Quinacridone Pigment Or Derivative Patents (Class 106/497)
  • Patent number: 5472496
    Abstract: The present invention relates to novel solid solutions which comprise a quinacridonequinone component, a pyrrolo[3,4-c]pyrrole component and a third component which is a 2-anilinoacridone, a 5,6,7,8-tetrahydro-2-anilinoacridone, 2-phenoxyacridone, a 5,6,7,8-tetrahydro-2-phenoxyacridone or a mixture thereof. The solid solutions are three component solid solutions which consist of the components identified above or are four component solid solutions which additionally contain a quinacridone component. Pigment compositions containing the disclosed solid solutions and a method of pigmenting high molecular weight organic material with the solid solutions are also disclosed.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: December 5, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Shivakumar B. Hendi, Lindsay Kilmurry, Edward E. Jaffe
  • Patent number: 5453151
    Abstract: This invention relates to a resinated 2,9-dimethylquinacridone pigment, which is prepared by a process comprising (a) preparing an aqueous suspension containing a 2,9-dimethylquinacridone pigment, a mixture of water-soluble acid salts and a particle growth inhibitor, wherein the mixture of water-soluble acid salts consists essentially of from about 50 to about 95 parts by weight of a water-soluble resin acid salt, and from about 5 to about 50 parts by weight of a water-soluble salt of a napthenic acid or a dimeric acid, or a mixture thereof, (b) precipitating the mixture of acid salts from the suspension in the form of insoluble salts and (c) isolating the resinated 2,9-dimethylquinacfidone pigment from the suspension. The resinated 2,9-dimethylquinacridone pigment possesses excellent dispersability, color strength, saturation and heat stability. It is especially useful for coloring plastics, coatings and inks.
    Type: Grant
    Filed: January 25, 1994
    Date of Patent: September 26, 1995
    Assignee: Ciba-Geigy Corporation
    Inventor: Fridolin Babler
  • Patent number: 5387281
    Abstract: The present invention relates to a heat stable red pigment composition comprising a 2,9-dichloroquinacridone and a bis-(4, 5,6,7-tetrachloroisoindolin-1-on-3-ylidene)-phenylene-1,4-diamine pigment and a process for its preparation. The red pigment compositions are particularly useful for pigmenting engineering plastics.
    Type: Grant
    Filed: December 1, 1993
    Date of Patent: February 7, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Fridolin Babler, Charles G. Orange
  • Patent number: 5383966
    Abstract: The present invention relates to a process for conditioning quinacridone pigments by(a) preparing an aqueous slurry of a crude quinacridone;(b) thoroughly mixing the aqueous slurry with about 0.3 to about 2.9 parts by weight, relative to the quinacridone, of at least one C.sub.1 -C.sub.12 alkyl ester of a C.sub.7 -C.sub.12 aromatic carboxylic acid at a temperature of between about 70.degree. C. and about 200.degree. C.;(c) hydrolyzing the alkyl ester used in step (b); and(d) collecting the quinacridone pigment.
    Type: Grant
    Filed: September 15, 1993
    Date of Patent: January 24, 1995
    Assignee: Miles Inc.
    Inventor: Daphne R. Johnson
  • Patent number: 5378274
    Abstract: Disclosed herein are a color filter wherein an organic pigment is comprised of primary particles having an average particle size of 20 to 200 nm and a particle size distribution within .+-.35 nm and said organic pigment has a color difference of 5 or less when it is subjected to exposure at an illuminance of 100,000 lux or more for 100 hours or more under the condition of a surface temperature at 50.degree. C.; a color filter wherein the film of coloring matter in green has a ratio (T.sub.485 /T.sub.610) of the transmittance of 485 nm (T.sub.485) to that of 610 nm (T.sub.610 ) of 3.5 or less, the maximum transmittance of the film of coloring matter in green is 60% or more and said maximum transmittance is assigned a wavelength of 540 to 550 nm; and a color filter using a specific organic pigment as each of red, green and blue pigments.
