Starch Ester Patents (Class 106/207.1)
  • Patent number: 11098134
    Abstract: The present disclosure describes tunable methods of treating cellulosic materials with a composition that provides increased hydrophobicity and/or lipophobicity to such materials without sacrificing the biodegradability thereof. The methods as disclosed provide for binding of saccharide fatty acid esters on cellulosic materials, including that the disclosure provides products made by such methods. The materials thus treated display higher hydrophobicity, lipophobicity, barrier function, and mechanical properties, and may be used in any application where such features are desired.
    Type: Grant
    Filed: January 3, 2020
    Date of Patent: August 24, 2021
    Assignee: HS Manufacturing Group, LLC
    Inventors: Jonathan Spender, Michael Albert Bilodeau, Daryl Aubrey Basham, Nirmal Singh Basi
  • Patent number: 11046789
    Abstract: The present disclosure describes tunable methods of treating cellulosic materials with a composition that provides increased hydrophobicity and/or lipophobicity to such materials without sacrificing the biodegradability thereof. The methods as disclosed provide for binding of saccharide fatty acid esters on cellulosic materials, including that the disclosure provides products made by such methods. The materials thus treated display higher hydrophobicity, lipophobicity, barrier function, and mechanical properties, and may be used in any application where such features are desired.
    Type: Grant
    Filed: January 3, 2020
    Date of Patent: June 29, 2021
    Assignee: HS Manufacturing Group, LLC
    Inventors: Jonathan Spender, Michael Albert Bilodeau, Daryl Aubrey Basham, Nirmal Singh Basi
  • Patent number: 10934448
    Abstract: A barrier coating composition comprising a starch material characterised in that the starch material has a weight average molecular weight of 50.000 to 1.000.000 Dalton and a glass transition temperature (Tg) of no more than 120° C.
    Type: Grant
    Filed: December 7, 2016
    Date of Patent: March 2, 2021
    Assignee: CARGILL, INCORPORATED
    Inventors: Mercedes Brighenti, Olaf Meinders, Dogan Sahin Sivasligil, Richard Thalhofer
  • Patent number: 10323158
    Abstract: A coating slip includes water, at least one pigment and at least one modified starch, exhibiting: a weight-average molecular weight ranging from 250 000 to 2 000 000 Da; and a solubility, measured according to a test A, ranging from 50 to 85%. A process for the preparation of the slip, and a process for coating paper using this slip are also described.
    Type: Grant
    Filed: November 16, 2012
    Date of Patent: June 18, 2019
    Assignee: Roquettes Freres
    Inventors: Julien Mesnager, Vincent Wiatz, Patrick Dauchy, Ludivine Onic
  • Patent number: 10221526
    Abstract: Provided is a textile printing paper for use in a paper printing method, the textile printing paper being excellent in releasability from a printing substrate and resistance to fogging of the print while satisfying the requirements for adhesiveness of a printed paper to a printing substrate. The textile printing paper comprises a base paper and a glue layer on a surface of the base paper, the base paper having a wax pick resistance of No. 8A or higher.
