Abstract: An aqueous solution and method for applying the solution to a metal surface form a zinc phosphate coating on the metal surface. The zinc phosphate coating minimizes corrosion and improves adhesion of subsequently coated materials such as sealants and paints. The solution of the composition and method of application consume free acidity otherwise left on the metal surface, and obviate the need for subsequent rinsing or extensive drying or stoving operations. The composition includes an aqueous solution including water, a zinc source, phosphoric acid, a polyhydric compound (preferably pentaerythritol), a metal salt, and optionally, an oxidizer.

Abstract: The invention relates to a corrosion inhibitor for bathing water containing chloride and sulfate. Said corrosion inhibitor can be produced by mixing a) between 10 and 40 wt % of phosphoric acid, b) between 5 and 25 wt. % of an alkali hydroxide, c) between 0.01 and 10 wt. % of zinc chloride, d) between 0.01 and 5 wt. % of aminotrimethylene phosphonic acid, and e) water to add up to 100 wt. %.

Abstract: A corrosion protective lacquer is for producing a corrosion protective coating, and a method is for removing the corrosion protective coating. For a more favorable removal, while maintaining simultaneous corrosion protection, the corrosion protective lacquer, and thus also the corrosion protective coating produced from it, includes protective substances that react with oxygen. The corrosion protective coating is abraded by the abrasive effect of the brake linings during braking, the protective substances of the corrosion protective coating being rubbed into the braking surface.

Abstract: Excellent adhesion to subsequently applied paint or elastomer is obtained by coating a metal substrate with a phosphate conversion coating by contact with a liquid phosphating solution that contains zinc cations, phosphate anions, and at least one adhesion promoter selected from (i) film-forming organic substances, (ii) polymers of vinyl phenols modified by substitution of substituted aminomethyl moieties on their aromatic rings, (iii) inorganic oxides of one of the elements silicon, aluminum, titanium, and zirconium. Preferably, the phosphating solution also contains manganese and nickel cations and either iron cations or hydroxylamine. If adhesion to paint is desired, the adhesion promoter preferably is an acrylic film-forming substance, while if adhesion to elastomers is desired, the adhesion promoter preferably is a polymer of vinyl phenol and the phosphating solution preferably also contains calcium cations.

Abstract: The invention concerns a method for protecting metal products against corrosion, characterised in that it consists in applying directly on the metal products, that is without prior treatment, a composition consisting at least of a film-forming binder, at least a corrosion inhibiting additive reactive with metal and at least an oligomer additive bearing phosphonic acids. The inventive composition is characterised in that it comprises a film-forming binder, at least a corrosion inhibiting additive reactive with metal and at least an oligomer additive bearing phosphonic acids.

Abstract: A chromium-free corrosion inhibiting coating composition, which does not utilize harmful chromium compounds and can be used for corrosion inhibition of a metal surface, comprising a slurry mixture in which coated aluminum fine powder treated with a hydrophilic coupling agent is suspended in an acidic phosphate bonding solution and which can be stored in a refrigerator, is disclosed. A titanium-coupling agent is preferable to use as the coupling agent, which treats a surface of the aluminum fine powder. In this aqueous chromium-free corrosion inhibiting coating composition, 25 to 40% by weight of the aluminum fine powder a surface of which is treated with the coupling agent is suspended in the acidic phosphate bonding solution.

Abstract: Antioxidant coating compositions containing 10-75 wt % H2O, 20-65 wt % H3PO4, 0.1-20 wt % alkali metal mono-, di-, or tri-basic phosphate, 0-2 wt % hydrated boron oxide, 0-18 wt % KH2PO4, 3-10 wt % of a transition metal oxide, and 0-20 wt % hydrated manganese phosphate, 0-25 wt % Al(H2PO4)3, and 0-10 wt % Zn3(PO4)2, provided that at least one of Al(H2PO4)3, Zn3(PO4)2, and hydrated manganese phosphate is present. Also, brake discs made from carbon composite articles having their surface treated with certain antioxidant coatings. During a manufacturing process, carbon matrix 15 of brake disc 11 is covered on its outer and inner edges with antioxidant layers 19 and portions of the working surface of brake disc 11 may also be covered with antioxidant layers 13, potentially decreasing the fitness of the brake disc for service. In accordance with this invention, brake disc 12 is manufactured from brake disc 11 by the removal from its working surface of antioxidant layers 13.

