Boron, Sulfur, Or Halogen Containing (e.g., Alum, Etc.) Patents (Class 106/815)
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Patent number: 12103894Abstract: A polymer masonry unit is disclosed that can include a polymer added to a quarry byproduct to manufacture a quality brick unit. The present disclosure solves the technological problem of providing a structurally sound brick or concrete alternative without the need for kiln firing, using traditionally unusable waste material. By combining quarry byproduct and a polymer, a polymer masonry unit can be fabricated having compressive strength and architectural utility. In one exemplary embodiment, fiber elements can be added to the byproduct and polymer mixture to increase structural stability. The present disclosure improves the performance of the system itself by providing a basic block or brick unit using an environmentally responsible manufacturing process that reduces cost and waste. The manufacturing process includes a polymer/base material that can be poured into molds that cures over a predetermined period, without the need for kiln firing.Type: GrantFiled: August 24, 2021Date of Patent: October 1, 2024Assignee: Lithic Industries Holding Co.Inventors: Todd Denton, Michael Doty, Griffith J. Williams, Samuel Lopez, Kameron Anthony Hill, Jonathan Ross, Dyllon Hagan, Timothy James Kennedy
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Patent number: 12037286Abstract: There is described a high-strength concrete generally having: about 100 parts by weight of cement; about 60 to about 360 parts by weight of fine aggregates; about 90 to about 230 parts by weight of mineral powder having a diameter D50 below 150 ?m; about 0.1 to about 25 parts by weight of superplasticizer; and about 20 to about 65 parts by weight of water, the high-strength concrete has a cement content less than about 500 kg/m3 and having a compressive strength after 28 curing days of about 55 MPa or greater.Type: GrantFiled: January 5, 2023Date of Patent: July 16, 2024Assignee: UNIVERSITE LAVALInventors: Luca Sorelli, David Bouchard
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Patent number: 11845696Abstract: A dry construction composition is easily wet-sprayable by means of a screw pump, thus forming, after hardening, a durably mechanically resistant insulating material (?<0.1 W·m?1·K?1). The composition contains: —A— at least one binder, itself including: —A1— at least one main binder containing lime and/or at least one alumina source and/or at least one calcium sulfate source, preferably at least one alumina source, —A2— at least one water-retaining agent, and —A3— preferably at least one surfactant; and —B— at least one biosourced filler, preferably of plant origin. The ratio B/A (liters/kg) is between 2 and 9. The composition is intended to be mixed with water in a water/binder ratio —A— of no lower than 0.8. Also disclosed is a wet composition, the preparation thereof, to the binder —A— taken in isolation, and to a method of spraying the composition onto a horizontal or vertical substrate or by molding.Type: GrantFiled: November 3, 2016Date of Patent: December 19, 2023Assignee: PAREXGROUP SAInventors: Marco Cappellari, Lisa Desroses, Anne Daubresse
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Patent number: 11608296Abstract: A polymer-based compound, useful as a polymer masonry unit is disclosed that can include a polymer added to a quarry byproduct to manufacture a quality brick unit. The present disclosure solves the technological problem of providing a structurally sound brick or concrete alternative without the need for kiln firing, using traditionally unusable waste material. By combining quarry byproduct and a polymer, a polymer masonry unit can be fabricated having compressive strength and architectural utility. In one exemplary embodiment, fiber elements can be added to the byproduct and polymer mixture to increase structural stability. The present disclosure improves the performance of the system itself by providing a basic block or brick unit using an environmentally responsible manufacturing process that reduces cost and waste. The manufacturing process includes a polymer/base material that can be poured into molds that cures over a predetermined period, without the need for kiln firing.Type: GrantFiled: February 22, 2022Date of Patent: March 21, 2023Assignee: Lithic Industries Holding Co.Inventors: Todd Denton, Michael Doty, Griffith J. Williams, Samuel Lopez, Kameron Anthony Hill, Jonathan Ross, Dyllon Hagan, Timothy James Kennedy