    Type: Grant
    Filed: January 27, 2016
    Date of Patent: March 5, 2019
    Assignee: MITSUBISHI PAPER MILLS LIMITED
    Inventor: Shinichiro Matsumoto
  • Patent number: 8623504
    Abstract: Particles of a polysaccharide derivative, having at least one substituent with conjugated unsaturated bonds and exhibiting an index of refraction in excess of 1.50 and a method for the production thereof. In the method, the raw-material is suspended in an organic solvent to form a suspension, which is contacted with an organic reactant comprising a residue with conjugated unsaturated bonds; the raw-material and the organic reactant are reacted to form a derivative exhibiting ester or ether bond between the raw-material and the residue with conjugated unsaturated bonds; the polysaccharide derivative is dissolved in a solvent to form a solution; and the solution is contacted with a non-solvent to precipitate particles of the polysaccharide derivative. The invention provides lightweight, optically improved organic pigments and fillers based on renewable resources and which are recyclable by combustion or composting.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: January 7, 2014
    Assignee: Teknologian Tutkimuskeskus VTT
    Inventors: Hannu Mikkonen, Kaisa Putkisto, Soili Peltonen, Sari Hyvärinen, Kimmo Koivunen
  • Patent number: 8597422
    Abstract: The present invention relates to a light, biodegradable, organic pigment and filler, and a method of manufacturing it. According to the present invention, a solution comprising a starch derivative is first prepared by dissolving the starch derivative into a suitable solvent, and, after that, the solution is brought into contact with a non-solvent to precipitate the starch derivative from the solvent, and, as a result, a dispersion is obtained, one which comprises a precipitate consisting of starch derivative and a liquid phase formed of the solvent and the non-solvent, after which the solvent is removed from the liquid phase and the precipitate is separated from the non-solvent and recovered. The present invention can be used to manufacture both a product comprising 100-300 nm spherical particles, which is suitable for use as a pigment, and a coral-like, porous product which is particularly suitable as a filler.
    Type: Grant
    Filed: October 1, 2004
    Date of Patent: December 3, 2013
    Assignee: Valtion Teknillinen Tutkimuskeskus
    Inventors: Soili Peltonen, Hannu Mikkonen, Pia Qvintus-Leino, Petri Varjos, Kirsi Kataja
  • Patent number: 8444820
    Abstract: An aqueous composition which is anionic in nature, includes at least one soluble gelatinized anionic starch and at least one insoluble anionic starch. A method of using the composition, in particular for the manufacture of a paper or of a flat board, and the paper or the flat board obtained therefrom, along with various industrial uses such as water treatment or the production of cosmetic products, are also described.
    Type: Grant
    Filed: November 18, 2008
    Date of Patent: May 21, 2013
    Assignee: Roquette Freres
    Inventors: Herve Gombert, Jerome Klaeyle, Claude Quettier
  • Patent number: 8277554
    Abstract: The invention relates to a hot melt adhesive, comprising at least one polysaccharide ester gained by a reaction of a polysaccharide with an imidazolide in melted imidazole. The invention relates, further, to a process for producing the hot melt adhesive, in which imidazole is melted, and an acid chloride and/or an acid anhydride and/or a lactone is reacted in and with the melted imidazole to form an imidazolide, whereby at least one polysaccharide is added to the melted imidazole, whereby the polysaccharide is reacted with the imidazolide to form a polysaccharide ester.
    Type: Grant
    Filed: November 16, 2010
    Date of Patent: October 2, 2012
    Assignees: Innovent e.V., Friedrich-Schiller-Universitat
    Inventors: Bernd Grünler, Andreas Heft, Marion Homuth, Thomas Heinze, Tim Liebert
  • Publication number: 20110180760
    Abstract: The invention relates to a hot melt adhesive, comprising at least one polysaccharide ester gained by a reaction of a polysaccharide with an imidazolide in melted imidazole. The invention relates, further, to a process for producing the hot melt adhesive, in which imidazole is melted, and an acid chloride and/or an acid anhydride and/or a lactone is reacted in and with the melted imidazole to form an imidazolide, whereby at least one polysaccharide is added to the melted imidazole, whereby the polysaccharide is reacted with the imidazolide to form a polysaccharide ester.
    Type: Application
    Filed: November 16, 2010
    Publication date: July 28, 2011
    Inventors: Bernd Grünler, Andreas Heft, Marion Homuth, Thomas Heinze, Tim Liebert
  • Patent number: 7931778
    Abstract: The present disclosure relates to lecithin containing starch compositions. The disclosure also relates to processes for preparing the lecithin-containing starch compositions. Further, the disclosure relates to uses of the lecithin-containing compositions in the preparation of paper products that have oil and grease resistant properties, and/or have release properties. Further, the disclosure relates to paper products that include lecithin-containing compositions and to paper products resulting from the processes herein.
