Erasable, Purified, Correctable, Fugitive, Indicator, Conductive, Fluorescent, Chromogenic, Or Magnetic Composition Patents (Class 106/31.64)
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Publication number: 20080087190Abstract: Disclosed is a phase change ink containing a fluorescent colorant that upon exposure to activating energy fluoresces such that an image that was not visible prior to exposure to the activating energy becomes visible. Also disclosed are an ink jet system and a process for authenticating a color document using the disclosed phase change ink.Type: ApplicationFiled: October 12, 2006Publication date: April 17, 2008Applicant: XEROX CORPORATIONInventors: Gabriel IFTIME, Christopher A. WAGNER, C. Geoffrey ALLEN, Peter M. KAZMAIER, Peter G. ODELL, Paul F. SMITH
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Patent number: 7344590Abstract: The present invention relates to silver pigments based on transparent, low-refractive-index, platelet-shaped substrates which have a high-refractive-index coating consisting of TiO2 having a layer thickness of 5-300 nm and optionally an outer protective layer, and to the use thereof in paints, coatings, printing inks, security printing inks, plastics, button pastes, ceramic materials, glasses, for seed coloring, as dopants in the laser marking of plastics and papers, as additives for coloring in the foods and pharmaceuticals sectors, and in cosmetic formulations and for the preparation of pigment compositions and dry preparations.Type: GrantFiled: March 29, 2004Date of Patent: March 18, 2008Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Christoph Schmidt, Tanja Delp, Johann Dietz
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Patent number: 7344587Abstract: The invention provides tissue markings (such as tattoos) comprising magnetic particles, e.g., magnetite, and methods for making and altering, e.g., removing them.Type: GrantFiled: August 6, 2004Date of Patent: March 18, 2008Assignee: The General Hospital CorporationInventors: Misbah H. Khan, Richard Rox Anderson
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Patent number: 7316790Abstract: Sulfur-containing phosphor powders, methods for making phosphor powders and devices incorporating same. The powders have a small particle size, narrow particle size distribution and are substantially spherical. The method of the invention permits the continuous production of such powders. The invention also relates to products such as display devices incorporating such phosphor powders.Type: GrantFiled: April 3, 2006Date of Patent: January 8, 2008Assignee: Cabot CorporationInventors: Mark J. Hampden-Smith, Toivo T. Kodas, James Caruso, Daniel J. Skamser, Quint H. Powell, Klaus Kunze
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Publication number: 20070289488Abstract: Disclosed is a water washable ink for offset lithographic newspaper printing containing: a modified soybean oil-based resin; a pigment; and an acid neutralization agent, wherein the water washable offset lithographic newspaper printing ink does not contain any of the following: a humectant, a surfactant or a modified linseed oil.Type: ApplicationFiled: June 16, 2006Publication date: December 20, 2007Inventors: Sidney McIntosh, Harold Bower, Richard Durand
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Patent number: 7285158Abstract: An image forming method, device and a recording agent for forming an image through subtractive color mixing by using ink of plural color components different in hue. The ink is created by mixing a first coloring agent expressing one of the color components and a second coloring agent identical in hue to the first coloring agent. The ink has a higher spectral reflectance than a spectral reflectance of the first coloring agent.Type: GrantFiled: March 25, 2004Date of Patent: October 23, 2007Assignee: Sharp Kabushiki KaishaInventors: Takuya Iwanami, Haruo Yamamoto, Satoshi Nishigaki, Tohru Sakuwa
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Publication number: 20070236551Abstract: An ink for ink-jet recording may contain a coloring agent and a marker. The coloring agent may contain a pigment. The marker may have a detector absorption peak for detecting the marker at a wavelength that is different from a wavelength of the maximum absorption peak of the coloring agent. The coloring agent and the marker may be contained in the ink in amounts that satisfy the following conditions (I) to (III): (I) about 1.2?A2/A3; (II) color difference (?E)?about 3; and (III) about 1?A2?about 10 in terms of a measurement optical path length of 1 mm, where A2 denotes an absorbance at the wavelength of the detector absorption peak of the marker, A3 denotes a baseline absorbance at the wavelength of the detector absorption peak of the marker.Type: ApplicationFiled: April 10, 2007Publication date: October 11, 2007Applicant: BROTHER KOGYO KABUSHIKI KAISHAInventor: Tatsunosuki Hoshi
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Patent number: 7220301Abstract: Disclosed herein is an ink comprising (i) first and second organic compounds which are incompatible with each other; (ii) at least one of a compound exhibiting fluorescence properties and a coloring material exhibiting fluorescence properties; and (iii) a liquid medium dissolving or dispersing the components (i) and (ii) therein.Type: GrantFiled: July 30, 2003Date of Patent: May 22, 2007Assignee: Canon Kabushiki KaishaInventors: Akira Nagashima, Shinichi Hakamada
