Antimony, Chromium, Arsenic, Or Tin Compound Containing (sb, Cr, As, Sn) Patents (Class 106/441)
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Patent number: 11142648Abstract: A method of treating particulate titanium dioxide includes providing the particulate titanium dioxide which includes a crystal structure and then treating the particulate titanium dioxide with a coating agent that is an alkylphosphonic acid or an ester thereof, and steam micronizing the particulate titanium dioxide with a steam micronizer so that a vapor exit temperature from the steam micronizer is 150° C. or higher, so as to obtain a micronized particulate titanium dioxide which includes the coating agent at an outer surface. The particulate titanium dioxide includes an aluminum oxide coating and/or includes within the crystal structure aluminum oxide in a molar excess of an amount required to compensate any Nb2O5 in the crystal structure. The alkylphosphonic acid includes a C6-C22 alkyl group.Type: GrantFiled: September 23, 2016Date of Patent: October 12, 2021Assignee: HUNTSMAN P&A UK LIMITEDInventors: Anthony G. Jones, David Williamson, Peter Costello, John L. Edwards
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Patent number: 10870743Abstract: Coated pigments for plastics, as well as processes for production of the pigments, the use thereof for colouring polyvinyl chloride (PVC), processes for colouring PVC, PVC coloured with such coated pigments, and also plastics products including such coated pigments, may include inorganic pigments coated with of at least one of hydroxides of magnesium, hydroxides of calcium, oxides of magnesium, and oxides of calcium.Type: GrantFiled: December 13, 2013Date of Patent: December 22, 2020Assignee: LANXESS Deutschland GmbHInventors: Krzysztof Chlopek, Ulrich Meisen, Ralf Gerhard Koenig
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Patent number: 9236605Abstract: Provided is a positive electrode active material capable of obtaining high capacity density and also capable of obtaining sufficient charge-discharge characteristics in a region which involves high current density, when the positive electrode active material is used in a non-aqueous electrolyte secondary battery. The positive electrode active material for the non-aqueous electrolyte secondary battery includes FeF3 in which at least a part of a surface thereof is coated with an electroconductive metal oxide.Type: GrantFiled: September 12, 2013Date of Patent: January 12, 2016Assignee: HONDA MOTOR CO., LTD.Inventors: Kaoru Omichi, Yuji Isogai, Shintaro Aoyagi
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Patent number: 9023147Abstract: There is provided provide a method for efficiently producing a rutile type titanium sol having a particle diameter based on dynamic light scattering method of 5 nm to 100 nm that is excellent in dispersibility. The method for producing a rutile type titanium oxide sol comprising: process (a): mixing metastannic acid, a titanium alkoxide, a quaternary ammonium hydroxide, oxalic acid, and water so as to contain 0.02 moles to 0.8 moles of tin atoms, 0.1 moles to 3.5 moles of the quaternary ammonium hydroxide, and 0.1 moles to 8.0 moles of the oxalic acid with respect to 1 mole of titanium atoms of the titanium alkoxide to prepare a titanium-containing aqueous solution with a concentration in terms of TiO2 of 0.1% by mass to 15% by mass; and process (b): subjecting the titanium-containing aqueous solution obtained in process (a) to a hydrothermal treatment at a temperature from 100° C. to 170° C.Type: GrantFiled: November 30, 2012Date of Patent: May 5, 2015Assignee: Nissan Chemical Industries, Ltd.Inventors: Natsumi Murakami, Ai Miyamoto, Yoshinari Koyama
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Patent number: 8974592Abstract: The present invention relates to a coating composition containing metal oxide particles with a high refractive index and low photocatalytic activity and a coating film obtained by applying the coating composition onto a substrate. The coating composition contains metal oxide particles with a high refractive index obtained by coating the specific fine particles of the titanium-based oxide on their surfaces with at least a silica-based oxide or a silica-based composite oxide, and the coating film is obtained by applying the coating composition onto a substrate. The metal oxide particles with not only a high refractive index but also low photocatalytic activity, and therefore a coating film with excellent weathering resistance and light resistance can be formed on a substrate.Type: GrantFiled: August 12, 2009Date of Patent: March 10, 2015Assignee: JGC Catalysts and Chemicals, Ltd.Inventors: Yoichi Ishihara, Sachio Murai, Toshiharu Hirai, Michio Komatsu
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Patent number: 8932512Abstract: The present invention relates to polymers comprising absorption pigments, which are distinguished by the fact that they have high absorption in the near IR region, and to the use thereof, in particular in thermoforming and in IR light welding.Type: GrantFiled: July 26, 2006Date of Patent: January 13, 2015Assignee: Merck Patent GmbHInventors: Gerhard Edler, Rainer Linzmeier
