Organic Silicon, Organic Boron Or Organic Phosphorus Patents (Class 106/806)
  • Patent number: 10633508
    Abstract: The invention relates to a method for producing a master batch comprising between 0.01 and 50 wt. % of carbonaceous nanofillers and at least one sulphurated material such as elemental sulphur by melt compounding, and to the master batch thus produced and the different uses thereof. The invention also relates to a solid composition comprising carbonaceous nanofillers dispersed in a sulphurated material.
    Type: Grant
    Filed: October 27, 2015
    Date of Patent: April 28, 2020
    Assignee: Arkema France
    Inventors: Alexander Korzhenko, Christophe Vincendeau, Thierry Aubert
  • Patent number: 9975909
    Abstract: Polyether alcohols having alkoxysilyl groups, the use thereof and a process for their preparation by means of DMC catalysis, characterized in that one or more epoxy-functional alkoxysilanes are added individually or in a mixture with further epoxide compounds and optionally further comonomers, either in block form or in random distribution, onto a chain starter of the formula (VII): R1—H??(VII); having at least one reactive hydroxyl group, where R1 is a saturated or unsaturated, optionally branched radical, or a polyether radical of the alkoxy-, arylalkoxy or alkylarylalkoxy group type, in which the carbon chain may be interrupted by oxygen atoms or corresponds to a polyetheralkoxy radical or to a singularly or multiply fused phenolic group.
    Type: Grant
    Filed: May 7, 2013
    Date of Patent: May 22, 2018
    Assignee: EVONIK DEGUSSA GMBH
    Inventors: Frank Schubert, Wilfried Knott
  • Patent number: 9040608
    Abstract: The present invention relates to a curable mixture suitable for obtaining “easy-to-clean” properties in the cured mixture, comprising at least one mineral binder, a powder comprising at least one fluoroorganyl-substituted silicon compound encapsulated in a water-soluble polymer, the amount of the silicon compound being 0.001% to 8% by weight, based on the present mixture, and optionally further adjuvants, and also to a process for preparing the mixture and to the use thereof. The invention further relates to a water-redispersible powder and also to a corresponding intermediate for use in the curable mixture in order to obtain “easy-to-clean” properties in the cured mixture. Also claimed, furthermore, is a process for preparing the powder, and the use thereof.
    Type: Grant
    Filed: March 30, 2011
    Date of Patent: May 26, 2015
    Assignees: Evonik Degussa GmbH, Akzo Nobel Chemicals International B.V.
    Inventors: Manuel Friedel, Philipp Albert, Burkhard Standke, Spomenko Ljesic, Ulf Kehrer
  • Patent number: 9005361
    Abstract: The present application relates to compositions comprising at least one siloxane and at least one superplasticizer based on polycarboxylate ethers or sulphonates of lignin, melamine or naphthalene or of resins thereof, and to the use of such compositions as or in building-product mixtures or building products, especially mortar mixtures or concrete mixtures. Preferably the siloxane is a branched siloxane containing at least one “T” unit and containing at least two different polyoxyalkylene moieties.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: April 14, 2015
    Assignee: Evonik Industries AG
    Inventors: Frauke Henning, Anke Reinschmidt, Ralph Scheuermann, George-Hans Bayne, Kerstin Klein, Markus Roos
  • Patent number: 8961672
    Abstract: Solid alkali metal salts of organosilanols and/or their hydrolysis/condensation products are prepared by hydrolysis of organosilanes in water and in the presence of a basic alkali metal salt. The products contain predominately methyl and ethyl organic groups, and C4 or higher hydrocarbon groups as well. The solid salts effectively hydrophobe building materials, while being easily mixed with water.
    Type: Grant
    Filed: May 7, 2012
    Date of Patent: February 24, 2015
    Assignee: Wacker Chemie AG
    Inventors: Michael Stepp, Dominik Auer, Karl-Heinz Felix, Daniel Schildbach
  • Patent number: 8920550
    Abstract: The present invention relates to a new mineral matter particle hydrophobization agent and to its various uses for the surface treatment of mineral matter particles.
    Type: Grant
    Filed: February 18, 2014
    Date of Patent: December 30, 2014
    Assignee: Coatex
    Inventors: Jean-Marc Suau, Jacques Mongoin, Christian Jacquemet
  • Publication number: 20140323362
    Abstract: Defoamer compositions are disclosed and methods for making and using same, where the defoamer has universal applicability at low concentrations. The defoamer compositions include between 40 vol. % and about 80 vol. % distilled water (other waters may be used instead), 10 vol. % and about 30 vol. % of silicon anti-foam agent and between about 10 vol. % and about 30 vol. % of active silicon anti-foam agent. The defoamer compositions are used in amount of less than or equal to 200 ppm in all foamed downhole fluid systems.
