Organic Nitrogen Compound Patents (Class 106/727)
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Control of the properties of cement slurries of normal densities with optimized polymers combination
Patent number: 8124569Abstract: The invention discloses a cement slurry composition for cementing a well comprising: an hydraulic cement, water and a combination made of a cellulosic polymer and an acrylamido-methyl-propane sulfonate co- or ter-polymer, wherein the density of said cement slurry is above 1700 kg/m3.Type: GrantFiled: July 9, 2009Date of Patent: February 28, 2012Assignee: Schlumberger Technology CorporationInventors: Tariq Mehmood Khan, Bernard Piot, Siti Humairah Abd Rahman -
Patent number: 8118930Abstract: An accelerating admixture for concrete, containing a liquid mixture being an aqueous solution or an aqueous dispersion, wherein a) the liquid mixture contains 13 to 43 weight % dissolved aluminium sulfate, b) the liquid mixture contains less than 1 weight % dissolved carboxylic acid, c) the liquid mixture contains at least 31 weight % water, d) the molar ratio of dissolved aluminium to dissolved sulfate in the liquid mixture is from 0.5 to 10.0.Type: GrantFiled: June 16, 2005Date of Patent: February 21, 2012Assignee: Construction Research & Technology GmbHInventor: Terje Angelskar
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Patent number: 8105500Abstract: A slurry rheology modifier comprises a first water-soluble low-molecular compound [referred to hereinafter as compound (A)] and a second water-soluble low-molecular compound [referred to hereinafter as compound (B)] being different from the compound (A), wherein the viscosity of an aqueous solution at 20° C. prepared by mixing an aqueous solution SA (with a viscosity at 20° C. of 100 mPa·s or less) of compound (A) with an aqueous solution SB (with a viscosity at 20° C. of 100 mPa·s or less) of compound (B) in the ratio of 50/50 by weight can be at least twice as high as the viscosity of either aqueous solution before mixed.Type: GrantFiled: April 30, 2008Date of Patent: January 31, 2012Assignee: Kao CorporationInventors: Hotaka Yamamuro, Koji Koyanagi, Daisuke Shiba
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Patent number: 8070875Abstract: The present invention relates to dispersants such as superplasticizers for hydratable cementitious compositions, and more particularly to methods for achieving variable degrees of longer slump life in concrete and mortar without loss of stability. This is achieved by using two admixture systems. The first admixture composition has multi-components for achieving initial-slump-enhancement, later-slump-retention, and limiting initial slump. The second admixture composition has the later-slump-enhancing component. Alternatively, conventional water reducers or superplasticizers can be employed initially, followed by the later-slump-enhancing admixture composition.Type: GrantFiled: October 12, 2006Date of Patent: December 6, 2011Assignee: W.R. Grace & Co.-Conn.Inventors: Ara A. Jeknavorian, Hideo Koyata, Darrick B. McGuire, Ivana Jovanovic
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Patent number: 8007584Abstract: A composition for use in construction that is substantially free of volatile organic compounds (VOC) that when applied to a surface produces a smooth or textured, water-shedding (hydrophobic properties), aesthetically-pleasing, protective continuous coating. The coated surface as well as the method of preparing and applying the composition is also provided.Type: GrantFiled: August 8, 2008Date of Patent: August 30, 2011Assignee: Formulated Solutions, LLCInventors: John Garuti, Jr., Louis M. Calvo
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Patent number: 8002889Abstract: The use of silicate as a retarder enhancer at appropriate levels to enhance the retarding effect of retarders at high temperatures encountered downhole while accelerating the set of cement at lower temperatures encountered near to the surface.Type: GrantFiled: December 7, 2009Date of Patent: August 23, 2011Assignee: Schlumberger Technology CorporationInventors: Bruno Drochon, Sylwia Komocki, Michel Michaux
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Publication number: 20110197790Abstract: A modified sulfur binder capable of implementing a physical property of being re-melted at a temperature less than 100° C., by mixing sulfur with a heterocyclicamine or alkylamine-based modifier and a dicyclopentadiene-based modifier, and a fabrication method thereof. A hydraulic modified sulfur material composition capable of being mixed with water by adding a surfactant to the modified sulfur binder, and obtained by mixing aggregate and a hydraulic material to the modified sulfur binder, and a fabrication method thereof. A hydraulic modified sulfur material obtained by molding the hydraulic modified sulfur material composition, and a fabrication method thereof. A combustible modified sulfur material composition obtained by adding aggregate to the modified sulfur binder, and by selectively adding a filler to the modified sulfur binder, and a fabrication method thereof.Type: ApplicationFiled: October 15, 2008Publication date: August 18, 2011Inventor: Mun-Son Choe
