Passing Through An Amorphous State Or Treating Or Producing An Amorphous Metal Or Alloy Patents (Class 148/561)
  • Patent number: 11753707
    Abstract: Provided is a method for preparing an amorphous strip master alloy. The method includes: providing an amorphous alloy and cementite Fe3C; and placing the amorphous alloy and the cementite Fe3C in a smelting furnace for smelting treatment to obtain the amorphous strip master alloy, wherein elements constituting the amorphous alloy include Fe element, Si element and B element. An amorphous strip master alloy prepared by the preparation method is also provided.
    Type: Grant
    Filed: January 9, 2020
    Date of Patent: September 12, 2023
    Inventors: Jingran Wang, Jiahao Wang, Jiahui Wang
  • Patent number: 11220734
    Abstract: A magnesium-based bulk metallic glass composite includes a magnesium-based bulk metallic glass composite comprising a magnesium-based material and a TiZr alloy.
    Type: Grant
    Filed: May 15, 2019
    Date of Patent: January 11, 2022
    Assignees: NATIONAL CENTRAL UNIVERSITY, TAIPEI MEDICAL UNIVERSITY
    Inventors: Chih-Hwa Chen, Shian-Ching Jang, Hsiang-Ho Chen, Lau-Yuen Woo, Erh-Yuan Chuang
  • Patent number: 10946447
    Abstract: Systems and methods in accordance with embodiments of the invention fabricate objects including amorphous metals using techniques akin to additive manufacturing. In one embodiment, a method of fabricating an object that includes an amorphous metal includes: applying a first layer of molten metallic alloy to a surface; cooling the first layer of molten metallic alloy such that it solidifies and thereby forms a first layer including amorphous metal; subsequently applying at least one layer of molten metallic alloy onto a layer including amorphous metal; cooling each subsequently applied layer of molten metallic alloy such that it solidifies and thereby forms a layer including amorphous metal prior to the application of any adjacent layer of molten metallic alloy; where the aggregate of the solidified layers including amorphous metal forms a desired shape in the object to be fabricated; and removing at least the first layer including amorphous metal from the surface.
    Type: Grant
    Filed: February 3, 2017
    Date of Patent: March 16, 2021
    Assignee: CALIFORNIA INSTITUTE OF TECHNOLOGY
    Inventor: Douglas C Hofmann
  • Patent number: 10941847
    Abstract: Systems and methods in accordance with embodiments of the invention implement bulk metallic glass-based macroscale gears. In one embodiment, a method of fabricating a bulk metallic glass-based macroscale gear, where at least either the thickness of the gear is greater than 3 mm or the diameter of the gear is greater than 9 mm, includes: obtaining design parameters of the gear to be formed; selecting a bulk metallic glass from which the gear will be formed based on the obtained design parameters, where the selected bulk metallic glass is characterized by a resistance to standard modes of wear and a resistance to brittle fracture such that a gear can be formed from the selected bulk metallic glass that accords with the obtained design parameters; and fabricating the gear from the selected bulk metallic glass that accords with the obtained design parameters.
    Type: Grant
    Filed: January 28, 2019
    Date of Patent: March 9, 2021
    Assignee: California Institute of Technology
    Inventors: Douglas C. Hofmann, Andrew Kennett, Kobie T. Boykins
  • Patent number: 10661334
    Abstract: The invention provides a method of producing an amorphous alloy ribbon, the method including a step of producing an amorphous alloy ribbon by discharging a molten alloy through a rectangular opening of a molten metal nozzle having a molten metal flow channel along which the molten alloy flows, the opening being an end of the molten metal flow channel, onto a surface of a rotating chill roll, in which, among wall surfaces of the molten metal flow channel, a maximum height Rz(t) of a surface t, which is a wall surface parallel to a flow direction of the molten alloy and to a short side direction of the opening, is 10.5 ?m or less.
    Type: Grant
    Filed: October 26, 2016
    Date of Patent: May 26, 2020
    Assignee: HITACHI METALS, LTD.
    Inventors: Hiroshi Shibasaki, Takayuki Motegi, Hajime Itagaki, Jun Sunakawa, Yoshio Bizen
  • Patent number: 10584397
    Abstract: A device for the production of a metallic strip using a rapid solidification technology is specified, which device includes a movable heat sink with an external surface onto which a melt is poured and on which the melt solidifies to produce the strip, and which device includes a rolling device which can be pressed against the external surface of the movable heat sink while the heat sink is in motion.