    Type: Grant
    Filed: October 19, 1993
    Date of Patent: January 3, 1995
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Seiichiro Yokoyama, Motoharu Ishikawa, Yoshio Hiroi, Nobuaki Watanabe
  • Patent number: 5368641
    Abstract: A process for the preparation of 2,9-dimethylquinacridone pigments or mixed crystal pigments or mixtures of 2,9-dimethylquinacridone and quinacridones which in the two outer fused benzene rings can be substituted, characterized by the form of their crystalline particles having an average ratio of length to width of <2:1 and an average particle size of <0.4 .mu.m, by adding to the solution of 2,9-dimethylquinacridone before or during the finishing of the corresponding crude quinacridones of the quinacridones mentioned in water or solvent mixtures at temperatures from about 60.degree. to about 200.degree. C., in each case a compound of the general formula (I) ##STR1## in an amount of about 1 to 20% by weight, in which Q is a quinacridone radical which is unsubstituted or substituted, Y is an --NR.sup.4 R.sup.5 group or the radical of a five-, six- or seven-membered heterocycle which contains one to three hetero atoms and can be substituted, R and R' are hydrogen or alkyl, and R.sup.1 to R.sup.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: November 29, 1994
    Assignee: Hoechst AG
    Inventors: Erwin Dietz, Adolf Kroh
  • Patent number: 5348580
    Abstract: Pigment compositions comprisinga) at least one organic pigment selected from the group consisting of diketopyrrolopyrroles, azo pigments quinacridones, quinophthalones, phthalocyanines, indanthrones, flavanthrones, pyranthrones, anthraquinones, perylenes, dioxazines, perinones, thioindigo, isoindolines isoindolinones and metal complexes andb) 0.01 to 100% by weight, based on the pigment, of a condensation or addition polymer, the recurring molecular unit of which contains at least one radical containing a nitroxyl or hydroxylamino group or is substituted by a side group containing a nitroxyl or hydroxylamino group, and copolymers thereof with one another or with nitroxyl- or hydroxylamine-free components.These pigment compositions are distinguished by outstanding resistance to light and weathering.
    Type: Grant
    Filed: August 25, 1993
    Date of Patent: September 20, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Laurent Chassot
  • Patent number: 5346545
    Abstract: Pigment compositions comprisinga) at least one organic pigment chosen from the group comprising azo pigments, quinacridones, phthalocyanines, indanthrones, flavanthrones, pyranthrones, anthraquinones, perylenes, dioxazines, perinones, thioindigo, isoindolines, isoindolinones and metal complexes andb) 1 to 100% by weight, based on the pigment, of a nitroxyl compound consisting of at least one unsubstituted or substituted 5-, 6- or 7-membered heterocyclic ring containing a divalent group of the formula ##STR1## in which R.sub.1 and R.sub.2 independently of one another are methyl, ethyl or phenyl, or together form a 4- to 12-membered aliphatic ring,L is an aromatic radicaland Y is O.,or of an acid addition salt thereof.These pigment compositions are distinguished by an outstanding resistance to light and weathering.
    Type: Grant
    Filed: March 5, 1993
    Date of Patent: September 13, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Laurent Chassot
  • Patent number: 5336309
    Abstract: The invention provides a flaky pigment comprising particles of a flaky substrate and particles of a pigment or dye, whereby said flaky pigment is in the form of an ordered mixture. The invention also involves preparation of the pigment by a process comprising subjecting said substrate and said pigment or dye to high speed stirring in the absence of a liquid medium.
    Type: Grant
    Filed: February 5, 1993
    Date of Patent: August 9, 1994
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Tamio Noguchi, Masahiko Yazawa
  • Patent number: 5318626
    Abstract: A process for converting a 2,9-dimethylquinacridone compound into a pigment, which comprises pouring a solution of a crude 2,9-dimethylquinacridone compound in sulfuric acid into continuously flowing water to form a fine precipitate, recovering said precipitate by filtration, washing it with water, adding it to a lower alcohol having 1 to 4 carbon atoms and heating the resultant mixture to 60.degree.-200.degree. C.