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Publication number: 20110179976Abstract: The invention relates to a process for dedusting a pulverulent building material composition, preferably a factory dry mortar and in particular tile adhesive, joint filler, filling compound, sealing slurry, repair mortar, levelling mortar, reinforcing adhesive, adhesive for composite thermal insulation systems (CTIS), mineral render, fine filler and screed systems, at least one dedusting agent which is liquid at 20° C. being brought into contact with the pulverulent building material composition at a temperature of >40° C. Preferably this occurs by spraying.Type: ApplicationFiled: May 28, 2009Publication date: July 28, 2011Inventors: Manfred Huber, Klaus-Dieter Hoetzl
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Patent number: 7985293Abstract: A hydraulic composition is provided. This composition exhibits an improved workability in its coating with a trowel, and accordingly, an improved working efficiency with no adverse effects on its physical properties. The hydraulic composition comprises at least one surfactant selected from anionic surfactants having foaming ability (group A), at least one surfactant selected from surfactants which are nonionic antifoaming agents (group B), and a water-soluble cellulose ether. The surfactants of group A and group B are respectively added at 0.000005 to 0.004% by weight (solid content) in relation to the powder ingredients in the hydraulic composition, and the water-soluble cellulose ether is added at 0.02 to 1.2% by weight of the hydraulic composition.Type: GrantFiled: July 31, 2007Date of Patent: July 26, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshiaki Sasage, Tsutomu Yamakawa
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Patent number: 7972435Abstract: A strength improvement admixture composition is provided that increases the compressive strength of cementitious compositions without negatively increasing the setting time. The admixture comprises the components of a polycarboxylate dispersant and strength improvement additive.Type: GrantFiled: June 2, 2009Date of Patent: July 5, 2011Assignee: Construction Research & Technology GmbHInventors: Jeffrey R Bury, Thomas M Vickers, Jr., Bruce J Christensen
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Patent number: 7947127Abstract: A cement retarder system for use in underground wells included a borate compound, an organophosphonate salt, and a copolymer formed from AMPS and a monomer selected from the group consisting of acrylic acid, acrylamide and mixtures thereof.Type: GrantFiled: March 15, 2010Date of Patent: May 24, 2011Assignee: Schlumberger Technology CorporationInventors: Michel Michaux, Tatiana Pyatina
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Patent number: 7931747Abstract: The present invention relates to cement-containing compositions which are characterized in that they have a proportion of organosilicon compounds of greater than 0.15% by weight, based on the proportion of cement, the organosilicon compounds being based on at least one organosilicon compound selected from the group consisting of the alkoxysilanes and at least one selected from the group consisting of the alkoxysiloxanes, to a process for the preparation thereof and to the use thereof.Type: GrantFiled: December 18, 2009Date of Patent: April 26, 2011Assignee: Evonik Goldschmidt GmbHInventors: Bernd Weyershausen, Stefan Stadtmueller, Markus Roos, Frank Koenig
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Patent number: 7931742Abstract: A biocidal structural barrier of a raw concrete or a structure made of concrete is provided containing a specific insecticidal biocide product and/or a repellent that has been incorporated throughout the mass. The invention is particularly suitable for the building and construction sector and more particularly for concrete structures located close to the soil or in the soil (slab, foundations, buried walls, prefabricated concrete blocks, etc.). The preferred insecticide for protection against termites is chlorfenapyr.Type: GrantFiled: November 2, 2006Date of Patent: April 26, 2011Assignees: BASF SE, Sep InnovatermInventors: Daniel Sanz, Eric Cazeneuve
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Patent number: 7927418Abstract: Methods and compositions involving the use of nitrogen-containing coordinated metal compounds for stabilizing chromium VI reducing metal cations. Exemplary uses include processes for making cement, and exemplary compositions include cement additives, concrete admixtures, as well as hydratable cement and cementitous compositions.Type: GrantFiled: August 9, 2007Date of Patent: April 19, 2011Assignee: W. R. Grace & Co.-Conn.Inventors: Neal S. Berke, Leslie A. Jardine, Vijay Gupta, Charles R. Cornman, Antonio J. Aldykiewicz, Jr., Urszula B Latosiewicz, Felek Jachimowicz, Durga Subramanian