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Patent number: 7192474Abstract: Water-soluble, photosensitive, optically variable (POV) inks exhibit improved OCR readability due to improved infrared absorption properties. The inks can produce images that can be viewed with both visible and ultraviolet light to have physically coincident positive and negative images. The new inks contain at least two types of colorants in addition to the IR absorber and other suitable ingredients. The first colorant comprises a fluorescent dye or pigment emitting light within a characteristic emission band when excited by fluorescent-exciting radiation. The second colorant comprises a carbon black infrared radiation absorbing composition alone or with one or more dyes or pigments having a light absorption band at longer wavelengths than the characteristic emission band of the first colorant or also overlapping the emission wavelength of the first colorant in such a way as to result in a dark color.Type: GrantFiled: June 22, 2004Date of Patent: March 20, 2007Assignee: Pitney Bowes Inc.Inventors: Judith D. Auslander, Mike Y. R. Chen
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Patent number: 7189341Abstract: The invention is directed to conductive polymer compositions, catalytic ink compositions (e.g., for use in screen-printing), electrodes produced by deposition of an ink composition, as well as methods of making, and methods of using such compositions and electrodes. An exemplary ink material comprises a metal catalyst (e.g., platinum black and/or platinum-on-carbon), graphite as a conducting material, a polymer binding material, and an organic solvent. In one aspect, the polymer binding material comprises a polymer binder blend comprising first and second polymers, wherein the first polymer has a glass transition temperature higher than the second polymer. In a second aspect, the polymer binding material comprises a hydrophilic acrylic polymer, copolymer, or terpolymer. The conductive polymer compositions of the present invention may be used, for example, to make electrochemical sensors. Such sensors may be used, for example, in a variety of devices to monitor analyte amount or concentrations in subjects.Type: GrantFiled: October 24, 2003Date of Patent: March 13, 2007Assignee: Animas Technologies, LLCInventors: Huawen Li, Michael J. Tierney
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Patent number: 7160371Abstract: A process for the preparation of organic pigments with enhanced fluorescence, which process comprises treating said pigments with a surfactant, and to the fluorescent organic pigments obtained by said process. The pigments according to the present invention can be used in marking applications, wherein durable fluorescence is required.Type: GrantFiled: May 24, 2005Date of Patent: January 9, 2007Assignee: Ciba Specialty Chemicals CorporationInventors: Iain Frank Fraser, Sharon Kathleen Wilson, Ian Alexander Macpherson
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Patent number: 7147801Abstract: Disclosed is an ink composition suitable for ink jet printing comprising a luminescent compound, a solvent, and an energy active compound, and optionally a non-luminescent colorant. The energy active compound, when exposed to energy, generates one or more active species that can react with the luminescent compound to alter one or more of the characteristics of the luminescent compound. The luminescent compound can be colored or colorless. Also disclosed is a method for marking substrates comprising providing a mark comprising a luminescent compound and an energy active compound. Further disclosed is a jet ink composition suitable for printing on substrates authentication or security marks which can be rendered unreadable. The luminescence of the mark is quenched and the visible color is changed when irradiated with a light.Type: GrantFiled: March 12, 2004Date of Patent: December 12, 2006Assignee: Videojet Technologies Inc.Inventors: Michael Kozee, Steven D. Looman, John P. Folkers
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Patent number: 7147696Abstract: A fluorescent water base ink for ink-jet recording to be used for an ink-jet printer contains water, a pigment, a compound having primary or secondary amide group, and a fluorescent dye represented by the following formula (1): wherein R1 represents OH or N(R3)R4, R2 represents hydrogen atom or halogen atom, and each of R3 and R4 represents hydrogen atom or alkyl group. A sufficient OD value and a fluorescence value are obtained while securing the vivid color development and the excellent water resistance principally in accordance with the interaction of the fluorescent dye and the compound having the amide group.Type: GrantFiled: August 12, 2004Date of Patent: December 12, 2006Assignee: Brother Kogyo Kabushiki KaishaInventors: Michiko Aoyama, Masashi Tsuda, Hideto Yamazaki, Hiromitsu Sago, Mayuko Umemura, Shunichi Higashiyama