    Type: Grant
    Filed: June 22, 1993
    Date of Patent: June 7, 1994
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Hitoshi Maki, Shigeki Kato
  • Patent number: 5300148
    Abstract: Pigments (P) obtainable by cationizing desolubilization of (L) the colored leuco form of sulphur dyes and standardization of the desolubilized products and their use, in particular in printing inks.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: April 5, 1994
    Assignee: Sandoz Ltd.
    Inventors: Manuel J. Domingo, Rolf Hasler, Tibor Robinson, Viktor Sanahuja
  • Patent number: 5286863
    Abstract: A process for preparing quinacridone pigments comprising oxidizing 6,13-dihydroquinacridone or derivatives thereof at elevated temperatures in the presence of a base, dimethyl sulfoxide medium and a quinone catalyst, drowning the resulting pigment solution to precipitate the quinacridone pigment and isolating the desired quinacridone product.
    Type: Grant
    Filed: December 18, 1991
    Date of Patent: February 15, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Fridolin Babler, Edward E. Jaffe
  • Patent number: 5281269
    Abstract: Aqueous processes for the preparation of a new beta quinacridone modification possessing a magenta color having C.I.E. color space values in masstone of L=33-36, A=34-40 and B=8-15 starting with the crude pigment and comprising several milling and alternative deaggregation and recrystallization steps, the latter being facilitated at elevated temperatures aided by the presence of base and minor amounts of crystal growth auxiliaries, and the beta quinacridone modification having the indicated C.I.E. color space values.
    Type: Grant
    Filed: September 14, 1992
    Date of Patent: January 25, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: James B. Ganci, Shivakumar B. Hendi, Walter C. Zukowski
  • Patent number: 5271759
    Abstract: Pigment compositions comprisinga) at least one organic pigment,b) 0.05 to 10% by weight, based on the organic pigment a), of at least one modified organic pigment of formula ##STR1## wherein A is the radical of an organic pigment, X is H, Na or K and m is an integer from 0.05 to 3, andc) 0.05 to 10% by weight, based on the organic pigment a), of at least one polymeric ammonium salt having an average molecular weight from 500 to 2 500 000 and which is soluble in water or a lower alkanol.These pigment compositions have excellent suitability for the wrap-free pigmenting of polyolefins and, when incorporated in paint systems and printing inks, exhibit excellent rheology.
    Type: Grant
    Filed: May 1, 1992
    Date of Patent: December 21, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Gary Wooden, Olof Wallquist
  • Patent number: 5269840
    Abstract: Colorant clusters comprising an aggregation of a plurality of grains of sol-derived material and colorant. The clusters are particularly useful as pigments in liquid compositions, e.g., paints and inks, for forming coatings that are retroreflective immediately upon drying. Also, a process for preparing such colorant clusters comprising admixing colorant in a binder sol to yield a pigment sol and then removing liquid medium from the pigment sol to yield the clusters. Also, a coating composition comprising retroreflective elements, a vehicle, and the aforementioned colorant clusters. After application of the composition to a substrate, the resultant coating is immediately retroreflective upon drying.
    Type: Grant
    Filed: February 4, 1992
    Date of Patent: December 14, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Geoffrey P. Morris, Chester A. Bacon, Jr., Wallace K. Bingham
  • Patent number: 5264032
    Abstract: Pigment preparation essentially comprisinga) at least one pigment from the class of azo, anthrapyrimidine, anthanthrone, quinacridone, perinone, diketopyrrolopyrrole, dioxazine, flavanthrone, indanthrone, isoindolinone, isoviolanthrone, perylene, phthalocyanine, pyranthrone or thioindigo pigments or a mixture of pigments belonging to various classes, andb) at least one dispersant of the formula (I) ##STR1## in which P, independently of the pigments mentioned in a), is a radical of an anthanthrone azo, quinacridone, perinone, diketopyrrolopyrrole, dioxazine, indanthrone, perylene, phthalocyanine or thioindigo pigment,R.sup.1 and R.sup.2, independently of one another, are hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.
