Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack.

Abstract: To provide a high-chromatic flaky pigment with good colorability, and to provide a method for producing the flaky pigment in a simple and inexpensive plant. A high-chromatic flaky pigment of which the entire surface of the flaky substrate coated with a metal oxide having an interference color is further coated with a semi-transparent thin metal film to enhance the interference color of the pigment.

Abstract: Disclosed are metal oxide sols made by mixing at least one metal alkoxide, wherein the metal is a transition metal, a post-transition metal, an alkali metal, or alkaline earth metal; at least one organosilane; at least one boron oxide compound selected from the group consisting of boric acid, alkoxy boron compounds, hydrocarbyl boric acids, hydrocarbyl hydroxy boron alkoxides, and hydroxy boron alkoxides; and a liquid. Also disclosed are composites containing a polymer and the metal oxide sols.

Abstract: Silica composite oxide particles comprising silica and a metal oxide other than silica, the content of the metal oxide other than silica being from 30 to 50 mol %, and a coefficient of variation in the particle diameter being not larger than 30%. The silica composite oxide particles contain metal oxides other than silica in an amount of not smaller than 30 mol %, which could not be produced thus far, and feature excellent spherical shape and excellent monodispersion property.

Abstract: The present invention provides titanium dioxide pigments with improved gloss and/or durability. The titanium dioxide pigments are made by treating titanium dioxide with a plurality of metal salts under conditions suitable to form the titanium dioxide pigment having improved gloss and/or durability, wherein at least one metal salt is capable of providing a monovalent anion. Preferred pigments of the present invention are substantially-sulfate free.

Abstract: Multilayer pearl lustre pigment on the basis of a platelet-shaped substrate comprising a material of low refractive index in the range from 1.35 to 1.8, which comprises at least (i) one first layer comprising a material having a refractive index of more than 1.8, (ii) optionally, a second layer comprising a material of low refractive index in the range from 1.35 to 1.8, (iii) a semitransparent metal layer which is applied to the substrate or to the layers (i) or (ii), and (iv) if desired, an aftercoating, the substrate being platelet-shaped silicon dioxide, aluminium oxide, boron oxide or magnesium fluoride.

Abstract: Thin-film-like particles and isolated films of an extremely small thickness having a skeleton constructed by carbons are provided. The thin-film-like particles take independent shapes, have a thickness of 0.4 to 10 nm and a breadth in a planar direction of 20 nm or more, and can disperse in a liquid having a relative dielectric constant of 15 or more. The thin-film-like particles are obtained by promoting separation of layers in oxidation of graphite. The particles in their dispersion are placed, along with the dispersion, on a mesh, and dried to obtain an isolated thin film. The thin-film-like particles are reduced to obtain thin-film-like graphite particles and these collective matters.

Abstract: The present invention relates to interference pigments on the basis of multiply coated, platelet-shaped substrates which comprise at least one layer sequence comprising (A) a coating having a refractive index n≧2.0, (B) a colorless coating having a refractive index n≦1.8, and (C) a nonabsorbing coating of high refractive index, and, if desired, (D) an external protective layer.

Abstract: Silica composite oxide particles comprising silica and a metal oxide other than silica, the content of the metal oxide other than silica being from 30 to 50 mol %, and a coefficient of variation in the particle diameter being not larger than 30%. The silica composite oxide particles contain metal oxides other than silica in an amount of not smaller than 30 mol %, which could not be produced thus far, and feature excellent spherical shape and excellent monodispersion property.

Abstract: Pigment flakes having cores preferably composed of resins, polymers, thermoplastics, and/or thermosets with colorant (pigment and/or dyes) deposited thereon, coating applications thereof, and a method for making pigment flakes which includes providing a core material, compounding the core material, processing the core material into uniform forms such as films, wires, thread with rectangular cross sections and bead strings, providing colorant material, vaporizing the colorant material, exposing a surface of core material to the vaporized colorant material to form a layer of colorant on thereon, and fracturing the resultant colorant layered core material into flakes.