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Patent number: 7901505Abstract: A method of producing cementitious mixtures containing fly ash as one of the cementitious components, under air entrainment conditions. The method involves forming a mixture comprising water, cement, fly ash, optionally other cementitious materials, aggregate, conventional chemical admixtures, and an air entrainment agent and agitating the mixture to entrain air therein. Additionally, at least one sacrificial agent is also included in the mixture. The sacrificial agent is a material or mixture of materials that is not required to act as an air entrainment agent but interacts preferentially with components of the fly ash that otherwise neutralize, repress or depress the activity of the air entrainment agent. The invention includes cementitious mixtures and hardened concretes resulting from the method and fly ash treated with sacrificial agent, or air entrainment agent/sacrificial agent combinations, and processes for selecting suitable sacrificial agents.Type: GrantFiled: February 2, 2009Date of Patent: March 8, 2011Assignee: Boral Material Technologies Inc.Inventors: Russell L. Hill, Carmel R. Jolicoeur, Monique Page, Ioan Spiratos, Thi Cong To
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Patent number: 7892349Abstract: A method of producing cementitious mixtures containing fly ash as one of the cementitious components, under air entrainment conditions. The method involves forming a mixture comprising water, cement, fly ash, optionally other cementitious materials, aggregate, conventional chemical admixtures, and an air entrainment agent and agitating the mixture to entrain air therein. Additionally, at least one sacrificial agent is also included in the mixture. The sacrificial agent is a material or mixture of materials that is not required to act as an air entrainment agent but interacts preferentially with components of the fly ash that otherwise neutralize, repress or depress the activity of the air entrainment agent. The invention includes cementitious mixtures and hardened concretes resulting from the method and fly ash treated with sacrificial agent, or air entrainment agent/sacrificial agent combinations, and processes for selecting suitable sacrificial agents.Type: GrantFiled: February 2, 2009Date of Patent: February 22, 2011Assignee: Boral Material Technologies Inc.Inventors: Russell L. Hill, Carmel R. Jolicoeur, Monique Page, Ioan Spiratos, Thi Cong To
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Patent number: 7892350Abstract: A method of producing cementitious mixtures containing fly ash as one of the cementitious components, under air entrainment conditions. The method involves forming a mixture comprising water, cement, fly ash, optionally other cementitious materials, aggregate, conventional chemical admixtures, and an air entrainment agent and agitating the mixture to entrain air therein. Additionally, at least one sacrificial agent is also included in the mixture. The sacrificial agent is a material or mixture of materials that is not required to act as an air entrainment agent but interacts preferentially with components of the fly ash that otherwise neutralize, repress or depress the activity of the air entrainment agent. The invention includes cementitious mixtures and hardened concretes resulting from the method and fly ash treated with sacrificial agent, or air entrainment agent/sacrificial agent combinations, and processes for selecting suitable sacrificial agents.Type: GrantFiled: February 2, 2009Date of Patent: February 22, 2011Assignee: Boral Material Technologies Inc.Inventors: Russell L. Hill, Carmel R. Jolicoeur, Monique Page, Ioan Spiratos, Thi Cong To
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Patent number: 7883577Abstract: An admixture formulation of at least one polycarboxylate dispersant and at least one naphthalene dispersant is provided. When the polycarboxylate dispersant and the naphthalene dispersant of the admixture formulation are combined at various ratios the admixture formulation reduces the tendency for bleed and segregation in cementitious mixtures without increasing water demand, retarding setting, increasing water sensitivity, promoting high viscosity, or reducing flow retention.Type: GrantFiled: April 7, 2010Date of Patent: February 8, 2011Assignee: Construction Research and Technology GmbHInventors: Sandra R. Sprouts, Frederick R. Goodwin, Alessandro Dal Bo
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Subterranean cementing methods and compositions comprising oil suspensions of water soluble polymers
Patent number: 7862655Abstract: Of the many methods and compositions provided herein, one method comprises providing a cement composition, wherein the cement composition comprises a cementitious component and an additive comprising a polymer, a phosphorus component, a polyvalent metal ion, an oil-based liquid, and a surfactant; introducing the cement composition into at least a portion of the subterranean formation; and allowing the cement composition to at least partially set therein. Another method provided herein comprises providing a cement composition that comprises a cementitious component and an additive comprising a polymer, a phosphorus component, a polyvalent metal ion, an oil-based liquid, and a surfactant; introducing the cement composition into a void located in a pipe string; and allowing the cement composition to at least partially set therein.Type: GrantFiled: June 14, 2007Date of Patent: January 4, 2011Assignee: Halliburton Energy Services Inc.Inventors: Lance Brothers, Bobby J. King, Gary P. Funkhouser -