    Type: Grant
    Filed: October 21, 1992
    Date of Patent: November 23, 1993
    Assignee: Hoechst AG
    Inventors: Erwin Dietz, Manfred Urban
  • Patent number: 5236498
    Abstract: This invention relates to quinacridone solid solutions containing(a) 95% to 5% by weight of 2,9-dimethoxyquinacridone, and (b) 5% to 95% by weight of 2,9-dichloroquinacridone, characterized by X-ray diffraction patterns that are different from the sum of the X-ray diffraction patterns of the individual quinacridone components. The invention further relates to the use of such solid solutions for pigmentation of fibers, plastics, coatings, printing inks, and the like.
    Type: Grant
    Filed: November 26, 1991
    Date of Patent: August 17, 1993
    Assignee: Miles Inc.
    Inventors: Charles G. Zaloum, Michael J. Greene
  • Patent number: 5223624
    Abstract: A new gamma quinacridone polytype having a yellowish-red color and a distinct X-ray diffraction pattern, said new form being prepared directly in high yield in pigmentary form by oxidation of 6,13-dihydroquinacridone in a basic dimethylsulfoxide medium.
    Type: Grant
    Filed: August 22, 1991
    Date of Patent: June 29, 1993
    Inventors: Fridolin Babler, Edward E. Jaffe
  • Patent number: 5207829
    Abstract: Pigment preparations whose pigment portion is composed essentially of organic pigments and of pigment additives of the formula I ##STR1## in which P is a radical of an organic pigment and X in the methylene groups of the lactam ring is hydrogen, C.sub.1 -C.sub.4 -alkyl, phenyl, hydroxyl, NR.sup.1 R.sup.2 or COOM, m is an integer from 3 to 20 and n can have a value from 0.1 to 4, are suitable for pigmenting high-molecular-weight organic materials in solvent-borne as well as aqueous systems.The pigment preparations have high flocculation stability and good rheological properties.
    Type: Grant
    Filed: December 4, 1991
    Date of Patent: May 4, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wolfgang Schwab, Erwin Dietz
  • Patent number: 5194088
    Abstract: A process for converting crude pigments into pigmentary form wherein the crude pigment is premilled, then contacted with a polar solvent at temperatures below 50.degree. C., with or without the presence of particle growth inhibitors, and finally isolated.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: March 16, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Fridolin Babler, Edward E. Jaffe
  • Patent number: 5190586
    Abstract: Disclosed are pigment composite particles which are superior in water resistance, weather resistance, thermal stability and hardness. The pigment composite particles are prepared by suspension-polymerizing an aqueous suspension comprising(a) a pigment paste comprising pigment and a pigment grinding resin having a hydrophilic group of at least 0.2 mmol/g,(b) a polymerizable monomer and(c) a polymerization initiator.
    Type: Grant
    Filed: November 28, 1990
    Date of Patent: March 2, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Katsumi Mizuguchi, Masanori Ohiwa, Keizou Ishii, Shinichi Ishikura
  • Patent number: 5145524
    Abstract: Surface modification of a variety of pigments, particularly quinacridone pigments, and the pigments resulting therefrom whereby the pigment is treated with a poly(vinyl lower alkyl ether) and, optionally, with a dispersion-improving derivative of the primary pigment resulting in compositions exhibiting enhanced performance in automotive and other finish systems. The surface treatment also improves flow properties of the pigment in the aqueous phase of processing leading to higher solids content for direct application in waterborne systems.
