Silicon Or Aluminum Compound Containing Patents (Class 106/431)
  • Patent number: 6648957
    Abstract: Multilayer pearl lustre pigment on the basis of a platelet-shaped substrate comprising a material of low refractive index in the range from 1.35 to 1.8, which comprises at least (i) one first layer comprising a material having a refractive index of more than 1.8, (ii) optionally, a second layer comprising a material of low refractive index in the range from 1.35 to 1.8, (iii) a semitransparent metal layer which is applied to the substrate or to the layers (i) or (ii), and (iv) if desired, an aftercoating, the substrate being platelet-shaped silicon dioxide, aluminium oxide, boron oxide or magnesium fluoride.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: November 18, 2003
    Assignee: Merck Patent GmbH
    Inventors: Stephanie Andes, Gerald Fuchs-Pohl, Gerhard Pfaff
  • Patent number: 6616746
    Abstract: The titanium dioxide pigment of this invention has on the titanium dioxide particle surface a coating layer comprising a polyhydric alcohol and a hydrolysis product of an aminosilane compound, has a dispersibility of not more than 20 kg/cm2 as judged in terms of resin pressure increase, and is excellent in hydrophobicity and dispersibility. The pigment is useful as a coloring agent for plastics which requires good lacing resistance and dispersibility.
    Type: Grant
    Filed: June 13, 2002
    Date of Patent: September 9, 2003
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Hideo Takahashi, Eiji Yamada, Toshihiko Akamatsu, Takeshi Fujimura
  • Patent number: 6596061
    Abstract: Inorganic anti-corrosive pigments consist of surface-coated solids having a grain size of 0.1 to 75 &mgr;m. In order to improve the resistance of the paints and coatings containing such pigments, firstly Mn3(PO4)2 and secondly aluminium oxides and/or aluminium hydroxides are precipitated onto the solids.
    Type: Grant
    Filed: May 4, 2001
    Date of Patent: July 22, 2003
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventor: Thomas Rentschler
  • Patent number: 6576052
    Abstract: The titanium dioxide pigment of the present invention comprises titanium dioxide particles, the coating layer containing the aluminum phosphate compound and the coating layer containing the hydrolyzate of the organosilane compound, on the surface of the particles, in which a difference in water content between 100° C. and 300° C., determined by the Karl Fischer method, is not greater than 1500 ppm, and is thus excellent in light fastness, hydrophobicity and dispersibility. In particular, the titanium dioxide pigment of the invention is extremely advantageous as a colorant for plastics, which requires light fastness (resistance to discoloration) lacing resistance and dispersibility, to a high degree.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: June 10, 2003
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Hideo Takahashi, Masaki Shimojo, Toshihiko Akamatsu
  • Patent number: 6533857
    Abstract: Luster pigments based on multiply coated reflecting platelet-shaped substrates and comprising at least one layer packet comprising A) a low refractive coating which selectively absorbs visible light and B) a reflective coating which is at least partially transparent to visible light and also, if desired, C) an outer protective layer.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: March 18, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Arno Böhm, Oliver Seeger, Norbert Mronga, Thorsten Clemens
  • Patent number: 6517627
    Abstract: Additive pigments having a box-shape spectral distribution are provided. These pigments are characterized in that they are pigment powders which respectively have a high reflectance in the regions corresponding to the three primary colors of light, and comprise three pigments respectively having the three primary colors of light (red, green, and blue), and that when these pigments of the three colors are mixed together, each pigment is subjected to additive color mixing.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: February 11, 2003
    Assignees: Nittetsu Mining Co., Ltd.
