Alkali Or Alkaline Earth Metal Containing Patents (Class 106/449)
-
Patent number: 11512205Abstract: The purpose of the present invention is to provide a composite pigment which can be dispersed and made into paint in a manner that saves labor compared with conventional flat emulsion paints, and which can achieve concealing properties and low glossiness (a luster reduction effect) without separately adding a matting agent. This composite pigment contains an inorganic compound and/or an organic compound, and a fixed extender pigment.Type: GrantFiled: October 23, 2017Date of Patent: November 29, 2022Assignee: ISHIHARA SANGYO KAISHA, LTD.Inventors: Takeshi Fujimura, Shogo Iseya, Hironori Shimoita, Yusuke Taniguchi
-
Patent number: 10533102Abstract: The invention relates to a pigment composition for preparing pigmented matt coatings, such as matt paints and printing inks. Further, the invention relates to a process for preparing such pigment composition, and to a coating formulation containing such composition. Finally, the invention is directed to a pigmented matt surface of a substrate, and to the use of the pigment compositions disclosed herein for matting substrates.Type: GrantFiled: February 1, 2017Date of Patent: January 14, 2020Assignee: Kronos International, Inc.Inventors: Frank Mersch, Volker Juergens
-
Patent number: 9802833Abstract: Nanowire synthesis and one dimensional nanowire synthesis of titanates and cobaltates. Exemplary titanates and cobaltates that are fabricated and discussed include, without limitation, strontium titanate (SrTiO3), barium titanate (BaTiO3), lead titanate (PbTiO3), calcium cobaltate (Ca3Co4O9) and sodium cobaltate (NaCo2O4).Type: GrantFiled: September 22, 2015Date of Patent: October 31, 2017Assignee: PURDUE RESEARCH FOUNDATIONInventors: Yue Wu, Gautam G. Yadav, Genqiang Zhang
-
Patent number: 9796598Abstract: A method for producing a potassium titanate easily and inexpensively produces a potassium titanate that exhibits high thermal stability and has a significantly low fibrous potassium titanate content. The method for producing a potassium titanate includes calcining a raw material mixture by heating the raw material mixture to a maximum calcination temperature that exceeds 1000° C. while controlling the heating rate from 1000° C. to the maximum calcination temperature to 15° C./min or less to obtain a calcine, and cooling the calcine while controlling the cooling rate from the maximum calcination temperature to 500° C. to 100° C.Type: GrantFiled: March 14, 2014Date of Patent: October 24, 2017Assignee: TOHO TITANIUM CO., LTD.Inventors: Naomichi Hori, Takuma Yoshida
-
Patent number: 9358548Abstract: This disclosure is drawn to systems, devices, apparatuses, and/or methods, related to milling particles in drilling fluid. Specifically, the disclosed systems, devices, apparatuses, and/or methods relate to milling particles in drilling fluid using multiple milling techniques. Some example apparatuses may include a first mill to grind particles from the original diameter to a first reduced diameter, and a second mill to grind the particles from the first reduced diameter to a second reduced diameter, where the second reduced diameter is less than the first reduced diameter.Type: GrantFiled: January 28, 2013Date of Patent: June 7, 2016Assignees: Ecutec Barcelona, S.L., M-I L.L.C.Inventors: Thomas Philip Barthelmess, Sergio Alegre Fernandez-Caro, Philip David Burton, Gary Woolsey
-
Patent number: 9327992Abstract: A pigment particle composition which comprises calcium carbonate particles and pigment particles, its method of manufacture and its use. According to the present invention, the calcium carbonate particles are carbonated so that they bind to each other, in which case calcium carbonate structures are generated, which comprise pigment particles and which form essentially opaque and stable pigment-calcium carbonate aggregates. It is possible to manufacture the composition by atomizing calcium hydroxide-bearing pigment slurry into a carbon dioxide-bearing gas, in which case the calcium hydroxide is carbonated in order to precipitate the calcium hydroxide particles to be attached to each other and the carbonation is continued until essentially all of the calcium hydroxide has been converted into calcium carbonate. The composition is suitable for use, among others, in paints, coating materials, fillers, polymers and printing inks.Type: GrantFiled: March 9, 2009Date of Patent: May 3, 2016Assignee: FP-Pigments OyInventors: Mikko Maijala, Roope Maijala
-
