Abstract: Methods and compositions are disclosed that comprise cement kiln dust having a mean particle size that has been altered. An embodiment discloses a method of preparing cement kiln dust comprising: providing cement kiln dust having an original particle size; and altering the mean particle size of the cement kiln dust from the original size by grinding, separating, or a combination thereof. Another embodiment discloses a well treatment fluid comprising: cement kiln dust having a mean particle size that has been altered from its original size by grinding, separating, or a combination thereof; and water.

Abstract: Embodiments disclose method and compositions that comprise cement kiln dust and rice husk ash. An embodiment comprises a method of cementing comprising: placing a settable composition into a subterranean formation, the settable composition comprising cement kiln dust, rice husk ash, and water; and allowing the settable composition to set.

Abstract: The disclosure concerns cost effective concrete formulations based on an alkali activated binder. The construction material of the concrete type, contains sand, fine aggregates, coarse aggregates, water and a binder comprising: from 55 to 80 wt. % of fly ash containing less than wt. 8% of CaO; from 15 to 40 wt. % of blast furnace slag; a chemical activator containing: from 0.8 to 4 wt. % of alkaline silicates; and from 1.5 to 9 wt. % of alkaline carbonates; wherein the chemical activator has an silica to alkali molar ratio from 0.1 to 0.55; and a booster comprising at least one strong base. The disclosure also concerns a method to produce such a concrete construction material.

Abstract: The present invention is directed to plug-and-abandon operations that use plugging compositions comprising cement kiln dust, pumicite, and/or lime. An embodiment includes a method of plugging a well bore for abandonment comprising: placing a plugging composition in the well bore, the plugging composition comprising: cement kiln dust in an amount of about 5% to about 100% by weight of cementitious components, pumicite in an amount of about 5% to about 100% by weight of cementitious components, 0% to about 24% of Portland cement by weight of cementitious components, and water; and allowing the plugging composition to set and form a plug.

Abstract: The present invention relates to acid-soluble cement compositions that comprise cement kiln dust (“CKD”) and/or a natural pozzolan and associated methods of use. An embodiment includes a method of cementing comprising: placing an acid-soluble cement composition in a subterranean formation, wherein the acid-soluble cement composition comprises a hydraulic cement, a component selected from the group consisting of CKD, pumicite, and a combination thereof, and water; allowing the acid-soluble cement composition to set; and contacting the set acid-soluble cement composition with an acid to dissolve the set acid-soluble cement composition.

Abstract: The present disclosure relates to geothermal grout, methods of making geothermal grout, and methods of using geothermal grout. The present disclosure is further directed to an geothermal grout with relative ease of preparation and desirable thermal conductivity while maintaining good sealant properties.

Abstract: Embodiments disclose method and compositions that comprise cement kiln dust and rice husk ash. An embodiment comprises a method of cementing comprising: placing a settable composition into a subterranean formation, the settable composition comprising cement kiln dust, rice husk ash, and water; and allowing the settable composition to set.

Abstract: The present invention provides settable compositions and methods of using settable compositions that comprise a hydraulic cement; a partially calcined kiln feed comprising SiO2, Al2O3, Fe2O3, CaO, MgO, SO3, Na2O, and K2O; metakaolin; and water. The location to be cemented may be above ground or in a subterranean formation.

Abstract: The present invention provides a composition and a process for the preparation of chemical activated cold setting fly ash building construction materials. The chemical activator is an alkaline aqueous solution of 11.2 to 13.6 in pH and 1.25 to 1.40 gm/cc in density which contains admixtures of different concentrations of hydroxyl, sulfate, acetate and chloride bearing chemical salts of calcium, magnesium, sodium, potassium and aluminum in water medium. The reaction of chemical activator solution and the mineral constituents of fly ash mix develop binding property. The binding matrix of chemical activated fly ash mix is mostly hydrous silica and silicate group of phases which on setting under atmospheric condition attains strength suitable for building construction application. Utilization of fly ash of any source by weight ranges from 80 to 99% in manufacture of building materials including heat and acid resistance and toxic waste disposal products.