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Publication number: 20140261085Abstract: A compound or a pigment comprising a compound where there is simultaneous substitution of more or more elements onto both the A and B sites of a pyrochlore lattice or a lattice related to a pyrochlore. The pigment comprises a compound with the formula of AyA?y?BxB?x?Zp. Elements A and A? have a valence of 1, 2, or 3; and are selected from the elements of groups 1, 2, 12, 13, 14, 15, and the first row of transition metals, excluding H, Pb, Cd, Hg, N, As, and Tl. Elements B and B? have a valence of 3, 4, 5, or 6; and are selected from the elements of the first, second, or third row of transition metals, groups 13, 14, and 15, excluding V, C, Pb, and Tl. Element Z is selected from O, F, N, a chalcogen, S, Se, hydroxide ion, and mixtures thereof.Type: ApplicationFiled: March 14, 2014Publication date: September 18, 2014Applicant: The Shepherd Color CompanyInventors: Simon K. Boocock, Andrew E. Smith, Miroslav Trojan
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Publication number: 20140251185Abstract: The present invention provides a CICP that maintains high durability and excellent color properties inherent in chromium-containing CICP while allowing a reduced amount of hexavalent chromium elution from the pigment. The CICP with reduced elution of hexavalent chromium therefrom characterized in that the pigment consists of: a pigment component selected from the group consisting of Colour Index (C.I.) Pigment Blue 36, C.I. Pigment Green 17, C.I. Pigment Green 51, C.I. Pigment Green 26, C.I. Pigment Yellow 162, C.I. Pigment Yellow 163, C.I. Pigment Red 233, C.I. Pigment Red 235, C.I. Pigment Red 236, C.I. Pigment Red 230, C.I. Pigment Brown 24, C.I. Pigment Brown 33, C.I. Pigment Brown 35, C.I. Pigment Brown 39, C.I. Pigment Brown 40, C.I. Pigment Brown 46, C.I. Pigment Black 27, C.I. Pigment Black 28, C.I. Pigment Brown 29, and C.I. Pigment Black 30; and an additive component in an amount of 0.Type: ApplicationFiled: November 2, 2012Publication date: September 11, 2014Applicant: TOKAN MATERIAL TECHNOLOGY CO., LTD.Inventors: Naoko Harada, Shuzo Mihara, Seiichi Kadooka, Hisashi Kamatani
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Publication number: 20140199554Abstract: A metal oxide particle containing titanium oxide coated with silicon dioxide-stannic oxide complex oxide including: a titanium oxide-containing core particle (A); and a coating layer with which the titanium oxide-containing core particle (A) is coated and that is made of silicon dioxide-stannic oxide complex oxide colloidal particles (B) having a mass ratio of silicon dioxide/stannic oxide of 0.1 to 5.0, wherein one or more intermediate thin film layers that are made of any one of an oxide; a complex oxide of at least one element selected from the group consisting of Si, Al, Sn, Zr, Zn, Sb, Nb, Ta, and W; and a mixture of the oxide and the complex oxide are interposed between the titanium oxide-containing core particle (A) and the coating layer made of the silicon dioxide-stannic oxide complex oxide colloidal particles (B).Type: ApplicationFiled: June 1, 2012Publication date: July 17, 2014Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Yoshinari Koyama, Tomoki Furukawa, Motoko Asada
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Patent number: 8585818Abstract: The present disclosure relates to a method of making coated perlite flakes comprises: (i) providing perlite flakes; (ii) applying a layer of tin oxide on the perlite flakes to obtain tin oxide coated perlite flakes; (iii) applying a layer titanium dioxide on the tin oxide coated perlite flakes obtained in step (ii) to obtain titanium dioxide and tin oxide coated perlite flakes; and (iv) applying a layer of iron oxide to the titanium dioxide and tin oxide coated perlite flakes to obtain the coated perlite flakes. The present disclosure also relates to coated perlite flakes comprising: perlite flakes with layer of tin oxide, then a layer of titanium dioxide, and then a layer of iron oxide.Type: GrantFiled: March 14, 2013Date of Patent: November 19, 2013Assignee: BASF SEInventor: Steven Alan Jones
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Publication number: 20130149363Abstract: The present invention relates to five-layered pigments based on multicoated platelet-shaped substrates which comprise a layer sequence comprising (A) a layer of SnO2 having a layer thickness of 0.1-50 nm, (B) a high-refractive-index coating consisting of TiO2 in the rutile modification having a layer thickness of 10-800 nm, (C) a colorless coating having a refractive index n?1.8 having a layer thickness of 20-800 nm, (D) a high-refractive-index coating consisting of SnO2 having a layer thickness of 0.1-50 nm, (E) a layer of TiO2 in the rutile modification having a layer thickness of 10-800 nm, and optionally (F) an outer protective layer, and to the use thereof in paints, coatings, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, as dopants for the laser marking of papers and plastics, in cosmetic formulations and for the preparation of pigment preparations and dry preparations.Type: ApplicationFiled: February 8, 2013Publication date: June 13, 2013Applicant: MERCK PATENT GMBHInventor: MERCK PATENT GMBH