    Type: Grant
    Filed: May 10, 2017
    Date of Patent: March 10, 2020
    Assignee: VACUUMSCHMELZE GMBH & CO KG
    Inventor: Robert Schulz
  • Patent number: 10581014
    Abstract: A packaging method of a display panel, a display panel and a display device are provided. The packaging method includes: providing a first substrate; providing an adhesive with a magnetic material distributed therein; applying the adhesive to a surface of the first substrate to form a first adhesive layer having a first pattern; providing a magnetic field to drive the magnetic material to mobilize the adhesive on the surface of the first substrate, so as to transform the first adhesive layer having the first pattern into a second adhesive layer having a second pattern, wherein, an orthogonal projection of the first adhesive layer having the first pattern on the first substrate is different from an orthogonal projection of the second adhesive layer having the second pattern on the first substrate; and bonding a second substrate onto the adhesive layer having the second pattern.
    Type: Grant
    Filed: May 31, 2018
    Date of Patent: March 3, 2020
    Assignee: BOE TECHNOLOGY GROUP CO., LTD.
    Inventor: Linlin Wang
  • Patent number: 9996053
    Abstract: Embodiments herein relate to forming nano- and/or micro-replication directly embossed in a bulk solidifying amorphous alloy comprising a metal alloy by superplastic forming of the bulk solidifying amorphous alloy at a temperature greater than a glass transition temperature (Tg) of the metal alloy.
    Type: Grant
    Filed: September 19, 2011
    Date of Patent: June 12, 2018
    Assignee: Crucible Intellectual Property, LLC
    Inventors: Sean Timothy O'Keeffe, Tran Quoc Pham, Theodore Andrew Waniuk
  • Patent number: 9963763
    Abstract: Methods and apparatus for forming high aspect ratio metallic glass, including metallic glass sheet and tube, by a melt deposition process are provided. In some methods and apparatus a molten alloy is deposited inside a tubular channel formed by two concentrically arranged substrates, and shaped and quenched by conduction to the substrates in a manner that enables the molten alloy to vitrify prior to undergoing substantial shear flow. The deposition method allows the molten alloy to be deposited and formed while being quenched, without undergoing substantial shear flow.
    Type: Grant
    Filed: September 30, 2014
    Date of Patent: May 8, 2018
    Assignees: Glassimetal Technology, Inc., Apple Inc.
    Inventors: Marios D. Demetriou, Joseph P. Schramm, William L. Johnson, David S. Lee
  • Patent number: 9752218
    Abstract: The invention concerns a zirconium and/or hafnium based, beryllium free, bulk, amorphous alloy, with the addition of silver and/or gold and/or platinum to increase its critical diameter.
    Type: Grant
    Filed: December 3, 2014
    Date of Patent: September 5, 2017
    Assignee: The Swatch Group Research and Development Ltd
    Inventors: Alban Dubach, Yves Winkler, Tommy Carozzani
  • Patent number: 9734994
    Abstract: Provided are a crystalline alloy having significantly better thermal stability than an amorphous alloy as well as glass-forming ability, and a method of manufacturing the crystalline alloy. The present invention also provides an alloy sputtering target that is manufactured by using the crystalline alloy, and a method of manufacturing the alloy target. According to an aspect of the present invention, provided is a crystalline alloy having glass-forming ability which is formed of three or more elements having glass-forming ability, wherein the average grain size of the alloy is in a range of 0.1 ?m to 5 ?m and the alloy includes 5 at % to 20 at % of aluminum (Al), 15 at % to 40 at % of any one or more selected from copper (Cu) and nickel (Ni), and the remainder being zirconium (Zr).
    Type: Grant
    Filed: December 4, 2012
    Date of Patent: August 15, 2017
    Assignee: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY
    Inventors: Seung-Yong Shin, Kyoung-Il Moon, Ju-Hyun Sun, Chang-Hun Lee
  • Patent number: 9623398
    Abstract: Provided herein are synthetic porous electron-rich covalent organonitridic frameworks (PECONFs). The PECONFs are useful as an adsorbent class of materials. In the PECONFs, inorganic nitridic building units are interconnected via electron-rich aromatic units to form porous covalent frameworks. The frameworks include tunable porous, electron-rich organonitridic frameworks, which are determined based upon synthetic methods as exemplified herein.