Abstract: Hydraulic binder comprising: at least one first calcium aluminosilicate derivative with a fineness of less than 6000 Blaine, slag microparticles with a fineness of greater than or equal to 6000 Blaine in an amount of between 1 and 35% of the total weight of the binder, preferably of between 5 and 15%, at least one source of calcium sulphate and at least one base in an amount of less than or equal to 1% of the total weight of the binder.

Abstract: Cement compositions containing biowaste ash and methods of cementing in subterranean formations using such cement compositions. Examples of suitable biowaste ash include agricultural waste ash, municipal waste ash, waste-water treatment waste ash, animal waste ash, non-human-non-animal industrial waste ash, and combinations thereof.

Abstract: The present invention relates to concrete with necessary durability using seawater and sea sand. The seawater mixed concrete of the present invention is obtained by mixing a mixture including slag-containing cement and sea sand, with seawater. And by including a nitrite-based admixture and pozzolan, the diffusion coefficient of concrete after hardening can be reduced to restrain the external intrusion of harmful factors. Further, the concrete structure according to the present invention can include seawater mixed concrete and reinforcement for increasing tensile strength.

Abstract: A method for manufacturing concrete bodies or forms containing electric arc furnace dust in an amount of up to about 4% at elevated temperatures to provide concrete bodies is disclosed. The concrete bodies have improved compressive strength and slump retention capability. The method for producing the bodies includes the steps of providing pre-selected amounts of electric arc furnace dust, water, cement and aggregate. The electric arc furnace dust is mixed with water and then added to the cement and aggregate and mixed together at a temperature of about 32° C. and 45° C. to form a hot mixture. The hot mixture is added to a mold and cast at an elevated temperature to form a body with improved strength and slump retention characteristics.

Abstract: A masonry product is formed from a composition comprising a blend of fly ash and kiln dust. A process for forming the product comprises mixing fly ash, kiln dust, and water; and applying a pressure.

Abstract: A thermally enhanced, single component, geothermal grout from recycled materials, such as class F fly ash and cement kiln dust. Additional components can include a mid-range water reducer and a dry caustic.

Abstract: A grout for filing a micro-trench formed in the ground includes comprises Class F fly ash in a range of approximately 0 to 30% by weight of grout and cement kiln dust in a range of approximately 50 to 90% by weight of grout.

Abstract: The present invention relates to building material mixtures which contain slag sand and zinc salts which have from 0 to 8 carbon atoms in their structure. The invention furthermore relates to the use of zinc salts for preventing discolorations during the hardening of the building material mixtures.

Abstract: Techniques are generally described for producing cement clinker that includes forming cement clinker in a kiln, heating waste additives, and applying the heated waste additives to the cement clinker in the kiln. Additionally, examples are generally described that include an apparatus for producing cement clinker that includes a kiln in which cement clinker is formed and a device having an opening positioned inside the kiln which provides heated waste additives to the kiln for application to the cement clinker. An example device for applying waste additives to cement clinker includes an eductor configured to receive waste additives and transport air in which the waste additives are pneumatically entrained, and includes a lance coupled to the eductor and configured to receive the pneumatically entrained waste additives and receive a support gas that reacts with the waste additives and heats the same for application to the cement clinker.

Abstract: Mineral Lime is a composition having from about 85% to about 95% by volume of fly ash and from about 5% to about 15% by volume of kiln dust. A composition for Mineral Lime can also have from about 85% to about 95% by volume of Class C fly ash; and from about 5% to about 15% by volume of lime kiln dust. A process for producing a composition of Mineral Lime including fly ash and kiln dust, includes the steps of feeding fly ash to a blender; feeding kiln dust to the blender; and blending the fly ash and kiln dust in the blender.

Abstract: Methods of manufacture and use of flowable materials are provided. The flowable fill materials include a cement-based fill material with a cement component and an aggregate component that are mixed with a chemical agent and the like in water. This provides the cement-based material in a flowable state that can be controllably set over time.