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Patent number: 7144449Abstract: The present invention provides a fluorescence ink having a high fluorescence intensity, and an ink jet recording method using the same. The ink contains a first fluorescent coloring material that emits fluorescence at a predetermined fluorescence wavelength to be used for measurement or determination with excitation at a predetermined excitation wavelength, a second fluorescent coloring material that emits fluorescence on excitation at the predetermined excitation wavelength, where the excitation spectrum of the first coloring material in the ink to obtain the fluorescence at the predetermined emission wavelength has a peak wavelength range next to the predetermined fluorescence wavelength, and the emission fluorescence spectrum of the second coloring material has an emission wavelength region substantially including at least the above peak wavelength range.Type: GrantFiled: June 14, 2004Date of Patent: December 5, 2006Assignee: Canon Kabushiki KaishaInventors: Masako Udagawa, Sadayuki Sugama, Shoji Koike, Makoto Aoki, Akira Nagashima, Shinichi Hakamada
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Patent number: 7141103Abstract: New photosensitive optically variable inks are capable of printing images having improved resistance to water. The inks produce images which can be viewed with both visible and ultraviolet light to have physically coincident positive and negative images. They contain at least two types of colorants and other suitable ingredients to enable preparation for printing. The first colorant comprises a fluorescent dye emitting light within a characteristic emission band when excited by fluorescent-exciting radiation. The second colorant, which comprises a colloidal pigment alone or with a dye, has a light absorption band at longer wavelengths than the characteristic emission band of the first colorant or overlapping the emission wavelength of the first colorant, effectively to result in a dark color.Type: GrantFiled: June 22, 2004Date of Patent: November 28, 2006Assignee: Pitney Bowes Inc.Inventors: Judith D. Auslander, Mike Y. R. Chen
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Patent number: 7138009Abstract: Signature protected photosensitive optically variable (POV) inks are provided, which are capable of providing a unique signature in addition to other security features of POV inks. The inks contain at least two types of colorants, and a third, signature component and other ingredients to enable printing. A first colorant comprises a fluorescent dye and/or pigment emitting light within a characteristic emission band when excited by fluorescent-exciting radiation. A second colorant comprises a dye and/or pigment having a light absorption band at overlapping or longer wavelengths than the characteristic emission band of the first colorant in such a way as to result in a dark color. The third component is a fluorescent/phosphorescent rare earth composition. The inks give dark visible ink images, which also produce detectable coincident fluorescent and phosphorescent images. The inks can be used with detectors of red phosphorescence to achieve a new level of security in high speed sorting operations.Type: GrantFiled: June 22, 2004Date of Patent: November 21, 2006Assignee: Pitney Bowes Inc.Inventor: Judith D. Auslander
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Patent number: 7118618Abstract: The colored liquid composition of the invention for a highlighter comprises a coloring element and water, the water content by weight lies in the range 10% to 30%. In addition, it comprises at least 40% of a liquid component having surface tension greater than 40 mN/m. In a variant, the coloring element is a tracer solvent having a fluorescent appearance under basic pH, in particular hydroxypyrenetrisulfonic acid, the pH of the composition lying in the range 8 to 9, and the component having surface tension greater than 40 mN/m is triethanolamine. Under such circumstances, the composition contains an acid to neutralize the triethanolamine in part in order to obtain the basic pH, for example hydrochloric acid.Type: GrantFiled: December 20, 2001Date of Patent: October 10, 2006Assignee: ConteInventors: José Duez, Carine Bethouart
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Patent number: 7063806Abstract: The present invention relates to fluorescent diketopyrrolopyrroles (“DPPs”) of the formula characterized in that that at least two adjacent substituents R5 to R11 form an aromatic or aliphatic fused ring system, or at least one substituent R5 to R11 is cycloalkyl, aralkyl, alkenyl, cycloalkenyl, alkynyl, a hydroxyl group, a mercapto group, alkylthio, an aryl thioether group, a heterocyclic group, halogen, haloalkyl, haloalkenyl, haloalkynyl, a cyano group, an aldehyde group, a carbonyl group, a carboxyl group, an ester group, a carbamoyl group, a nitro group, a silyl group, a siloxanyl group, a substituted or unsubstituted vinyl, arylamino or diarylamino group; a process for their preparation and their use for the preparation of inks, colorants, pigmented plastics for coatings, non-impact-printing material, color filters, cosmetics, or for the preparation of polymeric ink particles, toners, dye lasers and electroluminescent devices.Type: GrantFiled: June 20, 2002Date of Patent: June 20, 2006Assignee: Ciba Specialty Chemicals CorporationInventors: Hiroshi Yamamoto, Norihisa Dan, Olof Wallquist