Publication number: 20150096469Abstract: Composite pigments are provided which comprise a mineral pigment (such as kaolin clay, titanium dioxide, talc, mica or a mixture of two or more of these mineral pigments) and calcium carbonate precipitated in-situ on the surfaces of the particles of the mineral pigment.Type: ApplicationFiled: October 3, 2013Publication date: April 9, 2015Inventors: Zhenzhong Zhang, Yaping Li
-
Publication number: 20140343212Abstract: The disclosure provides a coating composition comprising a treated inorganic core particle, having improved dispersability, prepared by a process comprising: heating a slurry comprising porous silica treated inorganic core particle and water at a temperature of at least about 90° C., more typically about 93 to about 97° C., still more typically about 95 to about 97° C.; and adding a soluble alumina source to the slurry while maintaining the pH at about 8.0 to 9.5 to form an alumina treatment on the porous silica treated inorganic core particle; wherein the treated inorganic core particle does not comprise dense silica or alumina treatments, and has silica present in the amount of about 7% to about 14% and alumina present in the amount of about 4.0% to about 8.0%; and wherein the particle to particle surface treatments are substantially homogeneous.Type: ApplicationFiled: October 11, 2012Publication date: November 20, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: Michael Patrick Diebold, Daniel C. Kraiter, Eric Rusnak, Agingu Shih
-
Patent number: 8858701Abstract: The invention relates to the manufacture of pigment-containing composite pigment particles containing titanium dioxide pigment particles and at least one inorganic and/or organic filler as extender, as well as calcium carbonate that is precipitated in the process, and their use for improving the pigment light-scattering efficiency in coatings, plastics and laminates. The extender is preferably selected from Ca-, Ca—Mg- and Mg-carbonates, natural and synthetic silicon dioxide and oxides and are manufactured in a combined process of precipitation and dispersion. Depending on the combination selected, the use of composite pigment particles according to the invention permits pigment savings with little or no loss of optical properties. Alternatively, if the pigment content remains unchanged, it is possible to achieve better values, e.g. for tinting strength. Particularly, a part or the whole TiO2 quantity in the user system can be replaced by the composite pigment particles according to the invention.Type: GrantFiled: June 28, 2013Date of Patent: October 14, 2014Assignee: Kronos International, Inc.Inventors: Uwe Wilkenhoener, Frank Mersch
-
Publication number: 20140179852Abstract: Coating composition providing gloss and opacity on application, having a pigment volume concentration of from 5% up to the critical pigment volume concentration and characterised in that comprises at least one ground natural calcium carbonate having a volume median diameter of between 0.05 and 0.3 ?m, and at least one pigment having a refractive index of greater than or equal to 2.5.Type: ApplicationFiled: February 27, 2014Publication date: June 26, 2014Inventors: Patrick A.C. Gane, Detlet Gysau, George Saunders, Joseph McJunkins
-
Publication number: 20140000484Abstract: The invention relates to the manufacture of pigment-containing composite pigment particles containing titanium dioxide pigment particles and at least one inorganic and/or organic filler as extender, as well as calcium carbonate that is precipitated in the process, and their use for improving the pigment light-scattering efficiency in coatings, plastics and laminates. The extender is preferably selected from Ca-, Ca—Mg- and Mg-carbonates, natural and synthetic silicon dioxide and oxides and are manufactured in a combined process of precipitation and dispersion. Depending on the combination selected, the use of composite pigment particles according to the invention permits pigment savings with little or no loss of optical properties. Alternatively, if the pigment content remains unchanged, it is possible to achieve better values, e.g. for tinting strength. Particularly, a part or the whole TiO2 quantity in the user system can be replaced by the composite pigment particles according to the invention.Type: ApplicationFiled: June 28, 2013Publication date: January 2, 2014Inventors: Uwe Wilkenhoener, Frank Mersch
-