Abstract: A process for preparing an improved pigment which is readily dispersible in paints and plastics concentrates is provided. In accordance with the process, a particulate pigment is mixed with water to form a slurry thereof, and a surface active agent is mixed with the slurry so that the pigment therein is coated therewith. A preferred surface active agent is a mixture of ethoxylated sorbitan derivatives, non-ethoxylated mono and diglycerides and ethoxylated mono and diglycerides. After the pigment has been coated with the surface active agent, the coated pigment is dried.

Abstract: Multilayer interference pigment consisting of plateletlike titanium dioxide as carrier material, coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by solidification and hydrolysis of an aqueous solution of a thermally hydrolyzable titanium compound on a continuous belt, detachment of the resulting coat, coating of the resulting titanium dioxide platelets, with or without drying in between, by a wet method with, alternately, a metal oxide hydrate of high refractive index and a metal oxide hydrate of low refractive index by hydrolysis of the corresponding, water-soluble metal compounds, separation, drying and, if desired, calcining of the material obtained.

Abstract: The invention relates to a pearl luster pigment which may possess a first, inner layer, consisting of a platelet-shaped substrate, a second layer, comprising one or more metal oxides, the first and second layers forming a calcined base pigment, a third layer, comprising the corresponding uncalcined oxide, hydroxide or oxide hydrate of the oxide of the second layer, a fourth layer, comprising oxides, hydroxides and/or oxide hydrates of silicon or aluminum, a fifth layer, comprising oxides, hydroxides and/or oxide hydrates of silicon, aluminum, zirconium and/or cerium, this layer differing from the fourth layer, and a sixth layer, comprising one or more organofunctional coupling reagents. The present invention relates to also a preparation process, and the use of the pigments in paints, inks, plastics, coatings and cosmetics.

Abstract: The present invention relates to a pearl luster pigment on the basis of a platelet-shaped substrate coated with metal oxides and a top layer which is located on the metal oxide layer and can possess a multilayer structure, comprising a first layer, containing a hydroxide or oxide hydrate of the elements aluminum or silicon, a second layer, containing at least one hydroxide or oxide hydrate of the elements aluminum, silicon, cerium or zirconium, with the exception of the hydroxide or oxide hydrate which forms the first layer, and a third layer, containing at least one organic hydrophobic coupling agent. The present invention also relates to a preparation process and the use of pigments in paints, inks, plastics, coatings and cosmetics.

Abstract: The present invention provides titanium dioxide pigments with improved gloss and/or durability. The titanium dioxide pigments are made by treating titanium dioxide with a plurality of metal salts under conditions suitable to form the titanium dioxide pigment having improved gloss and/or durability, wherein at least one metal salt is capable of providing a monovalent anion. Preferred pigments of the present invention are substantially-sulfate free.

Abstract: A photocatalytic titanium dioxide coating composition is described, which comprises (a) finely-divided titanium dioxide particles exhibiting photocatalytic activity, (b) particles of an inorganic compound other than titanium dioxide, or particles of an organic compound convertible to particles of an inorganic compound on firing, (c) a binder, and (d) a solvent. The articles of an inorganic compound have an average particle diameter larger than that of the finely divided titanium dioxide particles and falls within the range of about 0.1 &mgr;m to about 1.0 &mgr;m. The inorganic compound particles are substantially insoluble in the solvent. The amount of the inorganic compound particles is in the range of about 0.5% to about 7% by weight based on the weight of the finely divided titanium dioxide particles. By coating a surface of a substrate with the coating composition, a coating film exhibiting excellent photocatalytic activity and no interference color is formed.