    Inventors: Takafumi Atarashi, Katsuto Nakatsuka
  • Patent number: 6488758
    Abstract: The invention relates to a pearl luster pigment which may possess a first, inner layer, consisting of a platelet-shaped substrate, a second layer, comprising one or more metal oxides, the first and second layers forming a calcined base pigment, a third layer, comprising the corresponding uncalcined oxide, hydroxide or oxide hydrate of the oxide of the second layer, a fourth layer, comprising oxides, hydroxides and/or oxide hydrates of silicon or aluminum, a fifth layer, comprising oxides, hydroxides and/or oxide hydrates of silicon, aluminum, zirconium and/or cerium, this layer differing from the fourth layer, and a sixth layer, comprising one or more organofunctional coupling reagents. The present invention relates to also a preparation process, and the use of the pigments in paints, inks, plastics, coatings and cosmetics.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: December 3, 2002
    Assignee: Merck Patent Gesellschaft mit beschraenkter Haftung
    Inventors: Ralf Glausch, Marita Jekel
  • Patent number: 6488757
    Abstract: The present invention relates to a pearl luster pigment on the basis of a platelet-shaped substrate coated with metal oxides and a top layer which is located on the metal oxide layer and can possess a multilayer structure, comprising a first layer, containing a hydroxide or oxide hydrate of the elements aluminum or silicon, a second layer, containing at least one hydroxide or oxide hydrate of the elements aluminum, silicon, cerium or zirconium, with the exception of the hydroxide or oxide hydrate which forms the first layer, and a third layer, containing at least one organic hydrophobic coupling agent. The present invention also relates to a preparation process and the use of pigments in paints, inks, plastics, coatings and cosmetics.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: December 3, 2002
    Assignee: Merck Patent Gesellschaft mit beschraenker Haftung
    Inventor: Ralf Glausch
  • Patent number: 6458197
    Abstract: The present invention relates to a pigment based on bismuth vanadate with a bright vivid yellow to orange color exhibiting improved resistance, in particular an improved resistance to heat, characterized in that it is coated with several layers of inorganic compounds in several successive stages, the last layer being based on a zinc and boron compound. The present invention also relates to the process for producing this pigment and to its application.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: October 1, 2002
    Assignee: Gebroeders Cappelle, N.V.
    Inventors: Frank Vermoortele, Emile Joseph Buyse
  • Patent number: 6440208
    Abstract: A color effect material is composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with copper, zinc, an alloy of copper, or an alloy of zinc first layer which acts as a reflector to light directed thereon, a second layer encapsulating the first layer in which the second layer provides an optically variable reflection of light impinging thereon and a third layer encapsulating the second layer and being selectively transparent to light directed thereon.
    Type: Grant
    Filed: November 6, 2000
    Date of Patent: August 27, 2002
    Assignee: Engelhard Corporation
    Inventors: James D. Christie, Daniel S. Fuller, Curtis J. Zimmermann
  • Patent number: 6409815
    Abstract: Surface-modified conductive pigment obtainable by partial coating of a conductive pigment with an organic modifying agent. The modifying agent is an organometallic compound of the elements silicon, tin, titanium, zirconium or aluminum. The pigment is prepared by dispersing a conductive pigment, subsequently adding the modifying agent, if appropriate as a mixture with a solvent, to the pigment dispersion, and in particular in an amount such that the powder electrical conductance of the partly coated conductive pigment is in the range between 80% of the starting value and 10−7 S, removing the solvent present, if appropriate, with further agitation and heating of the pigment to 100° C. and finally drying the partly coated pigment.
    Type: Grant
    Filed: April 5, 1995
    Date of Patent: June 25, 2002
    Assignee: Merck Patent Gesellschaft mit beschraenkter Haftung
    Inventors: Alfred Hennemann, Manfred Kieser
  • Patent number: 6387498
    Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: May 14, 2002
    Assignee: Flex Products, Inc.
    Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
  • Patent number: 6383638
    Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: May 7, 2002
    Assignee: Flex Products, Inc.
    Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
  • Patent number: 6270566
    Abstract: A process is disclosed for coloring building materials with inorganic pigments in the form of microgranulates. The granulates comprise one or more pigments and one or more compounds selected from boron, aluminum, silicon, titanium, zinc and tin.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: August 7, 2001
    Assignee: Bayer AG
    Inventors: Jakob Rademachers, Günther Teichmann
  • Patent number: 6193794
    Abstract: The iron oxide platelets comprise at least one layer packet comprising A) a colorless coating having a refractive index n≦1.8, and B) a colorless coating having a refractive index n≧2.0.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: February 27, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Oliver Seeger, Norbert Mronga
  • Patent number: 6176919
    Abstract: The invention is directed to a water-based paint composition comprising sodium silicate, water, water-soluble base, metal oxide pigment, a fused silica and, optionally, a low-melting glass frit, soda-lime-silica glass particles and/or zinc oxide. It may further optionally include surfactants and aluminum hydroxide. The paint composition is particularly useful as a black-out paint on automotive vehicle windshields and has been shown to impart improved stone chip resistance to the glass.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: January 23, 2001
    Assignee: Visteon Global Technologies, Inc.
