Pigment Containing -n=n- Group Patents (Class 106/496)
  • Patent number: 6274065
    Abstract: Preparation of a solid fluorescent composition comprising (1) mixing a host chromophore and an effective amount of a pigment precursor in a solvent, then generating a pigment as guest chromophore in-situ from the pigment precursor, and, subsequently, isolating the mixture of the host and guest chromophores, thereby forming a solid solution, or (2) mixing a polymer as a matrix or a polymer precursor and a pigment precursor in a solvent, if desired in the presence of a chromophore being a host component, then generating a pigment in-situ from the pigment precursor (being the guest component if a host component is present), and, subsequently, isolating the mixture of polymer and pigment, and—if present—the host component, thereby forming a solid solution, wherein in all cases where there is a host component, the absorption spectrum of the pigment (guest chromophore) overlaps with the fluorescence emission spectrum of the host chromophore.
    Type: Grant
    Filed: February 3, 1998
    Date of Patent: August 14, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Takashi Deno, Kunihiko Kodama, Abul Iqbal, Brian Gerrard Devlin
  • Patent number: 6261359
    Abstract: Compounds of formula A(B)x,   (I), wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group, B is a group of formula and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R1, R2, R3, R4, X, Y, Z, m and n, are as defined in claim 1.
    Type: Grant
    Filed: June 11, 1998
    Date of Patent: July 17, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Zhimin Hao, John S. Zambounis, Abul Iqbal
  • Patent number: 6261354
    Abstract: The present invention is directed to a transparent pigmentary composition for use as a colorant in printing inks. The composition is manufactured by coupling a mixture of diazonium salts obtained from about 98 to about 85% in moles of 2-methoxy-4-nitroaniline and about 2 to about 15% in moles of 4-chloro-2-nitroaniline with acetylaceto-2-anisidide.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: July 17, 2001
    Assignee: Gebroeders Cappelle Naamloze
    Inventors: Frank Vermoortele, Jean Mayer
  • Patent number: 6261358
    Abstract: Solid pigment preparations comprising as pigment at least one metal complex of an azo compound which in the form of its tautomeric structures conforms to the formula (I) wherein the rings X and Y may each independently bear one or two substituents selected from the group consisting of ═O, ═S, ═NR7, —NR6H7, —OR6, —SR6, —COOR6, —CN, —CONR6R7, —SO2R8, alkyl, cycloalkyl, aryl and aralkyl, the sum total of the endo- and exocyclic double bonds being three for each of the rings X and Y, R6 is hydrogen, alkyl, cycloalkyl, aryl or aralkyl, R7 is hydrogen, cyano, alkyl, cycloalkyl, aryl, aralkyl or acyl, R8 is alkyl, cycloalkyl, aryl or aralkyl, R1, R2, R3 and R4 are each independently hydrogen, alkyl, cycloalkyl, aryl or aralkyl and furthermore, as indicated by the broken lines in the formula (I), may form 5- or 6-membered rings to which further rings may be fused, R5 is —OH, —NR6R7, alkyl, cycloalkyl, aryl o
    Type: Grant
    Filed: October 8, 1999
    Date of Patent: July 17, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Richard Sommer, Frank Linke, Udo Herrmann, Gunther Stolp
  • Publication number: 20010007887
    Abstract: The invention relates to a pigment preparation comprising an organic pigment and 0.2 to 20% by weight, based on the total weight of the pigment preparation, of an ammonium polyphosphate or of an organophosphorus compound.
    Type: Application
    Filed: December 8, 2000
    Publication date: July 12, 2001
    Applicant: Clariant GmbH
    Inventors: Rudiger Jung, Klaus Saitmacher, Arpad Acs
  • Patent number: 6258158
    Abstract: The present invention relates to a process for pigmenting a porous metal oxide by applying a solution of a soluble pigment derivative and regenerating the organic pigment by heating, whereby the organic pigment is deposited into the metal oxide's pores. The invention also relates to pigmented porous metal oxides and materials comprising a solid substrate and a surface layer of a pigmented metal oxide.