Abstract: Moldings are disclosed for use as a catalyst or catalyst support for hydrating olefin, such as ethylene and propylene. The moldings are based on a pyrogenically produced mixed oxide having the following physicochemical parameters: External diameter 0.8-25 mm BET surface area 5-400 m2/g Pore volume 0.2-1.8 ml/g Fracture strength 5 to 350 N Composition At least two materials selected from the group of SiO2, Al2O3, TiO2 and ZrO2 in any desired combination, with the proviso that when the combination is a SiO2/Al2O3 mixed oxide, at least 75 wt. % of SiO2 is present based on the total weight of the mixed oxide. Other constituents <1 wt. % Bulk density 250-1500 g/l.

Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.

Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.

Abstract: The present invention provides a coated titanium dioxide pigment which includes a base titanium dioxide pigment; a first deposit of a phosphate compound contiguous with the base titanium dioxide pigment; a deposit of a silica or zirconia compound contiguous with the phosphate deposit; a second deposit of a phosphate compound contiguous with the silica or zirconia compound; and a deposit of an alumina compound contiguous with the second phosphate deposit. Titanium dioxide pigments of the present invention are easily dispersible, and display excellent durability and gloss.

Abstract: Multilayer interference pigment consisting of plateletlike titanium dioxide as carrier material, coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by solidification and hydrolysis of an aqueous solution of a thermally hydrolysable titanium compound on a continuous belt, detachment of the resulting coat, coating of the resulting titanium dioxide platelets, with or without drying in between, by a wet method with, alternately, a metal oxide hydrate of high refractive index and a metal oxide hydrate of low refractive index by hydrolysis of the corresponding, water-soluble metal compounds, separation, drying and, if desired, calcining of the material obtained.

Abstract: A process is disclosed for coloring building materials with inorganic pigments in the form of microgranulates. The granulates comprise one or more pigments and one or more compounds selected from boron, aluminum, silicon, titanium, zinc and tin.

Abstract: Colored pearl luster pigment consisting of a core of platelet shaped titanium dioxide and one or more layers of other metal oxides or metal oxide hydrates obtainable by solidifying an aqueous solution of a thermally hydrolyzable titanium compound on a continuous belt, detaching the resulting layer, coating the resulting titanium dioxide platelets, with or without drying in between, with one or more other metal oxides or metal oxide hydrates, for example Fe2O3, Fe3O4, FeOOH or Cr2O3, by a wet method, separating, drying and, if desired, calcining the material obtained.

Abstract: Multilayer interference pigment consisting of plateletlike titanium dioxide as carrier material, coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by solidification and hydrolysis of an aqueous solution of a thermally hydrolysable titanium compound on a continuous belt, detachment of the resulting coat, coating of the resulting titanium dioxide platelets, with or without drying in between, by a wet method with, alternately, a metal oxide hydrate of high refractive index and a metal oxide hydrate of low refractive index by hydrolysis of the corresponding, water-soluble metal compounds, separation, drying and, if desired, calcining of the material obtained.

Abstract: The invention concerns a novel titania pigment useful for external painting. This pigment has a titania nucleus coated successively with a layer of zirconium hydroxide or oxyhydroxide, then a layer of titanium hydroxide or oxyhydroxide, then of a layer of co-precipitated phosphate and silica, and finally a layer of aluinium oxyhydroxide. The invention also concerns a method for preparing said pigment and its use in paints, plastics and laminated paper.

Abstract: The iron oxide platelets comprise at least one layer packet comprising A) a colorless coating having a refractive index n≦1.8, and B) a colorless coating having a refractive index n≧2.0.

Abstract: A method of producing a low structure pyrogenic metal oxide filler is disclosed. The method involves subjecting pyrogenically produced metal oxide agglomerates and aggregates selected from silicon oxide, aluminum oxide, zirconium oxide, or titanium oxide to a dry milling process whereby the pyrogenically produced metal oxide is contacted in an agitating zone with an energy specific force.