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Patent number: 11286211Abstract: The present application relates to a setting and hardening accelerator for a cement, mortar or concrete composition, optionally comprising cement replacement materials (CSMs). The accelerator composition comprises an aqueous nitrate solution and an alkaline hydroxide. Particularly, the aqueous accelerator composition comprises between 30 and 55 w/w % of a nitrate salt as a nitrate solution and between 0.02 and 0.1 w/w % of an alkaline hydroxide, which is dissolved in the nitrate solution and, optionally, as a hydroxide precipitate in the accelerator composition, wherein the accelerator composition has a pH of at least 9.0. In case the cement, mortar or concrete composition comprises CSMs, the accelerator composition has a pH of at least 12.0.Type: GrantFiled: March 5, 2019Date of Patent: March 29, 2022Assignee: YARA INTERNATIONAL ASAInventors: Wolfram Franke, Hilde Thommesen
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Patent number: 9034099Abstract: The present invention relates to a novel cement which makes possible the preparation of concrete, grout or mortar which is resistant to internal sulfate reactions and to external sulfate attacks, and also the use of this cement for the preparation of concrete, grout or mortar.Type: GrantFiled: November 24, 2011Date of Patent: May 19, 2015Assignee: VICATInventors: Laetitia Bessette, Francois Hue, Martine Pasquier
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Patent number: 9011597Abstract: A method for preparing a composite material from a waste appearing as sludge is provided. The method comprises a step consisting in putting said waste appearing as sludge in contact with a dry cement mixture. Also provided are the thereby obtained composite material and the use of such a method for treating and/or inertizing wastes and notably industrial and/or radioactive wastes.Type: GrantFiled: January 18, 2011Date of Patent: April 21, 2015Assignee: Commissariat a l'Energie Atomique et aux Energies AlternativesInventors: Véronique Pauchon, Pascal Antonucci, Nadège Cedat
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Patent number: 9011596Abstract: The present invention provides a method for producing a cured article of a hydraulic composition, prepared by mixing glycerol, cement and water, the hydraulic composition containing a sulfate ion, the method including step 1 of preparing the hydraulic composition such that a molar ratio of the sulfate ion to the glycerol, sulfate ion/glycerol, is 5.0 to 20 and the content of the sulfate ion is 3.0 to 15 parts by weight to 100 parts by weight of cement; and step 2 of aging and curing the hydraulic composition obtained in the step 1.Type: GrantFiled: March 26, 2012Date of Patent: April 21, 2015Assignee: Kao CorporationInventors: Yusuke Yoshinami, Toshimasa Hamai, Hiroyuki Kawakami, Yohei Yoshikawa
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Publication number: 20150096470Abstract: Provided herein are compositions, methods, and systems for a material containing metastable carbonate and stabilizer. Methods for making the compositions and using the compositions are also provided.Type: ApplicationFiled: December 10, 2014Publication date: April 9, 2015Inventors: MIGUEL FERNANDEZ, IRVIN CHEN, PATRICIA TUNG LEE, MATTHEW GINDER-VOGEL
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Patent number: 8859719Abstract: Use of a non-ionic surfactant in the preparation of modified sulfur and/or modified sulfur cement that may or may not be modified sulfur concrete.Type: GrantFiled: April 21, 2009Date of Patent: October 14, 2014Assignee: United Arab Emirates UniversityInventors: Abdel-Mohsen Onsy Mohamed, Maisa Mabrouk El Gamal
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Publication number: 20140283712Abstract: The present invention relates to the production of a ternesite-belite-calcium sulfoaluminate (ferrite) clinker. The invention also relates to the use of alternative raw materials for clinker production, for example raw materials based on industrial byproducts, including those of low quality, such as lump slag and ash having a low glass content and/or a high free lime content and/or a high content of crystalline high-temperature phases, as well as naturally occurring rocks and rock glasses of comparative chemical composition.Type: ApplicationFiled: July 16, 2012Publication date: September 25, 2014Applicant: HEIDELBERGCEMENT AGInventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha
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Publication number: 20140238274Abstract: The present invention relates to a method for accelerating the hardening of hydraulic or latent hydraulic binders, wherein ternesite and an aluminum component are added to the binder, and relates to an additive that increasing early strength for hydraulic or latent hydraulic binders that contain ternesite and a non-hydraulically reactive aluminum component, and relates to the use of an additive comprising ternesite and an aluminum component for the purpose of accelerating the hardening of hydraulic or latent hydraulic binders.Type: ApplicationFiled: July 16, 2012Publication date: August 28, 2014Applicant: HEIDELBERGCEMENT AGInventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha
