Abstract: A method of applying a surface coating to promote gas carburization of a highly alloyed steel. The method includes the step of coating the highly alloyed steel with a layer of iron or an iron alloy to form a coated steel before carburizing the coated steel in a conventional gas carburizing atmosphere.

Abstract: A method for reforming hydrocarbons comprising coating portions of a reactor system with a material more resistant to carburization, reacting the material with metal oxides existing in the portions of the reactor system prior to coating, fixating or removing at least a portion of the oxide in the metal oxides, and reforming hydrocarbons in the reactor system under conditions of low sulfur.

Abstract: The process serves for the manufacture of an erosion-resistant turbine blade which is preferably used in the low-pressure stage of a steam turbine and is made of a vanadium-containing (.alpha./.beta.)-titanium base alloy. This involves the formation, by remelt alloying of a blade section which is situated in the region of the blade tip and comprises the leading edge of the blade, in a boron-, carbon- and/or nitrogen-containing gas atmosphere, with the aid of a high-power energy source, of an erosion-resistant protective layer made of a titanium boride, titanium carbide and/or titanium nitride. The remelt alloyed blade section is subjected to a heat treatment at a temperature between 600.degree. and 750.degree. C. with the formation of a vanadium-rich .beta.-titanium phase.

Abstract: The present invention relates to nickel alloy products with their surfaces nitrided and hardened which are formed by pressure casting nickel alloy material, and nitrided and hardened layers are formed in surface layers. Since the nitrided and hardened surfaces of the nickel alloy products according to the invention have much better corrosion resistance than iron products have, anticorrosion treatment such as plating is not required, and rich lubricity and excellent tightening property can be obtained without having seizure and scuffing phenomena.

Abstract: A permanent magnet alloy and method for production thereof. The permanent magnet alloy has a rare earth element including Nd, B, Fe, C, and oxygen, with additions of Co and at least one of Cu, Ga and Ag. The alloy may be produced by contacting particles thereof with carbon- and oxygen-containing material to achieve desired carbon and oxygen contents.

Abstract: A method and article of manufacture of a coated iron based alloy. The method includes providing an iron based alloy substrate, depositing a silicon containing layer on the alloy surface while maintaining the alloy at a temperature of about 700.degree. C.-1200.degree. C. to diffuse silicon into the alloy surface and exposing the alloy surface to an ammonia atmosphere to form a silicon/oxygen/nitrogen containing protective layer on the iron based alloy.

Abstract: An insulating film with low thermal expansion characteristics is formed by depositing aluminum alloy materials in thin film form without the use of high temperatures and which can then be oxidized to create an insulating film which has low stress. A mixture of aluminum and magnesium oxides, known as spinel, has the proportions which are approximately correct for zero expansion when crystallization results from the oxidation.

Abstract: A method for reforming hydrocarbons comprising coating portions of a reactor system with a material more resistant to carburization, reacting the material with metal oxides existing in the portions of the reactor system prior to coating, fixating or removing at least a portion of the oxide in the metal oxides, and reforming hydrocarbons in the reactor system under conditions of low sulfur.

Abstract: A method for reforming hydrocarbons comprising coating portions of a reactor system with a material more resistant to carburization, reacting the material with metal sulfides existing in the portions of the reactor system prior to coating, fixating and removing at least a portion of the sulfur in the metal sulfides, and reforming hydrocarbons in the reactor system under conditions of low sulfur.

Abstract: In a process for producing a workpiece from sintered metal, especially from sintered iron, the latter is subjected, after sintering, to a steam treatment at temperatures below 500.degree. C., especially at 430.degree.-480.degree. C., at a steam partial pressure of from 20 to 80 mbar, especially from 30 to 50 mbar, to form an oxide layer on the surface, and to subsequent surface-hardening. Workpieces, especially internally geared wheels for starters, having a wear-resistant surface and, in the core, properties unchanged by the hardening are obtained.

Abstract: The present invention provides a steel sheet for press working that exhibits excellent stiffness and satisfactory press workability. The steel sheet for press working includes: a composition of C+N+B=0.007 to 1.0 wt % in a region from the surface of the steel sheet to a position of 5% of the thickness in a direction of the thickness in at least either of the surface layers; a pole intensity of [{321}+{211}]/{100}.gtoreq.1.2 in a vertical direction to the sheet surface realized at a 3% thickness position in the direction of the thickness from the surface; and a composition of C+N+B=0.010 wt % less than in the central portion 40% except for two 30% portions of the two surface layers in the direction of the thickness.

Abstract: Apparatus and method for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloyants needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment.