Abstract: Modified pearl luster pigments for waterborn coating systems, based on a platelet-form substrate coated with metal oxides and, located on the topmost metal oxide layer, a top layer consisting of at least two oxides and/or mixed oxides from the group consisting of silicon dioxide, aluminium oxide, cerium oxide, titanium oxide and zirconium oxide, and on a water-based oligomeric silane system. The oligomeric silane system can be described, for example, by the following approximate structure: [HO[Si(A)(OH)z(CH3)1−zO]a[Si(B)(OH)y(CH3)1−yO]b[Si(E)(OH)w(CH3)1−wO]c[Si(D)(OH)v(CH3)1−vO]dH].

Abstract: A titanyl sulfate solution or a titanium tetrachloride solution is neutralized with an alkali to form orthotitanic acid, to which hydrochloric acid is added such as to adjust the TiO.sub.2 concentration to 80-140 g/L and the HCl concentration to 90-150 g/L and a synthesis reaction is performed at a temperature of 25-60.degree. C. to produce titanium oxide particles in which needles aggregate and/or bind together to yield fan-shaped particles.

Abstract: Metal oxide particles having a substantial uniform and homogeneous (across-particle) coating of a metal oxide or organofunctionalized metal oxide are disclosed and are prepared by hydrolysis of a monomeric precursor to the coating.

Abstract: Surface-modified, pyrogenically produced mixed oxides which contain two or more components of the series SiO.sub.2, Al.sub.2 O.sub.3, TiO.sub.2, ZrO.sub.2, Fe.sub.2 O.sub.3, Nb.sub.2 O.sub.5, V.sub.2 O.sub.5, WO.sub.3, SnO.sub.2, GeO.sub.2 and have been surface-modified with one to several compounds of the following groups:(a) organosilanes of the type (RO).sub.3 Si(C.sub.n H.sub.2n+1),(b) R'.sub.x (RO).sub.y Si(C.sub.n H.sub.2n+1),(c) X.sub.3 Si(C.sub.n H.sub.2n+1),(d) X.sub.2 (R')Si(C.sub.n H.sub.2n+1),(e) X(R').sub.2 Si(C.sub.n H.sub.2n+1),(f) (RO).sub.3 Si(CH.sub.2).sub.m --R',(g) (R").sub.x (RO).sub.y Si(CH.sub.2).sub.m --R',(h) X.sub.3 Si(CH.sub.2).sub.m --R',(i) (R)X.sub.2 Si(CH.sub.2).sub.m --R',(j) (R).sub.2 X Si(CH.sub.2).sub.m --R',(k) Silazanes of the type ##STR1## (l) Cyclic polysiloxanes, (m) Polysiloxanes or silicone oils.

Abstract: Purple pigments according to the invention based on a stovable support material, in particular a glass frit, having a coat applied by coprecipitation of an oxide hydrate of one or more elements from the range comprising Al, Si, Sn, Pb, Ti, Nb, Ta, Sc, Y, La, Ce and Zn and a water-insoluble gold compound or colloidal gold are distinguished from prior art pigments of a similar composition by improved color stability in high temperature firing. The pigments are obtainable in the aqueous phase by coprecipitation of an oxide hydrate and a gold compound or colloidal gold in the presence of a support material and in the absence of a reducing agent. Pigments containing gold compounds assume a purple color on heat treatment or by chemical reduction. Preferred pigments containing gold compounds, which may directly be used as decorative colorants, conveniently develop their color during firing of the decoration.

Abstract: Plateletlike titanium dioxide reduction pigment consisting of titanium dioxide, titanium suboxides and, if desired, a further metal oxide or titanium oxynitride, obtainable by solidifying an aqueous solution of a thermally hydrolysable titanium compound on a continuous belt, detaching the resulting coat, coating the resulting titanium dioxide platelets, with or without drying in between, with further titanium dioxide by a wet method, drying and, if desired, calcining the material, and treating the material obtained with a reducing agent in a nonoxidizing gas atmosphere.

