Six-ring Members In The Heterocyclic Ring Patents (Class 106/31.47)
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Publication number: 20070289487Abstract: An ink composition comprising a colorant, a solvent, a surfactant, and a defoaming agent is provided. The defoaming agent has a structure of Formula R1—X—(CH2CH2O)m-(CH CH3CH2O)n-R2 (I), in which, X is selected from the group consisting of COO, O, S, R3—N and R4(R5)—C; R1, R2, R3, R4, and R5 are each independently selected from the group consisting of a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group and a substituted or unsubstituted aralkyl group; m is an integer from 0 to 100; and n is a natural number from 1 to 100. The ink composition according to the exemplary embodiment exhibits low foaming properties in order to flow smoothly and has a good initial discharge capacity and less ink bleeding so that it is possible to achieve a high print quality during printing, and an ink cartridge including the same.Type: ApplicationFiled: February 2, 2007Publication date: December 20, 2007Inventors: Cheol Ham, Seung-min Ryu
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Publication number: 20070281139Abstract: A document uses a chemically reactive security ink to facilitate security, making it more difficult to alter a genuine security document. The chemically reactive security ink masks a warning word or message on a security document. The hidden warning word or message is revealed when the document is subjected to chemical washing.Type: ApplicationFiled: May 29, 2007Publication date: December 6, 2007Applicant: THE STANDARD REGISTER COMPANYInventors: Rajendra Mehta, Steven L. Yeager, Stephen D. Webendorfer
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Patent number: 7303615Abstract: There is provided a colorant material comprising a compound represented by at least one of the following general formulas (1) and (2) as a first colorant compound and at least one of a water insoluble triphenylmethane compound and a water insoluble xanthene compound as a second colorant compoundType: GrantFiled: February 24, 2005Date of Patent: December 4, 2007Assignee: Canon Kabushiki KaishaInventors: Yuko Yamagishi, Yasuaki Murai, Takeshi Miyazaki
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Patent number: 7297197Abstract: An ink jet ink is provided with which metallic luster appearing in printing on a recording medium, i.e. the bronze phenomenon is kept from occurring and good images can be obtained. The ink jet ink includes at least a coloring material which is a compound represented by a specific general formula, and further contains a specific amine compound.Type: GrantFiled: January 8, 2007Date of Patent: November 20, 2007Assignee: Canon Kabushiki KaishaInventors: Masanori Jinnou, Shin-ichi Sato, Jun Yoshizawa, Kunihiko Nakamura, Daiji Okamura, Tomohiro Yamashita
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Patent number: 7297196Abstract: The present invention provides magenta dyestuff represented by the formula (1): (wherein symbols are as defined in the present description), with hue and vividness suitable to ink-jet recording, records excellent in fastness to light, gas, water and so on and a superior ink composition using said dyestuff.Type: GrantFiled: May 20, 2004Date of Patent: November 20, 2007Assignee: Nippon Kayaku Kabushiki KaishaInventors: Hiroyuki Matsumoto, Katsunori Fujii, Yasuo Shirasaki, Takafumi Fujii, Yasuo Murakami
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Patent number: 7294183Abstract: An inkjet ink having an increased shelf life. The inkjet ink comprises an ink vehicle and a reactive colorant. The reactive colorant is nonreactive with water,thereby increasing the shelf life of the inkjet ink to greater than approximately twelve months. An inkjet printing system comprising the inkjet ink and an activating agent is also disclosed. A reactive colorant of the inkjet ink is nonreactive with water but is sufficiently reactive with the activating agent to form an activated complex to fix the reactive colorant to a textile substrate. A method of printing on a textile substrate is also disclosed.Type: GrantFiled: October 25, 2002Date of Patent: November 13, 2007Assignee: Hewlett-Packard Development Company, L.P.Inventor: David Tyvoll