    Type: Grant
    Filed: February 20, 1991
    Date of Patent: September 8, 1992
    Assignee: Ciba-Geigy Corporation
    Inventor: James B. Ganci
  • Patent number: 5137576
    Abstract: Quinacridones having selectively adjusted triboelectric effects, which quinacridones contain about 0.05% to 100 percent by weight of triboelectrically active compounds of the general formula IQ--A--Y].sub.n (I),in which Q is a quinacridone radical which is unsubstituted or substituted by halogen atoms, alkyl, alkoxy H.sub.2 N--CO--, alkyl--NH--CO-- or (alkyl).sub.2 N--CO groups, A is a direct bond or --O--, --S--, --NR.sup.1 --, --CO--, --SO.sub.2 --, --CR.sup.2 R.sup.3 -- or arylene and Y is an --NR.sup.4 R.sup.5 group or a five-, six- or seven-membered heterocycle which contains one to three heteroatoms from the series comprising nitrogen and/or oxygen and/or sulfur and which can be substituted by alkyl, alkoxy, hydroxyphenyl, halogen, --CN, --COOH, --CO-- NRR', --SO.sub.2 --NRR', hydroxyalkyl or alkylaminoalkyl, in which R and R' together with the nitrogen atom can be a heterocycle, R and R' are hydrogen atoms or alkyl and R.sup.1 to R.sup.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: August 11, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans-Tobias Macholdt, Adolf Kroh, Alexander Sieber, Erwin Dietz
  • Patent number: 5116712
    Abstract: A color toner, comprising a binder resin and a colorant, wherein the colorant comprises organic pigment particles treated with an isocyanic ester or a silicon-containing compound.
    Type: Grant
    Filed: April 11, 1990
    Date of Patent: May 26, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tatsuya Nakamura, Hiromi Mori, Masoyoshi Shimamura, Reiko Morimoto
  • Patent number: 5112404
    Abstract: The invention relates to readily dispersible pigment formulations which are stable to flocculation and are used for pigmenting naturally occurring and synthetic materials, preferably paints and printing inks, plastics and lacquers, in particular stoving lacquers. The pigment formulations contain compounds of the general formula (I) ##STR1## in which Q.sup.1, Q.sup.2 and Q.sup.3 each denote --X--A, --OR.sup.1, --SR.sup.1, halogen, --NR.sup.2 R.sup.3 or a radical Q which is built up from up to 15 trivalent groups (Ia) such that in each case one group (Ia) is bonded via W to a free valency of the next group (Ia) or to the triazine ring of (I) and the other free valencies are bonded to --X--A, --O--R.sup.1, halogen or --NR.sup.2 R.sup.3, at least one radical --X--A being present in (I), and A stands for an aromatic system with 2 to 6 rings and at least 9 ring atoms, or stands for a group of 2 to 3 aromatic ring systems, bonded via O, S, CO, SO, SO.sub.2 or C.sub.1 -C.sub.
    Type: Grant
    Filed: April 4, 1990
    Date of Patent: May 12, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Sommer, Erwin Dietz, Manfred Urban
  • Patent number: 5108509
    Abstract: A pigment is formed in an aqueous slurry. A mixture of the pigmented slurry and a vehicle is subjected to high speed, high shear mixing action. The water is forced out of the solid pigment and replaced by the vehicle forming bead-like spherical conglomerates. The conglomerates grow into clusters in the dispersing phase during the mixing process. The clusters are filtered from the dispersing water phase forming a flushed pigment which is used for dispersion in ink systems.
    Type: Grant
    Filed: May 8, 1990
    Date of Patent: April 28, 1992
    Assignee: Roma Color, Inc.
    Inventors: John S. Booth, Edward W. Makuch
  • Patent number: 5084573
    Abstract: 2,9-Dichloroquinacridone in platelet form having a length of 1-45 .mu.m, a width of 0.1-20 .mu.m and a thickness of 0.05-5 .mu.m; a process for the preparation thereof comprising conversion of the crude material in a polar solvent in the presence of a long chain thiol compound and a base; and the pigmentary use of said platelets.