    Type: Grant
    Filed: October 25, 2006
    Date of Patent: April 26, 2011
    Assignee: Cargill, Incorporated
    Inventors: Ki-Oh Hwang, Jagannadh V. Satyavolu, Kevin Ray Anderson, James Donald Steinke
  • Publication number: 20110039056
    Abstract: A carpet material with at least one of its components made easier for recycle by use of an adhesive which can be selectively altered to change the adhesion strength to allow component carpet layers to be separated.
    Type: Application
    Filed: September 21, 2009
    Publication date: February 17, 2011
    Applicant: INTERFACE INTERNATIONAL B.V.
    Inventors: John Robert Mantle, James Hanley Clark, Peter Samuel Shuttleworth
  • Publication number: 20100243188
    Abstract: An aqueous composition which is anionic in nature, includes at least one soluble gelatinized anionic starch and at least one insoluble anionic starch. A method of using the composition, in particular for the manufacture of a paper or of a flat board, and the paper or the flat board obtained therefrom, along with various industrial uses such as water treatment or the production of cosmetic products, are also described.
    Type: Application
    Filed: November 18, 2008
    Publication date: September 30, 2010
    Applicant: ROQUETTE FRERES
    Inventors: Herve Gombert, Jerome Klaeyle, Claude Quettier
  • Publication number: 20100126381
    Abstract: The invention relates to pharmaceutical, cosmetic, nutraceutical and food areas, in particular to compositions for coating tablets, capsules and other solid- or semisolid-form substances currently used in different application fields. More specifically, said invention relates to solid ready-for-use compositions for producing laminating solutions or dispersions for solid- or semisolid-form substances and is characterised in that the viscosity of said cold-regenerated solutions or dispersions is less than 1000 centipoises at a solid matter concentration greater than 20%, wherein said viscosity is obtainable by using natural film-forming agents which are cold-soluble and exhibit a low viscosity in an aqueous medium at high concentrations.
    Type: Application
    Filed: October 26, 2006
    Publication date: May 27, 2010
    Inventors: Laurence Paris, Frédéric Vaures
  • Patent number: 7384467
    Abstract: The invention relates to modified wheat flour containing sodium metaphosphate Nan[PnO3n] for increasing the suspension stability of the flour. According to the invention, said modified wheat flour can be used as a substitute for starch in paper production.
    Type: Grant
    Filed: May 21, 2004
    Date of Patent: June 10, 2008
    Assignee: Muhle Runingen GmbH & Co. KG
    Inventors: Frank Pluschke, Sigurd Witt, Jan-Peter Maczynski
  • Patent number: 7264666
    Abstract: The invention relates to an adhesive formulation that comprises a starch-based adhesive dissolved in water. According to the invention the adhesive is made up of a native starch transglycosylation product and the solids content of the adhesive formulation is at least 45% by weight. The invention also relates to a method for preparing such adhesive formulations and to the use of the adhesives.
    Type: Grant
    Filed: February 17, 2003
    Date of Patent: September 4, 2007
    Assignee: Valtion teknillinen tutkimuskeskus
    Inventors: Soili Peltonen, Hannu Mikkonen
  • Patent number: 7153354
    Abstract: A chemically modified plasticized starch (CMPS) is prepared by reacting starch with an organic dibasic acid or an anhydride of the acid in the presence of a plasticizer using optional free radical initiators, and optionally with the incorporation of nano clays in the reactive extrusion process. The starch is thermoplastic and has a lower viscosity than the traditional thermoplastic starch. The CMPS is useful in preparing starch polymer compositions which are at least partially biodegradable.
    Type: Grant
    Filed: November 19, 2004
    Date of Patent: December 26, 2006
    Assignee: Board of Trustees of Michigan State University
    Inventors: Raamani Narayan, Sunder Balakrishnan, Yogaraj Nabar, Boo-Young Shin, Philippe Dubois, Jean-Marie Raquez
  • Patent number: 7141108
    Abstract: The present invention describes a means for fixing skin care ingredients on the surface of non-woven webs and cellulosic mats. The active ingredients can be released (deposited) onto the skin by normal triggering mechanisms, which include the action of water or urine or by friction or rubbing. The fixative systems described herein provide the ability to control high load levels while not interfering with the wettabliity of the fabric or paper. Additionally, incompatible/reactive ingredients can be treated onto the same web and are kept as separate particles fixed to the surface until released.