Publication number: 20130216832Abstract: Heat reflective dry mix comprising of dry particulate, the said dry particulate matter comprising of pigment in the range of 20 to 45%, the balance proportion being extenders/fillers wherein the extenders/fillers shall consist of calcium carbonate not less than 15% with respect to total particulate matter having the average particle size of the dry particulate matter in the range of 2 to 6 micrometers.Type: ApplicationFiled: July 11, 2011Publication date: August 22, 2013Applicant: Institute of Chemical TechnologyInventors: Ramanand N. Jagtap, Bhupesh Marathe
-
Publication number: 20130202879Abstract: Coating composition providing gloss and opacity on application, having a pigment volume concentration of from 5% up to the critical pigment volume concentration and characterised in that comprises at least one ground natural calcium carbonate having a volume median diameter of between 0.05 and 0.3 ?m, and at least one pigment having a refractive index of greater than or equal to 2.5.Type: ApplicationFiled: January 25, 2011Publication date: August 8, 2013Inventors: Patrick A.C. Gane, Detlef Gysau, George Saunders, Joseph McJunkins
-
Patent number: 8475582Abstract: The present invention relates to a process for making a titanium dioxide pigment consisting of titanium dioxide and single layer of inorganic surface treatment consisting of aluminum phosphate wherein the pigment is characterized by and isoelectric point which is greater than pH 6 and a negative zeta potential of at a pH of 7.5 or more.Type: GrantFiled: March 6, 2008Date of Patent: July 2, 2013Assignee: E I du Pont de Nemours and CompanyInventors: Erik Shepard Thiele, John Davis Bolt, Scott Richard Mehr
-
Publication number: 20120301526Abstract: Nanomaterials of the JT phase of the titanium oxide TiO2-x, where 0?x?1 having as a building block a crystalline structure with an orthorhombic symmetry and described by at least one of the space groups 59 Pmmn, 63 Amma, 71 Immm or 63 Bmmb. The nanomaterials are in the form of nanofibers, nanowires, nanorods, nanoscrolls and/or nanotubes and are obtained from a hydrogen titanate and/or a mixed sodium and hydrogen titanate precursor compound that is isostructural to the JT crystalline structure. The titanates are the hydrogenated, the protonated, the hydrated and/or the alkalinized phases of the JT crystalline phase that are obtained from titanium compounds such as titanium oxide with an anatase crystalline structure, amorphous titanium oxide, and titanium oxide with a rutile crystalline structure, and/or directly from the rutile mineral and/or from ilmenite.Type: ApplicationFiled: June 19, 2012Publication date: November 29, 2012Applicant: INSTITUTO MEXICANO DEL PETROLEOInventors: José Antonio Toledo Antonio, Carlos Angeles Chávez, Maria Antonia Cortés Jacome, Fernando Alvarez RamÍrez, Yosadara Ruiz Morales, Gerardo Ferrat Torres, Luis Francisco Flores Ortiz, Esteban López Salinas, Marcelo Lozada y Cassou
-
Patent number: 8221834Abstract: A titania composite and a preparing method thereof are provided. The titania composite comprises an inner core and a coating film layer, wherein the inner core is a barium sulfate crystal and/or a strontitum sulfate crystal with subsphaeroidal shape, having a particle size of less than 1 ?m and whiteness of more than 98%, and the coating film layer is nano rutile titania. The preparing method thereof comprises the following steps: (a) preparing barium sulfate or strontium sulfate; (b) coating treatment; (c) subjecting the titania composite to a high-temperature heat treatment; and (d) subjecting the titania composite to a post treatment. The subsphaeroidal titania composite is obtained by chemically synthesizing a subsphaeroidal submicron barium sulfide or strontium sulfide, and then hydrolyzing and coating thereon to form a coating film layer of titania to make titania grow evenly.Type: GrantFiled: December 30, 2009Date of Patent: July 17, 2012Assignee: Chongqing Kechang Technology Co., Ltd.Inventors: Dong Hua, Zhengtao Liu
-
Patent number: 8197591Abstract: The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.Type: GrantFiled: February 23, 2007Date of Patent: June 12, 2012Assignee: Eckart GmbHInventors: Günter Kaupp, Ulrich Schmidt
-
Publication number: 20120094139Abstract: Kaolin clay pigments which contain a minor amount of gypsum provide improved properties of brightness, opacity and bulking to coated sheets.Type: ApplicationFiled: December 20, 2011Publication date: April 19, 2012Inventor: Zhenzhong Zhang
-