    Type: Application
    Filed: July 11, 2014
    Publication date: October 30, 2014
    Applicant: CLEARWATER INTERNATIONAL, LLC
    Inventors: Olusegun Matthew Falana, Edward C, Marshall, Frank Zamora
  • Publication number: 20140230698
    Abstract: Body-hydrophobing of mineral building compositions prepared from water curable mineral materials such as cement and plaster are obtained by admixing into the curable composition an organosilicon compound prepared by reacting a hydrocarbylhalosilane or hydrocarbylhydrocarbyloxysilane with a gylcol or polyglycol in a mol ratio of halo or hydrocarbyloxy radicals to hydroxyl radicals of 0.3 to 1.3. The organosilicon compounds are solid at 20° C.
    Type: Application
    Filed: October 1, 2012
    Publication date: August 21, 2014
    Applicant: Wacker Chemie AG
    Inventors: Michael Stepp, Herbert Koller, Daniel Schildbach
  • Patent number: 8753444
    Abstract: Reinforced sulphur concrete wherein one or more metal reinforcing members are in contact with sulphur concrete is disclosed. The reinforced sulphur concrete comprises an adhesion promoter that enhances the interaction between the sulphur and the one or more metal reinforcing members.
    Type: Grant
    Filed: October 26, 2011
    Date of Patent: June 17, 2014
    Assignee: Shell Oil Company
    Inventors: Juedu Austine, Yiu Chung Cheng, Michael David Lankshear, Cees Weijers
  • Publication number: 20140144350
    Abstract: A hydraulic binder containing 25 to 85 wt % of cement clinker, 0 to 7 wt % of CaSO4, a mineral additive(s), and 1 to 10 wt % of a dual setting control system that includes an activator and a retarder, in a weight ratio of activator to retarder, based on the dry substance selected to be greater than 85:15, in particular greater than 90:10, more particularly greater than 95:5, and, in particular, greater than 98:2.
    Type: Application
    Filed: July 9, 2012
    Publication date: May 29, 2014
    Applicant: HOLCIM TECHNOLOGY LTD.
    Inventors: Winnie Matthes, Zarina Castelltort, Thomas Matschei, Moussa Baalbaki
  • Publication number: 20140083334
    Abstract: A sulphur cement pre-composition, comprising sulphur and an organosilane coupling agent of formula (I); wherein R1, R2 and R3 are independently chosen from alkoxy, acyloxy, acyloxy, alkyl, aryl and halogen, wherein R4 is alkyl, wherein n is from 1 to 8, wherein R5 is alkyl, alkenyl or aralkyl and wherein p is an integer of at least 1, and wherein the weight ratio of sulphur to organosilane coupling agent is at least 1.
    Type: Application
    Filed: March 14, 2012
    Publication date: March 27, 2014
    Inventors: Guy Lode Magda Maria Verbist, Willem Posthumus, Catherine Frances Smura
  • Patent number: 8679247
    Abstract: The present invention relates to a hydraulic setting mixture comprising: a) 6% to 25% by weight of cement, b) 50% to 90% by weight of at least one aggregate, and c) 0.001% to 8% by weight of at least one fluoroorganyl-substituted silicon compound, and also to materials produced from this mixture, more particularly components, concrete articles or mouldings. The invention further relates to the use of a hydraulic setting mixture of the invention for producing materials, more particularly components, concrete articles or mouldings, for example as face concrete, where the surface of the materials exhibits only relatively low soiling tendency (“easy-to-clean” property) even on abrasion.
    Type: Grant
    Filed: March 30, 2011
    Date of Patent: March 25, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Manuel Friedel, Spomenko Ljesic, Philipp Albert, Burkhard Standke
  • Publication number: 20140069301
    Abstract: Solid alkali metal salts of organosilanols and/or their hydrolysis/condensation products are prepared by hydrolysis of organosilanes in water and in the presence of a basic alkali metal salt. The products contain predominately methyl and ethyl organic groups, and C4 or higher hydrocarbon groups as well. The solid salts effectively hydrophobe building materials, while being easily mixed with water.
    Type: Application
    Filed: May 7, 2012
    Publication date: March 13, 2014
    Applicant: WACKER CHEMIE AG
    Inventors: Michael Stepp, Dominik Auer, Karl-Heinz Felix, Daniel Schildbach
  • Publication number: 20140066347
    Abstract: The present disclosure is directed to compositions having lecithin and an organic acid and related methods. The disclosed compositions may also include one or more co-surfactants such as anionic surfactants and/or non-ionic surfactants, and may be used as a dispersant.
