Silicon Containing Patents (Class 106/454)
  • Patent number: 8933164
    Abstract: A dispersion, comprising 0.1 to 25% by weight hydrophobized silica, 8 to 90 wt % of at least one alcohol selected from the group consisting of ethanol, 1-propanol and 2-propanol, 7 to 89 wt % of water, 0 to 30% by weight solvent immiscible with water, and 0.04 to 5 wt % of at least one carboxyvinyl polymer present in neutralized form, can be applied to a surface using a non-drip application method and, by modifying the surface with hydrophobized silica, imparts water-repelling and self-cleaning properties to the surface.
    Type: Grant
    Filed: March 16, 2010
    Date of Patent: January 13, 2015
    Assignee: Evonik Degussa GmbH
    Inventors: Jörg Peggau, Harald Jakob, Wolfgang Lortz
  • Publication number: 20140256866
    Abstract: This invention relates to megakalsilite platelets, methods of hydrothermally forming said platelets and the megakalsilite platelets obtainable via the disclosed hydrothermal method. More specifically the disclosure describes an improved hydrothermal synthesis of megakalsilite platelets, which are suitable as platelet for interference pigments, and in barrier and flame retardant applications.
    Type: Application
    Filed: March 11, 2014
    Publication date: September 11, 2014
    Inventors: Meaghan Clark McGuire, Ivor Bull, Geoffrey Mark Johnson
  • Patent number: 8808447
    Abstract: The present invention relates to a pigment paint for an exterior material and to a method for manufacturing the same. The pigment paint comprises: a flake matrix, a first metal oxide layer coated on the upper portion of the transparent matrix, an oxide layer containing MgO—SiO2 coated on the upper portion of the first metal oxide layer, and a second metal oxide layer coated on the upper portion of the oxide layer. In order to ensure humidity resistance and weather resistance required for a lustrous pigment paint for exterior materials, a cerium layer and an aluminum oxide layer are further coated. Properties such as high luminance, high chromaticity, and high gloss, which could not be achieved using conventional techniques, can be achieved and a pigment paint having a multi-colored pearl luster can be provided.
    Type: Grant
    Filed: March 8, 2012
    Date of Patent: August 19, 2014
    Assignee: CQV Co., Ltd.
    Inventors: Jae-Il Jeong, Nam-Il Lee, Sang-Keun Park, Jin-Hyung Lee, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang
  • Patent number: 8709148
    Abstract: Particles colored with at least one colorant, where the colored glass particles are glass platelets with an average diameter of 1 to 500 ?m and the colorants at least include at least one of metallic nanoparticles and metal oxides. The glass platelets are planar and the colorants are present in a concentration from 1% to 55% by weight, based on the total weight of the colored glass platelets. The disclosure further relates to a method to a method for producing the colored glass particles and to the use thereof.
    Type: Grant
    Filed: November 24, 2009
    Date of Patent: April 29, 2014
    Assignee: Eckart GmbH
    Inventors: Stefan Trummer, Ulrich Schmidt, Dirk Schumacher, Günter Kaupp, Christian Wolfrum
  • Publication number: 20140031455
    Abstract: The present invention relates to a method for producing a compound that comprises a pseudolaminar silicate of natural origin, which is at least one clay of the paligorskite-sepiolite group, characterized in that said method comprises the following steps: defibrillating the microfibre bundles of the at least one clay in water; dispersing the defibrillated clay in an organic or inorganic liquid solvent until a stable gel is formed; adding to the dispersion at least one clay-surface-modifying agent; removing the solvent from the dispersion by means of a solid-liquid separation process and/or drying process; and deagglomerating the final compound until a powdered product is obtained. A further object of the present invention is the compound that can be obtained using said method, as well as the use of the compound as an additive or filler in composite polymeric materials in order to enhance the properties thereof, the composite polymeric material likewise being encompassed within the present invention.
