Phosphorus Containing Patents (Class 106/284.1)
  • Patent number: 11365318
    Abstract: The present technology relates to an anti-stripping agent for an asphalt mixture, which includes a refined slowly-cooled slag obtained by processing slag, generated in ironmaking and steelmaking processes, using a specific method, and to a method for preparing the same, an asphalt mixture including the same, and a method for preparing the asphalt mixture. The refined slowly-cooled slag may include 55 to 65 mass % of CaO, 5 to 10 mass % of SiO2, 1 to 5 mass % of Al2O3, and 1 to 5 mass % of MgO.
    Type: Grant
    Filed: December 4, 2018
    Date of Patent: June 21, 2022
    Assignees: KOREA INSTITUTE of CIVIL ENGINEERING and BUILDING TECHNOLOGY, SP Nature Co. Ltd
    Inventors: Soo Ahn Kwon, Moon Sup Lee, Kang Hun Lee, Jeong Tan Son, Young Nam Han, Dong Ho Ha, Byoung In Jang, Jin Hyoung Lee
  • Patent number: 10435633
    Abstract: The invention relates to a method of increasing the American Petroleum Institute (API) gravity of feedstocks by reacting one or more mono-cyclic ether solvents such as oxolane with the asphaltene resident in bitumen or crude oils, at an ambient or elevated temperature, and at ambient or elevated pressure, to increase the API gravity and the economic value of the bitumen or crude oil, and a method for in situ manufacturing a mono-cyclic ether, oxolane, to rejuvenate bitumen or heavy crude oils into their younger lighter crude oils by blending methyl linoleate and methanol in a ratio; heating to produce oxolane; and contacting the oxolane as a solvent with the asphaltene resident in bitumen and heavy crude oils to release not only aromatic compounds, represented by toluene, but also the paraffinic alkanes, represented by n-heptane, making the feedstocks ready for extraction, separation of sand, pipeline transport and refining.
    Type: Grant
    Filed: June 29, 2018
    Date of Patent: October 8, 2019
    Assignee: DPD CHEMICALS INC.
    Inventor: Mathew Zuckerman
  • Patent number: 10024362
    Abstract: In order to make a bearing, such as a roller bearing, insensitive to a lack of maintenance lubrication or irregular maintenance lubrication while at the same time retaining its mechanical performance, at least one bearing part of the bearing is provided at least partially with an oleophilic adhesion promoter layer. The adhesion promoter layer binds a lubricant layer of the bearing to the bearing part provided with the adhesion promoter layer. The adhesion promoter layer is bonded to an elemental-iron-free surface of a bearing part body. The removal of free iron from the bearing part body surface is carried out with nitric acid, chromate solution and/or citric acid. The treated bearing part has an oleophilic anti-corrosion adhesion promoter layer. The bearing may be used in pressure-operated devices, in particular in turbine handpieces used by dentists, because the loss of the lubricant layer during operation of the device was particularly high.
    Type: Grant
    Filed: April 13, 2017
    Date of Patent: July 17, 2018
    Assignee: GRW GEBR. REINFURT GMBH & CO. KG
    Inventors: Christof Diener, Herbert Niedermeier
  • Patent number: 8906152
    Abstract: Pavement compositions containing increased amounts of reclaimed asphalt pavement (RAP) are described. Addition of polyphosphoric acid (PPA) to pavement compositions containing RAP allows increased RAP content in road pavements while maintaining acceptable properties in the final pavement composition. Methods for producing road pavements containing RAP and PPA are also provided.
    Type: Grant
    Filed: June 18, 2010
    Date of Patent: December 9, 2014
    Assignee: Innophos, Inc.
    Inventor: Jean-Valery Martin
  • Publication number: 20140230693
    Abstract: The present invention relates to a method of improving the incorporation of recycled bituminous products by using at least one surfactant as an alternative to the known rejuvenating oils, for the preparation of asphalt mixes containing recycled bituminous products. The use of such alternative surfactant(s) results in better mechanical properties of the asphalt mix, while using smaller amounts of fresh bitumen and greater amounts of recycled bituminous products.
