Surface Contains Light Reacted Material Patents (Class 101/456)
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Silicon-containing resist underlayer film-forming composition having halogenated sulfonylalkyl group
Patent number: 11022884Abstract: A resist underlayer film allows an excellent resist pattern shape to be formed when an upper resist layer is exposed to light and developed using an alkaline developing solution or organic solvent; and composition for forming the resist underlayer film. A resist underlayer film-forming composition for lithography, the composition including, as a silane, hydrolyzable silane, hydrolysis product thereof, hydrolysis-condensation product thereof, or combination, wherein the hydrolyzable silane includes hydrolyzable silane of Formula (1): R1aR2bSi(R3)4?(a+b)??Formula (1) [where R1 is an organic group of Formula (2): —R4—R5—R6??Formula (2) (where R4 is optionally substituted C1-10 alkylene group; R5 is a sulfonyl group or sulfonamide group; and R6 is a halogen-containing organic group)]. In Formula (2), R6 may be a fluorine-containing organic group like trifluoromethyl group.Type: GrantFiled: July 9, 2015Date of Patent: June 1, 2021Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Wataru Shibayama, Kenji Takase, Makoto Nakajima, Satoshi Takeda, Hiroyuki Wakayama, Rikimaru Sakamoto -
Patent number: 10153675Abstract: A stator for an electric machine has a stator block and at least one first and one second phase winding. The first and second phase windings are supplied with current having different phases. At least one stator slot is formed in the stator block. Several layers of the first phase winding and several layers of the second phase winding are arranged in the stator slot. One layer of the first phase winding defines a layer of the second phase winding in the stator slot.Type: GrantFiled: November 10, 2014Date of Patent: December 11, 2018Assignee: LEANTEC Motor GmbHInventors: Udo Mueller, Soeren Hein
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Patent number: 9783559Abstract: ?-Ketophosphonic acid according to general formula I: in which A=an aliphatic C1-C18 radical which can be interrupted by —O—, —S—, —CO—O— or —O—CO—C—; n=1, 2, 3 or 4; m=1 or 2; X=absent or a C1-C10 radical which can be interrupted by —O—, —S—, —CO—C—, —O—CO—NH— or —CO—NR1—, wherein R1 is H or C1-C7-alkyl; and PG=a group which can undergo free radical polymerization. The ?-ketophosphonic acids are suitable in particular for the preparation of dental materials.Type: GrantFiled: May 27, 2014Date of Patent: October 10, 2017Assignee: Ivoclar Vivadent AGInventors: Norbert Moszner, Yohann Catel, Thorsten Bock
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Patent number: 9777102Abstract: A modified novolak phenolic resin is obtained by reacting a novolak phenolic resin containing at least 50 wt % of p-cresol with a crosslinker. This method increases the molecular weight of the existing novolak phenolic resin containing at least 50 wt % of p-cresol to such a level that the resulting modified novolak phenolic resin has heat resistance enough for the photoresist application.Type: GrantFiled: December 4, 2014Date of Patent: October 3, 2017Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Yoshinori Hirano, Hideyoshi Yanagisawa
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Patent number: 9648751Abstract: The method for producing a electroconductive sheet having a substrate, in particular made of paper, and an electroconductive layer include the steps of: a/ preparing a multi-layer structure with an anti-adhesive coating inserted between a plastic film and a base layer, b/ cross-laminating the multi-layer structure and the substrate, and c/ removing the plastic film and the anti-adhesive coating from the base layer. The base layer is a layer of an electroconductive material or is covered with an electroconductive layer by an additional step consisting of: d1/ depositing an electroconductive film on the base layer; or d2/ printing the base layer with at least one ink having electrical properties, with the base layer being a printable layer with a binder base of which the rate is 15% greater in dry weight in relation to the total dry matter weight of this layer.Type: GrantFiled: December 21, 2012Date of Patent: May 9, 2017Assignee: ARJO WIGGINS FINE PAPERS LIMITEDInventors: Gaël Depres, Jean-Marie Vau
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Patent number: 9481788Abstract: The present invention relates to a process for preparing stable aqueous epoxy resin dispersions with polyvinyl alcohol (PVOH) in finely divided, solid, or granular form as a primary dispersant, and stable aqueous epoxy resin dispersions made thereof. Specifically, the process is a solvent free continuous extrusion dispersion process.Type: GrantFiled: June 24, 2013Date of Patent: November 1, 2016Assignee: Dow Global Technologies LLCInventors: Liang Chen, Liang Hong, David L. Malotky