Abstract: A corrosion inhibitor is described which includes several supramolecular oxo-anion compositions useful for preventing the propagation of pit corrosion on aluminum and aluminum alloys. The oxo-anion compositions preferably include soluble polymeric oxidic acids comprising combinations of molybdenum, phosphorous, tungsten, and silicon. These compositions are useful as corrosion inhibitors in high-moisture, corrosive environments, such as radiators and cooling systems. For low-moisture environments, these oxo-anion compositions can be reacted with a counter-ion, such as various metals, including, but not limited to the rear earth metals, to form a soluble salt. The salt can then be adsorbed onto a carrier, such as paint pigments, which can then be applied to the surfaces of aluminum and aluminum alloys. These surface adsorbates then become sparingly soluble and are gradually released over time in the presence of an aqueous corrosive agent so as to prevent propagation of pit corrosion.

Abstract: The present invention provides methods and compositions for the reduction of the corrosion rate of already corroding steel reinforcements embedded in a hardened concrete structure as well as for the protective corrosion inhibition of uncorroded steel reinforcements embedded in a hardened concrete structure exposed to aggressive environments. The inventive new compositions employed for the novel method are essentially based on one or more amino- and/or hydroxyalkylamino compound(s), which are partially or completely neutralized with one or more inorganic acid(s) and/or derivatives thereof and/or aliphatic carboxylic- and/or aromatic carboxylic acid(s), one or more surfactant(s) and one or more water-based or water-thinnable water repellent agent(s) selected from the group of organosilicones.

Abstract: A liquid iron phosphating concentrate is provided which contains dispersed aromatic carboxylic acid. The aromatic carboxylic acid remains dispersed in the concentrate by incorporation of a thickener in the composition.

Abstract: A composition and process for inhibiting the corrosion of metallic substrates is revealed. The process utilizes an aqueous treatment solution comprising chitosan which has been reacted with an additive selected from the group consisting of phosphorus-containing compounds and sulfur-containing compounds and mixtures thereof. More preferably, the phosphorus-containing compound is a phosphonic acid and the sulfur-containing compound is a mercapto, thio, or thienyl containing compound or a mercapto functional silane. The composition and process are particularly useful in providing corrosion protection for aluminum and aluminum alloys.

Abstract: The present invention relates to a method for inhibiting high temperature of corrosion-prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of phosphorous acid, typically up to 1000 wppm, to the metal surface.

Abstract: A conversion coating composition and a method of applying the conversion coating composition to magnesium and magnesium alloy articles prior to painting to prevent corrosion. The conversion coating composition comprises a source of vanadate ions, a material comprising phosphorus, and nitric acid or a source of nitrate ions. In addition, the composition may also contain boric acid or a source of borate ions and a source of fluoride ions or a source of fluoroborate ions.

Abstract: A composition providing thermal, corrosion, and oxidation protection at high temperatures is based on a synthetic aluminum phosphate, in which the molar content of aluminum is greater than phosphorus. The composition is annealed and is metastable at temperatures up to 1400° C.

Abstract: Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems.

Abstract: Corrosion-inhibiting pigments based on manganese are described that contain a heptavalent (permanganate), hexavalent (manganate), or pentavalent (manganate) compound. An inorganic or organic material is used with the heptavalent, hexavalent, or pentavalent manganese ion to form a compound that is sparingly soluble in water. Specific solubility control cations are chosen to control the release rate of heptavalent, hexavalent, or pentavalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Solubility control agents may also modify the processing and handling characteristics of the formed powders. Many permanganate or manganate compounds are presented that can equal the performance of conventional hexavalent chromium systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure.