    Type: Application
    Filed: November 8, 2013
    Publication date: March 6, 2014
    Applicant: ARCHER DANIELS MIDLAND COMPANY
    Inventors: Shireen S. Baseeth, Teodora R. Tabuena-Salyers, Bruce R. Sebree
  • Patent number: 8664310
    Abstract: The present disclosure may provide a mixture for use in forming a transparent coating including a silicon alkoxide precursor and an organic polymer. The silicon alkoxide precursor may have a pH level between 1 and 4. The organic polymer may have an average molecular weight between 5,000 and 50,000 Da. The mixture may include 35% to 65% organic polymer by volume. The organic polymer may be removed from the mixture after application leaving a resultant transparent coating, wherein: the resultant coating has a porosity of ?35% to ?65%; a thickness in the range from ?95 nm to ?135 nm; pores having an average diameter from ?5 nm to ?50 nm; and a diameter distribution according to a log-norm distribution with a half-width of ?10 nm.
    Type: Grant
    Filed: September 26, 2007
    Date of Patent: March 4, 2014
    Assignee: Siemens Aktiengesellschaft
    Inventors: Anett Berndt, Florian Eder, Hans-Dieter Feucht
  • Patent number: 8608847
    Abstract: The invention relates to additives for hydraulic binders and systems produced from them, such as concrete and mortar. In particular, the present invention relates to a setting and hardening accelerator for hydraulic binders produced by means of reaction of a calcium compound CV with a silicon compound SV and addition of a phosphonic acid derivative, as well as its production.
    Type: Grant
    Filed: August 24, 2011
    Date of Patent: December 17, 2013
    Assignee: Sika Technology AG
    Inventors: Christian Buerge, Franz Wombacher, Christophe Kurz, Beat Marazzani, Gilbert Maeder, Ueli Sulser
  • Patent number: 8591646
    Abstract: The present invention relates to construction materials comprising at least one binder, at least one oil-containing filler and at least one metallate additive according to formula (1): (RO)m-M-(Oa—Xb—R?c—Yd)n??(1) wherein M is one of titanium and zirconium. The present invention also relates to methods of preparing and using the inventive construction materials. The inventive construction material compositions are capable of utilizing oil-containing fillers in which the oil is stable in the final composition and the desired mechanical properties of the construction material are maintained or improved.
    Type: Grant
    Filed: August 17, 2011
    Date of Patent: November 26, 2013
    Assignee: S&E Innovative Technologies LLC
    Inventor: Salvatore J. Monte
  • Patent number: 8580030
    Abstract: A concrete mix useful for producing concrete products having anti-efflorescence properties and a method for making such concrete products are provided. The concrete mix includes a hydraulic cement binder, aggregates and as an additive an ultrafine particulate material including carrier particles being surface treated with an efflorescence control agent. The method for making concrete includes a first step of mixing the hydraulic cement binder, aggregates, water and the ultrafine particulate material, a second step of pouring the mixture so obtained into a form, and a third step of curing the mixture.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: November 12, 2013
    Assignee: Omya International AG
    Inventors: Berndt Kanduth, Jean-Bernard Gelinas
  • Patent number: 8506700
    Abstract: A dry composition including at least one binder and at least one silicone oil with the following formula (I): in which: Z1 and Z2, identical or different, independently represent a terminal group selected from the group consisting of a hydrogen atom; a hydroxyl; a linear or branched, optionally substituted C1 to C12 alkyl; a linear or branched, optionally substituted C2 to C12 alkenyl radical; a linear or branched, optionally substituted C1 to C12 heteroalkyl; an optionally substituted C5 to C10 cycloalkyl radical; and an optionally substituted C6 to C18 aryl radical; R1 and R2, identical or different, independently represent a hydrogen atom; a hydroxyl; a linear or branched, optionally substituted C1 to C12 alkyl; a linear or branched, optionally substituted C2 to C12 alkenyl radical; a linear or branched, optionally substituted C1 to C12 heteroalkyl; an optionally substituted C5 to C10 cycloalkyl radical; or an optionally substituted C6 to C18 aryl radical; m and n, identical or different, independen
    Type: Grant
    Filed: August 25, 2011
    Date of Patent: August 13, 2013
    Assignee: Sika Technology AG
    Inventors: Christophe Guyot, Laurent Guillot
  • Publication number: 20130192494
    Abstract: The present invention relates to a hydraulic setting mixture comprising: a) 6% to 25% by weight of cement, b) 50% to 90% by weight of at least one aggregate, and c) 0.001% to 8% by weight of at least one fluoroorganyl-substituted silicon compound, and also to materials produced from this mixture, more particularly components, concrete articles or mouldings. The invention further relates to the use of a hydraulic setting mixture of the invention for producing materials, more particularly components, concrete articles or mouldings, for example as face concrete, where the surface of the materials exhibits only relatively low soiling tendency (“easy-to-clean” property) even on abrasion.