    Type: Application
    Filed: January 30, 2012
    Publication date: January 30, 2014
    Inventors: Julio Santarén Romé, Eduardo Aguilar Diez, Antonio Esteban Cubillo, Antonio Álvarez Berenguer, Esperanza Benito Cano, Nuria García García, Julio Guzmán Perote, Pilar Tiemblo Magro
  • Publication number: 20130216597
    Abstract: The present invention relates to pigments based on multicoated flake-form substrates which are distinguished by the fact that at least 8 layers [layers (A)-(H)] are on the substrate, where an SiO2 layer (=layer A) is located directly on the surface of the substrate, and to the use thereof, inter alia, in paints, surface coatings, automobile paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, paper, in toners for electrophotographic printing processes, in seed, in greenhouse sheeting and tarpaulins, as absorbers in the laser marking of paper and plastics, and in cosmetic formulations, for the preparation of pigment pastes with water, organic and/or aqueous solvents, for the preparation of pigment compositions and dry preparations.
    Type: Application
    Filed: October 20, 2011
    Publication date: August 22, 2013
    Applicant: MERCK PATENT GMBH
    Inventors: Marcus Mathias, Meike Saatze
  • Publication number: 20110269845
    Abstract: The present invention relates to pigments, comprising a plate-like substrate of perlite which does not contain 3D twin structure particles contained in milled expanded perlite in an amount of greater than 5% by weight, and (a) a dielectric material, especially a metal oxide, having a high index of refraction; and/or (a) a metal layer, especially a thin semi-transparent metal layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.
    Type: Application
    Filed: December 1, 2009
    Publication date: November 3, 2011
    Applicant: BASF SE
    Inventors: Patrice Bujard, Marc Baysang, Philippe Bugnon
  • Publication number: 20110251293
    Abstract: Glass particles colored with at least one colorant, where the colored glass particles are glass platelets with an average diameter of 1 to 500 ?m and the colorants comprise or consist of at least one of metallic nanoparticles and metal oxides. The glass platelets are planar and the colorants are present in a concentration from 1% to 55% by weight, based on the total weight of the colored glass platelets. The disclosure further relates to a method for producing the colored glass particles and to the use thereof.
    Type: Application
    Filed: November 24, 2009
    Publication date: October 13, 2011
    Inventors: Stefan Trummer, Ulrich Schmidt, Dirk Schumacher, Günter Kaupp, Christian Wolfrum
  • Patent number: 7842130
    Abstract: The present invention relates to a complex inorganic color effect pigment material based on multiply coated platelet-shaped substrates wherein one of the layers is a complex inorganic colored pigment. The present color effect pigment may be used in automotive applications, security inks, and decorative coatings.
    Type: Grant
    Filed: August 15, 2006
    Date of Patent: November 30, 2010
    Assignee: BASF Corporation
    Inventors: Curtis J. Zimmermann, Frank Mazella
  • Publication number: 20100255047
    Abstract: The present invention relates to effect pigments based on thin glass flakes and to a method for the production of such pigments. The resulting pigment can be used in any application for which pearlescent pigments have been heretofore used such as, for example, in plastics, paints, inks, cosmetic formulations, coatings including solvent or waterborne automotive paint systems, powder coatings, inks and agriculture foils.
    Type: Application
    Filed: June 16, 2010
    Publication date: October 7, 2010
    Inventors: Ralf ANSELMANN, Klaus Ambrosius, Marcus Mathias
  • Publication number: 20100203093
    Abstract: The present invention relates to pigments, comprising a plate-like substrate of perlite, and (a) a dielectric material, especially a metal oxide, having a high index of refraction; and/or (a) a metal layer, especially a thin semi-transparent metal layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.
    Type: Application
    Filed: June 26, 2008
    Publication date: August 12, 2010
    Applicant: CIBA CORPORATION
    Inventors: Patrice Bujard, Philippe Bugnon, Marc Baysang
  • Publication number: 20100170421
    Abstract: The present invention relates to a process for preparing, starting from a slag material, a filler for construction materials which contain bitumen or a hydraulic binding agent. The slag used to prepare the filler contains ?-dicalcium silicate. The process comprises the step of removing from the slag material a finer fraction formed by particles of a size between 0 and at least 0.75 mm so as to reduce the ?-dicalcium silicate content of the slag material; and the step of finely milling at least a portion of the remaining coarser fraction of the slag to obtain the filler. The invention also relates to the obtained filler, to the use thereof for preparing construction materials and to concrete or mortar compositions and asphalt compositions containing the filler.
