Cellulose Or Silica Containing (e.g., Sand, Etc.) Patents (Class 106/726)
  • Patent number: 12176522
    Abstract: Embodiments of the present disclosure generally relate to carbon foams, processes for forming carbon foams, doped carbon composites, processes for forming doped carbon composites, and uses thereof, e.g., as electrodes. Processes described herein relate to fabrication of carbon foam and materials derived from the pyrolyzation of biomass at supercritical and subcritical conditions for CO2, N2, H2O, or combinations thereof. The process includes exposing biomass to CO2, N2, H2O, or combinations thereof under various parameters for temperature, pressure, heating rate and fluid flow rate. Silicon-carbon composites and sulfur-carbon composites for use as, e.g., electrodes, are also described.
    Type: Grant
    Filed: December 2, 2021
    Date of Patent: December 24, 2024
    Assignee: UNIVERSITY OF WYOMING
    Inventors: Erica Belmont, Kurt Stahlfeld
  • Patent number: 11981828
    Abstract: The present teaching provides a water repellant and oil repellant film composition comprising a siloxane compound represented by formula (1) or a cured product of the siloxane compound. (In formula (1), each R1 denotes at least one atom or group that is selected from the group consisting of a hydrogen atom, organic groups having 2 to 10 carbon atoms and a carbon-carbon unsaturated bond that is able to be hydrosilylated, and alkyl groups having 1 to 10 carbon atoms, each R2 denotes at least one atom or group that is selected from the group consisting of a hydrogen atom, organic groups having 2 to 10 carbon atoms and a carbon-carbon unsaturated bond that is able to be hydrosilylated, and alkyl groups having 1 to 10 carbon atoms (the R2 groups in a single molecule may be the same as, or different from, each other).
    Type: Grant
    Filed: June 4, 2019
    Date of Patent: May 14, 2024
    Assignee: TOAGOSEI CO. LTD.
    Inventors: Naomasa Furuta, Takeshi Fujita
  • Patent number: 11512022
    Abstract: A nanoporous carbon-loaded cement composite that conducts electricity. The nanoporous carbon-loaded cement composite can be used in a variety of different fields of use, including, for example, a structural super-capacitor as an energy solution for autonomous housing and other buildings, a heated cement for pavement deicing or house basement insulation against capillary rise, a protection of concrete against freeze-thaw (FT) or alkali silica reaction (ASR) or other crystallization degradation processes, and as a conductive cable, wire or concrete trace.
    Type: Grant
    Filed: December 7, 2020
    Date of Patent: November 29, 2022
    Assignees: MASSACHUSETTS INSTITUTE OF TECHNOLOGY, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITÉ DE BORDEAUX
    Inventors: Roland J. M. Pellenq, Aikaterini Ioannidou, Nicolas Chanut, Thibaut Divoux, Renal Backov, Franz-Josef Ulm
  • Patent number: 11479507
    Abstract: A cementitious blend composition and a concrete mix composition preferable for making concrete resistant to high temperatures and alkaline conditions, particularly for making durable concrete for constructing an alumina digester tank in an aluminum smelter. The cementitious blend composition includes at least one hydraulic cement, silica fume (SF), and natural pozzolan (NP), wherein a weight percent ratio of at least one hydraulic cement:SF:NP in the cementitious blend composition lies in the range of (24-63):(5-44):(32-40) with the sum of the weight percentages of the at least one hydraulic cement, the SF, and the NP not exceeding 100%. The concrete mix composition comprises water and the cementitious blend composition, wherein a weight ratio of the water to the cementitious blend composition is 0.2-0.5, and wherein the concrete mix composition has a content of the cementitious blend composition of 400-550 kg/m3.
    Type: Grant
    Filed: October 23, 2018
    Date of Patent: October 25, 2022
    Assignee: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
    Inventors: Mohammed Ibrahim, Mohammed Salihu Barry, Mohammed Maslehuddin
  • Patent number: 11447425
    Abstract: A method may include: defining engineering parameter of a proposed cement slurry, the engineering parameters comprising at least a compressive strength requirement, a density requirement, a storage time requirement, and a thickening time requirement; selecting, based at least in part on a model of compressive strength, a model of storage time, and the density requirement, at least a cement and mass fraction thereof, at least one supplementary cementitious material and mass fraction thereof, and a water and mass fraction thereof, such that a cement slurry formed from the cement, the at least one supplementary cementitious material, and the water meets the compressive strength requirement and the density requirement; selecting, based at least in part on a model of thickening time, an accelerator and mass fraction thereof; selecting, based at least in part on a model of activator thickening time, an activator and mass fraction thereof; and preparing a cement slurry comprising the cement and mass fraction thereof
    Type: Grant
    Filed: July 8, 2020
    Date of Patent: September 20, 2022
    Assignee: Halliburton Energy Services, Inc.