    Inventor: Claude Franklin Mason
  • Patent number: 6139610
    Abstract: A corrosion-inhibiting composition for application to a metal substrate, such as steel, silver, copper or aluminum, includes a film-forming organic polymer component and a dispersed pigment phase of a stable unitary hybrid which contains organic and inorganic solid phase constituents interfaced at a micro-crystalline level, which are inseparable by physical separation procedures and which display uniphase behavior. The inorganic phase includes a cation selected from Zn, Al, Mg, Ca, Sr, Ti, Zr, Ce and Fe and an anion selected from phosphates, polyphosphates, phosphites, molybdates, silicates and cyanamides.
    Type: Grant
    Filed: June 3, 1999
    Date of Patent: October 31, 2000
    Assignee: Wayne Pigment Corp.
    Inventor: John Sinko
  • Patent number: 6139616
    Abstract: The present invention relates to an anti-corrosive pigment composition, characterized by comprising, as main components, white anti-corrosive pigment and an inorganic anion exchanger represented by the following formula (1):(3-4)[M.sub.1 ]O.Al.sub.2 O.sub.3.[M.sub.2 ]X.sub.2/m .multidot.nH.sub.2 O(1)(wherein, M.sub.1 and M.sub.2 are at least one selected from Ca.sup.2+ or Zn.sup.2+, X represents at least one anion selected from NO.sub.2.sup.-, NO.sub.3.sup.- or MoO.sub.4.sup.2-, m represents a valency of the anion, and n is 20 or less).
    Type: Grant
    Filed: March 30, 1999
    Date of Patent: October 31, 2000
    Assignees: Nippon Chemical Industrial Co., LTD, Toho Ganryo Kogyo Co., Ltd.
    Inventors: Takahiro Nagayama, Minoru Yokoyama
  • Patent number: 6136083
    Abstract: A description is given of coated inorganic pigments comprising an organic pigment which has a coating, prepared by the sol-gel process from glass-forming components and densified to form a xerogel or glass, having a layer thickness of at least 0.8 .mu.m. These pigments are prepared by spray drying a sol-pigment dispersion, followed if desired by thermal densification of the xerogel layer to form a glass layer. The coated pigments are suitable for producing enamels and moldings.
    Type: Grant
    Filed: December 8, 1997
    Date of Patent: October 24, 2000
    Assignee: Institut fuer Neue Materialien gemeinnuetzige GmbH
    Inventors: Helmut Schmidt, Martin Mennig, Axel Kalleder
  • Patent number: 6126737
    Abstract: The invention is directed to a dark colored high-solids water-based paint composition comprising sodium silicate, water, water-soluble base, metal oxide pigment, a low-melting glass frit, and optionally, soda-lime-silica glass particles and/or zinc oxide. It may further optionally include surfactants and aluminum hydroxide. The paint composition is particularly useful as a black-out paint on automotive glazings.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: October 3, 2000
    Assignee: Visteon Global Technologies, Inc.
    Inventor: Claude Franklin Mason
  • Patent number: 6083316
    Abstract: An adhesive-free, dry, free-flowing powder composition suitable for use in surface defect detection, where the powder composition comprises a physical mixture of particles of a colorant and particles of an extender, which mixture includes particles of colorant and particles of extender each having a particle size of less than 100 .mu.m. The powder compositions of the invention provide a simple, effective guide coat which readily highlights surface imperfections, such as scratches, orange peel effect and dry over-spray without the need for solvents. Also, there are disclosed methods of using such a powder composition to detect surface imperfections, an apparatus for applying same, a device for refilling such applying apparatus, and coated surfaces formed thereby.
