Ring Containing Atom Other Than Carbon Patents (Class 106/498)
  • Publication number: 20030084820
    Abstract: A finely divided pigment is formed of an aggregate of primary particles. A number of primary particles of not greater than 0.1 &mgr;m in particle size is at least 95% of an entire number of the primary particles, and a number of primary particles of greater than 0.1 &mgr;m in particle size is at most 5% of the entire number of the primary particles. The finely divided pigment can be produced by grinding a parent pigment (pre-division pigment) together with a water-soluble inorganic salt and a water-soluble organic solvent in a grinding machine at a temperature of from 30 to 90° C. for 2 to 6 hours under a load, and then removing the water-soluble inorganic salt and the water-soluble organic solvent. A coloring composition comprises a dispersing medium and the finely divided pigment dispersed in the dispersing medium.
    Type: Application
    Filed: June 27, 2002
    Publication date: May 8, 2003
    Applicant: Dainichiseika Color & Chem. Mfg. Co., Ltd.
    Inventors: Hisao Okamoto, Yutaka Nakagawa, Yoshiyuki Zama, Koji Tsuchiya, Shotoku Takami, Yoshio Abe, Michiei Nakamura
  • Patent number: 6544321
    Abstract: Disclosed are pigment particles prepared by a process which comprises (a) preparing a solution of a polyalkylene oxide compound in water; (b) preparing a solution of a cationic dye in water; (c) admixing the solution containing the polyalkylene oxide compound with the solution containing the cationic dye to form a mixture; (d) adding to the mixture a solution containing a heteropolyacid in water, an alcohol, or a mixture thereof, thereby resulting in formation of pigment particles having an average particle diameter of no more than about 300 nanometers; and (e) after addition of the heteropolyacid to the mixture, neutralizing the mixture by addition of a base. Another embodiment of the present invention is directed to an ink composition comprising water and the aforementioned pigment particles.
    Type: Grant
    Filed: November 7, 2001
    Date of Patent: April 8, 2003
    Assignee: Xerox Corporation
    Inventors: Maura A. Sweeney, Thomas W. Smith, Melvin D. Croucher
  • Patent number: 6544325
    Abstract: The present invention relates to pigmentary solid solutions comprising copper phthalocyanine (Pigment Blue 15; C.I. 74160) as host and other blue to violet pigments as guests. Preferred hosts are the &agr; (Pigment Blue 15:1), &bgr; (Pigment Blue 15:3) and &egr; (Pigment Blue 15:6) crystal forms of copper phthalocyanine, especially the &egr; crystal form. The present invention also relates to dispersions comprising solid solutions as pigment particles, and pigment derivatives as rheology improvers. Preferred dispersions of solid solutions in the e crystal lattice may be used in particular to prepare color filters for liquid-crystal displays (LCDs). The present invention also includes a process for preparing the dispersions of the invention, the solid solutions themselves, and the use thereof to pigment high molecular mass organic materials.
    Type: Grant
    Filed: July 3, 2001
    Date of Patent: April 8, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Véronique Hall-Goulle, Gerardus De Keyzer, Yves Grandidier
  • Patent number: 6540820
    Abstract: Compounds of the formula: where R1, R2, R3, R4, R5, R6, R7, R8, R′5, R′6, R′7, R′8 are hydroxy —NO2, —CN, —CF3, —CONH2, C1-12alkyl, phenyl, naphthyl, phenanthryl, anthryl, R9R10N—, R9—O—or R9—S—, —CONHR10, —CONR9R10 in which R9 and R10 are C1-C6-alkyl, C6-C10-aryl, (C6-C10)-aryl-(C1-C6)-alkyl or (C1-C6)-alkyl-(C6-C10)-aryl, in which the alkyl and/or aryl radicals can optionally be substituted by hydroxyl, C1-C6-alkoxy, C6-C10-aryloxy or halogen; and optionally, two adjacent groups can form an isocyclic or heterocyclic group; are eminently suitable for the mass coloring of polymers, in particular polar polymers, for coloring toners, powders and powder coating materials as well as for coloring ink-jet inks.
    Type: Grant
    Filed: June 8, 2000
    Date of Patent: April 1, 2003
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bansi Lal Kaul, Bruno Piastra, Valérie Wolf
  • Patent number: 6537362
    Abstract: A method of conditioning an organic crude pigment by treating, under high shear, 1 part by weight of the crude pigment and about 0.5 to 1.9 parts by weight of polyphosphoric acid or polyphosphoric acid methyl ester at a temperature ranging from about 90 to 160° C.