    Inventors: John Paul Bir Singh, Siva Rama Krishna Jandhyala, Thomas Jason Pisklak, Claudia Carmen Pineda
  • Patent number: 10626057
    Abstract: Disclosed is a method of spraying a surface with a set-delayed cement. The method comprises providing a set-delayed cement composition comprising water, pumice, hydrated lime, and a set retarder; spraying a surface with the set-delayed cement composition; and allowing the set-delayed cement composition to set on the surface.
    Type: Grant
    Filed: September 26, 2017
    Date of Patent: April 21, 2020
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Thomas Jason Pisklak, Kyriacos Agapiou, Ronnie Glen Morgan, Samuel Jason Lewis, Lance Everett Brothers
  • Patent number: 10161132
    Abstract: A cementitious composite and cured masonry block made from the cementitious composite. The cementitious composite contains a cement, a non-rubber aggregate, a crumb rubber and at least one of cement kiln dust and limestone powder. The crumb rubber aggregate is extracted from scrap tires after being processed and then mixed in specified percentages with the aggregate, the cement and water, then cured in forms to make the masonry blocks. In the present disclosure sand, which is used in conventional masonry blocks, is at least partially replaced with crumb rubber to produce a sand-free or sand-reduced masonry block that contains crumb rubber. The crumb rubber masonry blocks satisfy the ASTM non-load bearing requirements. The use of crumb rubber decreases the unit weight and increases thermal resistance of the masonry blocks. The use of cement kiln dust or limestone as a partial replacement of cement will lead to decrease in the cost.
    Type: Grant
    Filed: February 13, 2018
    Date of Patent: December 25, 2018
    Assignee: King Fahd University of Petroleum and Minerals
    Inventors: Mohammad Maslehuddin, Nasser M. Al-Aqeeli, Homoud M. Assehdi
  • Patent number: 9139476
    Abstract: Cement retarders for well cements are based on hydrophobins. Hydrophobins are proteins or polypeptides that form hydrophobic coatings on surfaces. The size of the hydrophobins is preferably between about 100 and 350 amino acids, and the preferred hydrophobin concentration is between about 0.001% and 1.0% by weight of cement. Portland cement is the preferred well cement. Cement slurries containing hydrophobins are useful for both primary and remedial cementing applications.
    Type: Grant
    Filed: November 3, 2010
    Date of Patent: September 22, 2015
    Assignee: Schlumberger Technology Corporation
    Inventors: Deepak Khatri, Cecilia Nguyen, Syed Ali
  • Patent number: 8946396
    Abstract: An agglomerated particulate lignosulfonate material may be made by introducing or forming lignosulfonate microparticles in a fluidized bed agglomerator, and introducing sufficient heated gas and lignosulfonate liquid in the agglomerator to convert the microparticles to lignosulfonate granules of enlarged size. The granules may have an average size of at least 0.1 mm, and may be used to make a dry-blended cement additive or oil well cement that may be dustless, easily poured and stored, and rapidly dissolved in water.
    Type: Grant
    Filed: August 28, 2012
    Date of Patent: February 3, 2015
    Assignee: Borregaard Industries Limited
    Inventor: Kåre Reknes
  • Patent number: 8652580
    Abstract: A manufacturing method of tiles includes the steps of: preparing mixed powder having a water content of 2 to 7% by mixing 30 to 80 parts by weight of calcium hydroxide powder or dolomite plaster powder, 20 to 70 parts by weight of porous aggregate, 0.1 to 5 parts by weight of a first photocatalyst and water; filling the mixed powder into a mold of a molding machine; forming a formed body by pressurizing the filled mixed powder; curing the formed body in a carbon dioxide atmosphere; and forming a thin layer made of a second photocatalyst on a surface of the formed body.
    Type: Grant
    Filed: January 28, 2010
    Date of Patent: February 18, 2014
    Assignee: Tagawasangyo Co., Ltd.
    Inventors: Nobuyoshi Yukihira, Tetsuro Oike, Katsuyuki Nakano
  • Patent number: 8648120
    Abstract: The present invention provides a liquid rheology modifier containing compounds (A) and (B) selected from combination (1) of compound (A) selected from cationic surfactants and compound (B) selected from anionic aromatic compounds and combination (2) of compound (A) from cationic surfactants and compound (B) selected from brominated compounds; and dicarboxylic acid (C).
    Type: Grant
    Filed: September 5, 2007
    Date of Patent: February 11, 2014
    Assignee: Kao Corporation
    Inventors: Koji Koyanagi, Hotaka Yamamuro, Toshiharu Kojima
  • Patent number: 8603239
    Abstract: This invention relates to a formulation with the addition of low density additives of volcanic ash, hollow ceramic microspheres or a combination of microspheres and volcanic ash or other low density additives into cementitious cellulose fiber reinforced building materials. This formulation is advantageously lightweight or low density compared as compared to current fiber cement products without the increased moisture expansion and freeze-thaw degradation usually associated with the addition of lightweight inorganic materials to fiber cement mixes. The low density additives also give the material improved thermal dimensional stability.