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Patent number: 7294184Abstract: Provided is an ink jet ink containing a coloring material having a buffer region in an ink use range, the ink jet ink being capable of suppressing the occurrence of the deterioration (dissolution) of a heating portion surface in contact with liquid; and the disconnection of wiring for applying a voltage to a heating portion even when long term continuous printing is performed. The ink jet ink is used for an ink jet recording apparatus equipped with a recording head having a heating portion surface in contact with liquid comprising a metal and/or a metal oxide. The ink jet ink contains a coloring material in a content (mass %) of 3 mass % or more with respect to the total mass of the ink jet ink. The coloring material is a colorant having a buffer region in an ink use range, and comprises a compound represented by the following general formula (I) and/or a compound represented by the following general formula (II) H(OCH2CH2)pR5.Type: GrantFiled: December 30, 2005Date of Patent: November 13, 2007Assignee: Canon Kabushiki KaishaInventors: Kuniaki Fujimoto, Shin-ichi Sato, Jun Yoshizawa, Yoshihide Aikawa, Kunihiko Nakamura, Masanori Jinnou
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Patent number: 7291213Abstract: An ink composition comprising: a coloring agent having an oxidation potential of more electropositive than 1.0V (vs SCE); a water; a guanidine compound; and a surfactant, the ink composition to be used in inkjet recording and an inkjet recording method with the use of the ink composition.Type: GrantFiled: August 23, 2005Date of Patent: November 6, 2007Assignee: Fujifilm CorporationInventors: Manabu Ogawa, Keiichi Tateishi
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Patent number: 7285159Abstract: Provided is an ink jet ink comprising at least a coloring material comprising a compound represented by the general formula (I) or a salt thereof; and a compound represented by the general formula (II).Type: GrantFiled: December 30, 2005Date of Patent: October 23, 2007Assignee: Canon Kabushiki KaishaInventors: Yoshihide Aikawa, Kuniaki Fujimoto, Shin-ichi Sato, Jun Yoshizawa, Kunihiko Nakamura, Masanori Jinnou
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Patent number: 7282090Abstract: An ink jet ink includes at least a coloring material. The coloring material is composed of at least one selected from the group consisting of C.I.Type: GrantFiled: February 27, 2006Date of Patent: October 16, 2007Assignee: Canon Kabushiki KaishaInventors: Koichi Osumi, Sadayuki Sugama
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Patent number: 7279034Abstract: It is an object of the present invention to provide an ink composition with which the indoor storage stability (gas resistance) of an image produced with an ink composition featuring a phthalocyanine-based cyan dye can be increased without causing any additive precipitation or bronzing. The present invention provides an ink composition containing at least water, a phthalocyanine-based cyan dye, and a lithium salt of an aromatic compound having a sulfo group and expressed by General Formulas 1 and/or 2 in the claims. The present invention also provides an ink composition containing at least water, a phthalocyanine-based cyan dye, and a lithium salt of an aromatic compound having a sulfo group and expressed by General Formulas 5 and/or 6 in the claims.Type: GrantFiled: December 19, 2005Date of Patent: October 9, 2007Assignee: Seiko Epson CorporationInventors: Yasuhiro Oki, Kazuhiko Kitamura
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Patent number: 7279033Abstract: An ink-jet ink containing a colorless, water-soluble, planar compound having more than ten delocalized pi-electrons per molecule.Type: GrantFiled: September 9, 2004Date of Patent: October 9, 2007Assignee: Fujifilm CorporationInventors: Yoshiharu Yabuki, Toshiki Taguchi, Makoto Suzuki
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Patent number: 7276111Abstract: An object of the present invention is to provide an ink composition that can improve the preservation characteristics (gas fastness) of an image produced by an ink composition which uses phthalocyanine group cyan dye. The present invention provides an ink composition wherein at least water, the phthalocyanine group cyan dye indicated by the general formula (I), and an aromatic compound having a sulfone group and/or the salt thereof represented by the general formulae (a) and/or (b) are contained; and an ink composition wherein at least water, the phthalocyanine group cyan dye indicated by the general formula (VIII), and an aromatic compound having a sulfone group and/or the salt thereof represented by the general formulae (a) and/or (b) are contained.Type: GrantFiled: January 25, 2005Date of Patent: October 2, 2007Assignee: Seiko Epson CorporationInventors: Yasuhiro Oki, Kazuhiko Kitamura
