Permanent Magnet Patents (Class 148/101)
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Patent number: 8252123Abstract: A rare earth permanent magnet is prepared by disposing a powdered metal alloy containing at least 70 vol % of an intermetallic compound phase on a sintered body of R—Fe—B system, and heating the sintered body having the powder disposed on its surface below the sintering temperature of the sintered body in vacuum or in an inert gas for diffusion treatment. The advantages include efficient productivity, excellent magnetic performance, a minimal or zero amount of Tb or Dy used, an increased coercive force, and a minimized decline of remanence.Type: GrantFiled: October 27, 2010Date of Patent: August 28, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hiroaki Nagata, Tadao Nomura, Takehisa Minowa
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Patent number: 8231740Abstract: A rare earth permanent magnet material is prepared by covering a sintered magnet body of R1—Fe—B composition wherein R1 is a rare earth element, with a powder comprising at least 30% by weight of an alloy of R2aTbMcAdHe wherein R2 is a rare earth element, T is Fe and/or Co, and M is Al, Cu or the like, and having an average particle size up to 100 ?m, and heat treating the powder-covered magnet body at a suitable temperature, for causing R2, T, M and A in the powder to be absorbed in the magnet body.Type: GrantFiled: April 12, 2007Date of Patent: July 31, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hajime Nakamura, Takehisa Minowa, Koichi Hirota
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Patent number: 8211246Abstract: In one embodiment, a permanent magnet has a composition represented by (Sm1-xRx)(FepMqCurCo1-p-q-r)z, where R is at least one element selected from Nd and Pr, M is at least one element selected from Ti, Zr and Hf, and 0.22?p?0.45, 0.005?q?0.05, 0.01 ?r?0.1, 0.05?x<0.5, and 7?z?9. The permanent magnet includes a Th2Zn17 crystal phase as a main phase, and a ratio of diffraction peak intensity I(113) from a (113) plane of the Th2Zn17 crystal phase in powder X-ray diffraction to diffraction peak intensity I(300) from a (300) plane in powder X-ray diffraction is in a range of 0.9?I(113)/I(300)?1.7.Type: GrantFiled: March 16, 2011Date of Patent: July 3, 2012Assignee: Kabushiki Kaisha ToshibaInventors: Masaya Hagiwara, Shinya Sakurada, Yosuke Horiuchi, Keiko Okamoto, Tsuyoshi Kobayashi, Shiori Kaji
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Patent number: 8206516Abstract: In a method for producing an R—Fe—B based rare-earth sintered magnet according to the present invention, first, provided is an R—Fe—B based rare-earth sintered magnet body including, as a main phase, crystal grains of an R2Fe14B type compound that includes a light rare-earth element RL, which is at least one of Nd and Pr, as a major rare-earth element R. Thereafter, the sintered magnet body is heated while a heavy rare-earth element RH, which is at least one element selected from the group consisting of Dy, Ho and Tb, is supplied to the surface of the sintered magnet body, thereby diffusing the heavy rare-earth element RH into the rare-earth sintered magnet body.Type: GrantFiled: March 1, 2007Date of Patent: June 26, 2012Assignee: Hitachi Metals, Ltd.Inventors: Koshi Yoshimura, Hideyuki Morimoto, Tomoori Odaka
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Patent number: 8187392Abstract: In an R—Fe—B based rare-earth sintered magnet according to the present invention, at a depth of 20 ?m under the surface of its magnet body, crystal grains of an R2Fe14B type compound have an (RL1-xRHx)2Fe14B (where 0.2?x?0.75) layer with a thickness of 1 nm to 2 ?m in their outer periphery. In this case, the light rare-earth element RL is at least one of Nd and Pr, and the heavy rare-earth element RH is at least one element selected from the group consisting of Dy, Ho and Tb.Type: GrantFiled: July 1, 2008Date of Patent: May 29, 2012Assignee: Hitachi Metals, Ltd.Inventors: Koshi Yoshimura, Hideyuki Morimoto, Tomoori Odaka
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Patent number: 8182619Abstract: First, an R—Fe—B based rare-earth sintered magnet body including, as a main phase, crystal grains of an R2Fe14B type compound that includes a light rare-earth element RL, which is at least one of Nd and Pr, as a major rare-earth element R is provided. Next, an M layer, including a metallic element M that is at least one element selected from the group consisting of Al, Ga, In, Sn, Pb, Bi, Zn and Ag, is deposited on the surface of the sintered magnet body and then an RH layer, including a heavy rare-earth element RH that is at least one element selected from the group consisting of Dy, Ho and Tb, is deposited on the M layer. Thereafter, the sintered magnet body is heated, thereby diffusing the metallic element M and the heavy rare-earth element RH from the surface of the magnet body deeper inside the magnet.Type: GrantFiled: July 5, 2011Date of Patent: May 22, 2012Assignee: Hitachi Metals, Ltd.Inventors: Hideyuki Morimoto, Tomoori Odaka, Masao Noumi
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Patent number: 8182618Abstract: A sintered rare-earth magnet includes an Nd2Fe14B type crystalline phase as its main phase and Al as an additive. The magnet includes at least one light rare-earth element LR selected from the group consisting of yttrium and the rare-earth elements other than Dy, Ho and Tb, and at least one heavy rare-earth element HR selected from the group consisting of Dy, Ho and Tb. The mole fractions ?1, ?2 and ? of the light and heavy rare-earth elements LR and HR and Al satisfy the inequalities 25??1+?2?40 mass %, 0<?2?40 mass %, ?>0.20 mass %, and 0.04??/?2?0.12.Type: GrantFiled: November 30, 2006Date of Patent: May 22, 2012Assignee: Hitachi Metals, Ltd.Inventors: Noriyuki Nozawa, Tomoori Odaka, Yutaka Matsuura