    Type: Grant
    Filed: April 25, 2012
    Date of Patent: December 10, 2013
    Assignee: James Hardie Technology Limited
    Inventors: James A. Gleeson, Kalynne H. Paradis, Brian P. Sloane, David L. Melmeth, Dean M. Seligman
  • Patent number: 8551240
    Abstract: A cement retarder system for use in underground wells included a borate compound, an organophosphonate salt, and a copolymer formed from AMPS and a monomer selected from the group consisting of acrylic acid, acrylamide and mixtures thereof.
    Type: Grant
    Filed: March 3, 2010
    Date of Patent: October 8, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Michel Michaux, Tatiana Pyatina
  • Patent number: 8550162
    Abstract: A retarder aid increases the applicable temperature range of phosphonate/borate cement-retarder systems to at least 302° C. (575° F.), and 207 MPa (30,000 psi). The retarder aid comprises a terpolymer of styrene sulfonate, maleic anhydride and acrylate of ethylene oxide. Cement slurries containing the retarder and retarder aid may be used for both primary-cementing and remedial-cementing applications.
    Type: Grant
    Filed: June 28, 2011
    Date of Patent: October 8, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Michel Michaux, Jean-Philippe Caritey
  • Patent number: 8377196
    Abstract: A dry cast cementitious composition including cement, water, and a rheology modifying additive (RMA) is provided. The inclusion of the RMA improves the dry cast cementitious composition's response to vibration and dampens out differences due to minor fluctuations in initial slump of the composition. The RMA may include a dispersant for the dry cast cementitious compositions. The dry cast cementitious composition may optionally include other admixtures or additives known in the industry. Methods for making the dry cast cementitious composition and dry cast cementitious articles from the composition are also provided.
    Type: Grant
    Filed: August 8, 2008
    Date of Patent: February 19, 2013
    Assignee: Construction Research & Technology GmbH
    Inventors: Jeffrey R. Bury, Lynn E. Brower
  • Patent number: 8349073
    Abstract: A cementitious composition the properties of which are useful for: a) reducing shrinkage cracking in stucco systems due to excess water present in initial mixing required to achieve adequate slump necessary for application, but not necessary for material hydration b) reducing full thickness cracking as a result of minor structural movement by increasing the flexural strength, c) reducing the time required to place the layers of a three-coat exterior stucco system. The composition of this material is a blend of ASTM C 150 Portland cement, an ASTM C 1328 Plastic (Stucco) cement and a minor amount of a sulfonated naphthalene formaldehyde condensate (SNF), also described as Polynaphthalene sulfonates (PNS) cement superplasticizer, also known as a HRWR (High Range Water Reducer).
    Type: Grant
    Filed: March 25, 2011
    Date of Patent: January 8, 2013
    Assignee: Texas Industries, Inc.
    Inventors: Stephen James Arment, Donald Nelson Gilbart
  • Patent number: 8333836
    Abstract: A fiber cement composite material that incorporates a blend of bleached and unbleached cellulose fibers as a partial or complete substitute for premium grade cellulose pulp is provided. Bleached standard grade cellulose fibers are used in conjunction with unbleached, standard grade cellulose fibers to provide a fiber cement composite product having substantially equal or even superior flexibility and strength as an equivalent fiber cement composite material reinforced by premium grade, unbleached cellulose fibers. A synergistic combination of bleached and unbleached standard grade cellulose fibers to produce a composite material with the desired properties previously achievable only through the use of premium grade cellulose pulp.
    Type: Grant
    Filed: April 7, 2011
    Date of Patent: December 18, 2012
    Assignee: James Hardie Technology Limited
    Inventors: Caidian Luo, Donald J. Merkley
  • Patent number: 8317916
    Abstract: A zinc-oxide based set retardant additive and admixture for use in Portland cement or other hydraulic cement mixtures. The admixture may comprise silica fume, vitreous calcium aluminosilicate, magnesium aluminum silicate hydrate, a cellulose ether derivative, or their equivalents. The zinc-oxide based set retardant may be interground or pre-blended, pre-packaged, or added on the jobsite, as an admixture, additive, or addition. The zinc-based set retardant may be subsequently added or mixed into a ready mix or wet mixture of portland cement or other hydraulic cement, sand and/or aggregate, with or without fillers, and water, with or without other pozzolans or polymers.
    Type: Grant
    Filed: September 9, 2010
    Date of Patent: November 27, 2012
    Assignee: Pebble Technology, Inc.
    Inventor: Jonathan E. Dongell
  • Patent number: 8277557
    Abstract: An agglomerated particulate lignosulfonate material may be made by introducing or forming lignosulfonate microparticles in a fluidized bed agglomerator, and introducing sufficient heated gas and lignosulfonate liquid in the agglomerator to convert the microparticles to lignosulfonate granules of enlarged size. The granules may have an average size of at least 0.1 mm, and may be used to make a dry-blended cement additive or oil well cement that may be dustless, easily poured and stored, and rapidly dissolved in water.