    Type: Grant
    Filed: November 24, 1997
    Date of Patent: July 4, 2000
    Assignee: 3M Innovative Properties Company
    Inventor: David R. Bastow
  • Patent number: 6080232
    Abstract: The invention relates to spherical colored pigments having an average particle diameter of less than 10 .mu.m on the basis of an oxide, a mixed oxide or a silicate. The pigments are obtainable by means of spray-pyrolysis technology: a solution containing oxide-forming or silicate-forming metal compounds is converted into an aerosol and the latter is fed, preferably after predrying, to a pyrolysis reactor; the pigment is separated from the pyrolysis gas. The colored pigments according to the invention are suitable for the production of ceramic decorations and for the coloring of plastics, synthetic foils, fibers and also lacquers. By reason of the spherical shape, unusual technical application properties are achieved.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: June 27, 2000
    Assignee: Degussa Aktiengesellschaft
    Inventors: Jorg Sperlich, Ralph Brandes, Hauke Jacobsen, Stipan Katusic, Andreas Schulz
  • Patent number: 6068692
    Abstract: The invention relates to a process for manufacturing decorated ceramic and glass articles according to which a ceramic dye composition, including fine particles which comprise ceramic pigments and binding medium resin(s) as well as possible further additives, is applied by means of an electrophotographic reproduction process onto a transfer means, for example paper coated with gum arabic, the transfer means coated with the ceramic dye composition is applied onto the ceramic or glass article, and after removal of the transfer means, the ceramic dye composition is combined with the ceramic or glass article by baking. The invention also includes decorative ceramic or glass articles obtainable by means of the above process and a ceramic dye composition of the type mentioned above.
    Type: Grant
    Filed: March 22, 1999
    Date of Patent: May 30, 2000
    Inventor: Michael Zimmer
  • Patent number: 5997953
    Abstract: In a protective coating formulation requiring the use of polyamine molecules, oleic acid is used as a very effective additive to remove any excess polyamines. The carboxyl groups of the oleic acid molecules react with the amine groups of the polyamines to form a harmless amide molecule. The oleic acid thus removes excess pollutants from the final coating. In addition, the oleic acid reduces the viscosity of the coating before curing, making it easier to apply to surfaces, and decreases the curing time necessary. However, the addition of oleic acid does not affect the beneficial characteristics of the coating in any way.
    Type: Grant
    Filed: September 4, 1997
    Date of Patent: December 7, 1999
    Assignee: 3L & T, Inc.
    Inventor: Leonid Rappoport
  • Patent number: 5993523
    Abstract: Metal particles useful for coating compositions, particularly aqueous coating compositions, are produced by treating the metal particles with a molybdate pigment. The molybdate pigment reacts with the surface of the metal particles. The molybdate pigment may be a salt such as a molybdate, phosphomolybdate or silicomolybdate salt, and the salt may include a multivalent cation such as calcium, strontium, barium, magnesium, zinc and aluminum. The metal particles show improved resistance to attack by water.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: November 30, 1999
    Assignee: Silberline Manufacturing Co., Inc.
    Inventors: Craig B. Keemer, William G. Jenkins, H. Taylor Lamborn, Robert E. Souerwine
  • Patent number: 5948471
    Abstract: The invention relates to a process for manufacturing decorated ceramic and glass articles according to which a ceramic dye composition, including fine particles which comprise ceramic pigments and binding medium resin(s) as well as possible further additives, is applied by means of an electrophotographic reproduction process onto a transfer means, for example paper coated with gum arabic, the transfer means coated with the ceramic dye composition is applied onto the ceramic or glass article, and after removal of the transfer means, the ceramic dye composition is combined with the ceramic or glass article by baking. The invention also includes decorative ceramic or glass articles obtainable by means of the above process and a ceramic dye composition of the type mentioned above.
    Type: Grant
    Filed: February 20, 1997
    Date of Patent: September 7, 1999
    Inventor: Michael Zimmer
  • Patent number: 5938834
    Abstract: The invention is directed to a water-based paint composition comprising sodium silicate, water, water-soluble base, metal oxide pigment, soda-lime-silica glass particles and at least one of a low-melting glass frit or zinc oxide. Preferably, it includes only the glass frit and it further preferably comprises surfactants and aluminum hydroxide. It also is a glass sheet carrying the paint on at least a portion of the sheet.