    Type: Grant
    Filed: July 13, 1990
    Date of Patent: January 28, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Fridolin Babler, Edward E. Jaffe
  • Patent number: 5084100
    Abstract: A dispersion milling process for reducing the particle size of quinacridone pigments wherein the quinacridone is milled in the presence of hydrated aluminum sulfate and, as a crystallizing solvent, a lower alkyl ester of a C.sub.2 -C.sub.10 dibasic carboxylic acid.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: January 28, 1992
    Assignee: Ciba-Geigy Corporation
    Inventor: Donald L. Bauman
  • Patent number: 5082498
    Abstract: Solid pigment formulations containing from 70 to 97% by weight, based on the total weight of the formulation, of one or more pigments and also from 3 to 30% by weight, based on the total weight of the formulation, of at least one surfactant which is an adduct of ethylene oxide and optionally propylene oxide with ethylenediamine, the proportion of ethylene oxide being from 46 to 100% by weight, based on the total weight of ethylene oxide and propylene oxide in the adduct, and the adduct having an average molecular weight of from 5000 to 40,000, are useful for pigmenting printing ink and gloss paint compositions.
    Type: Grant
    Filed: May 29, 1990
    Date of Patent: January 21, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Kurtz, Karl Muench, Joachim Kranz, Horst Belde
  • Patent number: 5069719
    Abstract: Disclosed is an organic solvent based ink composition which contains a specific dye and an organic solvent, especially an alcohol or a glycol and which has excellent stability with time and good writing properties. The organic solvent based ink composition comprises a dye and an organic solvent, wherein the dye is represented by ##STR1## wherein D represents a residue of an azo or anthraquinone dye which does not have a sulfone group and a carboxyl group, X represents an oxygen atom or a methylene group, Y represents a C.sub.2 -C.sub.12 alkyl group, a C.sub.2 -C.sub.4 hydroxyalkyl group, a C.sub.2 -C.sub.12 alkoxyalkyl group, a polybutyral residue, a polyvinyl alcohol residue, a phenol resin residue, or a cellulose residue and m shows 0 or 1.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: December 3, 1991
    Assignee: Orient Chemical Industries, Ltd.
    Inventor: Takashi Ono
  • Patent number: 5041163
    Abstract: A pigment is formed in an aqueous slurry. A mixture of the pigmented slurry and a vehicle is subjected to high speed, high shear mixing action. The water is forced out of the solid pigment and replaced by the vehicle forming bead-like spherical conglomerates. The conglomerates grow into clusters in the dispersing phase during the mixing process. The clusters are filtered from the dispersing water phase forming a flushed pigment which is used for dispersion in ink systems.
    Type: Grant
    Filed: June 8, 1989
    Date of Patent: August 20, 1991
    Assignee: Roma Color, Inc.
    Inventors: John S. Booth, Edward W. Makuch
  • Patent number: 4986852
    Abstract: Pigments of the formula I ##STR1## where A is a five- or six-membered aromatic fused or unfused heterocycle which contains one to three hetero atoms from the series consisting of nitrogen and/or oxygen and/or sulfur and which is bonded to the methylene group via a carbon atom, R.sub.1 and R.sub.2 are each hydrogen, alkyl C.sub.1 -C.sub.4, alkylene C.sub.2 or aryl, and together R.sub.1 and R.sub.2 may also be an aliphatic or aromatic ring, R.sub.3 is hydrogen, alkyl C.sub.1 -C.sub.4 hydroxylkyl C.sub.1 -C.sub.3 or alkylene C.sub.2, P is the radical of a polycyclic pigment or a radical of a mix-crystal of polycyclic pigments, and n is a number from 0.0001 to 0.