Patent number: 7854803Abstract: Boroncitrates provide a new and improved means for hydraulic cement compositions to take set faster or slower, as determined by the user and as the individual jobsite needs dictate; thereby providing the flexibility required in the concrete industry. Boroncitrates include boron lithium citrate, boron potassium citrate, and boron sodium citrate which may be used alone or in mixtures thereof. They can be used in but not limited to Portland cement, Class C Fly Ash, blended hydraulic cements, and mixtures thereof.Type: GrantFiled: January 11, 2006Date of Patent: December 21, 2010Inventors: William D. Kirkpatrick, Carole W. Kirkpatrick
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Patent number: 7846251Abstract: An exemplary composition for enhancing water repellency in cementitious material comprises a hydrophobic material solute that is dissolved in a glycol ether solvent. Thus, the composition is provided in the form of a non-aqueous solution or emulsion wherein water is in a noncontinuous phase. The use of such compositions to modify cementitious compositions and the cementitious materials obtained thereby are also described.Type: GrantFiled: September 28, 2005Date of Patent: December 7, 2010Assignee: W. R. Grace & Co.-Conn.Inventors: Antonio J. Aldykiewicz, Jr., Arnon Bentur, Neal S. Berke, Chia-Chih Ou
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Patent number: 7838597Abstract: A fluid loss additive for hydraulic cement, comprising a polyvinyl alcohol resin and a fluid loss ameliorating sulfonic acid-functionalized co-resin, where the polyvinyl alcohol has a characteristic viscosity in the range of about 1 to about 25 cps. The invention includes, in some embodiments, an aqueous concentrate of the PVOH resin and the sulfonic acid-functionalized co-resin, where the total resin content is in the range of about 10% to about 40% and the viscosity is less than 15,000 cps. By way of the invention it is possible to adjust hydraulic cement slurry characteristics in real time upon demand and reduce inventory by providing a concentrated aqueous fluid loss additive.Type: GrantFiled: August 2, 2005Date of Patent: November 23, 2010Assignee: Sekisui Specialty Chemicals America, LLCInventors: Michael E. George, Kristi J. Beckman, Freddie Lyn Sabins, Cory J. Sikora
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Patent number: 7799127Abstract: Rapid repair and retrofit of existing infrastructures demand durable high early strength materials that not only deliver sufficient strength within a few hours of placement but also significantly prolong the maintenance interval. The invention comprises a class of newly developed polyvinyl alcohol (PVA) fiber-reinforced high early strength engineered cementitious composites (ECC) materials featuring extraordinary ductility. The tailoring of preexisting flaw size distribution through non-matrix interactive crack initiators in the composite matrix results in high tensile ductility. The resulting high early strength ECC materials are capable of delivering a compressive strength of 21 MPa (3.0 ksi) within 4 hours after placement and retaining long-term tensile strain capacity above 2%.Type: GrantFiled: February 9, 2007Date of Patent: September 21, 2010Assignee: The Regents of the University of MichiganInventors: Victor C. Li, Shuxin Wang
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Publication number: 20100162925Abstract: Methods and compositions involving the use of nitrogen-containing coordinated metal compounds for stabilizing chromium VI reducing metal cations. Exemplary uses include processes for making cement, and exemplary compositions include cement additives, concrete admixtures, as well as hydratable cement and cementitous compositions.Type: ApplicationFiled: August 9, 2007Publication date: July 1, 2010Inventors: Neal S. Berke, Leslie A. Jardine, Vijay Gupta, Charles R. Cornman, Antonio J. Aldykiewicz, Urszula B. Latosiewicz, Felek Jachimowicz, Durga Subramanian
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Patent number: 7744692Abstract: A lightweight cementitious composition containing from 10 to 90 volume percent of a cement composition, from 10 to 90 volume percent of particles having an average particle diameter of from 0.2 mm to 8 mm, a bulk density of from 0.03 g/cc to 0.64 g/cc, an aspect ratio of from 1 to 3, and from 10 to 50 volume percent of sand and/or other fine aggregate, where at least a portion of the sand and/or fine aggregate has a fineness modulus of less than 2; where the sum of components used does not exceed 100 volume percent, and where after the lightweight cementitious composition is set it has a compressive strength of at least 1700 psi as tested according to ASTM C39 after seven days. The cementitious composition can be used to make concrete masonry units, construction panels, road beds and other articles.Type: GrantFiled: March 22, 2006Date of Patent: June 29, 2010Assignees: Nova Chemicals, Inc., Metromont CorporationInventors: Tricia Guevara, Michael T. Williams, David A. Cowan, John K. Madish, Kolapo Adewale, Roger Moore, Mary M. Moore, legal representative, Blain Hileman, Richard H. Pennell, Jr.