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Patent number: 8177921Abstract: An R—Fe—B based rare-earth sintered magnet according to the present invention includes, as a main phase, crystal grains of an R2Fe14B type compound that includes Nd, which is a light rare-earth element, as a major rare-earth element R. The magnet includes a heavy rare-earth element RH (which is at least one of Dy and Tb) that has been introduced through the surface of the sintered magnet by diffusion. The magnet has a region in which the concentration of the heavy rare-earth element RH in a grain boundary R-rich phase is lower than at the surface of the crystal grains of the R2Fe14B type compound but higher than at the core of the crystal grains of the R2Fe14B type compound.Type: GrantFiled: July 25, 2008Date of Patent: May 15, 2012Assignee: Hitachi Metals, Ltd.Inventors: Tomoori Odaka, Hideyuki Morimoto, Kohshi Yoshimura, Shigeru Takaki, Shinichiro Sakashita
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Patent number: 8177922Abstract: An R—Fe—B based anisotropic sintered magnet according to the present invention has, as a main phase, an R2Fe14B type compound that includes a light rare-earth element RL (which is at least one of Nd and Pr) as a major rare-earth element R, and also has a heavy rare-earth element RH (which is at least one element selected from the group consisting of Dy and Tb). In the crystal lattice of the main phase, the c-axis is oriented in a predetermined direction. The magnet includes a portion in which at least two peaks of diffraction are observed within a 2? range of 60.5 degrees to 61.5 degrees when an X-ray diffraction measurement is carried out using a CuK ? ray on a plane that is located at a depth of 500 ?m or less under a pole face of the magnet and that is parallel to the pole face.Type: GrantFiled: September 2, 2008Date of Patent: May 15, 2012Assignee: Hitachi Metals, Ltd.Inventors: Tomoori Odaka, Hideyuki Morimoto, Kohshi Yoshimura, Shigeru Takaki
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Patent number: 8157927Abstract: It is an object of the present invention to obtain a highly coercive R-T-B system sintered magnet by making the crystal microstructure of a raw material alloy prepared by strip casting more uniform, thereby making the crushed powder obtained from such raw material alloy more fine and making the size distribution more narrow. The present invention provides a raw material alloy for an R-T-B system sintered magnet containing grains of an R2T14B compound, wherein a P and/or S content is between 100 and 950 ppm. This raw material alloy preferably has a composition comprising 25 to 35% by weight of R, 0.5 to 4% by weight of B, 0.02 to 0.6% of one or both of Al and Cu, 5% by weight or less of Co, and the balance of Fe.Type: GrantFiled: December 23, 2009Date of Patent: April 17, 2012Assignee: TDK CorporationInventors: Yasushi Enokido, Chikara Ishizaka, Gouichi Nishizawa
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Patent number: 8157926Abstract: There is provided a method of manufacturing a permanent magnet in which Dy and/or Tb adhered to the surface of a sintered magnet containing a lubricant can be efficiently diffused and in which the permanent magnet having high magnetic properties can be manufactured at good productivity. The permanent magnet is manufactured by executing a first step of adhering at least one of Dy and Tb to at least a part of a surface of a sintered magnet made by sintering iron-boron-rare earth based alloy raw meal powder containing a lubricant; and a second step of heat-treating the sintered magnet at a predetermined temperature to thereby disperse at least one of Dy and Tb adhered to the surface of the sintered magnet into grain boundary phase of the sintered magnet. At this time, as the sintered magnet, there is used one manufactured in an average grain size within a range of 4 ?m˜8 ?m.Type: GrantFiled: December 19, 2007Date of Patent: April 17, 2012Assignee: Ulvac, Inc.Inventors: Hiroshi Nagata, Yoshinori Shingaki
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Patent number: 8142573Abstract: An R-T-B based sintered magnet includes both a light rare-earth element RL (which is at least one of Nd and Pr) and a heavy rare-earth element RH (which is at least one of Dy and Tb) and Nd2Fe14B type crystals as a main phase. The magnet has a first region, which includes either the heavy rare-earth element RH in a relatively low concentration or no heavy rare-earth elements RH at all, and a second region, which includes the heavy rare-earth element RH in a relatively high concentration. The first and second regions are combined together by going through a sintering process.Type: GrantFiled: April 11, 2008Date of Patent: March 27, 2012Assignee: Hitachi Metals, Ltd.Inventors: Hiroya Kobayashi, Futoshi Kuniyoshi
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Patent number: 8128758Abstract: An R—Fe—B based rare-earth alloy powder with a mean particle size of less than about 20 ?m is provided and compacted to make a powder compact. Next, the powder compact is subjected to a heat treatment at a temperature of about 550° C. to less than about 1,000° C. within hydrogen gas, thereby producing hydrogenation and disproportionation reactions (HD processes). Then, the powder compact is subjected to another heat treatment at a temperature of about 550° C. to less than about 1,000° C. within either a vacuum or an inert atmosphere, thereby producing desorption and recombination reactions and obtaining a porous material including fine crystal grains, of which the density is about 60% to about 90% of their true density and which have an average crystal grain size of about 0.01 ?m to about 2 ?m (DR processes). Thereafter, the porous material is subjected to yet another heat treatment at a temperature of about 750° C. to less than about 1,000° C.Type: GrantFiled: October 21, 2008Date of Patent: March 6, 2012Assignee: Hitachi Metals, Ltd.Inventors: Noriyuki Nozawa, Takeshi Nishiuchi, Satoshi Hirosawa, Tomohito Maki