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Patent number: 9310681Abstract: A negative resist composition containing as base resin a novolak resin having repeating unit “a”, wherein R1 represents a hydrogen atom, a hydroxy group, or any of a linear, a branched, or a cyclic alkyl group, alkoxy group, acyl group, acyloxy group, and alkoxy carbonyl group, these groups having 1 to 6 carbon atoms; and R2 represents a hydrogen atom, any of a linear, a branched, or cyclic alkyl group having 1 to 6 carbon atoms, alkenyl group having 2 to 10 carbon atoms, aryl group having 6 to 10 carbon atoms, which may contain a hydroxy group, an alkoxy group, an ether group, a thioether group, a carboxyl group, an alkoxy carbonyl group, and an acyloxy group. “A” is within the range of 0<a?1. A negative resist composition, a chemically amplified resist composition, having a high resolution, pattern profile after exposure, and high durability as a permanent film.Type: GrantFiled: December 9, 2014Date of Patent: April 12, 2016Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Jun Hatakeyama, Hiroyuki Urano, Masashi Iio
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Patent number: 8900798Abstract: On-press developable, negative-working, infrared radiation-sensitive lithographic printing plate precursors have an imageable layer on a substrate. The imageable layer includes a free radically polymerizable component, an initiator composition capable of generating free radicals upon exposure to infrared radiation, a polymeric binder, a first infrared radiation absorbing compound that has a tetraaryl pentadiene chromophore, and a second infrared radiation absorbing compound that is different than the first infrared radiation absorbing compound. The first IR absorbing compound absorbs in both the IR and visible regions of the electromagnetic spectrum and provides coloration for visual inspection of the lithographic printing plates.Type: GrantFiled: October 18, 2010Date of Patent: December 2, 2014Assignee: Eastman Kodak CompanyInventors: Celin Savariar-Hauck, Gerhard Hauck
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Patent number: 8877426Abstract: A printing plate comprises a substantially planar substrate, a porous non-anodic ungrained coating, having a thickness within the range of about 0.1 to about 30 microns and comprising at least one of metals, metal oxides and admixtures thereof, and an image recording layer, provided that where the porous coating consists essentially of oxide(s) only, it comprises at least one oxide of copper, magnesium, cadmium, aluminum, zirconium, hafnium, thorium, chromium, tungsten, molybdenum and (or) cobalt, and further provided that where the porous coating consists essentially of alumina only, it comprises specified pores. The invention also relates to an article of manufacture having a nanometric porous surface layer comprising at least one of metals, metal oxides and mixtures thereof, which comprises pores in the surface layer having a width in a range 0-100 nm, and wherein a major number of pores in this range have a width in a band of about 1 to about 30 nm.Type: GrantFiled: October 3, 2005Date of Patent: November 4, 2014Assignee: Acktar Ltd.Inventors: Dina Katsir, Zvi Finkelstein, Yuri Zarnitsky
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Patent number: 8445179Abstract: A method for treating a lithographic printing plate including the step of applying a liquid containing a surfactant to the plate, characterized in that the surfactant includes at least one hydrophilic segment including polyglycerol, and at least one hydrophobic segment selected from an optionally substituted alkylene group, an alkyl or aryl substituted poly(meth)acrylate, an optionally substituted polyester, polyether, polyurethane, polycarbosilane, polysiloxane, polystyrene and/or a polymer including a perfluoroalkyl group with the proviso that the liquid is not applied as a fountain solution.Type: GrantFiled: June 10, 2008Date of Patent: May 21, 2013Assignee: Agfa Graphics NVInventors: Peter Maessen, Hubertus Van Aert
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Patent number: 7895945Abstract: A method for imaging a printing form, in particular within a press, is disclosed. A printing form having a rewritable surface being provided, and an imaging material being applied to the surface of the printing form in order to provide a permanent and erasable image. During imaging, in a first step the imaging material is sprayed onto the surface with a relatively low resolution in an image data-oriented manner, and in a second step the imaging material sprayed onto the surface being exposed on the surface with a relatively high resolution in an image data-oriented manner.Type: GrantFiled: September 27, 2006Date of Patent: March 1, 2011Assignee: Man Roland Druckmaschinen AGInventor: Dirk Probian
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Patent number: 7841278Abstract: A method for treating a re-imageable printing form includes surface modifying a surface of the printing form acting as a printing area in a nanoscopic range by chemically functionalizing the surface through covering with molecules, in particular amphiphilic molecules or polymers. The printing form is subjected to a primary process of imaging by laser radiation, and subjected to a primary process of application of at least one lithographic fluid, for example dampening solution, printing ink and/or varnish. The molecules are fixed in image regions by the primary process of imaging. The molecules are removed in non-image regions substantially by at least one primary process different than the application of printing ink, in particular by imaging, application of dampening solution or chemical developing. An apparatus for treating a re-imageable printing form, a machine for processing printing material and a method for treating a surface contacting printing material, are also provided.Type: GrantFiled: December 19, 2007Date of Patent: November 30, 2010Assignee: Heidelberger Druckmaschinen AGInventors: Matthias Schlörholz, Martin Gutfleisch, Harald Latzel, Michaela Hoffmann, Gerald Erik Hauptmann, Uwe Tessmann
