Six-ring Members In The Heterocyclic Ring Patents (Class 106/31.77)
  • Patent number: 7025814
    Abstract: The present invention relates to an ink-jet ink, an ink-jet recording material or an ink-jet system containing at least one water-soluble hindered amine compounds of the general formula (I) or (II): wherein G1 and G2 are independently alkyl of (1) to (4) carbon atoms or are together pentamethylene; Z1 and Z2 are each methyl, or Z1 and Z2 ?together form an unsubstituted linking moiety or a linking moiety substituted by one or more groups selected from an ester, ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or an urethane group; E is oxyl; X is an inorganic or organic anion; and wherein the local charge of cations h is equal to the total charge of anions j.
    Type: Grant
    Filed: January 8, 2002
    Date of Patent: April 11, 2006
    Assignee: Ciba Specialty Chemicals Corp.
    Inventor: Stéphane Biry
  • Patent number: 7018455
    Abstract: An ink composition, a recording medium or printed matter containing a compound expressed by General Formula 1 The compound has a weight reduction after 1 hour at 60°C. of no more than 1%. This makes it possible to provide the ink composition, a recording medium, printed matter, and an ink jet recording method wherein a light resistance of the printed matter is excellent, there is no ink clogging, and a high-quality image with almost no yellowing of the printed matter can be obtained.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: March 28, 2006
    Assignee: Seiko Epson Corporation
    Inventors: Kazuhiko Kitamura, Yasuhiro Oki, Tetsuya Aoyama, Kyoichi Oka, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
  • Patent number: 7008475
    Abstract: The invention relates to aqueous colorant preparations containing A) between 0.1 and 50 wt. % of at least one organic and/or inorganic pigment and/or at least one organic colorant. B) between 0.01 and 80 wt. % of at least one naphthol-oxyalkylate sulfopropyl ether, one alkanol-oxyalkylate sulfopropyl ether or one alkylphenol-oxyalkylate sulfopropyl ether. C) between 0 and 30 wt. % of at least one organic solvent. D) between 0 and 20 wt. % of other standard derivatives and E) between 10 and 90 wt % of water, respectively in relation to the total weight (100%) of the colorant preparation. The colorant preparation is used, for example, in printing inks, especially ink jet printing inks.
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: March 7, 2006
    Assignee: Clariant GmbH
    Inventors: Rudolf Randler, Ulrike Rohr, Josef Geisenberger, Ruediger Baur, Hans-Tobias Macholdt, Heidemarie Menzel
  • Patent number: 6989056
    Abstract: The present invention relates to IR reflective black pigment compositions comprising a halogenated copper phthalocyanine such as C.I. Pigment Green 7 and a perylenetetracarboxylic acid diimide such as C.I. Pigment Violet 29. The compositions are characterized by an IR reflection spectrum with a positive slope in the wavelength range between 800 and 900 nm when incorporated as coloring agents in coatings or plastics. The inventive IR reflective black pigment compositions are useful for coloring high molecular weight materials like coatings, inks and plastics.
    Type: Grant
    Filed: September 20, 2004
    Date of Patent: January 24, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Bäbler
  • Patent number: 6972304
    Abstract: Disclosed is an aqueous ink composition comprising an aqueous liquid vehicle, a colorant, and an additive wherein, when the ink has been applied to a recording substrate in an image pattern and a substantial amount of the aqueous liquid vehicle has either evaporated from the ink image, hydrogen bonds of sufficient strength exist between the additive molecules so that the additive forms hydrogen-bonded oligomers or polymers.
    Type: Grant
    Filed: September 7, 2001
    Date of Patent: December 6, 2005
    Assignee: Xerox Corporation
    Inventors: Thomas W. Smith, David J. Luca, Kathleen M. McGrane
  • Patent number: 6972310
    Abstract: The present invention provides a golf ball having a marking that can be directly printed on the surface of golf ball body without undercoating treatment when printing the marking and has good appearance and excellent durability after repeated hitting. The present invention relates to a golf ball having a marking printed with an ink composition on the surface thereof, wherein the ink composition comprises epoxy resin having a terminal OH group, polyisocyanate curing agent and a coloring agent as essential components, and the curing agent comprises 25 to 35% by weight of isocyanurate polyisocyanate derived from hexamethylene diisocyanate, 25 to 35% by weight of biuret polyisocyanate derived from hexamethylene diisocyanate and 35 to 50% by weight of isocyanurate polyisocyanate derived from isophorone diisocyanate.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: December 6, 2005
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Kazuhiko Isogawa
  • Patent number: 6946024
    Abstract: An ultraviolet absorber having an acidic group is further added to an ink composition for inkjet recording which contains a colorant, a humectant, water, and a water-soluble substance that is condensation-polymerized in the absence of the water. A radical trapping agent having an acidic group is further added to an ink composition for inkjet recording which contains a colorant, a humectant, water, and a water-soluble substance that is condensation-polymerized in the absence of the water.