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Patent number: 7273519Abstract: An ink set where constituent inks all are an ink containing at least one dye having an oxidation potential more positive than 1.0 V (vs SCE), particularly where the ratio k1/k2 of the fading rate constant (k1) of an image drawn by using the ink alone to the fading rate constant (k2) of a mixed color image drawn by using all constituent inks constituting the ink set in equivalent amounts with the same density measurement light as in the measurement of k1 is 0.7 to 1.3 in all inks. According the present invention, an inkjet ink set capable of giving an image having good image quality and excellent image fastness regardless of the color of image, such as aging stability, light fastness and water resistance, and an inkjet image recording method using the ink set are provided.Type: GrantFiled: March 25, 2004Date of Patent: September 25, 2007Assignee: Fujifilm CorporationInventors: Toshiki Taguchi, Manabu Ogawa
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Patent number: 7270701Abstract: An ink jet ink is provided with which metallic luster appearing in printing on a recording medium, i.e. the bronze phenomenon is kept from occurring and good images can be obtained. The ink jet ink includes at least a coloring material which is a compound represented by a specific general formula, and further contains a specific amine compound.Type: GrantFiled: January 26, 2006Date of Patent: September 18, 2007Assignee: Canon Kabushiki KaishaInventors: Masanori Jinnou, Shin-ichi Sato, Jun Yoshizawa, Kunihiko Nakamura, Daiji Okamura, Tomohiro Yamashita
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Patent number: 7270699Abstract: The invention provides an ink set for ink-jet recording that is able to form an image having a sufficient optical density and causing no feathering and intercolor bleed within a short period of time while being excellent in reliability of the maintenance unit. The ink set comprises at least a liquid (a) containing a colorant, water soluble solvent and water; a liquid (b) containing a pH adjusting agent, water soluble solvent and water; and a liquid (c). The ink set satisfies any one of the conditions in the first embodiment: (i) the colorant is anionic, (ii) the liquid (b) has a pH of not higher than 6.5, (iii) the liquid (c) has a pH of not lower than 8.0, and (iv) the mixed liquid of the liquid (b) and the liquid (c) in a mass ratio of 1:1 has a pH of not lower than 7; or the second embodiment: (i) the colorant is cationic, (ii) the liquid (b) has a pH of not lower than 8.5, (iii) the liquid (c) has a pH of not higher than 6.Type: GrantFiled: September 1, 2004Date of Patent: September 18, 2007Assignee: Fuji Xerox Co., Ltd.Inventor: Takatsugu Doi
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Patent number: 7270703Abstract: To provide a novel phthalocyanine compound, and an inkjet ink and inkjet recording method capable of an image having an excellent hue, fastness to light and ozone gas resistance. To provide various coloring compositions such as an ink sheet for heat-sensitive recording material, color toner for electrophotography, and color filter, and to provide improving method of oxidation resistance of an image. [Means for Resolution] A phthalocyanine compound substituted with —SO2NH—Z (Z represents a heterocyclic group) in at least one combination of 2 and 3, 6 and 7, 10 and 11, and 14 and 15-positions, wherein at least one of the 1 to 16-positions has two or more carbon atoms and the total number of the carbon atom thereof is 8 or more, inkjet ink using the compound, ink sheet, color toner and a color filter composition, which use the compound.Type: GrantFiled: June 21, 2002Date of Patent: September 18, 2007Assignee: Fujifilm CorporationInventors: Keiichi Tateishi, Masaki Noro, Yoshiharu Yabuki, Tadashi Omatsu
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Patent number: 7256222Abstract: To provide a radiation-curable ink composition that can form a high-quality image on not only liquid absorbing materials to be recorded but also non-liquid absorbing materials to be recorded, is superior in curing properties in air, and is superior in storage stability, color tone, light fastness and water resistance of ink, and also to provide an image recording method. The radiation-curable ink composition comprises a monomer having a polymerizable group selected from the group consisting of an acryloyl group, a methacryloyl group, an allyl group, and a vinyl group, an oil-soluble dye, and from 0.005 to 1% by weight of a storage stabilizer, wherein the oil-soluble dye is dissolved in the ink.Type: GrantFiled: January 29, 2003Date of Patent: August 14, 2007Assignee: Fujifilm CorporationInventors: Takahiro Ishizuka, Kazue Sano, Junichi Yamanouchi, Keiichi Tateishi
