Abstract: A lightweight insulative and fire-retardant building material and component and manufacturing process are disclosed. The building material is based on cellulose impregnated with clay and can be formed in the form of posts, columns, bricks, blocks, and panels.

Abstract: Flame retardant panels generally include an adaptive cover layer and underlying batting layer. The cover layer includes a moisture vapor permeable synthetic fibrous layer, and a liquid impermeable but moisture vapor permeable thermoplastic layer disposed on an outer face of the cover layer, wherein the liquid impermeable but moisture vapor permeable thermoplastic layer is in an amount of about 2 to 15% by weight based on a total weight of the synthetic fibrous layer and the thermoplastic layer. The underlying batting layer can have a top surface and a bottom surface, the layer comprising a plurality of substantially vertically oriented flame retardant treated fibers extending from the top surface to the bottom surface; and a binder material.

Abstract: A fire-retarded cellulose fiber material composed of phosphoric acid and ammonium sulfate as fire-retardant chemical components, absorbed, adsorbed and/or adhered on the cellulose fibers, and optional non-fire retardant additives, and methods of producing the fire-retarded cellulose fiber material are disclosed.

Abstract: A method for preparation of graft modified ammonium polyphosphate with ultra-low hydroplaning and resistance to hydrolysis belongs to the field of the preparation of flame retardant. Ammonia water is used as hydrolytic agent of amino silane. In the early stage of synthesis of ammonium polyphosphate with phosphorus pentoxide, diammonium hydrogen phosphate and melamine as raw materials, hydrolyzed amino silane ammonia mixture is added, and continues warming reaction, when the temperature drops to a certain temperature, melamine is added to maintain high temperature reaction for a certain period of time, then cools to obtain graft modified ammonium polyphosphate with ultra-low hydroplaning and resistance to hydrolysis. The present disclosure grafts ammonium polyphosphate with two kinds of amino grafting in stages, and the modified ammonium polyphosphate products after grafted basically have no hydroplaning when meets water.

Abstract: The invention relates to molded cellulose bodies, in particular fibers, filaments, directly spun nonwovens, films, or foams which have flame-resistant properties. The fibers and filaments can be further processed as textiles into yarns, wovens, knitted fabrics, and nonwovens. The molded bodies are produced from solutions of cellulose and melamine cyanurate or cellulose and crosslinked or partially crosslinked melamine resin particles in an organic solvent. The melamine cyanurate or the melamine resin particles provide the molded cellulose bodies with flame-retardant properties. The molded cellulose bodies made of cellulose and melamine cyanurate or melamine resin particles can further contain flame retardants, in particular flame retardants which act synergistically, in a particulate form. The obtained textile fibers and nonwoven materials have a soft touch and can be processed or finished as filaments or yarns on conventional textile machines.

Abstract: A flame-retardant aconitic acid-derived cross-linker, a process for forming a flame-retardant resin, and an article of manufacture comprising a material that contains a flame-retardant aconitic acid-derived cross-linker are disclosed. The flame-retardant aconitic acid-derived cross-linker can have at least two phosphoryl or phosphonyl moieties with allyl functional groups, epoxy functional groups, propylene carbonate functional group, or functionalized thioether substituents. The process for forming the flame-retardant polymer can include forming an aconitic acid derivative, forming a phosphorus-based flame-retardant molecule, and reacting the aconitic acid derivative with the phosphorus-based flame-retardant molecule to form a flame-retardant aconitic acid-derived cross-linker, and binding the cross-linker to a polymer. The aconitic acid derivative can be synthesized from aconitic acid obtained from a bio-based source.

Abstract: A flame-retardant aconitic acid-derived monomer, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains a flame-retardant aconitic acid-derived monomer are disclosed. The flame-retardant aconitic acid-derived monomer can have at least one phosphoryl or phosphonyl moiety with functional groups that can participate in a polymerization reaction, such as allyl, epoxy, or propylene carbonate functional groups. The process for forming the flame-retardant polymer can include forming an aconitic acid derivative, forming a phosphorus-based flame-retardant molecule, and reacting the aconitic acid derivative with the phosphorus-based flame-retardant molecule to form a flame-retardant aconitic acid-derived monomer, which is then polymerized. The aconitic acid derivative can be synthesized from aconitic acid obtained from a bio-based source.

