Abstract: Aqueous solutions are provided for treating image-bearing lithographic plates.

Abstract: An image recording material formed with a support, a photosensitive composition layer formed on the support, and a mono-particle layer of solid particles of different optical transmittances formed on the photosensitive composition layer. When the recording material is exposed to light, the firmness with which the photosensitive composition holds the solid particles varies locally from point to point in accordance with the exposure energies of light passed through the solid particles. Thus by causing the dissolving force of the solvent or other physical forces to act on the photosensitive composition, the particles held weakly are selectively removed from the recording material, whereby an image is formed by the particles left on the recording material. The recording material on which the image has been formed can be used as a printing form as it is or by being subjected to simple after-treatment.

Abstract: A method for treating imaged lithographic printing plates with a solution comprising (1) water, (2) an active polymer component for rendering non-image areas of a lithographic printing plate hydrophilic, comprised of a polyacrylamide-based polymer or copolymer or a blend of polyacrylamide and polyacrylic acid, or the like, said polymer or copolymer or blend having an average molecular weight of from about 5,000 to about 10.sup.

Abstract: A photosensitive printing plate forming material having on its surface a matting layer composed of a resin and a fine particulate material dispersed therein, said resin being at least one member selected from rosin and rosin esters.

Abstract: A photosensitive lithographic printing plate having an excellent printing durability, which comprises a supporting layer, a hydrophilic layer formed on the supporting layer, a photosensitive layer formed on the hydrophilic layer surface and, optionally, a water-proof layer located between the supporting layer and the hydrophilic layer, the photosensitive layer being composed of a photosensitive diazo resin modified by a phenol compound and a water-soluble acrylic polymer compound, and the hydrophilic layer being composed of a resinous component comprising 5 to 40% by weight of a urea compound resin and 60 to 95% by weight of a polyamide resin, and a pigment component.

Abstract: The adherence of the oleophilic polymer printing surface of a lithographic printing plate to the support of the lithographic printing plate is improved by an anchoring layer formed from a hydrophobic oleophilic ester colloid which is capable of being rendered hydrophilic by treatment with an aqueous alkali solution. After an image-wise exposure of the photosensitive layer of the presensitized photosensitive sheet used to prepare the lithographic printing plate and removal of the non-polymerized (non-image) portions of the photosensitive layer the plate is contacted with an aqueous alkali solution to render those portions of the anchoring layer, which have been exposed by removal of the non-polymerized portions of the photosensitive layer, hydrophilic. Accordingly, the portions of the anchoring layer underlying the oleophilic hardened polymeric printing surface remain hydrophobic oleophilic and therefore can increase the number of satisfactory printings which can be made from the lithographic printing plate.

Abstract: A durable planographic driographic printing plate comprising a substrate having a highly abhesive layer thereon which is capable of repelling oleo ink when dry, and photobonded to the abhesive layer in image areas an oleo-ink receptive polymer layer. The photobonding occurs during imaging of the plate by including within the abhesive layer ethylenically unsaturated groups which are copolymerizable with a light-sensitive ethylenically unsaturated free radical initiated photopolymerizable material which provides the ink receptive image areas upon exposure.

Abstract: A lithographic printing plate in which the oleophilic imaging areas are formed as a thin cross-linked block copolymer film adhered to the hydrophilic surface of a backing plate. The block copolymer comprises blocks of copolylacrylate and polyurethane wherein the copolyacrylate blocks are a copolymer of a hydroxy-containing acrylate and a second acrylate component comprising one or more esters of acrylic acid or methacrylic acid or mixtures thereof and the polyurethane blocks are formed of polyoxybutylene as the prepolymer component. In forming the printing plate the block copolymer is deposited as a thin film containing an ultraviolet initiator and a cross linking promoter and the cross-linked imaging areas are formed by exposure to ultraviolet radiation.

Abstract: Improved waterless lithographic printing masters are provided having minimum background ink reflection density. The master comprises a crosslinked block copolymer containing elastomeric, ink releasing siloxane blocks chemically linked to organic image accepting thermoplastic blocks, said copolymer having a molecular weight for the organic blocks sufficient to provide strength and a background ink reflection density of less than 0.02 and preferably less than 0.01.

Abstract: Aqueous solutions are provided for treating image-bearing lithographic plates.

Abstract: Aqueous solutions are provided for treating image-bearing lithographic plates.

Abstract: A positive working radiation sensitive plate is image-wise exposed, developed and desensitized, and dried. Thereafter an oleophilic composition including a solvent capable of softening the image is applied to the plate and the plate is then washed to remove the oleophilic composition from the non-image areas. The image accepts ink readily even when the image-wise exposure is effected using a continuous tone original in the absence of a half-tone screen.

Abstract: Aqueous solutions are provided for treating imagebearing lithographic plates.