Abstract: A liquid iron phosphating concentrate is provided which contains dispersed aromatic carboxylic acid. The aromatic carboxylic acid remains dispersed in the concentrate by incorporation of a thickener in the composition.

Abstract: By including nitric acid and hydroxylamine in a manganese phosphating composition and controlling the ratio of nitric to phosphoric acids and the ratio of Total Acid to Free Acid within a specified range, satisfactory manganese phosphate conversion coatings can be obtained within a reasonable time at temperatures much lower than has previously been thought necessary for operating a manganese phosphating composition with no other metal cations (except possibly for iron).

Abstract: The invention provides an aqueous coating composition comprising nonionically and/or anionically stabilized film-forming polymers and metallic pigments and a compound which is the reaction product of a phosphonic acid derivative, a hydroxy-functional addition polymers and, optionally a compound having a hydroxy group, in which the phosphonic acid derivative is selected from one or both of wherein R and R′ are selected from the group consisting of an aliphatic and an aromatic substituent having 1 to 25 carbon atoms optionally including heteroatoms of at least one of oxygen, phosphorus and silicon.

Abstract: The invention is directed to a method for providing a corrosion inhibiting aqueous solution which includes zinc orthophosphate where the zinc orthophosphate is solubilized. The invention is directed to a method of making a substantially contaminant-free, concentrated aqueous solution of zinc orthophosphate from zinc metal or zinc oxide and aqueous phosphoric acid.

Abstract: The phosphate concentration, and therefore the pollution potential, of conventional high quality phosphating compositions containing zinc, manganese, and, optionally, nickel or copper cations, can be reduced without loss of corrosion protective value of the phosphate coatings formed by maintaining concentrations of active ingredients within prescribed ranges. Under the most preferred conditions, the corrosion resistance of phosphated and then painted cold rolled steel and the paint adhesion to phosphated and then painted electrogalvanized steel are improved over values obtained with the now most commonly used commercial high quality low zinc phosphating processes.

Abstract: The present invention relates to a composition for the treatment of metal substrates including an aqueous solution of a Group IVA metal ion, selected from the group consisting of zirconium, titanium, hafnium and mixtures thereof, and a water-soluble or water-dispersible polyphenolamine.

Abstract: The use of surface-coated rutile modification TiO2 pigments having a primary particle grain size d50 of 0.1 to 1.0 &mgr;m as an anticorrosive white pigment, with firstly magnesium phosphate and secondly aluminum oxides and/or aluminum hydroxides being precipitated onto the TiO2 pigments, is described.

Abstract: Anticorrosive white pigments useful for inhibiting corrosion include surface-coated TiO2 base bodies, preferably in the rutile modification, having Mn3(PO4)2 and one or more of the substances chosen from aluminum oxides, aluminum hydroxides, aluminum phosphates, aluminum hydrogen phosphates, aluminum dihydrogen phosphates and aluminum polyphosphates are precipitated on to the TiO2 base bodies. Mn3(PO4)2 may be replaced completely or partially by Zn3(PO4)2. Phosphates and/or oxides of cerium may be additionally deposited singly, or several of them may be deposited, on to the TiO2 base bodies.

Abstract: Potassium monofluorophosphate is found to be superior to sodium monofluorophosphate as a corrosion inhibitor for steel reinforcement members in reinforced concrete; conveniently the potassium monofluorophosphate in aqueous solution is contacted with a surface of the reinforced concrete to facilitate penetration of the potassium monofluorophosphate into the concrete.

Abstract: Inorganic anti-corrosive pigments consist of surface-coated solids having a grain size of 0.1 to 75 &mgr;m. In order to improve the resistance of the paints and coatings containing such pigments, firstly Mn3(PO4)2 and secondly aluminium oxides and/or aluminium hydroxides are precipitated onto the solids.