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Patent number: 7029524Abstract: A water-based, aerosol marking composition that adheres to a variety of surfaces but is removable by mechanical rubbing with a dry cloth or by washing with water is provided. The composition comprises 10 to 50% by weight water; 5 to 50% by weight of a solvent selected from the group consisting of a C6 to C15 aliphatic solvent, an aromatic solvent comprising 10 or fewer carbon atoms, an ether, and an alcohol, or combinations thereof; 0.1 to 4% of an emulsifier having a hydrophile to lipophile balance of from 1.8 to 16.7; a marking agent; and 10 to 45% propellant. In a preferred embodiment the composition lacks or contains only trace amounts of an alkyd-based drying oil, polyvinylpyrrrolidone, or polyvinyl alcohol, or another agent that serves as an adhesive for the pigment particles. In certain embodiments, the composition comprises an inorganic filler and from 0.05% to 3% surfactant.Type: GrantFiled: June 28, 2004Date of Patent: April 18, 2006Assignee: Day-Glo Color Corp.Inventors: Christopher J. Newbacher, Candido N. Vina, Vincent A. Veiram
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Patent number: 7018564Abstract: A method for making phosphor ink is provided which uses ultrasonic vibrations to remove surface defect layers from phosphor particles and to quickly and uniformly disperse the phosphor particles throughout a slurry. Propagation of low frequency vibration through the slurry generates cavitation, causing distortion and then removal of the surface defect layer, and propagation of high frequency vibration through the slurry causes the particles to be dispersed quickly and uniformly throughout the slurry. In this manner, a quantity of light generated in the phosphor and corresponding luminance of a PDP is increased.Type: GrantFiled: January 8, 2004Date of Patent: March 28, 2006Assignee: LG Electronics Inc.Inventors: Won-Seok Moon, Bum-Jin Bae, Na-Mi Byun, Jin-Mok Oh
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Patent number: 6946550Abstract: Azo compounds of formula (I), wherein X stands for halogen, in particular for chlorine, or C1-C4alkoxy, in particular for methoxy, Y stands for —CH2— or —O—, R1 and R2, independently from each other, stand for hydrogen, C1-C8alkyl, or C6-C14aryl, which may be substituted up to three times with C1-C8alkyl, C1-C4alkoxy or halogen, a process for their preparation and their use as fluorescent compounds, in particular as solid fluorescent compounds, such as for special effect printing, sectrity printing or in the opto-electronic field.Type: GrantFiled: November 19, 2002Date of Patent: September 20, 2005Assignee: Ciba Specialty Chemicals CorporationInventors: Iain Frank Fraser, Ian Alexander Macpherson, David Macdonald Smith, Simon Martyr, Greig Chisholm, Stephen John Coughlin
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Patent number: 6913860Abstract: An image forming material for forming an image on an image recording material with an image binding force being established between the image and the image recording material, the image forming material containing an image forming substance, and a binding force reducing substance which reduces the image binding force when the image is heated. A method of removing an image formed on an image recording material with a binding force being established between the image and the recording material by contacting a stripping member with the image with heating under pressure. A binding force reducing substance may be contained in the surface of the stripping member or in the image recording material.Type: GrantFiled: July 31, 2002Date of Patent: July 5, 2005Assignee: Ricoh Company, Ltd.Inventors: Hidehiro Mochizuki, Tadashi Saitou
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Patent number: 6905539Abstract: A shear-thinning eradicable ink including water, a dye selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, methine dyes, and a solvent, wherein the ink has a shear-thinning index in the range of about 0.35 to about 1.0; a kit including the ink and an eradicator solution; an ink complex including a colorless or substantially colorless dye selected from the group consisting of oxidized diarylmethane derivatives, oxidized triarylmethane derivatives, and oxidized methine dyes, and at least one or a gelling agent and thickener; and methods of using the ink as part of an eradicable ink system, are disclosed herein.Type: GrantFiled: July 15, 2003Date of Patent: June 14, 2005Assignee: Sanford L.P.Inventors: Sanjay Patel, David Godbout, Wing Sum Vincent Kwan
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Patent number: 6899752Abstract: A latent image ink composition including an organic fluorescent substance which responds to an excitation wavelength range of 600-850 nm and emits fluorescence in a wavelength range of 651-900 nm, a quencher, and a curing resin composition, prints which comprise a substrate and a latent image formed from the ink composition on the substrate, and a latent image data deciphering apparatus and latent image data deciphering method, provided with an emitting element for irradiating the prints with the excitation wavelength, a receiving element for detecting the emission of fluorescence in the wavelength range emitted from the cured ink of the print, and a computer processor for deciphering the detected emission of fluorescence against a standard value. Discrimination of the genuineness of articles can be accomplished reliably without the knowledge of third parties.Type: GrantFiled: May 16, 2003Date of Patent: May 31, 2005Assignees: Fujitsu Limited, Fujitsu Isotec LimitedInventors: Chiaki Sekioka, Muneo Maetani, Yoichi Hirasawa