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Patent number: 8409343Abstract: An organic-inorganic hybrid pigment composition is provided comprising an organic pigment, an inorganic pigment, and a fibrous clay. The fibrous clay can be selected from palygorskite, sepiolite, or a combination thereof. The inorganic pigment is selected from rutile pigments, spinel pigments, bismuth vanadate pigments, cerium sulfide pigments, and combinations thereof. The organic pigment is selected from anthraquinone pigments, anthrathrone pigments, anthrapyrimidine pigments, azo pigments, azomethine pigments, quinacridone pigments, quinophthalone pigments, diketopyrrolopyrrol pigments, inanthrone pigments, isoindoline pigments, metal complex pigments, perinone pigments, perylene pigments, phthalocyanine pigments, pyranthrone pigments, pyrazolo-quinazolone pigments, thioindigo pigments, and combinations thereof.Type: GrantFiled: January 21, 2009Date of Patent: April 2, 2013Assignee: Mayan Pigments, Inc.Inventors: Lori A. Niewold, Robyn Torres, Gary E. Williams
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Publication number: 20130008346Abstract: Complex inorganic titanate pigments with low dopant levels (i.e., less than about 5%) exhibit coloristic and enhanced infrared (IR) reflectance characteristics that make them useful in formulating colors exhibiting high IR reflectivity. This characteristic is becoming increasingly useful as a way to keep exterior surfaces and articles cooler during exposure to direct sunlight. Achieving this can decrease energy (e.g., cooling/air conditioning) consumption and costs. Low-loaded titanates can boost IR reflectivity by 1 to 10% in selected visual color spaces. Paint compositions containing those low loaded titanate pigments and a method for providing a surface with high infrared reflectance utilizing those pigments are also disclosed.Type: ApplicationFiled: July 3, 2012Publication date: January 10, 2013Applicant: The Shepherd Color CompanyInventors: James White, Doris Montgomery
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Publication number: 20120160130Abstract: A tinting system for producing a defined number of shades of a paint ready for use characterized by: (a) a dye set, (b) a color identification means, and (c) plurality of metering means for accommodating a shade component, and a brightening component. Each metering means being designed to manually meter the respective dye component and to exactly reproduce the number of shades defined by the color identification means.Type: ApplicationFiled: June 1, 2010Publication date: June 28, 2012Applicant: HEUBACH GMBHInventor: Rainer Heubach
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Patent number: 8137596Abstract: A transparent titanium oxide in which the titanium oxide particles have been coated with a hydrated metal oxide having no photocatalytic activity in order to block photocatalytic activity. Hydrous titanium oxide sol particles are coated with a layer comprising a hydrated oxide of silicon. The coating layer can further contain a hydrated oxide of at least one metal selected among tin, aluminum, and zirconium and a hydrated oxide of antimony. Also provided are a process for producing a sol of surface-coated transparent titanium oxide and a coating composition containing a sol of surface-coated transparent titanium oxide.Type: GrantFiled: September 10, 2007Date of Patent: March 20, 2012Assignee: Tayca CorporationInventor: Nobuyuki Yokoyama
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Publication number: 20120034178Abstract: The present invention relates to novel pigment mixtures comprising at least two different particulate components A and B. The first component A comprises titanium suboxide(s), a titanium oxynitride or a titanium nitride species. Component B particle comprises inorganic, or organic pigments. The titanium suboxide particles display a bluish metallic luster, are new and form a further aspect of the present invention. When combined with particles from component B such as variously coated micas, for example, the bluish or bluish/black metallic color effect from component A leads to special color effects in the various mixtures.Type: ApplicationFiled: October 21, 2011Publication date: February 9, 2012Inventors: Patrice Bujard, Philippe Bugnon, Marc Mamak, Urs Leo Stadler
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Patent number: 8038786Abstract: Disclosed are heat-ray cutoff compounds, films and method using them. The heat-ray compound is produced by dispersing conductive nanoparticles in an amphoteric solvent with acids and dispersion sol, which provides a low cost production for the heat-ray cutoff films because it is able to any resin binder without sorting the kinds of resin binders (hydrolic or alcoholic, or anti-hydrolic).Type: GrantFiled: March 17, 2003Date of Patent: October 18, 2011Assignee: Hae-Wook LEEInventors: Hae-Wook Lee, Jin-Hong Park