    Type: Grant
    Filed: November 10, 2000
    Date of Patent: March 25, 2003
    Assignee: Sun Chemical Corporation
    Inventors: Edward H. Sung, Humberto Velasquez, George H. Roberston, Veronica L. Chambers
  • Patent number: 6537364
    Abstract: The invention provides a process for the fine division of pigments which comprises dissolving coarsely crystalline crude pigments in a solvent and precipitating them with a liquid precipitation medium by spraying the pigment solution and the precipitation medium through nozzles to a point of conjoint collision in a reactor chamber enclosed by a housing in a microjet reactor, a gas or an evaporating liquid being passed into the reactor chamber through an opening in the housing for the purpose of maintaining a gas atmosphere in the reactor chamber, and the resulting pigment suspension and the gas or the evaporated liquid being removed from the reactor through a further opening in the housing by means of overpressure on the gas entry side or underpressure on the product and gas exit side.
    Type: Grant
    Filed: October 5, 2001
    Date of Patent: March 25, 2003
    Assignee: Clariant GmbH
    Inventors: Erwin Dietz, Joachim Weber, Dieter Schnaitmann, Christian Wille, Leonhard Unverdorben, Klaus Brychcy
  • Patent number: 6533860
    Abstract: A method for preparing a green pigment composition in which a mixture of a halogen-free organic blue pigment material and a halogen-free organic yellow pigment material are subjected to an atomizing process. The atomizing process is desirably (1) a co-kneading process conducted in the presence of a grinding material, or (2) a process that comprises dissolving the above-mentioned blue pigment material and yellow pigment material in a strong acid to obtain a solution, and injecting this solution into water to obtain a re-deposited substance. The method prevents the “fogging” problem, and provides high quality green shade having simultaneously sufficient light resistance and heat resistance. The resulting organic pigment composition is excellent also in plastics coloring use requiring a heating process at higher temperature, and has high safety/sanitation property, and causes no environmental problem.
    Type: Grant
    Filed: February 21, 2001
    Date of Patent: March 18, 2003
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Yasuhiko Hatakeyama, Toshikazu Tamura, Shigeki Kato
  • Patent number: 6530989
    Abstract: A process for the preparation of an organic pigment dispersion is disclosed and consists of dispersing a dried soft-textured organic pigment in a dispersion vehicle, wherein the dispersion vehicle contains an ink varnish and alkyd and the dispersion is carried out in a tank equipped with a sweep and a high speed dispersion blade.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: March 11, 2003
    Assignee: Sun Chemical Corporation
    Inventors: Kalpathy Anantharaman, Michael Lewis, Anthony Maliyackel, Alan Gregory, Sanjoy Ganguly, Allen Bauer
  • Publication number: 20030041780
    Abstract: Ready-to-use water dispersible pigment compositions containing waer-insoluble, hydrophilic pigments are provided. The compositions comprise a stable dispersion of the pigment such as a porphyrin pigment, carmine, curcumin and a carotenoid in the form of bodies of an average size which is at the most 10 &mgr;m is provided. The pigment bodies are dispersed without the use of a surface active substance in an aqueous phase comprising a hydrocolloid. The natural pigment compositions which are useful for coloring of food products and maceuticals do not migrate in the products and they are acid stable. The compositions are useful in coating compositions for tablets and dragees.
    Type: Application
    Filed: August 19, 2002
    Publication date: March 6, 2003
    Inventors: Per Pihlmann Isager, Marianne Winning
  • Patent number: 6524382
    Abstract: The present application relates to a process for the manufacture of pigmented vitreous materials, as well as to pigmented vitreous materials, characterized by the use of soluble pigment precursors and preferably the absence of significant amounts of dispersants. These pigmented vitreous materials can be used as colored materials for any known purposes. Soluble pigment precursors comprising a partial structure are also claimed, wherein X1 is an aromatic or heteroaromatic ring, B is hydrogen or a group of the formula but at least one group B is not hydrogen, and L is a solubilizing group.