    Type: Application
    Filed: October 12, 2012
    Publication date: August 21, 2014
    Applicant: CECA S.A.
    Inventors: Juan Antonio Gonzalez Leon, Gilles Barreto, Vincent Luca
  • Patent number: 8801849
    Abstract: Polyphosphoric acid compositions having a reduced viscosity compared to neat polyphosphoric acid. The viscosity of the polyphosphoric acid is reduced by combining the polyphosphoric acid with an additive that reduces the viscosity of the polyphosphoric acid composition. In one embodiment, additives that can cause solvation and/or partial neutralization of the polyphosphoric acid without the addition of water may be used. The reduced viscosity polyphosphoric acid may be used, for example, as an additive in asphalts used in road pavements.
    Type: Grant
    Filed: June 1, 2011
    Date of Patent: August 12, 2014
    Assignee: Innophos, Inc.
    Inventors: Jean-Valery Martin, Robert Finn
  • Patent number: 8771413
    Abstract: The present invention is related to asphalt and asphalt-mineral compositions including at least one cationic organosilicon compound selected from a group consisting of: Y3-aSi(R1a)R2N+R3R4R5X?, Y3-aSi(R1a)R2P+R3R4R5X?, Y3-aSi(R1a)R2ZX?; or mixtures thereof, wherein in each formula Y is independently selected from a group consisting of OR, O(CH2CH2O)nH, (CH3OCH2CH2O), and (CH3CH2OCH2CH2O); a has a value selected from 0, 1 or 2; n is a value from 1 to 10; R is C1-C4 alkyl; R1 is either methyl or ethyl; R2 is C1-C4 alkylene group; R3, R4 and R5 are each independently selected from a group consisting of C1-C22 alkyl wherein at least one such group has more than 8 C-atoms, —CH2C6H5, —CH2CH2OH, —CH2OH and —(CH2)yNHC(O)R6 wherein y has a value of from 2 to 10 and R6 is a C1-C12 perfluoroalkyl radical; X is chloride, bromide, fluoride, iodide, acetate or tosylate; and Z is pyridinium ring of formula C5H5N+.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: July 8, 2014
    Assignee: Zydex Industries
    Inventors: Ajay Ranka, Prakash Mehta
  • Patent number: 8664303
    Abstract: In a first aspect, bituminous asphalt binder materials which are modified by the addition of crumb rubber or ground tire rubber are described. In a second aspect, the present invention is directed to methods of producing a modified asphalt binder containing crumb rubber or ground tire rubber. The modified asphalt binders comprise neat asphalt, crumb rubber, one or more synthetic polymers, and one or more acids. The crumb rubber may be obtained from recycled truck and/or automobile tires.
    Type: Grant
    Filed: October 29, 2008
    Date of Patent: March 4, 2014
    Assignee: Innophos, Inc.
    Inventor: Jean-Valery Martin
  • Patent number: 8591646
    Abstract: The present invention relates to construction materials comprising at least one binder, at least one oil-containing filler and at least one metallate additive according to formula (1): (RO)m-M-(Oa—Xb—R?c—Yd)n??(1) wherein M is one of titanium and zirconium. The present invention also relates to methods of preparing and using the inventive construction materials. The inventive construction material compositions are capable of utilizing oil-containing fillers in which the oil is stable in the final composition and the desired mechanical properties of the construction material are maintained or improved.
    Type: Grant
    Filed: August 17, 2011
    Date of Patent: November 26, 2013
    Assignee: S&E Innovative Technologies LLC
    Inventor: Salvatore J. Monte
  • Patent number: 8496749
    Abstract: The present invention relates to bitumen additive mixtures, their use and application for the fabrication of asphalt mixtures used in pavement and waterproofing, and more specifically for construction, repair and maintenance of sidewalks, roads, highways, parking lots or airport runaways and service roads and any other rolling surfaces.
