Nickel, Cobalt, Copper, Or Cadmium Compound Containing (ni, Co, Cu, Cd) Patents (Class 106/440)
  • Patent number: 5968248
    Abstract: A heat-resistant inorganic pigment of the present invention comprises a composite metal oxide containing Ti and two divalent metals selected from the group consisting of Mg, Fe, Ni and Co, the content of said two divalent metals in said composite metal oxide being 0.95 to 1.05, in an atomic ratio, based on Ti, and the composition ratio of said two divalent metals being 95/5 to 5/95 in an atomic ratio. The pigment of the present invention is useful as a pigment for a heat-resistant coating material and is a novel heat-resistant inorganic pigment which does not pollute the environment.
    Type: Grant
    Filed: February 13, 1997
    Date of Patent: October 19, 1999
    Assignees: General of Agency of Industrial Science, Toda Kogyo Corporation
    Inventors: Yasuo Shibasaki, Kiichi Oda, Saburo Sano, Shigehisa Yamamoto, Nanao Horiishi
  • Patent number: 5961710
    Abstract: The invention relates to granules of inorganic pigments, a process for their production using several auxiliary substances by compacting and their use in many technical fields.
    Type: Grant
    Filed: February 12, 1998
    Date of Patent: October 5, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Linde, Manfred Eitel, Olaf Schmidt-Park, Kai Butje
  • Patent number: 5931998
    Abstract: Disclosed is a system of natural colors consisting of thousands of colored powders of mineral origin and of materials in or on which pigments have been applied and, afterwards, submitted to at least one thermal treatment and/or irradiation. These natural colors cover the totality of the visible spectrum and offer a great variety of tones, tints and reflections from white to black, including all the rainbow colors. The powders of this system are obtained by mechanical, chemical, thermal and/or physical processes and are used alone or in combination. They are particularly useful to color materials and, more especially those used in the construction and architectural fields.
    Type: Grant
    Filed: October 8, 1996
    Date of Patent: August 3, 1999
    Inventor: Paulette Tourangeau
  • Patent number: 5908499
    Abstract: Disclosed is a system of natural colors consisting of thousands of colored powders of mineral origin and of materials in or on which pigments have been applied and, afterwards, submitted to at least one thermal treatment and/or irradiation. These natural colors cover the totality of the visible spectrum and offer a great variety of tones, tints and reflections from white to black, including all the rainbow colors. The powders of this system are obtained by a combination of two mechanical, chemical, thermal and/or physical processes and are used alone or in combination. They are particularly useful to color materials and, more especially those used in the construction and architectural fields.
    Type: Grant
    Filed: October 8, 1996
    Date of Patent: June 1, 1999
    Inventor: Paulette Tourangeau
  • Patent number: 5853476
    Abstract: A method for coloring cementitious systems using compacted inorganic granules, wherein said compacted inorganic granules comprise an inorganic pigment and a dispersing agent. Particularly, a method for coloring cementitious systems using compacted inorganic granules; wherein said compacted inorganic granules are produced by a process consisting of: (a) mixing an inorganic pigment and a dispersing agent, (b) compacting the mixture, (c) milling the compacted mixture, and (d) classifying the compacted mixture into at least one oversize material stream, at least one undersize material stream and at least one product stream of compacted inorganic granules; and wherein the coloring effect of the compacted inorganic granules in the cementitious system equals or exceeds the powder standard.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: December 29, 1998
    Assignee: Elementis Pigments, Inc.
    Inventor: James T. Will
  • Patent number: 5849073
    Abstract: A pigment for sensing gas leakage can be produced by adding at least one of salts of platinum group metals to a slurry of particulate substrate, neutralizing the resultant mixture to deposit at least one of oxides, hydroxides and hydrated oxides of platinum group metals on the surfaces of said particulate substrate, and if necessary, further adding to said slurry at least one of compounds of aluminum, silicon, titanium, zinc, zirconium, tin, antimony and cerium, neutralizing the resultant mixture to deposit at least one of compounds such as oxides, hydroxides and hydrated oxides of aluminum, silicon, titanium, zinc, zirconium, tin, antimony and cerium, on the particles.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: December 15, 1998
    Assignees: Ishihara Sangyo Kaisha, Ltd., Act Research, Inc.
    Inventors: Masashi Sakamoto, Haruo Okuda, Hideo Futamata
  • Patent number: 5766336
    Abstract: Colored pigments are provided from the green-yellow to red spectrum based on oxide-nitrides with two or three different cations Q, R and S in the crystal lattice, wherein the nitrogen to oxygen atomic ratio is determinative for the color. These pigments crystallise in the pyrochlore, spinel or elpasolite structure. Pigments in the perovskite are as provided with increased color brilliance. The color of the pigments can be adjusted in a wide range of the color spectrum during their preparation within a substance class with the cations Q, R and S and while retaining the crystal structure, by increasing or lowering the atomic ratio N to O in the oxide-nitride and bringing about the required charge balancing by replacing an equivalent quantity of the cation Q with the valency q by a cation R with the valency q+1.