Abstract: An offset printing system and method wherein a plate cylinder, a blanket cylinder and ink applying means are arranged in cooperative relationship. The ink applying means applies ink to a plate removably carried by the plate cylinder and the ink applied to the plate is transferred as an image to an image receiving surface of a blanket secured to the blanket cylinder and having an image receiving surface comprising a solid fluoroelastomer. In the disclosed embodiment, the fluoroelastomer is a copolymer of vinylidene fluoride and hexafluoropropylene of a grade which remains solid and deforms elastically at temperatures in excess of 150.degree. F. The fluoroelastomer has a specific gravity between about 1.82 and 1.86 and the ink applying means may also be provided with a surface comprising a fluoroelastomer which remains solid and deforms elastically at temperatures in excess of 150.degree. F.

Abstract: A lithographic printing plate is prepared from a layer of a photopolymerizable composition comprising an oleophilic macromolecular organic binder and a leachable hydrophilic ethylenically unsaturated compound by e posing the layer and then leaching the compound from the unexposed areas by treating with a suitable developing solvent, preferably water, producing an oleophilic surface. A similar plate may be prepared from a composition containing a hydrophilic binder and oleophilic leachable compound by imagewise exposure and solvent leaching producing an oleophilic surface in exposed areas and a hydrophilic surface in unexposed areas.

Abstract: This invention relates to a composition comprising a blend of a copolyester, a polyisocyanate and a compatible organic polymer, the ratio by weight of polyester to polymer being within the range of from about 20 : 1 to 0.5 : 1 by weight. The invention also relates to a laminate including the novel composition.

Abstract: A light sensitive printing plate comprising a support having provided thereon a light sensitive layer and a matted layer, said matted layer being removable upon development and containing a light absorbing agent possessing an absorption in the spectral region to which the light-sensitive material coated on the light sensitive printing plate is sensitive.

Abstract: A process for producing a printing plate comprising imagewise exposing a light-sensitive material comprising a support with a hydrophilic surface and having thereon an unhardened silver halide emulsion layer, developing the imagewise exposed light-sensitive material with a non-tanning developer, fogging the remaining silver halide, developing the fogged remaining silver halide with a tanning developer to thereby simultaneously harden the emulsion layer at the areas developed, and removing the unhardened emulsion layer, whereby an oleophilic tanning relief image is formed.

Abstract: A lithographic printing plate which comprises using in an ink-repellent layer a polymer of a monomer or a copolymer containing said monomer, said monomer being represented by the following general formulas: ##STR1## WHEREIN: R is hydrogen or a methyl radical; R' is hydrogen or an alkyl radical having 1 to 10 carbon atoms; Rf is a perfluoroalkyl radical having 3 to 21 carbon atoms; and n is an integer of 1 to 10.

Abstract: A planographic printing master comprising an ink releasing photoconductive insulating layer and an ink receptive particulate image pattern.

Abstract: A letter press printing plate is disclosed for wrapping around a drum. The printing surface is formed with a light-sensitive material layer on a metal backing plate with two different levels, the high level representing areas of solid or dark tones of printing and the low level representing areas of light tones of printing. The printing plate overcomes the problem of even transfer of ink from the solid or dark tones of printing areas and the light tones of printing areas. A method of forming the letter press printing plate is also disclosed wherein a photo polymer layer on a backing plate is first exposed to a negative representing areas of solid or dark tones and light tones of printing. The photo polymer layer is then dissolved away to the backing plate in areas where no printing occurs and formed into a two-level printing surface with the areas of solid or dark tones being at a high level and the areas of light tones being at a low level.

Abstract: A driographic plate capable of being direct imaged by pen, pencil, typewriter, toner powder, etc. comprising a substrate having a coating thereon, the coating comprising a continuous medium having a solid fluorinated compound containing at least one fluorinated aliphatic radical uniformly dispersed therethrough in a manner such that the coating surface is ink repellent when dry. On direct imaging, the imaged areas will readily accept ink and prints can be made therefrom without necessity of a press dampening system.

Abstract: Aluminum based lithographic printing plates are treated with triethanolamine titanate and heat to impart added solvent resistance and strength to non-crosslinked ink-receptive image areas, thereby affording an increase in press life.

Abstract: A process for preparing a waterless lithographic printing master is provided. A suitable substrate, which is preferably ink accepting is first coated with a curable silicone which is curable at low or elevated temperature and a second different curable silicone deposited on said first silicone which can be preferentially cured at a lower temperature without curing the first silicone and which second silicone contains, in addition to its own catalyst, an amount of high temperature curing catalyst sufficient to cure the underlying silicone. The surface silicone is then preferentially cured at least on its surface to render it nontacky, but not the underlying silicone.

Abstract: A printing plate comprising a support, reliefs formed thereon as an image area, and from about 20 to about 4,000/cm.sup.2 small projections thereon in non-image areas, the height of the reliefs being at least 0.05 mm larger than that of the small projections, and a method for making a printing plate which comprises:A. superimposing a photosensitive resin layer having a thickness of at least 0.06 mm on a support, which is at least semi-transparent to actinic light, in intimate contact therewith;B. exposing the resulting assembly to actinic light through an image-bearing transparency from the side of the photosensitive resin layer;C. exposing the assembly to actinic light through a dot-image-bearing transparency having a transparent halftone dot area in a proportion of 1 to 40% from the side of the support to thereby form reliefs on the support, as image areas, and a number of small projections having a height of at least 0.