Abstract: A functionalized flame-retardant aconitic acid-derived molecule, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains a functionalized flame-retardant aconitic acid-derived molecule are disclosed. The functionalized flame-retardant aconitic acid-derived molecule can have at least one phosphoryl or phosphonyl moiety with allyl functional groups, epoxy functional groups, propylene carbonate functional groups, or functionalized thioether substituents. The process for forming the flame-retardant polymer can include reacting an aconitic acid derivative with a flame-retardant phosphorus-based molecule to form a functionalized flame-retardant aconitic acid-derived molecule, and combining the functionalized flame-retardant aconitic acid-derived molecule with a polymer. The material in the article of manufacture can be a resin, plastic, polymer, or adhesive, and the article of manufacture can further comprise an electronic component.

Abstract: A flame-retardant aconitic acid-derived small molecule, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains a flame-retardant aconitic acid-derived small molecule are disclosed. The flame-retardant aconitic acid-derived small molecule can be synthesized from aconitic acid obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety with phenyl, allyl, or thioether substituents. The process for forming the flame-retardant polymer can include reacting an aconitic acid derivative with a flame-retardant phosphorus-based molecule to form a flame-retardant aconitic acid-derived small molecule, and combining the flame-retardant aconitic acid-derived small molecule with a polymer. The material in the article of manufacture can be a resin, adhesive, polymer, etc.

Abstract: Provided is a binder composition and its use in aqueous based paints and coatings and other applications. The binder composition comprises: a polyurethane dispersion containing water and a polyurethane polymer, wherein the polyurethane polymer is prepared by reacting a nitroalcohol compound, a polyol compound, a polyisocyanate compound, and optionally chain extenders, wherein the nitroalcohol compound is of formula I, wherein R, R1, and Z are as defined herein.

Abstract: Disclosed herein are methods of recovering a low molecular weight alcohol or alcohol containing fluid in natural gas and oil production and transmission. Disclosed herein are also methods of recovering hydrocarbon fluid from a well, using fluids comprising an effective foam-forming amount of a fluorosurfactant compound.

Abstract: A novel flame retardant and fire extinguishing product for preventing and fighting fires in liquids is disclosed herein. The product comprises water, one or more flame retardants, one or more polymers, one or more surfactants, one or more emulsifiers, one or more preservatives, and one or more firming agents. In some embodiments, the product may further comprise one or more stabilizers, one or more binders, and/or one or more fining agents. The product may be used as a fire extinguishing agent in active firefighting and as a flame retardant to prevent fires. The product may be biodegradable in a natural environment, may be readily cleaned off equipment and materials to which it has been applied using water, and may also provide other features which render it safe for the environment as compared to other commonly used products in fire prevention and firefighting.

Abstract: Phosphazene-formaldehyde polymeric and phosphazene-formaldehyde metal polymeric compounds and methods for their preparation are described. In one aspect, a phosphazene-formaldehyde polymer is formed by reacting hexaminocyclotriphosphazene hexammoniumchloride, [{NP(NH2)2}3.6NH4Cl], and formaldehyde, HCHO, in an aqueous environment to form a reaction product.

Abstract: A fire-resistant cellulose material composed of a liquid acid fire-retardant chemical composition and methods of producing the cellulose material are disclosed.