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Patent number: 7247194Abstract: An ink jet ink is disclosed which includes water, a water-soluble organic solvent and a coloring material and has excellent properties. The coloring material is a specific phthalocyanine derivative and is contained in a specific amount in the ink. The water-soluble organic solvent includes a specific amount of 2-pyrrolidone. In addition, a d75 value is in a specific range where the d75 value corresponds to 75% of a dispersion distance distribution, measured by a small angle X-ray scattering method, of molecular aggregates in the ink jet ink whose coloring material concentration is adjusted to 0.5 mass %.Type: GrantFiled: December 30, 2005Date of Patent: July 24, 2007Assignee: Canon Kabushiki KaishaInventors: Daiji Okamura, Shin-ichi Sato, Jun Yoshizawa, Kunihiko Nakamura, Tomohiro Yamashita, Masanori Jinnou
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Patent number: 7244299Abstract: An ink jet recording ink comprising at least a copper phthalocyanine dye represented by the following general formula (1) and a compound represented by the following general formula (2):Type: GrantFiled: September 26, 2005Date of Patent: July 17, 2007Assignee: Canon Kabushiki KaishaInventors: Itaru Tsuji, Shinichi Tochihara, Hiroshi Tomioka, Koichi Osumi, Hiroyuki Takuhara, Minako Kawabe, Hideki Yamakami
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Patent number: 7241332Abstract: To provide an ink jet yellow ink to be used in combination with ink excellent in light resistance and environmental gas resistance with a color fading balance with respect to light and an environmental gas between the inks uniformized. The ink jet yellow ink is an ink jet yellow ink to be used for forming an image together with a cyan ink comprising a compound represented by a general formula (1) or a compound represented by a general formula (2) as a coloring material, the ink jet yellow ink comprising: at least one kind of coloring material selected from the following A group; and at least one kind of coloring material selected from the following B group. A group: C.I. Direct Yellow 132 and C.I. Direct Yellow 173 B group: C.I. Direct Yellow 142, C.I. Direct Yellow 86, and a compound represented by a general formula (3).Type: GrantFiled: January 26, 2006Date of Patent: July 10, 2007Assignee: Canon Kabushiki KaishaInventors: Jun Yoshizawa, Shin-ichi Sato, Kunihiko Nakamura
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Patent number: 7229488Abstract: An ink composition includes a colorant, a solvent, and an amine alcohol compound represented by formula I in which n is an integer and 0?n?9.Type: GrantFiled: August 1, 2006Date of Patent: June 12, 2007Assignee: Samsung Electronics Co., Ltd.Inventor: Jong-in Lee
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Patent number: 7223301Abstract: The present invention provides magenta dyestuff represented by the formula (1): (symbols are as defined in the present description), with hue and vividness suitable to ink-jet recording, excellent fastness to light, gas, water and so on in records and an ink composition using said dyestuff.Type: GrantFiled: May 20, 2004Date of Patent: May 29, 2007Assignee: Nippon Kayaku Kabushiki KaishaInventors: Hiroyuki Matsumoto, Katsunori Fujii, Yasuo Shirasaki, Takafumi Fujii, Yasuo Murakami, Noriko Kajiura
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Patent number: 7214260Abstract: The present invention provides an ink set for ink jet recording using at least two kinds of liquids. The first liquid contains at least a colorant, a water soluble solvent and water, and the second liquid contains at least a compound represented by the following general formula (1), a water soluble solvent and water.Type: GrantFiled: June 4, 2004Date of Patent: May 8, 2007Assignee: Fuji Xerox Co., Ltd.Inventors: Takatsugu Doi, Chizuru Koga, Takashi Ogino, Kiyoshi Hosoi, Tsukasa Matsuda
