Starch Ester Patents (Class 106/207.1)
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Patent number: 12157836Abstract: The present invention provides a preparation method of an oxidized anticoagulant starch adhesive, comprising the following steps: (1) an original starch and deionized water are mixed to form a starch emulsion, then the pH is adjusted to perform an oxidation reaction; a reductant is added to react with the unreacted oxidant, after the reaction is completed, an esterifying agent is added to perform an esterification reaction after adjusting pH; then a product is neutralized, washed, filtered and dried to obtain starch granules; and (2) a 40-50% starch emulsion is formulated by using the starch granules obtained in the step (1), the pH is adjusted to 6.5-7.5 after gelatinization, and dispersing agent, defoamer and water are added to form a starch adhesive. The esterifying agent used is composed of an anion and a cation, which significantly improves anticoagulant effect of the starch adhesive.Type: GrantFiled: October 15, 2020Date of Patent: December 3, 2024Assignee: Hongsheng Technology (Beijing) Co., LtdInventors: Zhongda Duan, Runda Yan
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Patent number: 11098134Abstract: The present disclosure describes tunable methods of treating cellulosic materials with a composition that provides increased hydrophobicity and/or lipophobicity to such materials without sacrificing the biodegradability thereof. The methods as disclosed provide for binding of saccharide fatty acid esters on cellulosic materials, including that the disclosure provides products made by such methods. The materials thus treated display higher hydrophobicity, lipophobicity, barrier function, and mechanical properties, and may be used in any application where such features are desired.Type: GrantFiled: January 3, 2020Date of Patent: August 24, 2021Assignee: HS Manufacturing Group, LLCInventors: Jonathan Spender, Michael Albert Bilodeau, Daryl Aubrey Basham, Nirmal Singh Basi
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Patent number: 11046789Abstract: The present disclosure describes tunable methods of treating cellulosic materials with a composition that provides increased hydrophobicity and/or lipophobicity to such materials without sacrificing the biodegradability thereof. The methods as disclosed provide for binding of saccharide fatty acid esters on cellulosic materials, including that the disclosure provides products made by such methods. The materials thus treated display higher hydrophobicity, lipophobicity, barrier function, and mechanical properties, and may be used in any application where such features are desired.Type: GrantFiled: January 3, 2020Date of Patent: June 29, 2021Assignee: HS Manufacturing Group, LLCInventors: Jonathan Spender, Michael Albert Bilodeau, Daryl Aubrey Basham, Nirmal Singh Basi
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Patent number: 10934448Abstract: A barrier coating composition comprising a starch material characterised in that the starch material has a weight average molecular weight of 50.000 to 1.000.000 Dalton and a glass transition temperature (Tg) of no more than 120° C.Type: GrantFiled: December 7, 2016Date of Patent: March 2, 2021Assignee: CARGILL, INCORPORATEDInventors: Mercedes Brighenti, Olaf Meinders, Dogan Sahin Sivasligil, Richard Thalhofer
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Patent number: 10323158Abstract: A coating slip includes water, at least one pigment and at least one modified starch, exhibiting: a weight-average molecular weight ranging from 250 000 to 2 000 000 Da; and a solubility, measured according to a test A, ranging from 50 to 85%. A process for the preparation of the slip, and a process for coating paper using this slip are also described.Type: GrantFiled: November 16, 2012Date of Patent: June 18, 2019Assignee: Roquettes FreresInventors: Julien Mesnager, Vincent Wiatz, Patrick Dauchy, Ludivine Onic
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Patent number: 10221526Abstract: Provided is a textile printing paper for use in a paper printing method, the textile printing paper being excellent in releasability from a printing substrate and resistance to fogging of the print while satisfying the requirements for adhesiveness of a printed paper to a printing substrate. The textile printing paper comprises a base paper and a glue layer on a surface of the base paper, the base paper having a wax pick resistance of No. 8A or higher.Type: GrantFiled: January 27, 2016Date of Patent: March 5, 2019Assignee: MITSUBISHI PAPER MILLS LIMITEDInventor: Shinichiro Matsumoto