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Publication number: 20140230697Abstract: The present invention relates to a ternesite calcium sulfoaluminate clinker as well as a ternesite clinker containing 20 to 100% by weight of C5S2$ and less than 15% by weight of C4A3$, as well as the use of ternesite as an additive to calcium sulfoaluminate (ferrite) (belite) (CSA(F)(B)) clinker, calcium sulfoaluminate (ferrite) (belite) cement, and calcium sulfoaluminate (ferrite) (belite) binder containing 10 to 90% by weight of CSA(F)(B) and 90 to 10% by weight of ternesite.Type: ApplicationFiled: July 16, 2012Publication date: August 21, 2014Applicant: HEIDELBERGCEMENT AGInventors: Frank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha, Barbara Batog, Maciej Zajac
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Patent number: 8808451Abstract: The invention relates to a reducing agent for the soluble chromate content of cement and to methods for the production thereof, which comprise concentrating an used sulfuric acid, containing iron (II) sulfate, and separating the sulfuric acid from the obtained precipitate which contains iron (II) sulfate.Type: GrantFiled: February 13, 2012Date of Patent: August 19, 2014Assignee: Crenox GmbHInventors: Michael Vössing, Auer Gerhard, Benno Laubach, Detlef Klein, Werner Schuy, Klaus Köllisch, Erwin Weiss, Werner Bahl, Philip Reese
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Patent number: 8758212Abstract: A sulfur-sand limestone mortar and methods of preparing the sulfur-sand limestone mortar and disposing of elemental sulfur, are disclosed. In embodiments, the sulfur-sand limestone mortar includes elemental sulfur, limestone powder, and sand. Modifiers, such as plasticizers, are not required and are not used in embodiments of the sulfur-sand limestone mortar. In embodiments of the method to prepare the sulfur-sand limestone mortar, each of the elemental sulfur, limestone powder, and sand are heated to at least 140 C, then combined, and then allowed to solidify.Type: GrantFiled: January 28, 2013Date of Patent: June 24, 2014Assignees: Saudi Arabian Oil Company, King Fahd University of Petroleum and MineralsInventors: Mohammed Al-Mehthel, Mohammed Maslehuddin, Saleh Al-Idi, Mohammed Rizwan Ali, Mohammed Salihu Barry
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Patent number: 8753444Abstract: Reinforced sulphur concrete wherein one or more metal reinforcing members are in contact with sulphur concrete is disclosed. The reinforced sulphur concrete comprises an adhesion promoter that enhances the interaction between the sulphur and the one or more metal reinforcing members.Type: GrantFiled: October 26, 2011Date of Patent: June 17, 2014Assignee: Shell Oil CompanyInventors: Juedu Austine, Yiu Chung Cheng, Michael David Lankshear, Cees Weijers
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Patent number: 8741058Abstract: By-product materials are processed to mitigate undesirable effects. In some embodiments, industrial waste by-products are recycled using calcium polysulfide and used in building materials. In certain implementations, toxins are rendered non-viable as human pathogens by reaction with calcium polysulfide to create non-soluble sulfide crystals locked in the material as hydration is completed. The sulfides are not soluble in water and are locked into position within the resulting hydrate material, which mitigates escape of or changes of state in the toxins.Type: GrantFiled: March 13, 2013Date of Patent: June 3, 2014Inventors: James Theodore Easton, James A. Papp
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Publication number: 20140048265Abstract: A lightweight cross-linked gelled settable cement fluid system derived by pre-hydrating a water gelling agent, and then using that to mix with a cement blend which results in a very stable cement blend, which will matriculate through any fluid and not disperse, and form a cohesive plug wherever it comes to rest; wherein the fluid is injected at the bottom of the 10 pound/gal brine, and the fluid rises to the top of the brine where it reforms into a cohesive plug and hardens; and wherein the fluid can be applied to any density solution, and provide stability and cohesiveness to any settable plug; and wherein the cement/gelled water mixture is then cross-linked using standard hydraulic fracturing cross-linkers to provide a stable structure and ability to matriculate through another fluid and not disperse into that fluid.Type: ApplicationFiled: July 17, 2013Publication date: February 20, 2014Inventors: N. Kyle Combs, Larry Watters, Fred Sabins
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Patent number: 8652251Abstract: A sulfur-steel slag aggregate concrete, and methods of preparing the sulfur-steel slag aggregate concrete and disposing of elemental sulfur, are disclosed. In embodiments, the sulfur-steel slag aggregate concrete includes elemental sulfur, steel slag aggregate, limestone powder, and sand. Modifiers, such as plasticizers, are not required and are not used in embodiments of the sulfur-sand limestone mortar. In embodiments of the method to prepare the sulfur-steel slag aggregate concrete, each of the elemental sulfur, limestone powder, steel-slag, and sand are heated to at least 140 C, then combined, and then allowed to solidify.Type: GrantFiled: January 28, 2013Date of Patent: February 18, 2014Assignee: Saudi Arabian Oil CompanyInventors: Mohammed Al-Mehthel, Mohammed Maslehuddin, Saleh Al-Idi, Mohammed Rizwan Ali, Mohammed Salihu Barry