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Publication number: 20110201749Abstract: The invention provides a pigment, the production and use thereof, furthermore a polymeric material delustred with pigments, processes for producing this polymeric material, and the use thereof.Type: ApplicationFiled: April 28, 2011Publication date: August 18, 2011Inventors: Jurgen KASTNER, Hartmut Wagner, Bernard Becker
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Patent number: 7951420Abstract: A method of preparing a pigment exhibiting a color-shifting effect, including at least heating mica powder suspension in water, adjusting the pH value of the mixture to between 2 and 9, adding a first inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 6 and 14, adding a second inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 2 and 9, adding a third inorganic salt solution, maintaining the pH value of the mixture constant, and stirring the mixture at constant temperature.Type: GrantFiled: September 26, 2009Date of Patent: May 31, 2011Inventors: Jiansheng Fu, Yiting Peng, Xiaohui Tian
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Patent number: 7951855Abstract: What is disclosed is a plurality of prepaints which are used in any combination to produce base paints and/or colored paints of varying end-use application characteristics. Additionally, a mobile paint factory for producing a plurality of lines of architectural coatings from a plurality of prepaints en route to and/or at various locations is disclosed. The mobile paint factory may include a vehicle having a paint production system and a paint mixer located thereon. Furthermore, a method of producing a plurality of lines of user-selected architectural coatings from a plurality of prepaints en route to and/or at various locations is disclosed. The method may include: providing a mobile paint factory; prompting a user to select through the paint production system an interior or exterior application environment, a paint sheen, and a paint quality; automatically dispensing predetermined amounts of appropriate prepaints; and agitating the dispensed prepaints.Type: GrantFiled: December 18, 2008Date of Patent: May 31, 2011Assignee: Microblend Technologies, Inc.Inventors: Daniel K. Trevino, III, Mel Sauder, Randall L. Hughes, David C. Philbrook, C. Daniel McClain
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Patent number: 7919546Abstract: What is disclosed is a plurality of prepaints which are used in any combination to produce base paints and/or colored paints of varying end-use application characteristics. Additionally, a mobile-paint factory for producing a plurality of lines of architectural coatings from a plurality of prepaints en route to and/or at various locations is disclosed. The mobile paint factory may include a vehicle having a paint production system and a paint mixer located thereon. Furthermore, a method of producing a plurality of lines of user-selected architectural coatings from a plurality of prepaints en route to and/or at various locations is disclosed. The method may include: providing a mobile paint factory; prompting a user to select through the paint production system an interior or exterior application environment, a paint sheen, and a paint quality; automatically dispensing predetermined amounts of appropriate prepaints; and agitating the dispensed prepaints.Type: GrantFiled: August 15, 2008Date of Patent: April 5, 2011Assignee: Microblend Technologies, Inc.Inventors: Daniel K. Trevino, III, Mel Sauder, Randall L. Hughes, David C. Philbrook, C. Daniel McClain, Mel Sauder, legal representative
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Publication number: 20100298482Abstract: An organic-inorganic hybrid pigment composition is provided comprising an organic pigment, an inorganic pigment, and a fibrous clay. The fibrous clay can be selected from palygorskite, sepiolite, or a combination thereof. The inorganic pigment is selected from rutile pigments, spinel pigments, bismuth vanadate pigments, cerium sulfide pigments, and combinations thereof. The organic pigment is selected from anthraquinone pigments, anthrathrone pigments, anthrapyrimidine pigments, azo pigments, azomethine pigments, quinacridone pigments, quinophthalone pigments, diketopyrrolopyrrol pigments, inanthrone pigments, isoindoline pigments, metal complex pigments, perinone pigments, perylene pigments, phthalocyanine pigments, pyranthrone pigments, pyrazolo-quinazolone pigments, thioindigo pigments, and combinations thereof.Type: ApplicationFiled: January 21, 2009Publication date: November 25, 2010Inventors: Lori A. Niewold, Robyn Torres, Gary E. Williams