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Patent number: 8623504Abstract: Particles of a polysaccharide derivative, having at least one substituent with conjugated unsaturated bonds and exhibiting an index of refraction in excess of 1.50 and a method for the production thereof. In the method, the raw-material is suspended in an organic solvent to form a suspension, which is contacted with an organic reactant comprising a residue with conjugated unsaturated bonds; the raw-material and the organic reactant are reacted to form a derivative exhibiting ester or ether bond between the raw-material and the residue with conjugated unsaturated bonds; the polysaccharide derivative is dissolved in a solvent to form a solution; and the solution is contacted with a non-solvent to precipitate particles of the polysaccharide derivative. The invention provides lightweight, optically improved organic pigments and fillers based on renewable resources and which are recyclable by combustion or composting.Type: GrantFiled: December 30, 2009Date of Patent: January 7, 2014Assignee: Teknologian Tutkimuskeskus VTTInventors: Hannu Mikkonen, Kaisa Putkisto, Soili Peltonen, Sari Hyvärinen, Kimmo Koivunen
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Patent number: 8597422Abstract: The present invention relates to a light, biodegradable, organic pigment and filler, and a method of manufacturing it. According to the present invention, a solution comprising a starch derivative is first prepared by dissolving the starch derivative into a suitable solvent, and, after that, the solution is brought into contact with a non-solvent to precipitate the starch derivative from the solvent, and, as a result, a dispersion is obtained, one which comprises a precipitate consisting of starch derivative and a liquid phase formed of the solvent and the non-solvent, after which the solvent is removed from the liquid phase and the precipitate is separated from the non-solvent and recovered. The present invention can be used to manufacture both a product comprising 100-300 nm spherical particles, which is suitable for use as a pigment, and a coral-like, porous product which is particularly suitable as a filler.Type: GrantFiled: October 1, 2004Date of Patent: December 3, 2013Assignee: Valtion Teknillinen TutkimuskeskusInventors: Soili Peltonen, Hannu Mikkonen, Pia Qvintus-Leino, Petri Varjos, Kirsi Kataja
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Patent number: 8444820Abstract: An aqueous composition which is anionic in nature, includes at least one soluble gelatinized anionic starch and at least one insoluble anionic starch. A method of using the composition, in particular for the manufacture of a paper or of a flat board, and the paper or the flat board obtained therefrom, along with various industrial uses such as water treatment or the production of cosmetic products, are also described.Type: GrantFiled: November 18, 2008Date of Patent: May 21, 2013Assignee: Roquette FreresInventors: Herve Gombert, Jerome Klaeyle, Claude Quettier
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Patent number: 8277554Abstract: The invention relates to a hot melt adhesive, comprising at least one polysaccharide ester gained by a reaction of a polysaccharide with an imidazolide in melted imidazole. The invention relates, further, to a process for producing the hot melt adhesive, in which imidazole is melted, and an acid chloride and/or an acid anhydride and/or a lactone is reacted in and with the melted imidazole to form an imidazolide, whereby at least one polysaccharide is added to the melted imidazole, whereby the polysaccharide is reacted with the imidazolide to form a polysaccharide ester.Type: GrantFiled: November 16, 2010Date of Patent: October 2, 2012Assignees: Innovent e.V., Friedrich-Schiller-UniversitatInventors: Bernd Grünler, Andreas Heft, Marion Homuth, Thomas Heinze, Tim Liebert
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Publication number: 20110180760Abstract: The invention relates to a hot melt adhesive, comprising at least one polysaccharide ester gained by a reaction of a polysaccharide with an imidazolide in melted imidazole. The invention relates, further, to a process for producing the hot melt adhesive, in which imidazole is melted, and an acid chloride and/or an acid anhydride and/or a lactone is reacted in and with the melted imidazole to form an imidazolide, whereby at least one polysaccharide is added to the melted imidazole, whereby the polysaccharide is reacted with the imidazolide to form a polysaccharide ester.Type: ApplicationFiled: November 16, 2010Publication date: July 28, 2011Inventors: Bernd Grünler, Andreas Heft, Marion Homuth, Thomas Heinze, Tim Liebert