    Type: Application
    Filed: June 2, 2008
    Publication date: July 8, 2010
    Inventors: Evelyne Nguyen, Dirk Van Mechelen
  • Publication number: 20100126562
    Abstract: The present invention provides mixed metal oxide based special effect pigments that can be incorporated into optically thin binder systems to produce a “metal flake” appearance that is superior to the “metal flake” appearance presently achievable using conventional special effect pigments. Special effect pigments according to the invention comprise at least 10 wt % of mixed metal oxides that exhibit the McConnellite (Cu1+Cr3+O2) crystal structure. Other metallic elements can be incorporated into the crystal lattice structure to alter the appearance effect of the pigments.
    Type: Application
    Filed: July 25, 2007
    Publication date: May 27, 2010
    Applicant: FERRO CORPORATION
    Inventors: Daniel R. Swiler, Gary L. Nuccetelli, Sean T. Weir
  • Publication number: 20100095868
    Abstract: The invention relates to coated pearlescent pigments, whereby the coating covers the pearlescent pigments and comprises uncured, however, chemically cross-linkable and/or oligomeric and/or polymeric binding agents that can be cross-linked by heat, IR radiation, UV radiation and/or electron rays. The invention also relates to a method for producing the coated pearlescent pigments and to the use thereof. The invention additionally relates to a coating composition and to a coated article.
    Type: Application
    Filed: June 23, 2006
    Publication date: April 22, 2010
    Inventors: Günter Kaupp, Ulrich Schmidt, Burkhard Schreiber, Alexander Albrecht
  • Patent number: 7611815
    Abstract: An external additive for a toner for electrophotography which contains oxide fine particles which contain silicon, in which the oxide fine particles have a primary particle diameter of 30 nm to 300 nm in number average, a standard deviation ? of a particle size distribution of the primary particle diameter satisfies a relation of: R/4???R, in which the R expresses the primary particle diameter, the oxide fine particles are substantially spherical having a circularity SF1 defined as equation (1) of 100 to 130 and a circularity SF2 defined as equation (2) of 100 to 125; SF1=(L2/A)×(?/4)×100??equation (1) SF2=(P2/A)×(1/4?)×100??equation (2), in the equations, “L” expresses the absolute maximum length of the oxide fine particles; “A” expresses a projected area of the oxide fine particles; and “P” expresses a maximum perimeter of the oxide fine particles.
    Type: Grant
    Filed: July 15, 2003
    Date of Patent: November 3, 2009
    Assignee: Ricoh Company, Ltd.
    Inventors: Hideki Sugiura, Satoshi Mochizuki, Kazuhiko Umemura, Shinya Nakayama, Yasuo Asahina
  • Publication number: 20090169499
    Abstract: The present invention relates to pigments, the particles of which generally have a length of from 2 ?m to 5 mm, a width of from 2 ?m to 2 mm, and a thickness of from 20 nm to 2 ?m, and a ratio of length to thickness of at least 2:1, wherein the particles contain a core of SiO2 or a silicon/silicon oxide obtained by heating SiOy flakes with 1.1?y?1.8 in an oxygen-free atmosphere at a temperature of at least 400° C., which core has a narrow distribution of particle sizes and two substantially parallel faces, the distance between which is the shortest axis of the core, and a material layer having a high index of refraction a metal oxide; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.
    Type: Application
    Filed: February 26, 2009
    Publication date: July 2, 2009
    Inventors: Patrice Bujard, Holger Leybach
  • Publication number: 20090004390
    Abstract: The present invention is directed to pigment compositions, thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).