Abstract: The invention relates to thermally-stable mineral wool which can dissolve in a physiological medium, comprising fibres containing the following constituents, expressed in percentage by weight, namely: 35-60 % SiO2, preferably 39-55 %; 12-27% Al2O3, preferably 16-25%; 0-35% CaO, preferably 3-25%; 0-30% MgO, preferably 0-15%; 0-17% Na2O, preferably 6-12%; 0-17% K2O, preferably 3-12%; 10-17% R2O (Na2O+K2O), preferably 12-17%; 0-5% P2O5, preferably 0-2%; 0-20% Fe2O3; 0-8% B2O3, preferably 0-4%; and 0-3% TiO2, and at least one phosphorous compound that can react with said fibres at a temperature of less than 1000° C. in order to form a coating on the surface thereof. The invention is characterised in that the phosphorous content of said compound, as expressed in phosphorus atom weight, varies between 0.0005%, in particular more than 0.01%, and 1%, in particular less than 0.5%, of the total weight of the fibres.

Abstract: A process in which an at least partially delignified pulp fiber web having a Kappa number of less than about 130 is treated with an aqueous endothermic fire retardant solution having a pH of about 10 or less. The treated pulp fiber web has a near neutral pH of from about 5 to about 9, and is treated with at least about 20 lbs of endothermic fire retardants per ton of the pulp fiber web, with at least about 5% of the total amount of endothermic fire retardants being added at a point prior to when the pulp fiber web is formed. Also a fire resistant pulp fiber web having a near neutral pH.

Abstract: Disclosed herein is a reinforced composition comprising: 55 to 80 wt % of a compatibilized blend of a polyphthalamide and a poly(phenylene ether) wherein said compatibilized blend is formed from a mixture of polyphthalamide and poly(phenylene ether) in a ratio of between 1.5:1 and 7.0:1, and a functionalizing agent in an amount sufficient to effect compatibilization; and 20 to 45 wt % of a nylon glass fiber, wherein the composition contains less than 0.1 wt % of phosphinates and less than 0.1 wt % of impact modifiers and weight percent is based on the total weight of the composition.

Abstract: Modified lignin having covalently attached phosphorous containing groups and methods for preparing such compounds are described herein. The modified lignin described herein provides a renewable source of flame retardant material.

Abstract: A novel flame retardant and fire extinguishing product for preventing and fighting fires in solid materials is disclosed herein. The product is thixotropic and comprises water, one or more flame retardants, one or more stabilizers, and one or more preservatives. In some embodiments, the product further comprises one or more thickeners, one or more binders, one or more fining agents, one or more firming agents, one or more water retention agents, one or more polymers, one or more detergents, and/or one or more surfactants. The product may be used as a flame retardant to prevent fires and in active firefighting. The product may be biodegradable in a natural environment, may be readily cleaned off equipment and materials using water, and may also provide other features which render it safe for the environment as compared to other commonly used products in fire prevention and firefighting.

Abstract: The present invention teaches a three-step method for an aqua based chemical composition for flame retardation. The composition comprises: Sodium Borate, Boric Acid, Guanylurea Phosphate, Hydrogen Peroxide, Magnesium Chloride, and Sodium Silicate. The referenced salts are dissolved in distilled water, and the resultant flame retarding solution is coated on substrate surfaces to be protected against flame retardation. The flame retarding composition solution from step-1 alone may be used on non-prepared substrate surfaces. The flame retarding composition solution fully satisfies the Federal Aviation Regulation (FAR) 25.853(a) vertical burn test, and Federal Aviation Regulation (FAR) 25.853(d) heat release test. The utility of the present invention extends to numerous commercial and non-commercial applications.

Abstract: Modified lignin having covalently attached phosphorous containing groups and methods for preparing such compounds are described herein. The modified lignin described herein provides a renewable source of flame retardant material.

Abstract: A process in which an at least partially delignified pulp fiber web having a Kappa number of less than about 130 is treated with an aqueous endothermic fire retardant solution having a pH of about 10 or less. The treated pulp fiber web has a near neutral pH of from about 5 to about 9, and is treated with at least about 20 lbs of endothermic fire retardants per ton of the pulp fiber web, with at least about 5% of the total amount of endothermic fire retardants being added at a point prior to when the pulp fiber web is formed. Also a fire resistant pulp fiber web having a near neutral pH.