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Patent number: 8128759Abstract: By causing at least one of Dy and Tb to be adhered to the surface of an iron-boron-rare earth based sintered magnet of a predetermined shape, and is then to be diffused into grain boundary phase, a permanent magnet can be manufactured at high workability and low cost. An iron-boron-rare earth based sintered magnet is disposed in a processing chamber and is heated to a predetermined temperature. Also, an evaporating material made up of a fluoride containing at least one of Dy and Tb disposed in the same or another processing chamber is evaporated, and the evaporated evaporating material is caused to be adhered to the surface of the sintered magnet. The Dy and/or Tb metal atoms of the adhered evaporating material are diffused into the grain particle phase of the sintered magnet before a thin film made of the evaporated material is formed on the surface of the sintered magnet.Type: GrantFiled: December 19, 2007Date of Patent: March 6, 2012Assignee: Ulvac, Inc.Inventors: Hiroshi Nagata, Kyuzo Nakamura, Takeo Katou, Atsushi Nakatsuka, Ichirou Mukae, Masami Itou, Ryou Yoshiizumi, Yoshinori Shingaki
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Patent number: 8105444Abstract: A process for producing a highly anticorrosive rare earth permanent magnet, characterized by sequentially subjecting an R—Fe—B sintered magnet to surface finishing involving cutting and/or polishing, plating pretreatment, nickel electroplating to a given plating thickness, immersion in an aqueous solution containing a phosphoric salt, washing with water and heat treatment at 150° to 400° C. for 1 to 24 hr in an atmosphere of 1.3×103 Pa or higher oxygen partial pressure so as to form a thin nickel oxide layer at the surface layer portion.Type: GrantFiled: May 30, 2007Date of Patent: January 31, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Kazuo Tamura
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Patent number: 8105446Abstract: Disclosed are a method for producing alloy flakes for rare earth sintered magnets, which makes uniform the intervals, size, orientation, and shape of the R-rich region and the dendrites of the 2-14-1 phase, and alloy flakes for a rare earth sintered magnet obtained by the method. A rare earth sintered magnet employing the alloy flakes is also disclosed.Type: GrantFiled: April 8, 2010Date of Patent: January 31, 2012Assignee: Santoku CorporationInventors: Kazumasa Shintani, Ryo Murakami, Kazuhiko Yamamoto
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Patent number: 8105443Abstract: A method for the production of pressed permanent magnets comprises the following steps: A mixture of at least one magnetic powder and a thermosetting binder is provided and pressed to produce a moulded body. In order to obtain a permanent and particularly reliable protection against oxidation and corrosion, the moulded body is impregnated with an acid and solvent mixture in an impregnating bath before the cure of the thermosetting binder, whereby the entire surface of the permanent magnet is coated with a reaction layer [FIG. 1].Type: GrantFiled: April 25, 2007Date of Patent: January 31, 2012Assignee: Vacuumschmelze GmbH & Co.Inventors: Georg Werner Reppel, Volker Zellmann
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Publication number: 20120006449Abstract: The present invention provides a method for producing metallic iron, which is operable at low temperature. The present invention relates to a method for producing a metallic iron, which comprises heating and reducing a raw material mixture containing a carbonaceous reducing agent and an iron oxide-containing material to produce the metallic iron, wherein the carbonaceous reducing agent has a volatile content of 20 to 60 mass %, a gas derived from the carbonaceous reducing agent is a CO—CO2—H2 gas, and the method comprises forming solid Fe3C by heating the raw material mixture in an atmosphere containing the CO—CO2—H2 gas, melting the Fe3C, and carburizing a reduced iron through the molten Fe3C.Type: ApplicationFiled: April 6, 2010Publication date: January 12, 2012Applicants: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.), Mitsutaka HINOInventors: Mitsutaka Hino, Isao Kobayashi, Akira Uragami, Takuya Negami
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Publication number: 20110308668Abstract: A process for forming a magnetite coating on a ferrous metal surface and for chemical reagents used to implement the coating process. The process comprises the step of making the ferrous metal surface more reactive by contacting the surface with an activating reagent and then contacting the activated surface with an oxidizing reagent to form the coating at a relatively low temperature range. The surface is activated by contact with an acid solution to form a surface rich in reactive iron. The activated surface is then oxidized by contact with an aqueous reagent of alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite, and mixtures thereof.Type: ApplicationFiled: May 17, 2011Publication date: December 22, 2011Inventors: William V. Block, Bryce D. Devine