    Type: Grant
    Filed: October 10, 2000
    Date of Patent: February 25, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Patrice Bujard, Véronique Hall-Goulle, Zhimin Hao, Hitoshi Nagasue, Gerardus De Keyzer
  • Patent number: 6524383
    Abstract: Disclosed is a pigment dispersion that can be used for an ink jet printing-use pigment ink that affords stable printing characteristics and has excellent storage stability in an ink jet printer having a head driven at a high frequency and having finer nozzles in order to enhance image quality and raise the speed. Disclosed is also a method for manufacturing this pigment dispersion. This manufacturing method includes a step of surface-treating a self-dispersing type of pigment, in which at least hydrophilic, dispersibility-imparting group is introduced to the pigment surface directly and/or via a polyvalent group, and a step of dispersing the self-dispersing pigment obtained in said surface-treating step in an aqueous medium, wherein the dispersion step is a step in which at least the self-dispersing pigment, a wetting agent, and water are dispersed in the form of a liquid mixture.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: February 25, 2003
    Assignee: Seiko Epson Corporation
    Inventors: Hidehiko Komatsu, Hiroto Nakamura, Hitoshi Ohta, Masahiro Yatake, Kazuhiko Hara
  • Patent number: 6521038
    Abstract: A near-infrared reflecting composite pigment comprises a near-infrared non-absorbing colorant and a white pigment coated with the near-infrared non-absorbing pigment. The near-infrared reflecting composite pigment can be produced by mixing a colorant dispersion, in which the near-infrared non-absorbing colorant is dispersed in a liquid medium, with the white pigment in a form selected from powder or a dispersion and then drying the resultant mixture. A near-infrared reflecting coating agent comprises as a coloring agent the near-infrared reflecting composite pigment. A near-infrared reflecting material comprises a base material coated on a surface thereof with the near-infrared reflecting coating agent.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: February 18, 2003
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Hiromitsu Yanagimoto, Yoshiyuki Zama, Hisao Okamoto, Tohru Hosoda, Yoshio Abe, Michiei Nakamura
  • Patent number: 6521756
    Abstract: The present invention provides a process for preparing transparent perylimide pigments of the formula (I) in which u is a number from 0 to 8 and, if u>0, E is a chlorine or bromine atom and, where u>1, may be a combination thereof, which comprises wet-grinding a crude perylimide pigment in a liquid medium in a stirred ballmill operated at a power density of from 1.0 kW per liter of milling space and at a stirrer tip speed of more than 12 m/s under the action of grinding media having a diameter of less than or equal to 0.9 mm, and isolating the resulting pigment.
    Type: Grant
    Filed: February 5, 2001
    Date of Patent: February 18, 2003
    Assignee: Clariant GmbH
    Inventors: Joachim Weber, Gerhard Wilker, Manfred Urban, Martin Böhmer, Erwin Dietz
  • Patent number: 6517630
    Abstract: The present invention is directed to a pigment of the formula which, in a gravure ink, has a lightness L* of not more than 48, a chroma C* of at least 53 and a hue angle h of from 295 to 315.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: February 11, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Yves Grandidier, Urs Schlatter
  • Patent number: 6508957
    Abstract: The present invention relates to methods for using a maleimide of formula (I) with the proviso that R1 and R2 do not simultaneously stand for phenyl or a maleimide of formula Ia as UV fluorescent material for void detection and for the preparation of scintillators films, luminescent solar energy collectors, organic electroluminescent devices, printing inks, non-impact printing inks, electrophotographic toners, color filters, and colored high molecular organic material.
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: January 21, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Kazuhiko Kunimoto, Junji Otani, Kunihiko Kodama, Hiroshi Yamamoto, Patrick Verhoustraeten, Sonia Megert, Adalbert Braig
  • Patent number: 6506245
    Abstract: Colored pigments having one or more desired parameters and/or properties are described. These parameters and/or properties include: a) a particles size of from about 10 nm to about 300 nm; b) an accusizer number of less than 1010 particles/ml of dispersion at 15% solids which are greater than 0.5 micron; c) a filterability such that when in a liquid medium, 100 ml having 10% solids of the colored pigment filters through a 3 micron nylon absolute filter; d) a colored pigment purity of greater than about 80%, based on extractable material; and/or e) a stability such that the above-described properties do not change by more than 50% at 25 degrees C for at least one week. Colored pigments having at least one organic group and having one or more of the above-described characteristics is also described as well as a process for preparing surface-modified colored pigments.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: January 14, 2003
    Assignee: Cabot Corporation
    Inventors: Thomas A. Kinney, Friedrich K. von Gottberg, Yuan Yu, John F. Welch
  • Patent number: 6503317
    Abstract: Aqueous based pigment dispersions wherein the pigment is dispersed in a dispersant dye in the absence of any other dispersant or additive and aqueous based printing ink compositions containing these a pigment dispersions. Methods for preparing aqueous based pigment dispersions, wherein the pigment is dispersed in a dispersant dye, and method for preparing printing ink compositions incorporating these dispersions.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: January 7, 2003
    Assignee: Sun Chemical Corporation
    Inventors: Darren Mark Ortalano, Christopher Joseph Vissing
  • Patent number: 6494943
    Abstract: Colored pigments having one or more desired parameters and/or properties are described. These parameters and/or properties include: a) a particles size of from about 10 nm to about 300 nm; b) an accusizer number of less than 1010 particles/ml of dispersion at 15% solids which are greater than 0.5 micron; c) a filterability such that when in a liquid medium, 100 ml having 10% solids of the colored pigment filters through a 3 micron nylon absolute filter; d) a colored pigment purity of greater than about 80%, based on extractable material; and/or e) a stability such that the above-described properties do not change by more than 50% at 25 degrees C. for at least one week. Colored pigments having at least one organic group and having one or more of the above-described characteristics is also described as well as a process for preparing surface-modified colored pigments.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: December 17, 2002
    Assignee: Cabot Corporation
    Inventors: Yuan Yu, Friedrich K. von Gottberg, Robert M. Amici, Paul S. Palumbo
  • Patent number: 6488760
    Abstract: A universal tinting concentrate for both solvent- and water-based paints and coatings. The universal tinting concentrate is a composition which includes a colorant component, such as pigment, colorant, tinting agent and/or metal effect agent; a pigment dispersant including a moiety selected from the group consisting of an organic acid, anhydride, salt thereof, and derivative thereof, wherein the dispersant facilitates the dispersal of the colorant component in organic-based and aqueous-based vehicles; and a pH-neutralizing agent. In one embodiment of the invention, the pigment dispersant is represented by the following structure: where r and s are integers and r+s is 6 to 16; x and y are integers and x+y is 0 to 19; Z is H or COOH; and Z′ is H or COOH.