Patent number: 8129022Abstract: A fluororesin film, of which discoloration, a change in the visible light transmittance and a decrease in the mechanical strength can be suppressed for a long period of time even though it contains titanium oxide, the fluorescent film having a pigment dispersed in a fluororesin, which pigment are composite particles each comprising a particle containing titanium oxide, a first covering layer containing cerium oxide and a second covering layer containing silicon oxide in this order from the inside, wherein the amount of cerium oxide is from 5 to 30 parts by mass based on 100 parts by mass of titanium oxide, the amount of silicon oxide is from 5 to 60 parts by mass based on 100 parts by mass of titanium oxide, and the average particle size of the composite particles is from 0.15 to 3 ?M; and a process for its production.Type: GrantFiled: June 18, 2009Date of Patent: March 6, 2012Assignee: Asahi Glass Company, LimitedInventor: Hiroshi Aruga
-
Patent number: 8070874Abstract: The invention provides a surface-modified titanium dioxide particle inhibited in photocatalytic activity and reduced in amount of volatile water. The surface-modified titanium dioxide particle has on the surface a crystalline composite compound of at least one of alkaline earth metals selected from magnesium, calcium, barium and strontium complexed with titanium dioxide in an amount of 0.1-20% by weight based on the weight of the surface-modified titanium dioxide particle in terms of oxide of the alkaline earth metal. The surface-modified titanium dioxide particle is produced by heating a compound of an alkaline earth metal and a titanium dioxide particle at a temperature of 60° C. or higher so that the alkaline earth metal is complexed with titanium dioxide to form a crystalline composite compound on the surface of the titanium dioxide particle in an amount of 0.1-20% by weight based on the weight of the surface-modified titanium dioxide particle in terms of oxide of the alkaline earth metal.Type: GrantFiled: June 25, 2010Date of Patent: December 6, 2011Assignee: Sakai Chemical Industry, Co., Ltd.Inventors: Kazunobu Abe, Kazumi Sugimoto, Atsuki Terabe, Masaru Mikami
-
Publication number: 20110253012Abstract: A titania composite and a preparing method thereof are provided. The titania composite comprises an inner core and a coating film layer, wherein the inner core is a barium sulfate crystal and/or a strontitum sulfate crystal with subsphaeroidal shape, having a particle size of less than 1 ?m and whiteness of more than 98%, and the coating film layer is nano rutile titania. The preparing method thereof comprises the following steps: (a) preparing barium sulfate or strontium sulfate; (b) coating treatment; (c) subjecting the titania composite to a high-temperature heat treatment; and (d) subjecting the titania composite to a post treatment. The subsphaeroidal titania composite is obtained by chemically synthesizing a subsphaeroidal submicron barium sulfide or strontium sulfide, and then hydrolyzing and coating thereon to form a coating film layer of titania to make titania grow evenly.Type: ApplicationFiled: December 30, 2009Publication date: October 20, 2011Applicant: CHONGQING KECHANG TECHNOLOGY CO., LTD.Inventors: Dong Hua, Zhengtao Liu
-
Publication number: 20110011305Abstract: A pigment particle composition which comprises calcium carbonate particles and pigment particles, its method of manufacture and its use. According to the present invention, the calcium carbonate particles are carbonated so that they bind to each other, in which case calcium carbonate structures are generated, which comprise pigment particles and which form essentially opaque and stable pigment-calcium carbonate aggregates. It is possible to manufacture the composition by atomizing calcium hydroxide-bearing pigment slurry into a carbon dioxide-bearing gas, in which case the calcium hydroxide is carbonated in order to precipitate the calcium hydroxide particles to be attached to each other and the carbonation is continued until essentially all of the calcium hydroxide has been converted into calcium carbonate. The composition is suitable for use, among others, in paints, coating materials, fillers, polymers and printing inks.Type: ApplicationFiled: March 9, 2009Publication date: January 20, 2011Applicant: FP-Pigments OyInventors: Mikko Maijala, Roope Maijala
-
Publication number: 20100330288Abstract: Disclosed are methods for reclaiming inorganic material from waste carpeting. The method comprises providing a waste carpeting composition comprising an inorganic filler component and an organic component. The waste carpeting is heat treated under conditions effective to separate at least a portion of the organic component from the waste carpeting composition and to provide a reclaimed inorganic filler composition at least substantially free of the organic component. Also disclosed are carpets comprising the reclaimed inorganic material reclaimed by the methods disclosed herein.Type: ApplicationFiled: May 10, 2010Publication date: December 30, 2010Inventors: Jeffery Segars, Jeffrey J. Wright, James Jarrett