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Patent number: 6896723Abstract: An imaging composition comprising a mixture of a solvent and a functional material; wherein the solvent is a compressed fluid and the functional material is a hole transporting material which is dissolved, dispersed and/or solubilized in the compressed fluid; wherein the mixture is thermodynamically stable or thermodynamically metastable or both; wherein the functional material is solvent-free upon deposition on a substrate; and wherein the functional material forms a solid film upon deposition on the substrate.Type: GrantFiled: December 6, 2002Date of Patent: May 24, 2005Assignee: Eastman Kodak CompanyInventors: Glen C. Irvin, Ramesh Jagannathan, Seshadri Jagannathan, Rajesh V. Mehta, Sridhar Sadasivan, Ross A. Sprout, Tin T. Vo
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Patent number: 6893490Abstract: An ink for a display panel that at a time of application is a mixture of a powder material, a water-soluble resin included in a range of 1 wt % to 20 wt % inclusive of the ink, and a water-miscible solvent. The ink is water-soluble, and in comparison to conventional organic inks, the ink of the present invention exhibits a markedly reduced susceptibility to the occurrence of electrostatic action. Thus, even when the ink is discharged through a plurality of fine nozzle holes, for example, it is possible for the application process to be conducted with great efficiency, since the individual ink flows discharged from the nozzle holes flow in a vertically downward direction without reacting with each other and becoming warped as a result. The ink of the present invention may, for example, be a phosphor ink, an Ag electrode ink, a shading film (black matrix) ink, a sealant glass ink, or a white reflective layer ink, and the ink may be used in forming structural layers of a display panel.Type: GrantFiled: April 16, 2001Date of Patent: May 17, 2005Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Hiroyuki Kawamura, Keisuke Sumida, Shigeo Suzuki
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Patent number: 6893489Abstract: A coating, such as ink or paint, is used, where particles in the coating are selected based on electric, magnetic, or light/photo properties, and are dispersed in the coating to provide a desired physical color. In one approach, the application of the coating to the substrate such as paper is controlled using an electric or magnetic field. In another approach, a pattern is formed in a coating on a substrate by targeting an electric, magnetic or photo field to specific locations on the coating. In yet another approach, the color of a coating that is applied to an object is shifted to match a background color so that the coating appears to be erased. In this approach, the coating may be in the form of a label, such as a bar code, that can be read by a scanner at a point of sale location. In another approach a pattern or code is scrambled or removed by applying an electric, magnetic, or photo field to specific locations on the coating or substrate.Type: GrantFiled: December 20, 2001Date of Patent: May 17, 2005Assignee: Honeywell International Inc.Inventors: Kwok-Wai Lem, Ronald P. Rohrbach
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Patent number: 6881249Abstract: The present invention provides microparticles that create permanent tissue markings, such as tattoos, designed in advance for change and/or removal on demand, as well as methods for implanting the microparticles in tissue and changing and/or removing the resulting markings. Colored microparticles are constructed with specific electromagnetic absorption and/or structural properties that facilitate changing and/or removing tissue markings made using the microparticles by applying specific energy (such as electromagnetic radiation from a laser or flash-lamp) to the tissue marking site.Type: GrantFiled: March 14, 2003Date of Patent: April 19, 2005Assignees: The General Hospital Corporation, Freedom-2, LLCInventors: Richard R. Anderson, Susanna K. Mlynarczyk, Craig A. Drill
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Patent number: 6863720Abstract: The problem is to provide a thermosensitive color-changing dry offset ink, having no problem in an ink transferability and an excellent printing characteristics. As a thermosensitive color-changing dry offset ink is used one composed of thermosensitive, color-changing microcapsules mixed in a vehicle the capsule having two particle size characteristics of (1) particle size distribution: particles of less than 0.5 ?m are contained in not less than 10 volume % and those not larger than 3.0 ?m are contained in not less than 90 volume % and (2) mean particle diameter: 0.2-1.5 ?m.Type: GrantFiled: June 6, 2002Date of Patent: March 8, 2005Assignee: Matsui Shikiso Chemical Co., Ltd.Inventors: Yosuke Kitagawa, Shozo Suefuku, Masaki Kariya