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Patent number: 8075707Abstract: A method for preparing a rare earth permanent magnet material comprises the steps of disposing a powder on a surface of a sintered magnet body of R1aTbAcMd composition wherein R1 is a rare earth element inclusive of Sc and Y, T is Fe and/or Co, A is boron (B) and/or carbon (C), M is Al, Cu, Zn, In, Si, P, S, Ti, V, Cr, Mn, Ni, Ga, Ge, Zr, Nb, Mo, Pd, Ag, Cd, Sn, Sb, Hf, Ta, or W, said powder comprising an oxide of R2, a fluoride of R3 or an oxyfluoride of R4 wherein R2, R3, and R4 are rare earth elements inclusive of Sc and Y and having an average particle size equal to or less than 100 ?m, heat treating the magnet body and the powder at a temperature equal to or below the sintering temperature of the magnet body for absorption treatment for causing R2, R3, and R4 in the powder to be absorbed in the magnet body, and repeating the absorption treatment at least two times.Type: GrantFiled: March 28, 2007Date of Patent: December 13, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hajime Nakamura, Takehisa Minowa, Koichi Hirota
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Patent number: 8044547Abstract: In a radial-direction gap type magnet motor, when an energy density increases, a direction change M?/?p of a static magnetic field with respect to a mechanic angle between different poles increases in an exponential manner and thus to decrease a cogging torque of the motor is not compatible to increase a torque density. In order to solve the problem, assuming that ?t denotes a mechanic angle of a stator iron core teeth, ?p denotes a mechanical angle of a magnetic pole, and M? denotes an angle of a static magnetic field with respect to a circumferential tangential line of a radial magnetic pole center, a radial-direction type magnet motor in which ?t<?p, M? in a magnetic pole center region is 75 to 90°, and M?/?p?7 is satisfied in the magnetic pole end region of ?p×0.1°, and further, a static magnetic field generating source is configured as a magnetic anisotropic magnetic pole having an energy density (BH) max?150 kJ/m3 is provided.Type: GrantFiled: November 15, 2007Date of Patent: October 25, 2011Assignee: Panasonic CorporationInventors: Fumitoshi Yamashita, Hiroshi Murakami, Yukihiro Okada, Kiyomi Kawamura
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Patent number: 8038807Abstract: First, an R—Fe—B based rare-earth sintered magnet body including, as a main phase, crystal grains of an R2Fe14B type compound that includes a light rare-earth element RL, which is at least one of Nd and Pr, as a major rare-earth element R is provided. Next, an M layer, including a metallic element M that is at least one element selected from the group consisting of Al, Ga, In, Sn, Pb, Bi, Zn and Ag, is deposited on the surface of the sintered magnet body and then an RH layer, including a heavy rare-earth element RH that is at least one element selected from the group consisting of Dy, Ho and Tb, is deposited on the M layer. Thereafter, the sintered magnet body is heated, thereby diffusing the metallic element M and the heavy rare-earth element RH from the surface of the magnet body deeper inside the magnet.Type: GrantFiled: January 12, 2007Date of Patent: October 18, 2011Assignee: Hitachi Metals, Ltd.Inventors: Hideyuki Morimoto, Tomoori Odaka, Masao Noumi
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Patent number: 8025744Abstract: A rare earth permanent magnet is prepared by disposing a powdered metal alloy containing at least 70 vol % of an intermetallic compound phase on a sintered body of R—Fe—B system, and heating the sintered body having the powder disposed on its surface below the sintering temperature of the sintered body in vacuum or in an inert gas for diffusion treatment. The advantages include efficient productivity, excellent magnetic performance, a minimal or zero amount of Tb or Dy used, an increased coercive force, and a minimized decline of remanence.Type: GrantFiled: March 17, 2008Date of Patent: September 27, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hiroaki Nagata, Tadao Nomura, Takehisa Minowa
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Patent number: 8012269Abstract: A rare earth permanent magnet material is based on an R—Fe—Co—B—Al—Cu system wherein R is at least one element selected from Nd, Pr, Dy, Tb, and Ho, 15 to 33% by weight of Nd being contained. At least two compounds selected from M-B, M-B—Cu and M-C compounds (wherein M is Ti, Zr or Hf) and an R oxide have precipitated within the alloy structure as grains having an average grain size of up to 5 ?m which are uniformly distributed in the alloy structure at intervals of up to 50 ?m.Type: GrantFiled: December 23, 2005Date of Patent: September 6, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kenji Yamamoto, Koichi Hirota, Takehisa Minowa
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Patent number: 8002906Abstract: The present invention provides a rare earth magnet, which is formed through at least hot molding, the rare earth magnet containing grains including an R2X14B phase as a main phase, and a grain boundary phase surrounding peripheries of the grains, in which R is at least one element selected from the group consisting of Nd, Pr, Dy, Tb and Ho, and X is Fe or Fe with a part being substituted by Co; in which an element RH is more concentrated in the grain boundary phase than in the grains, in which the element RH is at least one element selected from the group consisting of Dy, Tb and Ho; and the element RH is present with a substantially constant concentration distribution from the surface part of the magnet to the central part of the magnet.Type: GrantFiled: June 30, 2009Date of Patent: August 23, 2011Assignee: Daido Tokushuko Kabushiki KaishaInventors: Shunji Suzuki, Hayato Hashino, Masahiro Hiraoka, Takao Yabumi