    Type: Grant
    Filed: November 8, 1999
    Date of Patent: July 10, 2001
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Philippe Bugnon, Seiji Homma, Patrick Verhoustraeten
  • Patent number: 6254671
    Abstract: In one embodiment, the present invention relates to a green shade yellow pigment composition comprising a compound having the formula: wherein R1 and R2 are independently hydrogen, halogen, an alkyl group having 1 to about 4 carbon atoms, an alkoxy group having 1 to about 4 carbon atoms, an alkoxycarbonyl group having 1 to about 6 carbon atoms, nitro, cyano, phenoxy or trifluoromethyl; and M2+ is a divalent metal. The green shade yellow pigment composition is suitable for use in plastics, paints, inks, electrostatic toners, powder coatings, and paper.
    Type: Grant
    Filed: November 15, 1999
    Date of Patent: July 3, 2001
    Assignee: Engelhard Corporation
    Inventor: Byron G. Hays
  • Publication number: 20010004871
    Abstract: Various modified pigment products are described which are preferably capable of being dispersed in a variety of materials such as coatings, inks, toners, films, plastics, polymers, elastomers, and the like. The modified pigments are pigments having attached groups, such as polymeric groups, onto the pigment by means other than adsorption.
    Type: Application
    Filed: December 29, 2000
    Publication date: June 28, 2001
    Inventors: Joseph E. Johnson, Nanying Bian, Collin P. Galloway
  • Patent number: 6241813
    Abstract: The invention relates to a process for preparing organic pigment granules with a particular particle size wherein an organic pigment with a particle size of 0.01 to 10 &mgr;m is mixed with water, a C1-C4alcohol, a C3-C8ketone or a mixture thereof, a binder and ammonia or a C1-C3amine and an emulsifier. This mixture is pressed in a continuously operating apparatus through one or more apertures each having a size of 0.2-5.0 mm2, the apparatus consisting of at least one conveying device and a shaping section comprising the apertures, and being constructed, and operated with a throughput, such that the pressure in its shaping section does not exceed 10 bar. The granulated product is then dried at a temperature of −50 to 200° C. at atmospheric pressure or under reduced pressure. The invention also relates to pigment granules prepared by the process of the invention, with a particle size of 0.5 to 4 mm, wherein the pigment present essentially has a particle size from 0.01 to 10&mgr;m.
    Type: Grant
    Filed: March 29, 1999
    Date of Patent: June 5, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Paolo Balliello, Horst Olaf Brücker
  • Patent number: 6235099
    Abstract: A water-dispersed inkjet recording liquid excellent in water resistance and transparency and also excellent in the property of ejection from a nozzle, containing, as a colorant, a water-based dispersion of an organic pigment (A) which is at least one member selected from the group consisting of a quinacridone pigment, a benzimidazolone pigment, an insoluble azo pigment, a fuzed azo pigment, a quinophthalone pigment, a naphthol pigment, a perylene pigment and an isoindolinone pigment and has an average particle diameter of 10 to 150 nm (measured by laser scattering), the water-based dispersion of the organic pigment (A) being obtained by mechanically kneading a mixture containing at least three components of the organic pigment (A), a water-soluble inorganic salt (B) in an amount by weight at least three times as large as the amount of the organic pigment (A) and a water-soluble solvent (C) to finely mill the organic pigment (A), and then removing the water-soluble inorganic salt (B) and the water-soluble solv
    Type: Grant
    Filed: July 28, 1997
    Date of Patent: May 22, 2001
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Seiji Aida, Tsutomu Fujigamori, Hisashi Uraki, Ichiro Toyoda, Sunao Satake, Seiji Sawada, Yasuharu Iida
  • Patent number: 6235100
    Abstract: In one embodiment, the present invention relates to a method of preparing a medium shade yellow pigment composition comprising making an azo pigment by coupling (i) two or more diazonium components made from two or more aromatic amines including 2-amino-5-chloro-4-ethylbenzene-1-sulfonic acid and 2-amino-4-chloro-5-methylbenzene-1-sulfonic acid with (ii) at least 1-(3′-sulfophenyl)-3-methyl-5-pyrazolone, and metallizing the azo pigment with a divalent metal to provide the medium shade yellow pigment composition. The medium shade yellow pigment composition is suitable for use in plastics, paints and inks.
