Pencil Leads Patents (Class 106/31.11)
  • Patent number: 11072722
    Abstract: A pencil lead and a pencil containing the pencil lead wherein the pencil lead is polymer-based, extrudable, non-expanded, non-calcined and comprises graphite, of which 25% to 100% by weight or 50% to 100% by weight of the graphite, in relation to the total weight of the graphite, is expanded graphite.
    Type: Grant
    Filed: April 9, 2018
    Date of Patent: July 27, 2021
    Assignee: SOCIETE BIC
    Inventors: Julien Gouerec, Frédéric Claptien, Philippe Lefebvre, Christelle Debrauwer
  • Patent number: 9896591
    Abstract: A pencil lead includes an organic-inorganic hybrid resin inside fine pores of a porous lead body. A colorant may also be included inside the fine pores. The organic-inorganic hybrid resin is preferably a silica-organic hybrid resin.
    Type: Grant
    Filed: December 1, 2016
    Date of Patent: February 20, 2018
    Assignee: MITSUBISHI PENCIL COMPANY, LIMITED
    Inventors: Hiroyuki Arai, Satoru Banzai
  • Patent number: 9856387
    Abstract: Provided is a color pencil lead which is excellent in a hue, a light resistance and a strength and can be erased with an eraser and which is suited to pencil leads for mechanical pencils and wooden pattern holder pencils. The above color pencil lead is characterized by containing a resin in which a dye is dissolved or included in a pencil lead body.
    Type: Grant
    Filed: February 20, 2015
    Date of Patent: January 2, 2018
    Assignee: MITSUBISHI PENCIL COMPANY, LIMITED
    Inventor: Satoru Banzai
  • Patent number: 8349063
    Abstract: A pencil lead containing flake graphite which has an ab face having a flatness of at least 2 ?m or less and in which an aspect ratio of an a axis or a b axis in the ab face to a c axis is 5 or more is provided with a structure in which nanoparticles having a mv value of 0.05 to 2 based on 100 of a volume average diameter (mv value) of the graphite and having a sphericity of 0.1 to 20 nm or nanoparticles having a mv value of 0.05 to 2 based on 100 of a volume average diameter (mv value) of the graphite and having a specific surface area of 200 to 600 m2/g are brought into contact with the ab face of the graphite or a structure in which they are adhered to the ab face of the graphite.
    Type: Grant
    Filed: April 22, 2010
    Date of Patent: January 8, 2013
    Assignee: Mitsubishi Pencil Company, Limited
    Inventors: Satoru Banzai, Katsunori Kitazawa
  • Publication number: 20120037035
    Abstract: A pencil lead containing flake graphite which has an ab face having a flatness of at least 2 ?m or less and in which an aspect ratio of an a axis or a b axis in the ab face to a c axis is 5 or more is provided with a structure in which nanoparticles having a my value of 0.05 to 2 based on 100 of a volume average diameter (my value) of the graphite and having a sphericity of 0.1 to 20 nm or nanoparticles having a my value of 0.05 to 2 based on 100 of a volume average diameter (my value) of the graphite and having a specific surface area of 200 to 600 m2/g are brought into contact with the ab face of the graphite or a structure in which they are adhered to the ab face of the graphite.
    Type: Application
    Filed: April 22, 2010
    Publication date: February 16, 2012
    Applicant: MITSUBISHI PENCIL COMPANY, LIMITED
    Inventors: Satoru Banzai, Katsunori Kitazawa
  • Publication number: 20110244385
    Abstract: The invention relates to aqueous pigment preparations containing (A) at least one organic and/or inorganic pigment, (B) a dispersant of formula (I) or (II), or mixtures of the dispersants of formula (I) and (II), (C) optionally wetting agents, (D) optionally other surfactants and/or dispersants, (E) optionally one or more organic solvents or one or more hydrotropic substances, (F) optionally other additives used conventionally for the production of aqueous pigment dispersions and (G) water.