    Type: Grant
    Filed: May 15, 2003
    Date of Patent: September 20, 2005
    Assignee: Matsushita Electric Industrial Co. Ltd.
    Inventors: Mamoru Soga, Hidekazu Arase
  • Patent number: 6918955
    Abstract: An ink-jet recording liquid using a dye and a pigment, which is excellent in dispersibility and has good printing performance and storage stability, and a process for producing the same are provided. There are provided an ink-jet recording liquid containing a pigment, a dye and a surfactant which are incorporated in an aqueous medium, characterized in that (1) the pigment and the dye at least partly comprise a pigment and a dye reversibly adsorbed thereon without involving a chemical reaction, (2) the dye reversibly adsorbed on the pigment without involving a chemical reaction contains a dye having a dye adsorption shown by the following formula (1) of 0.02 g/g or more, and (3) as the surfactant, a nonionic surfactant and an anionic surfactant coexist; and a process for producing the same.
    Type: Grant
    Filed: June 23, 2004
    Date of Patent: July 19, 2005
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masanobu Yokoyama, Hisao Takeuchi, Hideaki Tanaka, Kazuhiro Maruyama, Katsuhito Kanazawa
  • Patent number: 6916364
    Abstract: An ink jet recording liquid including a compound represented by the following Formula (1), (2) or (3):
    Type: Grant
    Filed: May 14, 2003
    Date of Patent: July 12, 2005
    Assignee: Konica Corporation
    Inventors: Kyoko Iwamoto, Satoru Ikesu, Takatsugu Suzuki
  • Patent number: 6902607
    Abstract: The ink composition comprises as its coloring matter component a water-based magenta composition containing anthrapyridone compound represented by the formula (1): wherein R represents hydrogen atom or methyl group; X represents phenyl group, phenoxy group or halogen atom; and n is an integer of 1 to 4, or salt thereof.
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: June 7, 2005
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Hiroyuki Matsumoto, Katsunori Fujii, Yasuo Shirasaki
  • Patent number: 6872243
    Abstract: Disclosed is a phase change ink composition comprising an ink vehicle, a colorant, and a nonpolymeric organic gelator selected from the group consisting of anthracene-based compounds, steroid compounds, partially fluorinated high molecular weight alkanes, high molecular weight alkanes with exactly one hetero atom, chiral tartrate compounds, chiral butenolide-based compounds, bis-urea compounds, guanines, barbiturates, oxamide compounds, ureidopyrimidone compounds, and mixtures thereof, said organic gelator being present in the ink in an amount of no more than about 20 percent by weight of the ink, said ink having a melting point at or below which the ink is a solid, said ink having a gel point at or above which the ink is a liquid, and said ink exhibiting a gel state between the melting point and the gel point, said ink exhibiting reversible transitions between the solid state and the gel state upon heating and cooling, said ink exhibiting reversible transitions between the gel state and the liquid state upon
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: March 29, 2005
    Assignee: Xerox Corporation
    Inventors: Marcel P. Breton, Danielle C. Boils-Boissier, Donald R. Titterington, Jule W. Thomas, Jr., Jeffrey H. Banning, Christine E. Bedford, James D. Wuest
  • Patent number: 6872245
    Abstract: This invention relates to azo pigments of general formula (I) wherein D represents the radical of a diazo component; R1 and R2 are the same or different and represent hydrogen, a C1-C4 alkyl radical which is optionally substituted by hydroxy, amino, halogen or methoxy, or a (C6-C10) aryl radical which is optionally substituted by one, two or three substituents from the group C1-C4 alkyl, C1-C4 alkoxy, F, Cl, Br, CF3, NO2, OH, CONH2, CONH(C1-C4 alkyl), CON(C1-C4 alkyl)2, COO(C1-C4 alkyl), SO2NH2, SO2NH(C1-C4 alkyl) and SO2N(C1-C4 alkyl)2, provided that R1 and R2 do not simultaneously represent hydrogen; R4 represents hydrogen, C1-C4 alkyl, halogen, trifluoromethyl, C1-C4 alkoxy, NO2, or CN; and n represents 1, 2 or 3
    Type: Grant
    Filed: July 24, 2002
    Date of Patent: March 29, 2005
    Assignee: Clariant GmbH
    Inventors: Felix W. Grimm, Hans Joachim Metz, Andreas Wacker
  • Patent number: 6860928