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Publication number: 20100218703Abstract: The present invention relates to pigments comprising (A) a platelet-shaped substrate (S), (B) a coating comprising two different metal oxides having a difference in refractive index of at least 0.1, wherein the metal oxide having a higher refractive indexis the metal oxide MOH and the metal oxide having a lower refractive index is the metal oxide MOL, wherein the amount of MOH and the amount of MOL changes (continuously), (C) a coating comprising metal oxides MOH and MOL, wherein the amount of MOH and the amount of MOL changes (continuously), and (D) optionally an outer protecting layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass. The pigments can show enhanced colour chroma while maintaining the lightness of coventional interference pigments, or vice versa.Type: ApplicationFiled: July 21, 2008Publication date: September 2, 2010Inventors: Patrice Bujard, Philippe Bugnon
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Publication number: 20100189666Abstract: The present invention provides products comprising rutile-type titanium dioxide of a specific shape, i.e., cosmetics which have high UV blocking ability, provide a good feel upon use without leaving squeakiness or graininess on the skin, and also give a natural bare skin appearance without causing white masking, due to adequate tinting strength and covering power, as well as external additives for toner which are excellent in prevention of filming on a photosensitive member and inhibition of aggregation between toner particles.Type: ApplicationFiled: January 26, 2010Publication date: July 29, 2010Applicant: TITAN KOGYO KABUSHIKI KAISHAInventors: Akira NAKAMURA, Masayasu MORISHITA, Hiromasa KONDOH
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Patent number: 7754106Abstract: A release agent is flash evaporated and deposited onto a support substrate under conventional vapor-deposition conditions and a conductive metal oxide, such as ITO, is subsequently sputtered or deposited by reactive electron beam onto the resulting release layer in the same process chamber to form a very thin film of conductive material. The resulting multilayer product is separated from the support substrate, crushed to brake up the metal-oxide film into flakes, and heated or mixed in a solvent to separate the soluble release layer from the metallic flakes. Thus, by judiciously controlling the deposition of the ITO on the release layer, transparent flakes may be obtained with the desired optical and physical characteristics.Type: GrantFiled: June 7, 2006Date of Patent: July 13, 2010Assignee: Sigma Laboratories of Arizona, LLCInventors: Michael G. Mikhael, Angelo Yializis
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Publication number: 20100148135Abstract: A transparent titanium oxide in which the titanium oxide particles have been coated with a hydrated metal oxide having no photocatalytic activity in order to block photocatalytic activity. Hydrous titanium oxide sol particles are coated with a layer comprising a hydrated oxide of silicon. The coating layer can further contain a hydrated oxide of at least one metal selected among tin, aluminum, and zirconium and a hydrated oxide of antimony. Also provided are a process for producing a sol of surface-coated transparent titanium oxide and a coating composition containing a sol of surface-coated transparent titanium oxide.Type: ApplicationFiled: September 10, 2007Publication date: June 17, 2010Applicant: TAYCA CORPORATIONInventor: Nobuyuki Yokoyama
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Patent number: 7708823Abstract: The present invention relates to semitransparent interference pigments having a neutral mass tone comprising a substrate and a coating comprising metallic tin and additionally at least one metal oxide, to a process for the preparation of these pigments, and to the use thereof.Type: GrantFiled: June 9, 2006Date of Patent: May 4, 2010Assignee: Merck Patent GmbHInventors: Helge Bettina Kniess, Klaus Bernhardt, Wolf-Dietrich Weber, Gerhard Pfaff
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Publication number: 20100064941Abstract: A pearlescent pigment includes a ceramic flake coated with a metal oxide. The metal oxide is, preferably, an oxide of titanium, iron, tin, chromium1, zirconium or a combination thereof, and the refractive index of the metal oxide coating is preferably at least 0.5 higher than that of the ceramic flake. The pearlescent pigment may be included in a coating applied to a metallic or plastic surface to give the surface a lustrous or pearlescent optical effect.Type: ApplicationFiled: October 30, 2007Publication date: March 18, 2010Inventor: Charles Watkinson
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Patent number: 7658793Abstract: The invention relates to a pigment preparation based on at least one inorganic pigment and at least one organic pigment, and to a method for producing one such pigment preparation. Said pigment preparation contains particles wherein fine organic pigment particles are combined with inorganic pigment particles, said particles also being provided with an organic macromolecular coating. The inventive pigment preparation is produced by wet-grinding the inorganic and organic pigments, optionally adding other constituents, in the presence of a surface-active substance in the form of a macromolecular organic compound.Type: GrantFiled: March 5, 2004Date of Patent: February 9, 2010Assignee: Heubach GmbHInventors: Rainer Heubach, Yvonne Brussaard, Hugo Brussaard