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Patent number: 7931778Abstract: The present disclosure relates to lecithin containing starch compositions. The disclosure also relates to processes for preparing the lecithin-containing starch compositions. Further, the disclosure relates to uses of the lecithin-containing compositions in the preparation of paper products that have oil and grease resistant properties, and/or have release properties. Further, the disclosure relates to paper products that include lecithin-containing compositions and to paper products resulting from the processes herein.Type: GrantFiled: October 25, 2006Date of Patent: April 26, 2011Assignee: Cargill, IncorporatedInventors: Ki-Oh Hwang, Jagannadh V. Satyavolu, Kevin Ray Anderson, James Donald Steinke
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Publication number: 20110039056Abstract: A carpet material with at least one of its components made easier for recycle by use of an adhesive which can be selectively altered to change the adhesion strength to allow component carpet layers to be separated.Type: ApplicationFiled: September 21, 2009Publication date: February 17, 2011Applicant: INTERFACE INTERNATIONAL B.V.Inventors: John Robert Mantle, James Hanley Clark, Peter Samuel Shuttleworth
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Publication number: 20100243188Abstract: An aqueous composition which is anionic in nature, includes at least one soluble gelatinized anionic starch and at least one insoluble anionic starch. A method of using the composition, in particular for the manufacture of a paper or of a flat board, and the paper or the flat board obtained therefrom, along with various industrial uses such as water treatment or the production of cosmetic products, are also described.Type: ApplicationFiled: November 18, 2008Publication date: September 30, 2010Applicant: ROQUETTE FRERESInventors: Herve Gombert, Jerome Klaeyle, Claude Quettier
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Publication number: 20100126381Abstract: The invention relates to pharmaceutical, cosmetic, nutraceutical and food areas, in particular to compositions for coating tablets, capsules and other solid- or semisolid-form substances currently used in different application fields. More specifically, said invention relates to solid ready-for-use compositions for producing laminating solutions or dispersions for solid- or semisolid-form substances and is characterised in that the viscosity of said cold-regenerated solutions or dispersions is less than 1000 centipoises at a solid matter concentration greater than 20%, wherein said viscosity is obtainable by using natural film-forming agents which are cold-soluble and exhibit a low viscosity in an aqueous medium at high concentrations.Type: ApplicationFiled: October 26, 2006Publication date: May 27, 2010Inventors: Laurence Paris, Frédéric Vaures
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Patent number: 7384467Abstract: The invention relates to modified wheat flour containing sodium metaphosphate Nan[PnO3n] for increasing the suspension stability of the flour. According to the invention, said modified wheat flour can be used as a substitute for starch in paper production.Type: GrantFiled: May 21, 2004Date of Patent: June 10, 2008Assignee: Muhle Runingen GmbH & Co. KGInventors: Frank Pluschke, Sigurd Witt, Jan-Peter Maczynski
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Patent number: 7264666Abstract: The invention relates to an adhesive formulation that comprises a starch-based adhesive dissolved in water. According to the invention the adhesive is made up of a native starch transglycosylation product and the solids content of the adhesive formulation is at least 45% by weight. The invention also relates to a method for preparing such adhesive formulations and to the use of the adhesives.Type: GrantFiled: February 17, 2003Date of Patent: September 4, 2007Assignee: Valtion teknillinen tutkimuskeskusInventors: Soili Peltonen, Hannu Mikkonen
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Patent number: 7153354Abstract: A chemically modified plasticized starch (CMPS) is prepared by reacting starch with an organic dibasic acid or an anhydride of the acid in the presence of a plasticizer using optional free radical initiators, and optionally with the incorporation of nano clays in the reactive extrusion process. The starch is thermoplastic and has a lower viscosity than the traditional thermoplastic starch. The CMPS is useful in preparing starch polymer compositions which are at least partially biodegradable.Type: GrantFiled: November 19, 2004Date of Patent: December 26, 2006Assignee: Board of Trustees of Michigan State UniversityInventors: Raamani Narayan, Sunder Balakrishnan, Yogaraj Nabar, Boo-Young Shin, Philippe Dubois, Jean-Marie Raquez