    Type: Application
    Filed: June 28, 2007
    Publication date: January 1, 2009
    Inventors: Jerome David Smith, Pedro A. Jimenez, Tony Jackson
  • Patent number: 7318861
    Abstract: An effect pigment is constituted by coated laminar platelets in which the platelets are a mixture of different platelet materials, one of which is platy glass or platy aluminum oxide, and in which the pigment exhibits visual homogeneity.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: January 15, 2008
    Assignee: BASF Catalysts LLC
    Inventors: Frank Bagala, Sr., Curtis J. Zimmermann
  • Patent number: 7316741
    Abstract: Described herein are ceramic colorants consisting of suspensions of particles of nanometric dimensions, their production and use.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: January 8, 2008
    Assignee: Colorobbia Italia S.p.A.
    Inventors: Giovanni Baldi, Marco Bitossi, Andrea Barzanti
  • Patent number: 7282264
    Abstract: A composition and method which exhibits enhanced moisture sealing properties, suitable for use with flooring materials, such as concrete, and flooring installations, such as carpeting, wood, tiles, etc. are provided. The composition is preferably non-water-based and can form a non-aqueous barrier coating on the flooring substrate, and most preferably provides a desirable pH and blocks migration of alkaline salts through the substrate.
    Type: Grant
    Filed: October 8, 2004
    Date of Patent: October 16, 2007
    Assignee: W.F. Taylor Co., Inc.
    Inventors: Robert Kintu Ddamulira, John Edmund Raidy, Jr., Barry Kenneth Wright
  • Patent number: 7220793
    Abstract: A curable film-forming composition is provided comprising (i) 10 to 90 percent by weight based on the total weight of resin solids in the film-forming composition of a crosslinking agent; (ii) 10 to 90 percent by weight of a polymer containing a plurality of functional groups reactive with the crosslinking agent; and (iii) 5 to 85 percent by volume of particles having a mean particle size less than 100 nm. The particles comprise 1 to 99 percent by weight of at least one metal oxide wherein the metal is selected from zinc, titanium, cerium, manganese, bismuth, copper, zirconium and iron. A multi-component composite coating composition is also provided, comprising a pigmented basecoat and a clear coat. The basecoat and/or clearcoat may be derived from the curable film-forming composition described above. Also provided are coated substrates in which the curable coating compositions or the multi-component composite coating compositions described above are applied to a substrate and cured to form a cured coating.
    Type: Grant
    Filed: February 6, 2003
    Date of Patent: May 22, 2007
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Noel R. Vanier, Calum H. Munro
  • Patent number: 7217318
    Abstract: In a method for the manufacture of a nacreous pigment, in which a multi-layer film is produced by vacuum evaporation coating on a substrate and, after release from the substrate, the particles thus produced are comminuted to pigment particles of a desired size, vapor deposition of a plurality of layers taking place at separate locations within an evacuable container and the substrate being passed along the sources of evaporation, it is provided that at least a backing (A), in particular a silicon oxide layer, and at least a metal oxide layer (B), in particular a titanium oxide layer, are vapor-deposited on the substrate, in particular a circulating metal belt.
    Type: Grant
    Filed: July 28, 2004
    Date of Patent: May 15, 2007
    Assignee: Eckart GmbH & Co. KG
    Inventor: Günter Sommer
  • Patent number: 7208039
    Abstract: The present invention relates to a hydrous kaolin product having improved optical properties, for example, when used in the production of paper products. The present invention comprises an improved barrier coating for paper and a method of making the coated paper. The present invention also comprises an improved method from making filled and coated paper products. The present invention uses a composition comprising kaolin having a shape factor of at least about 70:1, such as at least about 80:1 or at least about 100:1.
    Type: Grant
    Filed: March 23, 2005
    Date of Patent: April 24, 2007
    Assignee: Imerys Pigments, Inc.