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Publication number: 20100011992Abstract: The present invention relates to novel pigment mixtures comprising at least two different particulate components A and B. The first component A comprises titanium suboxide(s), a titanium oxynitride or a titanium nitride species. Component B particle comprises inorganic, or organic pigments. The titanium suboxide particles display a bluish metallic luster, are new and form a further aspect of the present invention. When combined with particles from component B such as variously coated micas, for example, the bluish or bluish/black metallic color effect from component A leads to special color effects in the various mixtures.Type: ApplicationFiled: December 17, 2007Publication date: January 21, 2010Inventors: Patrice Bujard, Philippe Bugnon, Marc Mamak, Urs Leo Stadler
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Publication number: 20090311209Abstract: The present invention relates to pigments, comprising a plate-like substrate of glass having an average thickness of <1 ?m, especially of from 20 nm to 400 nm, and (a) a dielectric material, especially a metal oxide, having a high index of refraction; or (a) a metal layer, especially a thin semi-transparent metal layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.Type: ApplicationFiled: June 12, 2006Publication date: December 17, 2009Inventor: Patrice Bujard
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Publication number: 20090275686Abstract: A pigment, the production and use thereof, furthermore a polymeric material delustered with pigments, processes for producing this polymeric material, and the use thereof.Type: ApplicationFiled: June 11, 2007Publication date: November 5, 2009Inventors: Jurgen Kastner, Hartmut Wagner, Bernard Becker
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Patent number: 7592065Abstract: There are disclosed insulated ultrafine powder comprising electroconductive ultrafine powder which is in the form of sphere, spheroid or acicular each having a minor axis in the range of 1 to 100 nm and an insulating film applied thereto; a process for producing the same which is capable of covering the surfaces of the insulated ultrafine powder with the insulating film having a thickness in the range of 0.3 to 100 nm without causing any clearance or vacancy; and a resin composite material which uses the same. A high dielectric constant of the material is assured by adding a small amount of insulated ultrafine powder wherein an insulating film is applied to the electroconductive ultrafine powder, while maintaining the processability and moldability that are the characteristics inherent in a resin material.Type: GrantFiled: February 13, 2004Date of Patent: September 22, 2009Assignee: Mitsubishi Gas Chemical Company Inc.Inventors: Takahiro Matsumoto, Toshiaki Yamada, Hirotaka Tsuruya
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Patent number: 7575731Abstract: The present invention relates to fine particles of a tin-modified rutile-type titanium dioxide obtained through the reaction of an aqueous solution of a titanium compound having a Ti concentration of 0.07 to 5 mol/l at a pH in the range of ?1 to 3 in the co-presence of a tin compound at a molar ratio of tin to titanium (Sn/Ti) of 0.001 to 2, wherein said fine particle has an Sn/Ti composition molar ratio of 0.001 to 0.5, and a short axis and a long axis of a crystal grain diameter thereof have a length of 2 to 20 nm.Type: GrantFiled: June 29, 2005Date of Patent: August 18, 2009Assignee: Mitsui Chemicals, Inc.Inventors: Tomonori Iijima, Norio Nakayama, Toyoharu Hayashi
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Publication number: 20090126604Abstract: A flame spray pyrolysis process for the preparation of ultrafine titania particles coated with a smooth, homogeneous coating of one or more metal oxides is provided. The metal oxide coating is achieved by contacting the titania particles with a metal oxide precursor downstream of the titania formation zone, after the titania particles have formed. The process provides titania particles with a high rutile content and a smooth and homogeneous coating of a metal oxide.Type: ApplicationFiled: November 16, 2007Publication date: May 21, 2009Inventors: M. Kamal Akhtar, Sotiris Emmanuel Pratsinis, Martin Christian Heine, Alexandra Teleki Harsanyi, Reto Strobel
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Publication number: 20090004390Abstract: The present invention is directed to pigment compositions, thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).Type: ApplicationFiled: June 28, 2007Publication date: January 1, 2009Inventors: Jerome David Smith, Pedro A. Jimenez, Tony Jackson
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Patent number: 7341626Abstract: A pigment composition containing one or more, organic yellow pigments selected from the group C.I. Pigment Yellow (213), Pigment Yellow (214) and disazo pigment of the formula (I) and containing one or more inorganic pigments.Type: GrantFiled: August 18, 2004Date of Patent: March 11, 2008Assignee: Clariant Produkte (Deutschland) GmbHInventors: Joachim Weber, Gerhard Wilker