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Patent number: 7833689Abstract: A lithographic printing plate precursor comprising a support and an image-recording layer containing at least one infrared absorbing agent of a cyanine dye in which a HOMO energy level of each of substituents present on both terminal nitrogen atoms is ?10.0 eV or higher.Type: GrantFiled: September 27, 2006Date of Patent: November 16, 2010Assignee: Fujifilm CorporationInventors: Yu Iwai, Hideakzu Oohashi
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Patent number: 7824840Abstract: Positive-working imageable elements comprise a radiation absorbing compound and inner and outer layers on a substrate having a hydrophilic surface. The inner layer comprises a specific polymeric binder represented by Structure (I): -(A)w-(B)x-(C)y-(D)z-??(I) wherein A represents recurring units derived from one or more N-alkoxymethyl (alkyl)acrylamides or alkoxymethyl (alkyl)acrylates, B represents recurring units derived from one or more ethylenically unsaturated polymerizable monomers having a pendant cyano group, C represents recurring units derived from one or more ethylenically unsaturated polymerizable monomers having one or more carboxy, sulfonic acid, or phosphate groups, D represents recurring units derived from one or more ethylenically unsaturated polymerizable monomers other than those represented by A, B, and C, w is from about 3 to about 80 weight %, x is from about 10 to about 85 weight %, y is from about 2 to about 80 weight %, and z is from about 10 to about 85 weight %.Type: GrantFiled: August 10, 2007Date of Patent: November 2, 2010Assignee: Eastman Kodak CompanyInventors: Jayanti Patel, Ting Tao, Shashikant Saraiya
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Patent number: 7767384Abstract: A method for making a heat-sensitive negative-working lithographic printing plate precursor including the steps of providing a support having a hydrophilic surface or which is provided with a hydrophilic layer, and applying onto the support a coating solution including an infrared absorbing agent, hydrophobic thermoplastic polymer particles, a hydrophilic binder, and a polymer including siloxane and/or perfluoroalkyl monomeric units.Type: GrantFiled: November 24, 2005Date of Patent: August 3, 2010Assignee: Agfa Graphics NVInventors: Joan Vermeersch, Marc Van Damme
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Patent number: 7700265Abstract: An image forming method in which a planographic printing plate precursor having, on a support, an image recording layer containing (A) a polymerization initiator, (B) a polymerizable compound, and (C) a binder polymer, and having photosensitivity in a wavelength range of 250 nm to 420 nm, is subjected to exposure using laser light in the wavelength range of 250 nm to 420 nm, and a one-pixel drawing time is one millisecond or less, a planographic printing plate precursor having the image recording layer which further contains (D) a compound having a polymerizable group and a support adsorptive group, or (F) a filler, and a planographic printing method including development-on-machine, are provided.Type: GrantFiled: March 24, 2005Date of Patent: April 20, 2010Assignee: Fujifilm CorporationInventors: Satoshi Hoshi, Hiroshi Sunagawa, Toshifumi Inno, Naonori Makino, Gaku Kumada, Norio Aoshima
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Patent number: 7700264Abstract: A photosensitive resin composition containing an alkali soluble resin, an ethylenically unsaturated compound, a near infrared absorbing dye, a compound containing a halomethyl group and a compound containing an organoboron anion, wherein the alkali soluble resin is an acryl resin having one or more pendant groups in which both terminals of a diol compound have been blocked with isophorone diisocyanates and then (meth)acryloyl has been added. Also provided is an image forming material having a substrate, and a photosensitive layer formed by the photosensitive resin composition on the substrate, as well as an image forming method.Type: GrantFiled: October 31, 2006Date of Patent: April 20, 2010Assignee: Nippon Paint Co., Ltd.Inventor: Hirotoshi Umemoto
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Patent number: 7618762Abstract: A polymer having a polymerizable group and an alkyleneoxy groups on side chains thereof, and a polymerizable composition containing the polymer. The polymerizable composition preferably contains a polymerizable compound and a polymerization initiator. Also provided is a planographic printing plate precursor having a polymerizable layer on a hydrophilic support, the polymerizable layer containing a polymer having a polymerizable on a side chain thereof. The planographic printing plate precursor can form an image without being subjected to an alkali development. An undercoat layer containing a specific copolymer may be provided between the support and the photopolymerizable layer.Type: GrantFiled: March 10, 2008Date of Patent: November 17, 2009Assignee: Fujifilm CorporationInventors: Kazuto Kunita, Sumiaki Yamasaki