    Type: Grant
    Filed: June 24, 1999
    Date of Patent: May 22, 2001
    Assignee: Engelhard Corporation
    Inventor: Byron G. Hays
  • Patent number: 6221150
    Abstract: The present invention relates to pigment dispersants of the formula (I) in which Z1 is a radical of the formula (Ia) —[X—Y]q—[X1—Y1]r—[X2—NH]sH  (Ia) in which X, X1 and X2 are identical or different and are a branched or unbranched C2-C6-alkylene radical or a C5-C7-cycloalkylene radical which can be substituted by from 1 to 4 C1-C4-alkyl radicals, hydroxyl radicals, and/or by from 1 to 2 further C5-C7-cycloalkyl radicals; Y and Y1 are identical or different and are an NH—, —O— or N(C1-C6-alkyl) group, q is a number from 1 to 6, r and s independently of one another are a number from 0 to 6, but are not simultaneously zero; and Z is defined as Z1, Z2 or Z3, where Z2 is a radical of the formula (Ib) —[X—O]q1—[X1—O]qH  (Ib) in which q1 is a number from 0 to 6, and Z3 is hydrogen, hydroxyl, amino or C1-C6-alkyl where the alkyl group can
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: April 24, 2001
    Assignee: Clariant GmbH
    Inventors: Joachim Weber, Manfred Urban, Erwin Dietz
  • Patent number: 6211346
    Abstract: Metal complexes of an azo compound which in the form of its tautomeric structures conforms to the formula (I) wherein the substituents are each as defined in the description, and which metal complexes host a compound as guest compound, characterized in that they have a dispersing harshness of less than 250.
    Type: Grant
    Filed: October 8, 1999
    Date of Patent: April 3, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Frank Linke, Kent Faubion, Udo Herrmann, Dirk Pfützenreuter, Ronald Göbel
  • Patent number: 6200378
    Abstract: A compound according to the formula (I) wherein R1 and R2 are independently the atoms necessary to complete the formation of a substituted or unsubstituted aromatic or aliphatic carbocyclic or heterocyclic ring system and R3 and R4 have the meaning indicated in claim 1, a new process for the preparation of such a compound, solid solutions and mixtures comprising such a compound and the use of a compound of formula (I) as a pigment.
    Type: Grant
    Filed: July 23, 1999
    Date of Patent: March 13, 2001
    Assignee: Clariant Finance (BVIØ) Limited
    Inventors: Bruno Piastra, Bansi Lal Kaul
  • Patent number: 6150509
    Abstract: A water-insoluble yellow monoazo pigment has the following formula (I): ##STR1##
    Type: Grant
    Filed: November 12, 1999
    Date of Patent: November 21, 2000
    Assignee: Dominion Colour Corporation
    Inventors: Alan Gray, Henry Lui, Dorothy-Grace Manarang
  • Patent number: 6146455
    Abstract: The invention relates to a novel crystal modification (.delta.-modification) of C.I. Pigment Red 53:2 of the formula (1) ##STR1## having the following characteristic reflections in the X-ray powder diffraction pattern:______________________________________ 2.THETA. d relative intensity (in %) ______________________________________ 3.3 26.6 32 4.7 18.7 100 7.5 11.9 14 9.4 9.3 19 10.5 8.4 13 13.8 6.4 10 14.2 6.2 9 14.9 5.9 10 16.7 5.3 11 17.6 5.0 9 18.1 4.9 16 18.9 4.7 10 20.4 4.3 7 21.1 4.2 9 22.1 4.0 9 22.7 3.9 12 23.1 3.8 9 23.6 3.8 13 24.1 3.7 9 24.9 3.6 10 25.5 3.5 23 26.3 3.4 9 27.7 3.2 9 28.1 3.2 6 28.9 3.1 6 30.4 2.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: November 14, 2000
    Assignee: Clariant GmbH
    Inventors: Martin Ulrich Schmidt, Hans Joachim Metz
  • Patent number: 6143455
    Abstract: Aluminum azo complex dyes of the formula (I) or (I') ##STR1## are used as charge control agents in electrophotographic toners and developers, powder coating materials, electret materials, color filters, electrostatic separation processes and in inkjet inks.
    Type: Grant
    Filed: July 16, 1999
    Date of Patent: November 7, 2000
    Assignee: Clariant GmbH
    Inventors: Hans-Tobias Macholdt, Ruediger Baur
  • Patent number: 6136087
    Abstract: A crystal growth inhibitor for azo pigments is disclosed. The crystal growth inhibitor comprises: (1) one or more sulfonated or carboxylated amines, and (2) one or more coupling components selected from the group consisting of acetoacetanilides, naphthanilides, pyrazalones and benzamidazoles; the coupling component being bonded to the sulfonated or carboxylated amines. The crystal growth inhibitor can be produced separately and added to the coupling component prior to the coupling reaction, or it can be formed in situ with the pigment. Preferably, an improved pigment according to the invention includes 2% to 5% by weight of the crystal growth inhibitor. Monoazo pigments including the crystal growth inhibitor have been shown to have greatly improved gloss, transparency and tinctorial strength.