    Abstract: Disclosed are compounds of the formulae wherein Z is a group of the formula —OR1, a group of the formula —SR1, or a group of the formula —NR1R2, Y is a group of the formula —OR3, a group of the formula —SR3, or a group of the formula —NR3R4, n is an integer representing the number of repeat —(CH2)— or —(CH2CH2O)— units, wherein, provided that at least one of R1, R2, R3, R4, R5, and R6 is a hydrogen atom, provided that at least one of R1, R2, R3, R4, R5, and R6 is other than a hydrogen atom, and provided that at least one Z or Y within the compound is a group of the formula —NR1R2 or a group of the formula —NR3R4, R1, R2, R3, R4, R5, R6, and R7 each, independently of the others, is (i) a hydrogen atom, (ii) an alkyl group, (iii) an aryl group, (iv) an arylalkyl group, or (v) an alkylaryl group, and wherein R7 can also be (vi) an alkoxy group, (vii) an aryloxy group, (Viii) an arylalkyloxy group, (ix) an alkylaryloxy group, (x) a polyalkyleneoxy group, (xi) a polyaryleneoxy group, (xii) a polyarylalkylen
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: March 1, 2005
    Assignee: Xerox Corporation
    Inventors: Marcel P. Breton, Danielle C. Boils-Boissier, Jule W. Thomas, Jr., Donald R. Titterington, H. Bruce Goodbrand, Jeffrey H. Banning, James D. Wuest, Dominic Laliberte, Marie-Eve Perron
  • Patent number: 6855193
    Abstract: An ink jet ink composition of water, humectant and a self-assembling colorant that is capable of spontaneously forming a nanoparticulate dispersion without any prior physical attrition or surface modification, the colorant having the formula: (A)m—Q—(Z)n wherein: Q represents a chromophore; each A independently represents an organic or inorganic group capable of hydrogen bonding or other non-covalent bonding; each Z independently represents an organic or inorganic group capable of electrostatic bonding; and m and n each independently represents an integer from 0 to 10; with the proviso that n+m is at least 1; and with the further proviso that at least about 50 wt. % of the colorant is present in the composition as particles.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: February 15, 2005
    Assignee: Eastman Kodak Company
    Inventors: Andrei Andrievsky, David T. Southby, Steven Evans, Dale E. Decann
  • Patent number: 6852154
    Abstract: The invention provides: an ink set comprising a yellow ink composition, a magenta ink composition, and a cyan ink composition, wherein the magenta ink composition contains as a colorant at least one member selected from compounds represented by the following formula (1) and salts thereof; and an ink set comprising two magenta ink compositions differing in color density, wherein the magenta ink composition having a lower color density contains as a colorant at least one member selected from compounds represented by the following formula (1) and salts thereof. Also disclosed are: an ink cartridge housing the ink set; a process for recording with the ink set; and recorded matter obtained by recording with the ink set.
    Type: Grant
    Filed: April 21, 2003
    Date of Patent: February 8, 2005
    Assignee: Seiko Epson Corporation
    Inventors: Kazuhiko Kitamura, Hiroko Hayashi, Kyoichi Oka
  • Patent number: 6849110
    Abstract: For providing an ink composition which can reduce matamerizm while reducing the total amount of inks used when such ink composition is simultaneously used with another ink composition, and prevent reduction of the image quality, the present invention provides an ink composition wherein the difference between the maximum value and the minimum value of the reflectance of an output color through an ink jet output over a light source wavelength range of 400 to 700 nm, in which such output color satisfies formulae (1), (2) and (3) below at a spatial coordinate (L* a* b*) stipulated by CIE under the D 50 light source is not more than 20%: (1) 45?L*?55 (2) ?10<a*<10 (3) ?10<b*<10
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: February 1, 2005
    Assignee: Seiko Epson Corporation
    Inventor: Tsuyoshi Sano
  • Patent number: 6846351
    Abstract: An ink jet recording liquid including a compound represented by the following Formula (1), (2) or (3):
    Type: Grant
    Filed: May 7, 2003
    Date of Patent: January 25, 2005
    Assignee: Konica Corporation
    Inventors: Kyoko Iwamoto, Satoru Ikesu, Takatsugu Suzuki
  • Patent number: 6838513
    Abstract: A golf ball 1 has a core 2, a cover 3, a mark layer 4, and a finishing coat layer 5. An ink used for the mark layer 4 includes an isocyanate curing agent that contains a diisocyanate trimer, a base material, and a colorant. Preferred curing agent contains an isophorone diisocyanate trimer. The ink includes a diisocyanate curing agent at equal to or greater than 1% by weight and equal to or less than 20% by weight, calculated on the basis of the solid content. The base material includes a polymer having a hydroxyl group as a principal component. The “NCO/OH” value, which is a ratio of isocyanate groups of the isocyanate curing agent and hydroxyl groups of the base material, is equal to or greater than 0.5 and equal to or less than 2.0. The mark layer 4 may be printed on a base coat layer, alternatively, may be printed on a crosslinked rubber. This ink has excellent adhesiveness to a base.