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Patent number: 7615323Abstract: Lithographic printing plate precursor comprising (a) a lithographic substrate with a hydrophilic surface and (b) a radiation-sensitive coating on the hydrophilic surface comprising (i) one or more types of monomers and/or oligomers and/or polymers, each comprising at least one ethylenically unsaturated group accessible to a free radical polymerization, (ii) at least one sensitizer, and at least one coinitiator capable of forming free radicals together with the sensitizer (ii); characterized in that the at least one sensitizer is an oligomeric or polymeric compound comprising the following structural unit (Formula (I)), wherein ?1 is an aromatic or heteroaromatic unit or a combination of the two so that a conjugated n-system is present between the two groups Z in structure (I), each Z independently represents a heteroatom, each R1 and R2 is independently selected from a halogen atom, an alkyl, aryl, alkylaryl or aralkyl group, a group —NR3R4 and a group —OR5, each R3, R4 and R5 is independently selected from aType: GrantFiled: November 11, 2005Date of Patent: November 10, 2009Assignee: Kodak Graphic Communications, GmbHInventors: Bernd Strehmel, Harald Baumann, Udo Dwars, Detlef Pietsch, Axel Draber, Michael Mursal
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Patent number: 7592128Abstract: The present invention relates to negative-working imageable elements that can be used for the manufacture of printing plates. These imageable elements can be developed on on-press by the action of a lithographic printing ink used in combination with either water or a fountain solution. The imageable elements comprise an imageable layer that is not removable in water or fountain solution alone. The imageable layer includes a free radically polymerizable compound, a free radical initiator composition, an infrared radiation absorbing compound, and a polymeric binder comprising poly(alkylene oxide) pendant groups, and preferably additionally pendant cyano groups.Type: GrantFiled: August 7, 2006Date of Patent: September 22, 2009Assignee: Eastman Kodak CompanyInventors: Jianbing Huang, Kevin B. Ray, Scott A. Beckley
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Patent number: 7422840Abstract: The invention pertains to an apparatus and a process for forming a printing form from a photosensitive element having a cylindrical support, and in particular, to an apparatus and a process for thermally treating the photosensitive element to form a relief pattern and particularly to form a cylindrically-shaped flexographic printing form. The apparatus and process includes supporting the cylindrical support to accommodate thermal treating of photosensitive elements with various sizes of the cylindrical support.Type: GrantFiled: November 8, 2005Date of Patent: September 9, 2008Assignee: E.I. du Pont de Nemours and CompanyInventors: Dietmar Dudek, Allan Banke, Soren Michael Juul Jorgensen, Helmut Luetke, Andreas Koch
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Patent number: 7358034Abstract: A method of deactivating and on-press developing an exposed lithographic printing plate is disclosed. The plate comprises on a substrate a photosensitive layer developable with ink and/or fountain solution and capable of hardening upon exposure to a radiation. The plate is exposed with the radiation, deactivated, and then on-press developed with ink and/or fountain solution. The deactivation of the exposed plate allows the handling of the plate under regular office light or any other light without causing the hardening of the non-exposed areas of the photosensitive layer.Type: GrantFiled: February 18, 2006Date of Patent: April 15, 2008Inventor: Gary Ganghui Teng
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Patent number: 7341815Abstract: A positive planographic printing plate precursor includes a support having disposed thereon a lower thermosensitive layer containing a water-insoluble but alkali-soluble polymer compound and an upper thermosensitive layer containing a water-insoluble but alkali-soluble polymer compound, with alkali-solubility increasing under heat, wherein (i) both the upper thermosensitive layer and the lower thermosensitive layer contain an IR absorbing dye, with the ratio of the IR absorbing dye concentration in the upper thermosensitive layer to the IR absorbing dye concentration in the lower thermosensitive layer is 1.6 to 10.0, and/or (ii) the upper thermosensitive layer and the lower thermosensitive layer contain different IR absorbing dyes, and/or (iii) at least one of the upper thermosensitive layer and the lower thermosensitive layer contains an IR absorbent having, in one molecule, at least two chromophoric groups that absorb IR light, with the chromophoric groups bonding to each other via a covalent bond.Type: GrantFiled: June 26, 2002Date of Patent: March 11, 2008Assignee: FUJIFILM CorporationInventors: Akio Oda, Hideo Miyake, Tomoyoshi Mitsumoto, Takeshi Serikawa, Ikuo Kawauchi, Ippei Nakamura
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Patent number: 7214469Abstract: The present invention provides a lithographic printing plate precursor and a lithographic printing method using the lithographic printing plate precursor, which is capable of an image recording by infrared laser scanning and an on-press development and excellent in fine line reproducibility and press life while maintaining good on-press developing properties, the lithographic printing plate precursor comprising: a support; and an image recording layer capable of being removed by a printing ink and/or a fountain solution, in which the image recording layer comprises an infrared absorber and a graft polymer having a specific graft chain.Type: GrantFiled: December 22, 2004Date of Patent: May 8, 2007Assignee: Fujifilm CorporationInventor: Sumiaki Yamasaki