    Inventors: J. Philip E. Jones, Robert J. Pruett, Jun Yuan, Michael J. Garska, David O. Cummings, Bomi M. Bilimoria, Robin Wesley
  • Patent number: 7060126
    Abstract: The invention relates to multilayered luster pigments based on metallic substrates, which are completely surrounded by a plurality of layers, where these layers comprise at least one layer pack (A) having a colorless dielectric layer of a material with a refractive index n of ?1.8, and a colorless dielectric layer of a material with a refractive index n of >1.8, and a selectively or non-selectively absorbent layer (B), and to a process for their production, and to their use.
    Type: Grant
    Filed: June 12, 2002
    Date of Patent: June 13, 2006
    Assignee: Merck Patent GmbH
    Inventors: Stephanie Andes, Gerald Fuchs-Pohl, Martin Friz, Gerhard Pfaff, Siegfried Raabe, Michael Uhlig
  • Patent number: 7018465
    Abstract: A spray glaze or opaque composition for coating dental restorations and other surfaces and objects such as hobby ceramics that comprises about 4 to about 50 weight % glaze material, about 5 to about 60 weight % restoration wetting agent, and about 10 to about 90% non CFC propellant. An opaque composition further comprises about 5 to about 30% opaque material.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: March 28, 2006
    Assignee: Enamelite, LLC
    Inventors: Phillip G. Pitts, James R. Vinson
  • Patent number: 6997982
    Abstract: The invention relates to a pigment with a metallic luster, comprising a plate-like non-metallic substrate having a thickness lower an 200 nm, which is entirely coated with a metallic layer.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: February 14, 2006
    Assignee: Merck Patent GmbH
    Inventors: Gerhard Pfaff, Stephanie Andes, Michael Uhlig
  • Patent number: 6929690
    Abstract: A pigment with a metallic luster, comprising a wafer-like substrate made of aluminium dioxide having a thickness of more than 250 nm and less than 1 ?m, which is fully enveloped by a metal layer.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: August 16, 2005
    Assignee: Merck Patent GmbH
    Inventors: Reiner Vogt, Gerhard Pfaff, Stephanie Andes, Michael Uhlig, Martin Friz, Katsuhisa Nitta
  • Patent number: 6890643
    Abstract: A floor polishing composition containing a film-formable organic high molecular material as the main component, which further contains at least scaly particles.
    Type: Grant
    Filed: August 28, 2001
    Date of Patent: May 10, 2005
    Assignees: Asahi Glass Company, Limited, Dohkai Chemical Industry Co., Ltd.
    Inventors: Kunihiko Terase, Masaki Inoue, Atsunari Fujii, Eiichi Ono, Takayoshi Sasaki
  • Patent number: 6875264
    Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: April 5, 2005
    Assignee: Engelhard Corporation
    Inventors: Curtis J. Zimmermann, Daniel Stevenson Fuller
  • Patent number: 6866711
    Abstract: A composite pigment is provided with the composite pigment including a dense inorganic material and silica. The pigment composition is characterized by a CTAB surface area of greater than about 20 m2/g; a BET surface area of greater than about 15 m2/g; and a density of greater than about 2.5 g/cm3.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: March 15, 2005
    Inventors: Fitzgerald Alphanso Sinclair, Mark Edward Wozniak, Louis Frank Gatti, William C. Fultz
  • Patent number: 6818051
    Abstract: The invention relates to particles with an opalescent effect, which have a particle size in the range from 5 &mgr;m to 5000 &mgr;m, comprising monodisperse spheres having a diameter of 50 nm to 2 &mgr;m with a standard deviation of less than 5% in a packed and regularly ordered structure which is three-dimensional in terms of domains and is mechanically stabilized by physical or chemical modification.
    Type: Grant
    Filed: November 14, 2002
    Date of Patent: November 16, 2004
    Assignee: Merck GmbH
    Inventors: Ralf Anselmann, Thomas Albrecht, Sara Rodriguez-Mozaz
  • Patent number: 6783584
    Abstract: To provide a high-chromatic flaky pigment with good colorability, and to provide a method for producing the flaky pigment in a simple and inexpensive plant. A high-chromatic flaky pigment of which the entire surface of the flaky substrate coated with a metal oxide having an interference color is further coated with a semi-transparent thin metal film to enhance the interference color of the pigment.