    Type: Grant
    Filed: August 7, 2009
    Date of Patent: October 2, 2012
    Assignee: Borregaard Industries Limited
    Inventor: Kåre Reknes
  • Patent number: 8182606
    Abstract: This invention relates to a formulation with the addition of low density additives of volcanic ash, hollow ceramic microspheres or a combination of microspheres and volcanic ash or other low density additives into cementitious cellulose fiber reinforced building materials. This formulation is advantageously lightweight or low density compared as compared to current fiber cement products without the increased moisture expansion and freeze-thaw degradation usually associated with the addition of lightweight inorganic materials to fiber cement mixes. The low density additives also give the material improved thermal dimensional stability.
    Type: Grant
    Filed: June 7, 2010
    Date of Patent: May 22, 2012
    Assignee: James Hardie Technology Limited
    Inventors: James A. Gleeson, Kalynne H. Paradis, Brian P. Sloane, David L. Melmeth, Dean M. Seligman
  • Patent number: 8167997
    Abstract: Flowable concrete mixtures have an aqueous foam admixture mixed therein to give the concrete mixture desired strength, flowability, and density. The concrete mixtures include a hydration stabilizer to stabilize the aqueous foam. The hydration stabilizer inhibits the reaction between the hydraulic cement and the water in the aqueous foam. The aqueous foam can be stabilized using a fluorochemical surfactant.
    Type: Grant
    Filed: February 5, 2010
    Date of Patent: May 1, 2012
    Assignee: Jack B. Parson Companies
    Inventor: Lonnie James Gray
  • Patent number: 8124569
    Abstract: The invention discloses a cement slurry composition for cementing a well comprising: an hydraulic cement, water and a combination made of a cellulosic polymer and an acrylamido-methyl-propane sulfonate co- or ter-polymer, wherein the density of said cement slurry is above 1700 kg/m3.
    Type: Grant
    Filed: July 9, 2009
    Date of Patent: February 28, 2012
    Assignee: Schlumberger Technology Corporation
    Inventors: Tariq Mehmood Khan, Bernard Piot, Siti Humairah Abd Rahman
  • Patent number: 8105500
    Abstract: A slurry rheology modifier comprises a first water-soluble low-molecular compound [referred to hereinafter as compound (A)] and a second water-soluble low-molecular compound [referred to hereinafter as compound (B)] being different from the compound (A), wherein the viscosity of an aqueous solution at 20° C. prepared by mixing an aqueous solution SA (with a viscosity at 20° C. of 100 mPa·s or less) of compound (A) with an aqueous solution SB (with a viscosity at 20° C. of 100 mPa·s or less) of compound (B) in the ratio of 50/50 by weight can be at least twice as high as the viscosity of either aqueous solution before mixed.
    Type: Grant
    Filed: April 30, 2008
    Date of Patent: January 31, 2012
    Assignee: Kao Corporation
    Inventors: Hotaka Yamamuro, Koji Koyanagi, Daisuke Shiba
  • Patent number: 8070875
    Abstract: The present invention relates to dispersants such as superplasticizers for hydratable cementitious compositions, and more particularly to methods for achieving variable degrees of longer slump life in concrete and mortar without loss of stability. This is achieved by using two admixture systems. The first admixture composition has multi-components for achieving initial-slump-enhancement, later-slump-retention, and limiting initial slump. The second admixture composition has the later-slump-enhancing component. Alternatively, conventional water reducers or superplasticizers can be employed initially, followed by the later-slump-enhancing admixture composition.
    Type: Grant
    Filed: October 12, 2006
    Date of Patent: December 6, 2011
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Ara A. Jeknavorian, Hideo Koyata, Darrick B. McGuire, Ivana Jovanovic
  • Patent number: 7985293
    Abstract: A hydraulic composition is provided. This composition exhibits an improved workability in its coating with a trowel, and accordingly, an improved working efficiency with no adverse effects on its physical properties. The hydraulic composition comprises at least one surfactant selected from anionic surfactants having foaming ability (group A), at least one surfactant selected from surfactants which are nonionic antifoaming agents (group B), and a water-soluble cellulose ether. The surfactants of group A and group B are respectively added at 0.000005 to 0.004% by weight (solid content) in relation to the powder ingredients in the hydraulic composition, and the water-soluble cellulose ether is added at 0.02 to 1.2% by weight of the hydraulic composition.