Abstract: Improved coated inorganic pigments having a first coating of Al.sub.2 O.sub.3, SiO.sub.2, or optionally other oxide such as a source of P.sub.2 O.sub.5, or mixtures thereof, an optional coating of ZrO.sub.2, SnO.sub.2, TiO.sub.2, SiO.sub.2, CeO.sub.2 or mixtures thereof, and a final coating of Al.sub.2 O.sub.3 which exhibit good durability, dispersibility, and optical properties in plastic or paint compositions are disclosed. Also disclosed is a process whereby an aqueous slurry of an inorganic pigment is milled to achieve a particular particle size distribution, a first coating of Al.sub.2 O.sub.3, SiO.sub.2, or optionally other oxide such as a source of P.sub.2 O.sub.5, or mixtures thereof is precipitated onto the pigment material within a first pH range, an optional amount of ZrO.sub.2, SnO.sub.2, SiO.sub.2, TiO.sub.2, CeO.sub.2 or mixtures thereof is added to the aqueous slurry within a second pH range to obtain an optional coating over the first coating, and a final coating of Al.sub.2 O.sub.

Abstract: The invention relates to granules of inorganic pigments, a process for their production using several auxiliary substances by compacting and their use in many technical fields.

Abstract: Goniochromatic luster pigments based on multiply coated, high refractive, nonmetallic, platelet-shaped substrates which are at least partially transparent to visible light, comprising at least one layer packet ofA) a colorless coating having a refractive index n.ltoreq.1.8 andB) a reflecting, selectively or nonselectively absorbing coating which is at least partially transparent to visible light,and also, if desired, additionallyC) an outer protective layer,and their use for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.

Abstract: Antioxidant-containing polyolefin compositions are provided including titanium dioxide-coated mica particles having an overcoating calcined thereon to prevent yellowing of the compositions. Reduced photo-darkening and improved densification of the pigment can also be achieved.

Abstract: A pigmentary material comprises particulate titanium dioxide the particles of which have been treated with a polymeric hindered amine stabiliser. The stabiliser is a polymer having a main chain substantially free of acidic groups and having hindered amine stabilising groups. The stabilising groups comprise at least 35 per cent by weight of the polymer. Preferably, the titanium dioxide particles are also treated with an organic compound such as a polyhydric alcohol, an alkanolamine, a polysiloxane or a fatty acid.

Abstract: A process for preparing a low-dusting, free-flowing pigment which has not been subjected to any micronizing treatment comprising the steps of providing an inorganic pigment material; providing a source of water; forming a fine, well dispersed slurry of the pigment and water; milling the slurry; depositing a treating agent having the formula ROOCCHSO.sub.3 MCH.sub.2 COOR' wherein R and R' are monovalent alkyl radicals having from about 2 to about 20 carbon atoms, and M is a metallic monovalent cation on the slurried milled pigment; and drying the pigment material having a treating agent deposited thereon. The invention also provides the free-flowing pigments produced by this process.

Abstract: The present invention relates to nanodisperse titanium dioxide, to a process for the production thereof and to the use thereof.

Abstract: In a method of producing TiO.sub.2 pigment particles a TiO.sub.a X.sub.b (OH).sub.c -based precursor is suspended in a liquid with or without fuel additives. The suspension is then sprayed to form droplets. The droplets are transported into a flow reactor with a carrier gas. The droplets are decomposed in the flow reactor at high temperatures to form TiO.sub.2 pigment particles which are collected downstream of the flow reactor. In a preferred embodiment, a colloidal suspension of an insoluble TiO(SO.sub.4).sub.b (OH).sub.c precipitate with suitable fuel additives was spray-calcined at 900.degree. to 1200.degree. C. to produce pigment-quality TiO.sub.2. The primary particle size of the TiO.sub.2 pigment particles is between 150-250 nm and the particles are minimally aggregated.

Abstract: This invention relates to a process for the production of inorganically coated pigments and fillers and to the use thereof.