Abstract: Inorganic-organic composite articles and methods for producing them using inorganic acidic/alkaline precursor components as inorganic adhesives is provided. Articles prepared therefrom provide improved flexibility, zero flame spread, no release of volatile organic compounds, and low carbon foot print.

Abstract: The invention provides a calcium sulphate-based product comprising a phosphate as additive for increased fire resistance. Particularly preferred phosphate additives may be those containing aluminium or ammonium ions.

Abstract: A process in which an at least partially delignified pulp fiber web having a Kappa number of less than about 130 is treated with an aqueous endothermic fire retardant solution having a pH of about 10 or less. The treated pulp fiber web has a near neutral pH of from about 5 to about 9, and is treated with at least about 20 lbs of endothermic fire retardants per ton of the pulp fiber web, with at least about 5% of the total amount of endothermic fire retardants being added at a point prior to when the pulp fiber web is formed. Also a fire resistant pulp fiber web having a near neutral pH.

Abstract: Inorganic-organic composite articles and methods for producing them using inorganic acidic/alkaline precursor components as inorganic adhesives is provided. Articles prepared therefrom provide improved flexibility, zero flame spread, no release of volatile organic compounds, and low carbon foot print.

Abstract: The invention relates to a ceramifying composition for forming a fire resistant ceramic under fire conditions the composition comprising: (i) at least 10% by weight of mineral silicate; (ii) from 8% to 40% by weight of at least one inorganic phosphate that forms a liquid phase at a temperature of no more than 800° C.; and (iii) at least 15% by weight based on the total weight of the composition of a polymer base composition comprising at least 50% by weight of an organic polymer.

Abstract: Inorganic-organic composite articles and methods for producing them using inorganic acidic/alkaline precursor components as inorganic adhesives is provided. Articles prepared therefrom provide improved flexibility, zero flame spread, no release of volatile organic compounds, and low carbon foot print.

Abstract: Cellulose based insulation materials are treated with phosphate compounds to provide flame retardant properties and reduce or eliminate the propensity of the cellulose based materials to ignite and propagate flame or smolder. The phosphate compounds may be blended with the cellulose based material in a dry process. Alternatively, the phosphate compound may be dissolved or dispersed in water or other solvent and sprayed on the cellulosic material. The cellulose material is then dried prior to use. The treated cellulose materials may be further conditioned prior to use by heating to between 30° C. and 100° C. for 12 to 48 hours.

Abstract: The present invention relates to a fire-retardant material and method. More specifically, the present invention relates to an insulating, fire-retardant coating (and method) that shields underlying substrates from thermal and other types of insult. The invented coating is especially applicable to energy transport means including oil pipelines. The invented coating and method is also useful in providing a insulating and fire-resistant coating for a variety of substrates including but not limited to: concrete, metals, foamed polymeric materials (i.e. styrofoam), gypsum, synthetics and other substrates.

Abstract: The invention relates to a flame resistant paper product and a method for manufacturing a flame resistant paper product. In an embodiment the invention is a paper product comprising a paper substrate having a first surface and a second surface and a flame retardant composition, wherein the first surface is smoother than the second surface. In another embodiment, the invention is a method for forming a flame resistant paper product comprising applying a flame retardant composition to a web of fibers having a first surface and a second surface, wherein the first surface is smoother than the second surface by at least about 70 SSU according to TAPPI T538.

Abstract: The ecological flame retardant composition is adapted to protect materials that are flammable. No bromine or borax components are included in the composition. The composition has at least one of i) a mixture of ammonium sulphate and disodium hydrogen phosphate and ii) a mixture of water, ammonium sulphate and disodium hydrogen phosphate.

Abstract: A composition for treating wood-based material including at least one C1-C7 monocarboxylic acid salt or C1-C7 monocarboxylic acid or a mixture thereof as active agent against deteriation of wood. The composition also includes alkyd emulsion of high unsaturated fatty acid content and/or aluminum ion containing compound in the form of polyaluminum formate in a same aqueous liquid carrier as the C1-C7 monocarboxylic acid salt or C1-C7 monocarboxylic acid or a mixture thereof.