    Type: Grant
    Filed: August 21, 1995
    Date of Patent: June 16, 1998
    Assignee: Cerdec Aktiengesellschaft Keramische Farben
    Inventors: Martin Jansen, Hans-Peter Letschert
  • Patent number: 5766335
    Abstract: The invention relates to colored luster pigments consisting of a transparent or metallic reflecting core, of a coating consisting of at least one silicon oxide of the composition SiO.sub.0.25 to SiO.sub.0.95 and of further optional coatings, to coating processes by coating metallic silicon in the presence of oxygen, if required with changing its partial pressure, as well as to the use of these luster pigments for pigmenting plastic materials, paints and printing inks, and to pigmented compositions comprising these luster pigments.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: June 16, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Patrice Bujard, Natacha Bonnard
  • Patent number: 5759256
    Abstract: A rutile mixed metal oxide pigment can be prepared by calcining a rutile ore with a transition metal oxide. The rutile mixed oxide pigment can be dispersed in an emulsion to produce a paint or coating or the pigment can be combined with a network former and network modifier to produce a ceramic glaze.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: June 2, 1998
    Assignee: Kerr-McGee Chemical Corp.
    Inventor: Rodney D. Stramel
  • Patent number: 5749959
    Abstract: A stable dark or moderately dark opaque exterior coating constituted of pentations and binder materials having low solar absorbing properties capable of visual and infrared camouflage. The pigmentations and binder materials may be selected for the proper optical qualities by previous testing before mixture and application as a coating.
    Type: Grant
    Filed: February 10, 1969
    Date of Patent: May 12, 1998
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Robert F. Supcoe, Melvin Greenberg
  • Patent number: 5707436
    Abstract: Prior art production of purple pigments based on colloidal gold on stovable/sinterable/fireable support material involves the reduction of a gold compound in the presence of a chemical reducing agent.Purple pigments may be produced more simply according to the invention by intimately mixing and/or grinding the support material and the gold compound in dry form or by bringing an aqueous solution or suspension of a gold compound and a support material into contact and then thermally treating the mixture at a temperature above the decomposition temperature of the gold compound and below the sintering temperature of the support material, wherein the gold compound is converted into colloidal gold.
    Type: Grant
    Filed: March 29, 1995
    Date of Patent: January 13, 1998
    Assignee: Cerdec Aktiengesellschaft Keramische Farben
    Inventors: Klaus-Dieter Fritsche, Bernd Dorbath, Norbert Giesecke, Kerstin Ruhnau
  • Patent number: 5693134
    Abstract: An interference pigment comprising a platelet-shaped substrate coated with titanium dioxide and additionally oxidic compounds of copper and manganese, whereby the pigment powder color is dark gray.
    Type: Grant
    Filed: December 29, 1994
    Date of Patent: December 2, 1997
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventor: Alfred Stephens
  • Patent number: 5667892
    Abstract: Multicolored flakes with two faces, having a thickness between approximately 60 .mu.m and approximately 200 .mu.m, consist in a film of uniform color of polymer, copolymer or terpolymer, or a mixture thereof, having on at least part of one face only a decorative coating different from the uniform color.
    Type: Grant
    Filed: April 18, 1995
    Date of Patent: September 16, 1997
    Assignee: Sarl Quadra Industries
    Inventor: Robert Marillier
  • Patent number: 5662738
    Abstract: Luster pigments useful for coloring paints, printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations are based on multiply coated plateletlike metallic substrates comprisingA) a first, colorless or selectively absorbing layer of metal oxide,B) a second, nonselectively absorbing layer of carbon, metal and/or metal oxide, andC) if desired a third, colorless or selectively absorbing layer of metal oxide.
    Type: Grant
    Filed: July 22, 1994
    Date of Patent: September 2, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Norbert Mronga
  • Patent number: 5540770
    Abstract: Luster pigments based on coated plateletlike substrates comprising nitrogen-containing metal layers and if desired additionally one or more layers consisting essentially of colorless or selectively absorbing metal oxide, are prepared and used for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.
    Type: Grant
    Filed: June 16, 1995
    Date of Patent: July 30, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Norbert Mronga, Harald Ochmann, J org Adel
  • Patent number: 5364467
    Abstract: Luster pigments useful for coloring paints, printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations are based on multiply coated plateletlike metallic substrates comprisingA) a first, colorless or selectively absorbing layer of metal oxide,B) a second, nonselectively absorbing layer of carbon, metal and/or metal oxide, andC) if desired a third, colorless or selectively absorbing layer of metal oxide.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: November 15, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Norbert Mronga
  • Patent number: 5194089
    Abstract: Coated spinel color pigments with a core of a colored spinel, in particular CoAl.sub.2 O.sub.4, and a coating glassy layer of a silicate are described. The coating layer is essentially silicon dioxide and one or more oxides of the group of alkali metals, alkaline earth metals, and/or earth metals show a high resistance to bleeding in the presence of glass fluxes, as compared to uncoated spinels. The pigments are produced by sintering, for 0.5 to 5 hours, a powder mixture of the spinel, silicon dioxide, and at least one member chosen from the group of alkali metal halides, alkaline earth metal halides, earth metal halides and mixtures thereof as mineralizer at 900.degree. to 1,300.degree. C. The coated spinel color pigments are suitable for the production of ceramic decorations with improved contour sharpness.