    Type: Application
    Filed: April 29, 2008
    Publication date: October 6, 2011
    Inventors: Bjoern Fechner, Carsten Schaefer, Alexander Woerndle
  • Patent number: 7833343
    Abstract: The invention relates to a pigment preparation containing (a) 50-99 percent by weight of at least one pigment, (b) 1 to 50 percent by weight of an additive based on polyalkylene glycols, and (c) 0 to 10 percent by weight of an auxiliary agent from among the group comprising fillers, fire retardants, preservatives, light-stability agents, pigmentary and non-pigmentary dispersing agents, surfactants, antioxidants, foam inhibitors, resins, and antistatic agents, the percentages being in relation to the total weight of the pigment preparation. The additive that is based on polyalkylene glycols corresponds to formula Z?-[-(AO—)n1—B-T-X—Y]m—Z (1), wherein AO represents a C2-C10 alkyleneoxy unit, B represents a C2-C10 alkylene radical, and T represents —NR—, X represents one of the groups (formula), and Y represents a chemical bond or —NR3—.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: November 16, 2010
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Carsten Plueg, Jesús Pitarch López
  • Patent number: 7803220
    Abstract: An unburnt color lead for writing devices, drawing devices and painting devices, includes at least one coloring material, at least one binder, at least one organic lubricant which is solid at room temperature, and at least one filler material whose particles essentially have a disk-shaped configuration. The color lead contains 20 to 80 weight % of the at least one filler material, and the color lead contains at least 20 weight % hexagonal bornitride as a first filler material.
    Type: Grant
    Filed: February 14, 2007
    Date of Patent: September 28, 2010
    Assignee: J.S. Staedtler GmbH & Co. KG
    Inventor: Andreas Thies
  • Patent number: 7682437
    Abstract: There is provided a transparent solid marker that has high bending strength and low writing resistance as stick-formed goods, is difficult to break or bend, generates few remnants while coating is carried out, and does not cause spreading of a writing surface even if it is coated on a surface which is written on by oily or aqueous writing implements. There is provided a transparent solid marker that is obtained by heating and mixing a composition including a gel forming material that includes an alkali metal salt or ammonium salt of an aliphatic carboxylic acid having 8 to 36 carbon atoms, a transparency agent, a subsidiary transparency agent, hydrogenated glucose syrup, a basic pigment, and oil, and cooling it.
    Type: Grant
    Filed: May 21, 2009
    Date of Patent: March 23, 2010
    Assignee: Dong-A Teaching Materials Co., Ltd.
    Inventors: Hak-Jae Kim, Han-Shin Jung
  • Patent number: 7547355
    Abstract: A solid drawing material containing a gel-forming substance of an alkali metal salt or an ammonium salt of an aliphatic carboxylic acid having 8 to 36 carbon atoms, an alkoxylated nitrogen-containing compound, a reduced starch saccharide, and a coloring agent. The solid drawing material which is in the form of a stick features a large strength, a small drawing resistance, is less subject to be collapsed or broken, produces little shavings while drawing, makes it possible to favorably form a drawing even on smooth surfaces such as windowpanes, and of which the traces after drawn can be easily wiped out with a wet cloth.
    Type: Grant
    Filed: September 11, 2006
    Date of Patent: June 16, 2009
    Assignee: Buncho Corporation
    Inventors: Koji Seki, Jung Han Sin
  • Publication number: 20080078301
    Abstract: A process for the production of leads which contain pigments and/or effect substances, wherein pigments and/or effect substances are mixed with fillers and further lead ingredients, the resulting material is homogenised and then extruded to provide extrusions of predetermined diameter, wherein then the extruded portions are dried optionally after adjustment of the extrusion length to a constant weight, wherein at least a proportion of the pigment and/or effect material is brought into contact with a polysaccharide solution and an aqueous solution of a precipitation agent prior to admixing of the further ingredients, the mixture is dried and then optionally ground.
    Type: Application
    Filed: October 20, 2005
    Publication date: April 3, 2008
    Applicant: SCHWAN-STABILO COSMETICS GMBH & CO. KG
    Inventors: Reinhard Pinzer, Christian Sprogar, Jurgen Peukert
  • Patent number: 6875261
    Abstract: For the improvement of moldability of a lead and bending strength of a lead, a non-calcined lead of a colored pencil contains a colorant, a binder, a body filler, waxes and/or oils, and a hydrophilic surfactant, and as a hydrophilic surfactant, a polyethylene additive of oils is contained. For the improvement of water resistance, a non-calcined lead of a colored pencil contains a colorant, a binder, a body filler, waxes and/or oils, and a hydrophilic surfactant, and further, a water repellent substance. Further, as a non-calcined lead of a colored pencil with easy quality control process, it contains plate type alumina and/or plate type alumina hydrate.