Abstract: A chromium-free agent for treating metallic surface comprising the following (i)-(iv): (i) at least one of (A) a mixture of an aluminum salt and an inorganic oxide particle and (B) an aluminum-containing inorganic oxide particle comprising aluminum, oxygen and at least one element other than these two (ii) a salt of a metal other than aluminum (iii) a phosphorus compound (iv) a resin and/or a precursor thereof provided that when (i) is a mixture of an aluminum salt and an inorganic oxide particle, the equivalent ratio of phosphorus/aluminum is not less than 0.1. The agent for treating metallic surface is applied to the surface of a metal material such as steel plate, plated steel plate, alloy-plated steel plate, alloy plate, silicon steel plate, stainless steel plate, shape steel, pipe, wire material and the like, and dried to form a film superior in corrosion resistance, adhesion to a metal material and adhesion to a paint.

Abstract: A non-chromate protective coating and coating solution useful for coating iron and iron alloys, particularly steel, includes V2O5, Ce2(MoO4)3 or SrWO4 as a corrosion inhibitive component

Abstract: Metal pigment particles are treated with a product resulting from the reaction between an organic phosphonic acid with an amine having at least one organic group containing at least six carbon atoms to inhibit their reactivity to water. The treated metal particles can be used in coating and ink compositions. Additionally, the treated metal particles can be used to formulate pastes and dispersions that are provided to a coatings manufacturer.

Abstract: The present invention provides a corrosion inhibitor composition for magnesium or magnesium alloys which contains as an effective component, at least one compound selected from among aromatic carboxylic acids and salts thereof as an effective component. Further, the present invention provides a surface treating agent for magnesium and/or magnesium alloy components which contains a phosphate, at least one compound selected from among aromatic carboxylic acids and salts thereof, and further, as required, at least one compound selected from among pyrazole compounds and triazole compounds,and surface-treating method using the surface treating agent.

Abstract: The present invention relates to a surface-treated steel sheet coated with a chromate layer having excellent corrosion resistance, fuel resistance and seam weldability, and a chromate solution used for preparing the surface-treated steel sheet. Specifically, the chromate solution of the present invention comprises (a) a main solution prepared by adding to a chrome solution having 0.4 to 0.8 of trivalent chrome composition and 7 to 50 g/l of dissolved chrome, on the basis of the chrome in the chrome solution, 50 to 80 w % of phosphate, 20 to 40 w % of fluoric acid, 300 to 2000 w % of colloidal silica, 5 to 15 w % of sulfuric acid, and 25 to 40 w % of sodium phosphate, and (b) a hardener solution containing added epoxy silane or glycidyl silane of 2 to 10 w % on the basis of total hardener solution, the pH of which is controlled between 2 and 3, wherein 10 to 60 w % of the hardener solution being added to the main solution.

Abstract: The invention is directed to gassing stabilized aqueous coating compositions comprising A) a metallic pigment and at least one reaction product of: (a) 5 to 95 weight percent of a at least one phosphonic acid derivative selected form compound I and II wherein R1 is H or O═P(OH)2; R2 and R3 are independently H, OH or an aliphatic, cycloaliphatic and aromatic substituent having 1 to 25 carbon atoms and optionally up to 10 heteroatoms of at least one of oxygen and phosphorus; and R′ is an aliphatic, cycloaliphatic and aromatic substituent having 1 to 25 carbon atoms and optionally up to 10 heteroatoms of at least one of oxygen and phosphorus; (b) 5 to 95 weight percent of a at least one compound having at least two epoxy groups and a number average molecular weight Mn of 300 to 5000 g/mol; and (c) 0 to 90 weight percent of a compound having one epoxy-functional group, wherein the proportions by weight of components (a), (b) and (c) total 100 weight percent.