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Patent number: 8647431Abstract: A catalyst composition for pozzolan compositions, includes: a) one or more chlorides, selected from the group consisting of: sodium chloride, potassium chloride, magnesium chloride, calcium chloride, strontium chloride, barium chloride and/or ammonium chloride, preferably ammonium chloride; b) aluminum chloride, and c) one or more metal oxides, preferably selected from the group consisting of: oxides from metals from Group II of the Periodic Table, oxides from metals from Group VIII B of the Periodic Table (e.g. iron oxide), more preferably oxides from metals from Group II of the Periodic Table, even more preferably magnesium oxide or calcium oxide, most preferably magnesium oxide. The use of the catalytic composition for addition to cement for oil well cementing, and for lowering the pH of cement, a method for obtaining a composition for reinforcing cement, a binder composition and a construction composition are also described.Type: GrantFiled: August 15, 2012Date of Patent: February 11, 2014Assignee: MEGA-TECH Holding B.V.Inventor: Robin De La Roij
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Publication number: 20140033954Abstract: An activator composition, in particular suitable for activating latent hydraulic and/or pozzolanic materials in binder compositions, includes: a first component A, including an alkali metal salt and/or an earth alkali metal salt; a second component B, including a metal sulfate; optionally, a third component C, suitable for accelerating the hardening of a hydraulic binder material; and optionally, a filler material; with at least the components A, B and C, if present, being chemically different.Type: ApplicationFiled: March 22, 2012Publication date: February 6, 2014Applicant: SIKA TECHNOLOGY AGInventors: Robert Flatt, Christophe Guyot, Pascal Bailleul
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Patent number: 8623135Abstract: A method of cementing in a subterranean formation comprising the steps of: (A) introducing a cement composition into the subterranean formation, the cement composition comprising: (i) cement; (ii) water; and (iii) a high-density additive selected from the group consisting of silicon carbide, sintered bauxite, and any combination thereof, wherein the cement composition has a density of at least 16 pounds per gallon; and (B) allowing the cement composition to set. According to an embodiment, the high-density additive is in a concentration of at least 30% by weight of the cement. A cement composition for use in an oil or gas well comprises: (A) cement; (B) water; and (C) a high-density additive selected from the group consisting of silicon carbide, sintered bauxite, and a combination thereof, wherein the high-density additive is in a concentration of at least 30% by weight of the cement, and wherein the cement composition has a density of at least 16 pounds per gallon.Type: GrantFiled: February 7, 2013Date of Patent: January 7, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Rahul Chandrakant Patil, Sandip Prabhakar Patil, Keith Armstrong
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Publication number: 20140000490Abstract: A catalyst composition for pozzolan compositions, includes: a) one or more chlorides, selected from the group consisting of: sodium chloride, potassium chloride, magnesium chloride, calcium chloride, strontium chloride, barium chloride and/or ammonium chloride, preferably ammonium chloride; b) aluminum chloride, and c) one or more metal oxides, preferably selected from the group consisting of: oxides from metals from Group II of the Periodic Table, oxides from metals from Group VIII B of the Periodic Table (e.g. iron oxide), more preferably oxides from metals from Group II of the Periodic Table, even more preferably magnesium oxide or calcium oxide, most preferably magnesium oxide. The use of the catalytic composition for addition to cement for oil well cementing, and for lowering the pH of cement, a method for obtaining a composition for reinforcing cement, a binder composition and a construction composition are also described.Type: ApplicationFiled: August 15, 2012Publication date: January 2, 2014Applicant: MEGA-TECH HOLDING B.V.Inventor: Robin DE LA ROIJ
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Patent number: 8568528Abstract: The present invention relates to a novel iron-doped sulphoaluminate-belite clinker, a process for preparing this clinker, and also the use of the clinker for the preparation of hydraulic binder and, consequently, of grout, concrete or mortar.Type: GrantFiled: July 20, 2011Date of Patent: October 29, 2013Assignee: VicatInventors: Laury Barnes-Davin, Pascal Meric, Michel Pasquier, Guy Beauvent