    Type: Grant
    Filed: June 15, 2001
    Date of Patent: April 5, 2005
    Assignee: Sakura Color Products Corporation
    Inventors: Yuka Hashimoto, Hiroki Nishino
  • Patent number: 6830610
    Abstract: A method for increasing the tensile, breaking and flexural strength of coloured leads. The method is characterized in that 1 to 50 percent by weight alkyl and/or hydroxyalkyl cellulose which are soluble in organic solvents and whose alkyl radicals can be straight-chained or branched are added to the lead substance. The invention also relates to coloured pencils containing said coloured leads.
    Type: Grant
    Filed: April 15, 2003
    Date of Patent: December 14, 2004
    Assignee: Schwan-Stabilo Cosmetics GmbH & Co. KG
    Inventors: Werner Bruchert, Christian Sprogar, Willy Weiss
  • Publication number: 20040123770
    Abstract: The ink set for ink jet recording of the present invention, which exhibits a high recorded image quality, an excellent image preservability (heat stability, light fastness, oxidation resistance) and little change of color balance with time, and an ink jet recording method using same, and which comprises a plurality of inks containing a dye, a water-miscible organic solvent and water, wherein the ink set comprises at least yellow, magenta, cyan, black and dark yellow inks, and the dark yellow ink contains at least one of a magenta-azo dye having a specific structure having a 6-membered heterocyclic group connected to diazo group and a cyan dye having a specific structure.
    Type: Application
    Filed: July 23, 2003
    Publication date: July 1, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Naotaka Wachi
  • Patent number: 6746524
    Abstract: Disclosed is a process for producing a sintered color pencil lead characterized by pigmenting a white or light-colored porous sintered pencil lead with an organic pigment by treating said porous sintered pencil lead with a solution of at least one compound of the following Formula (I) to be filled with said compound and then by forming said organic pigment within the pores by means of heating, A(B)x in which x is an integer from 1 to 8, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, indanthrone, isoindolinone, isoindoline, dioxazine, azo series, phthalocyanine or diketopyrrolopyrrole which is attached to x groups B via one or more heteroatoms selected from the group consisting of N, O and S and forming part of the radical A, B is hydrogen or a group of the formula where at least one group B is not hydrogen and, if x is 2 to 8, all the groups B can be identical or different, and L is any suitable solubilizing group.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: June 8, 2004
    Assignee: Mitsubishi Pencil Kabushiki Kaisha
    Inventor: Katsunori Kitazawa
  • Patent number: 6709501
    Abstract: Provided is a baked color pencil lead which comprises a baked lead obtained by impregnating pores of a porous baked lead comprising at least a filler with a solution containing a polysiloxane having a structural unit represented by the following Formula (I) and subjecting it to heat treatment in an oxidation atmosphere and/or a non-oxidation atmosphere and a colorant filled into the pores of the resultant baked lead and which is excellent in mechanical strength (bending strength, tensile strength, impact strength and the like) while exhibiting a satisfactory coloring power and sufficient drawn line density: wherein R1 and R2 each represent an alkyl group, an alkoxy group, a hydroxy group or a siloxane group, and they may be the same or different.
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: March 23, 2004
    Assignee: Mitsubishi Pencil Kabushiki Kaisha
    Inventor: Atsushi Satoh
  • Publication number: 20040016366
    Abstract: For the improvement of moldability of a lead and bending strength of a lead, a non-calcined lead of a colored pencil contains a colorant, a binder, a body filler, waxes and/or oils, and a hydrophilic surfactant, and as a hydrophilic surfactant, a polyethylene additive of oils is contained. For the improvement of water resistance, a non-calcined lead of a colored pencil contains a colorant, a binder, a body filler, waxes and/or oils, and a hydrophilic surfactant, and further, a water repellent substance. Further, as a non-calcined lead of a colored pencil with easy quality control process, it contains plate type alumina and/or plate type alumina hydrate.
    Type: Application
    Filed: August 4, 2003
    Publication date: January 29, 2004
    Inventors: Yuka Hashimoto, Hiroki Nishino
  • Patent number: 6645279
    Abstract: A process for producing a baked color pencil lead, comprising dipping a white or pale color porous baked lead having a volume-based median pore diameter of 0.27 &mgr;m or less in a dye ink and then applying a pressure of 1.5 MPa or more thereto to impregnate pores of the above baked lead with the dye ink, in particular, a process for producing a baked color pencil lead, comprising impregnating the pores thereof with a dye ink solution containing as the solvents 35 to 90% by weight of at least one of non-volatile solvents represented by the following Formulas (I) to (III) based on the ink solution and a low boiling organic solvent by applying pressure and then drying the above low boiling organic solvent, and a color pencil lead obtained by the above process: CH3(CH2)7CH═CH(CH2)7CH2OH  (I) R1O(CH2CH2O)nH  (II) in Formula (II), R1 represents decanoyl, undecanoyl, lauroyl, tridecanoyl or oleoyl, and n is 4.