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Patent number: 7214259Abstract: An ink comprising a liquid medium and a colorant, wherein the liquid medium comprises water and a water-miscible organic solvent and the colorant is of Formula (1), wherein the colorant is dissolved in the liquid medium: Formula (1) wherein: each independently is a water-solubilising group selected from sulfo, carboxy, phosphato and poly(ethylene oxide); each Z independently is optionally substituted alkyl, optionally substituted aryl or optionally substituted aralkyl; each Q independently is a direct bond or —NR— wherein R is H, optionally substituted aryl or optionally substituted alkyl; rings A,B,C and D are each independently unsubstituted or carry a substituent selected from optionally substituted alkyl, optionally substituted aryl and optionally substituted aralkyl; each n independently is from 1 to 3; and each m independently is 0, 1 or 2; provided that when either or both of the groups represented by Q is a direct bond then at least one n has a value of at least 2.Type: GrantFiled: April 7, 2004Date of Patent: May 8, 2007Assignee: Fujifilm Imaging Colorants LimitedInventors: Clive Edwin Foster, David Schofield, Helen Ava O'Shaughnessy
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Patent number: 7211132Abstract: To provide an ink set capable of recording images with good ozone fastness on a recording medium, an ink set of the present invention comprises at least a yellow ink composition, a magenta ink composition, and a cyan ink composition. The cyan ink composition contains at least one of the compounds expressed by formula (1) below as a cyan dye: and the magenta ink composition contains, as a colorant, at least one substance selected from the group consisting of compounds expressed by formula (2) below: and salts thereof (in formula (2), A represents an alkylene group, an alkylene group containing a phenylene group, or a group expressed by formula (3) below: and X represents a group selected from the group consisting of NH2, OH, and Cl).Type: GrantFiled: September 28, 2004Date of Patent: May 1, 2007Assignee: Seiko Epson CorporationInventors: Yasuhiro Oki, Kazuhiko Kitamura, Tetsuya Aoyama, Masahiro Hanmura, Hiroshi Fukumoto
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Patent number: 7205406Abstract: An azomethine dye represented by the following Formula 1: wherein Y represents a substituent of 0.2??p?0.9, Z1 and Z2 each represent —CR1?, where R1 represents a hydrogen atom or a substituent, or —N?, L represents the group represented by the following Formula 1a, X represents an unsubstituted or substituted di-alkylamino group, R represents an unsubstituted or substituted alkyl group, and n represents an integer more than 0. wherein B represents a group of non-metallic atoms which are necessary to form a heterocyclic ring.Type: GrantFiled: July 1, 2005Date of Patent: April 17, 2007Assignee: Konica Minolta Holdings, Inc.Inventors: Emiko Kataoka, Takatugu Suzuki, Dai Ikemizu
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Patent number: 7201791Abstract: There is provided an ink jet light-color ink which is excellent in color developability and is capable of achieving compatibility between environmental gas resistance and bronze resistance. The ink jet light-color ink to be used in combination with ink jet deep-color ink has a relatively large coloring material content, and comprises at least water, a water-soluble organic solvent, and a coloring material. The ink jet deep-color ink and the ink jet light-color ink satisfy specific conditions.Type: GrantFiled: January 26, 2006Date of Patent: April 10, 2007Assignee: Canon Kabushiki KaishaInventors: Daiji Okamura, Yoshihisa Takizawa, Shin-ichi Sato, Jun Yoshizawa, Kunihiko Nakamura, Yoshihide Aikawa, Tomohiro Yamashita, Masanori Jinnou
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Patent number: 7195664Abstract: The present invention provides an ink set, an ink jet recording apparatus, an ink jet recording method, a recording unit, and an ink cartridge, which can produce ink jet color images in which the color balance does not easily become unstable even if the image is stored for a long time, and in which the color images have greater durability so that degradation of the visual appearance is not easily recognizable even if the image is stored for a long time. The ink set includes a first aqueous ink and a second aqueous ink having the same color tone, the second ink having a lower coloring material content than that of the first ink, and the degree of fading of an image produced with the second ink is the same as or lower than that of an image produced with the first ink.Type: GrantFiled: October 10, 2003Date of Patent: March 27, 2007Assignee: Canon Kabushiki KaishaInventors: Kumiko Mafune, Tsuyoshi Kanke
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Patent number: 7195665Abstract: An ink jet ink includes at least a coloring material. The coloring material is composed of at least one selected from the group consisting of C.I. Direct Violet 107, C.I. Acid Red 14, C.I. Acid Red 52, C.I. Acid Red 87 and C.I.Type: GrantFiled: February 27, 2006Date of Patent: March 27, 2007Assignee: Canon Kabushiki KaishaInventors: Koichi Osumi, Sadayuki Sugama