    Type: Grant
    Filed: August 31, 2000
    Date of Patent: December 3, 2002
    Assignee: The Valspar Corporation
    Inventors: Mark Binns, Dana L. Phillips, Don Diehl, Stephen Korenkiewicz, Larry Brandenburger
  • Patent number: 6485559
    Abstract: The present Application relates to pigment colourants of formula wherein R1 is C1-C6alkyl, C1-C6alkoxy, phenoxy or halogen, R2 is hydrogen, C1-C6alkyl, C1-C6alkoxy, phenoxy, halogen, acylamino, —CH2NHacyl or the radical and R3 is C1-C6alkyl, C1-C6alkoxy, phenoxy or halogen, the ring A may be further substituted by —SO3−M+, wherein M+ is a cation, and the rings B and C may be unsubstituted or further mono- or poly-substituted by halogen, hydroxy, —SH, amino, C1-C6alkylamino, C1-C6alkyl, C1-C6alkoxy, phenoxy, acylamino, C1-C6thioalkyl or by thiophenyl, and the ring B may be substituted in the 5- or 8-position by a radical of formula wherein R1, R2 and R3 are as defined above, to a process for their preparation, and to their use in the mass-coloring of synthetic materials.
    Type: Grant
    Filed: December 27, 2000
    Date of Patent: November 26, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Jean-Marie Adam
  • Patent number: 6485558
    Abstract: The invention relates to a process for the preparation of pigment granules, which comprises adding a wax or a waxy polymer to an organic pigment during the finish in an organic or aqueous organic medium and spray-drying the aqueous suspension obtained after removal of the organic solvent by steam distillation or washing out with water.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: November 26, 2002
    Assignee: Clariant GmbH
    Inventors: Hans Joachim Metz, Heinfred Ohleier
  • Patent number: 6478866
    Abstract: Aqueous pigment preparations containing a) at least one pigment, b) at least one condensation product based on A) suphonated aromatics, B) aldehydes and/or ketones and optionally C) one or several compounds selected from the group of non sulphonated aromatics, urea and urea derivatives, and c) at least one polyether polyol with a boiling point of above 150° C., at normal pressure. The inventive preparations are highly suitable for pigmenting natural or synthetic materials.
    Type: Grant
    Filed: August 14, 2000
    Date of Patent: November 12, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Roger Nyssen, Wolfgang Zarges, Achim Brand, Thomas Roick, Hans Peter Geiger
  • Patent number: 6471764
    Abstract: An etheramine pigment dispersing salt for enhancing the dispersion performance of an organic pigment composition adding to 100 parts by weight of pigment about 1 to 40 parts by weight of an etheramine pigment dispersing salt.
    Type: Grant
    Filed: November 16, 2000
    Date of Patent: October 29, 2002
    Assignee: Sun Chemical Corporation
    Inventors: George H. Robertson, Kevin A. Arthur, Russell J. Schwartz, Stanislav Vilner, George McLaren
  • Patent number: 6471762
    Abstract: Colored lustrous pigments of superior quality are prepared by dry blending a platy substrate such as a metal oxide-coated mica nacreous pigment and a hydrophobic colorant at low shear. The resulting blend exhibits a well dispersed, stable coloration, increased hydrophobicity and is particularly useful in industrial and automotive applications. The technique can also be employed to prepare pigments for cosmetic application.
    Type: Grant
    Filed: August 23, 2000
    Date of Patent: October 29, 2002
    Assignee: Engelhard Corp.
