Abstract: Starch derived from a dry milled cereal grain such as corn or milo is hydrolyzed to provide a sterile aqueous fermentable sugar solution which is especially adapted for fermentative conversion to ethanol with minimum thermal expenditure. Following a preliminary acid-catalyzed hydrolysis of the starch to provide a sterile hydrolysate slurry, the slurry is further hydrolyzed in the presence of added aqueous non-fermentable carbohydrate to reequilibrate the hydrolysis reaction in favor of increased production of fermentable sugar, primarily glucose. Substantially all of the water insoluble protein and oil components, and a portion of the water soluble components, e.g., sugars, proteins and vitamins, are separately recovered from the sterile hydrolysate either before or after the further hydrolysis step with the water solubles being recycled to the system to effect reequilibration of a further quantity of hydrolysate.

Abstract: This invention relates to a process for producing cyclodextrins, which comprises passing a solution containing cyclodextrins and reducing sugars as primary ingredients through a column packed with alkali or alkali earth metal salts of strongly acidic cation exchange resin to separate and collect cyclodextrins from the sugar solution.

Abstract: Clear stable gels are made from hydrogenated maltose containing starch hydrolysates having 35-49% maltitol, 11-14% sorbitol, and minor amounts of higher saccharides by the addition of amorphous silica gelling agents. These gels are useful in formulating confections and food specialties.

Abstract: The invention relates to a non-cariogenic hydrogenated starch hydrolysate as well as to a process for preparing it.The starch hydrolysate according to the invention comprises:less than 3% by weight of polyols of DP higher than 20;less than 60% by weight of maltitol (DP 2);less than 19% by weight of sorbitol (DP 1), the balance to 100 being constituted by polyols of DP 3 to 20.This starch hydrolysate can be used in food products as a sweetening non-cariogenic agent.

Abstract: Starch derived from a dry milled cereal grain such as corn or milo is hydrolyzed to provide a sterile aqueous fermentable sugar solution which is especially adapted for fermentative conversion to ethanol with minimum thermal expenditure. Following an initial acid-catalyzed hydrolysis to thin, or liquefy, the starch, substantially all of the water insoluble protein and oil components, and a portion of the water soluble components, e.g., sugars, proteins and vitamins, are separately recovered from the partial starch hydrolysate with the water solubles being recycled to the system. Thereafter, the partial starch hydrolysate is subjected to further hydrolysis in the presence of an acidic cationic exchange resin as catalyst to provide an aqueous solution of fermentable sugar.

Abstract: A continuous process is provided for effecting the acid hydrolysis of whole grains, e.g., corn, at high solids and in an economically desirable manner. The process produces glucose which is readily fermentable to produce ethanol.

Abstract: The processing of barley grain by a series of sequential steps to produce a carbohydrate syrup having a high maltose content, novel protein products, a gluten-like product, a carbohydrate gum, all useful in the food industry, and a fermentable product which can be converted to alcohol. The processing steps comprise conditioning and milling, separation of starches, conversion of starch residues to the syrup and protein products, and recovery of the products and by-products.

Abstract: Hydrolyzed wheat, corn, and potato starches are effective flocculants in destabilizing dilute as well as thick sludge suspensions. These starches are equal to, or better than, the synthetic polyacrylamide flocculants in destabilizing sludge suspensions, particularly when used in the treatment of bituminous tar sands tailings.The hydrolyzed wheat starch is especially effective when first contacted with metal salts such as salts containing calcium, aluminum and phosphate ions and most particularly when first treated with a combination of such salts formed in situ, and a lower aliphatic alcohol.Among the potato starch flocculants which were found to be generally better than the corn starch flocculants, those containing AlPO.sub.4 were the best. Potato starch flocculants are equally effective on oil-removed and no-oil-removed sludge suspensions.

Abstract: Starch derived from dry milled corn is hydrolyzed to provide a sterile aqueous fermentable sugar solution which is especially adapted for fermentative conversion to ethanol with minimum thermal expenditure. Following an initial mild hydrolysis to thin, or liquefy, the starch, substantially all of the water insoluble protein and oil components, and a portion of the water soluble components, e.g., sugars, lipids, proteins and vitamins, are separately recovered from the partial starch hydrolysate with the water solubles being recycled to the system. Thereafter, the partial starch hydrolysate is subjected to further hydrolysis to provide an aqueous solution of fermentable sugar.

Abstract: Methods and apparatus for high-moisture extrusion of starch-bearing grains is disclosed which yield cooked, gelatinized products suitable for short-time enzymatic conversion to sugars, and particularly those subject to fermentation to alcohol; the high production rates afforded through use of extrusion equipment, and the short conversion time of the resultant products, is particularly advantageous for economical alcohol manufacture, both for alcoholic beverages and for use as fuel. Preferably, whole or cracked starch-bearing grain is presoaked in an excess of water to a substantial moisture level, and the resultant slurry is fed to a specialized extruder. In the extruder the water is at least partially separated and carried from the process, and the grain is highly cooked and gelatinized for subsequent conversion.

Abstract: The invention relates to a non-cariogenic hydrogenated starch for confectionery and process for preparing this hydrolysate. This hydrogenated starch hydrolysate comprises a content of polyols of DP higher than 20 which is sufficiently low for the cariogenic character of these polyols not to be troublesome and a content of low molecular weight products, which is sufficiently low for their presence not to interfere with the applicability of said hydrolysates in confectionery. The hydrogenated starch hydrolysate can be used in the manufacture of "hard candies" and chewing gums.