Abstract: The present invention relates to geopolymer compositions, methods of producing the compositions, and uses thereof. The geopolymer compositions broadly are comprised of a geopolymer binder and an aggregate and, once cured, can exhibit compressive strengths in excess of that of Portland cement-based concrete formulations. The geopolymer composition of the present invention adheres to most surfaces and can b used in the formation of a mortarless building block, floor screed, bench, building block brick, support column or pre-molded column, beam, paving stone, tiles, stone accouterment for a garden, countertop, bathtub, sink, a geopolymer slab, a structural geopolymer composition, a reinforced geopolymer composition, a steel reinforced geopolymer composition, or as a substitute for structural concrete in foundations, beams, columns, or slab with the addition as necessary of steel reinforcement.

Abstract: A high early strength blended cement composition includes larger sized fly ash and/or natural pozzolan particles blended with smaller sized hydraulic cement particles containing tricalcium silicate and/or dicalcium silicate (e.g., Portland cement and/or ground granulated blast furnace slag). Excess calcium released from the hydraulic cement particles when mixed with water forms calcium hydroxide available for reaction with the fly ash and/or natural pozzolan. The fineness of the hydraulic cement particles is substantially greater than the fineness of the fly ash and/or natural pozzolan particles (e.g., about 1.25 to about 50 times greater). Reducing or eliminating coarse hydraulic cement particles that cannot fully hydrate but include unreacted cores reduces or eliminates wasted cement normally found in concrete.

Abstract: Mercury adsorbed from combustion gas by activated carbon can be sequestered in concrete containing air-entraining admixtures. The activated carbon may be made by providing a carbon char made from coconut shell, wood, or lignite that was activated by a method selected from the group consisting of activating with steam, activating with CO2, activating in an environment containing free oxygen, and combinations thereof to provide an activated carbon with an Acid Blue 80 Index of less than about 30 milligrams per gram of carbon. The activated carbon may be injected into a combustion gas stream containing fly ash and mercury and may then be removed with fly ash from the gas stream. The resulting composition may be used as a partial substitute for cement in air-entrained concretes.

Abstract: When fly ash is added to a cement kiln to materialize it after being desalinated by washing, scale is prevented from growing in a dissolution reaction apparatus depositing calcium-containing compounds dissolved in slurry, and the fly ash is effectively used as a cement material. A dissolution reaction apparatus according to the invention comprises: a dissolution tub 3 for dissolving powder material, a wet dust collector 5 for collecting powder material and mist while reacting slurry S in the dissolution tub 3 with gas G and returning the collected powder material and mist to the dissolution tub 3. A second wet dust collector 7 can be provided for collecting powder material and the like accompanying to the gas G discharged from the wet dust collector 5, and both the wet dust collectors 5, 7 can be vertical type and mounted independently with each other on the dissolution tub 3.

Abstract: The present invention relates to the field of settable compositions for general purpose concrete mixes, and more particularly to settable compositions containing pulverized fly ash and/or bottom ash for improved final and early strength. The fly ash and/or bottom ash is pulverized to a Blaine fineness of 4000 cm2/g or more.

Abstract: A high early strength pozzolan cement includes larger sized pozzolan particles blended with smaller sized hydraulic cement particles containing tricalcium silicate and/or dicalcium silicate (e.g., Portland cement). Excess calcium release from the hydraulic cement when mixed with water forms calcium hydroxide available for reaction with the pozzolan. The fineness of the hydraulic cement particles is substantially greater than the fineness of the pozzolan particles (e.g., about 1.25 to about 50 times greater). Reducing or eliminating coarse hydraulic cement particles that cannot fully hydrate but include unreacted cores reduces or eliminates wasted cement normally found in concrete. Replacing some or all of the coarse cement particles with pozzolan particles provides a pozzolan cement composition having significantly lower water demand compared to the hydraulic cement by itself.