    Type: Grant
    Filed: April 11, 2011
    Date of Patent: April 18, 2017
    Assignee: Lehigh University
    Inventors: Kai Landskron, Mohanty Paritosh
  • Patent number: 9539628
    Abstract: Embodiments herein relate processes for bulk solidifying amorphous metal alloys by rapid capacitor discharge.
    Type: Grant
    Filed: October 15, 2012
    Date of Patent: January 10, 2017
    Assignee: Apple Inc.
    Inventors: Joseph C. Poole, Christopher D. Prest
  • Patent number: 9516739
    Abstract: Disclosed are a heat dissipation material comprising a metallic glass and an organic vehicle and a light emitting diode package including at least one of a junction part, wherein the junction part includes a heat dissipation material including a metallic glass.
    Type: Grant
    Filed: November 19, 2014
    Date of Patent: December 6, 2016
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Eun Sung Lee, Sang Soo Jee, Kun Mo Chu, Se Yun Kim, Kyu Hyoung Lee, Sang Mock Lee
  • Patent number: 9487454
    Abstract: Provided is a gas generating agent with a low combustion temperature and good ignition ability. The gas generating agent includes: (a) a fuel; (b) an oxidizing agent including a basic metal nitrate; (c) a basic metal carbonate; and (d) a binder (not including a component selected from starch, etherified starch, methyl cellulose, hydroxyethyl methyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl cellulose, guar gum, etherified guar gum, tamarind gum, poly(vinyl alcohol), polyvinyl ether, polyacrylamide, polyethylene oxide, and polyvinyl pyrrolidone). The fuel of the component (a) includes melamine cyanurate (MC) and nitroguanidine (NQ), with MC/NQ (ratio of contents) of being within a range of 0.20 to 1.50.
    Type: Grant
    Filed: March 22, 2012
    Date of Patent: November 8, 2016
    Assignee: DIACEL CORPORATION
    Inventor: Syouji Kobayashi
  • Patent number: 9430102
    Abstract: Touch sensing systems comprising bulk-solidifying amorphous alloys and methods of making touch sensing arrays and electronic devices containing touch sensitive screens that include arrays containing bulk-solidifying amorphous alloys. The bulk-solidifying amorphous alloy substrates have select areas of crystalline and amorphous alloy providing for discrete areas of conductivity and resistivity.
    Type: Grant
    Filed: July 5, 2012
    Date of Patent: August 30, 2016
    Assignee: APPLE
    Inventors: Christopher D. Prest, Matthew S. Scott, Stephen P. Zadesky, Dermot J. Stratton, Joseph C. Poole
  • Patent number: 9328406
    Abstract: Methods are provided for shape-setting hyperelastic, single-crystal shape memory alloy (SMA) material while preserving the hyperelastic properties of the material. A wire or rod of a single crystal shape memory alloy material is heated to an annealing temperature (Ta). While maintained at the annealing temperature, the wire or rod is shaped by driving the wire or rod and a shaping form together into contact with each other, and the shaped wire or rod is quenched in a quenching medium virtually simultaneously with the shaping.
    Type: Grant
    Filed: March 31, 2014
    Date of Patent: May 3, 2016
    Assignee: Ormco Corporation
    Inventors: Alfred David Johnson, Sammel S. Alauddin
  • Patent number: 9290829
    Abstract: An alloy having a formula Zr100-x-u (Cu100-aNia)xAlu wherein X, U and a are in atomic percentages wherein X is less than or equal to 48 and greater than or equal to 37, wherein U is less than or equal to 14 and greater than or equal to 3, and wherein a is less than or equal to ten and greater than or equal to 3. Methods of forming the alloy and bulk metallic glass comprising the alloy are also provided. The alloy and bulk metallic glass are useful in a wide number of applications which includes sports and luxury products, electronic goods, medical instruments, and military equipment.
    Type: Grant
    Filed: January 19, 2012
    Date of Patent: March 22, 2016
    Assignee: National University of Singapore
    Inventors: Li Yi, Irene Lee, Dong Wang
  • Patent number: 9074273
    Abstract: The present disclosure is directed at metal alloys and methods of processing with application to slab casting methods and post-processing steps towards sheet production. The metals provide unique structure and exhibit advanced property combinations of high strength and/or high ductility.