Abstract: A method of manufacturing a composite lithographic product for use in medium to long-run printing applications consisting of the steps of providing a sheet of metal of between 0.004 to 0.008 inch thick and having a lithographic quality surface, treating at least one surface of the metal sheet to accept a sensitizing coating, providing a backing sheet and laminating the backing sheet to the untreated surface of the metal sheet.

Abstract: Improved waterless lithographic plates are provided. The master which comprises a copolymer of siloxane blocks crosslinked to an elastomeric ink releasing condition and organic thermoplastic blocks which are ink accepting is imaged with a particulate material, preferably an ink accepting thermoplastic polymer, and the thermoplastic blocks heated and cooled to bond the particulate imaging material thereto.

Abstract: A light-sensitive lithographic printing plate comprising a support with a hydrophilic surface having thereon a light-sensitive layer comprising a light-sensitive polyester containing o-quinonediazido groups as terminal groups.

Abstract: A planographic dry offset master plate composed of a substrate and, formed thereon, a crosslinking agent-cured layer of a diorganopolysiloxane in which 5 to 40 mole % of the organic groups directly bonded to silicon atoms are phenyl groups. The master plate is especially suitable for plate-making by an electrostatic process and a direct image process. The resulting printing plate has good durability and are free from scumming during printing.

Abstract: A method of manufacturing an article carrying a relief image intended for printing comprises exposing to an appropriate activating radiation the surface of a receptor material having at least a part of its thickness from the surface thereof formed of a homogeneous mixture of a solid material whose aptitude for softening when heated is modified when it is exposed to said activating radiation, and of at least one substance which releases a gas upon being heated, in such a manner as to transcribe therein a latent image in the form of differences in aptitude for softening and by heating the receptor material to a temperature such that its exposed parts and its non-exposed parts are softened to different degrees, said temperature being at least equal to that at which said substance releases said gas, thereby causing swelling of the exposed parts and the non-exposed parts to different heights thereby forming a relief image based on differential capacity for softening.

Abstract: Improved waterless lithographic plates are provided. The master which comprises a copolymer of siloxane blocks crosslinked to an elastomeric ink releasing condition and organic thermoplastic blocks which are ink accepting is imaged with a particulate material, preferably an ink accepting thermoplastic polymer, and the thermoplastic blocks heated and cooled to bond the particulate imaging material thereto.

Abstract: A repellent composition containing an oil of low volatility having a surface energy less than 27 dynes/cm. and a solid fluorinated polymer such as a polymer of a fluoroalkyl acrylate. In accord with certain embodiments of the invention, a resinous binder and/or a particulate fluorocarbon powder may be added to the repellent composition. The repellent composition may be used to prepare an ink repellent surface for a "waterless" lithoplate or as a coating on the surface of an electrographic element from which a liquid developed electrographic image is transferred.

Abstract: Aluminum substrates are provided having a coating of particulate material bound thereto by means of an in situ formed binder of aluminum hydroxyoxide. The coated aluminum constructions have utility in imaging and reproduction processes (e.g., as printing plates, as electrographic elements, etc.), as magnetic recording surfaces, controlled roughness surfaces, decorative panels, protective surfaces, etc.

Abstract: Photopolymeric image inlay articles comprising a photopolymeric image inlaid into a resilient polyester resin coated matrix of a solidified synthetic rock-like mixture.

Abstract: A new dry planographic plate having a non-ink receptive silicone rubber background area that does not require a fountain solution to repel printing ink and process of producing this new plate comprising applying the photoresponsive sensitizer to a polymeric support film and bringing the sensitizer layer into intimate adhesive contact with an uncured silicone gum and thereafter curing the silicone gum.

Abstract: A dry presensitized planographic plate composed of a support having coated thereon one or two layers of (a) a silicone rubber, (b) a photosensitive azide compound, (c) a cyclized rubber, and (d) a copolymer of vinylidene chloride and acrylonitrile, the uppermost layer, when the planographic plate has two layers, containing at least the component (a) and (b) and the lower layer containing at least the component (c).

Abstract: An aqueous developable subtractive printing plate is presented comprising a photosensitized hydrophilic surface having a photosensitive diazo-borofluoride salt thereon.A method for making a photosensitized printing plate is also presented wherein a photosensitive diazo-borofluoride salt is coated on the plate.

Abstract: In a lithographic printing plate comprising a base and a lithographic printing surface thereon, said printing surface comprising colloidal silica and an insolubilized hydrophilic polymer, the improvement which comprises providing a positively charged colloidal silica as said colloidal silica component and, as said hydrophilic polymer, a nonionic or cationic polymer or a mixture of the same.