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Patent number: 7194956Abstract: There is prepared a printing plate on which a material being hydrophilic due to light energy at a first temperature and being hydrophobic at a second temperature due to heat energy which is lower than the first temperature is provided. First, the whole surface of the printing plate is forcibly made either one of hydrophobic or hydrophilic. Next, a region having the other nature out of hydrophobic and hydrophilic is formed so as to correspond to an image to be printed. Then, ink is supplied onto the region having hydrophobic nature to conduct offset printing.Type: GrantFiled: September 10, 2004Date of Patent: March 27, 2007Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobufumi Mori, Takao Nakayama, Takashi Nakamura, Koji Kamiyama
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Patent number: 7183038Abstract: A lithographic printing plate precursor comprises an image-forming layer containing a polymerization initiator and a polymerizable compound, and a hydrophilic support, wherein the lithographic printing plate precursor comprises a compound containing at least one functional group having an interaction with a surface of the hydrophilic support.Type: GrantFiled: July 22, 2004Date of Patent: February 27, 2007Assignee: Fuji Photo Film Co., Ltd.Inventors: Sumiaki Yamasaki, Naonori Makino, Toshifumi Inno
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Patent number: 7152530Abstract: A printing form (10) having a surface (12) of pure silicon or of a silicon ceramic, which bears a pattern composed of hydrophilic and hydrophobic regions, the hydrophilic regions having a first chemical state and the hydrophobic regions having a second chemical state that differs from the first chemical state, in hydrophobic regions, the surface (12) having silicon atoms, to which at least one organic terminal group is attached in each instance. The organic terminal group may be, in particular, an unsubstituted or halogenated aryl terminal group or alkyl terminal group and be attached via an Si—C, Si—O—C or Si—O—Si—C bond. Also a method for modifying the wetting properties of the printing form, the surface (12) being brought into a first chemical state having a first wetting property, and a portion of all regions of the surface (12) being brought into a second chemical state having a second wetting property by modifying the chemical terminal groups of the surface (12).Type: GrantFiled: December 11, 2003Date of Patent: December 26, 2006Assignee: Heidelberger Druckmaschinen AGInventors: Andreas Schmohl, Peter Hess
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Patent number: 7146909Abstract: An image forming material, a lithographic printing plate precursor and a lithographic printing method, in which a color image with good visibility is obtained by laser exposure, are provided, wherein the image forming material and the lithographic printing plate precursor each comprising a support and a layer comprising a compound represented by formula (1) which changes from a colorless state to a colored state by the effect of heat; and a lithographic printing method comprising on-press development using the lithographic printing plate precursor:Type: GrantFiled: July 19, 2005Date of Patent: December 12, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Hidekazu Oohashi, Kazuto Kunita
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Patent number: 7074545Abstract: Disclosed are a printing plate material capable of being developed on a printing press and its manufacturing method which comprises the steps of subjecting an aluminum plate to electrolytic surface roughening treatment, subjecting the electrolytic surface roughened aluminum plate to etching treatment in an aqueous alkali solution, subjecting the resulting aluminum plate to anodization treatment, whereby an aluminum support is obtained, and providing on the aluminum support an image formation layer which contains thermoplastic particles and a light-to-heat conversion dye and changes in color due to infrared laser exposure.Type: GrantFiled: December 4, 2003Date of Patent: July 11, 2006Assignee: Konica Minolta Holdings, Inc.Inventor: Takahiro Mori
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Patent number: 7060416Abstract: Alkali soluble copolymers, imageable elements useful as lithographic printing plate precursors that contain the alkali soluble copolymers, and methods for forming images using the imageable elements are disclosed.Type: GrantFiled: March 4, 2005Date of Patent: June 13, 2006Assignee: Eastman Kodak CompanyInventors: Kevin B. Ray, Anthony Paul Kitson, John Kalamen
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Patent number: 7051652Abstract: A wet offset printing form has atop layer containing a photocatalytically and thermally modifiable material. The material can be brought photocatalytically into a hydrophilic state by irradiation with light and into a lipophilic state by heating. The hydrophilic state forms a surface that can be illustrated and the lipophilic state forms an illustrated surface. The top layer of the wet offset printing form may contain absorption centers for irradiation, especially for laser radiation in the NIR range, with which heating of the top layer in the pattern of an image is brought about.Type: GrantFiled: March 28, 2002Date of Patent: May 30, 2006Assignee: Maschinenfabrik WIFAGInventors: Matthias Riepenhoff, Olivier Stehlin