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Patent number: 7998283Abstract: The disclosure provides a rare earth anisotropic hard magnetic material, which has, on atomic percent basis, a composition of (Sm1-?R?)xFe100-x-y-zMyIz, wherein, R is Pr alone or a combination of Pr with at least one rare earth element selected from the group consisting of La, Ce, Nd, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and Y; M is at least one element selected from the group consisting of Si, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Nb, Mo, Al, and Zr; I is N alone or a combination of N and C; 0.01???0.30; 7?x?12, 0.01?y?8.0, 6?z?14.4, and which anisotropic rare earth hard magnetic material is crystallized in a Th2Zn17-type structure, of which crystalline grains are in a flake shape with a gain size ranging from 1 to 5 ?m, and c-axis of the crystalline grains, an easy magnetization direction, being oriented along the minor axis of the flake crystalline grains.Type: GrantFiled: April 13, 2007Date of Patent: August 16, 2011Inventor: Yingchang Yang
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Patent number: 7988795Abstract: An R-T-B—C rare earth sintered magnet (R?Ce, Pr, Nd, Tb, or Dy; T=Fe) is obtained by mixing an R-T-B—C magnet matrix alloy with an R fluoride and an R-rich R-T-B—C sintering aid alloy, followed by pulverization, compaction and sintering. The sintered structure consists of an R2T14B type crystal primary phase and a grain boundary phase. The grain boundary phase consists essentially of 40-98 vol % of R—O1-x—F1+2x and/or R—Fy, 1-50 vol % of R—O, R—O—C or R—C compound phase, 0.05-10 vol % of R-T phase, 0.05-20 vol % of B-rich phase or M-B2 phase (M=Ti, V, Cr, Zr, Nb, Mo, Hf, Ta or W), and the balance of an R-rich phase.Type: GrantFiled: November 30, 2006Date of Patent: August 2, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Koichi Hirota, Takehisa Minowa
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Patent number: 7988797Abstract: A nanocomposite magnet according to the present invention has a composition represented by the general formula: RxQyMz(Fe1-mTm)bal, where R is at least one rare-earth element, Q is at least one element selected from the group consisting of B and C, M is at least one metal element that is selected from the group consisting of Al, Si, Ti, V, Cr, Mn, Cu, Zn, Ga, Zr, Nb, Mo, Ag, Hf, Ta, W, Pt, Au and Pb and that always includes Ti, and T is at least one element selected from the group consisting of Co and Ni. The mole fractions x, y, z and m satisfy the inequalities of 6 at %?x<10 at %, 10 at %?y?17 at %, 0.5 at %?z?6 at % and 0?m?0.5, respectively. The nanocomposite magnet includes a hard magnetic phase and a soft magnetic phase that are magnetically coupled together. The hard magnetic phase is made of an R2Fe14B-type compound, and the soft magnetic phase includes an ?-Fe phase and a crystalline phase with a Curie temperature of 610° C. to 700° C. (? phase) as its main phases.Type: GrantFiled: May 17, 2010Date of Patent: August 2, 2011Assignee: Hitachi Metals, Ltd.Inventors: Yasutaka Shigemoto, Satoshi Hirosawa, Toshio Miyoshi
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Patent number: 7985303Abstract: A rare earth permanent magnet is prepared by disposing a powdered metal alloy containing at least 70 vol % of an intermetallic compound phase on a sintered body of R—Fe—B system, and heating the sintered body having the powder disposed on its surface below the sintering temperature of the sintered body in vacuum or in an inert gas for diffusion treatment. The advantages include efficient productivity, excellent magnetic performance, a minimal or zero amount of Tb or Dy used, an increased coercive force, and a minimized decline of remanence.Type: GrantFiled: October 27, 2010Date of Patent: July 26, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hiroaki Nagata, Tadao Nomura, Takehisa Minowa
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Patent number: 7976643Abstract: A nanocomposite magnet containing an Fe particle in the grain boundary of an Nd2Fe14B compound particle is produced by mixing a dispersion of the Nd2Fe14B compound particle in a solvent containing a surface-active agent and a dispersion of the Fe particle in a solvent containing a surface-active agent, and then supporting the Fe particle on the surface of the Nd2Fe14B compound particle by stirring the mixture of the dispersions while adding an amphiphilic solvent, and then performing the drying and the drying and the sintering.Type: GrantFiled: November 27, 2007Date of Patent: July 12, 2011Assignee: Toyota Jidosha Kabushiki KaishaInventors: Noritsugu Sakuma, Tetsuya Shoji
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Patent number: 7972448Abstract: Disclosed herein is a method for the production of an anisotropic magnetic powder or a magnet produced from said powder, wherein a hydrogenating and dehydrogenating method is applied to the starting material in order to produce the powder. An anisotropic oriented magnetic material, more particularly magnetic scrap metal, is advantageously used as starting material so that the complicated use of a molten mass with isotropic distribution of the c axes of the hard metal crystals is not required. The result is an anisotropic material having a fine grain structure and a crystallographic orientation matching a TMXB phase formed during hydrogenation.Type: GrantFiled: November 27, 2003Date of Patent: July 5, 2011Assignee: Vacuumschmelze GmbH & Co. KGInventor: Georg Werner Reppel