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Patent number: 8523999Abstract: Masses for obtaining poured concrete, concrete for bricks, concrete for tiles or mortar are known, in which Portland cement and Colemanite, water and additives to regulate the process are involved as aggregate. The invention achieves a remarkable increase in the capacity of neutron radiation protection of the material. For this, Portland cement is replaced by Alumina cement and a new component is inserted into the mass, specifically anhydrous calcium sulfate, the Colemanite staying as aggregate.Type: GrantFiled: July 5, 2012Date of Patent: September 3, 2013Assignee: Arraela, S. L.Inventor: Juan Manuel Caruncho Rodado
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Patent number: 8512469Abstract: The method of production of polymeric construction material from flotation waste originating from copper ore flotation and waste sulfur is described. The method includes mixing of 20-50% by weight of waste sulfur which is combined with 10-50% by weight of flotation waste from flotation of copper ore and 3-25% by weight of waste phosphogypsum as pH regulator. Finally, 10-40% by weight of mineral filler is added. The mixing occurs at a temperature of 130-150 degrees Celsius and the mixing lasts for about 30 minutes with rotational speed of an agitator of 20 rpm.Type: GrantFiled: November 2, 2010Date of Patent: August 20, 2013Inventors: Wlodzimierz Myslowski, Andrzej Janiczek
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Publication number: 20130145970Abstract: A method of cementing in a subterranean formation comprising the steps of: (A) introducing a cement composition into the subterranean formation, the cement composition comprising: (i) cement; (ii) water; and (iii) a high-density additive selected from the group consisting of silicon carbide, sintered bauxite, and any combination thereof, wherein the cement composition has a density of at least 16 pounds per gallon; and (B) allowing the cement composition to set. According to an embodiment, the high-density additive is in a concentration of at least 30% by weight of the cement. A cement composition for use in an oil or gas well comprises: (A) cement; (B) water; and (C) a high-density additive selected from the group consisting of silicon carbide, sintered bauxite, and a combination thereof, wherein the high-density additive is in a concentration of at least 30% by weight of the cement, and wherein the cement composition has a density of at least 16 pounds per gallon.Type: ApplicationFiled: February 7, 2013Publication date: June 13, 2013Applicant: Halliburton Energy Services, Inc.Inventor: Halliburton Energy Services, Inc.
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Publication number: 20130118384Abstract: The present invention relates to a novel iron-doped sulphoaluminate-belite clinker, a process for preparing this clinker, and also the use of the clinker for the preparation of hydraulic binder and, consequently, of grout, concrete or mortar.Type: ApplicationFiled: July 20, 2011Publication date: May 16, 2013Applicant: VICATInventors: Laury Barnes-Davin, Pascal Meric, Michel Pasquier, Guy Beauvent
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Patent number: 8435342Abstract: A concrete composition comprising a mouldable mixture of aggregate, binder and liquid vehicle, wherein the aggregate comprises sulphur concrete-derived aggregate and wherein the binder comprises hydraulic binder. The use of crushed sulphur concrete as aggregate in cement-based concrete reduces the hardening time of the concrete.Type: GrantFiled: December 15, 2010Date of Patent: May 7, 2013Assignee: Shell Oil CompanyInventors: Marwa Al-Ansary, Parilakathoottu Aboobacker Sunifar, Guy Lode Magda Maria Verbist
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Publication number: 20130061780Abstract: A method for preparing a composite material from a waste appearing as sludge is provided. The method comprises a step consisting in putting said waste appearing as sludge in contact with a dry cement mixture. Also provided are the thereby obtained composite material and the use of such a method for treating and/or inertizing wastes and notably industrial and/or radioactive wastes.Type: ApplicationFiled: January 18, 2011Publication date: March 14, 2013Applicant: Commissariat a l'energie atomique et aux energies alternativesInventors: Véronique Pauchon, Pascal Antonucci, Nadège Cedat
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Publication number: 20130052150Abstract: Method of reducing the odour of sulphur-bound products, in particular modified sulphur or sulphur concrete, comprising contacting the sulphur-bound products with a bleaching agent, like e.g. sodium hydrochloride or hydrogen peroxide. The resulting sulphur-bound products emit reduced levels of sulphur-containing gases such as H2S and SO2 and have a reduced odour.Type: ApplicationFiled: December 5, 2010Publication date: February 28, 2013Inventors: Gyula Imre Dreisziger, Cornelis Pieter Hamelink, Guy Lode Magda Maria Verbist