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: January 4, 2005
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Yoshiyuki Okido, Satoru Komatsu, Hiroaki Tanaka, Kazuhisa Fushihara
  • Publication number: 20040261657
    Abstract: A phase change ink composition comprising a phase change ink carrier and a colorant compound of the formula 1
    Type: Application
    Filed: June 26, 2003
    Publication date: December 30, 2004
    Applicant: Xerox Corporation
    Inventors: Bo Wu, Jeffery H. Banning, James M. Duff, Wolfgang G. Wedler, Jule W. Thomas, Randall R. Bridgeman
  • Publication number: 20040244645
    Abstract: The present invention provides an ink set for ink jet recording using at least two kinds of liquids. The first liquid contains at least a colorant, a water soluble solvent and water, and the second liquid contains at least a compound represented by the following general formula (1), a water soluble solvent and water. The present invention also provides an ink jet recording apparatus comprising a recording head from which the ink set for ink jet recording is ejected, and an ink jet recording method by which an image is formed by applying the first and second liquids on a recording medium so as to contact each other.
    Type: Application
    Filed: June 4, 2004
    Publication date: December 9, 2004
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Takatsugu Doi, Chizuru Koga, Takashi Ogino, Kiyoshi Hosoi, Tsukasa Matsuda
  • Patent number: 6827768
    Abstract: An ink jet printing process having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink jet recording elements having a support having thereon an image-receiving layer; C) loading the printer with an ink jet ink composition of water, humectant and a self-assembling colorant that is capable of spontaneously forming a nanoparticulate dispersion without any prior physical attrition or surface modification, the colorant having the formula: (A)m—Q—(Z)n wherein: Q represents a chromophore; each A independently represents an organic or inorganic group capable of hydrogen bonding or other non-covalent bonding; each Z independently represents an organic or inorganic group capable of electrostatic bonding; and m and n each independently represents an integer from 0 to 10; with the proviso that n+m is at least 1; and with the further proviso that at least about 50 wt.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: December 7, 2004
    Assignee: Eastman Kodak Company
    Inventors: Andrei Andrievsky, David T. Southby, Steven Evans, Dale E. Decann
  • Publication number: 20040237842
    Abstract: The invention pertains to the field of green colour filters and LCDs. It has been found that pigments with surprisingly improved coloristic, chemical and physical properties are obtained by salt-kneading a halogenated phthalocyanine pigment together with a yellow pigment of the disazo condensation, barbituric acid or azoquinolone series. The process takes place in the presence of an organic liquid and in the absence of binder or optionally in the presence of a relatively small amount of binder. Claimed are the process itself as well as the green pigment composition obtained by the process and compositions comprising it.
    Type: Application
    Filed: April 6, 2004
    Publication date: December 2, 2004
    Inventors: Veronique Hall-Goulle, Takashi Deno
  • Publication number: 20040237837
    Abstract: A lightfast additive and an ink composition including the same include a benzophenone moiety for lightfastness and a moiety for wettability and the ability to stabilize a colorant, wherein the two moieties are covalently bonded. The lightfast additive may exhibit effective ultraviolet (UV) light absorption capacity, effective wettability, and an ability to stabilize a colorant. The ink composition utilizing the light fast additive thus has an improved lightfastness and long-term storage stability.
    Type: Application
    Filed: May 24, 2004
    Publication date: December 2, 2004
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Kyung-hoon Lee, Seung-min Ryu, Yeon-kyoung Jung
  • Patent number: 6811595
    Abstract: Compounds of the formulae wherein, provided that at least one of R1, R2, and R3 is not a hydrogen atom, R1, R2 and R3 each, independently of the other, is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, and wherein R1 and R2 can also be alkoxy, aryloxy, arylalkyloxy, alkylaryloxy, polyalkyleneoxy, polyaryleneoxy, polyarylalkyleneoxy, polyalkylaryleneoxy, silyl, siloxane, polysilylene, polysiloxane, or a group of the formula wherein r and s are integers representing a number of repeat —CH2— groups, and wherein X is a direct bond, oxygen, sulfur, —NR40— wherein R40 is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, or —CR50R60— wherein R50 and R60 each, independently of the other, is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, and R10 and R11 each, independently of the other, is alkylene, arylene, arylalkylene, or alkylarylene, and wherein R10 can also be polyalkyleneoxy, polyaryleneoxy, polyarylalkyleneoxy, polyalkylaryleneoxy, silylen
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: November 2, 2004
    Assignee: Xerox Corporation
    Inventors: Danielle C. Boils-Boissier, Marcel P. Breton, Jule W. Thomas, Jr., Donald R. Titterington, Jeffrey H. Banning, H. Bruce Goodbrand, James D. Wuest, Marie-Eve Perron, Hugues Duval
  • Patent number: 6811597
    Abstract: An ink composition and/or a recording medium are made to contain a compound expressed by general formula (1) and a hydrazide compound. An ink composition thereby obtained does not clog and the ink composition and recording medium thus obtained can offer high quality images that hardly cause yellowing of the resulting recording with superior light resistance. Recording and an inkjet recording method pertaining thereto are also provided.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: November 2, 2004
    Assignee: Seiko Epson Corporation
    Inventors: Yasuhiro Oki, Kazuhiko Kitamura, Tetsuya Aoyama, Kyoichi Oka, Nobuo Uotani, Hiroshi Takahashi, Yuji Ito
  • Publication number: 20040206271
    Abstract: The invention relates to aqueous colorant preparations containing A) between 0.1 and 50 wt. % of at least one organic and/or inorganic pigment and/or at least one organic colorant. B) between 0.01 and 80 wt. % of at least one naphthol-oxyalkylate sulfopropyl ether, one alkanol-oxyalkylate sulfopropyl ether or one alkylphenol-oxyalkylate sulfopropyl ether. C) between 0 and 30 wt. % of at least one organic solvent. D) between 0 and 20 wt. % of other standard derivatives and E) between 10 and 90 wt % of water, respectively in relation to the total weight (100%) of the colorant preparation. The colorant preparation is used, for example, in printing inks, especially ink jet printing inks.