-
Publication number: 20100326323Abstract: The invention provides a surface-modified titanium dioxide particle inhibited in photocatalytic activity and reduced in amount of volatile water. The surface-modified titanium dioxide particle has on the surface a crystalline composite compound of at least one of alkaline earth metals selected from magnesium, calcium, barium and strontium complexed with titanium dioxide in an amount of 0.1-20% by weight based on the weight of the surface-modified titanium dioxide particle in terms of oxide of the alkaline earth metal. The surface-modified titanium dioxide particle is produced by heating a compound of an alkaline earth metal and a titanium dioxide particle at a temperature of 60° C. or higher so that the alkaline earth metal is complexed with titanium dioxide to form a crystalline composite compound on the surface of the titanium dioxide particle in an amount of 0.1-20% by weight based on the weight of the surface-modified titanium dioxide particle in terms of oxide of the alkaline earth metal.Type: ApplicationFiled: June 25, 2010Publication date: December 30, 2010Applicant: SAKAI CHEMICAL INDUSTRY CO., LTD.Inventors: Kazunobu ABE, Kazumi SUGIMOTO, Atsuki TERABE, Masaru MIKAMI
-
Publication number: 20100282127Abstract: The present invention relates to a process for the preparation of a pigment comprising a surface-reacted precipitated calcium carbonate (PCC), the process comprising the steps of a) providing at least one precipitated calcium carbonate (PCC)-comprising pigment; b) providing H3O+ ions; c) providing at least one anion being capable of forming water-insoluble calcium salts, said anion being solubilised in an aqueous medium; d) contacting said PCC-comprising pigment, with said H3O+ ions and with said solubilised anions in an aqueous medium to form a slurry of surface-reacted PCC-comprising pigment, wherein said surface-reacted PCC comprises an insoluble, at least partially crystalline calcium salt of said anion formed on the surface of the PCC; wherein excess solubilised calcium ions are provided during step d). The present invention further relates to a slurry of surface-reacted PCC comprising pigment obtained by this process, its use as well as the surface-reacted PCC contained in the slurry.Type: ApplicationFiled: December 2, 2008Publication date: November 11, 2010Inventors: Daniel E. Gerard, Patrick A.C. Gane, Joachim Schölkopf, Hans-Joachim Weitzel
-
Publication number: 20100168307Abstract: It is an object of the present invention to provide: a modified perovskite-type composite oxide, which effectively suppresses elution of A-site metals from a perovskite-type composite oxide, and which can be particularly preferably used as an inorganic filler for a composite dielectric body; a method for producing the same; and a composite dielectric material using the same. The modified perovskite-type composite oxide of the present invention is produced by primarily coating the particle surface of a perovskite-type composite oxide with silica and then secondarily coating it with a coupling agent, characterized in that the layer primarily coated with silica is produced by performing a heat treatment at 800° C. to 1200° C. on hydrolyzed silica obtained by the hydrolysis of tetraalkoxysilane.Type: ApplicationFiled: January 16, 2008Publication date: July 1, 2010Inventors: Naoaki Narishige, Shinji Tanabe
-
Publication number: 20100093908Abstract: To obtain an alkaline metal titanate adhered to titanate, which is excellent in friction and wear characteristics when used as a friction modifier, and is excellent in mechanical properties and dielectricity when used as a dielectric material, a method for manufacturing the same, and a resin composition containing the same. An alkaline metal titanate adhered to titanate is characterized in that an alkaline earth metal titanate represented by the formula (2) is adhered onto the surface of titanate represented by the formula (1): AxMy?Ti2-(y+z)O4??(1) wherein A and M are different from each other and represent a mono- to trivalent metal, ? represents a defective portion of Ti, X represents a positive real number which satisfies 0<X<1.0, and y and z each represents 0 or a positive real number which satisfies 0<y+z<1.0, and BO·TiO2??(2) wherein B represents one or more kinds of an alkaline earth metals.Type: ApplicationFiled: February 25, 2008Publication date: April 15, 2010Inventors: Minoru Aki, Atsushi Kamifuku