    Type: Grant
    Filed: July 31, 2007
    Date of Patent: July 26, 2011
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshiaki Sasage, Tsutomu Yamakawa
  • Patent number: 7972436
    Abstract: An exemplary surface active agent admixture composition of the invention comprises (1) a first surface active agent comprising a betaine, an alkyl or aryl or alkylaryl sulfonate, or mixture thereof; and (2) a second surface active agent comprising a nonionic oxyalkylene-containing polymer surfactant. The present invention therefore provides a system for ensuring the presence in a hydratable cementitious composition (when hardened) a sufficient air volume and sufficient air void fineness and consistency. Further exemplary admixture compositions may comprise one or more plasticizers and one or more clay activity-modifying agents. Cementitious compositions and methods for modifying cementitious compositions, which incorporate the above-mentioned surface active agent combination, are also described. The invention provides the ability to adjust and stabilize air void systems in hydratable cementitious compositions, while allowing conventional air entraining agent (AEA) dosage practices to be followed.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: July 5, 2011
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Chia-Chih Ou, Ara A. Jeknavorian, Christon L. Hill
  • Patent number: 7942964
    Abstract: A fiber cement composite material that incorporates a blend of bleached and unbleached cellulose fibers as a partial or complete substitute for premium grade cellulose pulp is provided. Bleached standard grade cellulose fibers are used in conjunction with unbleached, standard grade cellulose fibers to provide a fiber cement composite product having substantially equal or even superior flexibility and strength as an equivalent fiber cement composite material reinforced by premium grade, unbleached cellulose fibers. A synergistic combination of bleached and unbleached standard grade cellulose fibers to produce a composite material with the desired properties previously achievable only through the use of premium grade cellulose pulp.
    Type: Grant
    Filed: January 7, 2004
    Date of Patent: May 17, 2011
    Inventors: Caidian Luo, Donald J. Merkley
  • Patent number: 7901505
    Abstract: A method of producing cementitious mixtures containing fly ash as one of the cementitious components, under air entrainment conditions. The method involves forming a mixture comprising water, cement, fly ash, optionally other cementitious materials, aggregate, conventional chemical admixtures, and an air entrainment agent and agitating the mixture to entrain air therein. Additionally, at least one sacrificial agent is also included in the mixture. The sacrificial agent is a material or mixture of materials that is not required to act as an air entrainment agent but interacts preferentially with components of the fly ash that otherwise neutralize, repress or depress the activity of the air entrainment agent. The invention includes cementitious mixtures and hardened concretes resulting from the method and fly ash treated with sacrificial agent, or air entrainment agent/sacrificial agent combinations, and processes for selecting suitable sacrificial agents.
    Type: Grant
    Filed: February 2, 2009
    Date of Patent: March 8, 2011
    Assignee: Boral Material Technologies Inc.
    Inventors: Russell L. Hill, Carmel R. Jolicoeur, Monique Page, Ioan Spiratos, Thi Cong To
  • Patent number: 7892349
    Abstract: A method of producing cementitious mixtures containing fly ash as one of the cementitious components, under air entrainment conditions. The method involves forming a mixture comprising water, cement, fly ash, optionally other cementitious materials, aggregate, conventional chemical admixtures, and an air entrainment agent and agitating the mixture to entrain air therein. Additionally, at least one sacrificial agent is also included in the mixture. The sacrificial agent is a material or mixture of materials that is not required to act as an air entrainment agent but interacts preferentially with components of the fly ash that otherwise neutralize, repress or depress the activity of the air entrainment agent. The invention includes cementitious mixtures and hardened concretes resulting from the method and fly ash treated with sacrificial agent, or air entrainment agent/sacrificial agent combinations, and processes for selecting suitable sacrificial agents.
    Type: Grant
    Filed: February 2, 2009
    Date of Patent: February 22, 2011
    Assignee: Boral Material Technologies Inc.
    Inventors: Russell L. Hill, Carmel R. Jolicoeur, Monique Page, Ioan Spiratos, Thi Cong To
  • Patent number: 7892350
    Abstract: A method of producing cementitious mixtures containing fly ash as one of the cementitious components, under air entrainment conditions. The method involves forming a mixture comprising water, cement, fly ash, optionally other cementitious materials, aggregate, conventional chemical admixtures, and an air entrainment agent and agitating the mixture to entrain air therein. Additionally, at least one sacrificial agent is also included in the mixture. The sacrificial agent is a material or mixture of materials that is not required to act as an air entrainment agent but interacts preferentially with components of the fly ash that otherwise neutralize, repress or depress the activity of the air entrainment agent. The invention includes cementitious mixtures and hardened concretes resulting from the method and fly ash treated with sacrificial agent, or air entrainment agent/sacrificial agent combinations, and processes for selecting suitable sacrificial agents.
    Type: Grant
    Filed: February 2, 2009
    Date of Patent: February 22, 2011
    Assignee: Boral Material Technologies Inc.
    Inventors: Russell L. Hill, Carmel R. Jolicoeur, Monique Page, Ioan Spiratos, Thi Cong To
  • Patent number: 7892348
    Abstract: The present invention relates to a formulation of a high-performance foamed cement material, comprising: at least one hydraulic binder, microparticles whose grain size ranges between 0.1 and 30 ?m, whose proportion ranges between 15% and 50% by mass in relation to the mass of hydraulic binder, mineral particles whose grain size ranges between 1 and 500 ?m, whose proportion ranges between 10% and 35% by mass in relation to the mass of hydraulic binder, the proportion of particles being lower than the proportion of microparticles, a hydrosoluble polymer thinning agent whose proportion ranges between 0.1% and 8% by mass in relation to the mass of hydraulic binder, water whose proportion is at most 40% by mass in relation to the mass of hydraulic binder, a foaming agent whose proportion ranges between 0.1% and 10% by mass in relation to the mass of hydraulic binder.