    Type: Application
    Filed: March 30, 2011
    Publication date: August 1, 2013
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Manuel Friedel, Spomenko Ljesic, Philipp Albert, Burkhard Standke
  • Publication number: 20130174760
    Abstract: The present application relates to compositions comprising at least one siloxane and at least one superplasticizer based on polycarboxylate ethers or sulphonates of lignin, melamine or naphthalene or of resins thereof, and to the use of such compositions as or in building-product mixtures or building products, especially mortar mixtures or concrete mixtures.
    Type: Application
    Filed: December 19, 2012
    Publication date: July 11, 2013
    Inventors: Frauke HENNING, Anke Reinschmidt, Ralph Scheuermann, George-Hans Bayne, Kerstin Klein, Markus Roos
  • Publication number: 20130152827
    Abstract: The present invention relates to iron oxide particles, consisting of a core and a coating, wherein the core is essentially selected from FeO(OH), Fe2O3, or Fe3O4, and mixtures thereof, and the coating comprises a polysiloxane coating, wherein the polysiloxane coating is present in an amount of 0.1% to 10% by weight based on the weight of the core.
    Type: Application
    Filed: April 21, 2011
    Publication date: June 20, 2013
    Applicant: Rockwood Italia S.P.A.
    Inventors: Gerardo Ripandelli, Daniela Fontana
  • Publication number: 20130112116
    Abstract: The invention relates to additives for hydraulic binders and systems produced from them, such as concrete and mortar. In particular, the present invention relates to a setting and hardening accelerator for hydraulic binders produced by means of reaction of a calcium compound CV with a silicon compound SV and addition of a phosphonic acid derivative, as well as its production.
    Type: Application
    Filed: August 24, 2011
    Publication date: May 9, 2013
    Applicant: SIKA TECHNOLOGY AG
    Inventors: Christian Buerge, Franz Wombacher, Christophe Kurz, Beat Marazzani, Gilbert Maeder, Ueli Sulser
  • Publication number: 20130098271
    Abstract: A dry mortar mixture based on at least one hydraulic and/or latently hydraulic binder which in the made-up and not yet cured state has firm properties is claimed. The novel dry mortar mixture is characterized in that it contains at least one representative of a dispersant and at least one compound having superabsorbent properties. This mixture makes it possible to carry over the advantages of known tile adhesives for horizontal application to vertical application possibilities.
    Type: Application
    Filed: October 28, 2010
    Publication date: April 25, 2013
    Inventors: Michael Eberwein, Christian Trieflinger, Michael Schinabeck, Jutta Karin Langlotz, Stefan Friedrich, Gregor Herth
  • Publication number: 20130087080
    Abstract: The present invention relates to a hydraulically setting mixture comprising: a) 6% to 25% by weight of cement, b) 50% to 90% by weight of at least one aggregate, and c) 0.01% to 8% by weight of at least one fluoroorganyl-substituted silicon compound, and also to materials produced from this mixture, more particularly components, concrete articles or mouldings. The invention further relates to the use of a hydraulically setting mixture of the invention for producing materials, more particularly components, concrete articles or mouldings, for example as facing concrete, where the surface of the materials exhibits only relatively low soiling tendency (“easy-to-clean” property) even on abrasion.
    Type: Application
    Filed: March 30, 2011
    Publication date: April 11, 2013
    Applicant: Evonik Degussa GmbH
    Inventors: Manuel Friedel, Philipp Albert, Burkhard Standke, Spomenko Ljesic
  • Publication number: 20120186493
    Abstract: A process for the preparation of a sulphur cement product is disclosed. Sulphur is mixed with a coupling agent and with a particulate inorganic material at a temperature at which sulphur is molten to obtain a molten sulphur cement product, which is solidified. The coupling agent is supplied as a solid composition comprising the coupling agent and at least 10 wt %, based upon the weight of the solid composition, of carrier material selected from one or more of wax, inorganic filler and polymer. The coupling agent is chosen from the group of organosilanes and organotitanates.
    Type: Application
    Filed: May 18, 2010
    Publication date: July 26, 2012
    Inventors: Paul de Boer, Yiu Chung Cheng, Michael David Lankshear, Catherine Frances Smura, Guy Lode Magda Maria Verbist, Willem Posthumus
  • Patent number: 8221533
    Abstract: A method to render stone, ceramic, or cementitious structures water repellent is disclosed. The method includes the step of contacting the stone, ceramic, or cementitious structures with an alkylphosphonic acid. The alkylphosphonic acid can be dispersed in an aqueous medium and can be at least partially neutralized with ammonia, an amine, or a basic alkali salt.