    Type: Grant
    Filed: November 4, 1998
    Date of Patent: October 24, 2000
    Assignee: Uhlich Color Company, Inc.
    Inventor: Sain D. Kapoor
  • Patent number: 6136081
    Abstract: An aqueous ink Jet ink composition comprising a humectant in an amount of up to about 70% by weight of the composition, and from about 0.
    Type: Grant
    Filed: August 10, 1999
    Date of Patent: October 24, 2000
    Assignee: Eastman Kodak Company
    Inventors: Raymond P. Scaringe, Steven Evans, Richard C. VanHanehem
  • Patent number: 6132501
    Abstract: An aqueous ink jet ink composition comprising a humectant in an amount of up to about 70% by weight of the composition, and from about 0.
    Type: Grant
    Filed: August 10, 1999
    Date of Patent: October 17, 2000
    Assignee: Eastman Kodak Company
    Inventors: Raymond P. Scaringe, Steven Evans, Richard C. VanHanehem
  • Patent number: 6129786
    Abstract: Composite pigments based on nanoparticulate metal oxides modified by crosslinked or uncrosslinked polyalkylenepolyamine and anionic dyes are useful for coloring paints, inks, plastic, paper, wood, leather and textile materials.
    Type: Grant
    Filed: May 19, 1998
    Date of Patent: October 10, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Boubacar Camara, Manfred Patsch, Ulrich Steuerle, Jurgen Romeis
  • Patent number: 6123763
    Abstract: A colorless or only slightly colored pigment dispersing agent which is feasible as a pigment dispersing agent for pigments having various hues and has the general formula (1), ##STR1## wherein R.sub.1, R.sub.2, X.sub.1, Y.sub.1, Y.sub.2, k and h are as defined in claim 1.
    Type: Grant
    Filed: January 20, 1999
    Date of Patent: September 26, 2000
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Takashi Kamikubo, Yuuji Hirasawa, Toru Omura
  • Patent number: 6123761
    Abstract: A pigment composition comprising pigment and an amido phthalocyanine compound having the general formula I:MPc--(CONR.sup.1 R.sup.2).sub.n Iwherein which Pc is a phthalocyanine ring which is optionally further substituted by up to an average of one chlorine or bromine atom or of a sulphonic acid; M is hydrogen or a metal such as Mg, Al, Ni, Fe, Zn, Pb, Sn or Cu: n is a number ranging from 0.1 to 4.0; R.sup.1 and R.sup.2 are independently selected from hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.7 -C.sub.12 aralkyl, C.sub.6 -C.sub.10 aryl, C.sub.4 -C.sub.6 alkyl amino alkyl, C.sub.2 -C.sub.20 aliphatic amine, C.sub.2 -C.sub.20 aliphatic amine acid salt, C.sub.2 -C.sub.20 alcohol, polyoxyalkylene, polyoxyalkylene amine.
    Type: Grant
    Filed: August 18, 1999
    Date of Patent: September 26, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Thomas Healy
  • Patent number: 6113683
    Abstract: Colored pearlescent pigment comprising a pearlescent pigment and a second pigment, characterized in using an adhesion promotor for the mutual adsorbance of the pearlescent pigment and the second pigment, whereby the adhesion promotor is a polymer containing hydroxy groups, a process for its preparation, its use and a colored high molecular weight material.