    Type: Grant
    Filed: February 6, 2015
    Date of Patent: July 7, 2015
    Assignee: The NanoSteel Company, Inc.
    Inventors: Daniel James Branagan, Grant G. Justice, Andrew T. Ball, Jason K. Walleser, Brian E. Meacham, Kurtis Clark, Longzhou Ma, Igor Yakubtsov, Scott Larish, Sheng Cheng, Taylor L. Giddens, Andrew E. Frerichs, Alla V. Sergueeva
  • Patent number: 9067258
    Abstract: A forging apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via forging in a time frame of less than 1 second.
    Type: Grant
    Filed: October 15, 2013
    Date of Patent: June 30, 2015
    Assignee: California Institute of Technology
    Inventors: Georg Kaltenboeck, Joseph P. Schramm, Marios D. Demetriou, William L. Johnson
  • Patent number: 9005376
    Abstract: Alloys and methods for preparing the same are provided. The alloys are represented by the general formula of (ZraAlbCucNid)100-e-fYeMf, wherein a, b, c, and d are atomic fractions, in which: 0.472?a?0.568; 0.09?b?0.11; 0.27?c?0.33; 0.072?d?0.088; the sum of a, b, c, and d equals 1; e and f are atomic numbers of elements Y and M respectively, in which 0?e?5 and 0.01?f?5; and M is selected from the group consisting of Nb, Ta, Sc, and combinations thereof.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: April 14, 2015
    Assignee: BYD Company Limited
    Inventors: Qing Gong, Faliang Zhang, Yongxi Jian
  • Publication number: 20150090375
    Abstract: The present disclosure is directed to the use of cellulosic materials, such as wood, paper, etc., or synthetic polymeric materials, such as a thermoplastic, rubber, etc., or a composite containing one or more of these materials as feedstock barrels for the process of injection molding of metallic glasses by rapid capacitor discharge forming (RCDF) techniques.
    Type: Application
    Filed: September 30, 2014
    Publication date: April 2, 2015
    Inventors: David S. Lee, Joseph P. Schramm, Marios D. Demetriou, William L. Johnson, Montague Rittgers
  • Patent number: 8986472
    Abstract: The present invention is directed at metal alloys that are capable of forming spinodal glass matrix microconstituent structure. The alloys are iron based and include nickel, boron, silicon and optionally chromium. The alloys exhibit ductility and relatively high tensile strengths and may be in the form of sheet, ribbon, wire, and/or fiber. Applications for such alloys are described.
    Type: Grant
    Filed: November 2, 2011
    Date of Patent: March 24, 2015
    Assignee: The NanoSteel Company, Inc.
    Inventors: Daniel James Branagan, Brian E. Meacham, Jason K. Walleser, Alla V. Sergueeva, Andrew T. Ball, Grant G. Justice
  • Publication number: 20150068648
    Abstract: In one embodiment, the invention provides a process for thermoplastic forming of a metallic glass. For example, in one embodiment, the invention provides a process for thermoplastic forming of a metallic glass ribbons having a thickness of between about 50 to about 200 microns. Related articles of manufacture and processes for customizing articles in accordance with the process as described herein are also provided.
    Type: Application
    Filed: March 15, 2013
    Publication date: March 12, 2015
    Inventors: Jan Schroers, Thomas M. Hodges, Michael Kanik, Punnathal Bordeenithikasem
  • Patent number: 8961716
    Abstract: An apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via any number of techniques including, for example, injection molding, dynamic forging, stamp forging, sheet forming, and blow molding in a time frame of less than 1 second.
    Type: Grant
    Filed: October 15, 2013
    Date of Patent: February 24, 2015
    Assignee: California Institute of Technology
    Inventors: William L. Johnson, Marios D. Demetriou, Joseph P. Schramm
  • Patent number: 8936664
    Abstract: One embodiment provides a method of melting, comprising: providing a mixture of alloy elements that are at least partially crystalline; and heating the mixture in a container to a temperature above a melting temperature of the alloy elements to form an alloy, wherein the container comprises silica, and wherein the mixture comprising Zr and is free of Ti and Be.
    Type: Grant
    Filed: August 5, 2011
    Date of Patent: January 20, 2015
    Assignee: Crucible Intellectual Property, LLC
    Inventor: Theodore Andrew Waniuk
  • Patent number: 8911876
    Abstract: A method for forming pattern on substrate comprises steps of: providing a metal substrate; amorphousizing the metal substrate to from an amorphous pattern layer in the metal substrate; etching the metal substrate and forming an etching portion in the surface of the metal substrate which is not covered with the amorphous pattern layer. The article manufactured by the method is also provided.