Abstract: Tri-cation zinc phosphate conversion coating compositions are disclosed. The compositions include a phosphate component, ions of nickel, manganese, and zinc, and a glycerophosphate component, such as disodium glycerophosphate. Coatings formed from these compositions provide improved corrosion resistance to metal substrates and provide a uniform layer for the application of paint finishes. Processes of making and using these compositions are also disclosed.

Abstract: The present invention provides an aqueous agent for treating metal surfaces capable of degreasing and forming a zinc phosphate coat simultaneously. The present metal surface treating agent includes an aqueous solution that includes water and a water-soluble organic solvent where the amount of water is larger than the amount of the water-soluble organic solvent; phosphate ions; nitrate ions; and zinc ions.

Abstract: A non-carcinogenic corrosion inhibiting additive includes an anodic corrosion inhibitor and a cathodic corrosion inhibitor.

Abstract: The present invention is to provide an aqueous agent for treating metal surfaces that can carry out degreasing and forming a zinc phosphate coat simultaneously.

Abstract: Phosphate conversion coatings having very fine crystal size are obtained using liquid compositions containing phosphate, zinc cations and relatively low concentrations of Co, Ni and Mn.

Abstract: An anti-corrosive sol-gel that is a combination of an organometallic salt, an organosilane, and a borate, phosphate, or zinc functional component. The organosilane component may be selected from a large group of equivalent compounds but is preferably an alkoxyzirconium salt, and most preferably Zr (IV) n-propoxide. The organosilane may also be selected from a large group of equivalent compounds, but is preferably 3-glycidoxypropyltrimethoxysilane (GTMS). Combination of the components takes place in the presence of an organic catalyst, preferably acetic acid.

Abstract: A composition for metal surface treatment which comprises an aluminum ion, a magnesium ion, a manganese ion, a water-soluble organic resin, an acid and water; and a surface treated metal material which has been treated with the composition. The resultant surface treated metal material is free from the danger of water contamination owing to chromium, since the composition is free of chromium, and also is excellent in both electrical conductivity and corrosion resistance. Accordingly, the metal material can be used in a wide variety of applications in place of a conventional chromate-treated steel sheet and the like.

Abstract: A corrosion inhibitor is described which includes several supramolecular oxo-anion compositions useful for preventing the propagation of pit corrosion on aluminum and aluminum alloys. The oxo-anion compositions preferably include soluble polymeric oxidic acids comprising combinations of molybdenum, phosphorous, tungsten, and silicon. These compositions are useful as corrosion inhibitors in high-moisture, corrosive environments, such as radiators and cooling systems. For low-moisture environments, these oxo-anion compositions can be reacted with a counter-ion, such as various metals, including, but not limited to the rear earth metals, to form a soluble salt. The salt can then be adsorbed onto a carrier, such as paint pigments, which can then be applied to the surfaces of aluminum and aluminum alloys. These surface adsorbates then become sparingly soluble and are gradually released over time in the presence of an aqueous corrosive agent so as to prevent propagation of pit corrosion.

Abstract: A composition and process for inhibiting the corrosion of metallic substrates is revealed. The process utilizes an aqueous treatment solution comprising chitosan which has been reacted with an acid selected from the group consisting of phosphonic acids, carboxylic acids and mixtures thereof. The composition and process are particularly useful in providing corrosion protection for aluminum and aluminum alloys.

Abstract: A non-toxic chemical composition inhibits corrosion in metal substrates. The composition contains a Phosphorus compound, comprising an acid and a metal selected from the group consisting of an alkali, alkaline earth, or transition metal. The composition also contains a Boron compound comprising an acid and a metal selected from the group consisting of an alkali, alkaline earth, or transition metal. A process of making the chemical composition comprises the steps of filling a mixer with 30-60% by weight of hot water and adding 10-20% by weight of barium carbonate or strontium carbonate, 10-20% by weight of phosphoric acid (75%), 5-15% by weight of lime, and 10-20% by weight of Boric acid; mixing the said contents for 10-15 minutes to create a wet slurry; pouring said wet slurry into an attrition mill for 15-60 minutes; drying said wet slurry and milling said wet slurry to an average particle size of 1.0-2.0 microns to form a dry pigment; pushing said dry pigment through a 325 mesh sieve.