-
Publication number: 20090169589Abstract: Filler pigments based on platelet-shaped substrates, which are coated with barium sulfate and at least two metal oxides and/or metal hydroxides are highly suitable as filler pigments especially for cosmetic formulations.Type: ApplicationFiled: December 16, 2008Publication date: July 2, 2009Inventors: Christoph Schmidt, Sabine Schoen, Tamio Noguchi
-
Publication number: 20090004390Abstract: The present invention is directed to pigment compositions, thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).Type: ApplicationFiled: June 28, 2007Publication date: January 1, 2009Inventors: Jerome David Smith, Pedro A. Jimenez, Tony Jackson
-
Publication number: 20080271642Abstract: Simplified and improved processes are provided for manufacturing titanium dioxide pigments including a surface treatment whereby a plurality of inorganic oxides or a combination of one or more inorganic oxides with one or more inorganic phosphates are applied to a titanium dioxide base pigment. Aqueous acid-soluble sources of the desired inorganic oxides and/or phosphates are predissolved in an aqueous acid, and these can be added on a batch wise or more preferably on a continuous basis to an alkaline slurry containing the titanium dioxide base pigment and to which aqueous alkaline-soluble sources of the desired inorganic oxides are being or have been added previously. Co-precipitation of the oxides and/or oxides and phosphates is then accomplished by an adjustment of the pH, to provide a surface treated pigment with excellent homogeneity of the deposited mixed oxides and/or oxides and phosphates.Type: ApplicationFiled: May 3, 2007Publication date: November 6, 2008Inventors: Daniel H. Craig, Venkata Rama Rao Goparaju
-
Publication number: 20080181921Abstract: The present invention relates to interference pigments on the basis of multiply coated, platelet-shaped substrates which comprise at least one layer sequence comprising: (A) a metal oxide coating having a refractive index n?2.0, (B) a colorless metal oxide or fluoride coating having a refractive index n?1.8, (C) a nonabsorbing metal oxide coating of high refractive index, and, wherein the pigment further comprises (D) an oxide of calcium, magnesium, or zinc. The present pigment may be used in paints, printing inks, and for producing counterfeit-protected documents of value, such as bank notes, cheques, cheque cards, credit cards, identity cards, etc.Type: ApplicationFiled: October 16, 2007Publication date: July 31, 2008Applicant: BASF CorporationInventor: Carmine DeLuca
-
Publication number: 20080156229Abstract: The present invention provides hydrothermal processes for the production of titanium dioxide from titanyl hydroxide. The use of specific crystallization directors, or additives, can promote the formation of rutile, anatase, or brookite. Variation of process operating parameters can lead to either pigmentary-sized or nano-sized rutile.Type: ApplicationFiled: December 28, 2006Publication date: July 3, 2008Applicant: E. I. DUPONT DE NEMOURS AND COMPANYInventors: DAVID RICHARD CORBIN, KEITH W. HUTCHENSON, SHENG LI, CARMINE TORARDI, EUGENE MICHAEL MCCARRON
-
Patent number: 7381398Abstract: A titanium oxide powder holding a barium compound on the surface of the particles thereof is used for manufacturing a highly crystalline fine barium titanate powder by solid-phase reaction. When the titanium oxide powder and a barium-containing powder material are mixed and calcined to prepare the barium titanate powder, the barium compound on the surfaces of the titanium oxide powder particles inhibits the sintering, or the growth, of the titanium oxide during the calcination. Consequently, the resulting barium titanate powder is highly crystalline and fine.Type: GrantFiled: October 3, 2003Date of Patent: June 3, 2008Assignee: Murata Manufacturing Co., Ltd.Inventors: Syunsuke Nakaya, Masami Yabuuchi
-
Patent number: 7135066Abstract: Ice paint for painting ice surfaces. The ice paint comprises rutile TiO2, precipitated calcium carbonate manufactured to a particle size of 0.8 microns, and water. The rutile TiO2 is combined with the precipitated calcium carbonate in a ratio of at least 1 part rutile TiO2 to 6.5 parts precipitated calcium carbonate.Type: GrantFiled: March 31, 2006Date of Patent: November 14, 2006Inventors: James Nafus, Jr., James Nafus, Sr.