    Type: Grant
    Filed: May 29, 2012
    Date of Patent: December 16, 2014
    Assignees: Shenzhen Futaihong Precision Industry Co., Ltd., FIH (Hong Kong) Limited
    Inventors: Quan Zhou, Xin-Wu Guan, Po-Feng Ho
  • Patent number: 8911572
    Abstract: A family of iron-based, phosphor-containing bulk metallic glasses having excellent processability and toughness, methods for forming such alloys, and processes for manufacturing articles therefrom are provided. The inventive iron-based alloy is based on the observation that by very tightly controlling the composition of the metalloid moiety of the Fe-based, P-containing bulk metallic glass alloys it is possible to obtain highly processable alloys with surprisingly low shear modulus and high toughness. Further, by incorporating small fractions of silicon (Si) and cobalt (Co) into the Fe—Ni—Mo—P—C—B system, alloys of 3 and 4 mm have been synthesized with high saturation magnetization and low switching losses.
    Type: Grant
    Filed: September 27, 2011
    Date of Patent: December 16, 2014
    Assignee: California Institute of Technology
    Inventors: Samuel T. Kim, Marios D. Demetriou, William L. Johnson
  • Patent number: 8911571
    Abstract: This invention discloses an L,R,C method and equipment for casting amorphous, ultracrystallite and crystallite metal slabs or other shaped metals. A workroom (8) with a constant temperature of tb=?190° C. and a constant pressure of pb=1 bar, and liquid nitrogen of ?190° C. and 1.877 bar is used as a cold source for cooling the casting blank. A liquid nitrogen ejector (5) ejects said liquid nitrogen to the surface of ferrous or non-ferrous metallic slabs or other shaped metals (7) with various ejection quantity v and various jet velocity k. Ejected liquid nitrogen comes into contact with the casting blank at cross section c shown in FIG. 2. This method adopts ultra thin film ejection technology, with a constant thickness of said film at 2 mm and ejection speed Kmax of said liquid nitrogen at 30 m/s.
    Type: Grant
    Filed: April 12, 2013
    Date of Patent: December 16, 2014
    Inventor: Zhuwen Ming
  • Publication number: 20140345919
    Abstract: A transparent conductor includes a metallic glass, and a method of manufacturing a transparent conductor includes: preparing a metallic glass or a mixture comprising the metallic glass; and firing the metallic glass or the mixture comprising the metallic glass at a predetermined temperature higher than a glass transition temperature of the metallic glass.
    Type: Application
    Filed: December 3, 2013
    Publication date: November 27, 2014
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Se Yun KIM, Eun Sung LEE, Keum Hwan PARK, Weon Ho SHIN, Suk Jun KIM, Jin Man PARK, Sang Soo JEE
  • Publication number: 20140346038
    Abstract: Provided are a crystalline alloy having significantly better thermal stability than an amorphous alloy as well as glass-forming ability, and a method of manufacturing the crystalline alloy. The present invention also provides an alloy sputtering target that is manufactured by using the crystalline alloy, and a method of manufacturing the alloy target. According to an aspect of the present invention, provided is a crystalline alloy having glass-forming ability which is formed of three or more elements having glass-forming ability, wherein the average grain size of the alloy is in a range of 0.1 ?m to 5 ?m and the alloy includes 5 at % to 20 at % of aluminum (Al), 15 at % to 40 at % of any one or more selected from copper (Cu) and nickel (Ni), and the remainder being zirconium (Zr).
    Type: Application
    Filed: December 4, 2012
    Publication date: November 27, 2014
    Inventors: Seung-Yong Shin, Kyoung-Il Moon, Ju-Hyun Sun, Chang-Hun Lee
  • Patent number: 8882940
    Abstract: Bulk solidifying amorphous alloys exhibiting improved processing and mechanical properties and methods of forming these alloys are provided. The bulk solidifying amorphous alloys are composed to have high Poisson's ratio values. Exemplary Pt-based bulk solidifying amorphous alloys having such high Poisson's ratio values are also described. The Pt-based alloys are based on Pt—Ni—Co—Cu—P alloys, and the mechanical properties of one exemplary alloy having a composition of substantially Pt57.5Cu14.7Ni5.3P22.5 are also described.