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Patent number: 7967919Abstract: The present invention provides a method for manufacturing a self-organized rare earth-iron bonded magnet, including: a first step of covering a rare earth-iron magnet powder with oligomer or prepolymer in which one molecule includes at least two or more reactive ground substances to provide a surface-treated magnet powder; a second step of melting and kneading stretchable polymer and the surface-treated magnet powder to coarsely crush the resultant material to provide a granule; a third step of dry blending the granule with hardener to provide a compound; a fourth step of compressing the compound under temperature conditions by which the oligomer or prepolymer, the polymer, and the hardener are caused to melt and to flow to provide a green compact; a fifth step of causing the green compact to be a self-organized rare earth-iron bonded magnet by reacting the oligomer or prepolymer, and polymer with the hardener; and a sixth step of stretching the bonded magnet to transform the shape to any of a circular-shapeType: GrantFiled: May 26, 2005Date of Patent: June 28, 2011Assignee: Panasonic CorporationInventor: Fumitoshi Yamashita
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Patent number: 7955442Abstract: The present invention provides a method for producing a sintered magnet, which can have a sufficient sintered density even when the magnet has a low-R composition. The method is for producing a sintered magnet comprising R (R: one or more rare-earth elements), T (T: one or more transition metal elements essentially comprising Fe, or Fe and Co) and B (boron) as the main components, wherein a starting alloy prepared by strip casting is pulverized to a given particle size to form a fine powder, where the starting alloy comprises discolored deposit 1 on the surface and the area ratio of the discolored deposit 1 is 1.5% or less, the resulting fine powder is compacted in a magnetic field to prepare a compact, and the compact is sintered.Type: GrantFiled: November 16, 2004Date of Patent: June 7, 2011Assignee: TDK CorporationInventors: Tetsuya Hidaka, Chikara Ishizaka
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Patent number: 7955443Abstract: A permanent magnet material is prepared by covering an anisotropic sintered magnet body of formula: R1x(Fe1-yCoy)100-x-z-aBzMa wherein R1 is a rare earth element, M is Al, Cu or the like, with a powder comprising an oxide of R2, a fluoride of R3 or an oxyfluoride of R4 wherein R2, R3, and R4 are rare earth elements, and having an average particle size up to 100 ?m, heat treating the powder-covered magnet body in a hydrogen gas-containing atmosphere for inducing disproportionation reaction on R12Fe14B compound, and continuing heat treatment at a reduced hydrogen gas partial pressure for inducing recombination reaction to said compound, thereby finely dividing said compound phase to a crystal grain size up to 1 ?m, and for effecting absorption treatment, thereby causing R2, R3 or R4 to be absorbed in the magnet body.Type: GrantFiled: April 11, 2007Date of Patent: June 7, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hajime Nakamura, Takehisa Minowa, Koichi Hirota
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Patent number: 7948135Abstract: A radial anisotropic sintered magnet formed into a cylindrical shape includes a portion oriented in directions tilted at an angle of 30° or more from radial directions, the portion being contained in the magnet at a volume ratio in a range of 2% or more and 50% or less, and a portion oriented in radial directions or in directions tilted at an angle less than 30° from radial directions, the portion being the rest of the total volume of the magnet. The radial anisotropic sintered magnet has excellent magnet characteristics without occurrence of cracks in the steps of sintering and cooling for aging, even if the magnet has a shape of a small ratio between an inner diameter and an outer diameter.Type: GrantFiled: October 6, 2009Date of Patent: May 24, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Koji Sato, Mitsuo Kawabata, Takehisa Minowa
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Patent number: 7942981Abstract: A seamless, rotationally symmetrical hollow blank formed by a non-cutting operation from a deformable permanently magnetic alloy is provided, said alloy consisting essentially of 5.0 to 20.0 percent by weight cobalt, 20.0 to 35.0 percent by weight chromium, for the remainder iron and impurities caused by melting and/or by chance. The seamless hollow body is suitable in particular for use in hysteresis clutches, hysteresis brakes, and position measuring devices. Furthermore, non-cutting shaping processes for producing the seamless rotationally symmetrical hollow body are provided, with roller spinning being preferred.Type: GrantFiled: September 19, 2007Date of Patent: May 17, 2011Assignee: Vacuumschmelze GmbH & Co. KGInventors: Ottmar Roth, Hartwin Weber, Lutz Hinrich, Jens Diehl
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Patent number: 7938915Abstract: A method for producing a rare-earth alloy based binderless magnet according to the present invention includes the steps of: (A) providing a rapidly solidified rare-earth alloy magnetic powder; and (B) compressing and compacting the rapidly solidified rare-earth alloy magnetic powder by a cold process without using a resin binder, thereby obtaining a compressed compact, 70 vol % to 95 vol % of which is the rapidly solidified rare-earth alloy magnetic powder.Type: GrantFiled: August 3, 2006Date of Patent: May 10, 2011Assignees: Hitachi Metals, Ltd., Nippon Kagaku Yakin Co., Ltd.Inventors: Hirokazu Kanekiyo, Toshio Miyoshi, Katsunori Bekki, Ikuo Uemoto, Kazuo Ishikawa