-
Patent number: 6793720Abstract: A solid marking composition comprises a solid matrix containing at least one type of optically variable interference pigment flakes. The solid marking composition provides a document or article with a copy and counterfeit protection feature, and is preferably used in a writing instrument for applying hand-written anti-counterfeit markings and signatures.Type: GrantFiled: September 26, 2002Date of Patent: September 21, 2004Assignee: SICPA Holding S.A.Inventors: Edgar Müller, Olivier Rozumek
-
Patent number: 6638349Abstract: A composition consisting of the reaction product of a halogenated carboxylic acid, an amine, and optionally a fatty acid. The composition has biocidal properties and enhances pigment dispersibility.Type: GrantFiled: March 5, 2002Date of Patent: October 28, 2003Inventor: George K. Atkinson
-
Patent number: 6627336Abstract: An aqueous dispersion of titanium oxide particles comprising chloride ion, and a Brønsted base other than chloride ion, preferably at least one kind of ion selected from nitrate ion and phosphate ion. Preferably the titanium oxide particles are predominantly comprised of brookite titanium oxide particles. The aqueous titanium oxide dispersion is prepared by hydrolyzed titanium tetrachloride in the presence of at least one kind of a Brønsted acid. A thin film formed from this aqueous titanium oxide dispersion exhibits good photo-catalytic activity, transparency and adhesion to a base material.Type: GrantFiled: February 16, 2001Date of Patent: September 30, 2003Assignee: Showa Denko Kabushiki KaishaInventors: Masahiro Ohmori, Hidenori Nakamura
-
Publication number: 20030181329Abstract: A method of producing composite particles of titanium dioxide and a compound inactive as a photocatalyst, comprising the steps of preparing a water based slurry of pH 3 to 5 comprising titanium dioxide, preparing a water based solution comprising a compound inactive as a photocatalyst, and reacting the slurry and the water based solution together at a pH within a range from 4 to 10 is provided, together with highly active photocatalyst particles produced using such a method, and potential uses of such photocatalyst particles.Type: ApplicationFiled: December 19, 2002Publication date: September 25, 2003Applicant: SHOWA DENKO K.K.Inventors: Jun Tanaka, Masayuki Sanbayashi, Yoshinori Ueyoshi
-
Patent number: 6610136Abstract: Aggregated mineral pigments (such as kaolin clay pigments) having a high surface area and useful in coating and filling compositions for ink jet printing media are manufactured by dry grinding an unground mineral composition starting material and then optionally acid treating the ground material.Type: GrantFiled: March 21, 2002Date of Patent: August 26, 2003Assignee: Thiele Kaolin CompanyInventors: Prakash B. Malla, Siva Devisetti
-
Patent number: 6605147Abstract: The use of surface-coated rutile modification TiO2 pigments having a primary particle grain size d50 of 0.1 to 1.0 &mgr;m as an anticorrosive white pigment, with firstly magnesium phosphate and secondly aluminum oxides and/or aluminum hydroxides being precipitated onto the TiO2 pigments, is described.Type: GrantFiled: June 14, 2002Date of Patent: August 12, 2003Assignee: Sachtleben Chemie GmbHInventors: Thomas Rentschler, Jochen Winkler
-
Publication number: 20030121451Abstract: Titanium dioxide-calcium carbonate composite particles capable of realizing characteristic properties inherent in titanium dioxide such as a high opacity, a process for producing the same, and a complex composition or complex incorporated with the same are provided. The composite particles were prepared by adding titanium dioxide particles having an average particle diameter of 0.1 to 0.5 &mgr;m in a carbonation step, typically a step of introducing a gaseous mixture of carbon dioxide and air into a calcium hydroxide slurry with stirring, to conduct a carbonation, and continuing the reaction till pH of the slurry becomes 7 by continuous introduction of the gaseous mixture. Moreover, by incorporating the formed composite particles, complexes such as coatings and paints for paper making or composite materials such as paper, plastic molded materials, and rubber molded materials are produced.Type: ApplicationFiled: January 3, 2003Publication date: July 3, 2003Inventors: Katsuyuki Tanabe, Kouhei Mitsuhashi, Takehiko Yoshida
-