    Type: Grant
    Filed: February 1, 2012
    Date of Patent: November 11, 2014
    Assignee: Crucible Intellectual Property, LLC
    Inventors: William Johnson, Jan Schroers
  • Patent number: 8858739
    Abstract: A method and system of forming a micro-wire including heating metal feedstock to a liquid state within a glass tube, wherein the metal feedstock includes an iron based glass forming alloy comprising one or more of nickel and cobalt present in the range of 7 atomic percent to 50 atomic percent and one or more of boron, carbon, silicon, phosphorous and nitrogen present in the range of 1 to 35 atomic percent. Negative pressure may be provided to the interior the glass tube and the glass tube containing the metal feedstock may be drawn down. The metal feedstock in the glass tube may be cooled at a rate sufficient to form a wire exhibiting crystalline microstructures present in the range of 2 to 90 percent by volume in a glass matrix.
    Type: Grant
    Filed: October 22, 2010
    Date of Patent: October 14, 2014
    Assignee: The NanoSteel Company, Inc.
    Inventors: Daniel James Branagan, Alla V. Sergueeva, Jikou Zhou, James N. Milloway
  • Publication number: 20140283959
    Abstract: A method to form an enclosure or assembly which is fitted together and joined via a thermoplastic forming operation in order to seal the enclosure and hinder attempts to tamper with the contents.
    Type: Application
    Filed: September 30, 2011
    Publication date: September 25, 2014
    Applicant: Crucible Intellectual Property, LLC
    Inventors: Theodore Andrew Waniuk, Tran Quoc Pham, Dennis Ogawa
  • Patent number: 8795444
    Abstract: A method of thermomagnetically processing a material includes disposing a workpiece within a bore of a magnet; exposing the workpiece to a magnetic field of at least about 1 Tesla generated by the magnet; and, while exposing the workpiece to the magnetic field, applying heat energy to the workpiece at a plurality of frequencies to achieve spatially-controlled heating of the workpiece. An apparatus for thermomagnetically processing a material comprises: a high field strength magnet having a bore extending therethrough for insertion of a workpiece therein; and an energy source disposed adjacent to an entrance to the bore. The energy source is an emitter of variable frequency heat energy, and the bore comprises a waveguide for propagation of the variable frequency heat energy from the energy source to the workpiece.
    Type: Grant
    Filed: February 21, 2014
    Date of Patent: August 5, 2014
    Assignee: UT-Battelle, LLC
    Inventors: Roger A. Kisner, Orlando Rios, John B. Wilgen, Gerard M. Ludtka, Gail M. Ludtka
  • Patent number: 8776566
    Abstract: An apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool in combination with an electromagnetic force generated by the interaction of the applied current with a transverse magnetic field. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous metal and the equilibrium melting point of the alloy in a time scale of several milliseconds or less, at which point the interaction between the electric field and the magnetic field generates a force capable of shaping the heated sample into a high quality amorphous bulk article via any number of techniques including, for example, injection molding, dynamic forging, stamp forging, and blow molding in a time scale of less than one second.
    Type: Grant
    Filed: August 6, 2013
    Date of Patent: July 15, 2014
    Assignee: California Institute of Technology
    Inventors: William L. Johnson, Georg Kaltenboeck, Marios D. Demetriou, Scott N. Roberts, Konrad Samwer
  • Publication number: 20140150933
    Abstract: Metallic dental prostheses made of bulk-solidifying amorphous alloys wherein the dental prosthesis has an elastic strain limit of around 1.2% or more and methods of making such metallic dental prostheses are provided.
    Type: Application
    Filed: February 6, 2014
    Publication date: June 5, 2014
    Applicant: Crucible Intellectual Property, LLC
    Inventors: Atakan Peker, Choongnyun Paul Kim, Tranquoc Thebao Nguyen
  • Publication number: 20140096874
    Abstract: An article made of an alloy of the general formula Pt1-a-bMa(B1-xMdx)b in which i) M stands for one or a mixture of metallic element(s) of the group Zr, Ti, Fe, Ni, Co, Cu, Pd, Ag, Al; ii) Md stands for one or a mixture of several metalloids of the group Si, P, C, S, As, Ge; iii) a is smaller than 0.2; iv) b is comprised between 0.2 and 0.5; v) x is comprised between 0 and 0.8; vi) the overall P content, if present, is less than 10 atomic percent the proportions of the elements forming the alloy having been selected to confer a hardness of at least 400 HV, a melting point below 1000° C. and improved processibility to the alloy.