    Type: Grant
    Filed: November 10, 1998
    Date of Patent: September 5, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Fritz Herren, Kimiya Takeshita, Michel Fran.cedilla.ois
  • Patent number: 6103006
    Abstract: Thermoplastic, non-water soluble, fluorescent pigments having improved lightfastness are provided which are suitable for coloring a variety of materials including plastics, particularly polyolefins, as well as paints, inks and textiles. The pigments of the present invention referred to herein as the "light fast pigments" demonstrate good color, migration resistance, heat stability, water insolubility, friability and resistance to plateout. The light fast pigments of the present invention have several embodiments, the polyamide embodiment, polyamide ester embodiment and the polyester embodiment. The pigments of the present invention comprises a polymer which comprises polymerized units of fluorescent dye and polymerized monomers such as for example dicarboxylicacids, polycarboxylicacids, diamines, polyamines, alkanolamines, carboxyalcohols, carboxyamines and difunctional alcohols, and/or polyhydric alcohols.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: August 15, 2000
    Assignee: Day-Glo Color Corporation
    Inventor: Thomas C. DiPietro
  • Patent number: 6102996
    Abstract: A pigment-based ink composition is provided which employs a pigment precursor that is soluble in a non-aqueous solvent. Preferably, the ink composition is in the form of an aqueous, two-phase system wherein the pigment precursor is solubilized in a high boiling, water-insoluble organic compound. Optionally, a second high boiling compound miscible with both aqueous and organic phases and at least one amphiphile are also present.
    Type: Grant
    Filed: December 12, 1997
    Date of Patent: August 15, 2000
    Assignee: Hewlett-Packard Company
    Inventor: Dennis P Parazak
  • Patent number: 6099635
    Abstract: This invention provides a process for forming an acetoacetarylide-based pigment, comprising: (a) reacting a diketene with an amine to form an acetoacetarylide slurry; (b) separating the acetoacetarylide as a solid from the acetoacetarylide slurry; (c) adding the acetoacetarylide solid to a homogenizer; (d) homogenizing the acetoacetarylide in the presence of water and one or more additives to form an acetoacetarylide slurry; (e) pumping the acetoacetarylide slurry to a reaction tank; (f) adding an alkali or alkaline metal base to the slurry; (g) adding an acid to form a precipitate of the acetoacetarylide; and (h) reacting the precipitate with an azo compound, thereby forming a pigment. This invention also includes the pigments and intermediates thereto formed by the above processes.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: August 8, 2000
    Assignee: Lonza AG
    Inventors: Rebecca Lee Rosas, James Michael McCormick
  • Patent number: 6083315
    Abstract: An agglomerated pigment comprises (1) an organic pigment compound, (2) either a sulfonated organic pigment compound obtained by incorporating at least one sulfonic group into the organic pigment compound or a sulfonated organic pigment derivative obtained by incorporating at least one sulfonic group into a derivative of the organic pigment compound, (3) univalent inorganic counter ions bonded to sulfonic groups of component (2), and (4) bivalent or higher inorganic counter ions which are bonded to sulfonic groups of component (2) and wherein each such group has an at least univalent positive charge, the surface of the agglomerated organic pigment as a whole being positively charged. An aqueous pigment dispersion and a water-based ink composition both having excellent storage stability, an agglomerated pigment for use as a raw material for the dispersion, and a process for producing the pigment are provided.
    Type: Grant
    Filed: December 22, 1997
    Date of Patent: July 4, 2000
    Assignees: Seiko Epson Corporation, Mikuni Color Ltd.
    Inventors: Hiroto Nakamura, Hidehiko Komatsu, Michinari Tsukahara, Hideo Yamazaki, Minoru Waki, Naoki Okamoto, Kazumi Adachi
  • Patent number: 6077339
    Abstract: The present invention relates to a method for ink-jet printing with a printing ink containing a pigment preparation containing(a) water(b) a dispersing agent, and(c) at least one pigment consisting of a barbituric acid substituted by radicals containing methine or azo groups or a derivative thereof, preferably present as a salt or a complex, a solid solution, an inclusion compound, or an intercalation compound.
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: June 20, 2000
    Assignees: Bayer Aktiengesellschaft, Bayer Corporation
    Inventors: Roger Nyssen, Dirk Pfutzenreuter, Rolf Richter, Fritz Puchner, Karin Hassenruck
  • Patent number: 6066203
    Abstract: This invention relates to pigment derivatives having the formula ##STR1## wherein Q represents an organic pigment moiety;X is -SO.sub.2 - or -CO-;Alk is C.sub.2 -C.sub.8 alkylene or substituted C.sub.2 -C.sub.8 alkylene;m is an integer of from 1 to 4;n and p are independently integers of from 2 to 6.This invention further relates to the treatment of organic pigments with such pigment derivatives and the use of such treated pigments in coating compositions.