    Type: Grant
    Filed: September 8, 2005
    Date of Patent: November 28, 2006
    Assignee: National Starch and Chemical Investment Holding Corp.
    Inventors: James L. Eden, Mark A. Cole, Remo Santacecilia
  • Patent number: 7056377
    Abstract: A starch with a high content in amylose, obtained through a process comprising acetylation and pre-gellation, can provide useful coatings in food, drug, cosmetic and dietetic fields, both for humans and animals, and also in agriculture.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: June 6, 2006
    Assignee: F.T. Holdings S.A.
    Inventor: Francesco Roversi
  • Patent number: 7048794
    Abstract: An inorganic-organic composite comprises an inorganic phase, such as gypsum crystals, and a film forming organic phase. The film forming organic phase is selected from substituted starches having a degree of polymerization; degree of substitution and viscosity such that the substituted starches are insoluble in water during mixing but dissolve at a higher processing temperature during forming, setting or drying of the composite. Thus, excessive migration of the substitute starch is prevented and the composite is substantially strengthened.
    Type: Grant
    Filed: September 27, 2004
    Date of Patent: May 23, 2006
    Assignee: Innovative Construction and Building Materials, LLC
    Inventors: Christopher D. Tagge, Jacob Freas Pollock, Ken Saito
  • Patent number: 7022174
    Abstract: The present invention relates to compositions of starch. The compositions consist of an anionic and a cationic starch wherein at least one of the starches is waxy. The compositions are surprisingly not resulting in an agglomerated product when cooked. The compositions are used in paper or cardboard preparation. The compositions are cooked and added at the wet end of the paper production process. This results in a high possible addition level and the use of the size press is abolished. The resulting paper and board are shown to have better characteristics than the paper and board prepared with the same components which have not been mixed prior to addition but which are added separately.
    Type: Grant
    Filed: May 10, 2004
    Date of Patent: April 4, 2006
    Assignee: Cerestar Holding B.V.
    Inventors: Detlev Glittenberg, Peter Leonhardt
  • Patent number: 6899755
    Abstract: A sand sculpting composition including approximately 100 parts by dry weight of sand, between 0.1 part and 5 parts by dry weight of at least one non-toxic cold water-soluble adhesive agent selected from the group consisting of pre-gelatinized starches, chemically modified starches and chemically modified celluloses, and between 6 and 25 parts by weight water. The adhesive agent has been combined with the sand and an amount of water sufficient to both dissolve the adhesive agent and allow the adhesive agent to coat the particles of sand. A coloring agent may be added to the adhesive agent.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: May 31, 2005
    Assignee: Sandsmart, Inc.
    Inventor: Daniel Perlman
  • Patent number: 6811599
    Abstract: A biodegradable thermoplastic material comprising a natural polymer, a plasticizer and an exfoliated clay having a layered structure and a cation exchange capacity of from 30-250 milliequivalents per 100 grams and a process of preparing a biodegradable thermoplastic material comprising preparing a suspension of clay, combining said suspension with a natural polymer and a plasticizer and extruding the resultant composition at a temperature of 35-200° C.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: November 2, 2004
    Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO
    Inventors: Hartmut Rudolf Fischer, Sabine Fischer
  • Patent number: 6809197
    Abstract: Novel modified starch products and methods of preparation thereof are disclosed, wherein the starch products exhibit excellent water hydration and emulsion stabilization properties, while substantially maintaining individual granular structure. The modified starches are expanded or preswelled and cross-linked, preferably using a phosphate cross-linker, followed by substitution with hydrophobic moieties such as those derived from suitable acids or acid anhydrides.
