Abstract: Continuous preparation of polyisobutylene having a content of terminal double bonds of more than 50% by polymerizing isobutene in the presence of a polymerization catalyst customary therefor, by combining a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream together with a stream of pure isobutene and feeding them into the reaction zone in such a way that the steady-state concentration of the isobutene in the combined stream at the feed point of the combined stream into the reaction zone has an average value of at least 40% by weight, and a polymerization plant therefor.

Abstract: A piston ring for at least one of a piston of an internal combustion engine and a compressor may include at least one substantially annular metallic base having a nitrided layer. The base may include at least one chamfer and at least one outer surface that maintains contact with a layer of lubricating oil. The nitrided layer may exhibit a substantially constant thickness over at least one surface of the base and the at least one chamfer. The nitrided layer may include a nitrided diffusion layer that maintains direct contact with the layer of lubricating oil and has a residual tension ranging from +100 megapascal to ?100 megapascal.

Abstract: A method for producing a welded part from two components, where at least one of the components has a hardened surface. The method can include case hardening the surface of one of the components using a salt bath nitriding process and then welding the case hardened first component to the second component by gas metal arc welding (GMAW).

Abstract: A method and apparatus for nitriding of highly-alloyed metal article is disclosed herein. In one embodiment, the method and apparatus uses at least one nitrogen source gas such as nitrogen and/or ammonia in an oxygen-free nitriding gas atmosphere, with small additions of one or more hydrocarbons. In this or other embodiments, the method and apparatus described herein is applicable to metal articles comprising iron, nickel and cobalt based alloys and which tend to form passive oxide films on at least a portion of their surface, heated to and nitrided at a certain temperature without prior surface preparation. The apparatus includes an external gas injector comprising 50-60 Hz AC, high voltage/low-current arc discharge electrodes, activating the nitriding atmosphere stream on its way from source to nitriding furnace.

Abstract: A cutting tool insert for machining by chip removal includes a body of a hard alloy of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel, onto which a hard and wear resistant coating is deposited. The coating includes at least one polycrystalline nanolaminated structure having sequences of alternating A and B layers, wherein layer A is (Alx1Me11-x1)Ny1 with 0.3<x1<0.95, 0.9<y1<1.1 and Me1 is one or more of the elements Ti, Y, V, Nb, Mo, Si and W, or Me1 is Ti and one or more of the following elements Y, V, Nb, Mo, Si, Cr and W, and layer B is (Zr1-x2-z2Six2Me2z2)Ny2 with 0<x2<0.30, 0.90<y2 <1.20, 0<z2<0.25 and Me2 is one or more of the elements Y, Ti, Nb, Ta, Cr, Mo, W and Al.

Abstract: A method for joining metal components by welding includes welding a first component to a second component. At least one of the components is a nitrogen-containing component, and titanium is added to at least one of the components before the welding step.

Abstract: Disclosed are a method for adjusting the pore size of a porous metal material and the pore structure of a porous metal material. The method comprises: permeating at least one element into the surface of the pores of the material to generate a permeated layer on the surface of the pores, so that the average pore size of the porous material is reduced to within a certain range, thus obtaining a pore structure of the porous metal material having the pores distributed on the surface of the material and the permeated layer provided on the surface of the pores.

Abstract: A hand-held work implement having a tool has a braking device for the tool that includes a brake band which wraps around a brake drum. The brake band and the brake drum undergo friction as they move relative to one another during braking. At least one of the band or drum comprises an austenitic steel, a duplex steel, super duplex steel, a nickel-base alloy or a cobalt-base alloy and has a base body and a marginal layer. The hardness of the marginal layer is approximately 150% to approximately 600% of the hardness of the base body and the carbide proportion in the marginal layer is less than approximately 0.5% by weight. A process for production of the foregoing includes diffusing carbon and/or nitrogen into a marginal layer at a temperature of less than 500° C.

Abstract: A method of activating an article of passive ferrous or non-ferrous metal by heating at least one compound containing nitrogen and carbon, wherein the article is treated with gaseous species derived from the compound. The activated article can be subsequently carburized, nitrided or nitrocarburized in shorter time at lower temperature and resulting superior mechanical properties compared with non-activated articles and even articles of stainless steel, nickel alloy, cobalt alloy or titanium based material can be carburized, nitrided or nitrocarburized.

