a higher Tg polymers without solvent use. When used in stone composite formulations with fillers like quartz and/or titanium dioxide, example resulting products have high hardness, very low water absorption, and high mechanical strength along with stain, chemical, and heat resistance.

Abstract: A process is provided for making a silica masterbatch, that contains silica and solution-made rubber. The silica masterbatch has physical properties similar to those found in a comparable dry-mixed composition, but the silica masterbatch can be incorporated more easily and less expensively into tires and other rubber products than the dry-mixed composition. A process is also provided for making a masterbatch of silica, a solution-made rubber and an emulsion-made rubber.

Abstract: The invention relates to a crosslinkable polymer composition (1), comprising a crosslinkable polymer material (2), particularly a polyolefin, preferably a polyethylene, additives (3), a first initiator (4) and a second initiator (5), wherein said first initiator (4) and second initiator (5) are different.

Abstract: This disclosure discloses a preparing method of transforming commercial base thermoplastics into germ-repellent resins or functional masterbatch through plasma and (melt)mixing assisted grafting process. The resins or masterbatch concentrate composition enable a number of product reforming processes, including but not limited to thermoforming, profile extrusion, injection molding, blow molding, blow filming, film casting, and spinning into articles of different shapes and geometries or overmolding on plastic substrates that can resist surface adsorption of microbes after solidification.

Abstract: Methods of cross-linking or chain extending a polymeric material including a silane-modified poly(arylene ether) polymer (Si-PAE) in a shaped article include heating the shaped article from a temperature T1 to a temperature T2>T1, while maintaining the temperature at which the shaped article is heated within a specified range based on the increasing Tg of the polymeric material during the heating. Shaped articles cross-linked or chain extended by the methods are also described.

Abstract: The present invention relates to a textile fiber structure comprising man-made fibers fortified by a binder comprising a polymer latex obtained from the emulsion polymerization in aqueous medium of a mixture of ethylenically unsaturated monomers comprising: (a) an aliphatic conjugated diene (b) a vinyl aromatic compound; (c) an ethylenically unsaturated silane bearing at least one silicon bonded hydrolysable group, and (d) an ethylenically unsaturated acid and to its use in construction applications, and to the use of the above binder to fortify textile fiber structures.

Abstract: Polyvinyl-co-acetal films having a thickness of 1 ?m to 1000 ?m and containing less than 10 wt. % plasticizer are suitable for use as a hot melt in molding operations, exhibiting shorter cycle times as compared to conventional polyvinyl acetals. The polyvinyl-co-acetals are obtained by reacting at least one polyvinyl alcohol with at least two different aliphatic keto compounds, each containing 2 to 10 carbon atoms.

Abstract: In an embodiment, a monolayer, sealable film includes polyethylene; and between about 0.2 wt % and about 10 wt % of a branched cyclic olefin copolymer (bCOC) comprising: between about 50 wt % to about 98 wt % ethylene; and between about 2 wt % and about 50 wt % cyclic olefin derived monomer units. In another embodiment, a receptacle for containing organic material (such as food), gas, and/or fluent material includes a storage zone; a sealing zone extending around at least a portion of the storage zone; and a film structure having an exterior surface and a storage side surface facing the storage zone, wherein the film structure comprises a gas barrier film, comprising: polyethylene; and between about 0.2 wt % and about 10 wt % of a branched cyclic olefin copolymer (bCOC) comprising: between about 50 wt % and about 98 wt % ethylene; and between about 2 wt % and about 50 wt % cyclic olefin derived monomer units.

Abstract: Provided is a laminate including: a base material; and an anti-fogging layer provided on at least a part of the base material, in which the anti-fogging layer contains a siloxane binder, silica particles, and a water absorption organic polymer, the anti-fogging layer has a structure in which the silica particles are deposited, an irregular structure due to the silica particles is formed on a surface of the anti-fogging layer, and voids are formed inside the anti-fogging layer, a film density of the anti-fogging layer is in a range of 0.80 g/cm3 to 1.40 g/cm3, and a film thickness of the anti-fogging layer is in a range of more than 1 ?m and 10 ?m or less.

Abstract: Process for reducing fogging from high melt strength polypropylene (HMS-PP) obtained by heat treating polypropylene at a temperature between 150° C. and 300° C. in the presence of a dialkyl peroxydicarbonate, said process involving the introduction of an anhydride to said high melt strength polypropylene.