    Type: Grant
    Filed: November 18, 1997
    Date of Patent: August 17, 1999
    Assignee: Ford Motor Company
    Inventor: Premakaran Tucker Boaz
  • Patent number: 5904761
    Abstract: The present invention provides a method for preparing a needle-shaped pigment with a particle size of 0.3.+-.0.1 .mu.m, which has uniform particle distribution, higher thixotropy, an excellent gloss, and good absorption of printing ink, by continuous addition of aluminum sulfate solution and zinc sulfate solution to a milk of lime.
    Type: Grant
    Filed: October 14, 1997
    Date of Patent: May 18, 1999
    Inventor: Kyu Jae You
  • Patent number: 5777002
    Abstract: A method for preparing organopolysiloxane bases with high levels of fillers. The present inventors have found that by mixing the components of the base at a temperature below about 60.degree. C. for a period of time sufficient to effect essentially a homogeneous blend, a base composition is formed which can be further blended with a platinum group metal-containing catalyst, an organohydrogensiloxane, and optionally an inhibitor to form a curable liquid silicone rubber (LSR) composition. The curable LSR composition has improved flow characteristics and improved shelf life when compared to similar materials where the base is prepared at temperatures above about 60.degree. C. The improved flow characteristics allows larger quantities of fillers to be incorporated into the curable LSR composition while still maintaining acceptable flow characteristics.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: July 7, 1998
    Assignee: Dow Corning Corporation
    Inventors: Lori Jean Conway, Thomas Edward Gray, Phillip Joseph Griffith, William James Schulz, Jr.
  • Patent number: 5776239
    Abstract: An ultrafine titanium dioxide powder is disclosed that can be produced by hydrothermal treating an amino titanium oxalate composition. Ultrafine titanium dioxide powders are useful in cosmetic and other applications for controlling exposure to ultraviolet (UV) light.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: July 7, 1998
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Salvatore Anthony Bruno
  • Patent number: 5766336
    Abstract: Colored pigments are provided from the green-yellow to red spectrum based on oxide-nitrides with two or three different cations Q, R and S in the crystal lattice, wherein the nitrogen to oxygen atomic ratio is determinative for the color. These pigments crystallise in the pyrochlore, spinel or elpasolite structure. Pigments in the perovskite are as provided with increased color brilliance. The color of the pigments can be adjusted in a wide range of the color spectrum during their preparation within a substance class with the cations Q, R and S and while retaining the crystal structure, by increasing or lowering the atomic ratio N to O in the oxide-nitride and bringing about the required charge balancing by replacing an equivalent quantity of the cation Q with the valency q by a cation R with the valency q+1.
    Type: Grant
    Filed: August 21, 1995
    Date of Patent: June 16, 1998
    Assignee: Cerdec Aktiengesellschaft Keramische Farben
    Inventors: Martin Jansen, Hans-Peter Letschert
  • Patent number: 5753028
    Abstract: Bismuth vanadate pigments IBi.sub.x Fe.sub.y E.sub.v V.sub.(1-w) P.sub.w O.sub.z Iwith the following meanings of the variables:E denotes calcium, zinc, cerium, praseodymium, and/or silicon;x is a value from 0.8 to 1.2;y is greater than 0 to 0.1 when v is greater than 0 or is greater than or equal to 0.035 to 0.1 when v is equal to 0;v is greater than or equal to 0 to 0.2;w is greater than 0 to 0.1;z denotes the number of oxygen atoms required to satisfy the valence requirements of the cations.and the preparation and use of said pigments for dyeing coating compositions, printing inks, and plastics.