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Patent number: 7339000Abstract: The present invention is directed to the provision of premixed aqueous compositions which are used to provide a paint composition of varying finish characteristics at the point of sale. Thus, the merchant distributing the paint composition made from the subject premixed compositions need only maintain inventory of four compositions. The particular compositions which are the subject of the invention exhibit stable characteristics during storage in their respective reservoirs. The compositions include a pigment composition, a dispersant thickening agent, a high resin content binder, and a low resin content binder. The compositions are combined in differing amounts to produce paint compositions being suitable for either interior or exterior use and having differing sheens, quality levels, and color bases.Type: GrantFiled: May 24, 2000Date of Patent: March 4, 2008Assignee: Coatings Management Systems Inc.Inventors: C. Daniel McClain, Randall L. Hughes
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Patent number: 7316741Abstract: Described herein are ceramic colorants consisting of suspensions of particles of nanometric dimensions, their production and use.Type: GrantFiled: March 6, 2003Date of Patent: January 8, 2008Assignee: Colorobbia Italia S.p.A.Inventors: Giovanni Baldi, Marco Bitossi, Andrea Barzanti
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Patent number: 7291217Abstract: A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.Type: GrantFiled: July 23, 2003Date of Patent: November 6, 2007Assignee: University of DaytonInventors: Andrew Wells Phelps, Jeffrey Allen Sturgill, Joseph Thomas Swartzbaugh
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Patent number: 7250080Abstract: An improved process for making an organosilicon compound surface-treated titanium dioxide material, comprising (a) forming a mixture of the titanium dioxide material in water, (b) wet milling the mixture, (c) adjusting the pH of the slurry resulting from step (b) to between about 5.0 and about 8.5, (d) after step (c), removing the titanium dioxide material from the mixture by vacuum or pressure filtration, (e) after step (d), washing the titanium dioxide material so removed, (f) after step (e), converting the washed titanium dioxide material to a fluid dispersion having a pH of from about 3.5 to less than about 7 via addition of a fluidizing agent comprising a water-soluble monoprotic acid, (g) after, or concurrently with, step (f), adding to the resulting dispersion of titanium dioxide material an organosilicon compound, with mixing, and (h) spray drying the dispersion of the washed titanium dioxide material resulting from step (g) to yield a dry titanium dioxide pigment powder.Type: GrantFiled: September 6, 2006Date of Patent: July 31, 2007Assignee: Tronox LLCInventors: Daniel H. Craig, Mark D. Westmeyer
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Patent number: 7135065Abstract: The invention relates to a method for the post-treatment of titanium dioxide, in order to produce particularly weather-resistant titanium dioxide pigments with good optical properties. The method is characterized in that, together with the hydrous oxides of tin and zirconium, at least one other from the group comprising aluminium, silicon and titanium is additionally precipitated onto the particle surface. The post-treatment components are added to the aqueous TiO2 suspension either in the acidic range (pH value of 3 at most) or in the alkaline range (pH value of 10 at least). The pH value is subsequently set to between 6 and 8. Final tempering of the pigment at elevated temperatures from over 125° C. to up to 500° C. can improve the tone b. The pigment is particularly suitable for use in paints, coatings and plastics.Type: GrantFiled: July 12, 2005Date of Patent: November 14, 2006Assignee: Kronos InternationalInventors: Lydia Drews-Nicolai, Siegfried Bluemel
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Patent number: 7018465Abstract: A spray glaze or opaque composition for coating dental restorations and other surfaces and objects such as hobby ceramics that comprises about 4 to about 50 weight % glaze material, about 5 to about 60 weight % restoration wetting agent, and about 10 to about 90% non CFC propellant. An opaque composition further comprises about 5 to about 30% opaque material.Type: GrantFiled: July 17, 2003Date of Patent: March 28, 2006Assignee: Enamelite, LLCInventors: Phillip G. Pitts, James R. Vinson