Abstract: A method is designed to prepare foamed, opacifying elements each having a target light blocking value (LBVT) of at least 3, using a textile fabric substrate with a light blocking value (LBVS). The LBVT-S difference is calculated; a foamable aqueous composition is chosen; a dry coating weight for the foamable aqueous composition (when foamed) is determined to form a single dry opacifying layer that is foamed, dried, and densified to provide a dry thickness at least 20% less than the original dry thickness. The single dry opacifying layer a has light blocking value that is equal to LBVT-S, ±15%. The desired foamable aqueous composition can be chosen from a set of similar compositions to achieve the desired LBVT with the noted textile fabric substrate using suitable mathematical formula relating dry coating weight to light blocking value and a suitable data processor.

Abstract: A foam that includes a polylactide polymer in the form of a star polymer having at least three arms. The foam is an open cell foam having a density no greater than 0.1 g/cm3.

Abstract: The crosslinked polyolefin foam of the present invention is a crosslinked polyolefin foam made by crosslinking and foaming a polyolefin-based resin composition comprising a polypropylene-based resin and an elastomer, wherein the polypropylene-based resin being contained in an amount of 45 to 85 mass % based on the total resin components in the polyolefin-based resin composition, the crosslinked polyolefin foam having a 25% compressive strength of 60 to 120 kPa and a ratio of integral value of area under curve value of a stress-strain curve from 0% strain to 25% strain to a product of a strain of 25% and a stress at 25% strain of 0.45 to 0.65.

Abstract: The present invention is related to expandable vinyl aromatic polymers comprising from 1 to 10% by weight of homogeneously dispersed coke particles having a volume median particle diameter (D50) comprised between 0.5 and 8.5 ?m and from 0.1 to 5% by weight of a halogenated block copolymer. The invention further is related to a method for producing said expandable vinyl aromatic polymers and to the expanded foams.

Abstract: A foam rubber molded produce obtained by molding a rubber composition containing 100 parts by mass of ethylene-?-olefin-nonconjugated diene copolymer, 4 to 30 parts by mass of amorphous 4-methyl-1-pentene copolymer, 2 to 8 parts by mass of blowing agent, and a sulfur-based vulcanizing agent, and having a Mooney viscosity after kneading (ML1+4, 100° C.) of 54 or less. A specific gravity is 0.3 to 0.8, a compression set is less than 27%, and a foam state is an interconnected cell.

Abstract: The present invention provides expanded beads comprising a crosslinked multi-block copolymer containing an ethylene block and an ethylene-?-olefin copolymer block, having an apparent density of 40 to 300 g/L, a gel fraction of 30 to 70% by weight by a hot xylene extraction method, an average cell diameter (a) of 50 to 180 ?m, and an average surface layer thickness (b) of 3 to 27 ?m, and the expanded beads are excellent in in-mold moldability, and can produce an expanded beads molded article being excellent in tensile characteristics in a well balanced manner.

Abstract: The present invention relates to an expanded beads molded article containing a block copolymer of a polyethylene block and an ethylene-?-olefin copolymer block and having a density of 30 kg/m3 or more and less than 150 kg/m3 and a modulus of repulsion elasticity of 60% or more. The sole member of the present invention includes the expanded beads molded article of the present invention.

Abstract: Provided is a low-dielectric porous polymer film having a low dielectric constant at high millimeter-wave frequencies and thereby useful as a sheet for a millimeter-wave antenna. The low-dielectric porous polymer film comprises: a base material layer made of a polymer material and formed with fine pores dispersed therein; and a substantially smooth skin layer made of the same polymer material as that of the base material layer and formed on at least one of the surfaces of the base material layer.

Abstract: Provided is a low-dielectric porous polymer film having a low dielectric constant at high millimeter-wave frequencies and thereby useful as a sheet for a millimeter-wave antenna. The low-dielectric porous polymer film is made of a polymer material and formed with fine pores dispersed therein, wherein the film has a porosity of 60% or more, and the pores have an average pore diameter of 10 ?m or less.

Abstract: The present invention pertains to a porous polyimide film production method and a porous polyimide film produced using said method, said method including: a step (1) in which a poly(amic acid) solution comprising 40%-97% by mass organic polar solvent and 3%-60% by mass poly(amic acid) having an intrinsic viscosity, comprising tetracarboxylic acid units and diamine units, of 1.0-3.0 is cast in film form and immersed in or caused to come in contact with a coagulating solvent having water as an essential component thereof, and a porous film of poly(amic acid) is produced; and a step (2) in which the porous film of poly(amic acid) obtained in said step is heat treated and imidized. Shrinkage in the film longitudinal direction and transverse direction after heat treatment is suppressed to no more than 8% for each direction and the speed of temperature increase in a temperature range of at least 200° C. during the heat treatment is at least 25° C./min.