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Patent number: 6861012Abstract: A latent or “invisible ink” security marking formulation is provided using a phosphor with distinct emissions characteristics including visible emission due to excitation at a particular invisible wavelength. An insoluble inorganic phosphor with this or a similarly distinct emission characteristic is milled to a small particle size, preferably less than one micron particle diameter, and is combined with a carrier at very low pigment concentration, for example one percent by weight of the ink formulation. Preferably the pigment is cropped to resin particles in a binder. This ink formulation is diluted by a volatile solvent and applied using a conventional inkjet printer of the type used to mark codes on packages and labels. To test for security purposes the printing is irradiated and a response according to the predetermined characteristic is noted (or not noted) to detect security information.Type: GrantFiled: October 11, 2001Date of Patent: March 1, 2005Assignee: Laser Lock Technologies, Inc.Inventors: Norman A. Gardner, Terry Stovold
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Patent number: 6855196Abstract: An ink for a display panel effective in reducing the uneven adhesion of the ink is applied by an ink application apparatus using an inkjet method to form a structural layer (e.g. reflective layer, phosphor layer) of a display panel such as a plasma display panel. The ink is delivered through a nozzle of the ink application apparatus and includes a powder material used in forming the structural layer, water or a water-miscible solvent, a binder formed from a water-soluble resin, and a plasticizer. The flexibility retained by the ink, even after the ink is applied, allows for leveling of the applied ink to occur and uneven adhesion to be reduced as a result.Type: GrantFiled: April 16, 2001Date of Patent: February 15, 2005Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Hiroyuki Kawamura, Keisuke Sumida, Shigeo Suzuki
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Patent number: 6852157Abstract: A luminescent flexographic printing ink for printing control marks comprises a combination of a light-scattering pigment and an optical brightener and is not opaque. The luminescent flexographic printing ink is used for printing control marks and bar codes and for the production of decorative papers, wood laminates and floor panels.Type: GrantFiled: May 6, 2002Date of Patent: February 8, 2005Assignee: BASF AktiengesellschaftInventors: Herbert Hirschmann, Guido Schweizer, Jörg Pohé
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Patent number: 6846350Abstract: Disclosed is a red luminous ink composition comprising a europium complex represented by the formula: wherein R1 is a hydrogen atom or a substituent selected from the group consisting of an alkyl group having from 1 to 4 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms and a halogen atom, R is a group selected from the group consisting of a fluorine-comprising alkyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkyl group having from 1 to 6 carbon atoms, a substituted or unsubstituted aralkyl group having from 7 to 10 carbon atoms and a substituted or unsubstituted aryl group having from 6 to 12 carbon atoms. The red luminous ink composition exhibits satisfactory emission intensity under ultraviolet irradiation.Type: GrantFiled: July 16, 2002Date of Patent: January 25, 2005Assignee: Orient Chemical Industries, Ltd.Inventors: Keishi Imanishi, Yasuhiro Yamasaki
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Patent number: 6835326Abstract: A fluorescent ink composition comprising functionalized fluorescent nanocrystals, an aqueous-based ink carrier comprising water or a water-based solution, and a binder.Type: GrantFiled: April 16, 2003Date of Patent: December 28, 2004Assignee: BioCrystal, Ltd.Inventor: Emilio Barbera-Guillem
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Publication number: 20040253419Abstract: The invention relates to an ink set comprising a plurality of inks of a first and of a second group, having different colors. Inks of said first group comprise a visible colorant and an additional IR-absorbing compound (IR-taggant) which has an absorption peak at a predetermined wavelength in the near infrared. Inks of said second group comprise a visible colorant which has at the same time an infrared absorption peak at the same wavelength as that of the IR-taggant used in the inks of the first group. Preferred embodiment is a four-color process ink set comprising an IR feature.Type: ApplicationFiled: April 14, 2004Publication date: December 16, 2004Inventors: Anton Bleikolm, Pierre DeGott, Claude-Alain Despland, Edgar Muller
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Patent number: 6827769Abstract: Ink compositions described are suitable for ink jet printing (ink jet inks) and are highly effective for simultaneously imparting visible and fluorescent images. In the preferred forms, both a dark, visible image and a complementary fluorescent image will be visually discernable as well as machine readable to enable efficient hand and automated processing or handling of the objects printed. These results are achieved by ink formulations that moderate the natural phenomena of quenching while possessing the physical properties necessary for an ink jet ink.Type: GrantFiled: April 10, 2002Date of Patent: December 7, 2004Assignee: PItney Bowes Inc.Inventors: Judith D. Auslander, Richard A Bernard