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Patent number: 6911075Abstract: The invention relates to a process for preparing pigments, which comprises subjecting a crude pigment or mixture of crude pigments and a crystalline inorganic salt or mixture of crystalline inorganic salts together, essentially in the absence of other constituents, to the action of a rotor having a tangential speed of at least 10 m/s, so that a temperature of at least 80° C. is attained by means of friction effects; and subsequently kneading the product of this treatment with an organic liquid, during which it is possible if desired to add additional substances selected from the group consisting of inorganic salts, inert additives and colorant. These pigments and their use in polymers, printing inks and colours filters are also claimed. The invention in particular relates to a novel pigment form of Pigment Violet 23 obtained by above-mentioned process and having higher colour strength and colour saturation as well as excellent other applications properties in particular in printing inks.Type: GrantFiled: December 4, 2002Date of Patent: June 28, 2005Assignee: CIBA Specialty Chemicals Corp.Inventors: Yves Grandidier, Albert Riegler, Klaus Ruf, Urs Schlatter, Takashi Deno
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Patent number: 6884289Abstract: The present invention relates to colored pigments based on multicoated platelet-shaped substrates which are distinguished by the fact that they comprise (A) a coating having a refractive index of n>1.8 and a layer thickness of 20-500 nm, (B) a colorless coating having a refractive index of n?1.8 and a layer thickness of 10-100 nm, (C) a colorless coating having a refractive index of n>1.8 and a layer thickness of 20-500 nm, (D) a covering of absorbent pigment particles having a particle size of 1-500 nm, and optionally (E) an outer protective layer, and to their use in paints, coatings, printing inks, plastics, ceramic materials, glasses, for laser marking, in cosmetic formulations and for the production of pigment preparations and dry preparations.Type: GrantFiled: April 24, 2002Date of Patent: April 26, 2005Assignee: Merck Patent GmbhInventors: Sabine Schoen, Christoph Schmidt
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Patent number: 6875264Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack.Type: GrantFiled: January 17, 2003Date of Patent: April 5, 2005Assignee: Engelhard CorporationInventors: Curtis J. Zimmermann, Daniel Stevenson Fuller
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Patent number: 6838494Abstract: The present invention provides a light reflecting polymeric composition that includes at least one halogenated-flame-retardant-additive-free polymer having dispersed therein a pigment package including a combination of Sb2O3 and TiO2. The Sb2O3 and TiO2 preferably have an average particle size within the range of from about 0.05 ?m to about 1.0 ?m, and more preferably about 0.2 ?m. When used in combination, the Sb2O3 and TiO2 pigments synergistically interact together to provide a polymeric composition exhibiting a reflectivity that is substantially higher than can be obtained by the use of either of the pigments alone.Type: GrantFiled: December 30, 2002Date of Patent: January 4, 2005Assignee: Ferro CorporationInventors: Deenadayalu Chundury, Richard Abrams, Ronald M. Harris, Mir Ali, Theophilus G. McGee, II, Susan T. Schmidt
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Patent number: 6821333Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective layer which acts as a reflector to light directed thereon and a spacer pigment layer which is selectively transparent to light directed thereon.Type: GrantFiled: December 13, 2002Date of Patent: November 23, 2004Assignee: Engelhard CorporationInventors: Curtis J. Zimmermann, James D. Christie, Vivian K. Doxey, Daniel Stevenson Fuller
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Publication number: 20040074421Abstract: A composition for colouring the surface of a porous substrate is disclosed comprising a colorant, a binding agent, and a water-repelling agent is disclosed wherein upon application of the composition to the surface of the porous substrate, the composition penetrates the surface through the pores of the substrate, and adds colour to the surface of the porous substrate. Also disclosed is the method for coloring a substrate, a colored surface of a porous substrate and a process for producing such a composition.Type: ApplicationFiled: October 24, 2002Publication date: April 22, 2004Applicant: SILICA PACIFIC PTY. LIMITEDInventor: Stuart Anderson
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Patent number: 6648957Abstract: Multilayer pearl lustre pigment on the basis of a platelet-shaped substrate comprising a material of low refractive index in the range from 1.35 to 1.8, which comprises at least (i) one first layer comprising a material having a refractive index of more than 1.8, (ii) optionally, a second layer comprising a material of low refractive index in the range from 1.35 to 1.8, (iii) a semitransparent metal layer which is applied to the substrate or to the layers (i) or (ii), and (iv) if desired, an aftercoating, the substrate being platelet-shaped silicon dioxide, aluminium oxide, boron oxide or magnesium fluoride.Type: GrantFiled: December 4, 2001Date of Patent: November 18, 2003Assignee: Merck Patent GmbHInventors: Stephanie Andes, Gerald Fuchs-Pohl, Gerhard Pfaff