    Type: Grant
    Filed: August 2, 1996
    Date of Patent: May 19, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Harald Ochmann, Hansulrich Reisacher, Helmut Knittel, Norbert Mronga, Gunter Etzrodt, Henning Wienand
  • Patent number: 5702520
    Abstract: The invention is directed to a method of making a water-based paint composition comprising sodium silicate, water, water-soluble base, metal oxide pigment, soda-lime-silica glass particles and at least one of a low-melting glass frit or zinc oxide. Preferably, it comprises only the low-melting glass frit and further preferably comprises surfactants and aluminum hydroxide. In another aspect, it is also directed to a method of making a formed glazing having a cured coating of the paint composition thereon.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: December 30, 1997
    Assignee: Ford Motor Company
    Inventor: Premakaran Tucker Boaz
  • Patent number: 5698025
    Abstract: The invention is directed to glass sheets carrying a coating of a water-based paint composition comprising sodium silicate, water, water-soluble base, metal oxide pigment, soda-lime-silica glass particles and, at least one of a low-melting glass frit or zinc oxide. Preferably, it comprises only the glass frit and it further desirably comprises surfactants and aluminum hydroxide.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: December 16, 1997
    Assignee: Ford Motor Company
    Inventor: Premakaran Tucker Boaz
  • Patent number: 5698026
    Abstract: The invention is directed to a water-based paint composition comprising sodium silicate, water, water-soluble base, metal oxide pigment, soda-lime-silica glass particles and at least one of a low-melting glass frit or zinc oxide. Preferably, it includes only the glass frit and it further preferably comprises surfactants and aluminum hydroxide.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: December 16, 1997
    Assignee: Ford Motor Company
    Inventor: Premakaran Tucker Boaz
  • Patent number: 5677064
    Abstract: The invention is directed to a water-based paint composition comprising sodium silicate, water, water-soluble base, metal oxide pigment, and glass frit as an adhesion promoter. Preferably, it further comprises zinc oxide, surfactants, and aluminum hydroxide. In other aspects, it is directed to the method of making the composition, and glass sheets having a cured paint field thereon, and the method of making such glass sheets.
    Type: Grant
    Filed: March 4, 1996
    Date of Patent: October 14, 1997
    Assignee: Ford Motor Company
    Inventor: Premakaran T. Boaz
  • Patent number: 5637143
    Abstract: Metal pigment particles which are treated with a heteropolyanion compound, a phosphosilicate compound or a combination of a heterpolyanion compound and a phosphosilicate compound show increased stability against attack by water. The particles are especially useful in aqueous coating compositions.
    Type: Grant
    Filed: September 7, 1995
    Date of Patent: June 10, 1997
    Assignee: Silberline Manufacturing Co., Inc.
    Inventors: William G. Jenkins, Craig Keemer, H. Taylor Lamborn, Michael Curcio
  • Patent number: 5518535
    Abstract: The invention is directed to a water-based paint composition comprising sodium silicate, water, water-soluble base, metal oxide pigment, and zinc oxide as an adhesion promoter. Preferably, it further comprises glass frit and surfactants. In other aspects, it is directed to the method of making the composition, and glass sheets having a cured paint field thereon, and the method of making such glass sheets.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: May 21, 1996
    Assignee: Ford Motor Company
    Inventor: Premakaran T. Boaz
  • Patent number: 5389402
    Abstract: A method for producing decorations which are color-stable in a porcelain firing (glost firing), and a pigment composition suitable for this method, is disclosed. Inclusion pigments based on heavy-metal sulfides and selenides in an oxidic or silicate casing, especially ZrSiO.sub.4, result in more color-stable decorations in a porcelain firing if color-stabilizing auxiliary agents from the series of Zn compounds, especially ZnO or zinc-containing glass frits, or cerium(III) or cerium(IV) compounds, especially CeO.sub.2, are used in the decorative layer and/or glaze layer as color-stabilizing auxiliary agents. The amount used in the decorative layer is generally 5 to 50% by weight in the case of ZnO and CeO.sub.2, relative to the inclusion pigment. The pigment composition contains at least one of the color-stabilizing auxiliary agents in addition to an inclusion pigment.
    Type: Grant
    Filed: May 12, 1993
    Date of Patent: February 14, 1995
    Assignee: Degussa Aktiengesellschaft
    Inventors: Dietrich Speer, Akos Kiss, Jenny Horst, Guenter Halbritter, Rita Loew
  • Patent number: 5356469
    Abstract: Metal pigment particles which are treated with both a heteropoly anion compound and a phosphosilicate pigment compound show increased stability against attack by water. The particles are especially useful in aqueous coating compositions.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: October 18, 1994
    Assignee: Silberline Manufacturing Co., Inc.