    Type: Grant
    Filed: July 6, 2011
    Date of Patent: July 17, 2012
    Assignee: H20 Barrier Technologies LLC
    Inventors: Mark Rule, Harry Harshaw
  • Publication number: 20120096796
    Abstract: A waterproof masonry cement is disclosed. The masonry cement includes a waterproofing agent, in dry form, which is introduced into the cement during the grinding process. The waterproofing agent comprises siloxanes and alkoxysilanes and can also be introduced, in liquid form, into concrete blocks during the manufacture of same. In this manner, the concrete blocks incorporating the waterproofing agent along with the masonry cement containing the waterproofing agent can be utilized together to form a water repellant wall structure.
    Type: Application
    Filed: October 25, 2010
    Publication date: April 26, 2012
    Inventor: Christopher J. Sieto
  • Publication number: 20120073475
    Abstract: The invention relates to a compound of following formula (I): the preparation method thereof and the use of same.
    Type: Application
    Filed: March 31, 2010
    Publication date: March 29, 2012
    Applicant: CHRYSO
    Inventors: Philippe Maitrasse, Bruno Pellerin, Frederic Leising
  • Publication number: 20120068110
    Abstract: The application relates to a reactive ceramic binder suitable for producing ceramic products from ceramic powder, characterized in that the reactive ceramic binder represents hydroxyl compounds which carry reactive silyl groups and can be additionally (poly)siloxane-substituted.
    Type: Application
    Filed: April 26, 2010
    Publication date: March 22, 2012
    Applicant: EVONIK GOLDSCHMIDT GMBH
    Inventors: Frank Schubert, Thomas Ebbrecht, Matthias Naumann, Wilfried Knott
  • Patent number: 8137456
    Abstract: The present invention provides a process for the preparation of sulphur cement or a sulphur cement-aggregate composite comprising the following steps: (a) admixing at least an inorganic filler and/or aggregate and a polysulphide-containing organosilane having at least two organosilyl groups and allowing the organosilane to react with the inorganic filler and/or aggregate; (b) admixing during or after step (a) elemental sulphur with the inorganic filler and/or aggregate at a temperature at which sulphur is liquid to obtain an admixture comprising molten sulphur and inorganic filler and/or aggregate; and (c) solidifying the admixture to obtain sulphur cement or a sulphur cement-aggregate composite. The invention further provides sulphur cement or a sulphur cement-aggregate composite obtainable by such process and the use of a polysulphide-containing organosilane having at least two organosilyl groups as coupling agent in sulphur cement or a sulphur cement-aggregate composite.
    Type: Grant
    Filed: December 7, 2006
    Date of Patent: March 20, 2012
    Assignee: Shell Oil Company
    Inventors: Rob Aloysius Maria Van Trier, Guy Lode Magda Maria Verbist
  • Patent number: 8133600
    Abstract: Polymerization of siloxane is improved using a gypsum-based slurry that includes stucco, Class C fly ash, magnesium oxide and an emulsion of siloxane and water. This slurry is used in a method of making water-resistant gypsum articles that includes making an emulsion of siloxane and water, then combining the slurry with a dry mixture of stucco, magnesium oxide and Class C fly ash. The slurry is then shaped as desired and the stucco is allowed to set and the siloxane polymerizes. The resulting product is useful for making a water-resistant gypsum panel having a core that includes interwoven matrices of calcium sulfate dihydrate crystals and a silicone resin, where the interwoven matrices have dispersed throughout them a catalyst comprising magnesium oxide and components from a Class C fly ash.
