Abstract: A corrosion inhibitor composition for use in coating compositions on metal surfaces, or in metal containers, to provide corrosion resistance to said metals. The corrosion inhibitor comprises at least one alkoxylated phosphate ester; and at least one borate ester. The corrosion inhibitor composition optionally comprises at least one inorganic metal salt. There is also provided an end-use coating composition comprising said corrosion inhibitor composition, and a method of providing corrosion resistance to a metal surface by applying said coating composition thereto.

Abstract: A process for increasing the adhesion of a polymeric material to a metal surface, the process comprising contacting the metal surface with an adhesion promoting composition comprising: 1) an oxidizer; 2) an inorganic acid; 3) a corrosion inhibitor; and 4) an organic phosphonate; and thereafter b) bonding the polymeric material to the metal surface. The organic phosphonate aids in stabilizing the oxidizer and organic components present in the bath and prevents decomposition of the components, thereby increasing the working life of the bath, especially when used with copper alloys having a high iron content.

Abstract: An inorganic chromium-free metal surface treatment agent contains a compound X containing a metal X1, ionic species of which containing the metal X1 become cations in an aqueous solution, and a compound Y containing a metal Y1, ionic species of which containing the metal Y1 become anions in an aqueous solution, a total content of the compound X being from 0.01 to 10% by mass, a total content of the compound Y being from 0.01 to 10% by mass, a molar ratio of the metal X1 in the cation and the metal Y1 in the anion being from 0.1 to 5, the metal X1 being at least one member selected from the group consisting of Ti, Zr and Al, the metal Y1 being at least one member selected from the group consisting of Ti, Zr, Si, B and Al, and the metal surface treatment agent containing substantially no organic resin.

Abstract: Disclosed is a method for providing an anti-corrosion protective coating to a metal substrate that uses a coating composition comprising a resin and a polyfunctional bridging molecule to both bind to the resin and to chelate the bound polymeric resin directly to the metal substrate. One category of polyfunctional bridging molecules preferably includes at least one amine function to bind to a resin and at least one carboxylate, thiol, silane, phenolate, acetoacetonate, imine, phosphate, or phosphonate function to chelate to a metal substrate. It is theorized that the amine function can bind to certain pendent chains in coating resins through a Michael addition reaction while the carboxylate, thiol, silane, phenolate, acetoacetonate, imine, phosphate, or phosphonate functions chelate to the metal substrate. These polyfunctional bridging molecules provide an organic binding of the resin to the metal substrates.

Abstract: As an acidic liquid composition capable of forming an anticorrosive film having an appearance and corrosion resistance comparable to the anticorrosive film formed by chromate treatment on a substrate which has a metallic surface and a complicated shape, a chromium-free acidic liquid composition for reactive chemical conversion treatment for use in forming an anticorrosive film on a metallic surface is provided, the composition comprising: at least one oxidative substance selected from a nitric ion and hydrogen peroxide; at least one carboxylic acid compound selected from the group consisting of carboxylic acids, carboxylate ions, carboxylates, and derivatives of carboxylic acids; an aluminum-containing substance; a zirconium-containing substance; and a sulfate ion, wherein the composition does not substantially contain an organic film-forming component.

Abstract: Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems.

Abstract: An adhesion promoting composition and a process for treating metal surfaces with the adhesion promoting composition is described. The adhesion promoting composition comprises an oxidizer, an acid, a corrosion inhibitor, a source of halide ions and a material selected from a mercapto propane sulfonate, mercapto propane sulfonic acid, and bis-sodium sulfopropyl disulfide. The adhesion promoting composition increases the adhesion of polymeric materials to the metal surfaces and also provides increased acid resistance.

Abstract: A coating composition is disclosed that includes a binder, a tri-valent chromium solid, and a stabilized oxidizing agent. The coating composition is used in a method to protect a surface of a metallic article, such as an aluminum article. The tri-valent chromium solid forms a soluble hexavalent chromium compound as a result of reaction with the oxidizing agent when activated in the presence of a corrosive environment. The released water soluble hexavalent chromium migrates to coating defects to protect the metallic article.

Abstract: A coating composition is disclosed that includes a binder, a tri-valent chromium solid, and a stabilized oxidizing agent. The coating composition is used in a method to protect a surface of a metallic article, such as an aluminum article. The tri-valent chromium solid forms a soluble hexavalent chromium compound as a result of reaction with the oxidizing agent when activated in the presence of a corrosive environment. The released water soluble hexavalent chromium migrates to coating defects to protect the metallic article.

Abstract: A chrome-free corrosion inhibitor composition includes: titanium chloride; a stabilizer including a mixture of hydrogen peroxide and at least a compound selected from nitric acid, persulfate, nitrate, and chlorate; and a film-forming enhancer selected from monosaccharide, oligosaccharide, polysaccharide, derivatives of saccharide, and combinations thereof.

Abstract: A dye discharging ink for inkjet printing including at least a reducing agent and an amine compound. Embodiments of the dye discharging ink include, as the reducing agent, a sulphur reducing agent such as Rongalite, and, as the amine compound, an alcohol amine compound such as triethanolamine. Embodiments of the dye discharging ink also include a surface active surfactant and/or an antirust agent, and a pH in a range from 9.5 to 11.0. The dye discharging ink for inkjet printing can prevent corrosion of head nozzles due to acidic substances produced by decomposition of a reducing agent, so as to decrease inhibition of linear advancing property of ejected ink, and can prevent decrease in discharging capability due to hydrolysis of the reducing agent.

Abstract: An aqueous metal surface treatment composition comprising the following ingredients: (A) an aqueous dispersion of a phenolic resin that includes a reaction product of (i) a phenolic resin precursor; (ii) a modifying agent, comprising a hydrocarbyl moiety bonded to at least one functional moiety that enables the modifying agent to react with the phenolic resin precursor; and at least one ionic moiety comprising an ionizable sulfur or phosphorous group; and (iii) at least one multi-hydroxyphenolic compound; and (B) optionally an acid where (iii) in (A) is optional where the reaction product contains two or more reactive phenolic methylol groups.

Abstract: An aqueous metal surface treatment composition that includes (A) an aqueous dispersion of a phenolic novolak resin that includes water and a reaction product of a phenolic resin precursor, a modifying agent and a multi-hydroxy phenolic compound wherein the modifying agent includes at least one functional moiety that enables the modifying agent to react with the phenolic resin precursor and at least one ionic moiety, (B) an acid and, optionally, (C) a flexibilizer. According to one embodiment the modifying agent is an aromatic compound. According to another embodiment the ionic moiety of the modifying agent is sulfate, sulfonate, sulfinate, sulfenate or oxysulfonate and the dispersed phenolic resin reaction product has a carbon/sulfur atom ratio of 20:1 to 200:1.

Abstract: Disclosed herein is a surface treatment agent for steel, characterized in that, said agent contains 0.1-15% by mass of chromium sulfate and 10-40% by mass of a binder resin containing butyral resin or a mixture of butyral resin with another resin which is compatible with butyral resin.