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Publication number: 20110101262Abstract: The invention provides surface-treated reduced iron powder from which a powder magnetic core can be produced so that the powder magnetic core has small core loss and small frequency-dependence of the core loss and exhibits small core loss even when driven at high frequencies of 1 MHz or more. The surface-treated reduced iron powder is obtained by at least surface-treating reduced iron powder prepared by a reduction and slow oxidation method, and contains secondary particles formed through agglomeration of primary particles, the primary particles having an average particle diameter of 0.01-5 ?m. The secondary particles have a D90% particle diameter of 20 ?m or less, the surface of the primary particles is at least in part coated with an insulating layer containing iron phosphate, and the phosphorus content is 500-10000 ppm.Type: ApplicationFiled: October 1, 2010Publication date: May 5, 2011Applicant: TDK CORPORATIONInventors: Tomofumi KURODA, Masahito KOEDA
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Patent number: 7931756Abstract: A method of making a rare-earth alloy granulated powder according to the present invention includes the steps of: preparing a rare-earth alloy powder; generating remnant magnetization in the powder; and granulating the powder by utilizing agglomeration force produced by the remnant magnetization of the powder. Since the agglomeration force produced by the remnant magnetization is utilized, the addition of a granulating agent may be omitted.Type: GrantFiled: October 5, 2009Date of Patent: April 26, 2011Assignee: Hitachi Metals, Ltd.Inventors: Futoshi Kuniyoshi, Tomoiku Otani
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Patent number: 7927501Abstract: A magnet comprising magnetic powder containing at least one rare earth metal element, and an oxide binder for binding the magnetic powder, wherein an inter-face distance of the binder determined by diffraction analysis is 0.25 to 2.94 nm. The disclosure also discloses a method of manufacturing a magnet comprising; compacting magnetic powder containing at least one rare earth element under pressure in a mold; impregnating the compacted magnetic powder molding with a precursor solution of an oxide material; and heat-treating the compacted magnetic molding impregnated with the precursor thereby to impart an inter-face distance determined by diffraction analysis to the binder in the compacted molding. The distance is 0.25 to 2.94 nm.Type: GrantFiled: November 20, 2007Date of Patent: April 19, 2011Assignee: Hitachi, Ltd.Inventors: Matahiro Komuro, Yuichi Satsu, Takao Imagawa, Hiroyuki Suzuki
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Patent number: 7922832Abstract: A permanent magnet material is prepared by machining an anisotropic sintered magnet body having the compositional formula: Rx(Fe1-yCoy)100-x-z-aBzMa wherein R is Sc, Y or a rare earth element, M is Al, Cu or the like, to a specific surface area of at least 6 mm?1, heat treating in a hydrogen gas-containing atmosphere at 600-1,100° C. for inducing disproportionation reaction on the R2Fe14B compound, and continuing heat treatment at a reduced hydrogen gas partial pressure and 600-1,100° C. for inducing recombination reaction to the R2Fe14B compound, thereby finely dividing the R2Fe14B compound phase to a crystal grain size ?1 ?m.Type: GrantFiled: April 6, 2007Date of Patent: April 12, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hajime Nakamura, Takehisa Minowa
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Patent number: 7914695Abstract: The object of the present invention is to both reduce costs and improve magnetic characteristics of rare-earth bond magnets in which magnetic material is bound with a binding agent. In order to achieve this object, magnetic characteristics of a magnet are improved by performing cold forming on rare-earth magnetic powder by itself with no resin added. Then, in order to provide strength for the magnet, a low-viscosity SiO2 precursor is infiltrated and thermoset in the magnet shaped body. As a result, it is possible to obtain a rare-earth bond magnet in which magnetic characteristics are improved and costs are reduced.Type: GrantFiled: March 12, 2007Date of Patent: March 29, 2011Assignee: Hitachi, Ltd.Inventors: Yuichi Satsu, Matahiro Komuro, Takao Imagawa, Takashi Yasuhara, Yutaka Matsunobu
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Patent number: 7892365Abstract: A method of making a magnetically anisotropic magnet powder according to the present invention includes the steps of preparing a master alloy by cooling a rare-earth-iron-boron based molten alloy and subjecting the master alloy to an HDDR process. The step of preparing the master alloy includes the step of forming a solidified alloy layer, including a plurality of R2Fe14B-type crystals (where R is at least one element selected from the group consisting of the rare-earth elements and yttrium) in which rare-earth-rich phases are dispersed, by cooling the molten alloy through contact with a cooling member.Type: GrantFiled: December 5, 2007Date of Patent: February 22, 2011Assignee: Hitachi Metals, Ltd.Inventors: Hiroyuki Tomizawa, Yuji Kaneko