    Inventors: Carmine Vincent DeLuca, Jr., Jeannine M. Gale
  • Patent number: 6471765
    Abstract: The present invention relates to compositions comprising a sulfonated diketopyrrolopyrrole and a Mannich-type substituted dihydroquinacridone to produce colored materials having improved stability at high temperatures. The instant compositions can be used for pigmenting polymeric materials, such as color filters.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: October 29, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Gerardus De Keyzer
  • Patent number: 6471766
    Abstract: Pigment dispersants comprise compounds represented by the following formula (I) or (II) or metal, ammonium or amine salts thereof: wherein X1 is a hydrogen or halogen atom or an alkyl or acylamino group, Y1 is an anthraquinonylamino, phenylamino, naphthyl-amino or phenoxy group, each of R1 and R3 is a hydrogen atom or a substituted or unsubstituted alkyl or phenyl group, R2 is a substituted or unsubstituted alkylene, phenylene or naphthylene group, X2 is a hydrogen or halogen atom or a substituted or unsubstituted alkyl group, R4 is a substituted or unsubstituted phenyl or naphthyl group, and n means an average number of sulfonic acid groups introduced in said compound and stands for a number of from 0.5 to 2. Pigment compositions, such as colorants for gravure inks, paints or color filters, comprise pigments and the pigment dispersants.
    Type: Grant
    Filed: January 16, 2001
    Date of Patent: October 29, 2002
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Shigeru Ohki, Takayuki Soga, Kazutaka Aoki, Shotoku Takami, Hisao Okamoto, Hiroaki Saikatsu, Shirou Yamamiya
  • Patent number: 6468341
    Abstract: A pigment composition comprises a wet-ground pigment mixture of (A) &egr;-copper phthalocyanine and (B) at least one pigment selected from a group consisting of condensed polycyclic pigments and azo pigments. The weight ratio of thecomponent (A) to the component (B) is 100:0.1 to 100:50. The pigment composition can be produced by wet-grinding (A-1) &agr;-copper phthalocyanine and the component (B) at a weight ratio of from 100:0.1 to 100:50 in a non-aromatic solvent. A colorant comprises the pigment composition and at least one component selected from the group consisting of film-forming resins and liquid media. A colored article can be obtained using the colorant as a coloring agent.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: October 22, 2002
    Assignee: Dainichiseika Color & Chemicals
    Inventors: Nobuto Wada, Kazutaka Aoki, Yutaka Nakagawa, Shotoku Takami, Michiei Nakamura
  • Patent number: 6451103
    Abstract: There is disclosed a self-dispersible aqueous pigment dispersion and preparing method thereof, the dispersion comprising an aqueous solution, particles of a pigment and a water-soluble pigment derivative, said particles being dispersed in the aqueous pigment dispersion in a concentration within the range from 2 to 25 wt. % based on the amount of the aqueous pigment dispersion, wherein a part of the water-soluble pigment derivative is adsorbed on the surface of the particles of the pigment to form dispersed particles comprising the particles of the pigment adsorbed by said part of the pigment derivative, and the remaining parts of the water-soluble pigment derivative are free in the dispersion without being adsorbed on the surface of the pigment in a concentration less than the critical flocculation concentration on which flocculation is initiated on said particles of the pigment dispersed under said concentration.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: September 17, 2002
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Toshiyuki Uemura, Tsukasa Iguchi, Mikiya Kato, Akimitsu Mochizuki
  • Patent number: 6440207
    Abstract: This invention relates to a process for preparing dispersible organic pigments by (a) milling a mixture containing (1) one or more organic pigments, (2) at least about 1% by weight, relative to the organic pigment, of one or more aromatic polyalkylene oxide dispersants, (3) 0 to about 10 parts by weight, relative to the organic pigment, of a milling liquid in which the organic pigment is substantially insoluble, (4) 0 to about 50% by weight, relative to the organic pigment, of one or more milling additives other than dispersant (2), and (5) 0 to about 20% by weight, relative to the organic pigment, of one or more surface treatment additives; (b) optionally, adding to the milled pigment (6) one or more liquids in which the organic pigment is substantially insoluble in amounts such that the total solids content is not reduced below about 10%, and (7) one or more multivalent metal salts and/or one or more quaternary ammonium salt; and (c) isolating the milled organic pigment
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: August 27, 2002
    Assignee: Bayer Corporation
    Inventor: Gregory R. Schulz
  • Patent number: 6440206
    Abstract: The present invention is directed to a composition comprising a sorbitan ester of the formula I and a monoazo pigment. The present invention further encompasses a process for its preparation and its use as well as the use of the sorbitan ester I as additive to improve color strength and dispersion properties.