Abstract: There is provided a photosensitive thermosetting resin composition of an alkali development type from which it is possible to form a coating film that is halogen-free yet has high-level flame retardancy, has a superior low warpage property after it is cured, is excellent in plasticity, resolution, soldering heat resistance, chemical resistance, and the like, and a flexible printed circuit board using the same.

Abstract: This disclosure relates to inorganic coatings suitable for fire protection, fire retardancy, and articles comprising same. Specifically, the disclosure relates to the manufacture and use of inorganic phosphate-based coating formulations for fire protection, preventing or reducing fire propagation, and for heat management.

Abstract: The invention relates to novel compositions for fire-protection agents for materials, to a method for treating materials for protection against fire, and to the use of the compositions as fire-protection agents. More precisely, the invention relates to compositions for a fire-protection agent, such as a fire-protection paint, for materials, characterized in that ceramizing additives and volume-builders are contained as ingredients.

Abstract: A product to render flame- and fireproof surfaces and materials and inhibit the spread of fire on objects of various and diverse chemical nature and affinity, using non-toxic and non-carcinogenic basic fire and flame retardant intumescent mixtures with wide ranging chemical affinity, prepared in stable colloidal dispersion. The intumescent base comprises a colloidal solvent in which a source of phosphoric acid, a charring agent and a blowing agent are dissolved and dispersed. Intumescent mixtures are produced adding to said base flame spread reduction materials, thermal resistance enhancers, thermal transmission reduction and refractory, elasticity, water resistant materials and combinations thereof. Bipolar chemicals are also added to change the chemical affinity. Products are applicable on household, professional and industrial materials and objects, natural, synthetic and metallic.

Abstract: The present invention provides compositions for application to a material, such as building materials, prior to an exposure of the material to fire, or prior to, during or after exposure of the material to conditions favorable to the growth of microbes. When compositions within the present invention are properly applied to a material, they have the effect of reducing the amount of burning that occurs to the material, and/or reducing the amount or density of smoke and associated toxic gases produced by the material, when the material is exposed to fire, and inhibiting the growth of microbes on the material when the material is exposed to conditions favorable to the growth of microbes. The invention also provides methods for reducing the burning of a material that is exposed to fire, and for inhibiting the growth of microbes on a material exposed to conditions favorable to the growth of microbes.

Abstract: Compositions for creating flame-retardant, optically clear films without using halogen based flame retardants, including a coating containing phosphorous-based fire retardant materials, an acrylic or polyester adhesive base, and an organic solvent. Composite film structures containing the flame retardant coating may include a plurality of polymeric films and or coatings separated by flame retardant materials.

Abstract: The present invention relates to a floor covering based on linoleum having improved fire-protection properties, comprising at least one wear layer made of linoleum, which contains at least one phosphorus-containing compound, solution, suspension, or dispersion as a liquid/viscous flame retardant in a quantity of up to 20 weight-percent, in relation to the quantity of the wear layer, as well as a method for the manufacture thereof. Furthermore, the present invention relates to a floor covering based on cork having improved flame protection properties, comprising at least one phosphorus-containing compound, solution, suspension, or dispersion as a liquid/viscous flame retardant in a quantity of up to 20 weight-percent, in relation to the quantity of the wear layer.

Abstract: Fire retardant compositions containing an extract of African Oil Palm fruit, methods of preparing such compositions, and their use in imparting fire resistance to objects are disclosed.

Abstract: The present invention relates to a fire-resistant coating and method thereof, which confers enhanced flame and heat resistance to substrate such as building materials. The invented coating is especially applicable to cellulose-based building materials including but not limited to fiberboards, wallboards, roofing materials, particleboards, ceiling tiles, soundproofing boards and hardboards. This novel composition is also useful in providing a fire-resistant coating for concrete, metals, foamed polymeric materials, gypsum and other substrates. A preferred embodiment generally comprising: mono potassium phosphate, magnesium oxide, silica powder, calcium silicate, rice hull ash and water. A method for imparting fire-retardancy to substrates using the invented composition is also described.