Abstract: An aqueous starch slurry is initially hydrolyzed in the presence of acid or enzyme and thereafter, the liquefied starch is saccharified in the presence of an acid cationic exchange resin to provide a sterile aqueous solution containing at least about 60 weight percent fermentable sugar based on the weight of the original starch present.

Abstract: In the wet milling of a cereal grain such as corn for the recovery of starch and other products therefrom, steepwater containing much of the water soluble components of the grain, e.g., carbohydrates, proteins and minerals, is utilized as process water for each of the individual milling, screening, concentrating and washing operations and the process water is thereafter recycled for use as steepwater in a subsequent starch recovery sequence.

Abstract: A process and apparatus for producing modified starch products. A slurry of starch is continuously moved at elevated temperature and pressure through a tubular heating zone and the hot fluid mass emerging from the heating zone is forced through a flow restricting zone within which the fluid mass is highly compressed. This highly compressed fluid material emerges from the confining zone into a tubular reaction zone with a sudden release of energy in the form of a fine spray or mist. The compressive forces followed by the sudden energy release act on the starch molecules to temporarily greatly increase the reactivity of the starch within the reaction zone, whereby modified starch products are quickly formed.

Abstract: A continuous process for the production of starch hydrolysates, such as corn syrup. The process comprises continuously moving an aqueous acidic starch slurry feed through a confined preheat zone at a pressure of at least 300 psi to raise the temperature of the slurry to at least 100.degree. C., continuously forcing the hot fluid mass emerging from the preheat zone through an elongated compressing zone, continuously receiving the fluid material emerging from the compressing zone in the form of a fine spray or mist including water vapor in a confined zone of reduced pressure and continuously collecting from said reduced pressure zone a homogeneous starch syrup having a higher solids content than the starch slurry feed. The temperature and pressure of the hot fluid mass entering the elongated compressing zone and the acidity of the feed slurry can be controlled to selectively provide syrup products having a wide range of DE values.

Abstract: An amylaceous material having alkaline viscosities in the range of 10 to 20 seconds using a 1.3 g sample and 15 to 20 seconds using a 5.2 g sample and having cold water solubles of between 50% and 98% is made by hydrolysis of starting material such as corn, flour, corn meal, corn grits, corn starch, sorghum flour, sorghum meal and sorghum grits at moistures between 5% and 12%, adjusting the pH of the hydrolyzed amylaceous material to between pH 3 and 6, gelatinizing the pH adjusted hydrolyzed amylaceous material, and removing water from the gelatinized product.

Abstract: A continuous process for the production of starch hydrolysates, such as corn syrup. The process comprises continuously moving an aqueous acidic starch slurry feed containing at least about 35% by weight starch solids through a confined preheat zone at a pressure of at least 300 psi to raise the temperature of the slurry to at least 140.degree. C, continuously forcing the hot fluid mass emerging from the preheat zone through an elongated compressing zone, continuously receiving the fluid material emerging from the compressing zone in the form of a fine spray or mist including water vapor in a confined zone of reduced pressure and continuously collecting from said reduced pressure zone a homogeneous starch syrup having a higher solids content than the starch slurry feed. The temperature and pressure within the elongated compressing zone can be controlled to selectively provide syrup products having a wide range of DE values.

Abstract: Process for depolymerizing starch by irradiation in which granular starch, whose water content is at the most about 23%, is subjected, in the presence of an acid which is neutralized at the end of the treatment, to a dose of radiation which is a function of the nature and of the quantity of the acid used.

Abstract: Process for preparing a thermal converting starch by reacting an alkaline hypochlorite oxidized starch with a water soluble aluminum salt. The treatment provides a starch product which when pasted at high temperatures will degrade to give a low viscosity material. The process includes the steps of slurrying oxidized starch in water and treating the oxidized starch with a water soluble aluminum salt.

Abstract: A multi-step process for producing soluble amylose involving the dissolution and dissociation of amylose in a first organic solvent, the hydrolyzation of amylose into lower molecular weight components, and the use of a second organic solvent to form a precipitate.

Abstract: A starch composition having lower hydroscopicity, lower bulk-density and better film-forming and holding properties than low D.E. dextrins comprising granule starches which have been hydrolyged to a D.E. of less than about 1 with little or no reducing sugars being present while retaining their granule structure and have thereafter been gelatinized.

Abstract: Method for the preparation of starch hydrolysis products containing mixtures having a dextrose equivalent of 5 to 10 which mixtures have the property of forming together with water, white glossy thermoreversible gels having a neutral taste, which gels are stable to freezing and defrosting and the consistency of which gels may be varied from pasty to cutting hard depending upon the proportion of water contained in the gel, comprising mixing two starch products which in the admixture have an average dextrose equivalent of 5 to 10, the starch products being of respective degrees of polymerization differing from the other by at least ten times and each of the starch products being branched and at least one of the starch products being a starch hydrolysis product.

Abstract: Apparatus for carrying out fluidized operations including a housing defining an upper chamber and a lower chamber, with each of the chambers containing agitating means therein to insure a high degree of homogeneity in each of the chambers, a plurality of tubes enclosed in a jacket positioned between the upper and lower chambers and communicating therewith, the tubes providing large heat transfer surfaces, inlet means to supply a fluidizable material to the one chamber and outlet means to remove fluidizable material from the other chamber, and means to supply a fluidizing gas to the lower chamber whereby the fluidizing gas passes upwardly through the lower chamber and through the tubes into the upper chamber while fluidizing the material in each of the upper chamber, the tubes and the lower chamber. The apparatus of the invention is particularly well suited for converting starches to dextrin.