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Patent number: 7160372Abstract: There is provided ink jet ink containing at least a coloring material, in which: the coloring material is a compound represented by the following general formula (I) or a salt thereof; a content (weight %) of the coloring material is 3.0 weight % or more with respect to a total weight of the ink jet ink; in a dispersion distance distribution, measured by a small-angle X-ray scattering method, of molecular aggregates in the ink jet ink whose coloring material concentration is adjusted to 3.0 weight %, a dispersion distance d75 value corresponding to 75% of the distribution is 6.50 nm or more and 7.Type: GrantFiled: December 30, 2005Date of Patent: January 9, 2007Assignee: Canon Kabushiki KaishaInventors: Jun Yoshizawa, Shin-ichi Sato, Kunihiko Nakamura, Daiji Okamura, Tomohiro Yamashita, Masanori Jinnou
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Patent number: 7132012Abstract: An ink comprising a compound represented by formula (I) as defined in the specificationType: GrantFiled: July 15, 2005Date of Patent: November 7, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiichi Tateishi, Yoshiharu Yabuki
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Patent number: 7125442Abstract: A lightfast additive and an ink composition including the same include a benzophenone moiety for lightfastness and a moiety for wettability and the ability to stabilize a colorant, wherein the two moieties are covalently bonded. The lightfast additive may exhibit effective ultraviolet (UV) light absorption capacity, effective wettability, and an ability to stabilize a colorant. The ink composition utilizing the light fast additive thus has an improved lightfastness and long-term storage stability.Type: GrantFiled: May 24, 2004Date of Patent: October 24, 2006Assignee: Samsung Electronics Co., Ltd.Inventors: Kyung-hoon Lee, Seung-min Ryu, Yeon-kyoung Jung
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Patent number: 7125444Abstract: An inkjet ink comprising at least one dye having a heterocyclic ring and a metal ion in an aqueous medium, wherein the ink jet ink further comprises a compound capable of accelerating aggregation of the dye in the aqueous medium.Type: GrantFiled: March 24, 2004Date of Patent: October 24, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiki Taguchi, Naotaka Wachi
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Patent number: 7108742Abstract: The invention relates to an ink composition containing (a) a compound of formula (I), Lm?Ln3+(Ch?)n (I), wherein Ln represents a lanthanide, CH? is a negatively charged ligand containing at least one UV absorbing double bond, n denotes 3 or 4, m denotes a number from 1 to 4, in case n is 3, m denotes a number from 1 to 4 and L is a neutral monodentate or polydentate nitrogen-, oxygen- or sulfur-containing UV absorbing ligand with the exception of 2,2?-bipyridyl or, in case n is 4, m denotes 1 and L is a single-charged cation; and (b) a liquid ink carrier, which can be used for applying hidden mark on objects which can only be revealed under UV exposure.Type: GrantFiled: February 18, 2003Date of Patent: September 19, 2006Assignee: Ciba Specialty Chemicals CorporationInventors: Véronique Hall-Goulle, Stefan Koller, Mickael Mheidle
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Patent number: 7097701Abstract: An ink containing a phthalocyanine compound represented by the formula (I): wherein X1 to X4, Y1 to Y4, A1 to A4, and M are defined herein.Type: GrantFiled: December 29, 2003Date of Patent: August 29, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiichi Tateishi, Yoshiharu Yabuki, Shigeaki Tanaka
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Patent number: 7097698Abstract: In order to improve the water-resisting property of an image formed on a recording medium such as recording paper and plain paper by using an ink-jet recording ink, while also improving the light-resisting property of the image, an ink-jet recording ink, which contains a color material, water, a moisture-retaining agent, an organic silicon compound and an ultraviolet-ray absorbing agent, is allowed to contain an organic silicon compound in a range of 0.1 parts by weight to 50 parts by weight and an ultraviolet-ray absorbing agent in a range of 0.1 parts by weight to 10 parts by weight with respect to 100 parts by weight of the ink. The ultraviolet-ray absorbing agent is at least one compound selected from the group consisting of benzophenone-based, benzotriazole-based, cyanoacrylate-based and oxalic acid anilide-based compounds.Type: GrantFiled: March 4, 2003Date of Patent: August 29, 2006Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Mamoru Soga, Takuma Takasu, Hidekazu Arase