Abstract: The sealing agent for waterproof barriers in the form of a clay and cement suspension made of polymineral clays, characterized by the fact that it contains 3-15% parts by weight of cement, up to 65% parts by weight of fly-ash and/or rock dust of similar granulation, and 30-60% parts by weight, or better up to 50% parts by weight, of water suspension of clay, heavy or loamy.

Abstract: The present invention includes concrete block comprising one or more of limestone, volcanic ash, shellfish shells, seashells, rice hull ash, slag, fly ash, or any suitable combination of the same. The present invention further includes concrete block having one or more facial surface structures on one or more sides of the concrete block. The facial surface structures may include the structures referred to and illustrated herein as Socket Block, Fold Block, Bracket Block, Awning Block, Chisel Block, Spade Block, Shim Block, Pachinko Block, Tornado Block, Ripple Block, Sine Block, or Egg Block.

Abstract: The present invention relates to acid-soluble cement compositions that comprise cement kiln dust (“CKD”) and/or a natural pozzolan and associated methods of use. An embodiment includes a method of cementing comprising: placing an acid-soluble cement composition in a subterranean formation, wherein the acid-soluble cement composition comprises a hydraulic cement, a component selected from the group consisting of CKD, pumicite, and a combination thereof, and water; allowing the acid-soluble cement composition to set; and contacting the set acid-soluble cement composition with an acid to dissolve the set acid-soluble cement composition.

Abstract: The present invention is directed to plug-and-abandon operations that use plugging compositions comprising cement kiln dust, pumicite, and/or lime. An embodiment includes a method of plugging a well bore for abandonment comprising: placing a plugging composition in the well bore, the plugging composition comprising: cement kiln dust in an amount of about 5% to about 100% by weight of cementitious components, pumicite in an amount of about 5% to about 100% by weight of cementitious components, 0% to about 24% of Portland cement by weight of cementitious components, and water; and allowing the plugging composition to set and form a plug.

Abstract: Sorbent components containing calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents are added to the coal ahead of combustion and/or are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.

Abstract: A method for making a low embodied energy cementitious mixture by blending a variety of post-consumer wastes, post-industrial wastes, as well as renewable, organic and recyclable materials with Portland cement or a material having similar cementitious properties. The primary materials are recycled concrete, coal-fired fly ash waste, silica fume, post-industrial waste, organic or inorganic waste fibers. Glass, brick, ceramics, ground tires and other waste products, as well as virgin aggregate can also be included in the low embodied energy cementitious mixture.

Abstract: Mercury adsorbed from combustion gas by activated carbon can be sequestered in concrete containing air entraining admixtures. The activated carbon may be made by providing a carbon char made from anthracite or low-volatile bituminous coal that was devolatilized and carbonized in an oxygen-depleted environment and activating this char in the presence of steam to provide an activated carbon with an acid blue 80 index of less than about 30 milligrams per gram of carbon. The activated carbon may also be made by providing a carbon char that was devolatilized and carbonized in an oxygen-depleted environment and activating this char in the presence of oxygen to provide an activated carbon. The carbon may be injected into a combustion gas stream containing fly ash and mercury and may then be removed with fly ash from the gas stream. The resulting composition may be used as a partial substitute for cement in air-entrained concretes.

Abstract: Cement compositions and methods for making cement compositions are provided. The cement compositions can comprise at least one oxide having a particle size of less than about 600 nm.

Abstract: The present invention concerns the development of a simple, multipurpose, low cost, environmental friendly and safe binder formulation and related process, based on high volumes of alkaline activated class F fly ash residue (>760%) without ordinary Portland cement and related products, offering a wide scope of applications. More specifically, the universal binder is based on a very limited number of components (fly ash type F, Blast Furnace Slag and a mixture of alkali silicates and carbonates). The binder allows developing considerable strength at the early stage (at room temperature) and very high resistances at 28 days. The binder applies to pastes, mortars concretes and pre-cast with the same flexibility of an Ordinary Portland Cement.

Abstract: A thermally enhanced, single component, geothermal grout from recycled materials, such as class F fly ash and cement kiln dust. Additional components can include a mid-range water reducer and a dry caustic.