    Type: Grant
    Filed: September 22, 2010
    Date of Patent: March 13, 2012
    Assignee: United States Gypsum Company
    Inventors: Xuming Wang, Qingxia Liu, Paul Reed, Qiang Yu
  • Publication number: 20120037044
    Abstract: A dry composition including at least one binder and at least one silicone oil with the following formula (I): in which: Z1 and Z2, identical or different, independently represent a terminal group selected from the group consisting of a hydrogen atom; a hydroxyl; a linear or branched, optionally substituted C1 to C12 alkyl; a linear or branched, optionally substituted C2 to C12 alkenyl radical; a linear or branched, optionally substituted C1 to C12 heteroalkyl; an optionally substituted C5 to C10 cycloalkyl radical; and an optionally substituted C6 to C18 aryl radical; R1 and R2, identical or different, independently represent a hydrogen atom; a hydroxyl; a linear or branched, optionally substituted C1 to C12 alkyl; a linear or branched, optionally substituted C2 to C12 alkenyl radical; a linear or branched, optionally substituted C1 to C12 heteroalkyl; an optionally substituted C5 to C10 cycloalkyl radical; or an optionally substituted C6 to C18 aryl radical; m and n, identical or different, independen
    Type: Application
    Filed: August 25, 2011
    Publication date: February 16, 2012
    Applicant: SIKA TECHNOLOGY AG
    Inventors: Christophe GUYOT, Laurent GUILLOT
  • Patent number: 8092592
    Abstract: Exemplary embodiments as disclosed herein are directed to setting and curing accelerators for hydraulic binders, including at least one ester of a polyhydric alcohol with an acid and/or salts thereof, where the acid is a phosphoric acid, phosphorous acid or a C2 to C20 carboxylic acid. Compositions including at least one accelerator as disclosed herein can accelerate the setting and curing of hydraulic binders and mortar or concrete produced therefrom, such as quick-setting cement. Methods for accelerating the setting and curing of hydraulic binders and mortar or concrete produced therefrom are also disclosed.
    Type: Grant
    Filed: November 29, 2010
    Date of Patent: January 10, 2012
    Assignee: Sika Technology AG
    Inventors: Christian Buerge, Franz Wombacher, Andre Peter
  • Publication number: 20110290157
    Abstract: A sulphur cement pre-composition, comprising sulphur, a first organosilane and a second organosilane, and a sulphur cement product comprising sulphur, a particulate inorganic material, a first organosilane and a second organosilane are disclosed. The first organosilane comprises one or more functional groups chosen from thiol, sulphide, amine or alkenyl groups. The second organosilane does not comprise any thiol, sulphide, amine or alkenyl groups. Processes for making the sulphur cement pre-composition and the sulphur cement product are also disclosed.
    Type: Application
    Filed: January 28, 2010
    Publication date: December 1, 2011
    Inventors: Paul De Boer, Michael David Lankshear, Guy Lode Magda Maria Verbist
  • Patent number: 8057593
    Abstract: The present invention relates to a pigment dispersion and a black water-reducing agent, more particularly, to a pigment dispersion comprising a carbon black whose surface is modified with an aminosilane compound and a polycarboxylic acid-based water-reducing agent, and a black water-reducing agent using the same. The present invention is characterized in that the surface-modified carbon black with an aminosilane compound is water-dispersed by using a polycarboxylic acid-based water-reducing agent as a dispersing agent having better performance than a naphthanlene-based water-reducing agent. Therefore, the present invention can display black color of the water-reducing agent and cement at the same time and improve the flowability of cement owing to the presence of carbon black in the form of nanoparticles, which enables to manufacture ultrahigh strength concrete.
    Type: Grant
    Filed: March 3, 2011
    Date of Patent: November 15, 2011
    Assignee: OCI Company Ltd
    Inventors: Hae Yoon Ryu, Kwang Eui Yoon, Sang Je Cho, Moo Soo Park, Yo Bok Park, Se In Yang
  • Patent number: 7972424
    Abstract: Hydrophobicizing agents which are easily admixed with construction chemical products are prepared by providing a solution of a protective colloid and adding thereto a fatty acid compound sensitive to high pH environments, optionally, a hydrophobicizing organosilicon compound, and drying the resulting aqueous mixture.
    Type: Grant
    Filed: May 13, 2004
    Date of Patent: July 5, 2011
    Assignee: Wacker Chemie AG
    Inventors: Thomas Bastelberger, Reinhard Härzschel, Franz Jodlbauer
  • Patent number: 7931747
    Abstract: The present invention relates to cement-containing compositions which are characterized in that they have a proportion of organosilicon compounds of greater than 0.15% by weight, based on the proportion of cement, the organosilicon compounds being based on at least one organosilicon compound selected from the group consisting of the alkoxysilanes and at least one selected from the group consisting of the alkoxysiloxanes, to a process for the preparation thereof and to the use thereof.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: April 26, 2011
    Assignee: Evonik Goldschmidt GmbH
    Inventors: Bernd Weyershausen, Stefan Stadtmueller, Markus Roos, Frank Koenig
  • Publication number: 20110056411
    Abstract: A process for the preparation of a cement material for cementing. The process comprises adding to a cement material comprising cement and water a precondensate of at least one hydrolysable organosilane and, optionally, (nanoscale) particles.