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Patent number: 7699931Abstract: A setting and curing accelerator for hydraulic binders comprises: Al2(SO4)3 aluminum sulfate, Al(OH)3 aluminum hydroxide and mineral acid in aqueous solution. The setting and curing accelerator preferably comprises: 10-50% of Al2(SO4)3 aluminum sulfate, 5-30% of Al(OH)3 aluminum hydroxide, 0.5-10% of a mineral acid in aqueous solution.Type: GrantFiled: December 26, 2007Date of Patent: April 20, 2010Assignee: Sika Technology AGInventors: Marcel Sommer, Urs Mader, Franz Wombacher, Benedikt Lindlar
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Patent number: 7699929Abstract: A lightweight concrete composition containing from 10 to 90 volume percent of a cement composition, from 10 to 90 volume percent of particles having an average particle diameter of from 0.2 mm to 8 mm, a bulk density of from 0.03 g/cc to 0.64 g/cc, an aspect ratio of from 1 to 3, and from 0 to 50 volume percent of aggregate; where the sum of components used does not exceed 100 volume percent, and where after the lightweight concrete composition is set it has a compressive strength of at least 1700 psi as tested according to ASTM C39 after seven days. The concrete composition can be used to make concrete masonry units, construction panels, road beds and other articles.Type: GrantFiled: August 13, 2008Date of Patent: April 20, 2010Assignee: NOVA Chemicals Inc.Inventors: Tricia Guevara, Michael T. Williams, David A. Cowan, John K. Madish, Kolapo Adewale, Roger Moore, Mary Margaret Moore, legal representative, Tobias Blain Hileman
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Patent number: 7695559Abstract: A cement suspension includes the following, in relation to the cement material: water (22-35% by weight); acetic acid (1-10% by weight); plasticizer (up to 8% by weight); and dispersant agent (0-2% by weight), having an apparent viscosity of 0.5-2 Pa·s for the casting speed gradient. Pieces of cement that are prepared from the suspension and which can be used as electronic components are also disclosed.Type: GrantFiled: April 28, 2005Date of Patent: April 13, 2010Assignees: Centre National de la Recherche Scientifique (C.N.R.S.), Ecole Nationale Superieure de Ceramique Industrielle (ENSCI)Inventors: Thierry Chartier, Youssef El Hafiane, Agnes Smith, Jean-Pierre Bonnet
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Patent number: 7686884Abstract: Disclosed is a hydraulically setting composition containing phosphorus-oxygen acid esters or ester salts which comprise alkoxy groups. Also disclosed is a surface-modifying agent for structural steel, which contains or consists of phosphorus-oxygen acid esters or ester salts comprising alkoxy groups. The hydraulically setting composition and the surface-modifying agent are suitable for protecting reinforced concrete.Type: GrantFiled: May 4, 2004Date of Patent: March 30, 2010Assignee: Sika Technology AGInventors: Franz Wombacher, Beat Marazzani, Urs Mäder
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Patent number: 7678190Abstract: A cement retarder system for use in underground wells included a borate compound, an organophosphonate salt, and a copolymer formed from AMPS and a monomer selected from the group consisting of acrylic acid, acrylamide and mixtures thereof.Type: GrantFiled: March 26, 2007Date of Patent: March 16, 2010Assignee: Schlumberger Technology CorporationInventors: Michel Michaux, Tatiana Pyatina
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Patent number: 7674331Abstract: The use of silicate as a retarder enhancer at appropriate levels to enhance the retarding effect of retarders at high temperatures encountered downhole while accelerating the set of cement at lower temperatures encountered near to the surface.Type: GrantFiled: August 25, 2004Date of Patent: March 9, 2010Assignee: Schlumberger Technology CorporationInventors: Bruno Drochon, Sylwia Komocki, Michel Michaux
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Patent number: 7670426Abstract: Flowable concrete mixtures have an aqueous foam admixture mixed therein to give the concrete mixture desired strength, flowability, and density. The concrete mixtures include a hydration stabilizer to stabilize the aqueous foam. The hydration stabilizer inhibits the reaction between the hydraulic cement and the water in the aqueous foam. The aqueous foam can be further stabilized using a fluorochemical surfactant. Preferred fluorochemical surfactants comprise an oligomer having at least one hydrophilic nonionic monomer and at least one hydrophilic anionic monomer.Type: GrantFiled: December 19, 2005Date of Patent: March 2, 2010Assignee: Jack B. Parson CompaniesInventor: Lonnie James Gray
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Patent number: 7670427Abstract: A method of making a rapid setting composition for cement boards is disclosed. Compositions including portland cement, fly ash, gypsum, alkanolamine and phosphate are disclosed. A synergistic interaction between the alkanolamine and phosphate increases the effectiveness of accelerating reactions thus allowing for quick setting and increased early-age compressive strength compositions.Type: GrantFiled: June 6, 2007Date of Patent: March 2, 2010Assignee: United States Gypsum CompanyInventors: Marianela Perez-Pena, Yanfei Peng, Srinivas Veeramasuneni