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Patent number: 8361220Abstract: A strength improvement admixture composition is provided that increases the compressive strength of cementitious compositions without negatively increasing the setting time. The admixture comprises the components of a polycarboxylate dispersant, a set retarder, and a strength improvement additive.Type: GrantFiled: July 31, 2012Date of Patent: January 29, 2013Assignee: Construction Research & Technology GmbHInventors: Jeffrey R. Bury, Thomas M. Vickers, Jr., Bruce J. Christensen
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Publication number: 20130000524Abstract: This burned cement clinker is a burned cement clinker including at least one selected from the group consisting of fluorine, sulfur, chlorine and bromine, and at least one metallic element(s) selected from the group consisting of elements in groups 3 through 12 of the periodic table. Preferably, the amount of fluorine is within a range from 300 to 750 mg/kg, the amount of sulfur (expressed in terms of SO3) is within a range from 1.5 to 3.0% by mass, the amount of at least one chlorine equivalent(s) selected from the group consisting of chlorine and bromine is within a range from 150 to 350 mg/kg, and the amount of at least one metallic element selected from the group consisting of elements in groups 3 through 12 of the periodic table is within a range from 0.2 to 0.8% by mass.Type: ApplicationFiled: March 11, 2011Publication date: January 3, 2013Inventors: Makio Yamashita, Yoichiro Nakanishi, Hisanobu Tanaka
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Patent number: 8273175Abstract: PVC compositions, concrete composition including the PVC compositions, and reinforced concrete structures that contain the concrete compositions are described. Methods for manufacturing the reinforced concrete structures of the present technology, methods for repairing reinforced concrete structures having corroded rebar, and methods for reducing rebar corrosion in reinforced concrete structures are also described.Type: GrantFiled: January 26, 2011Date of Patent: September 25, 2012Assignee: Empire Technology Development, LLCInventor: Sung-Wei Chen
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Patent number: 8258210Abstract: A strength improvement admixture composition is provided that increases the compressive strength of cementitious compositions without negatively increasing the setting time. The admixture comprises the components of a polycarboxylate dispersant, a set retarder, and a strength improvement additive.Type: GrantFiled: February 26, 2004Date of Patent: September 4, 2012Assignee: Construction Research & Technology GmbHInventors: Jeffrey R. Bury, Thomas M. Vickers, Jr., Bruce J. Christensen
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Publication number: 20120216720Abstract: Methods for preventing, reducing, or eliminating construction heave, expansion, distresses, and damage primarily caused by the formation of ettringite are disclosed including introducing fluoride ion releasing agent/salt(s), such as sodium fluoride, calcium fluoride, and potassium fluoride, to expansive soil layers or concrete structural elements and allowing the fluoride ion releasing agent/salt(s) at ambient temperature to react with formed ettringite and to prevent the formation of ettringite of the expansive soil layers or concrete structural elements. Other embodiments are described and claimed.Type: ApplicationFiled: May 10, 2012Publication date: August 30, 2012Applicant: AMERICAN ACCUTECH LTD. CO.Inventors: Yun Deng, Lianxiang Du
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Patent number: 8246742Abstract: The invention concerns an accelerator mixture which contains aluminum in oxidation state 3, sulphate and hexafluorosilicic acid, a process for the preparation of said accelerators and the use of said accelerators for the coating of substrates with concrete or mortar. Furthermore the invention relates to concrete or mortar containing accelerators according to the invention and the hardened layers produced by applying the accelerators to concrete or mortar. The invention relates also to the use of hexafluorosilicic acid as a stabilizer.Type: GrantFiled: December 3, 2009Date of Patent: August 21, 2012Assignee: Construction Research & Technology GmbHInventors: Elena Kolomiets, Montserrat Alfonso, Martin Weibel
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Publication number: 20120204764Abstract: A wellbore servicing method comprises converting a water into an electrochemically activated water, preparing a wellbore servicing composition comprising the electrochemically activated water, and placing the wellbore servicing composition in a wellbore. Also, cement composition comprises a cement and an electrochemically activated water.Type: ApplicationFiled: April 24, 2012Publication date: August 16, 2012Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Jim Weaver, Mark Savery, Billy Slabaugh, Roger Cromwell