    Type: Application
    Filed: May 2, 2012
    Publication date: April 10, 2014
    Applicant: ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)
    Inventor: Ludger WEBER
  • Patent number: 8679267
    Abstract: The present disclosure relates to an iron based alloy composition that may include iron present in the range of 45 to 70 atomic percent, nickel present in the range of 10 to 30 atomic percent, cobalt present in the range of 0 to 15 atomic percent, boron present in the range of 7 to 25 atomic percent, carbon present in the range of 0 to 6 atomic percent, and silicon present in the range of 0 to 2 atomic percent, wherein the alloy composition exhibits an elastic strain of greater than 0.5% and a tensile strength of greater than 1 GPa.
    Type: Grant
    Filed: June 25, 2012
    Date of Patent: March 25, 2014
    Assignee: The NanoSteel Company, Inc.
    Inventors: Daniel James Branagan, Brian E. Meacham, Alla V. Sergueeva
  • Patent number: 8657967
    Abstract: The present invention is related to process for producing an amorphous Fe-based bulk metallic glass product, formed of an alloy having a chemical formula of Fe100-a-b-c-d-x-y MaNbbSicBdIxJy wherein: • M is Co and/or Ni, •I is one or more elements of the group consisting of Al, Cr, Cu, Mn, C and P, •J is one or more elements of the group consisting of Ti, S, N and O and wherein a, b, c, d, x and y are satisfying the following conditions: 0 wt. %<a?46. 1 wt. %, 5.4 wt. %?b?12.4 wt. %, 2.2 wt. %?c?4.4 wt. %, 2 wt. %<d?6 wt. %, x?2 wt. % and y?0.2 wt. %, the process comprising the steps of producing a master alloy by melting starting materials, comprising Fe-containing alloys, and by melting said master and pouring the molten alloy into a mold.
    Type: Grant
    Filed: April 15, 2009
    Date of Patent: February 25, 2014
    Assignee: OCAS Onderzoekscentrum voor Aanwending van Staal N.V.
    Inventors: Daniel Ruiz Romera, Serge Claessens, Marc De Wulf, Nele Van Steenberge, Joachim Antonissen
  • Patent number: 8641840
    Abstract: The present disclosure is directed and formulations and methods to provide non-stainless steel alloys having relative high strength and ductility. The alloys may be provided in sheet or pressed form and characterized by their particular alloy chemistries and identifiable crystalline grain size morphology. The alloys are such that they include boride pinning phases. In what is termed a Class 1 Steel the alloys indicate tensile strengths of 630 MPa to 1100 MPa and elongations of 10-40%. Class 2 Steel indicates tensile strengths of 875 MPa to 1590 MPa and elongations of 5-30%. Class 3 Steel indicates tensile strengths of 1000 MPa to 1750 MPa and elongations of 0.5-15%.
    Type: Grant
    Filed: April 16, 2013
    Date of Patent: February 4, 2014
    Assignee: The NanoSteel Company, Inc.
    Inventors: Daniel James Branagan, Brian E. Meacham, Jason K. Walleser, Andrew T. Ball, Grant G. Justice, Brendan L. Nation, Sheng Cheng, Alla V. Sergueeva
  • Patent number: 8641839
    Abstract: The present invention relates to materials, methods and apparatuses for performing imprint lithography using amorphous metallic materials. The amorphous metallic materials can be employed as imprint media and thermoplastic forming processes are applied during the pattern transfer procedure to produce micron scale and nanoscale patterns in the amorphous metallic layer. The pattern transfer is in the form of direct mask embossing or through a serial nano-indentation process. A rewriting process is also disclosed, which involves an erasing mechanism that is accomplished by means of a second thermoplastic forming process. The amorphous metallic materials may also be used directly as an embossing mold in imprint lithography to allow high volume imprint nano-manufacturing. This invention also comprises of a method of smoothening surfaces under the action of the surface tension alone.