    Type: Grant
    Filed: September 18, 2002
    Date of Patent: August 31, 2004
    Assignee: Merck Patent GmbH
    Inventor: Norio Takahashi
  • Patent number: 6783586
    Abstract: The present invention relates to a TiO2 pigment coated sequentially in a wet treatment process with hydrous silica and hydrous alumina both in the presence of citric acid wherein the resulting pigment is coated with from 1 to 4% amorphous alumina based on the weight of the untreated TiO2; from 3 to 6% silica glass based on the weight of the untreated TiO2.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: August 31, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Charles Robert Bettler, Michael Patrick Deibold
  • Patent number: 6770130
    Abstract: Silica composite oxide particles comprising silica and a metal oxide other than silica, the content of the metal oxide other than silica being from 30 to 50 mol %, and a coefficient of variation in the particle diameter being not larger than 30%. The silica composite oxide particles contain metal oxides other than silica in an amount of not smaller than 30 mol %, which could not be produced thus far, and feature excellent spherical shape and excellent monodispersion property.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: August 3, 2004
    Assignee: Tokuyama Corporation
    Inventors: Hiroshi Kato, Michimasa Tamura, Makoto Kameda
  • Patent number: 6767633
    Abstract: The invention relates to a transparent medium comprising multilayer pigments having angle-selective reflection or transmission properties and/or absorption properties, and to their use, in particular in transparent thermal insulation systems (TTIs).
    Type: Grant
    Filed: October 10, 2002
    Date of Patent: July 27, 2004
    Assignee: Merck Patent GmbH
    Inventors: Elke Steudel, Hans-Dieter Brückner, Gerhard Pfaff, Peter Reynders, Christoph Schmidt, Carsten Brabänder, Wolfgang Hechler
  • Patent number: 6730156
    Abstract: A filler comprising a substantially amorphous cluster comprising non-heavy metal oxide particles and heavy metal oxide. The filler can be mixed into a hardenable resin to provide radiopaque dental materials having desirable strength and aesthetic character.
    Type: Grant
    Filed: October 28, 1999
    Date of Patent: May 4, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Mark Steven Windisch, Xiaodong Zhang, Richard Paul Rusin, Sumita Basu Mitra
  • Patent number: 6648957
    Abstract: Multilayer pearl lustre pigment on the basis of a platelet-shaped substrate comprising a material of low refractive index in the range from 1.35 to 1.8, which comprises at least (i) one first layer comprising a material having a refractive index of more than 1.8, (ii) optionally, a second layer comprising a material of low refractive index in the range from 1.35 to 1.8, (iii) a semitransparent metal layer which is applied to the substrate or to the layers (i) or (ii), and (iv) if desired, an aftercoating, the substrate being platelet-shaped silicon dioxide, aluminium oxide, boron oxide or magnesium fluoride.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: November 18, 2003
    Assignee: Merck Patent GmbH
    Inventors: Stephanie Andes, Gerald Fuchs-Pohl, Gerhard Pfaff
  • Publication number: 20030027911
    Abstract: One aspect of the invention relates to a brown pigment composition with excellent weathering resistance containing iron oxide, chromium oxide, and one or more alumina and/or silica components. Another aspect of the invention relates to a method of making a brown pigment involving combining iron oxide, chromium oxide, and one or more alumina and/or silica components to form a mixture and heating the mixture to provide brown pigment particles. Yet another aspect of the invention relates to a plastic composition containing a major amount of a plastic material and a minor amount of a brown pigment composition containing iron oxide, chromium oxide, and one or more alumina and/or silica components.
    Type: Application
    Filed: July 17, 2001
    Publication date: February 6, 2003
    Inventors: William Gerald Loucka, Mark Edward Gall, John Gilbert Richardson
  • Publication number: 20030005859
    Abstract: The invention relates to multilayered luster pigments based on metallic substrates, which are completely surrounded by a plurality of layers, where these layers comprise at least one layer pack (A) having a colorless dielectric layer of a material with a refractive index n of ≦1.8, and a colorless dielectric layer of a material with a refractive index n of >1.8, and a selectively or non-selectively absorbent layer (B), and to a process for their production, and to their use.