    Type: Grant
    Filed: September 19, 2000
    Date of Patent: August 27, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Greig Chisholm, Barry William Hay
  • Patent number: 6436182
    Abstract: The invention relates to an advantageous process for producing highly concentrated pigment presscakes which comprises concentrating a pigment suspension on a high-pressure filter press with a pressure of at least 16 bar to a pigment content of at least 50% by weight without adding nonionic surfactants which have a cloud point in water.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: August 20, 2002
    Assignee: Clariant GmbH
    Inventors: Leonhard Unverdorben, Uwe Nickel, Andreas Harz, Gunnar Tilch
  • Patent number: 6432192
    Abstract: A pigment is synthesized in an aqueous medium and the pigment dispersion is purified by ultrafiltration or microfiltration. In particular, an aqueous pigment dispersion having a very small average particle size and a narrow particle size distribution may be prepared by the steps of (a) synthesizing a pigment in an aqueous medium and (b) removing an impurity such as a dissolved synthesis by-product or unreacted starting material through cross flow filtration using a membrane having an average pore diameter of from about 3 nanometers to about 3000 nanometers to produce a purified aqueous pigment dispersion.
    Type: Grant
    Filed: February 23, 2000
    Date of Patent: August 13, 2002
    Assignee: Flint Ink Corporation
    Inventors: Wayne L. Cook, Douglas P. Gebler, Norman E. Pratt
  • Patent number: 6432194
    Abstract: Various modified pigment products are described which are preferably capable of being dispersed in a variety of materials such as coatings, inks, toners, films, plastics, polymers, elastomers, and the like. The modified pigments are pigments having attached groups, such as polymeric groups, onto the pigment by means other than adsorption. A modified pigment product is described comprising a pigment having attached at least one group comprising the formula: —X—[NIon]pR wherein X comprises an aromatic group or an alkyl group, NIon comprises at least one type of non-ionic group, R represents hydrogen or comprises an aromatic group or an alkyl group, and p represents an integer from 1 to 500. Modified pigment products are also described comprising a pigment having attached at least one alkylene oxide group or at least one polymeric group.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: August 13, 2002
    Assignee: Cabot Corporation
    Inventors: Joseph E. Johnson, Nanying Bian, Collin P. Galloway
  • Patent number: 6432193
    Abstract: This invention relates to a continuous process for preparing perylenes by (a) continuously mixing a melt of the leuco form of a perylene tetracarboxylic diimide obtained by alkaline fusion of naphthalimide with a continuous water-containing stream containing (1) 2 to 50 parts of water per part of melt, (2) 0 to X1 moles of oxidizing agent per mole of the leuco form, (3) 0 to Y1 parts by weight of processing additives, based on the leuco form, and (4) 0 to Z1 parts by weight of an acid, based on the leuco form of the perylene tetracarboxylic diimide, to form a slurry; and (b) optionally mixing the slurry in one or more continuous or batchwise steps with a second stream containing (1) 0 to 10 parts by weight of water, based on the slurry, (2) 0 to X2 moles of oxidizing agent per mole of the leuco form of the perylene tetracarboxylic diimide, with the proviso the total of X1 and X2 represents at least the molar amount of oxidizing agent theoretically needed to oxidize all of the leuco form of the perylene tetr
    Type: Grant
    Filed: December 15, 1999
    Date of Patent: August 13, 2002
    Assignee: Bayer Corporation
    Inventors: Thomas R. Flatt, Richard Kent Faubion, Mark A. Putnam, Ulrich Feldhues, Richard A. Vogel
  • Patent number: 6423132
    Abstract: The present invention is drawn to pigment granules having a particle size from 0.5 to 4 mm, which consist of at least 90% by weight of at least one organic pigment selected from the group consisting of diketopyrrolopyrrole, quinacridone, perylene, indanthrone, flavanthrone, isoindolinone or amino- anthraquinone pigments and from 0 to 10% by weight of a binder having from 2 to 7 mol of carboxyl groups per 1000 g and from 0 to 5% by weight of a neutral emulsifier. The binder and the emulsifier together do not represent more than 10% by weight of the oveerall amount of pigment granules. The pigment present in the pigment granules has a particle size of from 0.01 to &mgr;m.
    Type: Grant
    Filed: February 15, 2001
    Date of Patent: July 23, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Paolo Balliello, Horst Olaf Brücker
  • Publication number: 20020088375
    Abstract: A method for manufacturing a pigment dispersed liquid, comprising at least:
    Type: Application
    Filed: June 28, 2001
    Publication date: July 11, 2002
    Applicant: SEIKO EPSON CORPORATION
    Inventors: Hidehiko Komatsu, Kazuhiko Hara, Hitoshi Ota, Hiroko Hayashi
  • Patent number: 6413309
    Abstract: Pigment preparations comprising a) at least one organic base pigment, b1) at least one perylene pigment dispersant of the formula (I)  and b2) at least one acidic, carboxyl- or sulfo-containing perylene pigment dispersant have advantageous rheological and coloristic properties.