    Type: Grant
    Filed: July 6, 2010
    Date of Patent: July 30, 2013
    Assignee: CECA S.A.
    Inventors: Juan Antonio Gonzalez Leon, Gilles Barreto, Vincent Luca, Eric Jorda
  • Patent number: 8382890
    Abstract: The invention relates to mixtures of bituminous products with granulates in the form of coated materials that can be used in the field of sealing, building and maintenance of road coatings, sidewalks and aviation strips, and to road coatings, sidewalks, cycling corridors, parking areas and aviation strips.
    Type: Grant
    Filed: April 28, 2008
    Date of Patent: February 26, 2013
    Assignee: CECA S.A.
    Inventors: Gilles Barreto, Lionel Grampre
  • Patent number: 8349065
    Abstract: The present invention is related to asphalt and asphalt-mineral compositions including at least one cationic organosilicon compound selected from a group consisting of: Y3-aSi(R1a)R2N+R3R4R5X?, Y3-aSi(R1a)R2P+R3R4R5X?, Y3-aSi(R1a)R2ZX?; or mixtures thereof, wherein in each formula Y is independently selected from a group consisting of OR, O(CH2CH2O)nH, (CH3OCH2CH2O), and (CH3CH2OCH2CH2O); a has a value selected from 0, 1 or 2; n is a value from 1 to 10; R is C1-C4 alkyl; R1 is either methyl or ethyl; R2 is C1-C4 alkylene group; R3, R4 and R5 are each independently selected from a group consisting of C1-C22 alkyl wherein at least one such group has more than 8 C-atoms, —CH2C6H5, —CH2CH2OH, —CH2OH and —(CH2)yNHC(O)R6 wherein y has a value of from 2 to 10 and R6 is a C1-C12 perfluoroalkyl radical; X is chloride, bromide, fluoride, iodide, acetate or tosylate; and Z is pyridinium ring of formula C5H5N+.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: January 8, 2013
    Assignee: Zydex Industries
    Inventors: Ajay Ranka, Prakash Mehta
  • Publication number: 20120006227
    Abstract: Polyphosphoric acid compositions having a reduced viscosity compared to neat polyphosphoric acid. The viscosity of the polyphosphoric acid is reduced by combining the polyphosphoric acid with an additive that reduces the viscosity of the polyphosphoric acid composition. In one embodiment, additives that can cause solvation and/or partial neutralization of the polyphosphoric acid without the addition of water may be used. The reduced viscosity polyphosphoric acid may be used, for example, as an additive in asphalts used in road pavements.
    Type: Application
    Filed: June 1, 2011
    Publication date: January 12, 2012
    Inventors: Jean-Valery Martin, Robert Finn
  • Patent number: 7968628
    Abstract: Bituminous asphalt binder materials which are modified by the addition of crumb rubber or ground tire rubber and a cross-linking agent are described. In addition, methods are provided for producing a modified asphalt binder containing crumb rubber or ground tire rubber and a cross-linking agent. The modified asphalt binders comprise neat asphalt, crumb rubber, one or more acids and a cross-linking agent. Optionally, the modified asphalt binder may include one or more polymer additives. The crumb rubber may be obtained from recycled truck and/or automobile tires. The addition of crumb rubber in asphalt binders can improve the consistency and properties of the asphalt binders at high and low temperatures. In particular, the modified asphalt binders of the present invention exhibit improved elastic behavior, resulting in improved performance of roads or other surfaces paved using the modified asphalt binder.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: June 28, 2011
    Assignee: Innophos, Inc.