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Patent number: 7666258Abstract: A lightweight cementitious composition containing from 22 to 90 volume percent of a cement composition and from 10 to 78 volume percent of particles having an average particle diameter of from 0.2 mm to 8 mm, a bulk density of from 0.03 g/cc to 0.64 g/cc, an aspect ratio of from 1 to 3, where after the lightweight cementitious composition is set it has a compressive strength of at least 1700 psi as tested according to ASTM C39. The cementitious composition can be used to make concrete masonry units, construction panels, road beds and other articles and can be included as a layer on wall panels and floor panels and can be used in insulated concrete forms. Aspects of the lightweight cementitious composition can be used to make lightweight structural units.Type: GrantFiled: February 24, 2006Date of Patent: February 23, 2010Assignee: NOVA Chemicals Inc.Inventors: Tricia Guevara, Michael T. Williams, David A. Cowan, John K. Madish, Kolapo Adewale, Roger Moore, Mary Margaret Moore, legal representative
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Patent number: 7644548Abstract: A lightweight concrete composition containing from 10 to 90 volume percent of a cement composition, from 10 to 90 volume percent of particles having an average particle diameter of from 0.2 mm to 8 mm, a bulk density of from 0.03 g/cc to 0.64 g/cc, an aspect ratio of from 1 to 3, and from 0 to 50 volume percent of aggregate; where the sum of components used does not exceed 100 volume percent, and where after the lightweight concrete composition is set it has a compressive strength of at least 1700 psi as tested according to ASTM C39 after seven days. The concrete composition can be used to make concrete masonry units, construction panels, road beds and other articles.Type: GrantFiled: March 22, 2006Date of Patent: January 12, 2010Assignee: NOVA Chemicals Inc.Inventors: Tricia Guevara, Michael T. Williams, David A. Cowan, John K. Madish, Kolapo Adewale, Roger Moore, Mary Margaret Moore, legal representative, Tobias Blain Hileman
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Patent number: 7632348Abstract: A lightweight concrete composition containing from 10 to 90 volume percent of a cement composition, from 10 to 90 volume percent of particles having an average particle diameter of from 0.2 mm to 8 mm, a bulk density of from 0.03 g/cc to 0.64 g/cc, an aspect ratio of from 1 to 3, and from 0 to 50 volume percent of aggregate, where the particles contain an antimicrobial agent; where the sum of components used does not exceed 100 volume percent, and where after the lightweight concrete composition is set it has a compressive strength of at least 1700 psi as tested according to ASTM C39 after seven days. The concrete composition can be used to make concrete masonry units, construction panels, dining tables, counter surfaces, bench tops, and/or examination tables as well as other articles.Type: GrantFiled: September 14, 2006Date of Patent: December 15, 2009Assignee: NOVA Chemicals Inc.Inventors: David Allen Cowan, Tricia Guevara, Gary F. Matz
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Patent number: 7621995Abstract: A viscosity modifying agent is added to a concrete mixture to give the concrete desirable rheological properties. The viscosity modifying agent is incorporated into a foam admixture before it is mixed into the concrete. Because the viscosity modifying agent is a component of the foam admixture, the viscosity modifying agent is dispersed in the aqueous film that forms the foam bubbles. The viscosity modifier in the foam bubbles gives the foam beneficial rheological properties. The viscosity modifier performs more efficiently when included in the foam bubbles as compared to being mixed directly into the concrete. The foam bubbles containing the viscosity modifier can be stabilized using a fluorochemical stabilizer, which is included in the foam admixture. The foam bubbles can be further stabilized with respect to cement mixtures by including a hydration stabilizing in the cement mixture.Type: GrantFiled: December 19, 2005Date of Patent: November 24, 2009Assignee: Jack B. Parson CompaniesInventor: Lonnie James Gray
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Patent number: 7618490Abstract: To provide a spraying material having an excellent quick-setting property and excellent adherability, a small alkali amount and excellent initial strength development, and a spraying method using it. The spraying material comprises a liquid quick-setting admixture containing an aluminum source, a sulfur source and a fluorine source, one or more quick-setting aids selected from the group consisting of calcium aluminate, calcium sulfoaluminate, calcium aluminosilicate, an alkali metal-containing substance, calcium hydroxide and aluminum hydroxide, and a cement concrete, and the method is to spray this spraying material.Type: GrantFiled: August 19, 2004Date of Patent: November 17, 2009Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Yasuhiro Nakashima, Shunichi Mishima, Masahiro Iwasaki, Isao Terashima, Atsumu Ishida, Takamitsu Murokawa, Tomohito Kobayashi