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Patent number: 7014985Abstract: A thermal negative type presensitized plate provided with an image recording layer hardened by infrared rays on an aluminum support, wherein the aluminum support has on the surface thereof, a grain shape with a structure in which a grained structure with medium undulation with a specified aperture diameter and a grained structure with small undulation with a specified aperture diameter are superimposed. For the presensitized plate, contact characteristics between the image recording layer and the support and scum resistance on a non-image area are kept compatible with each other at a high level, a thermal diffusion depression effect by which an energy generated by exposure can be efficiently used to form an image is excellent, and sensitivity is high.Type: GrantFiled: March 13, 2003Date of Patent: March 21, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Kei Kikuchi
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Patent number: 6972167Abstract: A negative type planographic printing plate in which recording can be performed directly from digital data of a computer or the like using an infrared laser. Sensitivity of the plate is high, ablation by a recording layer during recording is suppressed, a developing property is good, occurrence of a film residue does not occur, and image forming properties such as halftone dot reproducibility are excellent. The negative type planographic printing plate has on a supporting body, in the following order, a first layer that contains a polymer insoluble in water and soluble in an alkaline aqueous solution, and a second layer that contains a cross-linking or polymeric compound, which forms a covalent bond by action of light or heat and lowers solubility of the second layer in an alkaline developing liquid.Type: GrantFiled: May 3, 2001Date of Patent: December 6, 2005Assignee: Fuji Photo Film Co., Ltd.Inventor: Keitaro Aoshima
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Patent number: 6912956Abstract: Disclosed is a printing plate material comprising a substrate and a component layer provided thereon, the substrate having a center line average surface roughness Ra of from 0.2 to 1.0 ?m, and an oil-retention volume A2 of from 1 to 10, wherein the center line average surface roughness Ra is obtained from three dimension surface roughness measurement according to JIS-B-0601, and wherein an image is capable of being recorded on the component layer by imagewise exposure of infrared laser.Type: GrantFiled: October 24, 2003Date of Patent: July 5, 2005Assignee: Konica Minolta Holdings, Inc.Inventor: Takahiro Mori
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Patent number: 6911295Abstract: The positive planographic printing plate precursor of the present invention is a precursor comprising (I) a positive recording layer including a water-insoluble and alkali-soluble polymer compound and a light to heat converting agent, on a support having a hydrophilic surface in which a hydrophilic graft polymer chain is present. The precursor may further comprise (II) a lower layer including a water-insoluble and alkali-soluble polymer compound between the recording layer and the support.Type: GrantFiled: July 30, 2002Date of Patent: June 28, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Koichi Kawamura, Miki Takahashi, Sumiaki Yamasaki
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Patent number: 6905803Abstract: A lithographic printing plate precursor is disclosed, which comprises an image-forming layer which contains a hydrophilic resin, an acid precursor and at least one component selected from fine particles containing a compound having a vinyloxy group and microcapsules containing a compound having a vinyloxy group, on a hydrophilic support, which can be development processed on a printing machine.Type: GrantFiled: July 14, 2003Date of Patent: June 14, 2005Assignee: Fuji Photo Film Co., Ltd.Inventor: Kazuo Maemoto
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Patent number: 6890688Abstract: This invention relates to a lithographic template, a method of forming the lithographic template and a method for forming devices with the lithographic template. The lithographic template (10, 110, 210) is formed having a substrate (12, 112, 212) and a charge dissipation layer (20, 120, 220), and a patterned imageable relief layer, (16, 116, 216) formed on a surface (14, 114, 214) of the substrate (10, 110, 210) using radiation. The template (10, 110, 210) is used in the fabrication of a semiconductor device (344) for affecting a pattern in the device (344) by positioning (338) the template (10, 11, 210) in close proximity to semiconductor device (344) having a radiation sensitive material (334) formed thereon and applying a pressure (340) to cause the radiation sensitive material to flow into the relief image present on the template (10, 110, 210).Type: GrantFiled: December 18, 2001Date of Patent: May 10, 2005Assignees: Freescale Semiconductor, Inc., University of Texas SystemInventors: David P. Mancini, Douglas J. Resnick, Carlton Grant Willson