    Type: Grant
    Filed: December 20, 1988
    Date of Patent: January 22, 1991
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Erwin Dietz, Gustav Kapaun, Michael Kappert, Frank Prokschy, Adolf Kroh, Manfred Urban
  • Patent number: 4970248
    Abstract: Azine pigment which has one of the possible tautomeric forms of the formula I ##STR1## and which is present in its c-crystalline modification, which is characterized by the interplanar spacings (relative intensity) 3.29 (100); 3.60 (24); 3.73 (28); 4.64 (28); 6.23 (31); 6.97 (23); 8.05 (67); 9.36 (34); 12.63 (67); 13.96 (32) and 16.35 (30).This pigment is excellently suitable for coloring high-molecular weight organic material, in particular automobile paints.
    Type: Grant
    Filed: May 22, 1989
    Date of Patent: November 13, 1990
    Assignee: Ciba-Geigy Corporation
    Inventor: Martin Tanner
  • Patent number: 4881980
    Abstract: Pigments of the quinacridonequinone series consisting of 98-20 mol percent of a quinacridonequinone of the general formula (1) ##STR1## in which R denotes a hydrogen or chlorine atom or a methyl or carbonamide group and m and n are 1 or 2, and 1-65 mol percent of a quinacridone of the general formula (2) ##STR2## in which R, m and n have the abovementioned meaning, and 1-15 mol percent of one or two acridone derivatives of the general formulae (3) and/or (4) ##STR3## in which X denotes O or NH and R can be identical or different and, like m and n, has the abovementioned meaning, the added compounds of the general formulae (2), (3) and/or (4) being predominantly incorporated into the crystal lattice if the quinacridonequinone of the general formula (1), processes for their preparation and their use for coloring synthetic and naturally occurring materials.
    Type: Grant
    Filed: July 9, 1987
    Date of Patent: November 21, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Erwin Dietz, Frank Prokschy
  • Patent number: 4872916
    Abstract: An aqueous pigment dispersion containing as the dispersing agent a phosphate ester salt having the general formula: ##STR1## wherein: R and R' are the same or different linear or branched alkyl groups of 2 to 12 carbon atoms;k and l are the same or different integers having a value of 1 or 2;x and y are the same or different integers having values of greater than 1 but less than 13; and,M is a cation selected from the group consisting of potassium, sodium and ammonium. The dispersing agent is especially useful to disperse azo type pigments. The resulting pigment dispersion exhibits improved stability.
    Type: Grant
    Filed: September 22, 1988
    Date of Patent: October 10, 1989
    Assignee: Sun Chemical Corporation
    Inventor: Joseph A. Latosky
  • Patent number: 4857646
    Abstract: A new beta quinacridone polytype having a magenta color and a distinct X-ray diffraction pattern, said new form preferably having an average particle size of about 0.2-0.8 .mu.m and being prepared by various wet milling or reflux procedures in alcohol-base systems.
    Type: Grant
    Filed: August 24, 1987
    Date of Patent: August 15, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Edward E. Jaffe
  • Patent number: 4844742
    Abstract: Surface modification of a variety of pigments, particularly quinacridone pigments, and the pigments resulting therefrom whereby the pigment is treated with a solvent-free, basic, nitrogen-containing copolymer of the polyurethane series and with a dispersion-improving derivative of the primary pigment resulting in compositions exhibiting enhanced performance in automative and other finish systems.
    Type: Grant
    Filed: May 15, 1987
    Date of Patent: July 4, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Edward E. Jaffe
  • Patent number: 4762568
    Abstract: A pigment composition contains a pigment and a dispersant. The dispersant is a phosphoric ester compound represented by the following general formula: ##STR1## wherein at least one of the three Rs is a residuum of a polyester chain containing as principal bonds thereof ester bonds of a polycarboxylic acid and a polyalcohol.