    Type: Grant
    Filed: January 25, 2000
    Date of Patent: July 2, 2002
    Assignee: Clariant GmbH
    Inventors: Joachim Weber, Manfred Urban, Manfred Opravil, Erwin Dietz
  • Patent number: 6409956
    Abstract: An injection-molding process using warp-free pigment compositions including diaryldiketopyrrolo[3,4-C]pyrroles to improve the dimensional stability of the injection molded product by decreasing warping wherein the constituents of the formulation being injection molded are added into an injection molding machine in ready-premixed form or simultaneously as individual components. Preferred pigments are quinacridone pigments, disazo condensation pigments, isoindolinone pigments and pyrrolo[3,4-C]pyrrole pigments with pyrrolo[3,4-C]pyrrole pigments being especially preferred.
    Type: Grant
    Filed: April 20, 1999
    Date of Patent: June 25, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Franck Rey Flandrin, Guo-Hua Hu, Philippe Bugnon, Zhimin Hao
  • Patent number: 6409816
    Abstract: Pigment preparations comprise a) at least one diketopyrrolopyrrole pigment, and b) at least one perylene pigment dispersant of the formula (I)  and have advantageous rheological and coloristic properties.
    Type: Grant
    Filed: February 16, 2000
    Date of Patent: June 25, 2002
    Assignee: Clariant GmbH
    Inventors: Joachim Weber, Erwin Dietz
  • Patent number: 6410619
    Abstract: This invention relates to a process for preparing conditioned organic pigments by (a) milling a mixture comprising: (1) one or more crude organic pigments; (2) at least about 0.1% by weight, relative to the organic pigment, of one or more acrylic copolymer dispersants; and (3) 0 to about 100 parts by weight, relative to the organic pigment, of a milling liquid in which the organic pigment is substantially insoluble; and (b) isolating the milled organic pigment.
    Type: Grant
    Filed: November 22, 1999
    Date of Patent: June 25, 2002
    Assignees: Bayer Corporation, E.I. DuPont De Nemours and Company
    Inventors: Michael J. Greene, Patrick F. McIntyre, James G. King, Gregory R. Schulz, Karyn B. Visscher
  • Patent number: 6406525
    Abstract: New dioxazine compounds and mixtures thereof containing sulphonic acid groups according to formula (I) in which the substituents have the meanings given in claim 1, processes for their production and the use of such compounds for dyeing or printing organic substrates or as a component of printing inks.
    Type: Grant
    Filed: October 2, 2001
    Date of Patent: June 18, 2002
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Ludwig Hasemann
  • Patent number: 6403797
    Abstract: This invention relates to a process for preparing perylene pigment compositions by (a) reacting, at a temperature of less than about 25° C., a mixture of (1) a perylene tetracarboxylic compound, (2) at least about 0.1% by weight, relative to the perylene tetracarboxylic compound, of a surfactant of formula (I)  wherein R1, R2, R3, X, Y, Z, and Z′ are defined herein, (3) an equivalent excess, relative to the amount of the perylene tetracarboxylic compound, of ammonia or a primary amine RA—NH2, wherein RA is defined herein, and (4) optionally, a solvent,  to form a perylene intermediate; (b) heating the perylene intermediate at a temperature of about 50° C. to about 250° C., optionally in the presence of certain non-pigmentary cyclic anhydrides or imides and/or solvents; and (c) collecting the perylene pigment composition.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: June 11, 2002
    Assignee: Bayer Corporation
    Inventors: Charles W. Sandefur, Brian L. Thompson, Michael J. Greene, Gregory R. Schulz
  • Patent number: 6398858
    Abstract: The present invention relates to a process for preparing surface-modified colored pigments. The process includes the steps of: preparing a reaction batch comprising a treating agent and a diazotizing agent; adding a colored pigment to the batch; and mixing the colored pigment and the batch under high shear conditions to form a reaction product comprising a surface-modified colored pigment. The treating agent has an organic group which comprises at least one diazotizable group. In a preferred embodiment the diazotizable group comprises a) at least one aromatic group or at least one C1-C20 alkyl group, and b) at least one ionic group, ionizable group, nonionic group, or a mixture thereof. The surface-modified colored pigments prepared by the process of the present invention have been found useful in aqueous or solvent based compositions and particularly in ink jet ink compositions.