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Patent number: 6868787Abstract: Disclosed is a printing plate precursor composed of a substrate and provided thereon, a hydrophilic layer having a center line average roughness Ra of from 150 nm to less than 1000 nm and having effective protrusions of from 500 to less than 3000 per mm2, the effective protrusions protruding from an upper plane 1.0 ?m farther from the substrate than a center roughness plane in the three dimensional roughness plane of the hydrophilic layer, and having a ratio H/D of not less than 0.15, wherein H represents a height (?m) from the upper plane of the effective protrusions, and D represents a size (?m) of solids formed by the upper plane and the curved surface protruding from the upper plane of the effective protrusions.Type: GrantFiled: February 6, 2003Date of Patent: March 22, 2005Assignee: Konica CorporationInventor: Takahiro Mori
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Patent number: 6866985Abstract: With the method according to the invention for producing a printing plate, in particular for flexoprinting, a layer of a curable elastomer is applied to a carrier (15) with a cylindrical surface area (26), subsequently the elastomer layer is cured to an essentially cylindrical endless printing form blank and possibly ground to a cylindrical peripheral form or processed otherwise, and afterwards the printing form blank (33) is separated along a line which is essentially parallel to the axial direction of the carrier and the printing plate produced in such a manner.Type: GrantFiled: May 10, 2001Date of Patent: March 15, 2005Assignee: Polywest Kunststofftechnik Saueressig & Partner GmbH & Co. KGInventors: Heinz W. Lorig, Stephan Lorig
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Patent number: 6851366Abstract: Presented is a reusable printing form including a printing area that has a metal oxide surface, in particular a native oxidized titanium surface, which is treated with at least one amphiphilic organic compound whose polar region has an acidic character. In an advantageous embodiment, n-heptadecanyl hydroxamic acid {CH3-(CH2)16-C(O)—NH—OH} and/or n-octadecanyl phosphonic acid {CH3-(CH2)17-P(O)—(OH)2} is used. Also described is a method for imaging a reusable printing form. The reusable printing form can be used for offset printing.Type: GrantFiled: June 13, 2003Date of Patent: February 8, 2005Assignee: Heidelberger Druckmaschinen AGInventors: Martin Gutfleisch, Gerald Erik Hauptmann, Harald Latzel, Gerhard Peiter
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Patent number: 6851364Abstract: A printing plate material which can be adapted to digitization of the printing process and recycled and a method for renewing it. As the printing plate material, there can be used one which includes a substrate on the surface of which a coat layer containing a titanium oxide photocatalyst and at least one member selected from salts or oxides of Fe2+, Ni2+, Mn2+, Cr3+, and Cu2+ is formed. In an initial state of the printing plate as prepared, it is adjusted to a state where the surface of the coat layer is hydrophobic. This surface is irradiated with ultraviolet rays to convert a part of the surface to a hydrophilic surface. This conversion is performed based on digital data corresponding to an image to be printed. In this case, the hydrophobic portion is used as a printing image portion and the hydrophilic portion is used as a non-printing image portion.Type: GrantFiled: February 7, 2000Date of Patent: February 8, 2005Assignee: Mitsubishi Heavy Industries, Ltd.Inventor: Yasuharu Suda
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Patent number: 6851365Abstract: A method for producing multicolor printing, by using printing plates provided digitally with images and/or print, represents an efficient solution for multi-color printing, in particular in a large format. Printing plates, which had been used in a printing press, are removed from the printing form cylinders, are sent to a device for neutralization, and are neutralized. The neutralized printing plates are fixed at correct registration in an exposure and development unit where they are exposed and developed. The printing plates provided with new images are again applied to the printing form cylinder.Type: GrantFiled: February 1, 2001Date of Patent: February 8, 2005Assignee: Koenig & Bauer AktiengesellschaftInventor: Arndt Jentzsch
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Patent number: 6833225Abstract: A lithographic printing method forming a uniform layer of a hydrophobic substance on the entire surface of a printing plate precursor having a titanium dioxide-containing surface layer, by irradiating the surface of the precursor with active light to form imagewise hydrophilic areas to make a printing plate, said active light is far-ultraviolet light having a wavelength of 250 to 320 nm.Type: GrantFiled: March 1, 2002Date of Patent: December 21, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Hisao Ooishi
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Patent number: 6818372Abstract: A lithographic printing plate precursor comprising a hydrophilic support having provided thereon an image-forming layer containing a radical initiator, an infrared absorbing dye, and at least one component selected from fine particles containing a radical polymerizable compound having the specific structure and microcapsules encapsulating a radical polymerizable compound having the specific structure.Type: GrantFiled: March 7, 2002Date of Patent: November 16, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuto Kunita, Hiromitsu Yanaka