Abstract: There is provided a process for producing concrete, comprising: in producing concrete, previously providing at least one premix composition for a concrete mix, which has been measured and prepared by automatic control means according to properties required of the concrete; and kneading and mixing the previously provided premix composition for a concrete mix with cement, coarse aggregate, fine aggregates, and water.

Abstract: An embodiment of the present invention includes a method of cementing in a subterranean formation comprising: providing an extended settable composition comprising hydraulic cement, cement kiln dust, water, and a set retarding additive, wherein the extended settable composition is capable of remaining in a pumpable fluid state for at least about 1 day; adding a cement set accelerator to the extended settable composition; introducing the extended settable composition into a well bore; and allowing the extended settable composition to set. Another embodiment of the present invention includes a method of cementing in a subterranean formation comprising: providing an extended settable composition comprising hydraulic cement, cement kiln dust, water, and a set retarding additive; storing the extended settable composition; adding a cement set accelerator to the extended settable composition; introducing the extended settable composition into a well bore; and allowing the extended settable composition to set.

Abstract: A cementitious matrix for forming a moulded masonry product, the matrix formed from a group of materials comprising; an aggregate comprising granulated iron blast furnace slag; air-cooled iron blast furnace slag, bottom ash, pulverised fuel ash and at least one cementitious binder; and ground granulated iron blast furnace slag acting as binder and aggregate; and water.

Abstract: A variety of methods and compositions are disclosed herein, including, in one embodiment, a method comprising: introducing a settable composition into a subterranean formation, wherein the settable composition comprises: a cementitious component comprising a hydraulic cement and cement kiln dust; a swellable particle; and water; and allowing the settable composition to set in the subterranean formation. Another embodiment comprises a settable composition comprising: a cementitious component comprising a hydraulic cement and cement kiln dust, a swellable particle, and water.

Abstract: An embodiment of a method of cementing comprises: introducing a cement composition into a subterranean formation, wherein the cement composition comprises cement kiln dust, a natural pozzolan, and water; and allowing the cement composition to set. Another embodiment of a method comprises: introducing a cement composition into a subterranean formation, wherein the cement composition comprises a cement, a natural pozzolan, and water, wherein the cement comprises Portland cement interground with burned shale; and allowing the cement composition to set. Another embodiment includes a cement composition comprising at least one additive selected from the group consisting of cement, cement kiln dust, Portland cement interground with burned shale, and a combination thereof; a natural pozzolan; and water.

Abstract: Wallboards, as well as other building materials, are produced by methods which use significantly reduced embodied energy, generating far less greenhouse gases when compared with the energy used to fabricate gypsum wallboard. A novel cementitious core, consisting in one embodiment of post-industrial waste such as slag and combined with pH modifiers, provides a controlled exothermic reaction to create a gypsum-wallboard-like core which can be wrapped in a selected material such as recycled paper and manufactured on a conveyor system to appear, weigh and handle similar to gypsum wallboard, but without the large amounts of energy required to make gypsum wallboard. The manufacturing process results in lower greenhouse gas emissions than the processes used to make gypsum wallboard.

Abstract: An embodiment of the present invention includes a method of cementing in a subterranean formation comprising: providing an extended settable composition comprising hydraulic cement, cement kiln dust, water, and a set retarding additive, wherein the extended settable composition is capable of remaining in a pumpable fluid state for at least about 1 day; adding a cement set accelerator to the extended settable composition; introducing the extended settable composition into a well bore; and allowing the extended settable composition to set. Another embodiment of the present invention includes a method of cementing in a subterranean formation comprising: providing an extended settable composition comprising hydraulic cement, cement kiln dust, water, and a set retarding additive; storing the extended settable composition; adding a cement set accelerator to the extended settable composition; introducing the extended settable composition into a well bore; and allowing the extended settable composition to set.