Abstract: The application relates to stabilized vapor-deposition materials based on titanium oxide. These materials contain, as stabilizing additive, an oxide from the group consisting of zirconium oxide, hafnium oxide, yttrium oxide and ytterbium oxide.

Abstract: Composite conductive powder comprises a calcined mixture of conductive powder mainly comprising indium oxide which contains at least one member selected from the group consisting of tin oxide, titanium oxide and zirconium oxide as a dopant and conductive powder mainly comprising tin oxide which contains at least one member selected from the group consisting of antimony oxide, tantalum oxide and niobium oxide as a dopant, and a conductive film is formed from the composite, conductive powder. The composite, conductive powder and the conductive film produced from the powder permit the reduction in the amounts of materials for the ITO film, in particular, indium which is an expensive material and the composite, conductive powder can simultaneously satisfy both requirements for high transparency and high conductivity even if it is used for the formation of films through the coating technique.

Abstract: The invention relates to colored luster pigments consisting of a transparent or metallic reflecting core, of a coating consisting of at least one silicon oxide of the composition SiO.sub.0.25 to SiO.sub.0.95 and of further optional coatings, to coating processes by coating metallic silicon in the presence of oxygen, if required with changing its partial pressure, as well as to the use of these luster pigments for pigmenting plastic materials, paints and printing inks, and to pigmented compositions comprising these luster pigments.

Abstract: Colored pigments are provided from the green-yellow to red spectrum based on oxide-nitrides with two or three different cations Q, R and S in the crystal lattice, wherein the nitrogen to oxygen atomic ratio is determinative for the color. These pigments crystallise in the pyrochlore, spinel or elpasolite structure. Pigments in the perovskite are as provided with increased color brilliance. The color of the pigments can be adjusted in a wide range of the color spectrum during their preparation within a substance class with the cations Q, R and S and while retaining the crystal structure, by increasing or lowering the atomic ratio N to O in the oxide-nitride and bringing about the required charge balancing by replacing an equivalent quantity of the cation Q with the valency q by a cation R with the valency q+1.

Abstract: This invention discloses a process of making composite aggregate pigments (CAPs) having superior optical and dispersion characteristics. These pigments are produced by aggregating titanium dioxide and calcined clay with zirconium hydroxy complex chemicals in a slurry in the pH range of 6.0-10.5. Superior optical properties are obtained by heat treating the pigments after removal from the slurry. Multi-faceted pigments are obtained by including a small amount of a rod-shaped pigment, such as wollastonite, in the composite pigment.

Abstract: A process for preparing a low-dusting, free-flowing pigment which has not been subjected to any micronizing treatment comprising the steps of providing an inorganic pigment material; providing a source of water; forming a fine, well dispersed slurry of the pigment and water; milling the slurry; depositing a treating agent having the formula ROOCCHSO.sub.3 MCH.sub.2 COOR' wherein R and R' are monovalent alkyl radicals having from about 2 to about 20 carbon atoms, and M is a metallic monovalent cation on the slurried milled pigment; and drying the pigment material having a treating agent deposited thereon. The invention also provides the free-flowing pigments produced by this process.

Abstract: This invention provides a process for making titanium dioxide pigment, wherein an aqueous slurry of hydrous oxide surface-treated TiO.sub.2 particles is subjected to media milling. The TiO.sub.2 particles are surface-treated with a coating comprising a hydrous oxide such as silica and/or alumina, and the slurry is filtered prior to media milling. The milled slurry is dried and the dried product is fluid-energy milled to produce TiO.sub.2 pigment having good particle size distribution. The TiO.sub.2 pigments may be used to make coating formulations having high gloss.

Abstract: A TiO.sub.2 pigment particle having a surface coating of inorganic particles or mineral particles exhibiting improved light scattering efficiency of TiO.sub.2 at a moderate to high pigment volume concentration (PVC) and a low oil absorption when incorporated in coatings applications is disclosed, and methods of accomplishing the same.