Patent number: 6558464Abstract: The present invention discloses high solids slurries of anatase titanium dioxide pigment comprising greater than about 75% by weight of anatase TiO2 pigment dispersed in water. A process for producing the slurries of the present invention is disclosed which comprises the steps of a) dry milling the anatase titanium dioxide pigment, preferably by pressure rolling, and b) mixing the dry milled pigment with water in the presence of an acrylic acid dispersant.Type: GrantFiled: February 7, 2001Date of Patent: May 6, 2003Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Robert J. Kostelnik, Fu-chu Wen
-
Patent number: 6540824Abstract: The present invention provides a yellow pigment which contains a titanium-iron complex oxide of the pseudo-brookite type and produces a stabilized color more yellowish than conventionally and which is universally usable for coloring plastics, ceramics and coating compositions. The pigment of the invention is a titanium-iron complex oxide pigment which contains a pseudo-brookite complex oxide represented by the composition formula (M1-x•Fex)O•2TiO2 or the composition formula (Fe1-y•Aly)2O3•TiO2 wherein M is one of the bivalent metals Mg, Sr and Zn, the ratios of Fe, Al and M to Ti are in the respective ranges of 0.3≦Fe/Ti≦4.5, 0≦Al/Ti≦6.5 and 0≦M/Ti≦2.6, and x and y are in the respective ranges of 0≦x<1 and 0≦y<1.Type: GrantFiled: February 7, 2002Date of Patent: April 1, 2003Assignee: Ferro Enamels (Japan) LimitedInventors: Takayuki Suzuki, Koji Kataoka
-
Patent number: 6540823Abstract: The present invention relates to a novel zinc magnesium titanate represented by formula (I): Zn2−xMgx.yTiO4 in which x denotes a real number of 0.5 to 1.5; and y denotes an integer of 1 or 2, and to a process for preparing the same and a thermoregulating functional composition which comprises zinc magnesium titanate of formula (I).Type: GrantFiled: December 28, 2000Date of Patent: April 1, 2003Assignee: LG Chemical Ltd.Inventors: Dong Sung Seo, Hong Ha Sohn, Ji Ho Park, Seh Hoon Kang, Young Chang Yoo
-
Patent number: 6387498Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.Type: GrantFiled: April 7, 2000Date of Patent: May 14, 2002Assignee: Flex Products, Inc.Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
-
Publication number: 20020053303Abstract: A pigment composition composed of titanium dioxide and barium sulfate, wherein the barium sulfate being is in a titanium dioxide stabilizing and anti-agglomeration effective amount. Methods for use and products using the composition are also disclosed.Type: ApplicationFiled: October 11, 2001Publication date: May 9, 2002Inventor: Jeffrey F. Krizan
-
Patent number: 6383638Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.Type: GrantFiled: October 13, 2000Date of Patent: May 7, 2002Assignee: Flex Products, Inc.Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
-
Patent number: 6348092Abstract: A composition consisting of the reaction product of a halogenated carboxylic acid, an amine, and optionally a fatty acid. The composition has biocidal properties and enhances pigment dispersibility.Type: GrantFiled: October 25, 1999Date of Patent: February 19, 2002Inventor: George K. Atkinson
-
Publication number: 20010007231Abstract: The present invention discloses high solids slurries of anatase titanium dioxide pigment comprising greater than about 75% by weight of anatase TiO2 pigment dispersed in water. A process for producing the slurries of the present invention is disclosed which comprises the steps of a) dry milling the anatase titanium dioxide pigment, preferably by pressure rolling, and b) mixing the dry milled pigment with water in the presence of an acrylic acid dispersant.Type: ApplicationFiled: February 7, 2001Publication date: July 12, 2001Inventors: Robert J. Kostelnik, Fu-chu Wen
-
Patent number: 6251361Abstract: The potassium titanate of the present invention comprises particles of a diameter of 3 &mgr;m or less and a length of 5 &mgr;m or more with a ratio of the length to the diameter of 3:1 or more, at a content in number of 3% or less, with no hazardous particles contained therein from the respect of health and hygiene. The potassium titanate can be produced by heating a Ti source and a K source as the raw materials to a final TiO2:K2O ratio of 5.5:1 to 6.5:1 at a temperature elevation rate of 20° C./min in the temperature region above 800° C.Type: GrantFiled: January 6, 2000Date of Patent: June 26, 2001Assignee: Kawatetsu Mining Co., Ltd.Inventors: Hidefumi Konnai, Yoshio Suzuki, Yoshio Aso