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Publication number: 20110036460Abstract: A rare earth permanent magnet is prepared by disposing a powdered metal alloy containing at least 70 vol % of an intermetallic compound phase on a sintered body of R—Fe—B system, and heating the sintered body having the powder disposed on its surface below the sintering temperature of the sintered body in vacuum or in an inert gas for diffusion treatment. The advantages include efficient productivity, excellent magnetic performance, a minimal or zero amount of Tb or Dy used, an increased coercive force, and a minimized decline of remanence.Type: ApplicationFiled: October 27, 2010Publication date: February 17, 2011Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Hiroaki Nagata, Tadao Nomura, Takehisa Minowa
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Publication number: 20110036457Abstract: A rare earth permanent magnet is prepared by disposing a powdered metal alloy containing at least 70 vol % of an intermetallic compound phase on a sintered body of R—Fe—B system, and heating the sintered body having the powder disposed on its surface below the sintering temperature of the sintered body in vacuum or in an inert gas for diffusion treatment. The advantages include efficient productivity, excellent magnetic performance, a minimal or zero amount of Tb or Dy used, an increased coercive force, and a minimized decline of remanence.Type: ApplicationFiled: October 27, 2010Publication date: February 17, 2011Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Hiroaki Nagata, Tadao Nomura, Takehisa Minowa
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Publication number: 20110036459Abstract: A rare earth permanent magnet is prepared by disposing a powdered metal alloy containing at least 70 vol % of an intermetallic compound phase on a sintered body of R—Fe—B system, and heating the sintered body having the powder disposed on its surface below the sintering temperature of the sintered body in vacuum or in an inert gas for diffusion treatment. The advantages include efficient productivity, excellent magnetic performance, a minimal or zero amount of Tb or Dy used, an increased coercive force, and a minimized decline of remanence.Type: ApplicationFiled: October 27, 2010Publication date: February 17, 2011Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Hiroaki Nagata, Tadao Nomura, Takehisa Minowa
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Publication number: 20110036458Abstract: A rare earth permanent magnet is prepared by disposing a powdered metal alloy containing at least 70 vol % of an intermetallic compound phase on a sintered body of R—Fe—B system, and heating the sintered body having the powder disposed on its surface below the sintering temperature of the sintered body in vacuum or in an inert gas for diffusion treatment. The advantages include efficient productivity, excellent magnetic performance, a minimal or zero amount of Tb or Dy used, an increased coercive force, and a minimized decline of remanence.Type: ApplicationFiled: October 27, 2010Publication date: February 17, 2011Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Hiroaki Nagata, Tadao Nomura, Takehisa Minowa
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Patent number: 7883587Abstract: A rare earth permanent magnet is prepared by providing a sintered magnet body consisting of 12-17 at % of rare earth, 3-15 at % of B, 0.01-11 at % of metal element, 0.1-4 at % of O, 0.05-3 at % of C, 0.01-1 at % of N, and the balance of Fe, disposing on a surface of the magnet body a powder comprising an oxide, fluoride and/or oxyfluoride of another rare earth, and heat treating the powder-covered magnet body at a temperature below the sintering temperature in vacuum or in an inert gas, for causing the other rare earth to be absorbed in the magnet body.Type: GrantFiled: November 16, 2007Date of Patent: February 8, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hajime Nakamura, Koichi Hirota, Takehisa Minowa
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Patent number: 7867343Abstract: In a rare earth magnet, an added heavy rare earth element RH such as Dy is effectively used without any waste, so as to effectively improve the coercive force. First, a molten alloy of a material alloy for an R-T-Q rare earth magnet (R is a rare earth element, T is a transition metal element, and Q is at least one element selected from the group consisting of B, C, N, Al, Si, and P), the rare earth element R containing at least one kind of element RL selected from the group consisting of Nd and Pr and at least one kind of element RH selected from the group consisting of Dy Tb, and Ho is prepared. The molten alloy is quenched, so as to produce a solidified alloy. Thereafter, a thermal treatment in which the rapidly solidified alloy is held in a temperature range of 400° C. or higher and lower than 800° C. for a period of not shorter than 5 minutes nor longer than 12 hours is performed.Type: GrantFiled: June 26, 2007Date of Patent: January 11, 2011Assignee: Hitachi Metals, Ltd.Inventors: Hiroyuki Tomizawa, Yuji Kaneko
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Publication number: 20110001594Abstract: A magnetic article comprises, in total, elements in amounts capable of providing at least one (La1-aMa) (Fe1-b-cTbYc)13-dXe phase and less than 0.5 Vol % impurities, wherein 0?a?0.9, 0?b?0.2, 0.05?c?0.2, ?1?d?+1, 0?e?3, M is one or more of the elements Ce, Pr and Nd, T is one or more of the elements Co, Ni, Mn and Cr, Y is one or more of the elements Si, Al, As, Ga, Ge, Sn and Sb and X is one or more of the elements H, B, C, N, Li and Be. The magnetic article comprises a permanent magnet.Type: ApplicationFiled: September 30, 2009Publication date: January 6, 2011Applicant: Vacuumschmelze GmbH & Co. KGInventors: Matthias Katter, Joachim Gerster, Ottmar Roth