    Type: Grant
    Filed: September 9, 2009
    Date of Patent: February 22, 2011
    Assignee: Institut Francais du Petrole
    Inventors: Eric Lecolier, Alain Rivereau
  • Patent number: 7862655
    Abstract: Of the many methods and compositions provided herein, one method comprises providing a cement composition, wherein the cement composition comprises a cementitious component and an additive comprising a polymer, a phosphorus component, a polyvalent metal ion, an oil-based liquid, and a surfactant; introducing the cement composition into at least a portion of the subterranean formation; and allowing the cement composition to at least partially set therein. Another method provided herein comprises providing a cement composition that comprises a cementitious component and an additive comprising a polymer, a phosphorus component, a polyvalent metal ion, an oil-based liquid, and a surfactant; introducing the cement composition into a void located in a pipe string; and allowing the cement composition to at least partially set therein.
    Type: Grant
    Filed: June 14, 2007
    Date of Patent: January 4, 2011
    Assignee: Halliburton Energy Services Inc.
    Inventors: Lance Brothers, Bobby J. King, Gary P. Funkhouser
  • Publication number: 20100294172
    Abstract: In this invention a cementitious capillary crystalline waterproof material with an eka-molecular sieve structure and its manufacturing method is disclosed. The major ingredient of this material is Portland cement; the accessories include silicon dioxide, alumina, magnesia, calcium sulphonate, methlycellulose, quick-setting agent and sodium aluminate, etc. Put separately major ingredient and accessories premixed in given proportion separately into the major ingredient bin and the accessory bins. The major ingredient passing through an impulse flowmeter is carried to the dosing machine; and in the same time, the premixed accessories are automatically weighed by the weighing device using gewichtsabnahme method when they are carried to the above dosing machine; they are mixed in the premixing machine and the refine-mixing machine and prepared to the product. The product is mixed with water and forms slurry.
    Type: Application
    Filed: June 2, 2008
    Publication date: November 25, 2010
    Inventor: Huidong Zhang
  • Patent number: 7799127
    Abstract: Rapid repair and retrofit of existing infrastructures demand durable high early strength materials that not only deliver sufficient strength within a few hours of placement but also significantly prolong the maintenance interval. The invention comprises a class of newly developed polyvinyl alcohol (PVA) fiber-reinforced high early strength engineered cementitious composites (ECC) materials featuring extraordinary ductility. The tailoring of preexisting flaw size distribution through non-matrix interactive crack initiators in the composite matrix results in high tensile ductility. The resulting high early strength ECC materials are capable of delivering a compressive strength of 21 MPa (3.0 ksi) within 4 hours after placement and retaining long-term tensile strain capacity above 2%.
    Type: Grant
    Filed: February 9, 2007
    Date of Patent: September 21, 2010
    Assignee: The Regents of the University of Michigan
    Inventors: Victor C. Li, Shuxin Wang
  • Patent number: 7790278
    Abstract: The present invention provides for twisted and rectangular dice forms of sheeted fibrous materials and a process for making the dice forms. Specifically, the invention teaches the use of dice forms and sheet materials in construction and cementitious materials.
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: September 7, 2010
    Assignee: Buckeye Technologies Inc.
    Inventors: Robert Irvin Bell, Jeffery Todd Cook, Judson Fidler, Gerald Hunt Morton, Howard Leon Schoggen
  • Patent number: 7727329
    Abstract: This invention relates to a formulation with the addition of low density additives of volcanic ash, hollow ceramic microspheres or a combination of microspheres and volcanic ash or other low density additives into cementitious cellulose fiber reinforced building materials. This formulation is advantageously lightweight or low density compared as compared to current fiber cement products without the increased moisture expansion and freeze-thaw degradation usually associated with the addition of lightweight inorganic materials to fiber cement mixes. The low density additives also give the material improved thermal dimensional stability.
    Type: Grant
    Filed: February 28, 2008
    Date of Patent: June 1, 2010
    Assignee: James Hardie Technology Limited
    Inventors: James A. Gleeson, Kalynne H. Paradis, Brian P. Sloane, David L. Melmeth, Dean M. Seligman
  • Patent number: 7695559
    Abstract: A cement suspension includes the following, in relation to the cement material: water (22-35% by weight); acetic acid (1-10% by weight); plasticizer (up to 8% by weight); and dispersant agent (0-2% by weight), having an apparent viscosity of 0.5-2 Pa·s for the casting speed gradient. Pieces of cement that are prepared from the suspension and which can be used as electronic components are also disclosed.
    Type: Grant
    Filed: April 28, 2005
    Date of Patent: April 13, 2010
    Assignees: Centre National de la Recherche Scientifique (C.N.R.S.), Ecole Nationale Superieure de Ceramique Industrielle (ENSCI)
    Inventors: Thierry Chartier, Youssef El Hafiane, Agnes Smith, Jean-Pierre Bonnet
  • Patent number: 7674331
    Abstract: The use of silicate as a retarder enhancer at appropriate levels to enhance the retarding effect of retarders at high temperatures encountered downhole while accelerating the set of cement at lower temperatures encountered near to the surface.