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Patent number: 7087752Abstract: Compounds of the formulae wherein Z is OR1, SR1, or NR1R2, Y is OR3, SR3, or NR3R4, at least one of R1, R2, R3, R4, R5, and R6 is hydrogen, at least one of R1, R2, R3, R4, R5, and R6 is other than hydrogen, at least one Z or Y within the compound is NR1R2 or —NR3R4, R1, R2, R3, R4, R5, R6, and R7 each, independently of the others, is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, and wherein R7 can also be (vi) an alkoxy, aryloxy, arylalkyloxy, alkylaryloxy, polyalkyleneoxy, polyaryleneoxy, polyarylalkyleneoxy, polyalkylaryleneoxy, silyl, siloxane, polysilylene, polysiloxane, or wherein X is a direct bond, oxygen, sulfur, NR40— wherein R40 is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, or CR50R60— wherein R50 and R60 each, independently of the other, is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, and wherein R6 can also beType: GrantFiled: March 26, 2004Date of Patent: August 8, 2006Assignee: Xerox CorporationInventors: Marcel P. Breton, Danielle C. Boils-Boissier, Jule W. Thomas, Jr., Donald R. Titterington, H. Bruce Goodbrand, Jeffrey H. Banning, James D. Wuest, Dominic Laliberte, Marie-Eve Perron
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Patent number: 7083666Abstract: An inkjet ink comprising a dye, water, a water-soluble organic solvent and a betaine compound, wherein the total weight of inorganic ions in the ink is 2 wt % or less based on the ink.Type: GrantFiled: March 23, 2004Date of Patent: August 1, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiki Taguchi, Manabu Ogawa
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Patent number: 7077894Abstract: An inkjet ink set comprising at least two inks, wherein at least one ink contains a betaine compound and at least one other ink contains a nonionic surfactant.Type: GrantFiled: March 24, 2004Date of Patent: July 18, 2006Assignee: Fuji Photo Fim Co., Ltd.Inventors: Toshiki Taguchi, Manabu Ogawa
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Patent number: 7074265Abstract: An ink jet recording liquid exhibiting superior image color and improved color image fastness is disclosed, comprising a medium and an oil-soluble dye represented by the following formulasType: GrantFiled: June 4, 2004Date of Patent: July 11, 2006Assignee: Konica Minolta Holdings, Inc.Inventors: Satoru Ikesu, Takatugu Suzuki, Mari Takahashi
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Patent number: 7066990Abstract: The present invention relates to an ink jet ink, an ink jet recording material or an ink jet system comprising at least one compound selected from the group consisting of a) the dialkyl hydroxylamine stabilizers, b) the nitrone stabilizers and c) the amine oxide stabilizers. The present stabilizer compounds provide ink jet prints with outstanding light stability, gas fade stability and dark storage stability. The hydroxylamines are for example N,N-dihydrocarbylhydroxylamines of the formula R1R2N—OH, wherein R1 and R2 are independently benzyl, methyl, ethyl, octyl, lauryl, dodecyl, tetradecyl, hexadecyl, heptadecyl or octadecyl, or wherein R1 and R2 are each the alkyl mixture found in hydrogenated tallow amine. The nitrone and amine oxide stabilizers are for example nitrone and amine oxide analogues of the dialkylhydroxylamine stabilizers.Type: GrantFiled: January 21, 2004Date of Patent: June 27, 2006Assignee: Ciba Specialty Chemicals CorporationInventors: Mervin G. Wood, Joseph Suhadolnik, Ramanathan Ravichandran, Sai P. Shum
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Patent number: 7066991Abstract: An ink jet set comprising: a) a cyan ink comprising a carrier and a sulfonated copper phthalocyanine dye; b) a magenta ink comprising a carrier and an anthrapyridone magenta dye or metal complex magenta dye, or azo-naphthol derivative magenta dye or mixture thereof; c) a yellow ink comprising a carrier and an azo-aniline yellow dye or metal complex yellow dye or mixtures thereof; and d) a trisazo black dye of the following structure where Met is a metal atom, preferably Al, Co, Cr, Cu, Fe, or Ni; R1 is a phenyl or naphthalene radical substituted by 1, 2 or 3 substituents selected from the group consisting of OH, O(C1–C6)-alkyl, COOM, SO3M and NH2; R2 is C1–C6-alkyl, n is 0 or 1, X is a chemical bond or —CO— or —SO2—; R3 is H, methyl or O(C1–C6)-alkyl; R4 and R5 are each H, COOM or SO3M; R6 is a phenyl, pyridyl or pyrazole radical substituted by 1,2 or 3 substituents selected from the group consisting of OH, O(C1–C6)-alkyl, COOM, SO3M, NH2, NHaryl, NHacyl and phenylsulfo; and M is ammonium, H, K, Li, or NaType: GrantFiled: October 28, 2003Date of Patent: June 27, 2006Assignee: Eastman Kodak CompanyInventors: James W. Blease, LuAnn K. Weinstein