    Type: Grant
    Filed: June 20, 2001
    Date of Patent: November 11, 2003
    Assignee: Mitsubishi Pencil Kabushiki Kaisha
    Inventors: Katsunori Kitazawa, Masaaki Hoshiba, Noboru Kanba
  • Patent number: 6511533
    Abstract: A non-calcined lead of a colored pencil obtainable by following process: a binder or its solution are added to a mixture comprising a colorant, a body filler, and a solvent as required, and the resultant mixed compound is kneaded, after that, the said solvent is removed, and the resultant mixture is mixed together with O/W emulsion comprising an oily substance being a liquid at ordinary temperature, one or more surfactant(s) having a H.L.B value of not less than 7 nor more than 18 and water, the mixed ingredients are formed, and the water contained in the said O/W emulsion and the said solvent if any remains is removed. A synthetic mica is, contained as a lubricant, and the said body filler is at least one compound selected from the group consisting of wollastonite, attapulgite, haloysite kaolin and sepiolite.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: January 28, 2003
    Assignee: Sakura Color Products Corporation
    Inventor: Yuka Hashimoto
  • Publication number: 20030000420
    Abstract: Provided is a baked color pencil lead which comprises a baked lead obtained by impregnating pores of a porous baked lead comprising at least a filler with a solution containing a polysiloxane having a structural unit represented by the following Formula (I) and subjecting it to heat treatment in an oxidation atmosphere and/or a non-oxidation atmosphere and a colorant filled into the pores of the resultant baked lead and which is excellent in mechanical strength (bending strength, tensile strength, impact strength and the like) while exhibiting a satisfactory coloring power and sufficient drawn line density: 1
    Type: Application
    Filed: May 24, 2002
    Publication date: January 2, 2003
    Inventor: Atsushi Satoh
  • Publication number: 20020139278
    Abstract: A non-calcined lead of a colored pencil obtainable by following process:
    Type: Application
    Filed: February 20, 2002
    Publication date: October 3, 2002
    Applicant: Sakura Color Products Corporation
    Inventor: Yuka Hashimoto
  • Patent number: 6395076
    Abstract: A non-calcined lead of a colored pencil obtainable by following process: a binder or its solution are added to a mixture comprising a colorant, a body filler, and a solvent as required, and the resultant mixed compound is kneaded, after that, the said solvent is removed, and the resultant mixture is mixed together with O/W emulsion comprising an oily substance being a liquid at ordinary temperature, one or more surfactant(s) having a H.L.B value of not less than 7 nor more than 18 and water, the mixed ingredients are formed, and the water contained in the said O/W emulsion and the said solvent if any remains is removed. A synthetic mica is contained as a lubricant, and the said body filler is at least one compound selected from the group consisting of wollastonite, attapulgite, haloysite kaolin and sepiolite.
    Type: Grant
    Filed: January 25, 2000
    Date of Patent: May 28, 2002
    Assignee: Sakura Color Products Corporation
    Inventor: Yuka Hashimoto
  • Patent number: 6277182
    Abstract: A pigment-containing oil-based gel material which contains 0.1 to 25% by weight of a hydroxy-fatty acid having 10 to 20 C atoms, 0.1 to 30% by weight of C30-45-alkylmethicone, 1 to 70% by weight of an oil component and 0.1 to 50% by weight of pigments is described.
    Type: Grant
    Filed: March 8, 2000
    Date of Patent: August 21, 2001
    Assignee: Schwan-STABILO Cosmetics GmbH & Co.
    Inventors: Simona Lebok, Claudia Zarling, Wolfgang Winkler
  • Patent number: 6210471
    Abstract: A marking composition suitable for marking colored substrates, especially dark substrates, is disclosed. The marking composition comprises a wax, a fatty acid, a reflecting filler, and a colorant selected from an oil soluble dye, an oil dispersable dye, or an oil dispersable pigment. A defoamer and a non-reflecting filler can be optionally included in the marking composition. For example, the marking composition can be provided in the form of crayons, colored pencils, and the like. A method of providing a mark on a colored substrate is also disclosed.
    Type: Grant
    Filed: September 1, 2000
    Date of Patent: April 3, 2001
    Assignee: Binney & Smith Inc.
    Inventor: Michael S. Craig