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Publication number: 20040233465Abstract: An article is marked with image indicia for authentication, information, or decoration by providing a plurality of inks having a plurality of fluorescence colors when exposed to excitation energy, separating colors of the image indicia into a plurality of image levels in accordance with the fluorescence colors of the inks, and printing each image level in mutual registration on the article using the corresponding ink. The image printed with each ink may be substantially invisible under illumination within the visible spectrum. The invisibly printed images have multiple authentication features, including the use of covert UV-fluorescent materials, IR-fluorophores, microparticles, and other chemical taggants. Ink compositions, methods for making the inks, and methods and apparatus for using the inks are also disclosed.Type: ApplicationFiled: April 5, 2004Publication date: November 25, 2004Applicant: Angstrom Technologies, Inc.Inventors: William J. Coyle, John C. Smith
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Patent number: 6814760Abstract: The present invention provides microparticles that create permanent tissue markings, such as tattoos, designed in advance for change and/or removal on demand, as well as methods for implanting the microparticles in tissue and changing and/or removing the resulting markings. Colored microparticles are constructed with specific electromagnetic absorption and/or structural properties that facilitate changing and/or removing tissue markings made using the microparticles by applying specific energy (such as electromagnetic radiation from a laser or flash-lamp) to the tissue marking site.Type: GrantFiled: January 10, 2003Date of Patent: November 9, 2004Assignee: The General Hospital CorporationInventors: Richard R. Anderson, Susanna K. Mlynarczyk, Craig A. Drill
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Publication number: 20040220298Abstract: Disclosed is an ink composition suitable for ink jet printing comprising a luminescent compound, a solvent, and an energy active compound, and optionally a non-luminescent colorant. The energy active compound, when exposed to energy, generates one or more active species that can react with the luminescent compound to alter one or more of the characteristics of the luminescent compound. The luminescent compound can be colored or colorless. Also disclosed is a method for marking substrates comprising providing a mark comprising a luminescent compound and an energy active compound. Further disclosed is a jet ink composition suitable for printing on substrates authentication or security marks which can be rendered unreadable. The luminescence of the mark is quenched and the visible color is changed when irradiated with a light.Type: ApplicationFiled: March 12, 2004Publication date: November 4, 2004Applicant: Videojet Technologies Inc.Inventors: Michael Kozee, Steven D. Looman, John P. Folkers
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Patent number: 6802992Abstract: Non-green anti-Stokes luminescent material, comprising the elements Ln, erbium (Er) and ytterbium (Yb), Ln representing at least one element which is selected from the group consisting of yttrium (Y), gadolinium (Gd), scandium (Sc) and lanthanum (La), a process for its production and its use.Type: GrantFiled: November 8, 1999Date of Patent: October 12, 2004Inventors: Jürgen Wieczoreck, Alfred Siggel, Uwe Fischbeck
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Patent number: 6800122Abstract: The present invention provides microparticles that create permanent tissue markings, such as tattoos, designed in advance for change and/or removal on demand, as well as methods for implanting the microparticles in tissue and changing and/or removing the resulting markings. Colored microparticles are constructed with specific electromagnetic absorption and/or structural properties that facilitate changing and/or removing tissue markings made using the microparticles by applying specific energy (such as electromagnetic radiation from a laser or flash-lamp) to the tissue marking site.Type: GrantFiled: March 14, 2003Date of Patent: October 5, 2004Assignees: Freedom-2, LLC, The General Hospital CorporationInventors: Richard R. Anderson, Susanna K. Mlynarczyk, Craig A. Drill
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Patent number: 6800124Abstract: Water-based chemical indicator inks for ethylene oxide sterilization processes and methods for its use. The chemical indicator ink contains at least one pH indicator dye selected from the group consisting of Bromocresol green, Bromophenol blue, Methyl red, Ethyl orange, and combinations thereof. The pH indicator dye undergoes an irreversible color change when exposed to ethylene oxide vapor in the presence of low-temperature steam, but when exposed to other sterilization processes either does not undergo a color change or undergoes a color change that is different than is obtained when exposed to ethylene oxide.Type: GrantFiled: June 24, 2002Date of Patent: October 5, 2004Assignee: Illinois Tool Works Inc.Inventor: Shobha Shakher Puntambekar
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Patent number: 6793720Abstract: A solid marking composition comprises a solid matrix containing at least one type of optically variable interference pigment flakes. The solid marking composition provides a document or article with a copy and counterfeit protection feature, and is preferably used in a writing instrument for applying hand-written anti-counterfeit markings and signatures.Type: GrantFiled: September 26, 2002Date of Patent: September 21, 2004Assignee: SICPA Holding S.A.Inventors: Edgar Müller, Olivier Rozumek