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Patent number: 7141108Abstract: The present invention describes a means for fixing skin care ingredients on the surface of non-woven webs and cellulosic mats. The active ingredients can be released (deposited) onto the skin by normal triggering mechanisms, which include the action of water or urine or by friction or rubbing. The fixative systems described herein provide the ability to control high load levels while not interfering with the wettabliity of the fabric or paper. Additionally, incompatible/reactive ingredients can be treated onto the same web and are kept as separate particles fixed to the surface until released.Type: GrantFiled: September 8, 2005Date of Patent: November 28, 2006Assignee: National Starch and Chemical Investment Holding Corp.Inventors: James L. Eden, Mark A. Cole, Remo Santacecilia
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Patent number: 7056377Abstract: A starch with a high content in amylose, obtained through a process comprising acetylation and pre-gellation, can provide useful coatings in food, drug, cosmetic and dietetic fields, both for humans and animals, and also in agriculture.Type: GrantFiled: January 26, 2001Date of Patent: June 6, 2006Assignee: F.T. Holdings S.A.Inventor: Francesco Roversi
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Patent number: 7048794Abstract: An inorganic-organic composite comprises an inorganic phase, such as gypsum crystals, and a film forming organic phase. The film forming organic phase is selected from substituted starches having a degree of polymerization; degree of substitution and viscosity such that the substituted starches are insoluble in water during mixing but dissolve at a higher processing temperature during forming, setting or drying of the composite. Thus, excessive migration of the substitute starch is prevented and the composite is substantially strengthened.Type: GrantFiled: September 27, 2004Date of Patent: May 23, 2006Assignee: Innovative Construction and Building Materials, LLCInventors: Christopher D. Tagge, Jacob Freas Pollock, Ken Saito
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Patent number: 7022174Abstract: The present invention relates to compositions of starch. The compositions consist of an anionic and a cationic starch wherein at least one of the starches is waxy. The compositions are surprisingly not resulting in an agglomerated product when cooked. The compositions are used in paper or cardboard preparation. The compositions are cooked and added at the wet end of the paper production process. This results in a high possible addition level and the use of the size press is abolished. The resulting paper and board are shown to have better characteristics than the paper and board prepared with the same components which have not been mixed prior to addition but which are added separately.Type: GrantFiled: May 10, 2004Date of Patent: April 4, 2006Assignee: Cerestar Holding B.V.Inventors: Detlev Glittenberg, Peter Leonhardt
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Patent number: 6899755Abstract: A sand sculpting composition including approximately 100 parts by dry weight of sand, between 0.1 part and 5 parts by dry weight of at least one non-toxic cold water-soluble adhesive agent selected from the group consisting of pre-gelatinized starches, chemically modified starches and chemically modified celluloses, and between 6 and 25 parts by weight water. The adhesive agent has been combined with the sand and an amount of water sufficient to both dissolve the adhesive agent and allow the adhesive agent to coat the particles of sand. A coloring agent may be added to the adhesive agent.Type: GrantFiled: June 28, 2002Date of Patent: May 31, 2005Assignee: Sandsmart, Inc.Inventor: Daniel Perlman
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Patent number: 6811599Abstract: A biodegradable thermoplastic material comprising a natural polymer, a plasticizer and an exfoliated clay having a layered structure and a cation exchange capacity of from 30-250 milliequivalents per 100 grams and a process of preparing a biodegradable thermoplastic material comprising preparing a suspension of clay, combining said suspension with a natural polymer and a plasticizer and extruding the resultant composition at a temperature of 35-200° C.Type: GrantFiled: December 9, 2002Date of Patent: November 2, 2004Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNOInventors: Hartmut Rudolf Fischer, Sabine Fischer
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Patent number: 6809197Abstract: Novel modified starch products and methods of preparation thereof are disclosed, wherein the starch products exhibit excellent water hydration and emulsion stabilization properties, while substantially maintaining individual granular structure. The modified starches are expanded or preswelled and cross-linked, preferably using a phosphate cross-linker, followed by substitution with hydrophobic moieties such as those derived from suitable acids or acid anhydrides.Type: GrantFiled: June 11, 2003Date of Patent: October 26, 2004Assignee: MGP Ingredients, Inc.Inventors: Kyungsoo Woo, Clodualdo Maningat, Sukh Bassi