    Type: Application
    Filed: June 12, 2002
    Publication date: January 9, 2003
    Applicant: Merck Patent GmbH
    Inventors: Stephanie Andes, Gerald Fuchs-Pohl, Martin Friz, Gerhard Pfaff, Siegfried Raabe, Michael Uhlig
  • Patent number: 6492029
    Abstract: The invention relates to a novel method of enameling substrates comprised of glass or vitroceramic material, according to which method the enamel composition contains graphite as a component, with the aim of improving the mechanical properties of the enameled substrate and/or conferring anti-adhesive properties on the composition. The invention also relates to the composition, and the enameled substrates obtained.
    Type: Grant
    Filed: July 12, 1995
    Date of Patent: December 10, 2002
    Assignee: Saint-Gobain Glass France
    Inventor: Andre Beyrlé
  • Patent number: 6413307
    Abstract: In a method of manufacturing a gold containing pigment, a vaporizable gold compound, a vaporizable compound of another metal, which includes an oxide or a nitride with a melting temperature above the melting temperature of gold, and a reaction gas consisting of a mixture of argon and oxygen are introduced into a first microwave plasma, whereby cores covered with gold clusters are formed from the oxide or nitride and the gold cluster covered cores are subjected to a tempering process at 150° C. to 300° C. for causing coloration of the gold cluster covered oxide or nitride cores.
    Type: Grant
    Filed: November 29, 2000
    Date of Patent: July 2, 2002
    Assignee: Forschungszentrum Karlsruhe
    Inventors: Dieter Vollath, Steffen Heidenreich, Friedrich Wacker
  • Patent number: 6334893
    Abstract: The present invention relates to pigment mixtures containing at least two components component A being Al2O3 flakes coated with one or more metals, metal oxides and/or metal sulfides and component B being acicular or spherical colorants, and to their use in particular in varnishes, paints, printing inks, powder coating materials, plastics and cosmetic formulations.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: January 1, 2002
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Gerhard Pfaff, Sabine Schoen, Kaiman Shimizu
  • Patent number: 6270566
    Abstract: A process is disclosed for coloring building materials with inorganic pigments in the form of microgranulates. The granulates comprise one or more pigments and one or more compounds selected from boron, aluminum, silicon, titanium, zinc and tin.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: August 7, 2001
    Assignee: Bayer AG
    Inventors: Jakob Rademachers, Günther Teichmann
  • Publication number: 20010002578
    Abstract: In a method of manufacturing a gold containing pigment, a vaporizable gold compound, a vaporizable compound of another metal, which includes an oxide or a nitride with a melting temperature above the melting temperature of gold, and a reaction gas consisting of a mixture of argon and oxygen are introduced into a first microwave plasma, whereby cores covered with gold clusters are formed from the oxide or nitride and the gold cluster covered cores are subjected to a tempering process at 150° C. to 300° C. for causing coloration of the gold cluster covered oxide or nitride cores.
    Type: Application
    Filed: November 29, 2000
    Publication date: June 7, 2001
    Inventors: Dieter Vollath, Steffen Heidenreich, Friedrich Wacker
  • Patent number: 6214106
    Abstract: The present invention provides a process for the production of hydrophobic inorganic oxide products which comprises reacting the inorganic oxide particles with organohalosilanes, preferably organochlorosilanes, to produce hydrophobic organosilane coated inorganic oxides. It is preferred that the organohalosilane compounds be reacted with the inorganic oxide particles in an aqueous slurry and subjected to intense mixing. The inorganic oxide pigments prepared by the processes of this invention have essentially quantitative retention of the organosilanes and contain no adsorbed aldehydes on their surface. The by-products produced in the preferred embodiments of the invention are innocuous salts, which are environmentally safe and readily disposable.