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: June 4, 2002
    Assignee: Cabot Corporation
    Inventors: Yuan Yu, Ronald J. Gambale, Robert M. Amici
  • Patent number: 6391104
    Abstract: This invention relates to perylene pigment compositions containing a reactive co-precipitated blend of (1) about 75 to about 99.9 mol %, relative to the pigment composition, of a compound having the formula (I)  wherein R is hydrogen, C1-C6 alkyl, C5-C8 cycloalkyl, C7-C6 aralkyl, or C6-C10 aryl, A is C1-C6 alkyl, C1-C6 alkoxy, a sulfonyl group, amino, ammonium, hydroxy, nitro, or halogen, and m is zero or a number from 1 to 8; and (2) about 0.1 to about 25 mol %, relative to the pigment composition, of a perylene dicarboxamidine imide having the formula (II)  wherein W is optionally substituted or modified C2-C3 alkylene, and R, A, and m are defined as above.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: May 21, 2002
    Assignee: Bayer Corporation
    Inventor: Gregory R. Schulz
  • Patent number: 6387170
    Abstract: An orange laked monoazo pigment has the following formula (I): wherein M is an alkaline metal selected from the group consisting of calcium, barium, strontium, magnesium and manganese.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: May 14, 2002
    Assignee: Dominion Colour Corporation
    Inventors: Alan Gray, Henry Lui, Dorothy-Grace Manarang-Pena
  • Patent number: 6379451
    Abstract: There are disclosed a pigment composition comprising a dry-milled pigment, a water-soluble resin, and a nonionic surfactant composed of a compound having an acetylenic linkage; and a method for producing a pigment composition, comprising dry-milling a pigment containing coarse particles in the presence of a water-soluble resin and a nonionic surfactant composed of a compound having an acetylenic linkage. The production method is also possible in the form of comprising (a) dry-milling a pigment containing coarse particles in the presence of a nonionic surfactant composed of a compound having an acetylenic linkage thereby obtaining an intermediate milled product, and (b) further dry-milling a mixture of the intermediate milled product and a water-soluble resin.
    Type: Grant
    Filed: April 4, 2000
    Date of Patent: April 30, 2002
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Kenji Kitamura, Ataru Chiba
  • Patent number: 6375734
    Abstract: An alpha-II form of a 1,4-diketo-3,6-di(4′-tertiary butyl phenyl)-2,5-dihydro pyrrolo[3,4-c]pyrrole pigment characterized by C.I.E color space values, particularly a high chroma value and yellow hue, in masstone, and a process for its preparation is disclosed. The 1,4-diketo-3,6-di(4′-tertiary butyl phenyl)-2,5-dihydro pyrrolo[3,4-c]pyrrole pigment is especially useful for coloring coating compositions, such as automotive paints, and plastics.
    Type: Grant
    Filed: November 14, 2000
    Date of Patent: April 23, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Bäbler
  • Patent number: 6375732
    Abstract: Hybrid pigments of diketopyrrolo[3,4-c]pyrrole pigments and pigments bearing “acid” hydrogens like —NH, —OH or —CONH— groups, a process for the manufacturing of the hybrid diketopyrrolo[3,4-c]pyrrole pigments with pigments bearing “acid” hydrogens like —NH, — OH or —CONH— groups and their use as a pigment.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: April 23, 2002
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bansi Lal Kaul, Bruno Piastra, Valérie Wolf
  • Patent number: 6361594
    Abstract: A process is disclosed for the direct preparation of pigmentary 1,4-diketopyrrolo-[3,4-c]pyrroles of the formula (I) wherein each of R1 and R2 independently of the other is an isocyclic or heterocyclic aromatic radical, which process comprises heating an appropriate molar ratio of a disuccinate with a nitrile of the formula (II) R1—CN  (II) or of the formula (III) R2—CN  (III) or with mixtures of said nitrites, in an organic solvent and in the presence of a strong base and an effective amount of a selected particle growth inhibitor of formula (IV)-(X), and then obtaining the compound of formula (I) from the reaction product by protolysis. The process yields pigmentary 1,4-diketopyrrolo-[3,4-c]pyrroles directly, i.e., without the need for additional particle-size reducing aftertreatments. Also disclosed is a composition comprising a pigmentary 1,4-diketopyrrolo-[3,4-c]pyrrole and the particle growth inhibitor.
    Type: Grant
    Filed: February 14, 2000
    Date of Patent: March 26, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Shivakumar B. Hendi
  • Patent number: 6358304
    Abstract: A rheology-modified ink includes (1) an ink carrier, which is either aqueous-based or solvent-based, (2) an organic pigment, which is preferably an azo pigment of the type generally used with an aqueous-based ink carrier, and (3) a flow-modifier, which is a metal salt of either an aromatic carboxylic acid or an aromatic hydroxy carboxylic acid. Addition of the flow-modifier (also called a rheology-modifier) improves the dispersion of pigment within the aqueous-based carrier thereby improving the flow characteristic of the ink. Also disclosed is a pigment including a flow-modifier and a rheology-modified paint.
    Type: Grant
    Filed: May 18, 1999
    Date of Patent: March 19, 2002
    Assignee: Uhlich Color Company, Inc.
    Inventor: Sain D. Kapoor