    Type: Grant
    Filed: May 1, 1998
    Date of Patent: May 23, 2000
    Assignee: Bayer Corporation
    Inventors: Ibraheem T. Badejo, Daphne J. Rice
  • Patent number: 6063182
    Abstract: A stir-in pigment composition for coloring high-molecular-weight material, particularly coatings and ink systems, comprises 85 to 99.5 parts by weight of a pigment and 0.5 to 15 parts by weight of an additive comprising a vinylpyrrolidone polymer or copolymer. The stir-in pigment composition is in the form of microgranules and is obtainable by spray drying a high solids content aqueous pigment dispersion containing the pigment and the additive. The new pigment composition powders are easily handled, easily wetted and disperse rapidly to form homogeneous aqueous pigment dispersions which are practically free of larger pigment aggregates and can readily be incorporated into aqueous ink and paint systems as stir-in pigments without a dispersion step in a bead mill.
    Type: Grant
    Filed: December 16, 1998
    Date of Patent: May 16, 2000
    Assignee: Ciba Speciality Chemicals Corporation
    Inventor: Fridolin Babler
  • Patent number: 6056814
    Abstract: The present invention provide a pigment composition and a method for producing same at low cost, which has the same or more excellent quality compared with those produced by a salt milling process which has been commonly used. The pigment composition is produced by dry-milling a pigment in the presence of a surfactant and a water-soluble resin, said surfactant and said water-soluble resin being contained in amounts of 1 to 20% by weight and 2 to 50% by weight respectively based on an amount of the pigment. The pigment composition according to the present invention is readily dispersed into an aqueous system to obtain an aqueous pigment dispersion.
    Type: Grant
    Filed: November 17, 1998
    Date of Patent: May 2, 2000
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Mikiya Kato, Ataru Chiba, Junichi Tsuchida
  • Patent number: 6013126
    Abstract: This invention relates to a process for conditioning organic pigments by(a) grinding a crude organic pigment at a temperature of about 0.degree. C. to about 100.degree. C. in the presence of (i) about 1 to about 10 parts by weight, relative to the organic pigment, of an inorganic salt and (ii) about 1 to about 5 parts by weight, relative to the organic pigment, of a liquid in which the organic pigment and salt are substantially insoluble, to form a pigment paste;(b) grinding the pigment paste at a temperature of about 0.degree. C. to about 100.degree. C. in the presence of about 0.05 to about 1 parts by weight, relative to the organic pigment, of a C.sub.8 -C.sub.10 alkanoic acid to form a treated pigment paste;(c) stirring the treated pigment paste with water or water containing an acid and/or an organic liquid to complete the conditioning of the organic pigment; and(d) isolating the conditioned organic pigment.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: January 11, 2000
    Assignee: Bayer Corporation
    Inventors: Charles E. Shannon, Abdul Sattar, Robert C. Mott, Thomas R. Flatt
  • Patent number: 6010567
    Abstract: This invention relates to a black-pigmented high molecular weight organic material which is structured from a radiation-sensitive precursor by irradiation, the pigmentation of which material consists of coloured organic pigments, at least one of which is in latent form before irradiation. This material is preferably used as a thin layer which is built up in the form of patterns on a transparent substrate and which can be used, for example, as black matrix for optical colour filters. This invention also relates to a process for the preparation of this material as well as to novel soluble derivatives of yellow disazo condensation pigments which can be used in this process.
    Type: Grant
    Filed: April 8, 1998
    Date of Patent: January 4, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ulrich Schadeli, Eric Tinguely, Veronique Hall-Goulle, Gerardus de Keyzer
  • Patent number: 6007612
    Abstract: The present invention provides the use of a resinated pigment in which from 10 to 100% of the resinated proportion of the product is a resin ester, as colourant in a lithographic printing ink.
    Type: Grant
    Filed: December 10, 1997
    Date of Patent: December 28, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Paul Kerwin, David McGregor, John Bryce Blackburn
  • Patent number: 6005085
    Abstract: The present invention provides novel condensed azo compounds using bisamide compounds of 2-hydroxynaphthalene-3,6-dicarboxylic acid, amide, or ester as the couplers, which have excellent properties such as excellent water resistance, chemical resistance, solvent resistance, and heat resistance.