    Type: Grant
    Filed: October 28, 1998
    Date of Patent: April 10, 2001
    Assignee: Millenium Inorganic Chemicals, Inc.
    Inventors: Leon Weber, Robert J. Kostelnik, Charles Wheddon
  • Patent number: 6136083
    Abstract: A description is given of coated inorganic pigments comprising an organic pigment which has a coating, prepared by the sol-gel process from glass-forming components and densified to form a xerogel or glass, having a layer thickness of at least 0.8 .mu.m. These pigments are prepared by spray drying a sol-pigment dispersion, followed if desired by thermal densification of the xerogel layer to form a glass layer. The coated pigments are suitable for producing enamels and moldings.
    Type: Grant
    Filed: December 8, 1997
    Date of Patent: October 24, 2000
    Assignee: Institut fuer Neue Materialien gemeinnuetzige GmbH
    Inventors: Helmut Schmidt, Martin Mennig, Axel Kalleder
  • Patent number: 6132504
    Abstract: Multilayer interference pigment consisting of a central, absorbing layer and alternating layers of a material of low refractive index and of a metal or of a material of high refractive index either side of the central layer, the material of low refractive index preferably being acrylate and the metal being aluminium or chromium. The absorbing layer consists of a coating system which comprises carbon black or color-imparting absorption pigments.
    Type: Grant
    Filed: October 26, 1998
    Date of Patent: October 17, 2000
    Assignee: Merck Patent Gesellschaft mit Berschrankter Haftung
    Inventors: Matthias Kuntz, Gerhard Pfaff, Gerd Bauer, Christina Schank
  • Patent number: 6077341
    Abstract: A silica-metal oxide particulate composite comprising silica agglomerates having voids formed by random stacking of scaly silica primary particles, and metal oxide particulates supported on the surfaces, and the inner surfaces in the voids, of the silica agglomerates.
    Type: Grant
    Filed: September 28, 1998
    Date of Patent: June 20, 2000
    Assignees: Asahi Glass Company, Ltd., Dohkai Chemical Industry Co., Ltd.
    Inventors: Kunihiko Terase, Masaharu Tanaka, Masaki Inoue, Eiichi Ono, Takayoshi Sasaki
  • Patent number: 5976237
    Abstract: Improved coated inorganic pigments having a first coating of Al.sub.2 O.sub.3, SiO.sub.2, or optionally other oxide such as a source of P.sub.2 O.sub.5, or mixtures thereof, an optional coating of ZrO.sub.2, SnO.sub.2, TiO.sub.2, SiO.sub.2, CeO.sub.2 or mixtures thereof, and a final coating of Al.sub.2 O.sub.3 which exhibit good durability, dispersibility, and optical properties in plastic or paint compositions are disclosed. Also disclosed is a process whereby an aqueous slurry of an inorganic pigment is milled to achieve a particular particle size distribution, a first coating of Al.sub.2 O.sub.3, SiO.sub.2, or optionally other oxide such as a source of P.sub.2 O.sub.5, or mixtures thereof is precipitated onto the pigment material within a first pH range, an optional amount of ZrO.sub.2, SnO.sub.2, SiO.sub.2, TiO.sub.2, CeO.sub.2 or mixtures thereof is added to the aqueous slurry within a second pH range to obtain an optional coating over the first coating, and a final coating of Al.sub.2 O.sub.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: November 2, 1999
    Assignee: Kerr-McGee Chemical Corporation
    Inventors: John E. Halko, Fran Tyler
  • Patent number: 5958125
    Abstract: Goniochromatic luster pigments based on multiply coated, high refractive, nonmetallic, platelet-shaped substrates which are at least partially transparent to visible light, comprising at least one layer packet ofA) a colorless coating having a refractive index n.ltoreq.1.8 andB) a reflecting, selectively or nonselectively absorbing coating which is at least partially transparent to visible light,and also, if desired, additionallyC) an outer protective layer,and their use for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.
    Type: Grant
    Filed: July 5, 1996
    Date of Patent: September 28, 1999
    Inventors: Raimund Schmid, Norbert Mronga