Abstract: Precision ferrous metal parts subject to severe friction and corrosion in e are nitrided, preferably in a bath of molten salts based on CNO.sup.- cyanate ions, oxidized, preferably in baths of molten oxidizing alkaline salts, and then impregnated with a hydrophobic wax. A layer after the nitriding and oxidation steps is formed of a close-packed deep sub-layer and a porous superficial sub-layer ranging in thickness between 5 and 25 .mu.m, and exhibiting through pores ranging between 0.2 and 3 .mu.m in diameter. The impregnation wax is an organic compound with a high molecular weight between 500 and 10,000, with a surface tension in the liquid state ranging between 10 and 73 mN/m, the contact angle between the solid phase of the superficial layer and the wax in the liquid state ranging between 0 and 75.degree. C.

Abstract: A process for generating in-situ low-cost atmospheres suitable for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals, sealing glass to metals, and sintering metal and ceramic powders in a continuous furnace from non-cryogenically produced nitrogen containing up to 5% residual oxygen is presented. The disclosed process involves mixing nitrogen gas containing residual oxygen with a predetermined amount of a hydrocarbon gas, feeding the gaseous mixture through a nonconventional device into the hot zone of a continuous heat treating furnace, converting residual oxygen to an acceptable form such as a mixture of moisture and carbon dioxide, a mixture of moisture, hydrogen, carbon monoxide, and carbon dioxide, or a mixture of carbon monoxide, moisture, and hydrogen, and using the resultant gaseous mixture for annealing and heat treating metals and alloys, brazing metals, sintering metal and ceramic powders, and sealing glass to metals.

Abstract: A superalloy article has a nickel-based superalloy substrate containing TCP-phase forming elements such as rhenium, chromium, tantalum and tungsten. A carbide precipitate-containing region is formed within the substrate extending to a carbide depth below a surface of the substrate, preferably by depositing carbon on the surface of the substrate and diffusing the carbon into the substrate. An aluminum-rich diffusion layer extends from the surface of the substrate to an aluminide depth below the surface of the substrate. Preferably, the carbide depth is about the same as the aluminide depth. The presence of the carbide precipitates inhibits the formation of the deleterious TCP-phase.

Abstract: In order to improve the corrosion resistance, carbonitrided components formed of ferrous material are treated, after an oxidation treatment, with a solution of a heat hardenable organic synthetic resin and heat-treated at 80.degree. to 200.degree. C.

Abstract: A process for generating in-situ low-cost atmospheres suitable for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals, sealing glass to metals, and sintering metal and ceramic powders in a continuous furnace from non-cryogenically produced nitrogen containing up to 5% residual oxygen is presented. The disclosed process involves mixing nitrogen gas containing residual oxygen with a predetermined amount of a hydrocarbon gas, feeding the gaseous mixture through a nonconventional device into the hot zone of a continuous heat treating furnace, converting residual oxygen to an acceptable form such as a mixture of moisture and carbon dioxide, a mixture of moisture, hydrogen, carbon monoxide, and carbon dioxide, or a mixture of carbon monoxide, moisture, and hydrogen, and using the resultant gaseous mixture for annealing and heat treating metals and alloys, brazing metals, sintering metal and ceramic powders, and sealing glass to metals.

Abstract: A process for generating in-situ low-cost atmospheres suitable for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals and ceramics, sealing glass to metals, and sintering metal and ceramic powders in a continuous furnace from non-cryogenically produced nitrogen containing up to 5% residual oxygen is presented. The disclosed process involves mixing nitrogen gas containing residual oxygen with a pre-determined amount of a reducing gas such as hydrogen, a hydrocarbon, or a mixture thereof, feeding the gaseous mixture through a non-conventional device into the hot zone of a continuous heat treating furnace, converting residual oxygen to an acceptable form such as moisture, a mixture of moisture and carbon dioxide, or a mixture of moisture, hydrogen, carbon monoxide and carbon dioxide, and using the resultant gaseous mixture for annealing and heat treating metals and alloys, brazing metals and ceramics, sintering metal and ceramic powders, and sealing glass to metals.

Abstract: The steam turbine components having erosion resistant multiple treatments are disclosed. The components include a ferrous substrate having an integral boride layer which typically reduces the underlying fatigue strength of the substrate and includes cracks or defects disposed therein. The boride layer is coated with a sealing layer to substantially cover the cracks or defects for improving the surface erosion resistance and restorings the substrate fatigue strength of the steam turbine component.

Abstract: A method for annealing a Zircaloy member having a cold worked or beta quenched crystal structure to mitigate the reduction in nodular corrosion resistance caused by the anneal comprises, annealing the member in an atmosphere comprising oxygen and the balance an inert atmosphere to form an adherent black oxide on the member.

Abstract: Steel is nitrided first by treating the steel to be nitrided with NF.sub.3 at elevated temperatures to form a fluorinated layer on the steel, and then the steel is nitrided by heating in a nitriding atmosphere.