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Patent number: 6786958Abstract: Provided is an oil based ink for a ball-point pen comprising at least an alcohol-soluble dye, carbon black, a resin and an organic solvent, wherein the carbon black described above has a DBP oil absorption of 80 cc/100 g or less. The carbon black has preferably a particle diameter of 30 m&mgr; or less and a content of 1 to 15 mass % based on the total amount of the ink.Type: GrantFiled: September 6, 2002Date of Patent: September 7, 2004Assignee: Mitsubishi Pencil Kabushiki KaishaInventors: Masaaki Morita, Susumu Suzuki, Toshiaki Takayanagi, Kyoko Kobayashi
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Patent number: 6770687Abstract: A water-based security printing ink is provided with two means of security. The use of a variable light absorbing and/or transmitting pigment or dye is a first security and a water repelling agent is provided as a second security. Visible images can be generated from the printed ink upon exposure to UV or infrared light. The water repelling agent renders the image waterproof and differentiates the printed image from the substrate, which allows the image to be detected upon exposure to water or other aqueous mixture. Suitable inks can be used in conventional printing methods, such as jet printing, lithography, offset printing and impact printing. Also provided are substrates imaged with these security printing inks.Type: GrantFiled: April 5, 1999Date of Patent: August 3, 2004Assignee: NCR CorporationInventors: Yaoping Tan, Maurice W. Lewis
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Publication number: 20040147632Abstract: A water base erasable ink composition for use in marking pens which comprises 0.05-20% by weight of a colorant and 1-20% by weight of an oily material which is nonvolatile at normal temperatures (25° C.) and is dispersed in water, wherein the oily material has a viscosity of 5-40 mPa·s at 20° C. and is dispersed in water in the form of emulsion, and wherein the colorant is dispersed in the water with the aid of a polyvinyl alcohol resin as a dispersing agent which has a saponification degree of 70-85 mol % and of which aqueous solution of 4% concentration has a viscosity of 2-30 mPa·s at 20° C. in a weight ratio of the resin to the colorant of 0.5 to 5 and in an amount of 1 to 10% by weight based on the ink composition.Type: ApplicationFiled: January 14, 2004Publication date: July 29, 2004Inventors: Keiko Nakamura, Hidetoshi Fukuo, Jiro Nakagawa
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Patent number: 6749773Abstract: A phosphorescent ink composition suitable for use with an ink-jet printer and method of producing said composition are provided. The composition includes a mixture of an effective amount of a phosphorescent powder and a liquid ink vehicle. A method of producing the phosphorescent ink-jet ink composition includes the step of mixing an effective amount of a phosphorescent powder with a liquid ink vehicle. The ink composition may optionally include a dispersing agent for maintaining disbursement of the phosphorescent powder in the ink vehicle. The composition may also include a colorant.Type: GrantFiled: April 3, 2001Date of Patent: June 15, 2004Assignee: Hewlett-Packard Development Company, L.P.Inventor: Jeffrey V. Emanuel
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Patent number: 6749676Abstract: Erasable inks are provided for use in a writing instruments. In one aspect, the inks include a solvent, and, dispersed in the solvent as a colorant, a pigment having a flake-like morphology, the ink being substantially free of other colorants.Type: GrantFiled: July 3, 2001Date of Patent: June 15, 2004Assignee: Berol CorporationInventors: Jean L. Spencer, Pawel Czubarow
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Publication number: 20040074419Abstract: Disclosed herein is an ink comprisingType: ApplicationFiled: July 30, 2003Publication date: April 22, 2004Applicant: CANON KABUSHIKI KAISHAInventors: Akira Nagashima, Shinichi Hakamada
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Publication number: 20040069184Abstract: A marking composition is disclosed for placing a temporarily visible mark on a surface. The composition includes a paint base and a pigmented colorant. The pigmented colorant is dispersed within the paint base, and has characteristics that cause the mark to progressively become substantially invisible upon exposure to UV light. Additives, such as UV absorbers and anti-oxidants may be included to alter the rate at which the mark becomes invisible. The pigmented colorant may be a dispersion of dyed melamine-toluenesulfonamide-formaldehyde polymer in a mixture of alkyl based resins and aliphatic hydrocarbons. The colorant may be about 2 to 30 parts by weight of the composition. In one embodiment, the pigmented colorant is a Special Fugitive Colorant, with a color selected from the group consisting of: Special Fugitive Yellow Dispersion, No. 121M6669; Special Fugitive Orange Dispersion, No. 121M6665; Special Fugitive Red Dispersion, No. 121M6850; Special Fugitive Red Dispersion; No.Type: ApplicationFiled: September 17, 2003Publication date: April 15, 2004Inventors: Neil S. Fox, Christopher P. Finke