    Inventor: Jean-Valery Martin
  • Patent number: 7901563
    Abstract: The present invention relates to a method for preparing an industrial asphalt comprising (1) heating an asphalt flux to a temperature which is within the range of about 400° F. (204° C.) to 550° F. (288° C.) to produce a hot asphalt flux, (2) sparging an oxygen containing gas through the hot asphalt flux for a period of time which is sufficient to increase the softening point of the asphalt flux to a value of at least 100° F. (38° C.), to produce an underblown asphalt composition; and (3) mixing a sufficient amount of a polyphosphoric acid throughout the underblown asphalt composition while the underblown asphalt composition is maintained at a temperature which is within the range of 200° F. (93° C.) to 550° F. (288° C.) to attain a softening point which is within the range of 185° F. (85° C.) to 250° F. (121° C.) and a penetration value of at least 15 dmm at 77° F. (25° C.) to produce the industrial asphalt.
    Type: Grant
    Filed: February 1, 2006
    Date of Patent: March 8, 2011
    Assignee: Building Materials Investment Corporation
    Inventors: Yonghong Ruan, William K. Longcor, IV, Peter Lars Johnson
  • Publication number: 20110017096
    Abstract: The present invention provides a functionally dry warm mix asphalt binder composition modified with lubricating agents or additives that can be mixed with aggregate and compacted at temperatures substantially below asphalt binder compositions that do not contain the disclosed lubricating additives.
    Type: Application
    Filed: October 1, 2010
    Publication date: January 27, 2011
    Applicant: A.L.M. HOLDING COMPANY
    Inventors: Gerald H. Reinke, Gaylon L. Baumgardner, Steven L. Engber
  • Publication number: 20110015313
    Abstract: Pavement compositions containing increased amounts of reclaimed asphalt pavement (RAP) are described. Addition of polyphosphoric acid (PPA) to pavement compositions containing RAP allows increased RAP content in road pavements while maintaining acceptable properties in the final pavement composition. Methods for producing road pavements containing RAP and PPA are also provided.
    Type: Application
    Filed: June 18, 2010
    Publication date: January 20, 2011
    Inventor: Jean-Valery MARTIN
  • Patent number: 7824485
    Abstract: Asphalt compositions and methods of forming such are described herein. The asphalt compositions and methods of forming such are generally adapted to enable open air processing while producing asphalt compositions that exhibit properties capable of meeting SUPERPAVE™ specifications.
    Type: Grant
    Filed: February 6, 2008
    Date of Patent: November 2, 2010
    Assignee: Fina Technology, Inc.
    Inventors: Paul J. Buras, William Lee, James R. Butler
  • Publication number: 20100186629
    Abstract: A combination of antioxidants and method of incorporating the antioxidants into an asphalt binder to make a modified asphalt binder are described. The antioxidants comprise a thioester and an aldehyde. The aldehyde and thioester, in a ratio between about 1:100 and about 100:1, are added to an asphalt binder. An acidic catalyst is also added in a concentration between about 0.1 wt % and about 18 wt % of the asphalt binder. The antioxidants, asphalt binder, and catalyst are mixed at a temperature between about 85° C. and about 135° C. for a time between about 30 minutes and about 6 hours. The antioxidants are capable of improving the performance grade of the asphalt binder. The modified asphalt binder possesses superior resistance to oxidative age hardening compared to other modified asphalt binder compositions that incorporate various antioxidants.
    Type: Application
    Filed: March 31, 2010
    Publication date: July 29, 2010
    Inventors: Alex K. Apeagyei, William G. Buttlar, Barry J. Dempsey
  • Patent number: 7713345
    Abstract: The present invention is directed to an “warm” asphalt paving composition that contains an modified asphalt binder and aggregate, wherein the asphalt binder is modified, at least in part, by the addition of a hydrated phosphate modifier to the asphalt.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: May 11, 2010
    Assignee: ICL Performance Products, LP
    Inventors: Rene Maldonado, Michael Falkiewicz
  • Publication number: 20090249978
    Abstract: A process is provided for producing an improved asphalt composition is air blown for a reduced period of time prior to addition of polyphosphoric acid. The air blowing process is performed at temperatures and using air volumes typically used for air blown asphalt. The process may be performed using neat asphalt, or it may be used on mixtures of asphalt with flux, slop, or mixtures of flux and slop. After the initial air blowing period, polyphosphoric acid is added to the asphalt. The polyphosphoric acid may be added while the asphalt is at temperature, or the asphalt may be allowed to cool slightly before the addition of the polyphosphoric acid. Following addition of the polyphosphoric acid, the asphalt may undergo further air blowing to obtain desired properties.