Abstract: The present invention provides spring use heat treated steel which is cold coiled, can achieve both sufficient atmospheric strength and coilability, has a tensile strength of 2000 MPa or more, and can improve the performance as a spring by heat treatment after spring fabrication, that is, high strength spring-use heat treated steel characterized by containing, by mass %, C: 0.45 to 0.9%, Si: 1.7 to 3.0%, and Mn: 0.1 to 2.0%, restricting N: to 0.007% or less, having a balance of Fe and unavoidable impurities, and satisfying, in terms of the analyzed value of the extracted residue after heat treatment, [amount of Fe in residue on 0.2 ?m filter/[steel electrolysis amount]×100?1.1.

Abstract: A method of manufacturing a laminar ring, which permits an improvement of efficiency of a nitriding treatment of a plurality of metallic band members which constitute the laminar ring is provided.

Abstract: Disclosed is a plasma nitriding surface treatment method for a gray cast iron part. In the plasma nitriding surface treatment method, a nitride layer is formed on a surface of the gray cast iron part by a selective ion nitriding treatment. The plasma nitriding surface treatment method is carried out such that the surface of the gray cast iron part is prevented from being deformed, and a reduction of the frictional coefficient of the part is prevented.

Abstract: There is provided an aluminum surface treatment process, comprising: preparing an aluminum material containing silicon and magnesium; and plasma nitriding the aluminum material to form an aluminum nitride region on a surface of the aluminum material.

Abstract: The invention relates to a method for producing a friction element (3) comprising the steps: providing a metal main body (10), hardening the main body (10) on at least part of its surface (11, 12) in a salt bath, wherein the salt bath hardening is the final method step, and no further processing of the hardened surface (11, 12) is performed. Furthermore, the invention relates to a friction element produced according to this method and a friction component comprising the latter.

Abstract: A furnace of heat treatment capable of keeping a stable nitriding quality for a long period of time is provided. The furnace of heat treatment performs a halogenation treatment and a nitriding treatment by heating a steel material under a predetermined atmosphere. An alloy containing Ni ranging between 50 mass % or more and 80 mass % or less and Fe ranging between 0 mass % or more and 20 mass % or less is used as a material of surfaces of core internals exposed to a treatment space where the nitriding treatment is performed. Accordingly, a nitriding reaction is hardly caused on the surfaces of the core internals, and the halogenation treatment and the nitriding treatment to an article to be treated can be stably executed for a long period of time. Further, a nitrided layer can be stably formed according to purposes on any types of steel materials including a steel type hard to be nitride.

Abstract: The present invention relates to tubular elements, such as fuel assembly tubes, which are designed to be used in high pressure and high temperature water in nuclear reactors, such as pressurized water nuclear reactors. In particular, the present invention relates to a method of improving wear resistance and corrosion resistance by depositing a protective coating having a depth of from about 5 to about 25 ?m on the surface of the tubular elements. The coating is provided by nitriding the tubular element at a temperature of from about 400° C. to about 440° C. The nitridation of the tubular element can be carried out for a duration of from about 12 hours to about 40 hours.

Abstract: In a method for gas-nitriding high-pressure components of a high-pressure accumulator (rail) (1) for a common-rail injection system of an internal combustion engine, in which an internal thread of a feed or discharge opening (2) passing through the wall of the high-pressure accumulator (1) is covered during gassing, a cover screw (6) is screwed into the thread (5) to cover the thread (5).

Abstract: A surface treatment method for a metal material is provided which includes applying diluted sulfuric acid to a surface of the metal material that is composed primarily of iron, performing a heat treatment on the metal material in the presence of at least one of CO, CO2 and organic gas under nitriding conditions under which a nitrided layer is formed in a superficial layer of the metal material after the application of the diluted sulfuric acid to form a carbon film which includes at least one of carbon nanocoils, carbon nanotubes and carbon nanofilaments on a surface of the nitrided layer of the metal material.

Abstract: The present invention provides an improved metal separator for a fuel cell and a method for preparing same. More particularly, the invention provides a metal separator for a fuel cell, whereby the separator has a surface structure that imparts reduced contact resistance, improved corrosion resistance, and stable electrical conductivity. The invention further provides a surface treatment method for making the metal separator of the invention. The inventive method comprises sintering Fe—Cr—B—V-based powder on the surface of a metal foam to form an alloy layer; and forming a nitride layer of a (Cr—V—B)N-based material while supplying nitrogen gas on the surface of the alloy layer.