    Inventors: William G. Jenkins, Craig Keemer, H. Taylor Lamborn, Michael Curcio
  • Patent number: 5340395
    Abstract: The technical field of the invention is concerned with smoke-generating devices and with powdered materials scattered by dispersion means in order to produce a camouflaging cloud which is effective in the infrared region. The material in accordance with the invention essentially consists of at least one powder having grains provided with a coating which is chemically inert with respect to the grain, which affords resistance to temperatures lower than or equal to the dispersion temperature, and which does not oxidize in free air.
    Type: Grant
    Filed: July 1, 1992
    Date of Patent: August 23, 1994
    Assignee: Giat Industries
    Inventors: Daniel Larmignat, Phillippe C. Morand, Christian H. Prieur, Gilles F. Lacreuse
  • Patent number: 5296032
    Abstract: Metal pigment particles which are treated with a heteropoly anion compound show increased stability against attack by water. The particles are especially useful in aqueous coating compositions.
    Type: Grant
    Filed: August 11, 1993
    Date of Patent: March 22, 1994
    Assignee: Silberline Manufacturing Co., Inc.
    Inventors: William G. Jenkins, Craig Keemer, H. Taylor Lamborn, Michael Curcio
  • Patent number: 5269840
    Abstract: Colorant clusters comprising an aggregation of a plurality of grains of sol-derived material and colorant. The clusters are particularly useful as pigments in liquid compositions, e.g., paints and inks, for forming coatings that are retroreflective immediately upon drying. Also, a process for preparing such colorant clusters comprising admixing colorant in a binder sol to yield a pigment sol and then removing liquid medium from the pigment sol to yield the clusters. Also, a coating composition comprising retroreflective elements, a vehicle, and the aforementioned colorant clusters. After application of the composition to a substrate, the resultant coating is immediately retroreflective upon drying.
    Type: Grant
    Filed: February 4, 1992
    Date of Patent: December 14, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Geoffrey P. Morris, Chester A. Bacon, Jr., Wallace K. Bingham
  • Patent number: 5198026
    Abstract: Zinc powder, which contains a coloring element, e.g., Ti, Mn, or V, is heated to a temperature of from 350.degree. to 700.degree. C. so as to oxidize the surface of the powder and hence to develop such colors as brown, navy blue, blue, greenish-brown, green, and coffee brown. The colored zinc powder is sprayed onto a steel, aluminum, or ceramic article to produce a colored article. The colored zinc powder is also used as a pigment.
    Type: Grant
    Filed: September 25, 1991
    Date of Patent: March 30, 1993
    Assignee: Nippon Mining Co., Ltd.
    Inventors: Eiji Nishimura, Chikara Tominaga, Yusaku Masuda, Hiroshi Tasaki
  • Patent number: 5194089
    Abstract: Coated spinel color pigments with a core of a colored spinel, in particular CoAl.sub.2 O.sub.4, and a coating glassy layer of a silicate are described. The coating layer is essentially silicon dioxide and one or more oxides of the group of alkali metals, alkaline earth metals, and/or earth metals show a high resistance to bleeding in the presence of glass fluxes, as compared to uncoated spinels. The pigments are produced by sintering, for 0.5 to 5 hours, a powder mixture of the spinel, silicon dioxide, and at least one member chosen from the group of alkali metal halides, alkaline earth metal halides, earth metal halides and mixtures thereof as mineralizer at 900.degree. to 1,300.degree. C. The coated spinel color pigments are suitable for the production of ceramic decorations with improved contour sharpness.