    Type: Grant
    Filed: August 25, 2004
    Date of Patent: March 9, 2010
    Assignee: Schlumberger Technology Corporation
    Inventors: Bruno Drochon, Sylwia Komocki, Michel Michaux
  • Patent number: 7674332
    Abstract: An embodiment of the present invention includes a method of cementing in a subterranean formation comprising: providing an extended settable composition comprising hydraulic cement, cement kiln dust, water, and a set retarding additive, wherein the extended settable composition is capable of remaining in a pumpable fluid state for at least about 1 day; adding a cement set accelerator to the extended settable composition; introducing the extended settable composition into a well bore; and allowing the extended settable composition to set. Another embodiment of the present invention includes a method of cementing in a subterranean formation comprising: providing an extended settable composition comprising hydraulic cement, cement kiln dust, water, and a set retarding additive; storing the extended settable composition; adding a cement set accelerator to the extended settable composition; introducing the extended settable composition into a well bore; and allowing the extended settable composition to set.
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: March 9, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Craig W. Roddy, Jilen Chatterji, Bobby J. King, D. Chad Brenneis
  • Patent number: 7670426
    Abstract: Flowable concrete mixtures have an aqueous foam admixture mixed therein to give the concrete mixture desired strength, flowability, and density. The concrete mixtures include a hydration stabilizer to stabilize the aqueous foam. The hydration stabilizer inhibits the reaction between the hydraulic cement and the water in the aqueous foam. The aqueous foam can be further stabilized using a fluorochemical surfactant. Preferred fluorochemical surfactants comprise an oligomer having at least one hydrophilic nonionic monomer and at least one hydrophilic anionic monomer.
    Type: Grant
    Filed: December 19, 2005
    Date of Patent: March 2, 2010
    Assignee: Jack B. Parson Companies
    Inventor: Lonnie James Gray
  • Patent number: 7666334
    Abstract: A method is provided for use of a concrete composition and an associated apparatus. The method provides for mixing of the concrete material, accelerant powder and, optionally, an associated substance to enable the controlled hardening of the concrete material in a monolithic structure. The apparatus can dispose a slip-plane film to facilitate a relatively continuous process.
    Type: Grant
    Filed: August 5, 2005
    Date of Patent: February 23, 2010
    Assignee: Specialty Minerals (Michigan) Inc.
    Inventors: Dominick Michael Colavito, Joseph Michael Schmidt, Michael Joseph Buscarini, James Charles Peter Rosso, Ronald Warren Schmidt, Richard Charles Griffin, Fritz Henry
  • Publication number: 20090301354
    Abstract: A method of compressing a composition includes compacting a hydraulic binder in a quantity greater than 95% by weight and a disintegrating agent in a quantity less than or equal to 0.5% by weight, into compacts in a roller press. The milled pellet of a composition including a hydraulic binder in a quantity greater than 95% by weight and a disintegrating agent in a quantity less than or equal to 0.5% by weight.
    Type: Application
    Filed: April 14, 2006
    Publication date: December 10, 2009
    Inventors: Jean-Michel Faure, Corinne Fonquerne, Emmanuel Garcia
  • Patent number: 7621995
    Abstract: A viscosity modifying agent is added to a concrete mixture to give the concrete desirable rheological properties. The viscosity modifying agent is incorporated into a foam admixture before it is mixed into the concrete. Because the viscosity modifying agent is a component of the foam admixture, the viscosity modifying agent is dispersed in the aqueous film that forms the foam bubbles. The viscosity modifier in the foam bubbles gives the foam beneficial rheological properties. The viscosity modifier performs more efficiently when included in the foam bubbles as compared to being mixed directly into the concrete. The foam bubbles containing the viscosity modifier can be stabilized using a fluorochemical stabilizer, which is included in the foam admixture. The foam bubbles can be further stabilized with respect to cement mixtures by including a hydration stabilizing in the cement mixture.
    Type: Grant
    Filed: December 19, 2005
    Date of Patent: November 24, 2009
    Assignee: Jack B. Parson Companies
    Inventor: Lonnie James Gray
  • Patent number: 7569108
    Abstract: The prevention of latex inversion in saltwater cement compositions for use in subterranean formations by inclusion of a combination of latex stabilizers and associated methods of cementing. Saltwater cement compositions comprising saltwater, a cement, a latex, a first latex stabilizer comprising a surfactant having the formula: R—O—(OCH2CH2)mXM wherein R is an alkyl group having in the range of from about 10 carbons to about 20 carbons, m is an integer in the range of from about 10 to about 40, X is OSO3 or SO3, and M is a compatible cation, and a second latex stabilizer comprising an alcohol ether sulfate having the formula: R1—O—(OCH2CH2)nOSO3M wherein R1 is an alkyl group having in the range of from about 4 carbons to about 12 carbons, n is an integer in the range of from about 1 to about 10, and M is a compatible cation.