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Patent number: 7591893Abstract: A dense mortar includes: (i) an ettringite binder, including calcium sulphate and a calcium aluminate mineral compound, (ii) at least one poly(alkylene oxide) comb polymer and, (iii) at least one organic resin, the organic resin accounting for less than 2% by weight of the mortar.Type: GrantFiled: October 22, 2004Date of Patent: September 22, 2009Assignee: KerneosInventors: Loris Amathieu, Bruno Touzo, Lionel Raynaud, Dina Gauthier
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Patent number: 7582158Abstract: A rapid setting, controlled low strength composition of Class C fly ash is provided having a quantity of hydrated lime and an iron chelating compound in an amount sufficient to accelerate the hydration and set time of the fly ash. In some examples, a filler material is added. A method for acceleration of the hydration and set time of a cementitious mixture is provided wherein hydrated lime is added to the cementitious mixture in an amount in the range of 0.1% to 15% by weight and an iron chelating compound in an amount in the range of 0.01% to 5.0% by weight of the cementitious material. Further, a calcium source and an iron chelating compound may be added to a Class C fly ash to accelerate the hydration and set time of the ash.Type: GrantFiled: March 14, 2008Date of Patent: September 1, 2009Inventors: Jerry Setliff, Scott F. Timmons, Clinton W. Pike
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Patent number: 7572330Abstract: The invention relates to the composition of fresh concrete and admixtures for fresh concrete and can be used in the construction industry for producing monolithic and precast concrete and reinforced concrete structures, in spraying mixtures and also in the oil extraction industry when producing injection and insulation cement materials.Type: GrantFiled: November 26, 2004Date of Patent: August 11, 2009Inventors: Satanowskaja Olga Solomonowna Tselner, legal representative, Oswald Vocke, Mikhail Tselner
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Patent number: 7556684Abstract: A strength improvement admixture composition is provided that increases the compressive strength of cementitious compositions without negatively increasing the setting time. The admixture comprises the components of a polycarboxylate dispersant and strength improvement additive.Type: GrantFiled: February 25, 2005Date of Patent: July 7, 2009Assignee: Construction Research & Technology GmbHInventors: Jeffrey R. Bury, Thomas M. Vickers, Jr., Bruce J. Christensen
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Patent number: 7543642Abstract: Cement compositions comprising flexible, compressible beads, processes for preparing such cement compositions, and methods of cementing in subterranean formations using such cement compositions. One or more flexible, compressible beads are mixed with the cement before pumping the cement into a well bore. The flexible, compressible beads are preferably composed of an elastomeric material such as a copolymer of methylmethacrylate and acrylonitrile; a terpolymer of methylmethacrylate, acrylonitrile, and dichloroethane; a styrene-divinylbenzene copolymer; and polystyrene. The flexible, compressible beads may be heated to expand the beads before mixing with the cement such that the ensuing cement composition will have a desired density. Non-flexible beads such as spherulites may also be added to the cement compositions.Type: GrantFiled: January 24, 2003Date of Patent: June 9, 2009Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Krishna M. Ravi, Michael J. Szymanski
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Patent number: 7537656Abstract: Cement compositions may comprise one or more secondary amines substituted with a carboxyl group or salts thereof (e.g., 3-hydroxy N,N?-iminodisuccinic acid) for retarding the setting of such compositions. The inclusion of such materials in cement compositions may be highly beneficial. In wellbores having BHCT's of less than or equal to about 250° F., the use of the secondary amine as the set retarder ensures that the thickening time of the cement composition is sufficient to allow the cement composition to be pumped to its desired downhole location. Further, the secondary amine may be used in combination with conventional set retarders to enhance the ability of those retarders to increase the thickening time of the cement composition at higher BHCT's, e.g., from about 250° F. to about 525° F.Type: GrantFiled: June 22, 2005Date of Patent: May 26, 2009Assignee: Halliburton Energy Services, Inc.Inventors: Ashok K. Santra, Russell M. Fitzgerald