    Type: Application
    Filed: January 8, 2004
    Publication date: October 21, 2004
    Inventors: Rudolf Randler, Ulrike Rohr, Josef Geisenberger, Ruediger Baur, Hans-Tobias Macholdt, Heidemarie Menzel
  • Publication number: 20040182279
    Abstract: A lightfast colorant and a lightfast ink composition include a lightfast colorant that is derived by covalently binding a benzophenone derivative and a conventional colorant and that imparts effective lightfastness and long-term storage stability to an ink composition that is prepared with the same.
    Type: Application
    Filed: March 18, 2004
    Publication date: September 23, 2004
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Kyung-hoon Lee, Seung-min Ryu, Yeon-kyoung Jung
  • Patent number: 6793722
    Abstract: Inkjet ink composition with high chroma. The inkjet ink composition includes 0.1 to 15 weight % of Acid Red 92; at least one red colorant other than Acid Red 92; and an aqueous solution medium. By means of the addition of Acid Red 92, the chroma of magenta color of the ink composition is increased.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: September 21, 2004
    Assignee: Benq Corporation
    Inventors: Chia-Hsin Chien, In-Shan Sir, Yu-Ting Lin
  • Publication number: 20040170779
    Abstract: The present invention relates to an ink jet ink, an ink jet recording material or an ink jet system comprising at least one compound selected from the group consisting of a) the dialkyl hydroxylamine stabilizers, b) the nitrone stabilizers and c) the amine oxide stabilizers. The present stabilizer compounds provide ink jet prints with outstanding light stability, gas fade stability and dark storage stability. The hydroxylamines are for example N,N-dihydrocarbylhydroxylamines of the formula R1R2N—OH, wherein R1 and R2 are independently benzyl, methyl, ethyl, octyl, lauryl, dodecyl, tetradecyl, hexadecyl, heptadecyl or octadecyl, or wherein R1 and R2 are each the alkyl mixture found in hydrogenated tallow amine. The nitrone and amine oxide stabilizers are for example nitrone and amine oxide analogues of the dialkylhydroxylamine stabilizers.
    Type: Application
    Filed: January 21, 2004
    Publication date: September 2, 2004
    Inventors: Mervin G. Wood, Joseph Suhadolnik, Ramanathan Ravichandran, Sai P. Shum
  • Publication number: 20040163569
    Abstract: The present invention describes methods for preparing aqueous colored pigment dispersions comprising the step of combining, in any order, a) a colored pigment, b) an azo coupler, c) an aromatic amine, d) a diazotizing agent, and e) an aqueous medium, wherein the aromatic amine comprises as least one ionic group, at least one ionizable group, or a mixture of at least one ionic group and at least one ionizable group. These colored pigment dispersions are particularly useful as an inkjet ink composition.
    Type: Application
    Filed: January 16, 2004
    Publication date: August 26, 2004
    Inventor: Alexander I. Shakhnovich
  • Patent number: 6780229
    Abstract: A composition comprising: a) 0.1 to 30 parts of colorant; b) 0.1 to 20 parts of a compound of Formula (1): R1R2N—Ar—(SO3X)n  Formula (1) wherein: R1 is H, alkyl, cycloalkyl or aralkyl and R2 is alkyl, cycloalkyl or aralkyl; or R1 and R2, together with the N atom to which they are attached, form a 5- or 6-membered ring; Ar is phenylene or naphthylene; X is H or a cation; and n is 1 or 2; c) 1 to 40 parts of organic solvent; d) 0 to 20 parts of hydrotropic agent; e) 0 to 5 parts of biocide; f) 0 to 5 parts of surfactant; and g) 1 to 98.8 parts of water; wherein all parts are by weight and a)+b)+c)+d)+e)+f)+g) add up to 100. Also claimed are inks comprising these compositions, ink jet printer cartridges containing these inks, their use in ink jet printing especially where the temperature of application is greater than 30° C. and substrates printed with these compositions or inks.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: August 24, 2004
    Assignee: Avecia Limited
    Inventors: Alan John Hopper, William Albert Fern
  • Patent number: 6761758
    Abstract: Disclosed are compounds of the formulae wherein, provided that at least one of R1, R2, R3, R4, R5, and R6 is a hydrogen atom, and provided that at least one of R1, R2, R3, R4, R5, and R6 is not a hydrogen atom, R1, R2, R3, R4, R5, and R6 each, independently of the others, is (i) a hydrogen atom, (ii) an alkyl group, (iii) an aryl group, (iv) an arylalkyl group, or (v) an alkylaryl group. Also disclosed are phase change ink compositions comprising a colorant and a phase change ink carrier comprising a material of this formula.