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Publication number: 20120137934Abstract: The invention relates to a reducing agent for the soluble chromate content of cement and to methods for the production thereof, which comprise concentrating an used sulfuric acid, containing iron (II) sulfate, and separating the sulfuric acid from the obtained precipitate which contains iron (II) sulfate.Type: ApplicationFiled: February 13, 2012Publication date: June 7, 2012Applicant: Kerr-McGee Pigments GmbHInventors: Michael VÖSSING, Gerhard AUER, Benno LAUBACH, Detlef KLEIN, Werner SCHUY, Klaus KÖLLISCH, Erwin WEISS, Werner BAHL, Philip REESE
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Publication number: 20120085266Abstract: The invention concerns an accelerator mixture which contains aluminium in oxidation state 3, sulphate and hexafluorosilicic acid, a process for the preparation of said accelerators and the use of said accelerators for the coating of substrates with concrete or mortar. Furthermore the invention relates to concrete or mortar containing accelerators according to the invention and the hardened layers produced by applying the accelerators to concrete or mortar. The invention relates also to the use of hexafluorosilicic acid as a stabilizer.Type: ApplicationFiled: December 3, 2009Publication date: April 12, 2012Applicant: Construction Research & Technology GMBHInventors: Elena Kolomiets, Montserrat Alfonso, Martin Weibel
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Publication number: 20120073474Abstract: Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.Type: ApplicationFiled: October 21, 2011Publication date: March 29, 2012Inventors: BRENT R. CONSTANTZ, Kasra Farsad, Chris Camire, Joshua Patterson, Matthew Ginder-Vogel, Karin Yaccato, John Stagnaro, Martin Devenney, Justin Ries
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Patent number: 8137456Abstract: The present invention provides a process for the preparation of sulphur cement or a sulphur cement-aggregate composite comprising the following steps: (a) admixing at least an inorganic filler and/or aggregate and a polysulphide-containing organosilane having at least two organosilyl groups and allowing the organosilane to react with the inorganic filler and/or aggregate; (b) admixing during or after step (a) elemental sulphur with the inorganic filler and/or aggregate at a temperature at which sulphur is liquid to obtain an admixture comprising molten sulphur and inorganic filler and/or aggregate; and (c) solidifying the admixture to obtain sulphur cement or a sulphur cement-aggregate composite. The invention further provides sulphur cement or a sulphur cement-aggregate composite obtainable by such process and the use of a polysulphide-containing organosilane having at least two organosilyl groups as coupling agent in sulphur cement or a sulphur cement-aggregate composite.Type: GrantFiled: December 7, 2006Date of Patent: March 20, 2012Assignee: Shell Oil CompanyInventors: Rob Aloysius Maria Van Trier, Guy Lode Magda Maria Verbist
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Patent number: 8075688Abstract: The invention relates to an accelerator, preferably for sprayed concrete or sprayed mortar, which is present as an aqueous mixture, preferably dispersion, particularly preferably suspension, which contains the following: (a) aluminium in oxidation state 3, (b) sulphate, (c) fluoride, and/or (semi)metal fluoro complexes, (d) stabiliser, preferably inorganic stabiliser, particularly preferably magnesium silicate and/or kaolin and/or clay minerals and/or allophane, in particular magnesium silicate and/or bentonite, particularly preferably sepiolite, especially particularly preferably Si12Mg8O30(OH)4(OH2)4 and/or Mg4Si6O15(OH)2.Type: GrantFiled: December 4, 2008Date of Patent: December 13, 2011Assignee: Construction Research & Technology GmbHInventor: Martin Weibel
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Publication number: 20110290156Abstract: CO2-sequestering formed building materials are provided. The building materials of the invention include a composition comprising a carbonate/bicarbonate component. Additional aspects of the invention include methods of making and using the CO2-sequestering formed building material.Type: ApplicationFiled: July 26, 2011Publication date: December 1, 2011Inventors: Brent R. Constantz, Andrew Youngs, Terence C. Holland