Abstract: The invention relates to a flame retardant, comprising (A) a triazine-phenolic resin, (B) a nitrogen-containing compound, and (C) at least one metal compound, wherein said triazine-phenolic resin has formula (I): wherein, m and n are independently an integer ranging from 1 to 10 and R is OH, NH2, COOH, SO3H, C(O)H, or CH3CONH. The invention further relates to flame-retardant resin composition containing the above flame retardant and its use.

Abstract: A closed-loop system and process is used for applying fire retardant chemicals to fibers. Fibers are preferably positioned in a vessel such as a dye machine which circulates the fire retardant chemicals. After absorption of the fire retardant composition, non-absorbed fire retardant chemicals are recovered and re-used on subsequent batches of fibers. Recovery can be achieved by directing the non-absorbed fire retardant composition into a second dye machine containing additional fibers, or by extracting the fire retardant composition by centrifugation or other means, or by a combination of the two processes. The process is environmentally friendly, and allows for higher throughput on impregnating fibers with fire retardant chemicals.

Abstract: The invention relates to a white, biaxially oriented film which comprises a crystallizable thermoplastic as main componet and is characterized by further comprising at least one UV-stabilizer, at least one white pigment and at least one flame-proofing agent, which is soluble in the thermoplastic and introduced directly, during the film production, by masterbatch technology, whereby the masterbatch is pre-conditioned by gradual heating under reduced pressure and with stirring.

Abstract: An aerated refractory is provided comprising a mixture containing a phosphate compound, a metal oxide, a calcium containing compound; and an agent for increasing the volume of the mixture. Also provided is a method for protecting a substrate with aerated refractory, the method comprising dry mixing mono-potassium phosphate with a metal oxide and a calcium containing compound (i.e. hydroxyapatite) to produce a homogenous dry mixture; adding water to the mixture to produce a slurry; adding a foaming agent to the slurry; applying the slurry to the substrate; and allowing the slurry to dry.

Abstract: A process for an aqueous liquid flame retardant and fire quenching and extinguishing product for various and diverse materials with wide ranging chemical affinity. Preparations are safe, non-toxic, for professional and household use, in a stable colloidal dispersion. Mixtures include a base comprised a source of phosphoric acid, a charring agent, and a blowing agent. Products can be used with conventional manual and household spraying means, and have long shelf life and stability.

Abstract: Corrosion-inhibited fire retardant compositions and methods of making and using the same are provided. The corrosion-inhibited fire retardant compositions are comprised of at least one fire retardant component, at least one biopolymer having a particle size diameter of less than about 100 microns, and a corrosion inhibiting system.

Abstract: Biaxially oriented, co-extruded polyester films comprising a base layer consisting of at least 90 wt. % thermoplastic polyester, preferably polyethylene terephthalate (PET), at least one sealable outer layer and a second non-sealable outer layer and, optionally, other intermediate layers, in addition to at least one flame-retardant agent, preferably organic phosphorous compounds. The inventive films are characterized by low inflammability, no embrittlement when subjected to thermal stress and a surface which is devoid of troublesome opacity, and are suitable for a multiplicity of uses both indoors and outside. The outer layers contain anti-blocking agents such as silicic acid having a particle diameter of preferably less than 50 nm and/or more than 2 ?m. Preferably, the sealable outer layer consists of a copolyester which is made of ethylene terephthalate and ethylene isophthalate units.

Abstract: Inorganic resin compositions comprising, in combination, an aqueous solution of metal phosphate, an oxy-boron compound, a wollastonite compound and other optional additives, inorganic composite articles and products reinforced by fillers and fibers including glass fibers obtained from these compositions and processes for preparing said products.