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: July 13, 2004
    Assignee: Xerox Corporation
    Inventors: Danielle C. Boils-Boissier, Marcel P. Breton, Jule W. Thomas, Jr., Donald R. Titterington, Jeffrey H. Banning, H. Bruce Goodbrand, James D. Wuest, Marie-Eve Perron, Francis Monchamp, Hugues Duval
  • Patent number: 6759459
    Abstract: The present invention is drawn to colorless toner compositions for overcoating a print having an ink jet ink image printed thereon. The colorless toner can comprise: a toner resin and at least two additives independently selected from the group consisting of ultraviolet absorbers, free radical inhibitors, thermal stabilizers, and combinations thereof, wherein the ratio of toner resin to total additive is from 1:1 to 99:1 by weight. The colorless toner can also be comprised of a charge control agent and/or a low-melt wax.
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: July 6, 2004
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: An-Chung Robert Lin, Michael H. Lee
  • Patent number: 6756487
    Abstract: Monoazoquilolone pigments which, in one of the tautomeric forms thereof, correspond to formula (1), wherein Ar is a radical of formula (2a), (2b), (2c), (2d), 2(e) or (2f) wherein R1 is C1-C4alkyl, R2 and R3 are each independently of the other hydrogen, halogen, C1-C4alkyl, carboxy, sulfo, cyano, C1-C4alkoxycarbonal, C1-C4alkylcarbonyl, C1-C4alkanoylamino, benzoylamino that is unsubstituted or substituted in the phenyl ring by halogen, nitro, C1-C4alkyl or by C1 -C4alkoxy; carbamoyl, N-C1-C4alkylaminocarbonyl, N-arylaminocarbonyl that is unsubstituted or substituted in the aryl moiety by halogen, nitro, C1-C4alkyl or by C1-C4alkoxy; N,N-di-C1-C4alkylaminocarbonyl, C1-C4alkoxysulfonyl, C1-C4alkylsulfonyl, sulfamoyl, N-C1-C4alkylaminosulfonyl, N-arylaminosulfonyl that is unsubstituted or substituted in the aryl moiety by halogen, nitro, C1-C4alkyl or by C1-C4alkoxy; or N,N-di-C1-C4alkylaminosulfonyl, wherein carboxy and sulfo are in the form of the free acid or in salt form, R8and R9are each independently of th
    Type: Grant
    Filed: September 2, 2003
    Date of Patent: June 29, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Johannes Benkhoff, Olof Wallquist, Tetsuo Hyuga, Gerardus De Keyzer
  • Patent number: 6755902
    Abstract: Disclosed is a phase change ink composition comprising a phase change ink carrier and a colorant compound of the formula
    Type: Grant
    Filed: June 27, 2002
    Date of Patent: June 29, 2004
    Assignee: Xerox Corporation
    Inventors: Jeffrey H. Banning, Bo Wu, James D. Mayo, James M. Duff, Rina Carlini, Jule W. Thomas, Jr., Paul F. Smith
  • Patent number: 6746526
    Abstract: 1. A compound of Formula (1) and salts thereof: wherein: A is a substituted phenyl group carrying a group of the formula —NR3R4 and an ortho group selected from sulpho, phosphonato and phosphinato; n is 0 or 1; L1 and L2 are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or L1 and L2 together with the N atom to which they are attached form an optionally substituted 5- or 6-membered ring; R1 and R2 are each independently optionally substituted alkyl or optionally substituted alkoxy; and R3 and R4 are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or R3 and R4 together with the nitrogen atom to which they are attached form an optionally substituted 5- or 6-membered ring; or R3 is H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl and R4 is an acyl group.