Abstract: The present invention includes concrete block comprising one or more of limestone, volcanic ash, shellfish shells, seashells, rice hull ash, slag, fly ash, or any suitable combination of the same. The present invention further includes concrete block having one or more facial surface structures on one or more sides of the concrete block. The facial surface structures may include the structures referred to and illustrated herein as Socket Block, Fold Block, Bracket Block, Awning Block, Chisel Block, Spade Block, Shim Block, Pachinko Block, Tornado Block, Ripple Block, Sine Block, or Egg Block.

Abstract: This invention discloses a high strength magnesium slag brick and a method of producing the same. The high strength magnesium slag brick is composed of 60 to 80 percent by weight of furnace slag from the reduction process of a magnesium production, 15 to 25 percent by weight of crushed stones and/or pebbles, and 1 to 15 percent by weight of gypsum and/or lime. And the amount of water added to the composition is equivalent to 10 to 40 percent of the total weight of raw materials. The method includes dispensing of raw materials, adding of water, mingling, leaving it piled-up, pressing and molding, steam-bathing and drying to obtain the finished product. Gypsum, one of the raw materials of the slag brick, can be produced from the waste gas generated from the magnesium production process. And, the coal cinder or coal ash generated from the burning of coal in the magnesium production process, can also be used as one of the raw materials of the slag brick.

Abstract: A hydraulic composition of the present invention includes (A) 100 parts by weight of cement having a Blaine specific surface area of 2,500 to 5,000 cm2/g, (B) 10 to 40 parts by weight of fine particles having a BET specific surface area of 5 to 25 m2/g, and (C) 15 to 55 parts by weight of inorganic particles having a Blaine specific surface area which is 2,500 to 30,000 cm2/g and which is larger than that of the cement. The inorganic particles (C) may comprise 10 to 50 parts by weight of inorganic particles (C1) having a Blaine specific surface area of 5,000 to 30,000 cm2/g and 5 to 35 parts by weight of inorganic particles (C2) having a Blaine specific surface area of 2,500 to 5,000 cm2/g.

Abstract: A cementitious slurry comprising fly ash having a predominant particle size of up to about 10 microns, and/or aluminous material having a predominant particle size of up to about 150 microns. The additive acts as a water reduction agent and can replace either wholly or partially a conventional plasticiser.

Abstract: In a hydraulic binder containing slags, aluminium-silicates and calcium sulphate, slag, in particular furnace slag, in amounts below 50% (w/w) as well as aluminium-silicates different from furnace slag, as for example flue-ash and natural aluminium-silicates, as for example basalt or andesite, in amounts of 5 to 75% (w/w) respectively related to the entire blend with the requirement that the stm of slag and aluminium-silicates is between 82 and 95.9% (w/w) and as one of the activators CaSO4 in amounts between 4 and 15% (w/w) as essential components are present. Additionally alkali activators, in particular alkali hydroxides and/or carbonates of Na and/or K in amounts from 0.1 to 3% (w/w) are deployed.

Abstract: In a method for the production of high-strength, acid-resistant concrete by use of water, hydraulic binder and aggregates, a hydraulic binder containing aluminosilicates, calciumsulfate and an activator containing salts of alkalimetals is applied wherein the aluminosilicates are chosen from the group consisting of furnace slag, clay, marl and industry-by-products like flue-ash with the requirement that the Al2O3-content of the binder is greater than 5% (w/w) and that furnace slag is present in an amount less than 35% (w/w) of the binder and that cement kiln dust in amounts from 1 to 20% (w/w) of the binder is applied as activator whereby the hydraulic activator is applied in amounts >400 kg per m3 concrete safeguarding a water/binder ratio from 0.25 to 0.40.

Abstract: The present invention provides settable compositions that comprise water and cement kiln dust. The settable compositions optionally may comprise an additive that comprises at least one of the following group: fly ash; shale; slag cement; zeolite; metakaolin; and combinations thereof. The settable compositions optionally may be foamed with a gas. Methods of cementing also are provided that comprise: providing the settable composition; introducing the settable composition into a location to be cemented; and allowing the settable composition to set therein. The location to be cemented may be above ground or in a subterranean formation.