    Type: Grant
    Filed: February 13, 2008
    Date of Patent: February 4, 2014
    Assignee: Yale University
    Inventors: Jan Schroers, Golden Kumar, Hongxing Tang
  • Publication number: 20140007989
    Abstract: Provided in one embodiment is a method of selective microstructural transformation, comprising: providing a part comprising a bulk amorphous alloy; heating selectively a portion of the part to a first temperature such that at least some of the portion is transformed into a crystalline phase; and processing the transformed portion.
    Type: Application
    Filed: July 5, 2012
    Publication date: January 9, 2014
    Inventors: CHRISTOPHER D. PREST, Matthew S. Scott, Stephen P. Zadesky, Dermot J. Stratton, Joseph C. Poole
  • Publication number: 20130340897
    Abstract: Disclosed is an improved bulk metallic glass alloy and methods of making the alloy in which the alloy has the structure ZraNbbCucNidAle, wherein a-e represent the atomic percentage of each respective element, and wherein b/a is less than about 0.040, and c/d is less than 1.15. The bulk metallic glass alloy has improved thermal stability and an increased super cooled liquid region rendering it capable of being thermoplastically formed into a variety of shapes and sizes.
    Type: Application
    Filed: June 25, 2012
    Publication date: December 26, 2013
    Inventors: QUOC TRAN PHAM, Theodore A. Waniuk
  • Patent number: 8613815
    Abstract: An apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via any number of techniques including, for example, injection molding, dynamic forging, stamp forging, sheet forming, and blow molding in a time frame of less than 1 second.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: December 24, 2013
    Assignee: California Institute of Technology
    Inventors: William L. Johnson, Marios D. Demetriou, Joseph P. Schramm
  • Patent number: 8613814
    Abstract: A forging apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via forging in a time frame of less than 1 second.
    Type: Grant
    Filed: October 13, 2011
    Date of Patent: December 24, 2013
    Assignee: California Institute of Technology
    Inventors: Georg Kaltenboeck, Joseph P. Schramm, Marios D. Demetriou, William L. Johnson
  • Patent number: 8613813
    Abstract: An apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via any number of techniques including, for example, injection molding, dynamic forging, stamp forging, and blow molding in a time frame of less than 1 second.
    Type: Grant
    Filed: March 23, 2009
    Date of Patent: December 24, 2013
    Assignee: California Institute of Technology
    Inventors: William L. Johnson, Marios D. Demetriou, Choong Paul Kim, Joseph P. Schramm
  • Patent number: 8613812
    Abstract: A method of making a Zr-rich amorphous alloy article includes providing a Zr-rich master alloy made of an Zr—Cu—Al—Ni—Nb alloy, in which the purity of the raw Zr is substantially in a range of 98% to 99.9%; providing a vacuum induction furnace, and melting the Zr-rich master alloy in the furnace at a temperature in a range of 1100 degrees Celsius to 1200 degrees Celsius; cooling the master alloy to a temperature in a range from 800 degrees Celsius to 900 degrees Celsius in 30 min to 40 min; casting the master alloy into ingots, and then cooling the ingots to a temperature in a range from 200 degrees Celsius to 350 degrees Celsius; and die casting the alloy ingots to obtain Zr-rich amorphous alloy articles with thicknesses in a range of 0.5 mm to 2 mm. A Zr-rich amorphous alloy article made by the above-mentioned method is further provided.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: December 24, 2013
    Assignees: Hong Fu Jin Precision Industry (ShenZhen) Co., Ltd., Hon Hai Precision Industry Co., Ltd.
    Inventors: Xiao-Bo Yuan, Yi-Min Jiang, Jun-Qi Li
  • Patent number: 8613816
    Abstract: An apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming magnetic metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via any number of techniques including, for example, injection molding, dynamic forging, stamp forging, sheet forming, and blow molding in a time frame of less than 1 second.
    Type: Grant
    Filed: January 30, 2012
    Date of Patent: December 24, 2013
    Assignee: California Institute of Technology
    Inventors: Georg Kaltenboeck, Joseph P. Schramm, Marios D. Demetriou, William L. Johnson
  • Patent number: RE45353
    Abstract: A method of making composites of bulk-solidifying amorphous alloys, and articles made thereof, containing at least one type or reinforcement material, wherein the composite material preferably comprises a high volume fraction of reinforcement material and is fully-dense with minimum porosity are provided.
    Type: Grant
    Filed: July 14, 2011
    Date of Patent: January 27, 2015
    Assignee: Crucible Intellectual Property, LLC
    Inventor: Atakan Peker