    Type: Grant
    Filed: March 27, 2002
    Date of Patent: June 8, 2004
    Assignee: Avecia Limited
    Inventor: Prahalad Manibhai Mistry
  • Publication number: 20040099180
    Abstract: An aqueous ink composition which comprises a compound represented by the formula (1) or the salt thereof: (1) wherein R1 and R2 independently represent a hydrogen atom, an alkyl group, an alkoxy group, an alkanoylamino group, an alkoxyalkoxy group, a sulfonic acid group, a carboxyl group or an ureido group, m and n independently represent 1 or 2, and M1 represents a cation from a hydrogen atom, an alkali metal, an alkaline earth metal or an organic amine, or an ammonium ion. The composition has a hue and clarity suitable for the ink-jet recording, and can provide a recorded matter which is excellent in light resistance, water resistance and moisture resistance and can be controlled with respect to the degree of the discoloration or fading by the action of ozone.
    Type: Application
    Filed: December 17, 2003
    Publication date: May 27, 2004
    Inventors: Hirokazu Kitayama, Yasuo Shirasaki, Toru Tabei
  • Publication number: 20040099181
    Abstract: An ink characterized by containing at least one compound selected from phthalocyanine compounds represented by the general formulae (I), (II), (III) and (IV) has an absorption characteristic superior in color reproducibility as dyes of three primary colors and has sufficient fastness to light, heat, humidity, and active gases in an environment, and hence, can give colored images or colored materials having superior46. The ink can be used for various coloring compositions such as ink compositions for inkjet printing, ink sheets in thermal transfer image-forming materials, coloring compositions for color filters in electrophotographic toners, LCD, PDP, and CCD, and dyeing baths for dyeing various fibers.
    Type: Application
    Filed: October 31, 2003
    Publication date: May 27, 2004
    Inventors: Keiichi Tateishi, Masaki Noro, Yoshiharu Yabuki, Tadashi Omatsu
  • Patent number: 6736888
    Abstract: A compound comprising a disazo chromophore and an optionally substituted heterocyclic group linked together through a —SO2—NH— group, inks comprising these compounds, ink jet printer cartridges containing these inks and their use in ink jet printing.
    Type: Grant
    Filed: March 18, 2002
    Date of Patent: May 18, 2004
    Assignee: Avecia Limited
    Inventor: Mark Robert James
  • Publication number: 20040089198
    Abstract: A process for coloration of a substrate comprising applying thereto by means of an ink jet printer a composition comprising a medium and a compound of Formula (1): 1
    Type: Application
    Filed: September 11, 2003
    Publication date: May 13, 2004
    Inventors: Christine Millard, Clive Edwin Foster, Peter Gregory
  • Publication number: 20040083924
    Abstract: Compouns of formula (I) 1
    Type: Application
    Filed: August 1, 2003
    Publication date: May 6, 2004
    Inventor: Martin Oberholzer
  • Publication number: 20040081761
    Abstract: An inkjet ink having an increased shelf life. The inkjet ink comprises an ink vehicle and a reactive colorant. The reactive colorant is nonreactive with water,,thereby increasing the shelf life of the inkjet ink to greater than approximately twelve months. An inkjet printing system comprising the inkjet ink and an activating agent is also disclosed. A reactive colorant of the inkjet ink is nonreactive with water but is sufficiently reactive with the activating agent to form an activated complex to fix the reactive colorant to a textile substrate. A method of printing on a textile substrate is also disclosed.
    Type: Application
    Filed: October 25, 2002
    Publication date: April 29, 2004
    Inventor: David Tyvoll
  • Patent number: 6726762
    Abstract: A finely divided pigment is formed of an aggregate of primary particles. A number of primary particles of not greater than 0.1 &mgr;m in particle size is at least 95% of an entire number of the primary particles, and a number of primary particles of greater than 0.1 &mgr;m in particle size is at most 5% of the entire number of the primary particles. The finely divided pigment can be produced by grinding a parent pigment (pre-division pigment) together with a water-soluble inorganic salt and a water-soluble organic solvent in a grinding machine at a temperature of from 30 to 90° C. for 2 to 6 hours under a load, and then removing the water-soluble inorganic salt and the water-soluble organic solvent. A coloring composition comprises a dispersing medium and the finely divided pigment dispersed in the dispersing medium.
    Type: Grant
    Filed: June 27, 2002
    Date of Patent: April 27, 2004
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Hisao Okamoto, Yutaka Nakagawa, Yoshiyuki Zama, Koji Tsuchiya, Shotoku Takami, Yoshio Abe, Michiei Nakamura
  • Publication number: 20040075723
    Abstract: Disclosed are compounds of the formulae 1 2
    Type: Application
    Filed: September 4, 2002
    Publication date: April 22, 2004
    Applicant: Xerox Corporation
    Inventors: Marcel P. Breton, Danielle C. Boils-Boissier, Jule W. Thomas, Donald R. Titterington, H. Bruce Goodbrand, Jeffrey H. Banning, James D. Wuest, Dominic Laliberte, Marie-Eve Perron
  • Publication number: 20040069184
    Abstract: A marking composition is disclosed for placing a temporarily visible mark on a surface. The composition includes a paint base and a pigmented colorant. The pigmented colorant is dispersed within the paint base, and has characteristics that cause the mark to progressively become substantially invisible upon exposure to UV light. Additives, such as UV absorbers and anti-oxidants may be included to alter the rate at which the mark becomes invisible. The pigmented colorant may be a dispersion of dyed melamine-toluenesulfonamide-formaldehyde polymer in a mixture of alkyl based resins and aliphatic hydrocarbons. The colorant may be about 2 to 30 parts by weight of the composition. In one embodiment, the pigmented colorant is a Special Fugitive Colorant, with a color selected from the group consisting of: Special Fugitive Yellow Dispersion, No. 121M6669; Special Fugitive Orange Dispersion, No. 121M6665; Special Fugitive Red Dispersion, No. 121M6850; Special Fugitive Red Dispersion; No.