    Type: Application
    Filed: April 7, 2009
    Publication date: October 8, 2009
    Inventors: Jean-Valery Martin, Gaylon Lynn Baumgardner, Andrew Michael Menapace, John Medford Dumas
  • Publication number: 20090215931
    Abstract: Bituminous paving mixtures containing lubricating agents or additives may be prepared at hot mix temperatures and cooled, paved and compacted at temperatures 10-55 Celsius degrees lower than the hot mix temperatures. The increased temperature range between the hot mix temperatures and the paving and compacting temperatures is facilitated by the improved compacting properties of the paving mixture when it includes the lubricating agents or additives.
    Type: Application
    Filed: February 20, 2009
    Publication date: August 27, 2009
    Applicant: ALM Holding Co.
    Inventors: Gerald H. REINKE, Gaylon L. BAUMGARDNER, Steven L. ENGBER
  • Publication number: 20090068348
    Abstract: The present invention provides a functionally dry warm mix asphalt binder composition modified with lubricating agents or additives that can be mixed with aggregate and compacted at temperatures substantially below asphalt binder compositions that do not contain the disclosed lubricating additives.
    Type: Application
    Filed: October 12, 2007
    Publication date: March 12, 2009
    Inventors: Gerald H. Reinke, Gaylon L. Baumgardner, Steven L. Engber
  • Patent number: 7417082
    Abstract: Bituminous asphalt binder materials which are modified by the addition of crumb rubber or ground tire rubber and a cross-linking agent are described. In addition, methods are provided for producing a modified asphalt binder containing crumb rubber or ground tire rubber and a cross-linking agent. The modified asphalt binders comprise neat asphalt, crumb rubber, one or more acids and a cross-linking agent. Optionally, the modified asphalt binder may include one or more polymer additives. The crumb rubber may be obtained from recycled truck and/or automobile tires. The addition of crumb rubber in asphalt binders can improve the consistency and properties of the asphalt binders at high and low temperatures. In particular, the modified asphalt binders of the present invention exhibit improved elastic behavior, resulting in improved performance of roads or other surfaces paved using the modified asphalt binder.
    Type: Grant
    Filed: May 3, 2006
    Date of Patent: August 26, 2008
    Assignee: Innophos, Inc.
    Inventor: Jean-Valery Martin
  • Patent number: 7381251
    Abstract: The instant invention relates to a liquid composition comprising a mixture of: (1) water and/or a polar solvent; (2) a colloidal dispersion of mineral particles; and (3) a phosphonate terminated poly(oxyalkene) polymer; the invention also relates to process for stabilizing aqueous and/or solvent-based dispersions of mineral particles comprising the step of adding an efficient stabilising amount of a phosphonate terminated poly(oxyalkene) polymer.
    Type: Grant
    Filed: March 30, 2006
    Date of Patent: June 3, 2008
    Assignee: Rhodia Inc.
    Inventors: John Marshall Baker, Mikel Morvan, Amit Sehgal, Shiming Wo
  • Publication number: 20080119591
    Abstract: The present invention is directed to an air-blown roofing asphalt modified with polyphosphoric acid and roofing products made with the polyphosphoric acid-modified, air-blown asphalt.