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: December 21, 1999
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo
    Inventors: Ryuzo Ueno, Masaya Kitayama, Kenji Minami, Hiroyuki Wakamori, Katsunori Tanikawa
  • Patent number: 6001168
    Abstract: Pigment dispersions comprisinga polymer,a compound of the formula (I) ##STR1## and a water-free solvent ora water-containing solvent,process for their preparation and also the use of (I) and the pigment dispersions of the invention.
    Type: Grant
    Filed: June 30, 1998
    Date of Patent: December 14, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Veronique Hall-Goulle, Yves Grandidier, Hanspeter Hauser
  • Patent number: 5997628
    Abstract: Disclosed are red shade yellow compositions characterized by the formula: ##STR1## wherein X is a lower alkyl or a --COOR.sub.1 group; wherein R.sub.1 is a hydrogen or lower alkyl group; each Y is independently a lower alkyl, lower alkyloxy or halogen group; a is 0, 1, or 2; and M is a divalent metal. Also disclosed is a process for preparing red shade yellow pigment compositions prepared by initially a diazonium component comprised of one or more aromatic amines wherein at least one of said amines is a 1-sulfo-2-naphthylamine; and thereafter coupling the diazonium component with a coupling component comprised of a pyrazolone coupler to form a dye, and metallizing said dye with at least one divalent metal.
    Type: Grant
    Filed: June 8, 1998
    Date of Patent: December 7, 1999
    Assignee: Engelhard Corporation
    Inventor: Amrit Pal Bindra
  • Patent number: 5985019
    Abstract: A process for the manufacture of a pigment concentrate which comprises dispersing dry organic pigment granules in an organic vehicle.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: November 16, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: James McGeachie McCrae, Eric William Gilmour, Jean-Luc Schwitzguebel
  • Patent number: 5973126
    Abstract: A monoazo compound synthesized using 2-hydroxynaphthalene-3,6-dicarboxylic acid (or salt thereof), an amide, an ureide or an ester thereof as a coupler is novel, and is superior in water resistance, chemical resistance and solvent resistance. The present invention provides such a novel azo compound and a process for producing the same.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: October 26, 1999
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo
    Inventors: Ryuzo Ueno, Masaya Kitayama, Kenji Minami, Hiroyuki Wakamori
  • Patent number: 5968242
    Abstract: A molecular sieve, which contains in all, or only in some, of its cavities colorant molecules as well as a modifier which is covalently bound to said molecular sieve and which reduces its pore diameter, a process for its preparation as well as its use as pigment for coloring high molecular weight organic materials, preferably biopolymers and plastic materials, glasses, ceramic products, for formulations of decorative cosmetics, for the preparation of paint systems, preferably automotive lacquers, printing inks, dispersion paints and color filters as well as materials comprising the novel molecular sieves.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: October 19, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Wolfgang Holderich, Nadja Rohrlich, Laurent Chassot
  • Patent number: 5965715
    Abstract: The invention provides novel bisazo compounds which is obtained by coupling two molecules of a 2-hydroxynaphthalene-3,6-dicarboxylic acid derivative and a compound having two diazo groups in its molecule, as well as a process for producing the same. The present compounds are superior in resistance to water, chemical agents, solvents, heat and the like.
    Type: Grant
    Filed: June 22, 1998
    Date of Patent: October 12, 1999
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo
    Inventors: Ryuzo Ueno, Masaya Kitayama, Kenji Minami, Hiroyuki Wakamori
  • Patent number: 5958128
    Abstract: In the method of manufacturing a disazo pigment according to the present invention, a superior coupling reaction rate during the coupling reaction process makes it possible to manufacture a disazo pigment having superior transparency, brightness, color strength and gloss for the case in which a color strength agent is used. In this method, a coupling reaction is carried out while continuously feeding a coupler aqueous solution comprising a coupler component having the general formula (I) shown below and a tetrazo aqueous solution comprising a benzidine derivative tetrazo component at a molar ratio of 2:0.8.about.0.99 into an acidic aqueous solution held in a batch type mixing vessel. ##STR1## (where each of X, Y, Z independently represents H, CH.sub.3, OCH.sub.