Abstract: A flowable and pumpable aqueous semifinished product of gassing stability for the production of paints and lacquers comprises water, a pre-stabilized metallic pigment and an anticorrosive pigment.

Abstract: An aqueous bath for treating the surfaces of light metals and light metal alloys that does not contain hexavalent chromium or produce any other highly polluting effluent and that forms a highly corrosion-resistant and highly paint-adherent conversion coating has a pH from 1.0 to 7.0 and contains from 0.01 to 50 g/L of permanganic acid and/or salt(s) thereof and 0.01 to 20 g/L of at least one water soluble compound of titanium or zirconium.

Abstract: A highly effective and storage stable conditioning treatment for metal surfaces prior to phosphating them is a suspension in water containing solid miorosize particles of at least one phosphate of a divalent or trivalent metal and an accelerant selected from the group consisting of sacoharides and their derivatives thereof, orthophosphoric acid, condensed phosphoric acids, organophosphonic acids, and polymers of vinyl acetate and/or carboxylic acid. The surface conditioning liquid composition is used simply by effecting contact between the metal and the liquid composition, and can also be used to simultaneously carry out degreasing, particularly when the conditioning liquid also contains nonionic or anionic surfactant.

Abstract: The present invention relates to novel water-borne shop primer (preconstruction primer) compositions comprising 5-40% by volume of a pigment mixture; 1.4-10% by volume of one or more water soluble silicates (based on the dry volume of the silicate); 40-90% by volume of water; and optionally one or more additives; said pigment mixture comprising 40-90% by weight of zinc, 10-60% by weight of micaceous iron oxide (MIO), and 0-50% by weight of a second filler (e.g. barium sulphate, kaolin, muscovite, quartz, etc.). The present invention also provides a method of using a shop primer composition for temporary protection of a steel surface, and to a method for the manufacture of a steel construction.

Abstract: An anticorrosion treatment of an aluminium/zinc alloy surface is disclosed. The treatment includes the steps of forming on the alloy surface a coating of a solution which contain 5-40 grams of molybdenum per litre of the solution, 2-19% by volume of a phosphoric acid, and a surface etchant. The treatment also includes drying the coating to form a dried coating having a loading of molybdenum of at least 10 mg/m2 of the dried coating and of phosphorus of at least 15 mg/m2 of the dried coating.

Abstract: Metal surfaces, particularly the zinciferous surfaces of zinc-coated steel, can be given a chromate conversion coating that is superior in terms of blackening resistance and white rust resistance by drying into place on the surfaces a layer of a treatment liquid that contains water, hexavalent chromium atoms, trivalent chromium cations, nitrate ions and one or more types of metal ions selected from the group consisting of Ni, Co, Zn and Al, the molar ratio of the total of these metal ions to nitrate ions being in the range from 0.05 to 1.0, the molar ratio of trivalent chromium ions to hexavalent chromium atoms being in the range of 0.11:1.0 to 1.0:1.0, and the molar ratio of nitrate ions to total chromium atoms being in the range of 2.1 to 5.5. Preferably, the coating formed has a chromium content of 10 to 100 mg/m2.

Abstract: A process for producing a strontium chromate corrosion inhibitor includes the steps of providing an aqueous slurry containing dispersed particulate strontium chromate, adding to the slurry a phosphoric acid or a neutral or acidic soluble salt of a phosphoric acid selected from the group consisting of ortho-phosphoric, pyro-phosphoric, tri-phosphoric, polyphosphoric, metaphosphoric, polymetaphosphoric, cyclic tri-metaphosphoric acid, and phosphorous acid, and, filtering and drying the resultant material whereby particulate strontium chromate of reduced solubility is produced.

Abstract: A chromium-free agent for treating metallic surface comprising the following (i)-(iv):