    Type: Grant
    Filed: September 28, 2006
    Date of Patent: August 4, 2009
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jiten Chatterji, Bobby J. King, D. Chad Brenneis, Roger S. Cromwell
  • Patent number: 7497904
    Abstract: A cementitious composition is provided that is composed of hydraulic cement and a liquid coloring suspension. The liquid coloring suspension which contains polycarboxylate dispersant and pigment provides the cementitious composition with increased dispersion of pigment particles, lowered water content, and improved coloration over that observed in the prior art. Also, a liquid coloring suspension for cementitious compositions is provided which contains polycarboxylate dispersant, pigment, and thixotropic additive. The liquid coloring suspension increases the color of cementitious compositions, reduces the water content and has long term stability in that it does not become increasingly viscous over time.
    Type: Grant
    Filed: March 26, 2004
    Date of Patent: March 3, 2009
    Assignees: Construction Research & Technology GmbH, L.M. Scofield Company
    Inventors: Nancy A. Dulzer, Jeffrey L. Matrician, Martin E. Wild
  • Patent number: 7485184
    Abstract: A method of producing cementitious mixtures containing fly ash as one of the cementitious components, under air entrainment conditions. The method involves forming a mixture comprising water, cement, fly ash, optionally other cementitious materials, aggregate, conventional chemical admixtures, and an air entrainment agent and agitating the mixture to entrain air therein. Additionally, at least one sacrificial agent is also included in the mixture. The sacrificial agent is a material or mixture of materials that is not required to act as an air entrainment agent but interacts preferentially with components of the fly ash that otherwise neutralize, repress or depress the activity of the air entrainment agent. The invention includes cementitious mixtures and hardened concretes resulting from the method and fly ash treated with sacrificial agent, or air entrainment agent/sacrificial agent combinations, and processes for selecting suitable sacrificial agents.
    Type: Grant
    Filed: January 22, 2004
    Date of Patent: February 3, 2009
    Assignee: Handy Chemicals Ltd.
    Inventors: Russell Hill, Carmel R. Jolicoeur, Monique Page, Ioan Spiratos, Thi Cong To
  • Patent number: 7449062
    Abstract: A method of cementing a wellbore comprising preparing a cement composition comprising a water-soluble aromatic sulfonated polymer, and placing the cement composition into the wellbore, wherein the cement composition develops a compressive strength of greater than about zero in less time than a similar cement composition having a comparable thickening time and lacking a water-soluble aromatic sulfonated polymer. A cement composition comprising a water-soluble aromatic sulfonated polymer, wherein the cement composition develops a compressive strength of greater than about zero in less time than a similar cement composition having comparable thickening time and lacking a water-soluble aromatic sulfonated polymer.
    Type: Grant
    Filed: November 29, 2007
    Date of Patent: November 11, 2008
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Ashok K Santra, Mfon Antia, B. Raghava Reddy
  • Patent number: 7445670
    Abstract: A method is provided for reducing the density of a well cement composition for cementing in a subterranean formation. The method comprises providing a cement composition that comprises water and a cement, and then adding an additive comprising an anionic foam stabilizer and an anionic foaming agent or a Zwitterionic foam booster. A gas is added to this mixture to reduce the density. Further, foamed cement compositions and additives for foaming and stabilizing a well cement composition are provided.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: November 4, 2008
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Samuel J. Lewis, Michael J. Szymanski, Kristi D. Thacker
  • Patent number: 7442249
    Abstract: Cement compositions containing low reactivity materials are disclosed. The compositions are useful in conditions involving high temperatures, high pressures, and tectonic forces such as oil and gas wells. The cement compositions display increased compressive strength, flexural strength, and tensile strength. Fractures appear to occur in a non-linear fashion between the Interfacial Transition Zone (ITZ) of the particles, rather than in a straight line such as those observed in conventional cement materials.
    Type: Grant
    Filed: November 13, 2006
    Date of Patent: October 28, 2008
    Assignee: BJ Services Company
    Inventor: T. Dan Mueller
  • Patent number: 7438758
    Abstract: A method of servicing a wellbore that penetrates a subterranean formation includes displacing a cement composition comprising an aromatic sulfonated polymer into the wellbore and allowing the cement composition to set. In an embodiment, a transition time of the cement composition is less than or equal to about 60 minutes, alternatively less than or equal to about 50 minutes, less than or equal to about 40 minutes, less than or equal to about 30 minutes, less than or equal to about 20 minutes, or less than or equal to about 10 minutes. Thus, the transition time may be short enough to inhibit a substantial amount of gas migration into the cement composition before it sets. In yet another embodiment, the cement composition exhibits a viscosity that increases from a value of 35 Bc (Bearden units) to about 100 Bc in about 10 minutes or less when the cement composition sets.
    Type: Grant
    Filed: July 19, 2007
    Date of Patent: October 21, 2008
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Ashok K. Santra, B. Raghava Reddy, Russell M. Fitzgerald