    Type: Grant
    Filed: June 11, 2003
    Date of Patent: October 26, 2004
    Assignee: MGP Ingredients, Inc.
    Inventors: Kyungsoo Woo, Clodualdo Maningat, Sukh Bassi
  • Patent number: 6749722
    Abstract: The present invention relates to a method of manufacturing a paper of multi-color ink-jet printable grade. A proper hydrophicity for the paper is secured by using an 2-oxetanone size in the appropriate sizing steps. The size is made from non-branched and branched-chain fatty acids having main chain comprising 6-22 carbons linked with each other by saturated bonds.
    Type: Grant
    Filed: July 2, 2001
    Date of Patent: June 15, 2004
    Assignee: Raisio Chemicals Ltd.
    Inventors: Olof Malmström, Markku Nurminen, Raija Savolainen, Ari Teijo, Claes Zetter
  • Publication number: 20030173045
    Abstract: The present invention relates to a liquid starch dispersion for paper coating where the dispersion has 5 to 50 percent by weight of starch, and the starch contains from 20 to 100 percent by weight of at least one cationic starch. The liquid starch composition is characterized in that a 25 percent by weight starch solids dispersion has a 25° C. viscosity of from 500 to 2500 cps both initially, and also upon storage at room temperature for 90 days. The dispersion preferably contains a blend of cationic starch and ASA starch. The liquid starch dispersion is useful in paper and paperboard coating processes, as a rheology modifier, a structurant, and/or a binder, all at the same time. The liquid starch dispersion provides good coating holdout, gloss, and stiffness properties. The cationic nature of the starch coating improves printability with anionic inks, and makes the coatings useful for ink-jet and photographic papers.
    Type: Application
    Filed: March 18, 2002
    Publication date: September 18, 2003
    Inventors: Philip Confalone, Daniel B. Solarek, Aqnieszka Lapinska, Wayne Kibble
  • Publication number: 20030141637
    Abstract: The invention relates to the field of processing starch. In particular, the invention relates to a process for extruding starch to obtain a starch product having a certain intrinsic viscosity when dissolved or dispersed in water, which process requires less specific mechanical energy input than conventional extrusions of starch.
    Type: Application
    Filed: December 2, 2002
    Publication date: July 31, 2003
    Inventors: Ronald Peter W Kesselmans, Berend Venema, Egbert Hadderingh
  • Patent number: 6521088
    Abstract: This invention is directed to degraded, hydrated particulate starches that are hydrophobically modified and a method of providing paper with reduced porosity, resistance to liquid penetration and increased surface strength comprising applying to the surface of a paper substrate an effective amount of a surface sizing composition which comprises such starch. In particular, the starches are those in which the starch base is degraded to a water fluidity (WF) of from about 10 to 80 or the modified and/or particulate starch is degraded using a substantially equivalent amount of degradation agent and substantially the same reaction conditions, the starch is modified with a hydrophobic hydrocarbon group of 5 to 23 carbon atoms at about 1 to 20% substitution level by weight of bound hydrophobe based on the weight of starch, and the hydrated starch has a volume average hydrated particle size of at least about 20 microns and a volume fraction of hydrated particles at 1% solids of at least about 5%.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: February 18, 2003
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Paul H. Richardson, Ralph M. Trksak, John J. Tsai, Eric M. Weisser
  • Patent number: RE41622
    Abstract: The present invention relates to compositions of starch. The compositions consist of an anionic and a cationic starch wherein at least one of the starches is waxy. The compositions are surprisingly not resulting in an agglomerated product when cooked. The compositions are used in paper or cardboard preparation. The compositions are cooked and added at the wet end of the paper production process. This results in a high possible addition level and the use of the size press is abolished. The resulting paper and board are shown to have better characteristics than the paper and board prepared with the same components which have not been mixed prior to addition but which are added separately.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: September 7, 2010
    Assignee: Cerestar Holding B.V.
    Inventors: Detlev Glittenberg, Peter Leonhardt