    Type: Application
    Filed: December 9, 2008
    Publication date: March 10, 2011
    Applicant: EPG (ENGINEERED NANOPRODUCTS GERMANY) AG
    Inventors: Christian Schmidt, Klaus Endres, Helmut Schmidt
  • Patent number: 7879146
    Abstract: A controlled release formulation for a cement-based composition can be produced by intercalating an admixture (e.g. an accelerator, a set retarder, a superplasticizer) for the cement-based composition into a layered inorganic material (e.g. a layered double hydroxide (LDH)). A cement-based composition containing a cement-based material (e.g. cement, mortar or concrete) and such a controlled release formulation has better workability, especially in respect of slump-loss characteristics. With such a formulation release of an admixture in a cement-based composition may be controlled.
    Type: Grant
    Filed: July 27, 2006
    Date of Patent: February 1, 2011
    Assignee: National Research Council of Canada
    Inventors: Laila Raki, James J. Beaudoin
  • Patent number: 7833341
    Abstract: The invention provides modified sulphur comprising sulphur and a polysulphide-containing organosilane in an amount of in the range of from 0.3 to 25 wt % based on the weight of sulphur, in which modified sulphur the combined amount of sulphur and polysulphide-containing organosilane make up in the range of from 90 to 100 wt % of the obtained modified sulphur and wherein the polysulphide-containing organosilane is of the general molecular formula (1): (X3Si)mH(2n+1?m)Cn-Sa-Cn?H(2n?+1?m?)(SiX?3)m?; wherein a is an integer in the range of from 2 to 8, X and X? each are, independently, a hydrolysable group, n and n? each are, independently, an integer in the range of from 1 to 4, and m and m? each are, independently, an integer in the range of from 1 to (2n+1). The invention further provides a process for preparing such modified sulphur, a sulphur cement product comprising the modified sulphur and a process for preparing such.
    Type: Grant
    Filed: June 4, 2008
    Date of Patent: November 16, 2010
    Assignee: Shell Oil Company
    Inventors: Jany Birgitta Maria Antens, Denka Georgieva Hristova, Cornelis Hamelink, Guy Lode Magda Maria Verbist
  • Patent number: 7815730
    Abstract: Polymerization of siloxane is improved using a gypsum-based slurry that includes stucco, Class C fly ash, magnesium oxide and an emulsion of siloxane and water. This slurry is used in a method of making water-resistant gypsum articles that includes making an emulsion of siloxane and water, then combining the slurry with a dry mixture of stucco, magnesium oxide and Class C fly ash. The slurry is then shaped as desired and the stucco is allowed to set and the siloxane polymerizes. The resulting product is useful for making a water-resistant gypsum panel having a core that includes interwoven matrices of calcium sulfate dihydrate crystals and a silicone resin, where the interwoven matrices have dispersed throughout them a catalyst comprising magnesium oxide and components from a Class C fly ash.
    Type: Grant
    Filed: June 4, 2009
    Date of Patent: October 19, 2010
    Assignee: United States Gypsum Company
    Inventors: Xuming Wang, Qingxia Liu, Paul Reed, Qiang Yu
  • Publication number: 20100242807
    Abstract: The present invention provides a sulphur cement pre-composition, comprising sulphur and at least a polysulphide-containing organosilane in an amount of at least 0.3 wt % based on the weight of the total composition, which polysulphide-containing organosilane is of the general molecular formula: (X3Si)mH(2n+1?m)Cn—Sa—Cn?H(2n?+1?m?) (SiX?3)m? (1) wherein a is an integer in the range of from 2 to 8, X and X? each are, independently, a hydrolysable group, n and n? each are, independently, an integer in the range of from 1 to 4, and m and m? each are, independently, an integer in the range of from 1 to (2n+1). The invention further provides a process for preparing such sulphur cement pre-composition, a process for the preparation of sulphur cement or sulphur cement-aggregate composite, a sulphur cement or a sulphur cement-aggregate composite and the use of such sulphur cement pre-composition.
    Type: Application
    Filed: June 4, 2008
    Publication date: September 30, 2010
    Inventors: Jochem Okke Boer, Cornelis Hamelink, Guy Lode Magda Maria Verbist
  • Patent number: 7803226
    Abstract: Polymerization of siloxane is improved using a gypsum-based slurry that includes stucco, Class C fly ash, magnesium oxide and an emulsion of siloxane and water. This slurry is used in a method of making water-resistant gypsum articles that includes making an emulsion of siloxane and water, then combining the slurry with a dry mixture of stucco, magnesium oxide and Class C fly ash. The slurry is then shaped as desired and the stucco is allowed to set and the siloxane polymerizes. The resulting product is useful for making a water-resistant gypsum panel having a core that includes interwoven matrices of calcium sulfate dihydrate crystals and a silicone resin, where the interwoven matrices have dispersed throughout them a catalyst comprising magnesium oxide and components from a Class C fly ash.