    Type: Grant
    Filed: August 12, 1987
    Date of Patent: August 9, 1988
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Michiei Nakamura, Hitoshi Takeuchi, Tetsujiro Takahashi, Yoshitake Kori, Minoru Takizawa, Takamitsu Shinoda, Shojiro Horiguchi
  • Patent number: 4762569
    Abstract: The present invention relates to a easily dispersible pigment composition for non-aqueous vehicles, comprising 100 wt. parts of organic pigment or inorganic pigment and 0.5-15 wt. parts of tetracarboxylic acid diimid compound having the following formula [I], and a method for dispersing pigment in non-aqueous vehicle, comprising use of 0.5-15 wt. parts of the compound having the following formula [I] against 100 wt. parts of organic or inorganic pigment. ##STR1## In the formula [I], Q shows naphthaline radical or perylene radical having 4 carbonyl radicals at peri-positions and R.sup.1 and R.sup.2 show either the same or differently hydrogen atom or alkyl radical having 1-2 carbon atoms, and n is 2 or 3.
    Type: Grant
    Filed: August 7, 1987
    Date of Patent: August 9, 1988
    Assignee: Sanyo Color Works, Ltd.
    Inventors: Toshiyuki Miki, Mitsumasa Takeya
  • Patent number: 4760004
    Abstract: Compounds of the formulae I, II and III ##STR1## in which R is --F, --Cl, --Br, C.sub.1 -C.sub.18 alkoxy, and n is the number 0, 1, 2 or 3, are suitable in particular for use as photoconductive substances.
    Type: Grant
    Filed: November 12, 1987
    Date of Patent: July 26, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Alain C. Rochat, Edward E. Jaffe, Jin Mizuguchi
  • Patent number: 4760144
    Abstract: Process for preparing yellow shade modification of gamma quinacridone whereby the .gamma..sub.II form is converted to the .gamma..sub.I form (1) by milling in an alcohol and in the presence of a base or (2) by premilling the .gamma..sub.II form to the .gamma..sub.I form and then refluxing or milling the resulting .gamma..sub.I form in an alcohol in the presence of a base, the resulting product being a highly crystalline, bright, yellow shade, ready dispersable .gamma..sub.I quinacridone pigment.
    Type: Grant
    Filed: November 13, 1986
    Date of Patent: July 26, 1988
    Assignee: Ciba-Geigy Corporation
    Inventor: Edward E. Jaffe
  • Patent number: 4758665
    Abstract: A process for preparing the high-hiding form of the .gamma.-crystal modification of unsubstituted linear transquinacridone having improved tinctorial strength and producing a coating of higher gloss, which comprises carrying out (a) the known cyclization of 2,5-diphenylaminoterephthalic acid in highly concentrated polyphosphoric acid or in acid polyphosphoric acid ester to the quinacridone and/or (b) the known hydrolysis of the quinacridone melt obtained in (a) and/or (c) the known aqueous alkali extraction of the quinacridone obtained in (b) and/or (d) the known finishing of the quinacridone obtained in (a) in the presence of 0.5 to 10 percent by weight, based on quinacridone, of surface-active agents.
    Type: Grant
    Filed: November 13, 1986
    Date of Patent: July 19, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ernst Spietschka, Adolf Kroh
  • Patent number: H564
    Abstract: Aqueous pigment concentrates are produced by a two-step milling process. The process comprisesa. pumping a crude with from about 12% to about 48% by weight of surfactant, based on pigment, and an amount of water sufficient to reduce the crude concentration to 10 to 50% by weight, based on the total mixture, andb. continuously pumping the blend of (a) through at least two shot mills in series containing between 50 and 90% by volume of a grinding media that has a size in the range of 0.1 to 1.5 mm diameter and then grinding until the particle size has been reduced to where the pigment dispersion has suitable tinctorial strength for use in inks and coatings.
    Type: Grant
    Filed: April 28, 1986
    Date of Patent: January 3, 1989
    Assignee: BASF Corporation
    Inventors: Arthur H. Allen, III, Arthur R. Heuser, Richard J. Meyer, Judy B. Payne