Abstract: A conductive film comprises a phosphide particle coated film formed by attaching raw material particles including phosphide particles comprising a compound of Ti and/or Fe, and P to a surface of a substrate material. This conductive film exhibits good corrosion resistant conductivity, and can be easily formed at low costs because of comprising the phosphide particle coated film. A corrosion-resistant conduction film comprises an iron-containing titanium phosphide layer containing Ti, Fe and P as essential basic elements. A corrosion-resistant conduction material having this corrosion-resistant conduction film on a surface of a substrate exhibits good corrosion resistance or conductivity. This corrosion-resistant conduction material can be obtained, for example, by a process comprising a plating step of forming an Ni plating layer on a surface of a Ti-based material substrate and a nitriding step of applying nitriding treatment to the Ti-based material substrate after the plating step at not more than 880 deg.

Abstract: A method and process for at least partially forming a medical device that is at least partially formed of a metal alloy which improves the physical properties of the medical device.

Abstract: The present invention relates to a method for manufacturing an implant, in particular an intraluminal endoprosthesis, having a body containing metallic material, preferably iron. For controlling the degradation of the implant the method includes the following steps: (a) providing a first part of the implant body; and (b) performing heat treatment which alters the carbon content and/or the boron content and/or the nitrogen content in the structure of a near-surface boundary layer in the first part of the implant body in such a way that strain on the lattice or a lattice transformation, optionally following a subsequent mechanical load, is achieved in the near-surface boundary layer. Such an implant is also described.

Abstract: The disclosure provides a device and method used to produce a tubular structure made of a refractory metal compound. In particular, the disclosure provides a device and method used to produce a tubular structure made of a refractory metal compound by reacting a green tubular structure made of a refractory metal with at least one reactive gas.

Abstract: Provided according to embodiments of the invention are methods of manufacturing implant devices. In methods described herein, implant devices are exposed to a reactive gas that includes a reactive species, and optionally, an inert gas, at elevated temperatures, for a duration sufficient to generate a high density of nanoscale structures on the exposed surface of the device. Also provided are implant devices formed by methods described herein.

Abstract: Provided is a method of nitriding a surface of aluminum or aluminum alloy by cold spraying. That is, a surface of aluminum or aluminum alloy is coated by cold spraying, and then a heat treatment is performed thereon at low temperature for a short time period. Accordingly, the method is suitable for nitriding a surface of Al and Al alloy, which is very difficult to be nitrided, at low production costs. The method includes removing a foreign material from a surface of a mother substrate comprising Al or Al alloy; cold spraying 15 to 50 wt % of a catalyst powder and 50 to 85 wt % of a coating agent powder on the surface of the mother substrate to form a coating layer; and heat treating the coating layer at a temperature of 450 to 630° C. in a nitrogen atmosphere for 2 to 24 hours.

Abstract: The disclosure provides a device and method used to produce a tubular structure made of a refractory metal compound. In particular, the disclosure provides a device and method used to produce a tubular structure made of a refractory metal compound by reacting a green tubular structure made of a refractory metal with at least one reactive gas.

Abstract: Provided is a method of treating a metal surface, which can improve surface properties of a target metal, such as surface hardness and wear resistance in a simple manner and at low cost using very simple equipment alone, and which can prevent the deterioration of the metal to create high added value. The present invention is comprised of a method of treating a metal surface, characterized in that: heat-treating a target metal (10) to be surface-modified in nitrogen gas atmosphere (S), in such a state where the target metal (10) is buried in a carbon source powder (12) comprising a carbon powder and a powder of iron or an iron alloy mainly comprising iron and containing carbon, whereby the surface of the target metal (10) is at least nitrided or nitrogen-absorbed to modify the surface.

Abstract: Providing a method of manufacturing a laminar ring, which permits an improvement of efficiency of a nitriding treatment of a plurality of metallic band members which constitute the laminar ring.

Abstract: The present invention relates to valve metal particles uniformly containing nitrogen and a method for preparing the same, and a valve metal green pellet and a sintered pellet made from the particles, and an electrolytic capacitor anode. The present invention provides valve metal particles uniformly containing nitrogen, wherein the difference ratio of nitrogen contents of particles is 20% or less. The present invention provides a process for preparing said valve metal particles uniformly containing nitrogen, wherein the raw material particles of the valve metal were heated in a nitrogen-containing gas at a temperature of 200° C. or less for 2 hours or more. The present invention also provides a valve metal green pellet made from said valve metal particles. The present invention also provides a valve metal sintered pellet.

Abstract: A method of manufacturing a gear by a skiving process, the skiving process utilizing a cutter including a rotational axis inclined to a rotational axis of a work to be processed into the gear, the skiving process feeding the cutter in a tooth trace direction of a tooth to be formed at the work in a state where the cutter rotates in synchronization with the work, the method includes a surface hardening process for hardening a work surface of the work before the skiving process is performed.