    Type: Grant
    Filed: July 29, 2005
    Date of Patent: September 28, 2010
    Assignee: United States Gypsum Company
    Inventors: Xuming Wang, Qingxia Liu, Paul Reed, Qiang Yu
  • Publication number: 20100218704
    Abstract: The invention provides modified sulphur comprising sulphur and a polysulphide-containing organosilane in an amount of in the range of from 0.3 to 25 wt % based on the weight of sulphur, in which modified sulphur the combined amount of sulphur and polysulphide-containing organosilane make up in the range of from 90 to 100 wt % of the obtained modified sulphur and wherein the polysulphide-containing organosilane is of the general molecular formula (1): (X3Si)mH(2n+1?m)Cn-Sa-Cn?H(2n?+1?m?)(SiX?3)m?; wherein a is an integer in the range of from 2 to 8, X and X? each are, independently, a hydrolysable group, n and n? each are, independently, an integer in the range of from 1 to 4, and m and m? each are, independently, an integer in the range of from 1 to (2n+1). The invention further provides a process for preparing such modified sulphur, a sulphur cement product comprising the modified sulphur and a process for preparing such.
    Type: Application
    Filed: June 4, 2008
    Publication date: September 2, 2010
    Inventors: Jany Birgitta Maria Antens, Hristova Georgieva Denka, Hamelink Cornelis, Verbist Guy Lode Magda Maria
  • Publication number: 20100212549
    Abstract: The present invention concerns a method for preparing materials containing binder systems derived from amorphous silica and bases as well as the materials prepared by the method. Relative to known methods, the present invention allows for a continuous production of material as the two components of the binder are brought onto into contact where the binder system is to be applied. The product achieved by the invention has a broad range of applications, such as for construction materials, insulating materials, fire proof materials, reinforcement materials etc. The present invention also relates to a method for preparing materials containing binder systems derived from amorphous inorganic material and bases as well as the materials prepared by the method.
    Type: Application
    Filed: January 22, 2010
    Publication date: August 26, 2010
    Inventors: Kjeld HOLBEK, Erik Gydesen Sogaard
  • Publication number: 20100154682
    Abstract: The present invention relates to cement-containing compositions which are characterized in that they have a proportion of organosilicon compounds of greater than 0.15% by weight, based on the proportion of cement, the organosilicon compounds being based on at least one organosilicon compound selected from the group consisting of the alkoxysilanes and at least one selected from the group consisting of the alkoxysiloxanes, to a process for the preparation thereof and to the use thereof.
    Type: Application
    Filed: December 18, 2009
    Publication date: June 24, 2010
    Applicant: EVONIK GOLDSCHMIDT GMBH
    Inventors: Bernd Weyershausen, Stefan Stadtmueller, Markus Roos, Frank Koenig
  • Publication number: 20100147195
    Abstract: Embodiments of the invention provide cement and concrete admixtures and mixes, and CMUs made therewith that provide improved water resistance. Embodiments provide methods for making the admixtures, the mixes and the CMUs.
    Type: Application
    Filed: December 7, 2009
    Publication date: June 17, 2010
    Applicant: ACM Chemistries, Inc.
    Inventors: Craig Thomas WALLOCH, Theodore George Light, Marshall Lee Brown
  • Publication number: 20100132593
    Abstract: Disclosed is a cement material comprising a powder of a calcium salt having inositol phosphate and/or a salt thereof adsorbed on its surface, wherein the powder has a specific surface area of 60 to 120 m2/g. Also disclosed is a process for producing a cement material, comprising the steps of: mixing a solution containing a calcium ion and adjusted to an alkaline pH value with a solution containing a phosphate ion to produce a precipitate; aging the system containing the precipitate to produce a powder of the calcium salt: collecting and drying the powder of the calcium salt; and immersing the dried powder of the calcium salt in a solution of inositol phosphate and/or a salt thereof to cause the adsorption of the inositol phosphate and/or the salt thereof onto the surface of the powder of the calcium salt.
    Type: Application
    Filed: September 18, 2007
    Publication date: June 3, 2010
    Applicant: MEIJI UNIVERSITY
    Inventors: Mamoru Aizawa, Yukiko Horiguchi
  • Patent number: 7678193
    Abstract: The invention relates to the use of lithium glycerophosphate for treating structures made of a cement-based product and having steel rebars, making it possible to inhibit rebar corrosion, to prevent the alkali reaction and to avoid the presence of alkalis and sulfates in the structure.
    Type: Grant
    Filed: March 30, 2004
    Date of Patent: March 16, 2010
    Assignee: Arts Technology S.A.
    Inventors: Theophil Markus Lutz, Christian Chevret