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Patent number: 8066807Abstract: Flame-retarding additives that may also have insulating properties are disclosed that include at least one carbonate salt, and at least one additional salt, active ingredient or combination thereof. In addition, methods of forming flame-retarding additives are disclosed that include providing at least one carbonate salt, providing at least one additional salt, active ingredient or combination thereof; and combining the at least one carbonate salt along with the at least one additional salt, active ingredient or combination thereof to form the flame-retarding additive. Flame-retarding additives disclosed may also comprise at least one filler material, including sand or white sand. These additives may also be included in paints and a number of processed building materials.Type: GrantFiled: June 26, 2009Date of Patent: November 29, 2011Inventor: Daniel Adams
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Publication number: 20110054068Abstract: The present invention relates to compositions useful for isolating a portion of a wellbore. In one embodiment, a composition includes a sealant composition containing a wellbore treatment fluid and a set modifier component. The sealant composition can be placed into the wellbore and subjected to ionizing radiation that alters the set modifier component, triggering the setting of the sealant composition.Type: ApplicationFiled: August 25, 2009Publication date: March 3, 2011Inventors: Samuel J. Lewis, James Lynn Davis, Vijay Gupta, Michele Ostraat, David F. Myers, Mike Lamvik, Andrew K. Dummer, Vikram Rao, Lawrence R. Roberts, Anthony Badalamenti
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Publication number: 20110054084Abstract: Hydraulic cement compositions that include a carbonate compound composition, e.g., a salt-water derived carbonate compound composition containing crystalline and/or amorphous carbonate compounds, are provided. Also provided are methods of making and using the hydraulic cements, as well as settable compositions, such as concretes and mortars, prepared therefrom. The cements and compositions produced therefrom find use in a variety of applications, including use in a variety of building materials and building applications.Type: ApplicationFiled: October 20, 2010Publication date: March 3, 2011Inventors: Brent R. Constantz, Cecily Ryan, Laurence Clodic
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Patent number: 7819970Abstract: Provided is a protective concrete for weaken the intensity of proton radiation, and it is prepared by mixing 525# cement 500-700 Kg; barite sand 1000-1400 kg, barite stone 1500-1800 Kg, lead powder 180-200 Kg and water 170-180 Kg. The barite that can absorb the proton radiation is used, so the present concrete is much better than conventional concretes in weakening the proton radiation, and 1.5 m-thick wall without lead plates which is prepared with the present concrete can achieve the same effect on weakening the proton radiation with a conventional 2 m-thick wall covering with lead plates.Type: GrantFiled: July 20, 2007Date of Patent: October 26, 2010Inventors: Yingzhi Lv, Yingren Lv, Yan Lv, Qiang Lv, Yongsheng Gao
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Patent number: 7806183Abstract: Disclosed embodiments relate to well treatment fluids and methods that utilize nano-particles. Exemplary nano-particles are selected from the group consisting of particulate nano-silica, nano-alumina, nano-zinc oxide, nano-boron, nano-iron oxide, and combinations thereof. Embodiments also relate to methods of cementing that include the use of nano-particles. An exemplary method of cementing comprises introducing a cement composition into a subterranean formation, wherein the cement composition comprises cement, water and a particulate nano-silica. Embodiments also relate to use of nano-particles in drilling fluids, completion fluids, stimulation fluids, and well clean-up fluids.Type: GrantFiled: April 20, 2009Date of Patent: October 5, 2010Assignee: Halliburton Energy Services Inc.Inventors: Craig W. Roddy, Jiten Chatterji, Roger Cromwell
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Publication number: 20100229762Abstract: The invention relates to a mass for manufacturing products with a high neutron radioprotection capacity which, like that of any conventional concrete, is structured based on cement or mixture thereof with calcium sulfate (anhydrite), aggregates, water and chemical additives modifying the characteristics of the concrete. According to the invention, said mass uses as an aggregate colemanite and variable parts of borax, with a very continuous grain size to achieve a perfect homogeneity in the mass, determining an optimal barrier effect against neutron radiations, which allows considerably decreasing the wall thickness, without adversely affecting the barrier effect. The mass is suitable for obtaining poured concrete, concrete for bricks, concrete for slabs and dry mortar, which can be used in building radioactive premises such as radiotherapy and brachytherapy bunkers, radiology walls, etc. This concrete has no structural capacity.Type: ApplicationFiled: February 19, 2010Publication date: September 16, 2010Inventor: Juan Manuel Caruncho Rodado