    Type: Grant
    Filed: October 24, 1997
    Date of Patent: September 28, 1999
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Yoshimi Kikuchi, Hitoshi Sugamo
  • Patent number: 5958129
    Abstract: Novel pigment formulations which comprise at least one organic pigment selected from the class consisting of perylene, perinone, quinacridone, azo, benzimidazolone, anthraquinone or anthanthrone pigments and at least one pigment-dispersing agent of the formula (I) ##STR1## have improved rheological and coloristic properties, in particular in aqueous and nonaqueous coating systems.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: September 28, 1999
    Assignee: Clariant GmbH
    Inventors: Manfred Urban, Dieter Schnaitmann, Margit Haberlick
  • Patent number: 5944886
    Abstract: Colored aluminum pigments having a color pigment adhered closely, uniformly and firmly thereto through inorganic acid radical adsorbed on the surface of the aluminum pigment are suitable for use in paints, inks and molded resins. Color fading, poor chroma and processing complications commonly encountered with conventional aluminum pigments are avoided.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: August 31, 1999
    Assignee: Toyo Aluminium Kabushiki Kaisha
    Inventor: Yoshiki Hashizume
  • Patent number: 5931997
    Abstract: A new copper phthalocyanine pigment characterized by masstone and tint reflection spectra is disclosed. The new copper phthalocyanine pigment is especially useful for coloring coating compositions, such as automotive paints, and plastics. Also disclosed is a new process for preparing a conditioned pigment wherein a pigment crude is air jet milled.
    Type: Grant
    Filed: October 5, 1998
    Date of Patent: August 3, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Babler
  • Patent number: 5928419
    Abstract: A surface-treated organic pigment excellent in initial dispersibility and long-term dispersion stability in water and an organic solvent and free from the coagulation of pigment particles, obtained by reacting a sulfonating agent with an organic pigment dispersed in a solvent in which the organic pigment is insoluble or sparingly soluble, and thereby introducing a sulfonic acid group to the surface of each particle of the organic pigment.
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: July 27, 1999
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Toshiyuki Uemura, Tsukasa Iguchi, Sunao Satake, Hisashi Uraki, Yasuharu Iida
  • Patent number: 5922122
    Abstract: A composition containing an organic pigment and a compound having the formula (I): ##STR1## in which R.sup.1 is a group having the formula (II): ##STR2## in which R.sup.4 and R.sup.5 represent hydrogen or alkyl, or R.sup.4 and R.sup.5 are bonded to each other to form a ring together with a nitrogen atom, X represents alkylene or alkyleneoxyalkylene, and Y represents --O--, --S-- or a group represented by --NR.sup.6 -- wherein R.sup.6 is hydrogen or lower alkyl; and R.sup.2 and R.sup.3 represent a group having the formula (II), alkyl, aralkyl, aryl, alkoxy, aralkyloxy, aryloxy, alkylamino, arylamino or a halogen atom. A photosensitive colored composition is made of the composition, a polymer having acidic group, a photopolymerizable monomer and a photopolymerization initiator.
    Type: Grant
    Filed: July 29, 1997
    Date of Patent: July 13, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akihiko Takeda, Takekatsu Sugiyama
  • Patent number: 5919915
    Abstract: An azo pyrazolone compound of the formula: ##STR1## wherein Z represents a substituent selected from Cl, Br, F, NO.sub.2, SO.sub.2 R, CO.sub.2 R, NHSO.sub.2 R.sup.1 and NHCOR.sup.1 in which R and R.sup.1 are hydrocarbyl groups and the sulphonic acid group in ring A is in the 3- or 4-position relative to the pyrazolyl group, said compound being in the form of a salt, and its use as a pigment.
    Type: Grant
    Filed: July 17, 1997
    Date of Patent: July 6, 1999
    Assignee: Zeneca Limited
    Inventors: Alan Patrick Chorlton, James Mason
  • Patent number: 5910577
    Abstract: Compounds of the formula (I) ##STR1## in which R.sup.1 and R.sup.2 are identical or different and are Cl, COO(C.sub.1 -C.sub.4)-alkyl, CONH.sub.2, CONCH.sub.3, CON(CH.sub.3).sub.2 or SO.sub.2 NRR', where R and R' are identical or different and are hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl, it being possible for phenyl to be substituted by methyl, ethyl, methoxy, ethoxy or halogen,R.sup.3 is hydrogen, methyl, methoxy, ethoxy, chloro or bromo, andR.sup.4 is hydrogen, C.sub.1 -C.sub.3 -alkyl, chloro or bromo,are useful yellow pigments with high light fastness and weather fastness properties.
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: June 8, 1999
    Assignee: Clariant GmbH
    Inventors: Hans Joachim Metz, Joachim Weber