    Type: Grant
    Filed: May 9, 1991
    Date of Patent: March 16, 1993
    Assignee: Degussa AG
    Inventors: Dietrich Speer, Akos Kiss, Peter Kleinschmit, Jenny Horst
  • Patent number: 5171365
    Abstract: A family of novel and unique synthetic alkali metal alumino-silicates (SAMS) are produced by the hydrothermal reaction between kaolin and alkali metal silicates. The integrated composition of the SAMS products is a unique entity having an overall composition ofxM.sub.2 O:Al.sub.2 O.sub.3 :ySiO.sub.2 :zH.sub.2 Owhere x is the number of moles of alkali metal oxide and is an integer from 0.01 to 2.0, M is the alkali metal, y is the number of moles of SiO.sub.2 in the unique SAMS compositions and is an integer greater than 2.0, and z is the number of moles of bound water and is an integer ranging from 1.0 to 5.0. The unique SAMS compositions are structured materials in which the structure can be controlled, and are therefore useful as functional fillers, as TiO.sub.2 extenders, as silica extenders or as reinforcing agents for paper, paint, rubber, plastics and specialty products.
    Type: Grant
    Filed: July 24, 1991
    Date of Patent: December 15, 1992
    Assignee: J. M. Huber Corporation
    Inventor: Satish K. Wason
  • Patent number: 5164006
    Abstract: A method for preparing an acid resistant calcium carbonate pigment. An aqueous slurry of particulate calcium carbonate is provided at a pH of from about 11.0 to 12.0 and having from 2 to 5 g/l of excess calcium hydroxide. The slurry temperature is brought to the range of about 75.degree. to 80.degree. C., and sodium silicate solution is slowly mixed therewith to provide on a solid dry weight ratio from about 5 to 10% sodium silicate to calcium carbonate. Gaseous carbon dioxide is added to bring the slurry pH to the range of about 10.2 to 10.7, and the slurry is cooled to about 25.degree. to 30.degree. C. Finally zinc chloride is added to the cooled slurry to bring the pH to within the range of 7.5 to 8.0.
    Type: Grant
    Filed: April 8, 1991
    Date of Patent: November 17, 1992
    Assignee: ECC America Inc.
    Inventors: Vasant D. Chapnerkar, Vicente B. Lasmarias, Vijay K. Mathur
  • Patent number: 5110586
    Abstract: A white colored deodorizer comprising zinc oxide and at least one oxide selected from the group consisting of aluminium oxide and silicon oxide and a method for preparation of it are disclosed.
    Type: Grant
    Filed: June 21, 1990
    Date of Patent: May 5, 1992
    Assignee: Titan Kogyo Kabushiki Kaisha
    Inventors: Tokumitsu Kurihara, Tatsuo Saito, Hidefumi Harada
  • Patent number: 5035748
    Abstract: An inorganic pigment comprising a content of at least 0.1% by weight and at most 5% by weight of one or more polyorganosiloxanes, wherein the polyorganosiloxanes have viscosities of 10 to 100,000 mPa.s and a relative molecular weight of 500 to 500,000, have no reactive or crosslinking groups, contain at least one C.sub.9 -C.sub.25 Si-alkyl and/or one C.sub.9 -C.sub.25 Si-aryl group per molecule, the total content of these groups in the polyorganosiloxane being 7-70% by weight and the other organic radicals contained in the polyorganosiloxane having 1 to 8 carbon atoms. Such pigments can be used in lacquers, emulsion paints, plastics, toners, magnetic recording materials, building materials and enamels.
    Type: Grant
    Filed: November 22, 1989
    Date of Patent: July 30, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wilfried Burow, Jurgen Kischkewitz, Ottfried Schlak
  • Patent number: 5030284
    Abstract: An alumina-silica-sulfate of the formulaxR:Al.sub.2 O.sub.3 :ySiO.sub.2 :zSO.sub.4.pH.sub.2 Owherein R is an alkali or alkaline earth metal oxide, a transition metal capable of forming a sulfate salt or mixtures thereof, x is about 0.001 to 0.5, y is about 0.01 to 3.00, z is about 0.00 to 3.00, and p is about 0 to 100.00, and wherein the sulfate is present as a bound network. Compositions comprising the alumina-silica-sulfate of the invention and a carrier, articles of manufacture comprising the alumina-silica-sulfates of the invention in the form of a catalyst, rubber, plastics, paint and paper, among others. Hollow microspheres are formed by spray drying a gelled composition. Hollow microspheres containing a porous network are formed by calcining the spray-dried hollow microspheres to eliminate the sulfate network.
    Type: Grant
    Filed: January 12, 1989
    Date of Patent: July 9, 1991
    Inventor: Michael C. Withiam