    Type: Application
    Filed: September 17, 2003
    Publication date: April 15, 2004
    Inventors: Neil S. Fox, Christopher P. Finke
  • Publication number: 20040065227
    Abstract: Disclosed is a phase change ink composition comprising an ink vehicle, a colorant, and a nonpolymeric organic gelator selected from the group consisting of anthracene-based compounds, steroid compounds, partially fluorinated high molecular weight alkanes, high molecular weight alkanes with exactly one hetero atom, chiral tartrate compounds, chiral butenolide-based compounds, bis-urea compounds, guanines, barbiturates, oxamide compounds, ureidopyrimidone compounds, and mixtures thereof, said organic gelator being present in the ink in an amount of no more than about 20 percent by weight of the ink, said ink having a melting point at or below which the ink is a solid, said ink having a gel point at or above which the ink is a liquid, and said ink exhibiting a gel state between the melting point and the gel point, said ink exhibiting reversible transitions between the solid state and the gel state upon heating and cooling, said ink exhibiting reversible transitions between the gel state and the liquid state upon
    Type: Application
    Filed: September 4, 2002
    Publication date: April 8, 2004
    Applicant: Xerox Corporation
    Inventors: Marcel P. Breton, Danielle C. Boils-Boissier, Donald R. Titterington, Jule W. Thomas, Jeffrey H. Banning, Christine E. Bedford, James D. Wuest
  • Publication number: 20040060474
    Abstract: Disclosed are compounds of the formulae 1
    Type: Application
    Filed: September 4, 2002
    Publication date: April 1, 2004
    Applicant: Xerox Corporation
    Inventors: Danielle C. Boils-Boissier, Marcel P. Breton, Jule W. Thomas, Donald R. Titterington, Jeffrey H. Banning, H. Bruce Goodbrand, James D. Wuest, Marie-Eve Perron, Hugues Duval
  • Publication number: 20040050290
    Abstract: An ink jet ink composition of water, humectant and a self-assembling colorant that is capable of spontaneously forming a nanoparticulate dispersion without any prior physical attrition or surface modification, the colorant having the formula: (A)m-Q-(Z)n wherein: Q represents a chromophore; each A independently represents an organic or inorganic group capable of hydrogen bonding or other non-covalent bonding; each Z independently represents an organic or inorganic group capable of electrostatic bonding; and m and n each independently represents an integer from 0 to 10; with the proviso that n+m is at least 1; and with the further proviso that at least about 50 wt. % of the colorant is present in the composition as particles.
    Type: Application
    Filed: August 30, 2002
    Publication date: March 18, 2004
    Applicant: Eastman Kodak Company
    Inventors: Andrei Andrievsky, David T. Southby, Steven Evans, Dale E. Decann
  • Publication number: 20040050295
    Abstract: Disclosed are compounds of the formulae 1
    Type: Application
    Filed: September 4, 2002
    Publication date: March 18, 2004
    Applicant: Xerox Corporation
    Inventors: Danielle C. Boils-Boissier, Marcel P. Breton, Jule W. Thomas, Donald R. Titterington, Jeffrey H. Banning, H. Bruce Goodbrand, James D. Wuest, Marie-Eve Perron, Francis Monchamp, Hugues Duval
  • Publication number: 20040045477
    Abstract: An ink jet printing process having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink jet recording elements having a support having thereon an image-receiving layer; C) loading the printer with an ink jet ink composition of water, humectant and a self-assembling colorant that is capable of spontaneously forming a nanoparticulate dispersion without any prior physical attrition or surface modification, the colorant having the formula: (A)m-Q-(Z)n wherein: Q represents a chromophore; each A independently represents an organic or inorganic group capable of hydrogen bonding or other non-covalent bonding; each Z independently represents an organic or inorganic group capable of electrostatic bonding; and m and n each independently represents an integer from 0 to 10; with the proviso that n+m is at least 1; and with the further proviso that at least about 50 wt.
    Type: Application
    Filed: August 30, 2002
    Publication date: March 11, 2004
    Applicant: Eastman Kodak Company
    Inventors: Andrei Andrievsky, David T. Southby, Steven Evans, Dale E. Decann