Abstract: The present invention provides titanium material for a separator for solid polymer fuel cell use comprised of titanium which has a surface layer part where conductive compound particles are affixed, which is excellent in contact resistance between the separator surface and carbon paper and in durability, and which is low in cost and superior in recyclability and a method of production of the same. This titanium material for separator use has on the surface of the titanium base material a film comprised of the titanium compound particles made of titanium carbide, titanium nitride, or titanium carbonitride and titanium oxide. The film has a thickness of 0.1 to 1 ?m, the coverage rate is an area percentage of 20% or more, and the contents of carbon and nitrogen in the film total 5 to 40 at %. The titanium material for a separator is produced by annealing or shot blasting and pickling.

Abstract: The invention relates to a method and device for thermally treating workpieces, the device including a cooling chamber and two or more cementing chambers in which the workpieces are heated to a temperature of 950 to 1200° C. by means of direct heat radiation from a heating device.

Abstract: The invention relates to a method for producing a friction element (3) comprising the steps: providing a metal main body (10), hardening the main body (10) on at least part of its surface (11, 12) in a salt bath, wherein the salt bath hardening is the final method step, and no further processing of the hardened surface (11, 12) is performed. Furthermore, the invention relates to a friction element produced according to this method and a friction component comprising the latter.

Abstract: The disclosure concerns a method for treating a material in a static magnetic field having an intensity of more than 1 Tesla, including the following steps: a first step to heat the material, a second step to apply to the material a thermal shock and/or thermomechanical treatment and/or chemical treatment, wherein during at least the second treatment step, the material is subjected to the magnetic field while being held in position within the magnetic field.

Abstract: There is described a piston ring, particularly devised for use in internal combustion engines or compressors, comprising at least a metallic base (2) to which there is applied, by the process of physical vapor deposition (PVD), a coating (3) of chromium nitride that comprises a periodicity (P), formed by at least two adjacent layers (5,5?), each layer (5,5?) having a predominantly chromium nitride phase different from the adjacent layer.

Abstract: A method and apparatus for nitriding of highly-alloyed metal article is disclosed herein. In one embodiment, the method and apparatus uses at least one nitrogen source gas such as nitrogen and/or ammonia in an oxygen-free nitriding gas atmosphere, with small additions of one or more hydrocarbons. In this or other embodiments, the method and apparatus described herein is applicable to metal articles comprising iron, nickel and cobalt based alloys and which tend to form passive oxide films on at least a portion of their surface, heated to and nitrided at a certain temperature without prior surface preparation. The apparatus includes an external gas injector comprising 50-60 Hz AC, high voltage/low-current arc discharge electrodes, activating the nitriding atmosphere stream on its way from source to nitriding furnace.

Abstract: A method of activating an article of passive ferrous or non-ferrous metal by heating at least one compound containing nitrogen and carbon, wherein the article is treated with gaseous species derived from the compound. The activated article can be subsequently carburised, nitrided or nitrocarburised in shorter time at lower temperature and resulting superior mechanical properties compared with non-activated articles and even articles of stainless steel, nickel alloy, cobalt alloy or titanium based material can be carburised, nitrided or nitrocarburised.

Abstract: A method of forming a sputtering target and other metal articles having controlled oxygen and nitrogen content levels and the articles so formed are described. The method includes surface-nitriding a deoxidized metal powder and further includes consolidating the powder by a powder metallurgy technique. Preferred metal powders include, but are not limited to, valve metals, including tantalum, niobium, and alloys thereof.

Abstract: The invention provides a protected metal anode architecture comprising: a metal anode layer; and an organic protection film formed over and optionally in direct contact with the metal anode layer, wherein the metal anode layer comprises a metal selected from the group consisting of an alkaline metal and an alkaline earth metal, and the organic protection film comprises a reaction product of the metal and an electron donor compound. The invention further provides a method of forming a protected metal anode architecture.

Abstract: A Co—Cr—Mo alloy with nitrogen addition composed of 26 to 35% by weight of Cr, 2 to 8% by weight of Mo, 0.1 to 0.3% by weight of N, and balance of Co is subjected to solution treatment and then subjected to isothermal aging treatment holding the alloy at 670 to 830° C. for a predetermined period of time to form a multi-phase structure composed of an ?-phase and a Cr nitride by means of an isothermal aging effect. After cooling, the alloy subjected to reverse transformation treatment in which the alloy is heated at a temperature range of 870 to 1100° C. for reverse transformation to a single ?-phase from the multi-phase structure composed of an ?-phase and a Cr nitride.