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Patent number: 6815139Abstract: A method of making a lithographic printing master is disclosed which comprises the steps of providing an imaging material which comprises a lithographic base having a hydrophilic surface and a non-ablative image-recording layer which is removable in a single-fluid ink or can be rendered removable in a single-fluid ink by exposure to heat or light; image-wise exposing the image-recording layer to heat or light; processing the material by supplying to the image-recording layer a single-fluid ink which is an emulsion of an ink phase and a non-aqueous polar phase. The use of single-fluid ink as processing liquid is a simple, convenient method for the on-press processing of the above defined material.Type: GrantFiled: December 7, 2001Date of Patent: November 9, 2004Assignee: Agfa-GevaertInventor: Jo Vander Aa
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Patent number: 6806031Abstract: Disclosed is a presensitized plate, having an anodized layer and recording layer provided on a support for a lithographic printing plate, wherein the anodized layer is provided by subjecting an aluminum plate to graining and anodizing treatments. The presensitized plate has wide development latitude, makes it difficult for scratch-like non-image portions to be generated and facilitates handling in usual operation.Type: GrantFiled: May 15, 2001Date of Patent: October 19, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadashi Endo, Yoshitaka Masuda, Atsuo Nishino, Akio Uesugi, Katsuyuki Teraoka, Hisashi Hotta
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Publication number: 20040189960Abstract: Plate positioning and processing method and apparatus are disclosed. A plate is conveyed in a predetermined first direction so that the plate is in contact with a pair of first positioning pins. The plate is laterally moved contacting with the first positioning pins until reference positions displaced from contacting positions of the plate with the first positioning pins contact with the first positioning pins. A predetermined first processing is applied to the plate. The plate subjected to the first processing is conveyed in a predetermined second direction so that the plate is in contact with a pair of second positioning pins in positions different from the reference positions of front edge of the plate. The plate contacting with the second positioning pins is laterally moved until the same positions as the reference positions contact with the second positioning pins.Type: ApplicationFiled: March 18, 2004Publication date: September 30, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Akihiro Hashiguchi
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Patent number: 6796235Abstract: A process for imaging a lithographic printing plate having a coating containing diazo resins. An ink jet printer is used to apply micro drops of a basic chemical solution that insolubilizes the affected areas of the coating to a developing solution. The latent image may be cured by heating the plate for a short period, and is then developed. The process works with conventional, commercially available lithographic plates and developers.Type: GrantFiled: August 29, 2001Date of Patent: September 28, 2004Assignee: Maxryan Enterprises, Inc.Inventors: Albert S. Deutsch, Bruce R. Harrison
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Patent number: 6777164Abstract: The invention provides a lithographic printing for precursor having an imagable coating on an aluminum support, wherein the imagable coating comprises a polymeric substance comprising colorant groups, and wherein the aluminum support on which the coating is provided is anodized but not subsequently modified by means of a post-anodic treatment compound, and the coating does not comprise a colorant dye. The polymeric substance may also comprise pendent infra-red or developer dissolution inhibiting groups, and these groups may also be the colorant groups themselves.Type: GrantFiled: April 6, 2001Date of Patent: August 17, 2004Assignee: Kodak Polychrome Graphics LLCInventors: Geoffrey Horne, Kevin Barry Ray, Alan Stanley Victor Monk, Stuart Bayes
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Patent number: 6764807Abstract: A planographic printing member precursor comprises a first component, for example a hydroxy group containing polymer, and a second component which may be a siloxane or a compound of general formula (I), wherein M represents a silicon or a titanium atom and each of R1, R2, R3 and R4 is independently selected from hydrogen or halogen atoms; a hydroxy group; an optionally substituted alkyl, alkenyl or alkynyl group; an optionally substituted alkoxy group; or an optionally substituted saturated or unsaturated cyclic or heterocyclic group. On exposure, the second component reacts with the first component to define an oleophobic/hydrophilic material in exposed areas and in non-exposed areas the second component is removed, on processing of the precursor.Type: GrantFiled: September 5, 2001Date of Patent: July 20, 2004Assignee: Kodak Polychrome Graphics LLCInventors: Kevin Barry Ray, Mark John Spowage, Christopher David McCullough