    Type: Application
    Filed: November 22, 2006
    Publication date: May 22, 2008
    Applicant: ICL PERFORMANCE PRODUCTS LP
    Inventors: Michael Falkiewicz, Rene Maldonado
  • Patent number: 7309390
    Abstract: The present invention is directed to a stripping-resistant asphalt paving composition that contains asphalt, aggregate, polyphosphoric acid, and an alkaline anti-stripping additive.
    Type: Grant
    Filed: June 16, 2005
    Date of Patent: December 18, 2007
    Assignee: ICL Performance Products LP
    Inventor: Michael Falkiewicz
  • Patent number: 7094283
    Abstract: The subject of the present invention is a process for preparing a bituminous product, characterized in that a compound based on a phosphoric or polyphosphoric acid supported on a mineral oxide of high porosity is used. The subject of the invention is also the bituminous product that can be obtained by the above process, and its uses.
    Type: Grant
    Filed: October 25, 2004
    Date of Patent: August 22, 2006
    Assignee: Innophos, Inc.
    Inventors: Dominique Dupuis, Gilles Orange
  • Patent number: 7026384
    Abstract: The invention relates to a process for the preparation of an aqueous dispersion of halogenated vinyl polymers by polymerization, according to which, after polymerization, a basic agent is added in an amount such that the pH of the aqueous dispersion is less than approximately 5. The invention also relates to the aqueous dispersion obtained, which can be coated onto polymeric substrates made of paper or of regenerated cellulose.
    Type: Grant
    Filed: February 24, 2004
    Date of Patent: April 11, 2006
    Assignee: SOLVAY (Société Anonyme)
    Inventors: Yves Vanderveken, Bernard Guenaire, Xavier Bacque
  • Patent number: 6808558
    Abstract: The subject of the present invention is a process for preparing a bituminous product, characterized in that a compound based on a phosphoric or polyphosphoric acid supported on a mineral oxide of high porosity is used. The subject of the invention is also the bituminous product that can be obtained by the above process, and its uses.
    Type: Grant
    Filed: June 13, 2003
    Date of Patent: October 26, 2004
    Inventors: Dominique Dupuis, Gilles Orange
  • Publication number: 20040000256
    Abstract: The subject of the present invention is a process for preparing a bituminous product, characterized in that a compound based on a phosphoric or polyphosphoric acid supported on a mineral oxide of high porosity is used. The subject of the invention is also the bituminous product that can be obtained by the above process, and its uses.
    Type: Application
    Filed: June 13, 2003
    Publication date: January 1, 2004
    Inventors: Dominique Dupuis, Gilles Orange
  • Patent number: 6524704
    Abstract: A powder of dicalcium silicate is made by spray drying calcia and silica with incorporation of sodium and phosphorus or stabilized zirconia. The spray dried powder is sintered to form a thermal spray powder. Sprayed coatings have a web of interconnected, randomly oriented microcracks substantially perpendicular to the coating surface. The coatings are stable in thermal cycling and a hot corrosive environment.
    Type: Grant
    Filed: October 4, 2000
    Date of Patent: February 25, 2003
    Assignee: Sulzer Metco (US) Inc.
    Inventors: Xiaohan Wei, Mitchell R. Dorfman, Luis F. Correa, Franz Jansen, John Peters
  • Patent number: 6261356
    Abstract: The present invention provides an additive for asphalt which causes an improvement in anti-stripping effect of asphalt from aggregates, and exhibits the effect quickly. That is, the present invention provides an asphalt-additive composition comprising (A) a specific acidic phosphoric acid compound, and (B) at least one member selected from the group consisting of mineral oil, alcohol having 8 to 18 carbon atoms, carboxylic acid having 8 to 18 carbon atoms and triglyceride thereof; with the proviso that the amount of the (B) component is 25-400 parts by weight per 100 parts by weight of the (A) component.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: July 17, 2001
    Assignee: Kao Corporation
    Inventors: Kazuo Isobe, Ryoichi Tamaki, Keiichiro Tomioka