Abstract: The present disclosure is directed to a pin joint component for a pin joint assembly that has improved wear surfaces, especially for those portions of the pin joint component surface that interface thrust rings, lips, and other adjacent wear components. The pin joint component comprises a first treated region that is formed by removing material from the wear surface of the pin joint component and replaced with clad material. Prior to this operation, a second treated region is formed by removing material from a section of the pin joint component distinct from the first treated region and performing a nitriding process thereon.

Abstract: The present invention is directed to a method for protecting metal surfaces in oil & gas exploration and production, refinery and petrochemical process applications subject to solid particulate erosion at temperatures of up to 1000° C. The method includes the step of providing the metal surfaces in such applications with a hot erosion resistant cermet lining or insert, wherein the cermet lining or insert includes a) about 30 to about 95 vol % of a ceramic phase, and b) a metal binder phase, wherein the cermet lining or insert has a HEAT erosion resistance index of at least 5.0 and a K1C fracture toughness of at least 7.0 MPa-m1/2. The metal surfaces may also be provided with a hot erosion resistant cermet coating having a HEAT erosion resistance index of at least 5.0.

Abstract: The present invention is directed to a method for protecting metal surfaces in oil & gas exploration and production, refinery and petrochemical process applications subject to solid particulate erosion at temperatures of up to 1000° C. The method includes the step of providing the metal surfaces in such applications with a hot erosion resistant cermet lining or insert, wherein the cermet lining or insert includes a) about 30 to about 95 vol % of a ceramic phase, and b) a metal binder phase, wherein the cermet lining or insert has a HEAT erosion resistance index of at least 5.0 and a K1C fracture toughness of at least 7.0 MPa-m1/2. The metal surfaces may also be provided with a hot erosion resistant cermet coating having a HEAT erosion resistance index of at least 5.0.

Abstract: The present invention relates to a method for manufacturing an implant, in particular an intraluminal endoprosthesis, having a body containing metallic material, preferably iron. For controlling the degradation of the implant the method includes the following steps: (a) providing a first part of the implant body; and (b) performing heat treatment which alters the carbon content and/or the boron content and/or the nitrogen content in the structure of a near-surface boundary layer in the first part of the implant body in such a way that strain on the lattice or a lattice transformation, optionally following a subsequent mechanical load, is achieved in the near-surface boundary layer. Such an implant is also described.

Abstract: A treated austenitic steel and method for treating same includes an austenitic steel and a non-metal chemical element incorporated into a surface of the steel. The surface has a bi-layered structure of a compound layer at a top and an underlying diffusion layer, which protects said surface against hydrogen embrittlement.

Abstract: A conductive film comprises a phosphide particle coated film formed by attaching raw material particles including phosphide particles comprising a compound of Ti and/or Fe, and P to a surface of a substrate material. This conductive film exhibits good corrosion resistant conductivity, and can be easily formed at low costs because of comprising the phosphide particle coated film. A corrosion-resistant conduction film comprises an iron-containing titanium phosphide layer containing Ti, Fe and P as essential basic elements. A corrosion-resistant conduction material having this corrosion-resistant conduction film on a surface of a substrate exhibits good corrosion resistance or conductivity. This corrosion-resistant conduction material can be obtained, for example, by a process comprising a plating step of forming an Ni plating layer on a surface of a Ti-based material substrate and a nitriding step of applying nitriding treatment to the Ti-based material substrate after the plating step at not more than 880 deg.

Abstract: A surface processing method and power transmission component includes transforming a surface region of a metal alloy into a hardened surface region at a temperature that is less than a heat treating temperature of the metal alloy. The metal alloy includes about 11.1 wt % Ni, about 13.4 wt % Co, about 3.0 wt % Cr, about 0.2 wt % C, and about 1.2 wt % Mo which reacts with the C to form a metal carbide precipitate of the form M2C. The surface processing temperature, vacuum pressure, precursor gas flow and ratio, and time of processing are controlled to provide a desirable hardened surface region having a gradual transition in nitrogen concentration.

Abstract: A method of providing a porous surface on a nickel substrate comprising treating the substrate with a flowing stream of gas comprising ammonia or hydrazine at a temperature of at least 4000 C, the resultant porous surface comprising pores which are substantially all interconnected and have access to the surface.

Abstract: Low temperature carburization of a workpiece surface is accomplished faster by impregnating the surface with a diffusion promoter prior to or during the low temperature carburization process.

Abstract: A method of forming a sputtering target and other metal articles having controlled oxygen and nitrogen content levels and the articles so formed are described. The method includes surface-nitriding a deoxidized metal powder and further includes consolidating the powder by a powder metallurgy technique. Preferred metal powders include, but are not limited to, valve metals, including tantalum, niobium, and alloys thereof.