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Patent number: 7052535Abstract: Anti-bronzing compounds are added to inkjet inks to prevent bronzing of the inks when printed on specialty quick-dry inkjet photographic media. These compounds inhibit bronzing by the proper buffering of the dyes relative to the media of interest.Type: GrantFiled: July 28, 2003Date of Patent: May 30, 2006Assignee: Hewlett-Packard Development Company, L.P.Inventors: Linda C. Uhlir-Tsang, John R Moffatt, Mary E Austin
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Patent number: 7048789Abstract: An ink containing a water, a water-soluble organic solvent, a dye, and a betaine compound, which optionally further contains a nonionic surfactant or at least one another betaine compound.Type: GrantFiled: March 23, 2004Date of Patent: May 23, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiki Taguchi, Manabu Ogawa
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Patent number: 7041162Abstract: The present invention provides an aqueous ink composition comprising a color microparticle dispersion including an oil-soluble dye, a hydrophilic organic solvent and a perfluoroalkylenesulfonic acid or a fluorine type surfactant other than derivatives thereof, and an ink jet method for recording an image by using this aqueous ink composition.Type: GrantFiled: August 7, 2003Date of Patent: May 9, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Takahiro Ishizuka, Kenji Ikeda
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Patent number: 7025814Abstract: The present invention relates to an ink-jet ink, an ink-jet recording material or an ink-jet system containing at least one water-soluble hindered amine compounds of the general formula (I) or (II): wherein G1 and G2 are independently alkyl of (1) to (4) carbon atoms or are together pentamethylene; Z1 and Z2 are each methyl, or Z1 and Z2 ?together form an unsubstituted linking moiety or a linking moiety substituted by one or more groups selected from an ester, ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or an urethane group; E is oxyl; X is an inorganic or organic anion; and wherein the local charge of cations h is equal to the total charge of anions j.Type: GrantFiled: January 8, 2002Date of Patent: April 11, 2006Assignee: Ciba Specialty Chemicals Corp.Inventor: Stéphane Biry
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Patent number: 7025813Abstract: An ink composition is disclosed which contains at least one novel dye (CU)n(SAU)m that is capable of self-assembling under appropriate conditions to form supramolecular structures. More than one novel dye (CU)n(SAU)m and/or at least one non-colored self-assembling compound (SAU?)p(X)q may be incorporated in these supramolecular structures. Also disclosed is an ink-jet printing process using these novel dyes, and an ink-jet printing apparatus provided with an ink cartridge containing such a dye.Type: GrantFiled: May 12, 2004Date of Patent: April 11, 2006Assignee: AGFA-GevaertInventors: Luc Vanmaele, Johan Loccufier, Egbert Meijer, Henricus Janssen, Pieter Fransen
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Patent number: 7025816Abstract: An anthraquinone dye represented by the Formula (1), (2) or (3), and an ink jet recording liquid containing a compound represented by the following Formula (1), (2) or (3):Type: GrantFiled: November 12, 2004Date of Patent: April 11, 2006Assignee: Konica Minolta Holdings, Inc.Inventors: Takatugu Suzuki, Satoru Ikesu, Mari Takahashi
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Patent number: 7018455Abstract: An ink composition, a recording medium or printed matter containing a compound expressed by General Formula 1 The compound has a weight reduction after 1 hour at 60°C. of no more than 1%. This makes it possible to provide the ink composition, a recording medium, printed matter, and an ink jet recording method wherein a light resistance of the printed matter is excellent, there is no ink clogging, and a high-quality image with almost no yellowing of the printed matter can be obtained.Type: GrantFiled: March 21, 2002Date of Patent: March 28, 2006Assignee: Seiko Epson CorporationInventors: Kazuhiko Kitamura, Yasuhiro Oki, Tetsuya Aoyama, Kyoichi Oka, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito