Abstract: The present invention relates to a pigment preparation comprising a mixture of coated and/or uncoated SiO2 flakes, one or more special-effect pigments, and a phosphate derivative, and to the use thereof, especially in printing inks.

Abstract: Spindle-shaped goethite particles of the present invention contain Co of 8 to 45 atm %, calculated as Co, based on whole Fe, Al of 5 to 20 atm %, calculated as Al, based on whole Fe, and have an average major axial diameter of 0.05 to 0.18 &mgr;m, each of said spindle-shaped goethite particles comprising a seed portion and a surface layer portion, the weight ratio of said seed portion to said surface layer portion being 30:70 to 80:20 and the relationship of the Co concentration of the seed portion with that of the hematite particle being 50 to 95:100 when the Co concentration of the hematite particle is 100, and said Al existing in said surface layer portion. Such spindle-shaped goethite particles are fine particles and exhibit a good particle size distribution.

Abstract: A flaky fine powder comprising a flaky substance as the base and silica particles covering the surface of the base, aiming at reducing the glossiness of the base caused by the irregular ref lection of light on its surface and improving the slipperiness In particular the powder comprises a flaky base substance such as natural mica and silica particles deposited on the base surface, wherein the silica particles may be optionally further immobilized by the hydrolysate of alkoxysilane or silica gel. The flaky fine powder is produced either by adding alkoxysilane to a dispersion containing a flaky substance and silica particles and hydrolyzing it, by adding a silicic acid solution to the dispersion and gelling it, or by adding a combination of alkoxysilane and silicic acid solution. This powder can be compounded with various ingredients and is particularly useful with cosmetics.

Abstract: The present invention relates to pigment mixtures containing at least two components component A being Al2O3 flakes coated with one or more metals, metal oxides and/or metal sulfides and component B being acicular or spherical colorants, and to their use in particular in varnishes, paints, printing inks, powder coating materials, plastics and cosmetic formulations.

Abstract: A process is disclosed for coloring building materials with inorganic pigments in the form of microgranulates. The granulates comprise one or more pigments and one or more compounds selected from boron, aluminum, silicon, titanium, zinc and tin.

Abstract: This invention relates to a color stable pigment composition for coating hard mineral granules employed for weather surfacing asphalt roofing and siding shingles. The composition is a 40-60% aqueous slurry of pigment containing ferrosoferric oxide and a silicate/clay mixture which is suitable for coating the surface of the mineral granules. The invention also pertains to a process for the manufacture of the coated granules, to the dry coated mineral granule product containing ferrosoferric oxide bonded in a silicate/clay matrix which is suitable for surfacing asphaltic shingles, to the dried composition containing from about 5 to about 50 wt. % total pigment in a silicate/clay matrix in which the pigment contains Fe3O4 in a concentration of between about 2 and about 100% and to a Fe3O4 pigment mixture per se.

Abstract: The invention provides new stains which fire to a red-brown color for coloring ceramic compositions. The stains comprise Fe2O3 and/or an Fe compound which forms Fe2O3 on firing, in uniform distribution in a pulverulent matrix based on an oxide-like and/or silicate-like material which is amorphous to X-rays to the extent of at least 50% and has a specific surface area (BET) of at least 40 m2/g, and are obtainable by bringing the constituents into intensive contact together. The matrix preferably comprises 80 to 100% amorphous SiO2 or SiO2-rich silicate with a BET surface area of 90 to 300 m2/g and 0 to 20% of an auxiliary substance, such as silicone oil. The stains can be prepared by intensive dry grinding.

Abstract: The present invention provides a process for the production of hydrophobic inorganic oxide products which comprises reacting the inorganic oxide particles with organohalosilanes, preferably organochlorosilanes, to produce hydrophobic organosilane coated inorganic oxides. It is preferred that the organohalosilane compounds be reacted with the inorganic oxide particles in an aqueous slurry and subjected to intense mixing. The inorganic oxide pigments prepared by the processes of this invention have essentially quantitative retention of the organosilanes and contain no adsorbed aldehydes on their surface. The by-products produced in the preferred embodiments of the invention are innocuous salts, which are environmentally safe and readily disposable.

Abstract: The iron oxide platelets comprise at least one layer packet comprising A) a colorless coating having a refractive index n≦1.8, and B) a colorless coating having a refractive index n≧2.0.

Abstract: A process of using silicate and alkylphenol to surface-modify black iron oxide. The modified pigment shows superior heat stability. The process may be applied on a native slurry, hence providing a simple, economical and non-invasive method to modify black iron oxide on an industrial scale. The resultant black iron oxide may be used in lieu of mixed metal oxide in the majority of thermal applications.

Abstract: A corrosion-inhibiting composition for application to a metal substrate, such as steel, silver, copper or aluminum, includes a film-forming organic polymer component and a dispersed pigment phase of a stable unitary hybrid which contains organic and inorganic solid phase constituents interfaced at a micro-crystalline level, which are inseparable by physical separation procedures and which display uniphase behavior. The inorganic phase includes a cation selected from Zn, Al, Mg, Ca, Sr, Ti, Zr, Ce and Fe and an anion selected from phosphates, polyphosphates, phosphites, molybdates, silicates and cyanamides.

Abstract: A description is given of coated inorganic pigments comprising an organic pigment which has a coating, prepared by the sol-gel process from glass-forming components and densified to form a xerogel or glass, having a layer thickness of at least 0.8 .mu.m. These pigments are prepared by spray drying a sol-pigment dispersion, followed if desired by thermal densification of the xerogel layer to form a glass layer. The coated pigments are suitable for producing enamels and moldings.

Abstract: Pure-coloured iron oxide yellow pigments having a silking index of less than 5 and a heat resistance of greater than 220.degree. C. in polyethylene for at least 5 minutes are obtained by oxidation of metallic iron with nitrobenzene in an acid medium in the presence of compounds of elements chosen from main groups 3 and 4 of the periodic table.

Abstract: An adhesive-free, dry, free-flowing powder composition suitable for use in surface defect detection, where the powder composition comprises a physical mixture of particles of a colorant and particles of an extender, which mixture includes particles of colorant and particles of extender each having a particle size of less than 100 .mu.m. The powder compositions of the invention provide a simple, effective guide coat which readily highlights surface imperfections, such as scratches, orange peel effect and dry over-spray without the need for solvents. Also, there are disclosed methods of using such a powder composition to detect surface imperfections, an apparatus for applying same, a device for refilling such applying apparatus, and coated surfaces formed thereby.

Abstract: The present invention relates to phosphorus-containing ferromagnetic pigments comprising, in particular, from 30 to 70% by volume of a core, said core comprising essentially iron and cobalt, and from 30 to 70% of a shell, said shell comprising essentially aluminum, phosporus, silicon, oxygen, and optionally magnesium and sodium; the invention further relates to a process for preparation of said pigments, their use in magnetic recording materials and magnetic recording materials which contain such pigments.

Abstract: Surface-modified, pyrogenically produced mixed oxides which contain two or more components of the series SiO.sub.2, Al.sub.2 O.sub.3, TiO.sub.2, ZrO.sub.2, Fe.sub.2 O.sub.3, Nb.sub.2 O.sub.5, V.sub.2 O.sub.5, WO.sub.3, SnO.sub.2, GeO.sub.2 and have been surface-modified with one to several compounds of the following groups:(a) organosilanes of the type (RO).sub.3 Si(C.sub.n H.sub.2n+1),(b) R'.sub.x (RO).sub.y Si(C.sub.n H.sub.2n+1),(c) X.sub.3 Si(C.sub.n H.sub.2n+1),(d) X.sub.2 (R')Si(C.sub.n H.sub.2n+1),(e) X(R').sub.2 Si(C.sub.n H.sub.2n+1),(f) (RO).sub.3 Si(CH.sub.2).sub.m --R',(g) (R").sub.x (RO).sub.y Si(CH.sub.2).sub.m --R',(h) X.sub.3 Si(CH.sub.2).sub.m --R',(i) (R)X.sub.2 Si(CH.sub.2).sub.m --R',(j) (R).sub.2 X Si(CH.sub.2).sub.m --R',(k) Silazanes of the type ##STR1## (l) Cyclic polysiloxanes, (m) Polysiloxanes or silicone oils.

Abstract: The present invention relates to non-lustrous iron oxide-containing color pigments based on dry-milled inorganic plateletlike substrates having a particle size of <60 .mu.m, characterized in that the iron oxide compound is yellow FeO(OH) and/or Fe.sub.2 O.sub.3.

Abstract: The present invention relates to a spindle-shaped goethite particles containing cobalt of 8.0 to 50.0 atm %, calculated as Co, based on the total Fe in the spindle-shaped goethite particles and a compound of at least one element selected from the group consisting of Al, Si, Nd, Y, La, Ce, Pr, Tb, Ca, Mg, Ba and Sr of not more than 25.0 atm %, calculated as the element, based on the total Fe in the spindle-shaped goethite particles, and having an average major axis diameter of 0.05 to 0.15 .mu.m, a size distribution (standard deviation/major axis diameter) of not more than 0.30, an average minor axis diameter of 0.010 to 0.025 .mu.m, an aspect ratio of 4 to 8 and an X-ray crystallite size ratio (D.sub.020 /D.sub.110) of 2.0 to 3.5.

Abstract: A ceramic composition for the repair of porous ceramic bodies comprises a ceramic material having cations which are reactive with phosphate ions, a source of reactive phosphate ions, and filler. An aqueous slurry of the ceramic composition is prepared and applied to the damaged region of a porous ceramic body. The slurry mixture is dried within the damaged region of the porous ceramic body and heated to bind the mixture together and to bond the mixture to the porous ceramic body within the damaged region. The method of the invention allows for the in situ repair of ceramic materials without removing them from their supporting structure and can be used in the repair of ceramic tiles for spacecraft and aircraft.

Abstract: Goniochromatic luster pigments based on multiply coated, high refractive, nonmetallic, platelet-shaped substrates which are at least partially transparent to visible light, comprising at least one layer packet ofA) a colorless coating having a refractive index n.ltoreq.1.8 andB) a reflecting, selectively or nonselectively absorbing coating which is at least partially transparent to visible light,and also, if desired, additionallyC) an outer protective layer,and their use for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.

Abstract: Disclosed is a system of natural colors consisting of thousands of colored powders of mineral origin and of materials in or on which pigments have been applied and, afterwards, submitted to at least one thermal treatment and/or irradiation. These natural colors cover the totality of the visible spectrum and offer a great variety of tones, tints and reflections from white to black, including all the rainbow colors. The powders of this system are obtained by a combination of two mechanical, chemical, thermal and/or physical processes and are used alone or in combination. They are particularly useful to color materials and, more especially those used in the construction and architectural fields.

Abstract: Materials, such as kaolin clays, which are discolored by the presence of goethite mineral impurities are first heated to convert the goethite to hematite and then treated to remove the hematite, whereby the color and brightness of the product are improved over the starting material.

Abstract: A method for coloring cementitious systems using compacted inorganic granules, wherein said compacted inorganic granules comprise an inorganic pigment and a dispersing agent. Particularly, a method for coloring cementitious systems using compacted inorganic granules; wherein said compacted inorganic granules are produced by a process consisting of: (a) mixing an inorganic pigment and a dispersing agent, (b) compacting the mixture, (c) milling the compacted mixture, and (d) classifying the compacted mixture into at least one oversize material stream, at least one undersize material stream and at least one product stream of compacted inorganic granules; and wherein the coloring effect of the compacted inorganic granules in the cementitious system equals or exceeds the powder standard.

Abstract: A method for making magnetic ink compositions is disclosed. The magnetic particles used in the ink are prepared from an aqueous slurry. A surface derivatizing agent is added to the slurry to render the magnetic pigment particles hydrophobic. The particles then sink to the bottom of the slurry, and the bulk water is then removed. After air drying, dry magnetic pigment particles are provided. The particles will be hydrophobic, and thus will have superior resistance to water as compared to previously known magnetic pigment particles. Magnetic ink compositions are formulated from the magnetic particles.

Abstract: Spherical SiO.sub.2 particles with a size of from 5 to 500 nm coated at individual points with TiO.sub.2, Fe.sub.2 O.sub.3 or ZrO.sub.2 particles with a size of less than 60 nm. The coated SiO.sub.2 particles can be aftercoated with silanes or further metal oxides. The products obtained are used for pigmenting paints, printing inks, plastics and coatings or as sunscreen agents.

Abstract: This invention relates to a process for the production of inorganically coated pigments and fillers and to the use thereof.

Abstract: Colored pigments are provided from the green-yellow to red spectrum based on oxide-nitrides with two or three different cations Q, R and S in the crystal lattice, wherein the nitrogen to oxygen atomic ratio is determinative for the color. These pigments crystallise in the pyrochlore, spinel or elpasolite structure. Pigments in the perovskite are as provided with increased color brilliance. The color of the pigments can be adjusted in a wide range of the color spectrum during their preparation within a substance class with the cations Q, R and S and while retaining the crystal structure, by increasing or lowering the atomic ratio N to O in the oxide-nitride and bringing about the required charge balancing by replacing an equivalent quantity of the cation Q with the valency q by a cation R with the valency q+1.

Abstract: The invention relates to colored luster pigments consisting of a transparent or metallic reflecting core, of a coating consisting of at least one silicon oxide of the composition SiO.sub.0.25 to SiO.sub.0.95 and of further optional coatings, to coating processes by coating metallic silicon in the presence of oxygen, if required with changing its partial pressure, as well as to the use of these luster pigments for pigmenting plastic materials, paints and printing inks, and to pigmented compositions comprising these luster pigments.

Abstract: The present invention relates to color pigments based on substrates which are coated with a doped layer of iron(III) oxide, to processes for their preparation and to their use, especially in aqueous coating systems.

Abstract: Bismuth vanadate pigments IBi.sub.x Fe.sub.y E.sub.v V.sub.(1-w) P.sub.w O.sub.z Iwith the following meanings of the variables:E denotes calcium, zinc, cerium, praseodymium, and/or silicon;x is a value from 0.8 to 1.2;y is greater than 0 to 0.1 when v is greater than 0 or is greater than or equal to 0.035 to 0.1 when v is equal to 0;v is greater than or equal to 0 to 0.2;w is greater than 0 to 0.1;z denotes the number of oxygen atoms required to satisfy the valence requirements of the cations.and the preparation and use of said pigments for dyeing coating compositions, printing inks, and plastics.

Abstract: Coloring pigment of comparable quality to, and cheaper than, pigments products by chemical precipitation, is made from synthetic magnetite produced by oxidation of ferrous mill scale and reduced to a particle size such that preferably at least 85% of the product does not exceed 10 microns and 95% does not exceed 20 microns. The smaller the particle size the greater the tinting strength of the pigment. The pigment may be black or, by calcination of the synthetic magnetite, it may be red. For best quality the black pigment should contain 95-99.5% iron oxides, typically, and the magnetite should have a molecular ratio of 0.9 to 1.1:1. The shade and hue of red is dependent upon the calcination temperature and final size and shape of the particles. Reduction to the required particle size for the red coloring pigment may be done before and/or after calcination.

Abstract: The present invention provides magnetite particles having a particle shape of an octahedron, a specific surface area of 5 m.sup.2 /g or more as determined by the BET method and. a coercive force of 40 to 100 Oe, or a particle shape of a hexahedron, a specific surface area of 6 m.sup.

Abstract: The present invention relates to a process for the preparation of iron oxide black pigment granules which are stable to handling.

Abstract: The present invention relates to iron oxide pigments with an Fe(II) content of at least 5 wt. %, calculated as FeO, which have at least one inorganic after-treatment layer and at least one organic after-treatment coating, a process for preparing these iron oxide pigments and their use.

Abstract: Luster pigments useful for coloring paints, printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations are based on multiply coated plateletlike metallic substrates comprisingA) a first, colorless or selectively absorbing layer of metal oxide,B) a second, nonselectively absorbing layer of carbon, metal and/or metal oxide, andC) if desired a third, colorless or selectively absorbing layer of metal oxide.

Abstract: A minute-particle iron oxide red pigment slurry is formed by adding sodium silicate to a minute-particle iron oxide red pigment slurry, and used to form a red filter formed between a phosphor layer of a color cathode ray tube and a panel thereof. Therefore, even if the red filter is brought in contact with a black matrix under the condition of a process of manufacturing the color cathode ray tube at high temperature, the red filter does not discolor the black matrix.

Abstract: There are provided magnetite particles characterized in that they have surfaces each covered with a thin film or iron-zinc oxides or further covered thereon with a thin film of iron-silicon oxides and have a saturation magnetization of at least 79 emu/g, a degree of blackness (L) of at most 19.5 as measured with a differential colorimeter, and an absorption of at least 30 ml/100 g as measured according to JIS K 5101. There is also provided a process for preparing magnetite particles as described above.

Abstract: The present invention discloses a novel high surface area powder composition in which the individual powder particles comprise hollow silica shells, e.g., amorphous hydroxylated silica, coated with finely distributed surface accessible metal oxides. The invention also discloses metallic coatings, which are obtained by converting at least a portion of the oxide coatings into the corresponding metals.

Abstract: The present invention relates to surface-modified pigments based on platelet-like substrates which, for improving the settling and redispersion behavior, have been recoated with a mixture comprising two metal oxides selected from the group consisting of silica, alumina and zirconium dioxide.

Abstract: The disclosed invention relates to a composition comprising finely divided cationically charged particles of an inorganic material treated with at least one of anionic polysaccharide or anionically modified polysaccharide. The disclosed invention further relates to a method of providing paper of improved strength. The method entails providing finely divided particles of inorganic material, treating the particles with at least one of anionic polysaccharide or anionically modified polysaccharide, and adding the treated particles to cellulose fiber during an alkaline process for making paper. Also, an alkaline paper comprising the finely divided particles of inorganic material treated with at least one of anionic polysaccharide or anionically modified polysaccharide is disclosed.

Abstract: A process for preparing silane metal oxides comprising reacting a metal oxide with an amine compound to form an amine metal oxide intermediate, and subsequently reacting said intermediate with a halosilane.

Abstract: A silicone rubber binder composition is provided which includes silicone rubber, silicone dioxide and an aggregate such as sand, gravel, cinders and the like. The silicone rubber is preferably an RTV silicone rubber which is solubilized using a solvent and mixed with the silicone dioxide and aggregate. The mixture may be spray applied to form a roofing coating or may be molded to form another building element such as a beam, post, block, shingle, wallboard or the like.

Abstract: The present invention relates to a method of preparing Si-containing goethite (.alpha.-FeOOH) by the precipitation of Fe(II) salts with an excess of base, and subsequent oxidation in the presence of a silicate solution.

Abstract: A method for producing a low-structure magnesium silicate SLR product useful to lower the strike through of low brightness paper products comprises adding a raw mineral source of soluble magnesium ions and sulfuric acid in a proportion and under conditions effective to form a slurry comprising soluble magnesium sulfate and a silica leach residue (SLR), and adding to the slurry a solution of an alkali metal silicate in a molar equivalent proportion of MgO:SiO.sub.2 of 1:2.0-4.0 under conditions effective to precipitate the magnesium ions and form a product comprising a low-structure magnesium silicate and SLR having a proportion of SiO.sub.2 MgO:SLR of 50-75%:5-12%:10-50% by weight of the product.A low-structure magnesium silicate SLR filler comprises 50 to 75 wt % SiO.sub.2, 5 to 12 wt % MgO, 10 to 50 wt % SLR, 0 to 6 wt % Fe.sub.2 O.sub.3, and 0 to 7 wt % Al.sub.2 O.sub.3, wherein the proportion MgO:SiO.sub.2 is 1:2.0-4.0.A paper product comprises at least an amount of the filler of the invention.

Abstract: Colorant clusters comprising an aggregation of a plurality of grains of sol-derived material and colorant. The clusters are particularly useful as pigments in liquid compositions, e.g., paints and inks, for forming coatings that are retroreflective immediately upon drying. Also, a process for preparing such colorant clusters comprising admixing colorant in a binder sol to yield a pigment sol and then removing liquid medium from the pigment sol to yield the clusters. Also, a coating composition comprising retroreflective elements, a vehicle, and the aforementioned colorant clusters. After application of the composition to a substrate, the resultant coating is immediately retroreflective upon drying.

Abstract: Disclosed herein is an iron oxide coloring agent capable of suppressing aging of resins comprising plate-like hematite particles coated with amorphous silicon dioxide or hydrated alumina containing silicon dioxide fine particles or hydrated alumina fine particles having an average particle diameter of 50 to 1,000 .ANG..

Abstract: New electromagnetic interference (EMI) shielding pigments based on silver coated carrier pigments are disclosed which have a wider activity spectrum and are more economically available than previously known shielding pigments. The carrier pigments used are platelet shaped, ferro- or ferrimagnetic, Fe-containing, naturally occurring or synthetically produced laminar minerals. The Ag coating amounts to 5 to 25% by weight, based on the carrier pigment. Shielding pigments, which may be prepared by conventional chemical deposition of Ag or by sputtering, may be used for the production of EMI protective coatings and EMI protective films.

Abstract: Inclusion pigments are disclosed based on zirconium silicate as a casing component and cobalt-free spinels as discrete, included colored compounds. The inclusion pigments are prepared by fusing a mixture of a zirconium dioxide source, a silicon dioxide source, one or more mineralizer and cobalt-free oxides in a ratio suitable for spinel-formation. The inclusion pigments have high enamel-fastness and high color-fastness. Further, the pigments are drain-resistant under usual decoration firing conditions.

Abstract: A method for producing a low-structure magnesium silicate SLR product useful to lower the strike through of low brightness paper products comprises adding a raw mineral source of soluble magnesium ions and sulfuric acid in a proportion and under conditions effective to form a slurry comprising soluble magnesium sulfate and a silica leach residue (SLR), and adding to the slurry a solution of an alkali metal silicate in a molar equivalent proportion of MgO:SiO.sub.2 of 1:2.0-4.0 under conditions effective to precipitate the magnesium ions and form a product comprising a low-structure magnesium silicate and SLR having a proportion of SiO.sub.2 :MgO:SLR of 50-75%:5-12%:10-50% by weight of the product.A low-structure magnesium silicate SLR filler comprises 50 to 75 wt % SiO.sub.2, 5 to 12 wt % MgO, 10 to 50 wt % SLR, 0 to 6 wt % Fe.sub.2 O.sub.3, and 0 to 7 wt % Al.sub.2 O.sub.3, wherein the proportion MgO:SiO.sub.2 is 1:2.0-4.0.A paper product comprises at least an amount of the filler of the invention.

Abstract: Coated spinel color pigments with a core of a colored spinel, in particular CoAl.sub.2 O.sub.4, and a coating glassy layer of a silicate are described. The coating layer is essentially silicon dioxide and one or more oxides of the group of alkali metals, alkaline earth metals, and/or earth metals show a high resistance to bleeding in the presence of glass fluxes, as compared to uncoated spinels. The pigments are produced by sintering, for 0.5 to 5 hours, a powder mixture of the spinel, silicon dioxide, and at least one member chosen from the group of alkali metal halides, alkaline earth metal halides, earth metal halides and mixtures thereof as mineralizer at 900.degree. to 1,300.degree. C. The coated spinel color pigments are suitable for the production of ceramic decorations with improved contour sharpness.