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Patent number: 7527688Abstract: Cementitious compositions are provided that can be use in drilling oil and gas well applications. The compositions include a source of hydraulically settable cement, calcium carbonate, free lime and alkali ions, calcium sulfate and an organic component. Methods for cementing a casing and liners and for remedial operations such as plugging back and squeeze cementing are also provided.Type: GrantFiled: December 19, 2007Date of Patent: May 5, 2009Assignee: Holcim (US) Inc.Inventors: Arlen Earl Bingamon, Stephen C. Morrical, Francis Allison Innis, Anthony Martin Sorcic
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Patent number: 7507281Abstract: An antimicrobial cementitious composition for imparting antimicrobial characteristics to cement comprises a cement-based compound and an imazalil agent; combinations of agents also may be employed.Type: GrantFiled: May 29, 2007Date of Patent: March 24, 2009Assignee: Microban Products CompanyInventors: Ivan W. Ong, H. Wayne Swofford
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Patent number: 7497904Abstract: A cementitious composition is provided that is composed of hydraulic cement and a liquid coloring suspension. The liquid coloring suspension which contains polycarboxylate dispersant and pigment provides the cementitious composition with increased dispersion of pigment particles, lowered water content, and improved coloration over that observed in the prior art. Also, a liquid coloring suspension for cementitious compositions is provided which contains polycarboxylate dispersant, pigment, and thixotropic additive. The liquid coloring suspension increases the color of cementitious compositions, reduces the water content and has long term stability in that it does not become increasingly viscous over time.Type: GrantFiled: March 26, 2004Date of Patent: March 3, 2009Assignees: Construction Research & Technology GmbH, L.M. Scofield CompanyInventors: Nancy A. Dulzer, Jeffrey L. Matrician, Martin E. Wild
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Patent number: 7485184Abstract: A method of producing cementitious mixtures containing fly ash as one of the cementitious components, under air entrainment conditions. The method involves forming a mixture comprising water, cement, fly ash, optionally other cementitious materials, aggregate, conventional chemical admixtures, and an air entrainment agent and agitating the mixture to entrain air therein. Additionally, at least one sacrificial agent is also included in the mixture. The sacrificial agent is a material or mixture of materials that is not required to act as an air entrainment agent but interacts preferentially with components of the fly ash that otherwise neutralize, repress or depress the activity of the air entrainment agent. The invention includes cementitious mixtures and hardened concretes resulting from the method and fly ash treated with sacrificial agent, or air entrainment agent/sacrificial agent combinations, and processes for selecting suitable sacrificial agents.Type: GrantFiled: January 22, 2004Date of Patent: February 3, 2009Assignee: Handy Chemicals Ltd.Inventors: Russell Hill, Carmel R. Jolicoeur, Monique Page, Ioan Spiratos, Thi Cong To
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Patent number: 7449062Abstract: A method of cementing a wellbore comprising preparing a cement composition comprising a water-soluble aromatic sulfonated polymer, and placing the cement composition into the wellbore, wherein the cement composition develops a compressive strength of greater than about zero in less time than a similar cement composition having a comparable thickening time and lacking a water-soluble aromatic sulfonated polymer. A cement composition comprising a water-soluble aromatic sulfonated polymer, wherein the cement composition develops a compressive strength of greater than about zero in less time than a similar cement composition having comparable thickening time and lacking a water-soluble aromatic sulfonated polymer.Type: GrantFiled: November 29, 2007Date of Patent: November 11, 2008Assignee: Halliburton Energy Services, Inc.Inventors: Ashok K Santra, Mfon Antia, B. Raghava Reddy
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Patent number: 7445670Abstract: A method is provided for reducing the density of a well cement composition for cementing in a subterranean formation. The method comprises providing a cement composition that comprises water and a cement, and then adding an additive comprising an anionic foam stabilizer and an anionic foaming agent or a Zwitterionic foam booster. A gas is added to this mixture to reduce the density. Further, foamed cement compositions and additives for foaming and stabilizing a well cement composition are provided.Type: GrantFiled: January 29, 2007Date of Patent: November 4, 2008Assignee: Halliburton Energy Services, Inc.Inventors: Samuel J. Lewis, Michael J. Szymanski, Kristi D. Thacker