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Patent number: 6749722Abstract: The present invention relates to a method of manufacturing a paper of multi-color ink-jet printable grade. A proper hydrophicity for the paper is secured by using an 2-oxetanone size in the appropriate sizing steps. The size is made from non-branched and branched-chain fatty acids having main chain comprising 6-22 carbons linked with each other by saturated bonds.Type: GrantFiled: July 2, 2001Date of Patent: June 15, 2004Assignee: Raisio Chemicals Ltd.Inventors: Olof Malmström, Markku Nurminen, Raija Savolainen, Ari Teijo, Claes Zetter
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Publication number: 20030173045Abstract: The present invention relates to a liquid starch dispersion for paper coating where the dispersion has 5 to 50 percent by weight of starch, and the starch contains from 20 to 100 percent by weight of at least one cationic starch. The liquid starch composition is characterized in that a 25 percent by weight starch solids dispersion has a 25° C. viscosity of from 500 to 2500 cps both initially, and also upon storage at room temperature for 90 days. The dispersion preferably contains a blend of cationic starch and ASA starch. The liquid starch dispersion is useful in paper and paperboard coating processes, as a rheology modifier, a structurant, and/or a binder, all at the same time. The liquid starch dispersion provides good coating holdout, gloss, and stiffness properties. The cationic nature of the starch coating improves printability with anionic inks, and makes the coatings useful for ink-jet and photographic papers.Type: ApplicationFiled: March 18, 2002Publication date: September 18, 2003Inventors: Philip Confalone, Daniel B. Solarek, Aqnieszka Lapinska, Wayne Kibble
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Publication number: 20030141637Abstract: The invention relates to the field of processing starch. In particular, the invention relates to a process for extruding starch to obtain a starch product having a certain intrinsic viscosity when dissolved or dispersed in water, which process requires less specific mechanical energy input than conventional extrusions of starch.Type: ApplicationFiled: December 2, 2002Publication date: July 31, 2003Inventors: Ronald Peter W Kesselmans, Berend Venema, Egbert Hadderingh
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Patent number: 6521088Abstract: This invention is directed to degraded, hydrated particulate starches that are hydrophobically modified and a method of providing paper with reduced porosity, resistance to liquid penetration and increased surface strength comprising applying to the surface of a paper substrate an effective amount of a surface sizing composition which comprises such starch. In particular, the starches are those in which the starch base is degraded to a water fluidity (WF) of from about 10 to 80 or the modified and/or particulate starch is degraded using a substantially equivalent amount of degradation agent and substantially the same reaction conditions, the starch is modified with a hydrophobic hydrocarbon group of 5 to 23 carbon atoms at about 1 to 20% substitution level by weight of bound hydrophobe based on the weight of starch, and the hydrated starch has a volume average hydrated particle size of at least about 20 microns and a volume fraction of hydrated particles at 1% solids of at least about 5%.Type: GrantFiled: October 27, 2000Date of Patent: February 18, 2003Assignee: National Starch and Chemical Investment Holding CorporationInventors: Paul H. Richardson, Ralph M. Trksak, John J. Tsai, Eric M. Weisser
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Patent number: RE41622Abstract: The present invention relates to compositions of starch. The compositions consist of an anionic and a cationic starch wherein at least one of the starches is waxy. The compositions are surprisingly not resulting in an agglomerated product when cooked. The compositions are used in paper or cardboard preparation. The compositions are cooked and added at the wet end of the paper production process. This results in a high possible addition level and the use of the size press is abolished. The resulting paper and board are shown to have better characteristics than the paper and board prepared with the same components which have not been mixed prior to addition but which are added separately.Type: GrantFiled: December 20, 2006Date of Patent: September 7, 2010Assignee: Cerestar Holding B.V.Inventors: Detlev Glittenberg, Peter Leonhardt