    Type: Grant
    Filed: May 9, 1991
    Date of Patent: March 16, 1993
    Assignee: Degussa AG
    Inventors: Dietrich Speer, Akos Kiss, Peter Kleinschmit, Jenny Horst
  • Patent number: 5192365
    Abstract: Desirable buff rutile pigment compositions are described which comprise about 40 to about 55% by weight of titanium, from about 0.4 to about 5 parts by weight of cobalt, from about 7 to about 14% by weight of tungsten, from 0.01 to about 5 parts by weight of lithium and from about 0.1 to about 20 parts by weight of cerium.
    Type: Grant
    Filed: June 6, 1991
    Date of Patent: March 9, 1993
    Assignee: Engelhard Corporation
    Inventor: Zoltan M. Modly
  • Patent number: 5147686
    Abstract: Antimicrobial powders are obtained by suppporting at least one antimicrobial metal of copper, zinc and alloys thereof on the surface of hydrous titanium oxide or titanium oxide particles by electroless plating, vapor deposition, compression mixing, mixing and reducing, and thermal decomposition of a compound. These powders are used to provide antimicrobial resin compositions, antimicrobial rubber compositions, antimicrobial glass compositions and antimicrobial coating compositions.
    Type: Grant
    Filed: January 9, 1991
    Date of Patent: September 15, 1992
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Kenichi Ichimura, Hajime Murakami, Nobutoshi Yamada, Sadanori Mizukoshi
  • Patent number: 5137575
    Abstract: TiO.sub.2 -based chromatic pigments are provided by coating core particles of TiO.sub.2 having a mean particle size from 0.01 to 0.1 .mu.m with a layer of metal oxide of Ni, Co, Ce, Cu, Cr, Mn, V, W or a mixutre thereof.
    Type: Grant
    Filed: May 30, 1990
    Date of Patent: August 11, 1992
    Assignee: Tayca Corporation
    Inventors: Takashi Yasuki, Shunji Idei
  • Patent number: 5108508
    Abstract: Novel rutile mixed phase pigment microgranulates are disclosed which comprise hemispherical particles indented to form toroid-shaped beads. The microgranulates are free-flowing, non-dust forming, and are stable in handling.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: April 28, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jakob Rademachers, Hans-Ulrich Hofs, Dieter Rade
  • Patent number: 5091012
    Abstract: Disclosed herein are cobalt titanate particles having an average particle diameter in the range of 0.5-2.0 .mu.m, said particles being mono-dispersed and having uniform particle size distribution.
    Type: Grant
    Filed: June 14, 1991
    Date of Patent: February 25, 1992
    Assignee: Toda Kogyo Corp.
    Inventor: Tatsuya Nakamura
  • Patent number: 5017231
    Abstract: A heat-resistant pigment can be produced by forming a dense and uniform coating on the surface of the pigment by contacting a hydrophilic pigment with a metal oxide in at least partly water-miscible solvent.
    Type: Grant
    Filed: January 3, 1990
    Date of Patent: May 21, 1991
    Assignee: Mitsubishi Kinzoku Kabushiki Kaisha
    Inventors: Akira Nishihara, Makoto Tsunashima
  • Patent number: 4979991
    Abstract: A production process of pigment according to this invention comprises the steps of: a first step of forming an inorganic compound coating layer on the entire surfaces of scaly substrates made of ceramic; a second step of forming metallic glossy dots on the surfaces of the inorganic compound coating layer in a scattered manner by an electroless plating, and the metallic glossy dots occupying from 0.05 to 95% of the surfaces of the inorganic compound coating layer with respect to the total surface area of the inorganic compound coating layer; and a third step of irradiating ultraviolet ray on particles formed by the second step. The impurities and the like, which adversely affect the color hue of the pigment, have been discolored or faded away by the ultraviolet ray irradiation in the third step. Accordingly, the pigment having good weather resistance can be produced readily and stably by the present invention.
    Type: Grant
    Filed: September 18, 1989
    Date of Patent: December 25, 1990
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Junichi Handa, Hiroshi Itou, Taketoshi Minohara, Yoshio Takagi
  • Patent number: 4976787
    Abstract: A pigment comprises a substrate, a metallic layer formed on at least one surface of the substrate and imparting metallic luster, and a transparent inorganic compound layer formed on surfaces of the substrate and the metallic layer. Thereby, the pigment produces color by light interference of a ray reflected on a surface of the transparent inorganic compound layer and a ray passed through the transparent inorganic compound layer and reflected on a surface of the metallic layer. Thus, the pigment is excellent in coloring power and hiding power, and particularly useful for an automotive finishing paint.
    Type: Grant
    Filed: March 14, 1990
    Date of Patent: December 11, 1990
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Hiroshi Ito, Junichi Handa, Yoshio Takagi, Taketoshi Minohara